DE19522195A1 - Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt. - Google Patents
Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt.Info
- Publication number
- DE19522195A1 DE19522195A1 DE19522195A DE19522195A DE19522195A1 DE 19522195 A1 DE19522195 A1 DE 19522195A1 DE 19522195 A DE19522195 A DE 19522195A DE 19522195 A DE19522195 A DE 19522195A DE 19522195 A1 DE19522195 A1 DE 19522195A1
- Authority
- DE
- Germany
- Prior art keywords
- trifluoro
- naphthalene example
- diyl
- atoms
- naphthalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 28
- CWLKTJOTWITYSI-UHFFFAOYSA-N 1-fluoronaphthalene Chemical compound C1=CC=C2C(F)=CC=CC2=C1 CWLKTJOTWITYSI-UHFFFAOYSA-N 0.000 title 1
- -1 cyclopropan-1,2-diyl Chemical group 0.000 claims abstract description 687
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 57
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 27
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 14
- 125000005407 trans-1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])[C@]([H])([*:2])C([H])([H])C([H])([H])[C@@]1([H])[*:1] 0.000 claims abstract description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims abstract description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 12
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims abstract description 7
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims abstract description 7
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims abstract description 6
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 claims abstract description 5
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims abstract description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229930188620 butyrolactone Natural products 0.000 claims abstract description 3
- 125000004434 sulfur atom Chemical group 0.000 claims abstract description 3
- KLMSCYBXDCTEPC-UHFFFAOYSA-N 1,2,8-trifluoronaphthalene Chemical compound C1=CC=C(F)C2=C(F)C(F)=CC=C21 KLMSCYBXDCTEPC-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 60
- 239000000203 mixture Substances 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 9
- 125000005714 2,5- (1,3-dioxanylene) group Chemical group [H]C1([H])OC([H])([*:1])OC([H])([H])C1([H])[*:2] 0.000 claims description 6
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 2
- DSLKOTQBUFGMQY-UHFFFAOYSA-N 1,2,3-trifluoronaphthalene Chemical class C1=CC=C2C(F)=C(F)C(F)=CC2=C1 DSLKOTQBUFGMQY-UHFFFAOYSA-N 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 abstract description 3
- 125000005839 3,4,5-trifluoronaphthalene-2,6-diyl group Chemical group [H]C1=C([H])C2=C([H])C([*:1])=C(F)C(F)=C2C(F)=C1[*:2] 0.000 abstract description 2
- JNCMHMUGTWEVOZ-UHFFFAOYSA-N F[CH]F Chemical compound F[CH]F JNCMHMUGTWEVOZ-UHFFFAOYSA-N 0.000 abstract 1
- 108010081348 HRT1 protein Hairy Proteins 0.000 abstract 1
- 102100021881 Hairy/enhancer-of-split related with YRPW motif protein 1 Human genes 0.000 abstract 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 abstract 1
- VUWZPRWSIVNGKG-UHFFFAOYSA-N fluoromethane Chemical compound F[CH2] VUWZPRWSIVNGKG-UHFFFAOYSA-N 0.000 abstract 1
- 125000004785 fluoromethoxy group Chemical group [H]C([H])(F)O* 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 340
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 162
- QVGRUGAWUACWGZ-UHFFFAOYSA-N 1-tetradecylnaphthalene Chemical compound C1=CC=C2C(CCCCCCCCCCCCCC)=CC=CC2=C1 QVGRUGAWUACWGZ-UHFFFAOYSA-N 0.000 description 64
- 125000000246 pyrimidin-2-yl group Chemical group [H]C1=NC(*)=NC([H])=C1[H] 0.000 description 61
- AZLNHMGSTZDDIY-UHFFFAOYSA-N 1-nonylnaphthalene Chemical compound C1=CC=C2C(CCCCCCCCC)=CC=CC2=C1 AZLNHMGSTZDDIY-UHFFFAOYSA-N 0.000 description 59
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 42
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 29
- HOZQSRMTDXZVPJ-UHFFFAOYSA-N 3-butyloxirane-2-carboxylic acid Chemical compound CCCCC1OC1C(O)=O HOZQSRMTDXZVPJ-UHFFFAOYSA-N 0.000 description 19
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 18
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 239000002253 acid Substances 0.000 description 12
- 150000002148 esters Chemical class 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 239000012071 phase Substances 0.000 description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 10
- 239000005262 ferroelectric liquid crystals (FLCs) Substances 0.000 description 10
- ZUXGVGARWYYZKY-UHFFFAOYSA-N 3-propyloxirane-2-carboxylic acid Chemical compound CCCC1OC1C(O)=O ZUXGVGARWYYZKY-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- MTAODLNXWYIKSO-UHFFFAOYSA-N 2-fluoropyridine Chemical compound FC1=CC=CC=N1 MTAODLNXWYIKSO-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000004990 Smectic liquid crystal Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 229910000104 sodium hydride Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000012442 inert solvent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000005447 octyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 239000012312 sodium hydride Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 150000000185 1,3-diols Chemical class 0.000 description 2
- VMKOFRJSULQZRM-UHFFFAOYSA-N 1-bromooctane Chemical compound CCCCCCCCBr VMKOFRJSULQZRM-UHFFFAOYSA-N 0.000 description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003098 cholesteric effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 150000002440 hydroxy compounds Chemical class 0.000 description 2
- 238000000819 phase cycle Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- VCGRFBXVSFAGGA-UHFFFAOYSA-N (1,1-dioxo-1,4-thiazinan-4-yl)-[6-[[3-(4-fluorophenyl)-5-methyl-1,2-oxazol-4-yl]methoxy]pyridin-3-yl]methanone Chemical compound CC=1ON=C(C=2C=CC(F)=CC=2)C=1COC(N=C1)=CC=C1C(=O)N1CCS(=O)(=O)CC1 VCGRFBXVSFAGGA-UHFFFAOYSA-N 0.000 description 1
- SOCAXRLFGRNEPK-IFZYUDKTSA-N (1r,3s,5r)-2-n-[1-carbamoyl-5-(cyanomethoxy)indol-3-yl]-3-n-[(3-chloro-2-fluorophenyl)methyl]-2-azabicyclo[3.1.0]hexane-2,3-dicarboxamide Chemical compound O=C([C@@H]1C[C@H]2C[C@H]2N1C(=O)NC1=CN(C2=CC=C(OCC#N)C=C21)C(=O)N)NCC1=CC=CC(Cl)=C1F SOCAXRLFGRNEPK-IFZYUDKTSA-N 0.000 description 1
- DOMQFIFVDIAOOT-ROUUACIJSA-N (2S,3R)-N-[4-(2,6-dimethoxyphenyl)-5-(5-methylpyridin-3-yl)-1,2,4-triazol-3-yl]-3-(5-methylpyrimidin-2-yl)butane-2-sulfonamide Chemical compound COC1=C(C(=CC=C1)OC)N1C(=NN=C1C=1C=NC=C(C=1)C)NS(=O)(=O)[C@@H](C)[C@H](C)C1=NC=C(C=N1)C DOMQFIFVDIAOOT-ROUUACIJSA-N 0.000 description 1
- MAYZWDRUFKUGGP-VIFPVBQESA-N (3s)-1-[5-tert-butyl-3-[(1-methyltetrazol-5-yl)methyl]triazolo[4,5-d]pyrimidin-7-yl]pyrrolidin-3-ol Chemical compound CN1N=NN=C1CN1C2=NC(C(C)(C)C)=NC(N3C[C@@H](O)CC3)=C2N=N1 MAYZWDRUFKUGGP-VIFPVBQESA-N 0.000 description 1
- HGRWHBQLRXWSLV-DEOSSOPVSA-N (4s)-3'-(3,6-dihydro-2h-pyran-5-yl)-1'-fluoro-7'-(3-fluoropyridin-2-yl)spiro[5h-1,3-oxazole-4,5'-chromeno[2,3-c]pyridine]-2-amine Chemical compound C1OC(N)=N[C@]21C1=CC(C=3COCCC=3)=NC(F)=C1OC1=CC=C(C=3C(=CC=CN=3)F)C=C12 HGRWHBQLRXWSLV-DEOSSOPVSA-N 0.000 description 1
- UKGJZDSUJSPAJL-YPUOHESYSA-N (e)-n-[(1r)-1-[3,5-difluoro-4-(methanesulfonamido)phenyl]ethyl]-3-[2-propyl-6-(trifluoromethyl)pyridin-3-yl]prop-2-enamide Chemical compound CCCC1=NC(C(F)(F)F)=CC=C1\C=C\C(=O)N[C@H](C)C1=CC(F)=C(NS(C)(=O)=O)C(F)=C1 UKGJZDSUJSPAJL-YPUOHESYSA-N 0.000 description 1
- ZGYIXVSQHOKQRZ-COIATFDQSA-N (e)-n-[4-[3-chloro-4-(pyridin-2-ylmethoxy)anilino]-3-cyano-7-[(3s)-oxolan-3-yl]oxyquinolin-6-yl]-4-(dimethylamino)but-2-enamide Chemical compound N#CC1=CN=C2C=C(O[C@@H]3COCC3)C(NC(=O)/C=C/CN(C)C)=CC2=C1NC(C=C1Cl)=CC=C1OCC1=CC=CC=N1 ZGYIXVSQHOKQRZ-COIATFDQSA-N 0.000 description 1
- MOWXJLUYGFNTAL-DEOSSOPVSA-N (s)-[2-chloro-4-fluoro-5-(7-morpholin-4-ylquinazolin-4-yl)phenyl]-(6-methoxypyridazin-3-yl)methanol Chemical compound N1=NC(OC)=CC=C1[C@@H](O)C1=CC(C=2C3=CC=C(C=C3N=CN=2)N2CCOCC2)=C(F)C=C1Cl MOWXJLUYGFNTAL-DEOSSOPVSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 125000004955 1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])C1([H])[*:2] 0.000 description 1
- APWRZPQBPCAXFP-UHFFFAOYSA-N 1-(1-oxo-2H-isoquinolin-5-yl)-5-(trifluoromethyl)-N-[2-(trifluoromethyl)pyridin-4-yl]pyrazole-4-carboxamide Chemical compound O=C1NC=CC2=C(C=CC=C12)N1N=CC(=C1C(F)(F)F)C(=O)NC1=CC(=NC=C1)C(F)(F)F APWRZPQBPCAXFP-UHFFFAOYSA-N 0.000 description 1
- MJUVRTYWUMPBTR-MRXNPFEDSA-N 1-(2,2-difluoro-1,3-benzodioxol-5-yl)-n-[1-[(2r)-2,3-dihydroxypropyl]-6-fluoro-2-(1-hydroxy-2-methylpropan-2-yl)indol-5-yl]cyclopropane-1-carboxamide Chemical compound FC=1C=C2N(C[C@@H](O)CO)C(C(C)(CO)C)=CC2=CC=1NC(=O)C1(C=2C=C3OC(F)(F)OC3=CC=2)CC1 MJUVRTYWUMPBTR-MRXNPFEDSA-N 0.000 description 1
- ABDDQTDRAHXHOC-QMMMGPOBSA-N 1-[(7s)-5,7-dihydro-4h-thieno[2,3-c]pyran-7-yl]-n-methylmethanamine Chemical compound CNC[C@@H]1OCCC2=C1SC=C2 ABDDQTDRAHXHOC-QMMMGPOBSA-N 0.000 description 1
- CWZUTHDJLNZLCM-DFBGVHRSSA-N 1-[2-[(1r,3s,5r)-3-[(6-bromopyridin-2-yl)carbamoyl]-2-azabicyclo[3.1.0]hexan-2-yl]-2-oxoethyl]indazole-3-carboxamide Chemical compound O=C([C@@H]1C[C@H]2C[C@H]2N1C(=O)CN1N=C(C2=CC=CC=C21)C(=O)N)NC1=CC=CC(Br)=N1 CWZUTHDJLNZLCM-DFBGVHRSSA-N 0.000 description 1
- MNDIARAMWBIKFW-UHFFFAOYSA-N 1-bromohexane Chemical compound CCCCCCBr MNDIARAMWBIKFW-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- MZOGBVZHJWAQSG-UHFFFAOYSA-N 1-octylnaphthalene Chemical compound C1=CC=C2C(CCCCCCCC)=CC=CC2=C1 MZOGBVZHJWAQSG-UHFFFAOYSA-N 0.000 description 1
- OXPDQFOKSZYEMJ-UHFFFAOYSA-N 2-phenylpyrimidine Chemical class C1=CC=CC=C1C1=NC=CC=N1 OXPDQFOKSZYEMJ-UHFFFAOYSA-N 0.000 description 1
- HCDMJFOHIXMBOV-UHFFFAOYSA-N 3-(2,6-difluoro-3,5-dimethoxyphenyl)-1-ethyl-8-(morpholin-4-ylmethyl)-4,7-dihydropyrrolo[4,5]pyrido[1,2-d]pyrimidin-2-one Chemical compound C=1C2=C3N(CC)C(=O)N(C=4C(=C(OC)C=C(OC)C=4F)F)CC3=CN=C2NC=1CN1CCOCC1 HCDMJFOHIXMBOV-UHFFFAOYSA-N 0.000 description 1
- BYHQTRFJOGIQAO-GOSISDBHSA-N 3-(4-bromophenyl)-8-[(2R)-2-hydroxypropyl]-1-[(3-methoxyphenyl)methyl]-1,3,8-triazaspiro[4.5]decan-2-one Chemical compound C[C@H](CN1CCC2(CC1)CN(C(=O)N2CC3=CC(=CC=C3)OC)C4=CC=C(C=C4)Br)O BYHQTRFJOGIQAO-GOSISDBHSA-N 0.000 description 1
- YGYGASJNJTYNOL-CQSZACIVSA-N 3-[(4r)-2,2-dimethyl-1,1-dioxothian-4-yl]-5-(4-fluorophenyl)-1h-indole-7-carboxamide Chemical compound C1CS(=O)(=O)C(C)(C)C[C@@H]1C1=CNC2=C(C(N)=O)C=C(C=3C=CC(F)=CC=3)C=C12 YGYGASJNJTYNOL-CQSZACIVSA-N 0.000 description 1
- WNEODWDFDXWOLU-QHCPKHFHSA-N 3-[3-(hydroxymethyl)-4-[1-methyl-5-[[5-[(2s)-2-methyl-4-(oxetan-3-yl)piperazin-1-yl]pyridin-2-yl]amino]-6-oxopyridin-3-yl]pyridin-2-yl]-7,7-dimethyl-1,2,6,8-tetrahydrocyclopenta[3,4]pyrrolo[3,5-b]pyrazin-4-one Chemical compound C([C@@H](N(CC1)C=2C=NC(NC=3C(N(C)C=C(C=3)C=3C(=C(N4C(C5=CC=6CC(C)(C)CC=6N5CC4)=O)N=CC=3)CO)=O)=CC=2)C)N1C1COC1 WNEODWDFDXWOLU-QHCPKHFHSA-N 0.000 description 1
- SRVXSISGYBMIHR-UHFFFAOYSA-N 3-[3-[3-(2-amino-2-oxoethyl)phenyl]-5-chlorophenyl]-3-(5-methyl-1,3-thiazol-2-yl)propanoic acid Chemical compound S1C(C)=CN=C1C(CC(O)=O)C1=CC(Cl)=CC(C=2C=C(CC(N)=O)C=CC=2)=C1 SRVXSISGYBMIHR-UHFFFAOYSA-N 0.000 description 1
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- DOWVMJFBDGWVML-UHFFFAOYSA-N n-cyclohexyl-n-methyl-4-(1-oxidopyridin-1-ium-3-yl)imidazole-1-carboxamide Chemical compound C1=NC(C=2C=[N+]([O-])C=CC=2)=CN1C(=O)N(C)C1CCCCC1 DOWVMJFBDGWVML-UHFFFAOYSA-N 0.000 description 1
- NNKPHNTWNILINE-UHFFFAOYSA-N n-cyclopropyl-3-fluoro-4-methyl-5-[3-[[1-[2-[2-(methylamino)ethoxy]phenyl]cyclopropyl]amino]-2-oxopyrazin-1-yl]benzamide Chemical compound CNCCOC1=CC=CC=C1C1(NC=2C(N(C=3C(=C(F)C=C(C=3)C(=O)NC3CC3)C)C=CN=2)=O)CC1 NNKPHNTWNILINE-UHFFFAOYSA-N 0.000 description 1
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- LZMJNVRJMFMYQS-UHFFFAOYSA-N poseltinib Chemical compound C1CN(C)CCN1C(C=C1)=CC=C1NC1=NC(OC=2C=C(NC(=O)C=C)C=CC=2)=C(OC=C2)C2=N1 LZMJNVRJMFMYQS-UHFFFAOYSA-N 0.000 description 1
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- XIIOFHFUYBLOLW-UHFFFAOYSA-N selpercatinib Chemical compound OC(COC=1C=C(C=2N(C=1)N=CC=2C#N)C=1C=NC(=CC=1)N1CC2N(C(C1)C2)CC=1C=NC(=CC=1)OC)(C)C XIIOFHFUYBLOLW-UHFFFAOYSA-N 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- XGVXKJKTISMIOW-ZDUSSCGKSA-N simurosertib Chemical compound N1N=CC(C=2SC=3C(=O)NC(=NC=3C=2)[C@H]2N3CCC(CC3)C2)=C1C XGVXKJKTISMIOW-ZDUSSCGKSA-N 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 1
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- 125000006850 spacer group Chemical group 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
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- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/30—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
- C07C25/18—Polycyclic aromatic halogenated hydrocarbons
- C07C25/22—Polycyclic aromatic halogenated hydrocarbons with condensed rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
- C07C43/174—Unsaturated ethers containing halogen containing six-membered aromatic rings
- C07C43/1742—Unsaturated ethers containing halogen containing six-membered aromatic rings with halogen atoms bound to the aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
- C07C43/174—Unsaturated ethers containing halogen containing six-membered aromatic rings
- C07C43/1747—Unsaturated ethers containing halogen containing six-membered aromatic rings containing six membered aromatic rings and other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/62—Halogen-containing esters
- C07C69/63—Halogen-containing esters of saturated acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/26—Radicals substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
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- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
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Abstract
Description
Neben nematischen und cholesterischen Flüssigkristallen werden in jüngerer Zeit auch optisch aktive geneigt smektische (ferroelektrische) Flüssigkristalle in kommerziellen Displayvorrichtungen verwendet.In addition to nematic and cholesteric liquid crystals, more recently also optically active inclined smectic (ferroelectric) liquid crystals in commercial display devices used.
Clark und Lagerwall konnten zeigen, daß der Einsatz ferroelektrischer Flüssigkristalle (FLC) in sehr dünnen Zellen zu optoelektrischen Schalt- oder Anzeigeelementen führt, die im Vergleich zu den herkömmlichen TN ("twisted nematic")-Zellen um bis zu einem Faktor 1000 schnellere Schaltzeiten haben (siehe z. B. EP-A 0 032 362). Aufgrund dieser und anderer günstiger Eigenschaften, z. B. der bistabilen Schaltmöglichkeit und des nahezu blickwinkelunabhängigen Kontrasts, sind FLCs grundsätzlich für Anwendungsgebiete wie Computerdisplays gut geeignet.Clark and Lagerwall were able to show that the use of ferroelectric Liquid crystals (FLC) in very thin cells for optoelectric switching or Display elements leads, which compared to the conventional TN ("twisted nematic ") cells have switching times that are up to a factor of 1000 faster (see e.g. EP-A 0 032 362). Because of this and others cheaper Properties, e.g. B. the bistable switching option and almost angle-independent contrast, FLCs are basically for Areas of application such as computer displays are well suited.
Für die Verwendung von FLCs in elektrooptischen oder vollständig optischen Bauelementen benötigt man entweder Verbindungen, die geneigte bzw. orthogonale smektische Phasen ausbilden und selbst optisch aktiv sind, oder man kann durch Dotierung von Verbindungen, die zwar solche smektischen Phasen ausbilden, selbst aber nicht optisch aktiv sind, mit optisch aktiven Verbindungen ferroelektrische smektische Phasen induzieren. Die gewünschte Phase soll dabei über einen möglichst großen Temperaturbereich stabil sein.For the use of FLCs in electro-optical or completely optical Components either require connections that are inclined or form orthogonal smectic phases and are themselves optically active, or one can by doping compounds that are smectic Form phases, but are not optically active themselves, with optically active ones Compounds induce ferroelectric smectic phases. The desired The phase should be stable over the largest possible temperature range.
Zur Erzielung eines guten Kontrastverhältnisses in elektrooptischen Bauelementen ist eine einheitliche planare Orientierung der Flüssigkristalle nötig. Eine gute Orientierung in der SA und S*C-Phase läßt sich z. B. erreichen, wenn die Phasenfolge der Flüssigkristallmischung mit abnehmender Temperatur lautet:A uniform planar orientation of the liquid crystals is necessary to achieve a good contrast ratio in electro-optical components. A good orientation in the S A and S * C phase can e.g. B. achieve if the phase sequence of the liquid crystal mixture with decreasing temperature is:
Isotrop → N* → SA → S*C Isotropic → N * → S A → S * C
Voraussetzung ist, daß der Pitch (Ganghöhe der Helix) in der N*-Phase sehr groß (größer 10 µm) oder, noch besser, völlig kompensiert ist (siehe z. B. T. Matsumoto et al., p. 468-470, Proc. of the 6th Int. Display Research Conf., Japan Display, Sept. 30 - Okto. 2, 1986, Tokyo, Japan; M. Murakami et al., ibid. S. 344 - S. 347). Dies erreicht man z. B., indem man zu der chiralen Flüssigkristallmischung, die in der N*-Phase z. B. eine linksdrehende Helix aufweist, einen oder mehrere optisch aktive Dotierstoffe, die eine rechtsdrehende Helix induzieren, in solchen Mengen hinzugibt, daß die Helix kompensiert wird.The prerequisite is that the pitch (pitch of the helix) is very high in the N * phase large (larger than 10 µm) or, even better, completely compensated (see e.g. T. Matsumoto et al., P. 468-470, Proc. of the 6th Int. Display Research Conf., Japan Display, Sept. 30 - Octo. 2, 1986, Tokyo, Japan; M. Murakami et al., ibid. P. 344 - p. 347). This is achieved e.g. B. by going to the chiral Liquid crystal mixture which in the N * phase z. B. a left-turning helix has one or more optically active dopants, the one induce clockwise helix in such amounts that the helix is compensated.
Für die Verwendung des SSFLCD-Effektes (Surface Stabilized Ferroelectric Liquid Crystal Display) von Clark und Lagerwall zur einheitlichen, planaren Orientierung ist ferner Voraussetzung, daß der Pitch in der smektischen C* Phase wesentlich größer ist als die Dicke des Anzeigeelementes (Mol. Cryst. Liq. Cryst. 94 (1983) 213-134 und 114 (1984) 151-187). Dies erreicht man, wie im Fall des cholesterischen Pitches, durch Verwendung von Dotierstoffen mit entgegengesetztem Drehsinn der Helix.For the use of the SSFLCD effect (Surface Stabilized Ferroelectric Liquid Crystal Display) from Clark and Lagerwall for uniform, planar Orientation is also a prerequisite that the pitch in the smectic C * Phase is significantly greater than the thickness of the display element (Mol. Cryst. Liq. Cryst. 94 (1983) 213-134 and 114 (1984) 151-187). This is achieved, as in the Case of cholesteric pitch, by using dopants with opposite direction of rotation of the helix.
Die optische Schaltzeit T [µs] ferroelektrischer Flüssigkristallsysteme, die möglichst kurz sein soll, hängt von der Rotationsviskosität des Systems Y [mPas], der spontanen Polarisation PS[nC/cm²] und der elektrischen Feldstärke E[V/m] ab nach der BeziehungThe optical switching time T [µs] of ferroelectric liquid crystal systems, which should be as short as possible, depends on the rotational viscosity of the system Y [mPas], the spontaneous polarization P S [nC / cm²] and the electric field strength E [V / m] according to relationship
Da die Feldstärke E durch den Elektrodenabstand im elektrooptischen Bauteil und durch die angelegte Spannung festgelegt ist, muß das ferroelektrische Anzeigemedium niedrigviskos sein und eine hohe spontane Polarisation aufweisen, damit eine kurze Schaltzeit erreicht wird. Since the field strength E is due to the electrode spacing in the electro-optical component and is determined by the applied voltage, the ferroelectric Display medium be low viscosity and high spontaneous polarization have so that a short switching time is achieved.
Schließlich wird neben thermischer, chemischer und photochemischer Stabilität eine kleine optische Anisotropie Δn, vorzugsweise ≈ 0,13, und eine geringe positive oder vorzugsweise negative dielektrische Anisotropie Δ∈ verlangt (siehe z. B. S.T. Lagerwall et al., "Ferroelectric Liquid Crystals for Displays" SID Symposium, Oct. Meeting 1985, San Diego, Ca, USA). Die Gesamtheit dieser Forderungen ist nur mit Mischungen aus mehreren Komponenten zu erfüllen. Als Basis (oder Matrix) dienen dabei bevorzugt Verbindungen, die möglichst selbst bereits die gewünschte Phasenfolge I→N→SA→SC aufweisen. Weitere Komponenten der Mischung werden oftmals zur Schmelzpunktserniedrigung und zur Verbreiterung der SC- und meist auch N-Phase, zum Induzieren der optischen Aktivität, zur Pitch-Kompensation und zur Anpassung der optischen und dielektrischen Anisotropie zugesetzt, wobei aber beispielsweise die Rotationsviskosität möglichst nicht vergrößert werden soll.Finally, in addition to thermal, chemical and photochemical stability, a small optical anisotropy Δn, preferably ≈ 0.13, and a low positive or preferably negative dielectric anisotropy Δ∈ are required (see, for example, BST Lagerwall et al., "Ferroelectric Liquid Crystals for Displays" SID Symposium, Oct. Meeting 1985, San Diego, Ca, USA). All of these requirements can only be met with mixtures of several components. The basis (or matrix) used is preferably compounds which, if possible, already have the desired phase sequence I → N → S A → S C. Other components of the mixture are often added to lower the melting point and broaden the S C - and usually also the N phase, to induce optical activity, to compensate for pitch and to adjust the optical and dielectric anisotropy, but, for example, do not increase the rotational viscosity if possible shall be.
Ferroelektrische Flüssigkristallanzeigen lassen sich auch durch Nutzung des DHF (Distorted Helix Formation)-Effektes oder des PSFLCD-Effektes (Pitch Stabilized Ferroelectric Liquid Crystal Display, auch SBF = Short pitch Bistable Ferroelektric Effekt genannt) betreiben. Der DHF-Effekt wurde von B.I. Ostrovski in Advances in Liquid Crystal Research and Applications, Oxford/Budapest 1980, 469 ff. beschrieben, der PSFLCD-Effekt ist in DE-A 39 20 625 bzw. EP-A 0 405 346 beschrieben. Zur Nutzung dieser Effekte wird im Gegensatz zum SSFLCD-Effekt ein flüssigkristallines Material mit einem kurzen SC-Pitch benötigt.Ferroelectric liquid crystal displays can also be operated by using the DHF (Distorted Helix Formation) effect or the PSFLCD effect (Pitch Stabilized Ferroelectric Liquid Crystal Display, also called SBF = Short pitch Bistable Ferroelectric Effect). The DHF effect was described by BI Ostrovski in Advances in Liquid Crystal Research and Applications, Oxford / Budapest 1980, 469 ff., The PSFLCD effect is described in DE-A 39 20 625 and EP-A 0 405 346. In contrast to the SSFLCD effect, a liquid crystal material with a short S C pitch is required to use these effects.
Naphthalinderivate zur Verwendung in Flüssigkristallmischungen sind beispielsweise aus der WO-A 92/16500 bekannt.Naphthalene derivatives are for use in liquid crystal mixtures known for example from WO-A 92/16500.
Da die Entwicklung, insbesondere von ferroelektrischen Flüssigkristallmischungen, aber noch in keiner Weise als abgeschlossen betrachtet werden kann, sind die Hersteller von Displays an den unterschiedlichsten Komponenten für Mischungen interessiert. Dieses u. a. auch deshalb, weil erst das Zusammenwirken der flüssigkristallinen Mischungen mit den einzelnen Bauteilen der Anzeigevorrichtung bzw. der Zellen (z. B. der Orientierungsschicht) Rückschlüsse auf die Qualität auch der flüssigkristallinen Mischungen zuläßt.Because the development, especially of ferroelectric Liquid crystal mixtures, but in no way as complete can be considered, the manufacturers of displays on the various components interested in mixtures. This u. a. also because only the interaction of the liquid crystalline mixtures with the individual components of the display device or the cells (e.g. the Orientation layer) conclusions on the quality of the liquid crystalline Allows mixtures.
Aufgabe der vorliegenden Erfindung war es daher, neue Verbindungen bereitzustellen, die in flüssigkristallinen Mischungen geeignet sind, das Eigenschaftsprofil dieser Mischungen zu verbessern.The object of the present invention was therefore to create new compounds To provide, which are suitable in liquid crystalline mixtures, the To improve the property profile of these mixtures.
Es wurde nun überraschend gefunden, daß 2,6-disubstituierte 3,4,5-Trifluornaphthalin-Derivate der Formel (I) in besonderer Weise zum Einsatz in Flüssigkristallmischungen geeignet sind.It has now surprisingly been found that 2,6-disubstituted 3,4,5-trifluoronaphthalene derivatives of the formula (I) for use in Liquid crystal mixtures are suitable.
Gegenstand der Erfindung sind daher Verbindungen der Formel (I)The invention therefore relates to compounds of the formula (I)
R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e-B(-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)k-R² (I)R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (-A⁴) i (- M⁶) k -R² (I)
in der die Symbole und Indizes folgende Bedeutungen haben:
die Gruppe B istin which the symbols and indices have the following meanings:
is group B.
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 20 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂- Gruppen durch -O-, -S-, -CO-O-, -O-CO-, -O-CO-O-, -CO-, -CS-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂-, 1,4-Phenylen, trans-1,4-Cyclohexylen oder trans-1,3-Cyclopentylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome und/oder Schwefelatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -Br, -OR³, -SCN, -OCN oder -N₃ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch):R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 20 C atoms (with or without asymmetric carbon atom), one or more CH₂- Groups by -O-, -S-, -CO-O-, -O-CO-, -O-CO-O-, -CO-, -CS-, -CH = CH-, -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂-, 1,4-phenylene, trans-1,4-cyclohexylene or trans-1,3-cyclopentylene can be replaced can, with the proviso that oxygen atoms and / or Sulfur atoms are not directly bound to one another may, and / or wherein one or more H atoms of the alkyl radical be substituted by -F, -Cl, -Br, -OR³, -SCN, -OCN or -N₃ can, or one of the following groups (optically active or racemic):
R³, R⁴, R⁵, R⁶, R⁷ sind gleich oder verschieden Wasserstoff oder ein
geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen
(mit oder ohne asymmetrisches C-Atom), wobei auch eine
oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH-
ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome
nicht unmittelbar miteinander gebunden sein dürfen,
und/oder wobei ein oder mehrere H-Atome des Alkylrestes
durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können
zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein
Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran-,
Butyrolacton- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -S-, -CO-, -CO-O-,
-O-CO-, -O-CO-O-, -CO-S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-,
-O-CS-O, -S-CO-S-, -CS-, -CH₂-O-, -O-CH₂-, -CH₂-S-,
-S-CH₂-, -CH=CH-, -C≡C-, -CH₂-CH₂-CO-O-,
-O-CO-CH₂-CH₂- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder
mehrere H-Atome durch F, Cl und/oder CN ersetzt sein
können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome
durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl,
wobei ein oder zwei H-Atome durch F, Cl und/oder CN
ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere
H-Atome durch F, Cl und/oder CN ersetzt sein können,
Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl
und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen,
wobei ein oder zwei H-Atome durch CN und/oder CH₃
ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan-2,5-diyl,
1,3-Dithian-2,5-diyl, 1,3-Thiazol-2,4-diyl, wobei ein
H-Atom durch F, Cl und/oder CN ersetzt sein kann,
1,3-Thiazol-2,5-diyl, wobei ein H-Atom durch F, Cl und/oder
CN ersetzt sein kann, Thiophen-2,4-diyl, wobei ein H-Atom
durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl,
wobei ein oder zwei H-Atome durch F, Cl und/oder CN
ersetzt sein können, Piperazin-1,4-diyl, Piperazin-2,5-diyl,
Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch
F, Cl und/oder CN ersetzt sein können, Bicyclo[2.2.2]octan-1,4-diyl,
wobei ein oder mehrere H-Atome durch F, Cl
und/oder CN ersetzt sein können, 1,3-Dioxaborinan-2,5-diyl
oder die Gruppe B;
a, b, c, d, e, f, g, h, i und K sind null oder eins, vorzugsweise mit der Maßgabe,
daß die Summe aus b, d, g und i 0, 1 oder 2 sein muß.
R³, R⁴, R⁵, R⁶, R⁷ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom), where also one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran, butyrolactone or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO- S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂ -O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH = CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂ -CH₂- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, 1,3 -Dithiane-2,5-diyl, 1,3-thiazole-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, 1,3-thiazole-2,5-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms by F, Cl and / or CN e may be substituted, piperazine-1,4-diyl, piperazine-2,5-diyl, naphthalene-2,6-diyl, it being possible for one or more H atoms to be replaced by F, Cl and / or CN, bicyclo [2.2 .2] octane-1,4-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, 1,3-dioxaborinane-2,5-diyl or the group B;
a, b, c, d, e, f, g, h, i and K are zero or one, preferably with the proviso that the sum of b, d, g and i must be 0, 1 or 2.
Die Verbindungen der Formel (I) sind in reinem Zustand farblos und bilden im allgemeinen flüssigkristalline Mesophasen in einem für die elektrooptische Verwendung günstig gelegenen Temperaturbereich. Chemisch, thermisch und gegen Licht sind sie stabil.The compounds of formula (I) are colorless in the pure state and form in general liquid crystalline mesophases in one for electro-optical Use conveniently located temperature range. Chemical, thermal and they are stable against light.
Besonders geeignet sind die Verbindungen der Formel (I), um schon in geringen Zumischmengen die dielektrische Anisotropie Δ∈ flüssigkristalliner Mischungen in Richtung auf höhere negative Werte zu beeinflussen.The compounds of formula (I) are particularly suitable, even in small amounts The dielectric anisotropy Δ∈ in liquid-crystalline mixtures is added in Direction towards higher negative values.
Bevorzugt sind Verbindungen der allgemeinen Formel (I), in der die Symbole und
Indizes folgende Bedeutungen haben:
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃,
-CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder
verzweigter Alkylrest mit 1 bis 18 C-Atomen (mit oder ohne
asymmetrisches C-Atom), wobei auch eine oder mehrere
CH₂-Gruppen durch -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH=CH-,
-C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder
trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß
Sauerstoffatome nicht unmittelbar miteinander gebunden sein
dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes
durch -F, -Cl, -OR³, -OCN oder -N₃ substituiert sein können, oder
eine der nachfolgenden Gruppen (optisch aktiv oder racemisch):Compounds of the general formula (I) in which the symbols and indices have the following meanings are preferred:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 18 C atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH = CH- , -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F, -Cl, -OR³, -OCN or -N₃, or one of the following groups (optically active or racemic):
R³, R⁴, R⁵, R⁶, R⁷ sind gleich ein Wasserstoff oder ein
geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen
(mit oder ohne asymmetrisches C-Atom), wobei auch eine
oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH-
ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome
nicht unmittelbar miteinander gebunden sein dürfen,
und/oder wobei ein oder mehrere H-Atome des Alkylrestes
durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können
zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein
Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran- oder
Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-,
-O-CO-, -O-CO-O-, -O-CS-O-, -CH₂-O-, -O-CH₂-, -CH=CH-,
-C≡C- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder
mehrere H-Atome durch F, Cl und/oder CN ersetzt sein
können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome
durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl,
wobei ein oder zwei H-Atome durch F, Cl und/oder CN
ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere
H-Atome durch F, Cl und/oder CN ersetzt sein können,
Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl
und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen,
wobei ein oder zwei H-Atome durch CN und/oder CH₃
ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan-2,5-diyl,
Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl
und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein
oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein
können, Naphthalin-2,6-diyl, wobei ein oder mehrere
H-Atome durch F, Cl und/oder CN ersetzt sein können, oder
die Gruppe B;
a, b, c, d, e, f sind null oder eins, mit der Maßgabe, daß die Summe aus b, c, d
und e 0, 1 oder 2 ist.R³, R⁴, R⁵, R⁶, R⁷ are the same as hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O- , -CH₂-O-, -O-CH₂-, -CH = CH-, -C≡C- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, thiophene-2 , 4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, naphthalene -2,6-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, or the group B;
a, b, c, d, e, f are zero or one, with the proviso that the sum of b, c, d and e is 0, 1 or 2.
Besonders bevorzugt sind Verbindungen der allgemeinen Formel (I), in der die
Symbole und Indizes folgende Bedeutungen haben:
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃,
-CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder
verzweigter Alkylrest mit 1 bis 16 C-Atomen (mit oder ohne
asymmetrisches C-Atom), wobei auch eine, zwei oder drei CH₂-Gruppen
durch -O-, -CO-, -O-CO-, -CO-O-, -CH=CH-, Cyclopropan-1,2-diyl,
-Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein
können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar
miteinander gebunden sein dürfen, und/oder wobei ein oder
mehrere H-Atome des Alkylrestes durch -F, -Cl oder -OR³
substituiert sein können, oder auch eine der nachfolgenden
Gruppen (optisch aktiv oder racemisch):Compounds of the general formula (I) in which the symbols and indices have the following meanings are particularly preferred:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 16 C atoms (with or without an asymmetric carbon atom), where also one, two or three CH₂ groups by -O-, -CO-, -O-CO-, -CO-O-, -CH = CH-, cyclopropane-1,2 -diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical are used by -F , -Cl or -OR³ may be substituted, or also one of the following groups (optically active or racemic):
R³, R⁴, R⁵ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder
verzweigter Alkylrest mit 1-9 C-Atomen (mit oder ohne
asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen
durch -O- und/oder -CH=CH- ersetzt sein können, mit der
Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander
gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome
des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und
R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie
an ein Dioxolan-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-,
-O-CO-, -O-CO-O-, -CH₂-O-, -O-CH₂-, -CH=CH- oder eine
Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein, zwei
oder drei H-Atome durch F, Cl und/oder CN ersetzt sein
können, Pyridin-2,5-diyl, wobei ein oder zwei H-Atome durch
F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl,
wobei ein oder zwei H-Atome durch F, Cl und/oder CN
ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder
zwei H-Atome durch CN und/oder CH₃ ersetzt sein können,
(1,3,4)-Thiadiazol-2,5-diyl oder Naphthalin-2,6-diyl, wobei
ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein
können;
a, b, c, d, e, f, g, h, i, k sind null oder eins; vorzugsweise mit der Maßgabe, daß
die Summe aus b, d, g und i 0, 1 oder 2 ist.R³, R⁴, R⁵ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-9 carbon atoms (with or without an asymmetric carbon atom), with one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to a dioxolane system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, - O-CH₂-, -CH = CH- or a single bond;
A¹, A², A³, A⁴ are the same or different 1,4-phenylene, where one, two or three H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, one or two H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, it being possible for one or two H atoms to be replaced by F, Cl and / or CN, trans-1,4-cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) -Thiadiazol-2,5-diyl or naphthalene-2,6-diyl, where one or two H atoms by F , Cl and / or CN can be replaced;
a, b, c, d, e, f, g, h, i, k are zero or one; preferably with the proviso that the sum of b, d, g and i is 0, 1 or 2.
Insbesondere bevorzugt sind Verbindungen der Formel (I), in denen die Gruppe (-A¹)b(-M²)c(-A²)d(-M³)e-B(-M⁴)f(-A³)g(-M⁵)h(A⁴)i eine der folgenden Bedeutungen hat:Particularly preferred are compounds of formula (I) in which the group (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (A⁴) i has one of the following meanings:
wobei die Abkürzungenwith the abbreviations
(F)ICH = 3,4,5-Trifluornaphthalin-2,6-diyl,
Phe = 1,4-Phenylen,
Pyr = Pyridin-2,5-diyl,
Pym = Pyrimidin-2,5-diyl,
Diox = 1,3-Dioxan-2,5-diyl,
Naf = Naphthalin-2,6-diyl,
F₂Phe = Difluorbenzol-1,6-diyl,
(F)Pyr = Fluorpyridin-2,5-diyl und
TDZ = (1,3,4)-Thiadiazol-2,5-diyl(F) ICH = 3,4,5-trifluoronaphthalene-2,6-diyl,
Phe = 1,4-phenylene,
Pyr = pyridine-2,5-diyl,
Pym = pyrimidine-2,5-diyl,
Diox = 1,3-dioxane-2,5-diyl,
Naf = naphthalene-2,6-diyl,
F₂Phe = difluorobenzene-1,6-diyl,
(F) Pyr = fluoropyridine-2,5-diyl and
TDZ = (1,3,4) thiadiazole-2,5-diyl
bedeuten und M¹, M⁶, R¹, R² die in der Formel (I) angegebenen Bedeutungen haben.mean and M¹, M⁶, R¹, R² have the meanings given in formula (I) to have.
Die Herstellung der erfindungsgemäßen Verbindungen erfolgt nach an sich literaturbekannten Methoden, wie sie in Standardwerken zur Organischen Synthese, z. B. Houben-Weyl, Methoden der Organischen Chemie, Georg-Thieme-Verlag, Stuttgart, beschrieben werden.The compounds according to the invention are prepared per se methods known from the literature, as used in standard works on organic matter Synthesis, e.g. B. Houben-Weyl, Methods of Organic Chemistry, Georg-Thieme-Verlag, Stuttgart.
Die Herstellung erfolgt dabei unter Reaktionsbedingungen, die für die genannten Umsetzungen bekannt und geeignet sind. Dabei kann auch von an sich bekannten, hier nicht näher erwähnten Varianten Gebrauch machen.The production takes place under reaction conditions for the above Implementations are known and suitable. It can also by itself make use of known variants not mentioned here.
Die Ausgangsstoffe können gewünschtenfalls auch in situ gebildet werden, und zwar derart, daß man sie aus dem Reaktionsgemisch nicht isoliert, sondern sofort weiter zu den Verbindungen der Formel (I) umsetzt.If desired, the starting materials can also be formed in situ, and in such a way that they are not isolated from the reaction mixture, but rather immediately continues to react to the compounds of formula (I).
Beispielhaft ist in Schema 1 ein Syntheseweg zu Verbindungen der Formel (I) angegeben, wobei auch andere Verfahren denkbar und möglich sind. Exemplary in Scheme 1 is a synthetic route to compounds of formula (I) specified, although other methods are conceivable and possible.
Die Gruppe Pg ist gleich der Gruppierung R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e oder eine geeignete, gegebenenfalls geschützte Vorstufe hiervon, die in späteren Schritten nach an sich bekannten, dem Fachmann geläufigen Methoden in diese Gruppierung überführt werden kann.The group P g is equal to the grouping R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e or a suitable, optionally protected precursor thereof, which in later steps per se known methods known to those skilled in the art can be converted into this grouping.
Beispielsweise kann Pg ein Perfluoralkylsulfonat sein, wobei dann durch Kupplung mit beispielsweise einer entsprechenden Boronsäure die Gruppierung R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e eingeführt wird.For example, P g may be a perfluoroalkyl sulfonate, the group R 1 (-M 1) a (-A 1) b (-M 2) c (-A 2) d (-M 3) e then being introduced by coupling with, for example, a corresponding boronic acid.
Rx ist gleich der Gruppierung (-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)k-R² oder eine geeignete gegebenenfalls, geschützte Vorstufe hiervon, die in späteren Schritten nach an sich bekannten, dem Fachmann geläufigen Methoden in diese Gruppierung überführt werden kann.R x is equal to the grouping (-M⁴) f (-A³) g (-M⁵) h (-A⁴) i (-M⁶) k -R² or a suitable, if appropriate, protected precursor thereof which is known per se in later steps , methods familiar to the person skilled in the art can be transferred into this grouping.
Die Synthese des Restes R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e bzw. (-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)kR² erfolgt nach an sich bekannten, dem Fachmann geläufigen Methoden.The synthesis of the radical R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e or (-M⁴) f (-A³) g (-M⁵) h (-A⁴ ) i (-M⁶) k R² is carried out according to methods known per se and familiar to the person skilled in the art.
Die Herstellung erfolgt dabei unter Reaktionsbedingungen, die für die genannten Umsetzungen bekannt und geeignet sind. Dabei kann auch von an sich bekannten, hier nicht näher erwähnten Varianten Gebrauch machen.The production takes place under reaction conditions for the above Implementations are known and suitable. It can also by itself make use of known variants not mentioned here.
Beispielsweise sei verwiesen auf DE-A 23 44 732, 24 50 088, 24 29 093, 25 02 94, 26 36 684, 27 01 591 und 27 52 975 für Verbindungen mit 1,4-Cyclohexylen und 1,4-Phenylen-Gruppen; DE-A 26 41 724 für Verbindungen mit Pyrimidin-2,5-diyl-Gruppen; DE-A 40 26 223 und EP-A 03 91 203 für Verbindungen mit Pyridin-2,5-diyl-Gruppen; DE-A 32 31 462 für Verbindungen mit Pyridazin-3,6-diyl-Gruppen; EP-A 309 514 für Verbindungen mit (1,3,4)-Thiadiazol-2-5-diyl-Gruppen; WO-A 92/16500 für Naphthalin-2,6-diyl-Gruppen; DE-A 37 10 890 für Bicyclo[2.2.2.]octan-1,4-diyl-Gruppen; K. Seto et al., Journal of the Chemical Society, Chemical Communications 1988, 56 für Dioxoborinan-2,5-diyl-Gruppen.For example, reference is made to DE-A 23 44 732, 24 50 088, 24 29 093, 25 02 94, 26 36 684, 27 01 591 and 27 52 975 for connections with 1,4-cyclohexylene and 1,4-phenylene groups; DE-A 26 41 724 for connections with Pyrimidine-2,5-diyl groups; DE-A 40 26 223 and EP-A 03 91 203 for Compounds with pyridine-2,5-diyl groups; DE-A 32 31 462 for connections with pyridazine-3,6-diyl groups; EP-A 309 514 for connections with (1,3,4) -Thiadiazol-2-5-diyl groups; WO-A 92/16500 for naphthalene-2,6-diyl groups; DE-A 37 10 890 for bicyclo [2.2.2.] Octane-1,4-diyl groups; K. Seto et al., Journal of the Chemical Society, Chemical Communications 1988, 56 for Dioxoborinan-2,5-diyl groups.
Die Herstellung disubstituierter Pyridine, disubstituierter Pyrazine, disubstituierter Pyrimidine und disubstituierter Pyridazine findet sich beispielsweise auch in den entsprechenden Bänden der Serie "The Chemistry of Heterocyclic Compounds" von A. Weissberger und E.C. Taylor (Herausgeber).The production of disubstituted pyridines, disubstituted pyrazines, disubstituted pyrimidines and disubstituted pyridazines are found for example also in the corresponding volumes of the series "The Chemistry of Heterocyclic Compounds "by A. Weissberger and E.C. Taylor (editors).
Dioxanderivate werden zweckmäßig durch Reaktion eines entsprechenden Aldehyds (oder eines seiner reaktionsfähigen Derivate) mit einem entsprechenden 1,3-Diol (oder einem seiner reaktionsfähigen Derivate) hergestellt, vorzugsweise in Gegenwart eines inerten Lösungsmittels, wie Benzol oder Toluol, und/oder eines Katalysators, z. B. einer starken Säure, wie Schwefelsäure, Benzol- oder p-Toluolsulfonsäure, bei Temperaturen zwischen etwa 20°C und etwa 150°C, vorzugsweise zwischen 80°C und 120°C. Als reaktionsfähige Derivate der Ausgangsstoffe eignen sich in erster Linie Acetale.Dioxane derivatives are useful by reacting an appropriate one Aldehyde (or one of its reactive derivatives) with a corresponding 1,3-diol (or one of its reactive derivatives) prepared, preferably in the presence of an inert solvent such as benzene or toluene, and / or a catalyst, e.g. B. a strong acid, such as Sulfuric acid, benzene or p-toluenesulfonic acid, at temperatures between about 20 ° C and about 150 ° C, preferably between 80 ° C and 120 ° C. When reactive derivatives of the starting materials are primarily suitable for acetals.
Die genannten Aldehyde und 1,3-Diole sowie ihre reaktionsfähigen Derivate sind zum Teil bekannt, zum Teil können sie ohne Schwierigkeiten nach Standardverfahren der Organischen Chemie aus literaturbekannten Verbindungen hergestellt werden. Beispielsweise sind die Aldehyde durch Oxydation entsprechender Alkohole oder durch Reduktion von Nitrilen oder entsprechenden Carbonsäuren oder ihrer Derivate, die Diole durch Reduktion entsprechender Diester erhältlich.The aldehydes and 1,3-diols mentioned and their reactive derivatives are partly known, partly they can be followed without difficulty Standard methods of organic chemistry from literature Connections are made. For example, the aldehydes are through Oxidation of appropriate alcohols or by reduction of nitriles or corresponding carboxylic acids or their derivatives, the diols by reduction corresponding diester available.
Verbindungen, worin ein aromatischer Ring durch mindestens ein F-Atom substituiert ist, können auch aus den entsprechenden Diazoniumsalzen durch Austausch der Diazoniumgruppe gegen ein Fluoratom, z. B. nach den Methoden von Balz und Schiemann, erhalten werden. Compounds in which an aromatic ring has at least one F atom is substituted, can also from the corresponding diazonium salts Exchange of the diazonium group for a fluorine atom, e.g. B. according to the methods from Balz and Schiemann.
Was die Verknüpfung der Ringsysteme miteinander angeht, sei verwiesen auf: N. Miyaura, T. Yanagai und A. Suzuki in Synthetic Communications 11 (1981) 513-519; DE-C-39 30 663, M.J. Sharp, W. Cheng, V. Snieckus in Tetrahedron Letters 28 (1987) 5093; G.W. Gray in J. Chem. Soc. Perkin Trans II 1989, 2041 und Mol. Cryst. Liq. Cryst. 172 (1989)165, 204 (1991) 43 und 91; EP-A 0 449 015; WO-A 89/12039; WO-A 89/03821; EP-A 0 354 434 für die direkte Verknüpfung von Aromaten und Heteroaromaten; DE-A 32 01 721 für Verbindungen mit -CH₂CH₂-Brückengliedern und Koji Seto et al. in Liquid Crystals 8 (1990) 861-870 für Verbindungen mit -C≡C-Brückengliedern.Regarding the connection of the ring systems with each other, please refer to: N. Miyaura, T. Yanagai and A. Suzuki in Synthetic Communications 11 (1981) 513-519; DE-C-39 30 663, M.J. Sharp, W. Cheng, V. Snieckus in Tetrahedron Letters 28 (1987) 5093; G.W. Gray in J. Chem. Soc. Perkin Trans II 1989, 2041 and Mol. Cryst. Liq. Cryst. 172: 165, 204 (1991) 43 and 91; EP-A 0 449 015; WO-A 89/12039; WO-A 89/03821; EP-A 0 354 434 for the direct linking of aromatics and heteroaromatics; DE-A 32 01 721 for Connections with -CH₂CH₂ bridge members and Koji Seto et al. in liquid Crystals 8 (1990) 861-870 for connections with -C≡C bridge members.
Ester der Formel (I) können auch durch Veresterung entsprechender Carbonsäuren (oder ihrer reaktionsfähigen Derivate) mit Alkoholen bzw. Phenolen (oder ihren reaktionsfähigen Derivaten) oder nach der DCC-Methode (DCC = Dicyclohexylcarbodiimid) erhalten werden.Esters of the formula (I) can also be correspondingly esterified Carboxylic acids (or their reactive derivatives) with alcohols or Phenols (or their reactive derivatives) or by the DCC method (DCC = dicyclohexylcarbodiimide) can be obtained.
Die entsprechenden Carbonsäuren und Alkohole bzw. Phenole sind bekannt und können in Analogie zu bekannten Verfahren hergestellt werden.The corresponding carboxylic acids and alcohols or phenols are known and can be produced in analogy to known processes.
Als reaktionsfähige Derivate der genannten Carbonsäuren eignen sich insbesondere die Säurehalogenide, vor allem die Chloride und Bromide, ferner die Anhydride, z. B. auch gemischte Anhydride, Azide oder Ester, insbesondere Alkylester mit 1-4 C-Atomen in der Alkylgruppe.Suitable reactive derivatives of the carboxylic acids mentioned are especially the acid halides, especially the chlorides and bromides the anhydrides, e.g. B. also mixed anhydrides, azides or esters, in particular Alkyl esters with 1-4 C atoms in the alkyl group.
Als reaktionsfähige Derivate der genannten Alkohole bzw. Phenole kommen insbesondere die entsprechenden Metallalkoholate bzw. Phenolate, vorzugsweise eines Alkalimetalls, wie Natrium oder Kalium, in Betracht.Coming as reactive derivatives of the alcohols or phenols mentioned in particular the corresponding metal alcoholates or phenolates, preferably an alkali metal such as sodium or potassium.
Die Veresterung wird vorteilhaft in Gegenwart eines inerten Lösungsmittels durchgeführt. Gut geeignet sind insbesondere Ether, wie Diethylether, Di-n-butylether, THF, Dioxan oder Anisol, Ketone, wie Aceton, Butanon oder Cyclohexanon, Amide, wie DMF oder Phosphorsäurehexamethyltriamid, Kohlenwasserstoffe, wie Benzol, Toluol oder Xylol, Halogenkohlenwasserstoffe, wie Tetrachlorkohlenstoff, Dichlormethan oder Tetrachlorethylen und Sulfoxide, wie Dimethylsulfoxid oder Sulfolan.The esterification is advantageous in the presence of an inert solvent carried out. Particularly suitable are ethers, such as diethyl ether, Di-n-butyl ether, THF, dioxane or anisole, ketones such as acetone, butanone or Cyclohexanone, amides, such as DMF or phosphoric acid hexamethyltriamide, Hydrocarbons, such as benzene, toluene or xylene, halogenated hydrocarbons, such as carbon tetrachloride, dichloromethane or tetrachlorethylene and sulfoxides, such as dimethyl sulfoxide or sulfolane.
Ether der Formel (I) sind durch Veretherung entsprechender Hydroxyverbindungen, vorzugsweise entsprechender Phenole, erhältlich, wobei die Hydroxyverbindung zweckmäßig zunächst in ein entsprechendes Metallderivat, z. B. durch Behandeln mit NaH, NaNH₂, NaOH, KOH, Na₂CO₃ oder K₂CO₃ in das entsprechende Alkalimetallalkoholat oder Alkalimetallphenolat übergeführt wird. Dieses kann dann mit dem entsprechenden Alkylhalogenid, Sulfonat oder Dialkylsulfat umgesetzt werden, zweckmäßig in einem inerten Lösungsmittel, wie Aceton, 1,2-Dimethoxyethan, DMF oder Dimethylsulfoxid, oder auch mit einem Überschuß an wäßriger oder wäßrig-alkoholischer NaOH oder KOH bei Temperaturen zwischen etwa 200 und 100°C.Ethers of the formula (I) are more appropriate by etherification Hydroxy compounds, preferably corresponding phenols, are available, where the hydroxy compound expediently first in a corresponding Metal derivative, e.g. B. by treatment with NaH, NaNH₂, NaOH, KOH, Na₂CO₃ or K₂CO₃ in the corresponding alkali metal alcoholate or alkali metal phenolate is transferred. This can then be combined with the corresponding alkyl halide, Sulfonate or dialkyl sulfate are implemented, advantageously in an inert Solvents such as acetone, 1,2-dimethoxyethane, DMF or dimethyl sulfoxide, or with an excess of aqueous or aqueous-alcoholic NaOH or KOH at temperatures between about 200 and 100 ° C.
Was die Synthese spezieller Reste R¹ angeht, sei zusätzlich beispielsweise verwiesen auf EP-A 0 355 008 für Verbindungen mit siliziumhaltigen Seitenketten und EP-A 0 292 954 und EP-A 0 398 1 55 für Verbindungen mit Cyclopropylgruppen in der Seitenkette.As far as the synthesis of special R¹ radicals is concerned, for example refer to EP-A 0 355 008 for connections with silicon-containing Side chains and EP-A 0 292 954 and EP-A 0 398 1 55 for connections with Cyclopropyl groups in the side chain.
Mit der Bereitstellung von Verbindungen der Formel (I) wird ganz allgemein die Palette der flüssigkristallinen Substanzen, die sich unter verschiedenen anwendungstechnischen Gesichtspunkten zur Herstellung flüssigkristalliner Gemische eignen, erheblich verbreitert.With the provision of compounds of formula (I), the Range of liquid crystalline substances, which are among different technical aspects for the production of liquid crystalline Mixtures are suitable, considerably widened.
In diesem Zusammenhang besitzen die Verbindungen der Formel (I) einen breiten Anwendungsbereich. In Abhängigkeit von der Auswahl der Substituenten können sie als Basismaterialien dienen, aus denen flüssigkristalline Phasen zum überwiegenden Teil zusammengesetzt sind; es können aber auch Verbindungen der Formel (I) flüssigkristallinen Basismaterialien aus anderen Verbindungsklassen zugesetzt werden, um beispielsweise die dielektrische und/oder optische Anisotropie eines solchen Dielektrikums zu beeinflussen und/oder um dessen Schwellenspannung und/oder dessen Viskosität zu optimieren.In this connection, the compounds of formula (I) have a wide range Scope of application. Depending on the choice of substituents they can serve as base materials from which liquid crystalline phases for the majority are composed; but connections can also be made of the formula (I) liquid-crystalline base materials from others Classes of compound are added, for example the dielectric and / or to influence the optical anisotropy of such a dielectric and / or by its threshold voltage and / or its viscosity optimize.
Gegenstand der Erfindung ist auch die Verwendung von Verbindungen der Formel (I) in Flüssigkristallmischungen, vorzugsweise ferroelektrischen und nematischen, insbesondere ferroelektrischen.The invention also relates to the use of compounds of Formula (I) in liquid crystal mixtures, preferably ferroelectric and nematic, especially ferroelectric.
Weiterhin Gegenstand der Erfindung sind Flüssigkristallmischungen, vorzugsweise ferroelektrische und nematische, insbesondere ferroelektrische, enthaltend eine oder mehrere Verbindungen der Formel (I).The invention furthermore relates to liquid crystal mixtures, preferably ferroelectric and nematic, especially ferroelectric, containing one or more compounds of formula (I).
Die erfindungsgemäßen Flüssigkristallmischungen enthalten im allgemeinen 2 bis 35, vorzugsweise 2 bis 25, besonders bevorzugt 2 bis 20 Komponenten.The liquid crystal mixtures according to the invention generally contain 2 to 35, preferably 2 to 25, particularly preferably 2 to 20 components.
Sie enthalten im allgemeinen 0,01 bis 80 Gew.-%, vorzugsweise 0,1 bis 60 Gew.-%, besonders bevorzugt 0,1 bis 30 Gew.-%, an einer oder mehreren, vorzugsweise 1 bis 10, besonders bevorzugt 1 bis 5, ganz besonders bevorzugt 1 bis 3, der erfindungsgemäßen Verbindungen der Formel (I).They generally contain 0.01 to 80% by weight, preferably 0.1 to 60% by weight, particularly preferably 0.1 to 30% by weight, of one or more, preferably 1 to 10, particularly preferably 1 to 5, very particularly preferably 1 to 3, the compounds of formula (I) according to the invention.
Weitere Komponenten von Flüssigkristallmischungen, die erfindungsgemäße Verbindungen der Formel (I) enthalten, werden vorzugsweise ausgewählt aus den bekannten Verbindungen mit smektischen und/oder nematischen und/oder cholesterischen Phasen. Dazu gehören z. B.:Other components of liquid crystal mixtures, the invention Compounds of formula (I) are preferably selected from the known compounds with smectic and / or nematic and / or cholesteric phases. These include e.g. B .:
- - Derivate des Phenylpyrimidins, wie beispielsweise in WO 86/06401, US-A 4 874 542 beschrieben,Derivatives of phenylpyrimidine, as for example in WO 86/06401, US-A 4 874 542,
- - metasubstituierte Sechsringaromaten, wie beispielsweise in EP-A 0 578 054 beschrieben,- Meta-substituted six-ring aromatics, such as in EP-A 0 578 054,
- - Siliziumverbindungen, wie beispielsweise in EP-A 0 355 008 beschrieben,Silicon compounds, as described for example in EP-A 0 355 008,
- - mesogene Verbindungen mit nur einer Seitenkette, wie beispielsweise in EP-A 0 541 081 beschrieben,- Mesogenic compounds with only one side chain, such as in EP-A 0 541 081,
- - Hydrochinonderivate, wie beispielsweise in EP-A 0 603 786 beschrieben, Hydroquinone derivatives, as described for example in EP-A 0 603 786,
- - Pyridylpyrimidine, wie beispielsweise in WO 92/12974 beschrieben,Pyridylpyrimidines, as described for example in WO 92/12974,
- - Phenylbenzoate, wie beispielsweise bei P. Keller, Ferroelectrics 58 (1984), 3 und J. W. Goodby et al., Liquid Crystals and Ordered Fluids, Bd. 4, New York 1984 beschrieben und- Phenylbenzoates, such as from P. Keller, Ferroelectrics 58 (1984), 3 and J.W. Goodby et al., Liquid Crystals and Ordered Fluids, 4, New York 1984 and
- - Thiadiazole, wie beispielsweise in EP-A 0 309 514 beschrieben.Thiadiazoles, as described, for example, in EP-A 0 309 514.
Als chirale, nicht racemische Dotierstoffe kommen beispielsweise in Frage:Examples of chiral, non-racemic dopants are:
- - optisch aktive Phenylbenzoate, wie beispielsweise bei P. Keller, Ferroelectrics 58 (1984), 3 und J. W. Goodby et al., Liquid Crystals and Ordered Fluids, Bd. 4, New York 1984 beschrieben,optically active phenylbenzoates, such as, for example, P. Keller, Ferroelectrics 58 (1984), 3 and J.W. Goodby et al., Liquid Crystals and Ordered Fluids, Vol. 4, New York 1984,
- - optisch aktive Oxiranether, wie beispielsweise in EP-A 0 263 437 und WO-A 93/13093 beschrieben,- Optically active oxirane ethers, such as in EP-A 0 263 437 and WO-A 93/13093,
- - optisch aktive Oxiranester, wie beispielsweise in EP-A 0 292 954 beschrieben,- Optically active oxirane esters, as for example in EP-A 0 292 954 described
- - optisch aktive Dioxolanether, wie beispielsweise in EP-A 0 351 746 beschrieben,optically active dioxolane ethers, such as, for example, in EP-A 0 351 746 described
- - optisch aktive Dioxolanester, wie beispielsweise in EP-A 0 361 272 beschrieben,- Optically active dioxolane esters, such as, for example, in EP-A 0 361 272 described
- - optisch aktive Tetrahydrofuran-2-carbonsäureester, wie beispielsweise in EP-A 0 355 561 beschrieben, und- Optically active tetrahydrofuran-2-carboxylic acid esters, such as in EP-A 0 355 561 and
- - optisch aktive 2-Fluoralkylether, wie beispielsweise in EP-A 0 237 007 und US-A 5,051,506 beschrieben.- Optically active 2-fluoroalkyl ethers, such as, for example, in EP-A 0 237 007 and US-A 5,051,506.
Die Mischungen wiederum können Anwendung finden in elektrooptischen oder vollständig optischen Elementen, z. B. Anzeigeelementen, Schaltelementen, Lichtmodulatoren, Elementen zur Bildbearbeitung und/oder Signalverarbeitung oder allgemein im Bereich der nichtlinearen Optik.The mixtures in turn can be used in electro-optical or completely optical elements, e.g. B. display elements, switching elements, Light modulators, elements for image processing and / or signal processing or generally in the field of nonlinear optics.
Flüssigkristalline Mischungen, die Verbindungen der allgemeinen Formel (I) enthalten, sind besonders für die Verwendung in elektrooptischen Schalt- und Anzeigevorrichtungen (Displays) geeignet. Diese Displays sind üblicherweise so aufgebaut, daß eine Flüssigkristallschicht beiderseitig von Schichten eingeschlossen ist, die üblicherweise, in dieser Reihenfolge ausgehend von der LC-Schicht, mindestens eine Orientierungsschicht, Elektroden und eine Begrenzungsscheibe (z. B. aus Glas) sind. Darüber hinaus enthalten sie Abstandshalter, Kleberahmen, Polarisatoren sowie für Farbdisplays dünne Farbfilterschichten. Weitere mögliche Komponenten sind Antireflex-, Passivierungs-, Ausgleichs- und Sperrschichten sowie elektrisch-nichtlineare Elemente, wie Dünnschichttransistoren (TFT) und Metall-Isolator-Metall-(MIM)-Elemente. Im Detail ist der Aufbau von Flüssigkristalldisplays bereits in einschlägigen Monographien beschrieben (siehe z. B. E. Kaneko, "Liquid Crystal TV Displays: Principles and Applications of Liquid Crystal Displays", KTK Scientific Publishers 1987).Liquid-crystalline mixtures, the compounds of the general formula (I) included, are especially for use in electro-optical switching and Suitable display devices. These displays are usually like this built that a liquid crystal layer on both sides of layers is included, which is usually in that order starting from the LC layer, at least one orientation layer, electrodes and one Boundary disk (e.g. made of glass). They also contain Spacers, adhesive frames, polarizers and thin ones for color displays Color filter layers. Other possible components are anti-reflective, Passivation, compensation and barrier layers as well as non-linear electrical Elements such as thin film transistors (TFT) and metal insulator metal (MIM) elements. The structure of liquid crystal displays is already in detail relevant monographs (see, for example, E. Kaneko, "Liquid Crystal TV Displays: Principles and Applications of Liquid Crystal Displays ", KTK Scientific Publishers 1987).
Ferner sind die Mischungen für Feldbehandlung, d. h. zum Betrieb in der Quasi-Bookshelf-Geometrie (QBG) (siehe z. B. H. Rieger et al., SID 91 Digest (Anaheim) 1991, 396) geeignet.Furthermore, the mixtures for field treatment, i.e. H. for operation in the Quasi-Bookshelf Geometry (QBG) (see e.g. H. Rieger et al., SID 91 Digest (Anaheim) 1991, 396).
Ebenso sind die erfindungsgemäßen Mischungen geeignet für die Verwendung in ferroelektrischen Flüssigkristallanzeigen, die auf Nutzung des DHF-Effekts oder des PSFLCD-Effekts (Pitch Stabilized Ferroelectric Liquid Crystal Display, auch SBF = Short Pitch Bistable Ferroelectric Effect genannt) beruhen.The mixtures according to the invention are also suitable for use in ferroelectric liquid crystal displays based on the use of the DHF effect or the PSFLCD effect (Pitch Stabilized Ferroelectric Liquid Crystal Display, too SBF = Short Pitch Bistable Ferroelectric Effect).
Daneben können die Verbindungen der Formel (I) auch als Komponenten von antiferroelektrischen Flüssigkristallmischungen Verwendung finden.In addition, the compounds of formula (I) can also be used as components of antiferroelectric liquid crystal mixtures are used.
Die Erfindung wird durch die Beispiele näher erläutert, ohne sie darauf beschränken zu wollen. The invention is explained in more detail by the examples, without referring to them want to restrict.
10 mmol 3,4,5-Trifluor-6-(4-hydroxy-phenyl)-2-octyl-5,6,7,8-tetrahydro naphthalin werden in 50 ml DMF gelöst und mit 11 mmol Natriumhydrid versetzt. Nach 30 Minuten rühren tropft man 11 mmol 1-Octylbromid zu, rührt noch 140 Minuten bei 60°C und gießt in Wasser. Das Gemisch wird mit Dichlormethan extrahiert, die vereinigten organischen Phasen werden getrocknet, das Solvens im Vakuum entfernt und der Rückstand an Kieselgel chromatographiert. Man erhält 8 mmol 6-(4-Octyloxy-phenyl)-3,4,5-trifluor-2- octyl-naphthalin.10 mmol of 3,4,5-trifluoro-6- (4-hydroxyphenyl) -2-octyl-5,6,7,8-tetrahydro naphthalene are dissolved in 50 ml DMF and with 11 mmol sodium hydride transferred. After stirring for 30 minutes, 11 mmol of 1-octylbromide are added dropwise and the mixture is stirred 140 minutes at 60 ° C and poured into water. The mixture is with Extracted dichloromethane, the combined organic phases dried, the solvent removed in vacuo and the residue on silica gel chromatographed. 8 mmol of 6- (4-octyloxyphenyl) -3,4,5-trifluoro-2- are obtained octyl naphthalene.
Analog Beispiel 1 lassen sich weitere Halogenide mit 3,4,5-Trifluor-6-(4- hydroxy-phenyl)-2-octyl-naphthalin umsetzen.Analogously to Example 1, other halides with 3,4,5-trifluoro-6- (4- implement hydroxy-phenyl) -2-octyl-naphthalene.
10 mmol 3,4,5-Trifluor-6-(5-hydroxy-pyrimidin-2-yl)-2-octyl-naphthalin werden in 50 ml DMF gelöst und mit 11 mmol Natriumhydrid versetzt. Nach 30 Minuten rühren tropft man 11 mmol 1-Hexylbromid zu, rührt noch 140 Minuten bei 60°C und gießt in Wasser. Das Gemisch wird mit Dichlormethan extrahiert, die vereinigten organischen Phasen werden getrocknet, das Solvens im Vakuum entfernt und der Rückstand an Kieselgel chromatographiert. Man erhält 7,55 mmol 6-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-2-octyl-naphthalin.10 mmol of 3,4,5-trifluoro-6- (5-hydroxy-pyrimidin-2-yl) -2-octyl-naphthalene dissolved in 50 ml DMF and mixed with 11 mmol sodium hydride. After 30 minutes 11 mmol of 1-hexylbromide are added dropwise, stirring is continued for 140 minutes 60 ° C and pour in water. The mixture is extracted with dichloromethane combined organic phases are dried, the solvent in vacuo removed and the residue chromatographed on silica gel. You get 7.55 mmol of 6- (5-hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-2-octylnaphthalene.
Analog Beispiel 2 lassen sich weitere Halogenide mit 3,4,5-Trifluor-6-(5- hydroxy-pyrimidin-2-yl)-2-octyl-naphthalin umsetzen. Analogously to Example 2, other halides with 3,4,5-trifluoro-6- (5- implement hydroxy-pyrimidin-2-yl) -2-octyl-naphthalene.
10 mmol 3,4,5-Trifluor-2-(6-hexyl-pyridin-3-yl)-6-hydroxy-naphthalin werden in 50 ml DMF gelöst und mit 11 mmol Natriumhydrid versetzt. Nach 30 Minuten rühren tropft man 11 mmol 1-Octylbromid zu, rührt noch 140 Minuten bei 60°C und gießt in Wasser. Das Gemisch wird mit Dichlormethan extrahiert, die vereinigten organischen Phasen werden getrocknet, das Solvens im Vakuum entfernt und der Rückstand an Kieselgel chromatographiert. Man erhält 9 mmol 6-Octyloxy-3,4,5-trifluor-2-(6-hexyl-pyridin-3-yl)-naphthalin.10 mmol 3,4,5-trifluoro-2- (6-hexyl-pyridin-3-yl) -6-hydroxy-naphthalene are in 50 ml of DMF dissolved and mixed with 11 mmol of sodium hydride. After 30 minutes stirring is added dropwise 11 mmol of 1-octyl bromide, stirring is continued for 140 minutes at 60 ° C. and pour in water. The mixture is extracted with dichloromethane combined organic phases are dried, the solvent in vacuo removed and the residue chromatographed on silica gel. 9 mmol are obtained 6-octyloxy-3,4,5-trifluoro-2- (6-hexyl-pyridin-3-yl) naphthalene.
Analog Beispiel 3 lassen sich weitere Halogenide mit 3,4,5-Trifluor-2-(6-hexyl pyridin-3-yl)-6-hydroxy-naphthalin umsetzen.Analogously to Example 3, other halides with 3,4,5-trifluoro-2- (6-hexyl Implement pyridin-3-yl) -6-hydroxy-naphthalene.
3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4-octyloxy-phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluoro-phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-nonyl-naphthalin 3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-nonyl-naphthalin-3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-nonyl-na-phthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2-no-nyl-naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2-no-nyl-naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-nonyl-na-phthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2-no-nyl-naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2-no-nyl-naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-nonyl-naphth-alin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2-nonyl-naphth-aline
3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluoro-phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-nonyl-naphtha-lin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2-nonyl-naphtha-lin
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-nonyl-naphthali-n3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2-nonyl-naphthali-n
3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2-nonyl-napthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2-nonyl-napthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-nonyl-naphthalin-3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-nonyl-naphth-alin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2-nonyl-naphth-aline
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-nony-l-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2-nony-l-naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--nonyl- naphthalin 3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - nonyl- naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--nonyl- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - nonyl- naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-nonyl-napht-halin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2-nonylnaphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-no-nyl- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2-no-nyl- naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-nony-l-naphthalin 3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2-nony-l-naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-nonyl- naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) -2-nonyl- naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-nonyl- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -2-nonyl- naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-nonyl-naphthali-n3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2-nonyl-naphthali-n
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-nonyl-n-aphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2-nonyl-n-aphthaline
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2-nonyl-napthalene
3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-non-yl-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2-non-yl-naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-non-yl-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2-non-yl-naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2-nonyl-naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-nonyl-napht-halin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2-nonyl-napht-haline
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-nonyl-naphtha-lin 3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2-nonyl-naphtha-lin
3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-nonyl-n-aphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2-nonyl-n-aphthaline
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-nonyl-n-aphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2-nonyl-n-aphthaline
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-non-yl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2-non-yl-naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-nonyl- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyrimidin-2-y-l) -2-nonyl- naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-nonyl- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) -2-nonyl- naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- nonyl-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- nonyl naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- nonyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- nonyl naphthalene
3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[9,9-dimethylsila]tetradecyl--naphthalin3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [9,9-dimethylsila] tetradecylnaphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[9,9-dimethylsila]tet-radecyl- naphthalin 3,4,5-trifluoro-6- (5-octyloxy-pyrimidin-2-yl) -2- [9,9-dimethylsila] tet-radecyl- naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[9,9-dimethylsila]tetra-decyl- naphthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2- [9,9-dimethylsila] tetra-decyl- naphthalene
3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[9,9-dimethylsila-]tetradecyl- naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [9,9-dimethylsila-] tetradecyl- naphthalene
3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[9,9-dimethylsila-]tetradecyl- naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluorophenyl) -2- [9,9-dimethylsila-] tetradecyl- naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[9,9-dimethylsila]tetr-adecyl- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [9,9-dimethylsila] tetr-adecyl- naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[9,9-dimethyls-ila]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [9,9-dimethyls-ila] tetradecyl- naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[9,9-dimethylsil-a]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [9,9-dimethylsil-a] tetradecyl- naphthalene
3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[9,9-dimet-hylsila]tetra decyl-naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [9,9-dimethylsilyl] tetra decyl naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[9,9-dimet-hylsila]tetra decyl-naphthalin 3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [9,9-dimethylsilyl] tetra decyl naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[9,9-dimethyls-ila]tetra decyl-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [9,9-dimethyls-ila] tetra decyl naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[9,9-d-imethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[9,9-dim-ethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[9-,9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [9-, 9-dimethyl sila] tetradecyl-naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[9-,9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [9-, 9-dimethyl sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[9,9-dimethyls-ila]tetra decyl-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [9,9-dimethylsila] tetra decyl naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[9,9-d-imethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[9,9-dim-ethylsila] tetradecyl-naphthalin 3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonylpyridin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[9-,9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [9-, 9-dimethyl sila] tetradecyl-naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[9-,9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [9-, 9-dimethyl sila] tetradecyl-naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[9,9-dimethylsila]-tetradecyl- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [9,9-dimethylsila] tetradecyl- naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[9,9-dimet-hylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[9,9-dimethy-lsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [9,9-dimethy-isila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[9,9-d-imethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[1 -hexansäureester]-2,3-difluor-phenyl)-2-[9,9-dimethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[9,9-dimethylsila]tet-radecyl- naphthalin 3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [9,9-dimethylsila] tet-radecyl- naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[9,9-dimethyl-sila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [9,9-dimethyl-sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[9,9-dimethylsi-la] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [9,9-dimethylsi-la] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[9,9-dime-thylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[9,9-dime-thylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[9,9-dimethylsila]tetr-adecyl- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [9,9-dimethylsila] tetr-adecyl- naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[9,9-dimethyls-ila]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [9,9-dimethyls-ila] tetradecyl- naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[9,9-dimethylsil-a]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [9,9-dimethylsil-a] tetradecyl- naphthalene
3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[9,9-dimet-hylsila] tetradecyl-naphthalin 3,4,5-trifluoro-6- (3- [6-oxa-undecyl] -fluoropyridin-6-yl) -2- [9,9-dimet-hylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[9,9-dimet-hylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[9,9-d-methy-lsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [9,9-d-methyl-isila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[9,9--dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [9,9-dimethyl sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[9,9-d-imethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)2-[-9,9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) 2 - [- 9,9-dimethyl sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [9.9- dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[9-cycyclopropylnonyl]-phenyl)-2-[9,9-dimethylsi-la]tetradecyl- naphthalin3,4,5-trifluoro-6- (4- [9-cycyclopropylnonyl] phenyl) -2- [9,9-dimethylsi-la] tetradecyl- naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[9,9-dime-thylsila] tetradecyl-naphthalin 3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[9,9-dimeth-ylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [9,9-dimeth-ylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[9,9--dimethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [9.9 - dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[9,9--dimethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [9.9 - dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[9,9-dimet-hylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [9,9-dimet-hylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[9-,9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [9-, 9-dimethyl sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[9,9--dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [9,9-dimethyl sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [9.9- dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[9,9- dimethylsila]tetradecyl-naphthalin 3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [9.9- dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[9,9-dimethylsi-la]tetradecyl- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [9,9-dimethylsi-la] tetradecyl- naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[9,9-di-methylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[9,9-dime-thylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[9,-9-dimethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [9, -9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[9,-9-dimethylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [9, -9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[9,9-dimethylsila]t-etradecyl- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [9,9-dimethylsila] t-etradecyl- naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[9,9-dimeth-ylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [9,9-dimeth-ylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[9,9-dimethyl-sila]tetradecyl- naphthalin 3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [9,9-dimethyl-sila] tetradecyl- naphthalene
3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[9,9-di-methylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[9,9-di-methylsila] tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[9,-9-dimethyl sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [9, -9-dimethyl sila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyrimidin-2-y-l) -2- [9,9- dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [9,9- dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [9,9-dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [9,9-dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [9,9-dimethylsila] tetradecyl naphthalene
3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[9-cyclopropylnonyl]-naphthal-in 3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [9-cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[9-cyclopropylnonyl]--naphthalin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2- [9-cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[9-cycopropylnonyl]-nap-hthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2- [9-cycopropylnonyl] naphtaline
3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[9-cyclopropylnon-yl]-naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [9-cyclopropylnon-yl] naphthalene
3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[9-cyclopropylnon-yl]-naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluorophenyl) -2- [9-cyclopropylnon-yl] naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[9-cyclopropylnonyl]-n-aphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [9-cyclopropylnonyl] -n-aphthaline
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [9-cyclopropyl-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[9-cyclopropylno-nyl]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[9-cyclopr-opylnonyl]- naphthalin 3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [9-cyclopropyl-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[9-cyc-lopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [9-cyc-lopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[9-cyclo-propylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [9-cyclo-propylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [9-cyclopropyl nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[9-cyc-lopropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [9-cyc-lopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[9-cyclo-propylnonyl]- naphthalin 3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [9-cyclo-propylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[9-cyclopropylnony-l]- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [9-cyclopropylnony-l] - naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [9-cyclopr-opylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[9-cycloprop-ylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [9-cycloprop-ylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[9-cyc-lopropylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [9-cyc-lopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-[9-cyc-lopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [9-cyc-lopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[9-cyclopropylnonyl]--naphthalin 3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [9-cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[9-cyclopropy-lnonyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [9-cyclopropy-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[9-cyclopropyln-onyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [9-cyclopropyln-onyl] - naphthalene
3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[9-cyclopropylnonyl]-n-aphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [9-cyclopropylnonyl] -n-aphthaline
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [9-cyclopropyl-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[9-cyclopropylno-nyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [9-cyclopr-opylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [9-cyclopr-opylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[9-cycloprop-ylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [9-cycloprop-ylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[9-c-yclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [9-c-yclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[9-cyc-lopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [9-cyc-lopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[9-cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [9-cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[9-cyclo propylnonyl]-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [9-cyclo propylnonyl] naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[9-cyclopropylnon-yl]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [9-cyclopropylnon-yl] - naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[9-cyclopro-pylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-l[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[9-c-yclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (3-l [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [9-c-yclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[9-cy-clopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [9-cy-clopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [9-cyclopr-opylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[9-c-yclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [9-c-yclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [9- cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [9- cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[9-cyclopropyln-onyl]- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [9-cyclopropyln-onyl] - naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[9-cycl-opropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[9-cyclopropylnonyl-]-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [9-cyclopropylnonyl -] - naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[9-cyclopro-pylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[9-cyclopropy-lnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [9-cyclopropy-nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[9-cycl-opropylnonyl]- naphthalin 3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[9-cycl-opropylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [9-cyclopropylnonyl] - naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[9--cyclopropyl nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [9 - cyclopropyl nonyl] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyrimidin-2-y-l) -2- [9- cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [9- cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [9-cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [9-cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [9-cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [9-cyclopropylnonyl] naphthalene
3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[6-oxa-undecyl]-naphthalin3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [6-oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[6-oxa-undecyl]-napht-halin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2- [6-oxa-undecyl] naphtaline
3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[6-oxa-undecyl]-naphtha-lin 3,4,5-trifluoro-6- (5-octyloxy-pyridin-2-yl) -2- [6-oxa-undecyl] naphtha-lin
3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[6-oxa-undecyl]-n-aphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [6-oxa-undecyl] -n-aphthaline
3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[6-oxa-undecyl]-n-aphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluoro-phenyl) -2- [6-oxa-undecyl] -n-aphthaline
3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[6-oxa-undecyl]-naphth-alin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [6-oxa-undecyl] naphth-aline
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [6-oxa-undecyl -] - naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [6-oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [6-oxa-and-ecyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [6-oxa-and-ecyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [6-oxa-undecyl -] - naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[-6-oxa--undecyl]- naphthalin 3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2 - [- 6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [6-oxa-undecyl -] - naphthalene
3,4,5-Trifuor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifuor-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[6-oxa-u-ndecyl]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [6-oxa-u-decyl] - naphthalene
3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[6-oxa-undecyl]-na-phthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [6-oxa-undecyl] -na-phthaline
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[6-oxa-und-ecyl]- naphthalin 3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [6-oxa-and-ecyl] - naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[6-oxa-undec-yl]-naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [6-oxa-undec-yl] naphthalene
3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[6-oxa-undecyl]-napht-halin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [6-oxa-undecyl] naphtaline
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[6-oxa-undecy-l]-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [6-oxa-undecy-l] naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [6-oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [6-oxa-un-decyl] - naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [6-oxa-un-decyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[6-oxa-undecyl]-naphth-alin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [6-oxa-undecyl] naphth-aline
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [6-oxa-undecyl -] - naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [6-oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [6-oxa-and-ecyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [6-oxa-and-ecyl] - naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[6-oxa-undec-yl]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [6-oxa-undec-yl] - naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[6-o-xa-undecyl]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [6-o-xa-undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [6-oxa- undecyl] naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[6-oxa- undecyl]-naphthalin 3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [6-oxa- undecyl] naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[6-oxa-undecyl]-n-aphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [6-oxa-undecyl] -n-aphthaline
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [6-oxa-un-decyl] - naphthalene
3,4,5-Tifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[6-oxa-undec-yl]- naphthalin3,4,5-tifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [6-oxa-undec-yl] - naphthalene
3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[6-ox-a-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [6-ox-a-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[-6-o-xa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2 - [- 6-o-xa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [6-oxa-and-ecyl] - naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[6--oxa-undecyl]- naphthalin 3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[6-o-xa-undecyl]- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [6-o-xa-undecyl] - naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [6-oxa- undecyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [6-oxa- undecyl] naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [6-oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxyl-pyridin-2-yl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxyl-pyridin-2-yl) -2- [6-oxa-un-decyl] - naphthalene
3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2-3-difluor-phenyl)-2-[6--oxa-undecyl]- naphthalin 3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2-3-difluoro-phenyl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[6-oxa-undecyl]-nap-hthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [6-oxa-undecyl] napthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[6-oxa-unde-cyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [6-oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[6-oxa-undecy-l]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [6-oxa-undecy-l] - naphthalene
3,4,5-Trifluor-6(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[6-oxa-u-ndecyl]- naphthalin3,4,5-trifluoro-6 (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [6-oxa-u-decyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [6-oxa - undecyl] - naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [6 - oxa-undecyl] - naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxirane-2-carboxylic acid ester] pyrimidin-2-y-l) -2- [6-oxa- undecyl] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[6-oxa- undecyl]-naphthalin 3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [6-oxa- undecyl] naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2-[6- oxa-undecyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [6- oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2-[6- oxa-undecyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [6- oxa-undecyl] naphthalene
3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[perfluor-1H,1H-nonyl]-naphth-alin3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [perfluoro-1H, 1H-nonyl] naphth-aline
3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[perfluor-1H,1H-nonyl-]-naphthalin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2- [perfluoro-1H, 1H-nonyl -] - naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[perfluor-1H,1H-nonyl]--naphthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2- [perfluoro-1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[perfluor-1H,1H-n-onyl]- naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [perfluoro-1H, 1H-n-onyl] - naphthalene
3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[perfluor-1H,1H-n-onyl]- naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluorophenyl) -2- [perfluoro-1H, 1H-n-onyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[perfluor-1H,1H-nonyl]--naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [perfluoro-1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[perfluor-1H,1-H-nonyl]- naphthalin 3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [perfluoro-1H, 1-H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[perfluor-1H,1-H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [perfluoro-1H, 1-H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[perfluo-r-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [perfluoro-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin 3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[perfluor-1H,1-H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [perfluoro-1H, 1-H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[perfluo-r-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [perfluoro-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[perfluor-1H,1H-no-nyl]- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [perfluoro-1H, 1H-no-nyl] - naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[perfluor-1H-,1H-nonyl]- naphthalin 3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [perfluoro-1H-, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[perfu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [perfu-or-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[perfluor-1H,1H-nonyl-]-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [perfluoro-1H, 1H-nonyl -] - naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[perfluor-1H,-1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [perfluoro-1H, -1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[perfluor--1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [perfluoro - 1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[perfluor-1H,1H-nonyl]--naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [perfluoro-1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[perfiuor-1H,1-H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [perfiuor-1H, 1-H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[perfluor-1H-,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [perfluoro-1H-, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[per-fluor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [per-fluoro-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [perfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [perfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[perfluor-1H,1H-n-onyl]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [perfluoro-1H, 1H-n-onyl] - naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[perfluor--1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [perfluoro - 1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[perfluor-1-H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [perfluoro-1-H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[perf-luor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [perf-luor-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[perf-luor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [perf-luor-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[per-fluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [per-fluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [perfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [perfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[perflu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [perfluoro or 1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[pe-rfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [pe-fluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[pe-rfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [pe-fluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[perfluor-1H,1H-non-yl]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [perfluoro-1H, 1H-non-yl] - naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[perfluor-1-H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [perfluoro-1-H, 1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[perfluor-1H,-1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [perfluoro-1H, -1H-nonyl] - naphthalene
3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl).2-[perflu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) .2- [perflu-or-1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[perflu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [perfluoro or 1H, 1H- nonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[pe-rfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [pe-fluoro- 1H, 1H-nonyl] naphthalene
3,4, 5-Trifluor-6-(5-[3-butyloxjran-2-carbonsäureester]-pyrimidin-2-yl)-2--[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxjran-2-carboxylic acid ester] pyrimidin-2-yl) -2 - [perfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [perfluoro- 1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [perfluor-1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [perfluoro-1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [perfluor-1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [perfluoro-1H, 1H-nonyl] naphthalene
3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[2-Fluor-octyloxy]-naphthalin-3,4,5-trifluoro-6- (4-octyloxy-phenyl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[2-Fluor-octyloxy]-na-phthalin3,4,5-trifluoro-6- (5-octyloxy-pyrimidin-2-yl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[2-Fluor-octyloxy]-naph-thalin3,4,5-trifluoro-6- (5-octyloxy-pyridin-2-yl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[2-Fluor-octyloxy-]-naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoro-pyridin-6-yl) -2- [2-fluoro-octyloxy -] - naphthalene
3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[2-Fluor-octyloxy-]-naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluoro-phenyl) -2- [2-fluoro-octyloxy -] - naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[2-Fluor-octyloxy]-nap-hthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [2-fluoro-octyloxy] napthalene
3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[2-Fluor-octyl-oxy]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [2-fluoro-octyl-oxy] - naphthalene
3,4, 5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[2-Fluor-octyloxy]-n-aphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [2-fluoro-octyloxy] -n-aphthaline
3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [2-fluoro-o-ctyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [2-fluoro-o-ctyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[2-Fluor-octyl-oxy]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4, 5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[2-Fluor-oct-yloxy]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [2-fluoro-oct-yloxy] - naphthalene
3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [2 - fluorine octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [2 - fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[2-Fluor-octyl-oxy]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[2-Fluor--octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[2--Fluor-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [2 - fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [2 - fluorine octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[2-Fluor-octyloxy]--naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [2-fluoro-o-ctyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[2-Fluor-oct-yloxy]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [2-fluoro-oct-yloxy] - naphthalene
3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[1 -hexansäureester]-2,3-difluor-phenyl)-2-[2-Fluor-octyloxy]- naphthalin 3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[2-Fluor-octyloxy]-na-phthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[2-Fluor-octy-loxy]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[2-Fluor-octylo-xy]-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[2-Fluor--octyloxy- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy- naphthalene
3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[2-Fluor--octyloxy- naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [2-fluoro-octyloxy- naphthalene
3,4,5-Trifluor-6-(4-[-6-oxa-undecyl]-phenyl)-2-[2-Fluor-octyloxy]-na-phthalin3,4,5-trifluoro-6- (4 - [- 6-oxa-undecyl] phenyl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[2-Fluor-octyl-oxy- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [2-fluoro-octyl-oxy- naphthalene
3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[2-Fluor-octylox-y]-naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [2-fluoro-octylox-y] naphthalene
3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[2-Fluor-o-ctyloxy- naphthalin 3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [2-fluoro-o-ctyloxy- naphthalene
3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [2-fluoro-o-ctyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[2-Fluor-oct-yloxy]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [2-fluoro-oct-yloxy] - naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[2-F-luor-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [2-F-luoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [2-fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [2-fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[2-Fluor-octyloxy-]-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [2-fluoro-octyloxy -] - naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[2-Fluor--octyloxy]- naphthalin 3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[2-Fluor-oc-tyloxy]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [2-fluoro-oc-tyloxy] - naphthalene
3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[2-Fl-uor-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[2-Fl-uor-octyloxy]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [2-fluoro-o-ctyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [2 - fluorine octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[2-F-luor-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [2-F-luoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [2-fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[2-Fluor- octyloxy]-naphthalin 3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [2-fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[2-Fluor-octylo-xy]-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[2-Fluo-r-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[2-Fluor--octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[2--Fluor-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [2 - fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[2--Fluor-octyloxy]- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [2 - fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[2-Fluor-octyloxy]--naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[2-Fluor-oc-tyloxy]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [2-fluoro-oc-tyloxy] - naphthalene
3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[2-Fluor-octy-loxy]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[2-Fluo-r-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[2-Fluo-r-octyloxy]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluoro-phenyl) -2- [2-fluoro-octyloxy] - naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [2 - fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester1-pyrimidin-2-y-l)-2-[2- Fluor-octyloxy]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxirane-2-carboxylic acid ester 1-pyrimidin-2-y-l) -2- [2- Fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [2-fluoro- octyloxy] naphthalene
3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [2-Fluor-octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [2-fluoro-octyloxy] naphthalene
3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [2-Fluor-octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [2-fluoro-octyloxy] naphthalene
2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxynaphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxynaphthalene
2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octyloxy-naphth-alin2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy-naphth-aline
2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy-naphthal-in2- (4-hexyloxy-2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6-octyloxynaphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octylox-y-naphthalin2- (3- [5-Methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octylox-y-naphthalene
2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (4- [5-Methylheptyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-napht-halin2- (4- [6-Cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-napht-haline
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octylo-xy-naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin 2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octylo-xy-naphthalene
2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--octyloxy- naphthalin2- (3- [6-cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (4- [6-cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene
2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-octyloxy-napht-halin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6-octyloxy-napht-haline
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--octyloxy- naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene
2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthal-in2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin 2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (3- [1-heptanoic acid ester] -fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene
2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyl-oxy-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyl-oxy-naphthalene
2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [4-Oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [4-Oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octylox-y-naphthalin2- (3- [4-Oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octylox-y-naphthalene
2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (4- [4-Oxa-nonyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-napht-halin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphth-haline
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-napht-halin 2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphth-haline
2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (3- [6-oxa-dodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline
2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-na-phthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene
2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-octyloxy- naphthalin2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--octyloxy- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthal-in2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin 2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidi(n-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidi (n-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (3- [9-cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene
2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyl-oxy-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyl-oxy-naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxyl-pyrimidin-2-yl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxyl-pyrimidin-2-yl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene
2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-octyloxy- naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6-octyloxy- naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-octyloxy- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy--naphthalin 2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-o-ctyloxy- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-o-ctyloxy- naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-o-ctyloxy- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-o-ctyloxy- naphthalene
2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-octyloxy- naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-octyloxy- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-octyloxy- naphthalene
2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthali-n2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthali-n
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline
2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octy-loxy-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy naphthalene
2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octylo-xy-naphthalin 2- (4- [2-chloro-hexyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-octyl oxy-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6-octyl oxy-naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-octyl oxy-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6-octyl oxy-naphthalene
2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- octyloxy-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- octyloxy-naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- octyloxy-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- octyloxy-naphthalene
2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-naphthalin2- (4-hexyloxyphenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline
2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-methylhexyl]--naphthalin 2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-methylhexyl] naphthalene
2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-n-aphthalin2- (4-Hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] n-aphthaline
2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexy-1] naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexy-1] naphthalene
2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-meth-ylhexyl]- naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-meth-ylhexyl] - naphthalene
2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (4- [6-Cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin 2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[2-methyl hexyl]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [2-methyl hexyl] naphthalene
2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2--methyl hexyl]-naphthalin2- (4- [6-Cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene
2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[2-methylhexyl]- naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [2-methylhexyl] - naphthalene
2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene
2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-n-aphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] n-aphthaline
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene
2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-me-thylhexyl]- naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline
2-(5-[4-Oxa-nonyloxyl-pyrimidin-2-yl)-3,4-5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [4-Oxa-nonyloxyl-pyrimidin-2-yl) -3,4-5-trifluoro-6- [2-methylhexy-l] -naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [4-Oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexy-l] naphthalene
2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-meth-ylhexyl]- naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-meth-ylhexyl] - naphthalene
2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin 2- (4- [4-oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-naphth-alin2- (4- [6-oxadodecyl] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphth-aline
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene
2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-methy-lhexyl]- naphthalin2- (3- [6-oxadodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (4- [6-oxadodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhe-xyl]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene
2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[2-methyl- hexyl]-naphthalin 2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [2-methyl- hexyl] naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[2-methyl hexyl]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [2-methyl hexyl] naphthalene
2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-n-aphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] n-aphthaline
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene
2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-me-thylhexyl]- naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methyl hexyl]-naphthalin 2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methyl hexyl]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene
2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[2-methyl hexyl]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [2-methyl hexyl] naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[2- methylhexyl]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [2- methylhexyl] naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-2-methylhexyl]- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 2-methylhexyl] - naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-2-methylhexyl]- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 2-methylhexyl] - naphthalene
2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[2- methylhexyl]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2- methylhexyl] naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[2- methylhexyl]-naphthalin 2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [2- methylhexyl] naphthalene
2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-na-phthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene
2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-m-ethylhexyl]- naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-m-ethylhexyl] - naphthalene
2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[2--methyl hexyl]-naphthalin2- (4- [3-Propyloxiran-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[2- methylhexyl]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [2- methylhexyl] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[2- methylhexyl]-naphthalin 2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [2- methylhexyl] naphthalene
2-(3-[3-propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [2-methylhexyl]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [2-methylhexyl] naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [2-methylhexyl]-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [2-methylhexyl] naphthalene
2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctyloxy]-napht-halin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] naphtaline
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] naphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] naphthalene
2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cyclopropylo-ctyloxy]- naphthalin2- (3-hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclopropylo-ctyloxy] - naphthalene
2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloct-yloxy]- naphthalin2- (4-hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cyclopropyloct-yloxy] - naphthalene
2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]-naphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin 2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene
2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cycl-opropyloctyl oxy]-naphthalin2- (3- [5-Methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene
2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin2- (4- [5-Methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene
2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyl-octyloxy] - naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyl octyloxy]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyl octyloxy] naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyl octyloxy]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyl octyloxy] naphthalene
2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[6-cyclo propyloctyloxy]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [6-cyclo propyloctyloxy] naphthalene
2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin 2- (4- [6-Cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyloctyl oxy]-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyloctyl oxy] naphthalene
2-(5-[5,5-dimethylsila]octyl-Pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyloctyl oxy]-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyloctyl oxy] naphthalene
2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,s-trifiuor-6--[6-cyclopropyl octyloxy]-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4, s-trifiuor-6 - [6-cyclopropyl octyloxy] naphthalene
2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloct-yloxy]- naphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloct-yloxy] - naphthalene
2-(5-[1-Heptans-ureester]-Pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin2- (5- [1-heptane ureester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin 2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene
2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cy-clopropyl octyloxy]-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [6-cy-clopropyl octyloxy] naphthalene
2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]- naphthalin2- (4- [4-oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] - naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene
2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cycl-opropyloctyl oxy]-naphthalin2- (3- [4-Oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene
2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin2- (4- [4-Oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene
2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctyloxy-]-naphthalin 2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy -] - naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene
2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cyclo-propyloctyl oxy]-naphthalin2- (3- [6-oxa-dodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclo-propyloctyl oxy] naphthalene
2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyl oxy]-naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyl oxy] naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopro-pyloctyloxy]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[6-cyclo propyloctyloxy]-naphthalin 2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [6-cyclo propyloctyloxy] naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[6-cyclo propyloctyloxy]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [6-cyclo propyloctyloxy] naphthalene
2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloct-yloxy]- naphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloct-yloxy] - naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene
2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cy-clopropyl octyloxy]-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cy-clopropyl octyloxy] naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyl oxy]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyl oxy] naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin 2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[6-cyclo propyloctyloxy]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [6-cyclo propyloctyloxy] naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[6-cyclo propyloctyloxy]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [6-cyclo propyloctyloxy] naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl oxy]-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-6-cyclopropyl octyloxy]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 6-cyclopropyl octyloxy] naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-6-cyclopropyl octyloxy]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 6-cyclopropyl octyloxy] naphthalene
2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[6- cyclopropyloctyloxy]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6- cyclopropyloctyloxy] naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[6- cyclopropyloctyloxy]-naphthalin 2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [6- cyclopropyloctyloxy] naphthalene
2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopropylocty-loxy]- naphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyloxy] - naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyloxy] - naphthalene
2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-c-yclopropyl octyloxy]-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-c-yclopropyl octyloxy] naphthalene
2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyc-lopropyl octyloxy]-naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cyc-lopropyl octyloxy] naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[6--cyclopropyl octyloxy]-naphthalin2- (4- [3-Propyloxirane-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[6- cyclopropyloctyloxy]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [6- cyclopropyloctyloxy] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[6- cyclopropyloctyloxy]-naphthalin 2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [6- cyclopropyloctyloxy] naphthalene
2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [6-cyclopropyloctyloxy]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [6-cyclopropyloctyloxy] naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [6-cyclopropyloctyloxy]-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [6-cyclopropyloctyloxy] naphthalene
2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]nonyl-napht-halin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl-napht-haline
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene
2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-dimethylsi-la]nonyl- naphthalin2- (3-hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsi-la] nonyl- naphthalene
2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila-]nonyl- naphthalin2- (4-hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila-] nonyl- naphthalene
2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin 2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene
2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-di-methylsila] nonyl-naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethyls-ila] nonyl- naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila] nonyl-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila] nonyl-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene
2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5,5-dimethyl sila]nonyl-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5,5-dimethyl sila] nonyl-naphthalene
2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-,5-dimethyl sila]nonyl-naphthalin 2- (4- [6-Cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene
2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl- naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila] nonyl-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila] nonyl-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene
2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5,5-dimethyl sila]nonyl-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5,5-dimethyl sila] nonyl-naphthalene
2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-,5-dimethyl sila]nonyl-naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene
2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila-]nonyl- naphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila-] nonyl- naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin 2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,-5-dimethyl sila]nonyl-naphthalin2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5, -5-dimethyl sila] nonyl-naphthalene
2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5--dimethyl sila]nonyl-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5,5-dimethyl sila] nonyl-naphthalene
2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene
2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-di-methylsila] nonyl-naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin2- (4- [4-oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]nony-l-naphthalin2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nony-l-naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyls-ila] nonyl- naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyls-ila] nonyl- naphthalene
2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-dim-ethylsila] nonyl-naphthalin2- (3- [6-oxadodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dimet-hylsila] nonyl-naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimeth-ylsila]nonyl- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimeth-ylsila] nonyl- naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,-5-dimethyl sila]nonyl-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5, -5-dimethyl sila] nonyl-naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,-5-dimethyl sila]nonyl-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5, -5-dimethyl sila] nonyl-naphthalene
2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[5,5- dimethylsila]nonyl-naphthalin2- (3- [perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [5,5- dimethylsila] nonyl-naphthalene
2-(4-[Perfluor-1H,1H-hepyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[5,5- dimethylsila]nonyl-naphthalin2- (4- [Perfluoro-1H, 1H-hepyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [5.5- dimethylsila] nonyl-naphthalene
2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila-]nonyl- naphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila-] nonyl- naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,-5-dimethylsila] nonyl-naphthalin2- (3- [9-cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5, -5-dimethylsila] nonyl naphthalene
2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5--dimethylsila] nonyl-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5 - dimethylsila] nonyl naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimet-hylsila] nonyl-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-,5-dimethyl sila]nonyl-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-,5-dimethyl sila]nonyl-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene
2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[5,5- dimethylsila]nonyl-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [5,5- dimethylsila] nonyl-naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5,5- dimethylsila]nonyl-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5,5- dimethylsila] nonyl-naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dime-thylsila] nonyl-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-5,5-dimethyl sila]nonyl-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 5,5-dimethyl sila] nonyl-naphthalene
2-(5-[2,3-Chloro-fluor-hepyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-,5-dimethyl sila]nonyl-naphthalin2- (5- [2,3-chloro-fluoro-hepyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene
2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[5,5- dimethylsila]nonyl-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5- dimethylsila] nonyl-naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5,5- dimethylsila]nonyl-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5.5- dimethylsila] nonyl-naphthalene
2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]-nonyl- naphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl- naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimet-hylsila]nonyl- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimet-hylsila] nonyl- naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimet-hylsila]nonyl- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimet-hylsila] nonyl- naphthalene
2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5--dimethylsila] nonyl-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene
2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-d-imethylsila] nonyl-naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[5-,5-dimethyl sila]nonyl-naphthalin2- (4- [3-Propyloxiran-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5,5- dimethylsila]nonyl-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5,5- dimethylsila] nonyl-naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5,5- dimethylsila]nonyl-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5,5- dimethylsila] nonyl-naphthalene
2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [5,5-dimethylsila]nonyl-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [5,5-dimethylsila] nonyl-naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [5,5-dimethylsila]nonyl-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [5,5-dimethylsila] nonyl-naphthalene
2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[1-hexansäureester]-naphthali-n2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthali-n
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline
2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexansäurees-ter]- naphthalin2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexansäureeste-r]-naphthalin2- (4-Hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] r -naphthalene
2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin 2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexa-nsäureester]- naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexa-acid ester] - naphthalene
2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäure ester]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäure ester]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthalene
2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[1-hexan säureester]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [1-hexane acid ester] -naphthalene
2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (4- [6-Cyclopropylhexyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin 2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäureester]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäureester]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[1-hexansäure ester]-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [1-hexanoic acid ester] -naphthalene
2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[1-hexansäureeste-r]- naphthalin2- (4- [1-heptanoic acid ester] -phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester-r] - naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin 2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthalene
2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-he-xansäure ester]-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [1-he-xanoic acid ester] -naphthalene
2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexa-nsäureester]- naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexaic acid ester] - naphthalene
2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (4- [4-oxa-nonyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[1 -hexansäureester]-naphthalin2- (4- [6-oxadodecyl] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexan-säureester]- naphthalin2- (3- [6-oxadodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäu-reester]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[1-hexan säureester]-naphthalin2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [1-hexane acid ester] -naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[1-hexan säureester]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [1-hexane acid ester] -naphthalene
2-(4-[9-Cyclopropylnonyl]-pheny-)-3,4,5-trifluor-6-[1-hexansäureeste-r]-naphthalin 2- (4- [9-Cyclopropylnonyl] pheny -) - 3,4,5-trifluoro-6- [1-hexanoic acid ester] r -naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trjfluor-6-[1-he-xansäure ester]-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-he-xanoic acid ester] -naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene
2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[1-hexan säureester]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [1-hexane acid ester] -naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[1-hexan säureester]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [1-hexane acid ester] -naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-1-hexansäure ester]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 1-hexanoic acid ester] -naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-1-hexansäure ester]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 1-hexanoic acid ester] -naphthalene
2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[1-hexan säureester]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexane acid ester] -naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[1-hexan säureester]-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [1-hexane acid ester] -naphthalene
2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäureester-]-naphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester -] - naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin 2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-h-exansäure ester]-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-h-exanoic acid ester] -naphthalene
2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hex-ansäureester]- naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[1--hexansäure- ester]-naphthalin2- (4- [3-Propyloxiran-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [1 - hexanoic acid- ester] -naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6- [1-hexansäureester]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [1-hexanoic acid ester] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6- [1-hexansäureester]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [1-hexanoic acid ester] naphthalene
2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor- 6-[1-hexansäureester]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro- 6- [1-hexanoic acid ester] naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [1-hexansäureester]-naphthalin 2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [1-hexanoic acid ester] naphthalene
2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naphthalin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] naphthalene
2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] naphthalene
2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa-nonyloxy-]-naphthalin2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy -] - naphthalene
2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]--naphthalin2- (4-Hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene
2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin 2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] - naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene
2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene
2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5-oxa-nonyl oxy]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5-oxa-nonyl oxy] naphthalene
2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5--oxa-nonyl oxy]-naphthalin2- (4- [6-Cyclopropylhexyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyl oxy] naphthalene
2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]-naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene
2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin 2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene
2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5-oxa-nonyl oxy]-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5-oxa-nonyl oxy] naphthalene
2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene
2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]--naphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (3- [1-heptanoic acid ester] -fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene
2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-ox-a-nonyloxy]- naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-ox-a-nonyloxy] - naphthalene
2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (4- [4-oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy-xy] - naphthalene
2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy-xy] - naphthalene
2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] - naphthalene
2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (4- [4-oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-napht-halin2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphtaline
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]-naphthalin2- (5- [6-Oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] naphthalene
2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]-naphthalin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] naphthalene
2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa-n-onyloxy]- naphthalin2- (3- [6-oxa-dodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa-n-onyloxy] - naphthalene
2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nony-loxy]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-nony-loxy] - naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene
2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene
2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[5-oxa- nonyloxy]-naphthalin2- (3- [perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [5-oxa- nonyloxy] naphthalene
2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[5-oxa- nonyloxy]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [5-oxa- nonyloxy] naphthalene
2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]--naphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene
2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-ox-a-nonyloxy]- naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-ox-a-nonyloxy] - naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-non- oxy]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-non- oxy] naphthalene
2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-nonyl- oxy]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyl- oxy] naphthalene
2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[5-oxa- nonyloxy]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [5-oxa- nonyloxy] naphthalene
2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5-oxa- nonyloxy]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5-oxa- nonyloxy] naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-5-oxa- nonyloxy]-naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 5-oxa- nonyloxy] naphthalene
2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-5-oxa- nonyloxy]-naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 5-oxa- nonyloxy] naphthalene
2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[5-oxa- nonyloxy]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa- nonyloxy] naphthalene
2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5-oxa- nonyloxy]-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5-oxa- nonyloxy] naphthalene
2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-n-aphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] n-aphthaline
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene
2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene
2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-o-xa-nonyloxy]- naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-o-xa-nonyloxy] - naphthalene
2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[5--oxa- nonyloxy]-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [5 - oxa- nonyloxy] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5- oxa-nonyloxy]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5- oxa nonyloxy] naphthalene
2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5- oxa-nonyloxy]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5- oxa nonyloxy] naphthalene
2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [5-oxa-nonyloxy]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [5-oxa-nonyloxy] naphthalene
2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [5-oxa-nonyloxy]-naphthalin.2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [5-oxa-nonyloxy] naphthalene.
Claims (10)
die Gruppe B ist R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 20 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂- Gruppen durch -O-,-S-,-CO-O-,-O-CO-, -O-CO-O-, -CO-, -CS-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂-, 1,4-Phenylen, trans- 1,4-Cyclohexylen oder trans-1,3-Cyclopentylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome und/oder Schwefelatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -Br, -OR³, -SCN, -OCN oder -N₃ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch): R³, R⁴, R⁵, R⁶, R⁷ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen (mit oder ohne asymmetrisches C-Atom-, wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran-, Butyrolacton- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -S-,-CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO-S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂-O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH=CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂-CH₂- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan- 2,5-diyl, 1,3-Dithian-2,5-diyl, 1,3-Thiazol-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, 1,3-Thiazol-2,5-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Piperazin-1,4-diyl, Piperazin-2,5-diyl, Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Bicyclo[2.2.2]octan- 1,4-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, 1,3-Dioxaborinan-2,5-diyl oder die Gruppe B;
a, b, c, d, e, f, g, h, i, k sind null oder eins.1. 3,4,5-trifluoronaphthalene derivative of the formula (I), R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (-A⁴) i (-M⁶) k -R² (I) in which the symbols and indices have the following meanings:
is group B. R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 20 C atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being substituted by -O -, - S -, - CO-O -, - O-CO-, -O-CO-O-, -CO-, - CS-, -CH = CH-, -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂-, 1,4-phenylene, trans-1,4-cyclohexylene or trans-1,3 -Cyclopentylene can be replaced, with the proviso that oxygen atoms and / or sulfur atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical are replaced by -F, -Cl, -Br, -OR³, -SCN , -OCN or -N₃ can be substituted, or one of the following groups (optically active or racemic): R³, R⁴, R⁵, R⁶, R⁷ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom, where also one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ can together also - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran, butyrolactone or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -S -, - CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO- S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂ -O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH = CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂ -CH₂- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, 1,3 -Dithiane-2,5-diyl, 1,3-thiazole-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, 1,3-thiazole-2,5-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms by F, Cl and / or CN may be replaced, piperazin-1,4-diyl, piperazin-2,5-diyl, naphthalene-2,6-diyl, it being possible for one or more H atoms to be replaced by F, Cl and / or CN, bicyclo [2.2 .2] octane-1,4-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, 1,3-dioxaborinane-2,5-diyl or the group B;
a, b, c, d, e, f, g, h, i, k are zero or one.
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 18 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O-,-CO-,-CO-O-,-O-CO-, -O-CO-O-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -OR³, -OCN oder -N₃ substituiert sein können, oder eine der nachfolgenden Gruppen (optisch aktiv oder racemisch): R³, R⁴, R⁵, R⁶, R⁷ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O-, -CH₂-O-, -O-CH₂-, -CH=CH-, -C≡C- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan- 2,5-diyl, Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, oder die Gruppe B;
a, b, c, d, e, f, g, h, i, k sind null oder ein.2. trifluoronaphthalene derivative according to claim 1, characterized in that the symbols and indices in the formula (I) have the following meanings:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 18 C atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being substituted by -O -, - CO -, - CO-O -, - O-CO-, -O-CO-O-, -CH = CH- , -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F, -Cl, -OR³, -OCN or -N₃, or one of the following groups (optically active or racemic): R³, R⁴, R⁵, R⁶, R⁷ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom), where also one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O- , -CH₂-O-, -O-CH₂-, -CH = CH-, -C≡C- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) -Thiadiazol-2,5-diyl, 1,3-dioxane-2,5-diyl, thiophene-2 , 4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, naphthalene -2,6-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, or the group B;
a, b, c, d, e, f, g, h, i, k are zero or one.
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine, zwei oder drei CH₂- Gruppen durch -O-, -CO-, -O-CO-, -CO-O-, -CH=CH-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl oder -OR³ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch): R³, R⁴, R⁵ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-9 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Dioxolan-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, -O-CH₂-, -CH=CH- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein, zwei oder drei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl oder Naphthalin-2,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können;
a, b, c, d, e, f, g, h, i, k sind null oder eins.3. trifluoronaphthalene derivative according to claim 1 and / or 2, characterized in that the symbols and indices in the formula (I) have the following meanings:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 16 C atoms (with or without an asymmetric carbon atom), where also one, two or three CH₂ groups by -O-, -CO-, -O-CO-, -CO-O-, -CH = CH-, cyclopropane-1,2 -diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical are used by -F , -Cl or -OR³ may be substituted, or also one of the following groups (optically active or racemic): R³, R⁴, R⁵ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-9 carbon atoms (with or without an asymmetric carbon atom), with one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to a dioxolane system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, - O-CH₂-, -CH = CH- or a single bond;
A¹, A², A³, A⁴ are the same or different 1,4-phenylene, where one, two or three H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, one or two H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, it being possible for one or two H atoms to be replaced by F, Cl and / or CN, trans-1,4-cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) -Thiadiazol-2,5-diyl or naphthalene-2,6-diyl, where one or two H atoms by F , Cl and / or CN can be replaced;
a, b, c, d, e, f, g, h, i, k are zero or one.
(F)ICH = 3,4,5-Trifluornaphthalin-2-6-diyl,
Phe = 1,4-Phenylen,
Pyr = Pyridin-2,5-diyl,
Pym = Pyrimidin-2,5-diyl,
Diox = 1,3-Dioxan-2,5-diyl,
Naf = Naphthalin-2,6-diyl,
F₂Phe = Difluorbenzol-1,6-diyl,
(F)Pyr = Fluorpyridin-2,5-diyl und
TDZ = (1,3,4)-Thiadiazol-2,5-diyl
bedeuten und M¹, M⁶, R¹, R² die in der Formel (I) angegebenen Bedeutungen haben.4. trifluoronaphthalene derivative according to one or more of claims 1 to 3, characterized in that the group (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (A⁴) i has one of the following meanings: with the abbreviations
(F) ICH = 3,4,5-trifluoronaphthalene-2-6-diyl,
Phe = 1,4-phenylene,
Pyr = pyridine-2,5-diyl,
Pym = pyrimidine-2,5-diyl,
Diox = 1,3-dioxane-2,5-diyl,
Naf = naphthalene-2,6-diyl,
F₂Phe = difluorobenzene-1,6-diyl,
(F) Pyr = fluoropyridine-2,5-diyl and
TDZ = (1,3,4) thiadiazole-2,5-diyl
mean and M¹, M⁶, R¹, R² have the meanings given in the formula (I).
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DE19522195A DE19522195A1 (en) | 1994-06-20 | 1995-06-19 | Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt. |
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DE4421547 | 1994-06-20 | ||
DE19522195A DE19522195A1 (en) | 1994-06-20 | 1995-06-19 | Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt. |
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