DE19522195A1 - Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt. - Google Patents

Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt.

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DE19522195A1
DE19522195A1 DE19522195A DE19522195A DE19522195A1 DE 19522195 A1 DE19522195 A1 DE 19522195A1 DE 19522195 A DE19522195 A DE 19522195A DE 19522195 A DE19522195 A DE 19522195A DE 19522195 A1 DE19522195 A1 DE 19522195A1
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Prior art keywords
trifluoro
naphthalene example
diyl
atoms
naphthalene
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DE19522195A
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Javier Dr Manero
Robert Walter Dr Fuss
Barbara Hornung
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Merck Patent GmbH
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Hoechst AG
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Abstract

3,4,5-trifluoronaphthalene derivs. of formula (I) are new: R<1>(-M<1>)a(-A<1>)b(-M<2>)c(-A<2>)d(-M<3>)e-B(m<4>)f(-A<3>)g(-M<5>)h (-A<4>)i(-M<6>)k-R<2> (I); B= 3,4,5-trifluoro-naphthalene-2,6-diyl; R<1>, R<2> = (a) H, CN, F, Cl, CF3, CHF2, CH2F, OCF3, OCHF2 or OCH2F; (b) 1-20 C alkyl (opt. with an asymmetrical C atom), in which 1 or more CH2 gps. may be replaced by -O-, -S-, -CO-O-, -O-CO-, -O-CO-O-, -CO-, -CS-, -CH=CH-, -C=C-, cyclopropan-1,2-diyl, -SiMe2-, 1,4-phenylene, trans-1,4-cyclohexylene or trans-1,3-cyclopentylene, without directly linked O and/or S atoms, and/or with 1 or more, F, Cl, Br, OR<3>, -SCN, -OCN or N3 substit(s).; or (c) an (optically active or racemic) gp. of formulae (IIA-S): R<3-7> = H; 1-16 C alkyl (opt. with an asymmetrical C atom), in which 1 or more CH2 gps. may be replaced by -O- and/or -CH=CH-, without directly linked O atoms, and/or with 1 or more F or Cl substit(s).; or R<4>, R<5> = -(CH2)5- or -(CH2)5- if attached to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran, butyrolactone or valerolactone system; Y = Cl, F or CN; Z = -CO- or -CH2-; M<1>-M6 = -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O- -CO-S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S, -O-CS-O-, -S-CO-S-, -CS-, -CH2-O-, -O-CH2-, -S-CH2-, -CH=CH-, -C=C-, -CH2-CH2-CO-O-, -O-CO-CH2-CH2- or a single bond; A<1>-A<4> - 1,4-phenylene, pyridin-2,5-diyl, naphthalen-2,6-diyl or bicyclo(2.2.2)-octan-1,4-diyl, opt. with 1 or more F, Cl and/or CN substit(s).; pyrazin-2,5-diyl, pyridazin-3-6-diyl, pyrimidin-2,5-diyl or thiophen-2,5-diyl, opt. with 1 or 2 F, Cl and/or CN substits.; 1,3-thiazol-2,4- or -2,5-diyl or thiophen-2,4-diyl, opt. with one F, Cl and/or CN substit.; trans-1,4-cyclohexylene, opt. with 1 or 2 CN and/or Me substits.; (1,3,4)-thiadiazol-2,5-diyl; 1,3-dioxan-2,5-diyl; 1,3-dithian-2,5-diyl; piperazin-1,4- or -2,5-diyl; 1,3-dioxaborinan-2,5-diyl; or a B gp.; a,b,c,d,e,f,g,h,i,k = 0 or 1. Also claimed are liquid crystal (LC) mixts. contg. (I).

Description

Neben nematischen und cholesterischen Flüssigkristallen werden in jüngerer Zeit auch optisch aktive geneigt smektische (ferroelektrische) Flüssigkristalle in kommerziellen Displayvorrichtungen verwendet.In addition to nematic and cholesteric liquid crystals, more recently also optically active inclined smectic (ferroelectric) liquid crystals in commercial display devices used.

Clark und Lagerwall konnten zeigen, daß der Einsatz ferroelektrischer Flüssigkristalle (FLC) in sehr dünnen Zellen zu optoelektrischen Schalt- oder Anzeigeelementen führt, die im Vergleich zu den herkömmlichen TN ("twisted nematic")-Zellen um bis zu einem Faktor 1000 schnellere Schaltzeiten haben (siehe z. B. EP-A 0 032 362). Aufgrund dieser und anderer günstiger Eigenschaften, z. B. der bistabilen Schaltmöglichkeit und des nahezu blickwinkelunabhängigen Kontrasts, sind FLCs grundsätzlich für Anwendungsgebiete wie Computerdisplays gut geeignet.Clark and Lagerwall were able to show that the use of ferroelectric Liquid crystals (FLC) in very thin cells for optoelectric switching or Display elements leads, which compared to the conventional TN ("twisted nematic ") cells have switching times that are up to a factor of 1000 faster (see e.g. EP-A 0 032 362). Because of this and others cheaper Properties, e.g. B. the bistable switching option and almost angle-independent contrast, FLCs are basically for Areas of application such as computer displays are well suited.

Für die Verwendung von FLCs in elektrooptischen oder vollständig optischen Bauelementen benötigt man entweder Verbindungen, die geneigte bzw. orthogonale smektische Phasen ausbilden und selbst optisch aktiv sind, oder man kann durch Dotierung von Verbindungen, die zwar solche smektischen Phasen ausbilden, selbst aber nicht optisch aktiv sind, mit optisch aktiven Verbindungen ferroelektrische smektische Phasen induzieren. Die gewünschte Phase soll dabei über einen möglichst großen Temperaturbereich stabil sein.For the use of FLCs in electro-optical or completely optical Components either require connections that are inclined or form orthogonal smectic phases and are themselves optically active, or one can by doping compounds that are smectic Form phases, but are not optically active themselves, with optically active ones Compounds induce ferroelectric smectic phases. The desired The phase should be stable over the largest possible temperature range.

Zur Erzielung eines guten Kontrastverhältnisses in elektrooptischen Bauelementen ist eine einheitliche planare Orientierung der Flüssigkristalle nötig. Eine gute Orientierung in der SA und S*C-Phase läßt sich z. B. erreichen, wenn die Phasenfolge der Flüssigkristallmischung mit abnehmender Temperatur lautet:A uniform planar orientation of the liquid crystals is necessary to achieve a good contrast ratio in electro-optical components. A good orientation in the S A and S * C phase can e.g. B. achieve if the phase sequence of the liquid crystal mixture with decreasing temperature is:

Isotrop → N* → SA → S*C Isotropic → N * → S A → S * C

Voraussetzung ist, daß der Pitch (Ganghöhe der Helix) in der N*-Phase sehr groß (größer 10 µm) oder, noch besser, völlig kompensiert ist (siehe z. B. T. Matsumoto et al., p. 468-470, Proc. of the 6th Int. Display Research Conf., Japan Display, Sept. 30 - Okto. 2, 1986, Tokyo, Japan; M. Murakami et al., ibid. S. 344 - S. 347). Dies erreicht man z. B., indem man zu der chiralen Flüssigkristallmischung, die in der N*-Phase z. B. eine linksdrehende Helix aufweist, einen oder mehrere optisch aktive Dotierstoffe, die eine rechtsdrehende Helix induzieren, in solchen Mengen hinzugibt, daß die Helix kompensiert wird.The prerequisite is that the pitch (pitch of the helix) is very high in the N * phase large (larger than 10 µm) or, even better, completely compensated (see e.g. T. Matsumoto et al., P. 468-470, Proc. of the 6th Int. Display Research Conf., Japan Display, Sept. 30 - Octo. 2, 1986, Tokyo, Japan; M. Murakami et al., ibid. P. 344 - p. 347). This is achieved e.g. B. by going to the chiral Liquid crystal mixture which in the N * phase z. B. a left-turning helix has one or more optically active dopants, the one induce clockwise helix in such amounts that the helix is compensated.

Für die Verwendung des SSFLCD-Effektes (Surface Stabilized Ferroelectric Liquid Crystal Display) von Clark und Lagerwall zur einheitlichen, planaren Orientierung ist ferner Voraussetzung, daß der Pitch in der smektischen C* Phase wesentlich größer ist als die Dicke des Anzeigeelementes (Mol. Cryst. Liq. Cryst. 94 (1983) 213-134 und 114 (1984) 151-187). Dies erreicht man, wie im Fall des cholesterischen Pitches, durch Verwendung von Dotierstoffen mit entgegengesetztem Drehsinn der Helix.For the use of the SSFLCD effect (Surface Stabilized Ferroelectric Liquid Crystal Display) from Clark and Lagerwall for uniform, planar Orientation is also a prerequisite that the pitch in the smectic C * Phase is significantly greater than the thickness of the display element (Mol. Cryst. Liq. Cryst. 94 (1983) 213-134 and 114 (1984) 151-187). This is achieved, as in the Case of cholesteric pitch, by using dopants with opposite direction of rotation of the helix.

Die optische Schaltzeit T [µs] ferroelektrischer Flüssigkristallsysteme, die möglichst kurz sein soll, hängt von der Rotationsviskosität des Systems Y [mPas], der spontanen Polarisation PS[nC/cm²] und der elektrischen Feldstärke E[V/m] ab nach der BeziehungThe optical switching time T [µs] of ferroelectric liquid crystal systems, which should be as short as possible, depends on the rotational viscosity of the system Y [mPas], the spontaneous polarization P S [nC / cm²] and the electric field strength E [V / m] according to relationship

Da die Feldstärke E durch den Elektrodenabstand im elektrooptischen Bauteil und durch die angelegte Spannung festgelegt ist, muß das ferroelektrische Anzeigemedium niedrigviskos sein und eine hohe spontane Polarisation aufweisen, damit eine kurze Schaltzeit erreicht wird. Since the field strength E is due to the electrode spacing in the electro-optical component and is determined by the applied voltage, the ferroelectric Display medium be low viscosity and high spontaneous polarization have so that a short switching time is achieved.  

Schließlich wird neben thermischer, chemischer und photochemischer Stabilität eine kleine optische Anisotropie Δn, vorzugsweise ≈ 0,13, und eine geringe positive oder vorzugsweise negative dielektrische Anisotropie Δ∈ verlangt (siehe z. B. S.T. Lagerwall et al., "Ferroelectric Liquid Crystals for Displays" SID Symposium, Oct. Meeting 1985, San Diego, Ca, USA). Die Gesamtheit dieser Forderungen ist nur mit Mischungen aus mehreren Komponenten zu erfüllen. Als Basis (oder Matrix) dienen dabei bevorzugt Verbindungen, die möglichst selbst bereits die gewünschte Phasenfolge I→N→SA→SC aufweisen. Weitere Komponenten der Mischung werden oftmals zur Schmelzpunktserniedrigung und zur Verbreiterung der SC- und meist auch N-Phase, zum Induzieren der optischen Aktivität, zur Pitch-Kompensation und zur Anpassung der optischen und dielektrischen Anisotropie zugesetzt, wobei aber beispielsweise die Rotationsviskosität möglichst nicht vergrößert werden soll.Finally, in addition to thermal, chemical and photochemical stability, a small optical anisotropy Δn, preferably ≈ 0.13, and a low positive or preferably negative dielectric anisotropy Δ∈ are required (see, for example, BST Lagerwall et al., "Ferroelectric Liquid Crystals for Displays" SID Symposium, Oct. Meeting 1985, San Diego, Ca, USA). All of these requirements can only be met with mixtures of several components. The basis (or matrix) used is preferably compounds which, if possible, already have the desired phase sequence I → N → S A → S C. Other components of the mixture are often added to lower the melting point and broaden the S C - and usually also the N phase, to induce optical activity, to compensate for pitch and to adjust the optical and dielectric anisotropy, but, for example, do not increase the rotational viscosity if possible shall be.

Ferroelektrische Flüssigkristallanzeigen lassen sich auch durch Nutzung des DHF (Distorted Helix Formation)-Effektes oder des PSFLCD-Effektes (Pitch Stabilized Ferroelectric Liquid Crystal Display, auch SBF = Short pitch Bistable Ferroelektric Effekt genannt) betreiben. Der DHF-Effekt wurde von B.I. Ostrovski in Advances in Liquid Crystal Research and Applications, Oxford/Budapest 1980, 469 ff. beschrieben, der PSFLCD-Effekt ist in DE-A 39 20 625 bzw. EP-A 0 405 346 beschrieben. Zur Nutzung dieser Effekte wird im Gegensatz zum SSFLCD-Effekt ein flüssigkristallines Material mit einem kurzen SC-Pitch benötigt.Ferroelectric liquid crystal displays can also be operated by using the DHF (Distorted Helix Formation) effect or the PSFLCD effect (Pitch Stabilized Ferroelectric Liquid Crystal Display, also called SBF = Short pitch Bistable Ferroelectric Effect). The DHF effect was described by BI Ostrovski in Advances in Liquid Crystal Research and Applications, Oxford / Budapest 1980, 469 ff., The PSFLCD effect is described in DE-A 39 20 625 and EP-A 0 405 346. In contrast to the SSFLCD effect, a liquid crystal material with a short S C pitch is required to use these effects.

Naphthalinderivate zur Verwendung in Flüssigkristallmischungen sind beispielsweise aus der WO-A 92/16500 bekannt.Naphthalene derivatives are for use in liquid crystal mixtures known for example from WO-A 92/16500.

Da die Entwicklung, insbesondere von ferroelektrischen Flüssigkristallmischungen, aber noch in keiner Weise als abgeschlossen betrachtet werden kann, sind die Hersteller von Displays an den unterschiedlichsten Komponenten für Mischungen interessiert. Dieses u. a. auch deshalb, weil erst das Zusammenwirken der flüssigkristallinen Mischungen mit den einzelnen Bauteilen der Anzeigevorrichtung bzw. der Zellen (z. B. der Orientierungsschicht) Rückschlüsse auf die Qualität auch der flüssigkristallinen Mischungen zuläßt.Because the development, especially of ferroelectric Liquid crystal mixtures, but in no way as complete can be considered, the manufacturers of displays on the various components interested in mixtures. This u. a. also  because only the interaction of the liquid crystalline mixtures with the individual components of the display device or the cells (e.g. the Orientation layer) conclusions on the quality of the liquid crystalline Allows mixtures.

Aufgabe der vorliegenden Erfindung war es daher, neue Verbindungen bereitzustellen, die in flüssigkristallinen Mischungen geeignet sind, das Eigenschaftsprofil dieser Mischungen zu verbessern.The object of the present invention was therefore to create new compounds To provide, which are suitable in liquid crystalline mixtures, the To improve the property profile of these mixtures.

Es wurde nun überraschend gefunden, daß 2,6-disubstituierte 3,4,5-Trifluornaphthalin-Derivate der Formel (I) in besonderer Weise zum Einsatz in Flüssigkristallmischungen geeignet sind.It has now surprisingly been found that 2,6-disubstituted 3,4,5-trifluoronaphthalene derivatives of the formula (I) for use in Liquid crystal mixtures are suitable.

Gegenstand der Erfindung sind daher Verbindungen der Formel (I)The invention therefore relates to compounds of the formula (I)

R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e-B(-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)k-R² (I)R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (-A⁴) i (- M⁶) k -R² (I)

in der die Symbole und Indizes folgende Bedeutungen haben:
die Gruppe B istin which the symbols and indices have the following meanings:
is group B.

R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 20 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂- Gruppen durch -O-, -S-, -CO-O-, -O-CO-, -O-CO-O-, -CO-, -CS-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂-, 1,4-Phenylen, trans-1,4-Cyclohexylen oder trans-1,3-Cyclopentylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome und/oder Schwefelatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -Br, -OR³, -SCN, -OCN oder -N₃ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch):R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 20 C atoms (with or without asymmetric carbon atom), one or more CH₂- Groups by -O-, -S-, -CO-O-, -O-CO-, -O-CO-O-, -CO-, -CS-, -CH = CH-, -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂-, 1,4-phenylene, trans-1,4-cyclohexylene or trans-1,3-cyclopentylene can be replaced can, with the proviso that oxygen atoms and / or  Sulfur atoms are not directly bound to one another may, and / or wherein one or more H atoms of the alkyl radical be substituted by -F, -Cl, -Br, -OR³, -SCN, -OCN or -N₃ can, or one of the following groups (optically active or racemic):

R³, R⁴, R⁵, R⁶, R⁷ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran-, Butyrolacton- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO-S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂-O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH=CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂-CH₂- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan-2,5-diyl, 1,3-Dithian-2,5-diyl, 1,3-Thiazol-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, 1,3-Thiazol-2,5-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Piperazin-1,4-diyl, Piperazin-2,5-diyl, Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Bicyclo[2.2.2]octan-1,4-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, 1,3-Dioxaborinan-2,5-diyl oder die Gruppe B;
a, b, c, d, e, f, g, h, i und K sind null oder eins, vorzugsweise mit der Maßgabe, daß die Summe aus b, d, g und i 0, 1 oder 2 sein muß. R³, R⁴, R⁵, R⁶, R⁷ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom), where also one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran, butyrolactone or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -S-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO- S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂ -O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH = CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂ -CH₂- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, 1,3 -Dithiane-2,5-diyl, 1,3-thiazole-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, 1,3-thiazole-2,5-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms by F, Cl and / or CN e may be substituted, piperazine-1,4-diyl, piperazine-2,5-diyl, naphthalene-2,6-diyl, it being possible for one or more H atoms to be replaced by F, Cl and / or CN, bicyclo [2.2 .2] octane-1,4-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, 1,3-dioxaborinane-2,5-diyl or the group B;
a, b, c, d, e, f, g, h, i and K are zero or one, preferably with the proviso that the sum of b, d, g and i must be 0, 1 or 2.

Die Verbindungen der Formel (I) sind in reinem Zustand farblos und bilden im allgemeinen flüssigkristalline Mesophasen in einem für die elektrooptische Verwendung günstig gelegenen Temperaturbereich. Chemisch, thermisch und gegen Licht sind sie stabil.The compounds of formula (I) are colorless in the pure state and form in general liquid crystalline mesophases in one for electro-optical Use conveniently located temperature range. Chemical, thermal and they are stable against light.

Besonders geeignet sind die Verbindungen der Formel (I), um schon in geringen Zumischmengen die dielektrische Anisotropie Δ∈ flüssigkristalliner Mischungen in Richtung auf höhere negative Werte zu beeinflussen.The compounds of formula (I) are particularly suitable, even in small amounts The dielectric anisotropy Δ∈ in liquid-crystalline mixtures is added in Direction towards higher negative values.

Bevorzugt sind Verbindungen der allgemeinen Formel (I), in der die Symbole und Indizes folgende Bedeutungen haben:
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 18 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -OR³, -OCN oder -N₃ substituiert sein können, oder eine der nachfolgenden Gruppen (optisch aktiv oder racemisch):Compounds of the general formula (I) in which the symbols and indices have the following meanings are preferred:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 18 C atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH = CH- , -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F, -Cl, -OR³, -OCN or -N₃, or one of the following groups (optically active or racemic):

R³, R⁴, R⁵, R⁶, R⁷ sind gleich ein Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O-, -CH₂-O-, -O-CH₂-, -CH=CH-, -C≡C- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan-2,5-diyl, Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, oder die Gruppe B;
a, b, c, d, e, f sind null oder eins, mit der Maßgabe, daß die Summe aus b, c, d und e 0, 1 oder 2 ist.R³, R⁴, R⁵, R⁶, R⁷ are the same as hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O- , -CH₂-O-, -O-CH₂-, -CH = CH-, -C≡C- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, thiophene-2 , 4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, naphthalene -2,6-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, or the group B;
a, b, c, d, e, f are zero or one, with the proviso that the sum of b, c, d and e is 0, 1 or 2.

Besonders bevorzugt sind Verbindungen der allgemeinen Formel (I), in der die Symbole und Indizes folgende Bedeutungen haben:
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine, zwei oder drei CH₂-Gruppen durch -O-, -CO-, -O-CO-, -CO-O-, -CH=CH-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl oder -OR³ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch):Compounds of the general formula (I) in which the symbols and indices have the following meanings are particularly preferred:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 16 C atoms (with or without an asymmetric carbon atom), where also one, two or three CH₂ groups by -O-, -CO-, -O-CO-, -CO-O-, -CH = CH-, cyclopropane-1,2 -diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical are used by -F , -Cl or -OR³ may be substituted, or also one of the following groups (optically active or racemic):

R³, R⁴, R⁵ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-9 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Dioxolan-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, -O-CH₂-, -CH=CH- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein, zwei oder drei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl oder Naphthalin-2,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können;
a, b, c, d, e, f, g, h, i, k sind null oder eins; vorzugsweise mit der Maßgabe, daß die Summe aus b, d, g und i 0, 1 oder 2 ist.R³, R⁴, R⁵ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-9 carbon atoms (with or without an asymmetric carbon atom), with one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to a dioxolane system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, - O-CH₂-, -CH = CH- or a single bond;
A¹, A², A³, A⁴ are the same or different 1,4-phenylene, where one, two or three H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, one or two H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, it being possible for one or two H atoms to be replaced by F, Cl and / or CN, trans-1,4-cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) -Thiadiazol-2,5-diyl or naphthalene-2,6-diyl, where one or two H atoms by F , Cl and / or CN can be replaced;
a, b, c, d, e, f, g, h, i, k are zero or one; preferably with the proviso that the sum of b, d, g and i is 0, 1 or 2.

Insbesondere bevorzugt sind Verbindungen der Formel (I), in denen die Gruppe (-A¹)b(-M²)c(-A²)d(-M³)e-B(-M⁴)f(-A³)g(-M⁵)h(A⁴)i eine der folgenden Bedeutungen hat:Particularly preferred are compounds of formula (I) in which the group (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (A⁴) i has one of the following meanings:

wobei die Abkürzungenwith the abbreviations

(F)ICH = 3,4,5-Trifluornaphthalin-2,6-diyl,
Phe = 1,4-Phenylen,
Pyr = Pyridin-2,5-diyl,
Pym = Pyrimidin-2,5-diyl,
Diox = 1,3-Dioxan-2,5-diyl,
Naf = Naphthalin-2,6-diyl,
F₂Phe = Difluorbenzol-1,6-diyl,
(F)Pyr = Fluorpyridin-2,5-diyl und
TDZ = (1,3,4)-Thiadiazol-2,5-diyl(F) ICH = 3,4,5-trifluoronaphthalene-2,6-diyl,
Phe = 1,4-phenylene,
Pyr = pyridine-2,5-diyl,
Pym = pyrimidine-2,5-diyl,
Diox = 1,3-dioxane-2,5-diyl,
Naf = naphthalene-2,6-diyl,
F₂Phe = difluorobenzene-1,6-diyl,
(F) Pyr = fluoropyridine-2,5-diyl and
TDZ = (1,3,4) thiadiazole-2,5-diyl

bedeuten und M¹, M⁶, R¹, R² die in der Formel (I) angegebenen Bedeutungen haben.mean and M¹, M⁶, R¹, R² have the meanings given in formula (I) to have.

Die Herstellung der erfindungsgemäßen Verbindungen erfolgt nach an sich literaturbekannten Methoden, wie sie in Standardwerken zur Organischen Synthese, z. B. Houben-Weyl, Methoden der Organischen Chemie, Georg-Thieme-Verlag, Stuttgart, beschrieben werden.The compounds according to the invention are prepared per se methods known from the literature, as used in standard works on organic matter Synthesis, e.g. B. Houben-Weyl, Methods of Organic Chemistry, Georg-Thieme-Verlag, Stuttgart.

Die Herstellung erfolgt dabei unter Reaktionsbedingungen, die für die genannten Umsetzungen bekannt und geeignet sind. Dabei kann auch von an sich bekannten, hier nicht näher erwähnten Varianten Gebrauch machen.The production takes place under reaction conditions for the above Implementations are known and suitable. It can also by itself make use of known variants not mentioned here.

Die Ausgangsstoffe können gewünschtenfalls auch in situ gebildet werden, und zwar derart, daß man sie aus dem Reaktionsgemisch nicht isoliert, sondern sofort weiter zu den Verbindungen der Formel (I) umsetzt.If desired, the starting materials can also be formed in situ, and in such a way that they are not isolated from the reaction mixture, but rather immediately continues to react to the compounds of formula (I).

Beispielhaft ist in Schema 1 ein Syntheseweg zu Verbindungen der Formel (I) angegeben, wobei auch andere Verfahren denkbar und möglich sind. Exemplary in Scheme 1 is a synthetic route to compounds of formula (I) specified, although other methods are conceivable and possible.  

Schema 1 Scheme 1

Die Gruppe Pg ist gleich der Gruppierung R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e oder eine geeignete, gegebenenfalls geschützte Vorstufe hiervon, die in späteren Schritten nach an sich bekannten, dem Fachmann geläufigen Methoden in diese Gruppierung überführt werden kann.The group P g is equal to the grouping R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e or a suitable, optionally protected precursor thereof, which in later steps per se known methods known to those skilled in the art can be converted into this grouping.

Beispielsweise kann Pg ein Perfluoralkylsulfonat sein, wobei dann durch Kupplung mit beispielsweise einer entsprechenden Boronsäure die Gruppierung R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e eingeführt wird.For example, P g may be a perfluoroalkyl sulfonate, the group R 1 (-M 1) a (-A 1) b (-M 2) c (-A 2) d (-M 3) e then being introduced by coupling with, for example, a corresponding boronic acid.

Rx ist gleich der Gruppierung (-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)k-R² oder eine geeignete gegebenenfalls, geschützte Vorstufe hiervon, die in späteren Schritten nach an sich bekannten, dem Fachmann geläufigen Methoden in diese Gruppierung überführt werden kann.R x is equal to the grouping (-M⁴) f (-A³) g (-M⁵) h (-A⁴) i (-M⁶) k -R² or a suitable, if appropriate, protected precursor thereof which is known per se in later steps , methods familiar to the person skilled in the art can be transferred into this grouping.

Die Synthese des Restes R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e bzw. (-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)kR² erfolgt nach an sich bekannten, dem Fachmann geläufigen Methoden.The synthesis of the radical R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e or (-M⁴) f (-A³) g (-M⁵) h (-A⁴ ) i (-M⁶) k R² is carried out according to methods known per se and familiar to the person skilled in the art.

Die Herstellung erfolgt dabei unter Reaktionsbedingungen, die für die genannten Umsetzungen bekannt und geeignet sind. Dabei kann auch von an sich bekannten, hier nicht näher erwähnten Varianten Gebrauch machen.The production takes place under reaction conditions for the above Implementations are known and suitable. It can also by itself make use of known variants not mentioned here.

Beispielsweise sei verwiesen auf DE-A 23 44 732, 24 50 088, 24 29 093, 25 02 94, 26 36 684, 27 01 591 und 27 52 975 für Verbindungen mit 1,4-Cyclohexylen und 1,4-Phenylen-Gruppen; DE-A 26 41 724 für Verbindungen mit Pyrimidin-2,5-diyl-Gruppen; DE-A 40 26 223 und EP-A 03 91 203 für Verbindungen mit Pyridin-2,5-diyl-Gruppen; DE-A 32 31 462 für Verbindungen mit Pyridazin-3,6-diyl-Gruppen; EP-A 309 514 für Verbindungen mit (1,3,4)-Thiadiazol-2-5-diyl-Gruppen; WO-A 92/16500 für Naphthalin-2,6-diyl-Gruppen; DE-A 37 10 890 für Bicyclo[2.2.2.]octan-1,4-diyl-Gruppen; K. Seto et al., Journal of the Chemical Society, Chemical Communications 1988, 56 für Dioxoborinan-2,5-diyl-Gruppen.For example, reference is made to DE-A 23 44 732, 24 50 088, 24 29 093, 25 02 94, 26 36 684, 27 01 591 and 27 52 975 for connections with 1,4-cyclohexylene and 1,4-phenylene groups; DE-A 26 41 724 for connections with Pyrimidine-2,5-diyl groups; DE-A 40 26 223 and EP-A 03 91 203 for Compounds with pyridine-2,5-diyl groups; DE-A 32 31 462 for connections  with pyridazine-3,6-diyl groups; EP-A 309 514 for connections with (1,3,4) -Thiadiazol-2-5-diyl groups; WO-A 92/16500 for naphthalene-2,6-diyl groups; DE-A 37 10 890 for bicyclo [2.2.2.] Octane-1,4-diyl groups; K. Seto et al., Journal of the Chemical Society, Chemical Communications 1988, 56 for Dioxoborinan-2,5-diyl groups.

Die Herstellung disubstituierter Pyridine, disubstituierter Pyrazine, disubstituierter Pyrimidine und disubstituierter Pyridazine findet sich beispielsweise auch in den entsprechenden Bänden der Serie "The Chemistry of Heterocyclic Compounds" von A. Weissberger und E.C. Taylor (Herausgeber).The production of disubstituted pyridines, disubstituted pyrazines, disubstituted pyrimidines and disubstituted pyridazines are found for example also in the corresponding volumes of the series "The Chemistry of Heterocyclic Compounds "by A. Weissberger and E.C. Taylor (editors).

Dioxanderivate werden zweckmäßig durch Reaktion eines entsprechenden Aldehyds (oder eines seiner reaktionsfähigen Derivate) mit einem entsprechenden 1,3-Diol (oder einem seiner reaktionsfähigen Derivate) hergestellt, vorzugsweise in Gegenwart eines inerten Lösungsmittels, wie Benzol oder Toluol, und/oder eines Katalysators, z. B. einer starken Säure, wie Schwefelsäure, Benzol- oder p-Toluolsulfonsäure, bei Temperaturen zwischen etwa 20°C und etwa 150°C, vorzugsweise zwischen 80°C und 120°C. Als reaktionsfähige Derivate der Ausgangsstoffe eignen sich in erster Linie Acetale.Dioxane derivatives are useful by reacting an appropriate one Aldehyde (or one of its reactive derivatives) with a corresponding 1,3-diol (or one of its reactive derivatives) prepared, preferably in the presence of an inert solvent such as benzene or toluene, and / or a catalyst, e.g. B. a strong acid, such as Sulfuric acid, benzene or p-toluenesulfonic acid, at temperatures between about 20 ° C and about 150 ° C, preferably between 80 ° C and 120 ° C. When reactive derivatives of the starting materials are primarily suitable for acetals.

Die genannten Aldehyde und 1,3-Diole sowie ihre reaktionsfähigen Derivate sind zum Teil bekannt, zum Teil können sie ohne Schwierigkeiten nach Standardverfahren der Organischen Chemie aus literaturbekannten Verbindungen hergestellt werden. Beispielsweise sind die Aldehyde durch Oxydation entsprechender Alkohole oder durch Reduktion von Nitrilen oder entsprechenden Carbonsäuren oder ihrer Derivate, die Diole durch Reduktion entsprechender Diester erhältlich.The aldehydes and 1,3-diols mentioned and their reactive derivatives are partly known, partly they can be followed without difficulty Standard methods of organic chemistry from literature Connections are made. For example, the aldehydes are through Oxidation of appropriate alcohols or by reduction of nitriles or corresponding carboxylic acids or their derivatives, the diols by reduction corresponding diester available.

Verbindungen, worin ein aromatischer Ring durch mindestens ein F-Atom substituiert ist, können auch aus den entsprechenden Diazoniumsalzen durch Austausch der Diazoniumgruppe gegen ein Fluoratom, z. B. nach den Methoden von Balz und Schiemann, erhalten werden. Compounds in which an aromatic ring has at least one F atom is substituted, can also from the corresponding diazonium salts Exchange of the diazonium group for a fluorine atom, e.g. B. according to the methods from Balz and Schiemann.  

Was die Verknüpfung der Ringsysteme miteinander angeht, sei verwiesen auf: N. Miyaura, T. Yanagai und A. Suzuki in Synthetic Communications 11 (1981) 513-519; DE-C-39 30 663, M.J. Sharp, W. Cheng, V. Snieckus in Tetrahedron Letters 28 (1987) 5093; G.W. Gray in J. Chem. Soc. Perkin Trans II 1989, 2041 und Mol. Cryst. Liq. Cryst. 172 (1989)165, 204 (1991) 43 und 91; EP-A 0 449 015; WO-A 89/12039; WO-A 89/03821; EP-A 0 354 434 für die direkte Verknüpfung von Aromaten und Heteroaromaten; DE-A 32 01 721 für Verbindungen mit -CH₂CH₂-Brückengliedern und Koji Seto et al. in Liquid Crystals 8 (1990) 861-870 für Verbindungen mit -C≡C-Brückengliedern.Regarding the connection of the ring systems with each other, please refer to: N. Miyaura, T. Yanagai and A. Suzuki in Synthetic Communications 11 (1981) 513-519; DE-C-39 30 663, M.J. Sharp, W. Cheng, V. Snieckus in Tetrahedron Letters 28 (1987) 5093; G.W. Gray in J. Chem. Soc. Perkin Trans II 1989, 2041 and Mol. Cryst. Liq. Cryst. 172: 165, 204 (1991) 43 and 91; EP-A 0 449 015; WO-A 89/12039; WO-A 89/03821; EP-A 0 354 434 for the direct linking of aromatics and heteroaromatics; DE-A 32 01 721 for Connections with -CH₂CH₂ bridge members and Koji Seto et al. in liquid Crystals 8 (1990) 861-870 for connections with -C≡C bridge members.

Ester der Formel (I) können auch durch Veresterung entsprechender Carbonsäuren (oder ihrer reaktionsfähigen Derivate) mit Alkoholen bzw. Phenolen (oder ihren reaktionsfähigen Derivaten) oder nach der DCC-Methode (DCC = Dicyclohexylcarbodiimid) erhalten werden.Esters of the formula (I) can also be correspondingly esterified Carboxylic acids (or their reactive derivatives) with alcohols or Phenols (or their reactive derivatives) or by the DCC method (DCC = dicyclohexylcarbodiimide) can be obtained.

Die entsprechenden Carbonsäuren und Alkohole bzw. Phenole sind bekannt und können in Analogie zu bekannten Verfahren hergestellt werden.The corresponding carboxylic acids and alcohols or phenols are known and can be produced in analogy to known processes.

Als reaktionsfähige Derivate der genannten Carbonsäuren eignen sich insbesondere die Säurehalogenide, vor allem die Chloride und Bromide, ferner die Anhydride, z. B. auch gemischte Anhydride, Azide oder Ester, insbesondere Alkylester mit 1-4 C-Atomen in der Alkylgruppe.Suitable reactive derivatives of the carboxylic acids mentioned are especially the acid halides, especially the chlorides and bromides the anhydrides, e.g. B. also mixed anhydrides, azides or esters, in particular Alkyl esters with 1-4 C atoms in the alkyl group.

Als reaktionsfähige Derivate der genannten Alkohole bzw. Phenole kommen insbesondere die entsprechenden Metallalkoholate bzw. Phenolate, vorzugsweise eines Alkalimetalls, wie Natrium oder Kalium, in Betracht.Coming as reactive derivatives of the alcohols or phenols mentioned in particular the corresponding metal alcoholates or phenolates, preferably an alkali metal such as sodium or potassium.

Die Veresterung wird vorteilhaft in Gegenwart eines inerten Lösungsmittels durchgeführt. Gut geeignet sind insbesondere Ether, wie Diethylether, Di-n-butylether, THF, Dioxan oder Anisol, Ketone, wie Aceton, Butanon oder Cyclohexanon, Amide, wie DMF oder Phosphorsäurehexamethyltriamid, Kohlenwasserstoffe, wie Benzol, Toluol oder Xylol, Halogenkohlenwasserstoffe, wie Tetrachlorkohlenstoff, Dichlormethan oder Tetrachlorethylen und Sulfoxide, wie Dimethylsulfoxid oder Sulfolan.The esterification is advantageous in the presence of an inert solvent carried out. Particularly suitable are ethers, such as diethyl ether, Di-n-butyl ether, THF, dioxane or anisole, ketones such as acetone, butanone or Cyclohexanone, amides, such as DMF or phosphoric acid hexamethyltriamide, Hydrocarbons, such as benzene, toluene or xylene, halogenated hydrocarbons,  such as carbon tetrachloride, dichloromethane or tetrachlorethylene and sulfoxides, such as dimethyl sulfoxide or sulfolane.

Ether der Formel (I) sind durch Veretherung entsprechender Hydroxyverbindungen, vorzugsweise entsprechender Phenole, erhältlich, wobei die Hydroxyverbindung zweckmäßig zunächst in ein entsprechendes Metallderivat, z. B. durch Behandeln mit NaH, NaNH₂, NaOH, KOH, Na₂CO₃ oder K₂CO₃ in das entsprechende Alkalimetallalkoholat oder Alkalimetallphenolat übergeführt wird. Dieses kann dann mit dem entsprechenden Alkylhalogenid, Sulfonat oder Dialkylsulfat umgesetzt werden, zweckmäßig in einem inerten Lösungsmittel, wie Aceton, 1,2-Dimethoxyethan, DMF oder Dimethylsulfoxid, oder auch mit einem Überschuß an wäßriger oder wäßrig-alkoholischer NaOH oder KOH bei Temperaturen zwischen etwa 200 und 100°C.Ethers of the formula (I) are more appropriate by etherification Hydroxy compounds, preferably corresponding phenols, are available, where the hydroxy compound expediently first in a corresponding Metal derivative, e.g. B. by treatment with NaH, NaNH₂, NaOH, KOH, Na₂CO₃ or K₂CO₃ in the corresponding alkali metal alcoholate or alkali metal phenolate is transferred. This can then be combined with the corresponding alkyl halide, Sulfonate or dialkyl sulfate are implemented, advantageously in an inert Solvents such as acetone, 1,2-dimethoxyethane, DMF or dimethyl sulfoxide, or with an excess of aqueous or aqueous-alcoholic NaOH or KOH at temperatures between about 200 and 100 ° C.

Was die Synthese spezieller Reste R¹ angeht, sei zusätzlich beispielsweise verwiesen auf EP-A 0 355 008 für Verbindungen mit siliziumhaltigen Seitenketten und EP-A 0 292 954 und EP-A 0 398 1 55 für Verbindungen mit Cyclopropylgruppen in der Seitenkette.As far as the synthesis of special R¹ radicals is concerned, for example refer to EP-A 0 355 008 for connections with silicon-containing Side chains and EP-A 0 292 954 and EP-A 0 398 1 55 for connections with Cyclopropyl groups in the side chain.

Mit der Bereitstellung von Verbindungen der Formel (I) wird ganz allgemein die Palette der flüssigkristallinen Substanzen, die sich unter verschiedenen anwendungstechnischen Gesichtspunkten zur Herstellung flüssigkristalliner Gemische eignen, erheblich verbreitert.With the provision of compounds of formula (I), the Range of liquid crystalline substances, which are among different technical aspects for the production of liquid crystalline Mixtures are suitable, considerably widened.

In diesem Zusammenhang besitzen die Verbindungen der Formel (I) einen breiten Anwendungsbereich. In Abhängigkeit von der Auswahl der Substituenten können sie als Basismaterialien dienen, aus denen flüssigkristalline Phasen zum überwiegenden Teil zusammengesetzt sind; es können aber auch Verbindungen der Formel (I) flüssigkristallinen Basismaterialien aus anderen Verbindungsklassen zugesetzt werden, um beispielsweise die dielektrische und/oder optische Anisotropie eines solchen Dielektrikums zu beeinflussen und/oder um dessen Schwellenspannung und/oder dessen Viskosität zu optimieren.In this connection, the compounds of formula (I) have a wide range Scope of application. Depending on the choice of substituents they can serve as base materials from which liquid crystalline phases for the majority are composed; but connections can also be made of the formula (I) liquid-crystalline base materials from others Classes of compound are added, for example the dielectric and / or to influence the optical anisotropy of such a dielectric  and / or by its threshold voltage and / or its viscosity optimize.

Gegenstand der Erfindung ist auch die Verwendung von Verbindungen der Formel (I) in Flüssigkristallmischungen, vorzugsweise ferroelektrischen und nematischen, insbesondere ferroelektrischen.The invention also relates to the use of compounds of Formula (I) in liquid crystal mixtures, preferably ferroelectric and nematic, especially ferroelectric.

Weiterhin Gegenstand der Erfindung sind Flüssigkristallmischungen, vorzugsweise ferroelektrische und nematische, insbesondere ferroelektrische, enthaltend eine oder mehrere Verbindungen der Formel (I).The invention furthermore relates to liquid crystal mixtures, preferably ferroelectric and nematic, especially ferroelectric, containing one or more compounds of formula (I).

Die erfindungsgemäßen Flüssigkristallmischungen enthalten im allgemeinen 2 bis 35, vorzugsweise 2 bis 25, besonders bevorzugt 2 bis 20 Komponenten.The liquid crystal mixtures according to the invention generally contain 2 to 35, preferably 2 to 25, particularly preferably 2 to 20 components.

Sie enthalten im allgemeinen 0,01 bis 80 Gew.-%, vorzugsweise 0,1 bis 60 Gew.-%, besonders bevorzugt 0,1 bis 30 Gew.-%, an einer oder mehreren, vorzugsweise 1 bis 10, besonders bevorzugt 1 bis 5, ganz besonders bevorzugt 1 bis 3, der erfindungsgemäßen Verbindungen der Formel (I).They generally contain 0.01 to 80% by weight, preferably 0.1 to 60% by weight, particularly preferably 0.1 to 30% by weight, of one or more, preferably 1 to 10, particularly preferably 1 to 5, very particularly preferably 1 to 3, the compounds of formula (I) according to the invention.

Weitere Komponenten von Flüssigkristallmischungen, die erfindungsgemäße Verbindungen der Formel (I) enthalten, werden vorzugsweise ausgewählt aus den bekannten Verbindungen mit smektischen und/oder nematischen und/oder cholesterischen Phasen. Dazu gehören z. B.:Other components of liquid crystal mixtures, the invention Compounds of formula (I) are preferably selected from the known compounds with smectic and / or nematic and / or cholesteric phases. These include e.g. B .:

  • - Derivate des Phenylpyrimidins, wie beispielsweise in WO 86/06401, US-A 4 874 542 beschrieben,Derivatives of phenylpyrimidine, as for example in WO 86/06401, US-A 4 874 542,
  • - metasubstituierte Sechsringaromaten, wie beispielsweise in EP-A 0 578 054 beschrieben,- Meta-substituted six-ring aromatics, such as in EP-A 0 578 054,
  • - Siliziumverbindungen, wie beispielsweise in EP-A 0 355 008 beschrieben,Silicon compounds, as described for example in EP-A 0 355 008,
  • - mesogene Verbindungen mit nur einer Seitenkette, wie beispielsweise in EP-A 0 541 081 beschrieben,- Mesogenic compounds with only one side chain, such as in EP-A 0 541 081,
  • - Hydrochinonderivate, wie beispielsweise in EP-A 0 603 786 beschrieben, Hydroquinone derivatives, as described for example in EP-A 0 603 786,  
  • - Pyridylpyrimidine, wie beispielsweise in WO 92/12974 beschrieben,Pyridylpyrimidines, as described for example in WO 92/12974,
  • - Phenylbenzoate, wie beispielsweise bei P. Keller, Ferroelectrics 58 (1984), 3 und J. W. Goodby et al., Liquid Crystals and Ordered Fluids, Bd. 4, New York 1984 beschrieben und- Phenylbenzoates, such as from P. Keller, Ferroelectrics 58 (1984), 3 and J.W. Goodby et al., Liquid Crystals and Ordered Fluids, 4, New York 1984 and
  • - Thiadiazole, wie beispielsweise in EP-A 0 309 514 beschrieben.Thiadiazoles, as described, for example, in EP-A 0 309 514.

Als chirale, nicht racemische Dotierstoffe kommen beispielsweise in Frage:Examples of chiral, non-racemic dopants are:

  • - optisch aktive Phenylbenzoate, wie beispielsweise bei P. Keller, Ferroelectrics 58 (1984), 3 und J. W. Goodby et al., Liquid Crystals and Ordered Fluids, Bd. 4, New York 1984 beschrieben,optically active phenylbenzoates, such as, for example, P. Keller, Ferroelectrics 58 (1984), 3 and J.W. Goodby et al., Liquid Crystals and Ordered Fluids, Vol. 4, New York 1984,
  • - optisch aktive Oxiranether, wie beispielsweise in EP-A 0 263 437 und WO-A 93/13093 beschrieben,- Optically active oxirane ethers, such as in EP-A 0 263 437 and WO-A 93/13093,
  • - optisch aktive Oxiranester, wie beispielsweise in EP-A 0 292 954 beschrieben,- Optically active oxirane esters, as for example in EP-A 0 292 954 described
  • - optisch aktive Dioxolanether, wie beispielsweise in EP-A 0 351 746 beschrieben,optically active dioxolane ethers, such as, for example, in EP-A 0 351 746 described
  • - optisch aktive Dioxolanester, wie beispielsweise in EP-A 0 361 272 beschrieben,- Optically active dioxolane esters, such as, for example, in EP-A 0 361 272 described
  • - optisch aktive Tetrahydrofuran-2-carbonsäureester, wie beispielsweise in EP-A 0 355 561 beschrieben, und- Optically active tetrahydrofuran-2-carboxylic acid esters, such as in EP-A 0 355 561 and
  • - optisch aktive 2-Fluoralkylether, wie beispielsweise in EP-A 0 237 007 und US-A 5,051,506 beschrieben.- Optically active 2-fluoroalkyl ethers, such as, for example, in EP-A 0 237 007 and US-A 5,051,506.

Die Mischungen wiederum können Anwendung finden in elektrooptischen oder vollständig optischen Elementen, z. B. Anzeigeelementen, Schaltelementen, Lichtmodulatoren, Elementen zur Bildbearbeitung und/oder Signalverarbeitung oder allgemein im Bereich der nichtlinearen Optik.The mixtures in turn can be used in electro-optical or completely optical elements, e.g. B. display elements, switching elements, Light modulators, elements for image processing and / or signal processing or generally in the field of nonlinear optics.

Flüssigkristalline Mischungen, die Verbindungen der allgemeinen Formel (I) enthalten, sind besonders für die Verwendung in elektrooptischen Schalt- und Anzeigevorrichtungen (Displays) geeignet. Diese Displays sind üblicherweise so aufgebaut, daß eine Flüssigkristallschicht beiderseitig von Schichten eingeschlossen ist, die üblicherweise, in dieser Reihenfolge ausgehend von der LC-Schicht, mindestens eine Orientierungsschicht, Elektroden und eine Begrenzungsscheibe (z. B. aus Glas) sind. Darüber hinaus enthalten sie Abstandshalter, Kleberahmen, Polarisatoren sowie für Farbdisplays dünne Farbfilterschichten. Weitere mögliche Komponenten sind Antireflex-, Passivierungs-, Ausgleichs- und Sperrschichten sowie elektrisch-nichtlineare Elemente, wie Dünnschichttransistoren (TFT) und Metall-Isolator-Metall-(MIM)-Elemente. Im Detail ist der Aufbau von Flüssigkristalldisplays bereits in einschlägigen Monographien beschrieben (siehe z. B. E. Kaneko, "Liquid Crystal TV Displays: Principles and Applications of Liquid Crystal Displays", KTK Scientific Publishers 1987).Liquid-crystalline mixtures, the compounds of the general formula (I) included, are especially for use in electro-optical switching and Suitable display devices. These displays are usually like this  built that a liquid crystal layer on both sides of layers is included, which is usually in that order starting from the LC layer, at least one orientation layer, electrodes and one Boundary disk (e.g. made of glass). They also contain Spacers, adhesive frames, polarizers and thin ones for color displays Color filter layers. Other possible components are anti-reflective, Passivation, compensation and barrier layers as well as non-linear electrical Elements such as thin film transistors (TFT) and metal insulator metal (MIM) elements. The structure of liquid crystal displays is already in detail relevant monographs (see, for example, E. Kaneko, "Liquid Crystal TV Displays: Principles and Applications of Liquid Crystal Displays ", KTK Scientific Publishers 1987).

Ferner sind die Mischungen für Feldbehandlung, d. h. zum Betrieb in der Quasi-Bookshelf-Geometrie (QBG) (siehe z. B. H. Rieger et al., SID 91 Digest (Anaheim) 1991, 396) geeignet.Furthermore, the mixtures for field treatment, i.e. H. for operation in the Quasi-Bookshelf Geometry (QBG) (see e.g. H. Rieger et al., SID 91 Digest (Anaheim) 1991, 396).

Ebenso sind die erfindungsgemäßen Mischungen geeignet für die Verwendung in ferroelektrischen Flüssigkristallanzeigen, die auf Nutzung des DHF-Effekts oder des PSFLCD-Effekts (Pitch Stabilized Ferroelectric Liquid Crystal Display, auch SBF = Short Pitch Bistable Ferroelectric Effect genannt) beruhen.The mixtures according to the invention are also suitable for use in ferroelectric liquid crystal displays based on the use of the DHF effect or the PSFLCD effect (Pitch Stabilized Ferroelectric Liquid Crystal Display, too SBF = Short Pitch Bistable Ferroelectric Effect).

Daneben können die Verbindungen der Formel (I) auch als Komponenten von antiferroelektrischen Flüssigkristallmischungen Verwendung finden.In addition, the compounds of formula (I) can also be used as components of antiferroelectric liquid crystal mixtures are used.

Die Erfindung wird durch die Beispiele näher erläutert, ohne sie darauf beschränken zu wollen. The invention is explained in more detail by the examples, without referring to them want to restrict.  

Beispiel 1example 1 6-(4-Octyloxy-phenyl)-3,4,5,-trifluor-2-octyl-naphthalin6- (4-octyloxy-phenyl) -3,4,5, -trifluoro-2-octyl-naphthalene

10 mmol 3,4,5-Trifluor-6-(4-hydroxy-phenyl)-2-octyl-5,6,7,8-tetrahydro­ naphthalin werden in 50 ml DMF gelöst und mit 11 mmol Natriumhydrid versetzt. Nach 30 Minuten rühren tropft man 11 mmol 1-Octylbromid zu, rührt noch 140 Minuten bei 60°C und gießt in Wasser. Das Gemisch wird mit Dichlormethan extrahiert, die vereinigten organischen Phasen werden getrocknet, das Solvens im Vakuum entfernt und der Rückstand an Kieselgel chromatographiert. Man erhält 8 mmol 6-(4-Octyloxy-phenyl)-3,4,5-trifluor-2- octyl-naphthalin.10 mmol of 3,4,5-trifluoro-6- (4-hydroxyphenyl) -2-octyl-5,6,7,8-tetrahydro naphthalene are dissolved in 50 ml DMF and with 11 mmol sodium hydride transferred. After stirring for 30 minutes, 11 mmol of 1-octylbromide are added dropwise and the mixture is stirred 140 minutes at 60 ° C and poured into water. The mixture is with Extracted dichloromethane, the combined organic phases dried, the solvent removed in vacuo and the residue on silica gel chromatographed. 8 mmol of 6- (4-octyloxyphenyl) -3,4,5-trifluoro-2- are obtained octyl naphthalene.

Analog Beispiel 1 lassen sich weitere Halogenide mit 3,4,5-Trifluor-6-(4- hydroxy-phenyl)-2-octyl-naphthalin umsetzen.Analogously to Example 1, other halides with 3,4,5-trifluoro-6- (4- implement hydroxy-phenyl) -2-octyl-naphthalene.

Beispiel 2Example 2 6-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-2-octyl-naphthalin6- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-2-octylnaphthalene

10 mmol 3,4,5-Trifluor-6-(5-hydroxy-pyrimidin-2-yl)-2-octyl-naphthalin werden in 50 ml DMF gelöst und mit 11 mmol Natriumhydrid versetzt. Nach 30 Minuten rühren tropft man 11 mmol 1-Hexylbromid zu, rührt noch 140 Minuten bei 60°C und gießt in Wasser. Das Gemisch wird mit Dichlormethan extrahiert, die vereinigten organischen Phasen werden getrocknet, das Solvens im Vakuum entfernt und der Rückstand an Kieselgel chromatographiert. Man erhält 7,55 mmol 6-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-2-octyl-naphthalin.10 mmol of 3,4,5-trifluoro-6- (5-hydroxy-pyrimidin-2-yl) -2-octyl-naphthalene dissolved in 50 ml DMF and mixed with 11 mmol sodium hydride. After 30 minutes 11 mmol of 1-hexylbromide are added dropwise, stirring is continued for 140 minutes 60 ° C and pour in water. The mixture is extracted with dichloromethane combined organic phases are dried, the solvent in vacuo removed and the residue chromatographed on silica gel. You get 7.55 mmol of 6- (5-hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-2-octylnaphthalene.

Analog Beispiel 2 lassen sich weitere Halogenide mit 3,4,5-Trifluor-6-(5- hydroxy-pyrimidin-2-yl)-2-octyl-naphthalin umsetzen. Analogously to Example 2, other halides with 3,4,5-trifluoro-6- (5- implement hydroxy-pyrimidin-2-yl) -2-octyl-naphthalene.  

Beispiel 3Example 3 6-Octyloxy-3,4,5-trifluor-2-(6-hexyl-pyridin-3-yl)-naphthalin6-octyloxy-3,4,5-trifluoro-2- (6-hexyl-pyridin-3-yl) naphthalene

10 mmol 3,4,5-Trifluor-2-(6-hexyl-pyridin-3-yl)-6-hydroxy-naphthalin werden in 50 ml DMF gelöst und mit 11 mmol Natriumhydrid versetzt. Nach 30 Minuten rühren tropft man 11 mmol 1-Octylbromid zu, rührt noch 140 Minuten bei 60°C und gießt in Wasser. Das Gemisch wird mit Dichlormethan extrahiert, die vereinigten organischen Phasen werden getrocknet, das Solvens im Vakuum entfernt und der Rückstand an Kieselgel chromatographiert. Man erhält 9 mmol 6-Octyloxy-3,4,5-trifluor-2-(6-hexyl-pyridin-3-yl)-naphthalin.10 mmol 3,4,5-trifluoro-2- (6-hexyl-pyridin-3-yl) -6-hydroxy-naphthalene are in 50 ml of DMF dissolved and mixed with 11 mmol of sodium hydride. After 30 minutes stirring is added dropwise 11 mmol of 1-octyl bromide, stirring is continued for 140 minutes at 60 ° C. and pour in water. The mixture is extracted with dichloromethane combined organic phases are dried, the solvent in vacuo removed and the residue chromatographed on silica gel. 9 mmol are obtained 6-octyloxy-3,4,5-trifluoro-2- (6-hexyl-pyridin-3-yl) naphthalene.

Analog Beispiel 3 lassen sich weitere Halogenide mit 3,4,5-Trifluor-2-(6-hexyl­ pyridin-3-yl)-6-hydroxy-naphthalin umsetzen.Analogously to Example 3, other halides with 3,4,5-trifluoro-2- (6-hexyl Implement pyridin-3-yl) -6-hydroxy-naphthalene.

Beispiel 4Example 4

3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4-octyloxy-phenyl) -2-nonyl-naphthalene

Beispiel 5Example 5

3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2-nonylnaphthalene

Beispiel 6Example 6

3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2-nonylnaphthalene

Beispiel 7Example 7

3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2-nonyl-naphthalene

Beispiel 8Example 8

3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluoro-phenyl) -2-nonyl-naphthalene

Beispiel 9Example 9

3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-nonyl-naphthalin 3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2-nonyl-naphthalene  

Beispiel 10Example 10

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2-nonylnaphthalene

Beispiel 11Example 11

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-nonyl-naphthalin-3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2-nonyl-naphthalene

Beispiel 12Example 12

3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2-nonylnaphthalene

Beispiel 13Example 13

3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2-nonylnaphthalene

Beispiel 14Example 14

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2-nonyl-naphthalene

Beispiel 15Example 15

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2-nonyl-naphthalene

Beispiel 16Example 16

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-nonyl-na-phthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2-nonyl-naphthalene

Beispiel 17Example 17

3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2-no-nyl-naphthalene

Beispiel 18Example 18

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2-no-nyl-naphthalene

Beispiel 19Example 19

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2-nonylnaphthalene

Beispiel 20Example 20

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2-nonyl-naphthalene

Beispiel 21Example 21

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-nonyl-na-phthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2-nonyl-naphthalene

Beispiel 22Example 22

3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2-no-nyl-naphthalene

Beispiel 23Example 23

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-no-nyl-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2-no-nyl-naphthalene

Beispiel 24Example 24

3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2-nonyl-naphthalene

Beispiel 25Example 25

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2-nonylnaphthalene

Beispiel 26Example 26

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-nonyl-naphth-alin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2-nonyl-naphth-aline

Beispiel 27Example 27

3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2-nonyl-naphthalene

Beispiel 28Example 28

3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluoro-phenyl) -2-nonyl-naphthalene

Beispiel 29Example 29

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2-nonyl-naphthalene

Beispiel 30Example 30

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-nonyl-naphtha-lin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2-nonyl-naphtha-lin

Beispiel 31Example 31

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-nonyl-naphthali-n3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2-nonyl-naphthali-n

Beispiel 32Example 32

3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2-nonyl-napthalene

Beispiel 33Example 33

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2-nonyl-napthalene

Beispiel 34Example 34

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2-nonyl-naphthalene

Beispiel 35Example 35

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-nonyl-naphthal-in3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2-nonyl-naphthalene

Beispiel 36Example 36

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-nonyl-naphthalin-3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2-nonyl-naphthalene

Beispiel 37Example 37

3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2-nonyl-naphthalene

Beispiel 38Example 38

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2-nonyl-naphthalene

Beispiel 39Example 39

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-nonyl-naphth-alin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2-nonyl-naphth-aline

Beispiel 40Example 40

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-nony-l-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2-nony-l-naphthalene

Beispiel 41Example 41

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2-nonyl-naphthalene

Beispiel 42Example 42

3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--nonyl- naphthalin 3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - nonyl- naphthalene  

Beispiel 43Example 43

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--nonyl- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - nonyl- naphthalene

Beispiel 44Example 44

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2-nonyl-naphthalene

Beispiel 45Example 45

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2-nonylnaphthalene

Beispiel 46Example 46

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-nonyl-napht-halin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2-nonylnaphthalene

Beispiel 47Example 47

3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2-nonyl-naphthalene

Beispiel 48Example 48

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-nonyl--naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2-nonyl-naphthalene

Beispiel 49Example 49

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-nonyl-naph-thalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2-nonylnaphthalene

Beispiel 50Example 50

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-no-nyl- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2-no-nyl- naphthalene

Beispiel 51Example 51

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-nony-l-naphthalin 3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2-nony-l-naphthalene  

Beispiel 52Example 52

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-nonyl- naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) -2-nonyl- naphthalene

Beispiel 53Example 53

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-nonyl- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -2-nonyl- naphthalene

Beispiel 54Example 54

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-nonyl-naphthali-n3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2-nonyl-naphthali-n

Beispiel 55Example 55

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-nonyl-n-aphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2-nonyl-n-aphthaline

Beispiel 56Example 56

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-nonyl-nap-hthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2-nonyl-napthalene

Beispiel 57Example 57

3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-non-yl-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2-non-yl-naphthalene

Beispiel 58Example 58

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-non-yl-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2-non-yl-naphthalene

Beispiel 59Example 59

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-nonyl-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2-nonyl-naphthalene

Beispiel 60Example 60

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-nonyl-napht-halin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2-nonyl-napht-haline

Beispiel 61Example 61

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-nonyl-naphtha-lin 3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2-nonyl-naphtha-lin  

Beispiel 62Example 62

3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-nonyl-n-aphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2-nonyl-n-aphthaline

Beispiel 63Example 63

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-nonyl-n-aphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2-nonyl-n-aphthaline

Beispiel 64Example 64

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-non-yl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2-non-yl-naphthalene

Beispiel 65Example 65

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-nonyl- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyrimidin-2-y-l) -2-nonyl- naphthalene

Beispiel 66Example 66

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-nonyl- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) -2-nonyl- naphthalene

Beispiel 67Example 67

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- nonyl-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- nonyl naphthalene

Beispiel 68Example 68

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- nonyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- nonyl naphthalene

Beispiel 69Example 69

3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[9,9-dimethylsila]tetradecyl--naphthalin3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [9,9-dimethylsila] tetradecylnaphthalene

Beispiel 70Example 70

3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[9,9-dimethylsila]tet-radecyl- naphthalin 3,4,5-trifluoro-6- (5-octyloxy-pyrimidin-2-yl) -2- [9,9-dimethylsila] tet-radecyl- naphthalene  

Beispiel 71Example 71

3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[9,9-dimethylsila]tetra-decyl- naphthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2- [9,9-dimethylsila] tetra-decyl- naphthalene

Beispiel 72Example 72

3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[9,9-dimethylsila-]tetradecyl- naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [9,9-dimethylsila-] tetradecyl- naphthalene

Beispiel 73Example 73

3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[9,9-dimethylsila-]tetradecyl- naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluorophenyl) -2- [9,9-dimethylsila-] tetradecyl- naphthalene

Beispiel 74Example 74

3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[9,9-dimethylsila]tetr-adecyl- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [9,9-dimethylsila] tetr-adecyl- naphthalene

Beispiel 75Example 75

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[9,9-dimethyls-ila]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [9,9-dimethyls-ila] tetradecyl- naphthalene

Beispiel 76Example 76

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[9,9-dimethylsil-a]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [9,9-dimethylsil-a] tetradecyl- naphthalene

Beispiel 77Example 77

3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[9,9-dimet-hylsila]tetra­ decyl-naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [9,9-dimethylsilyl] tetra decyl naphthalene

Beispiel 78Example 78

3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[9,9-dimet-hylsila]tetra­ decyl-naphthalin 3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [9,9-dimethylsilyl] tetra decyl naphthalene  

Beispiel 79Example 79

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[9,9-dimethyls-ila]tetra­ decyl-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [9,9-dimethyls-ila] tetra decyl naphthalene

Beispiel 80Example 80

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[9,9-d-imethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene

Beispiel 81Example 81

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[9,9-dim-ethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 82Example 82

3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[9-,9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [9-, 9-dimethyl sila] tetradecyl-naphthalene

Beispiel 83Example 83

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[9-,9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [9-, 9-dimethyl sila] tetradecyl naphthalene

Beispiel 84Example 84

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[9,9-dimethyls-ila]tetra­ decyl-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [9,9-dimethylsila] tetra decyl naphthalene

Beispiel 85Example 85

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[9,9-d-imethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene

Beispiel 86Example 86

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[9,9-dim-ethylsila]­ tetradecyl-naphthalin 3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonylpyridin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene  

Beispiel 87Example 87

3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[9-,9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [9-, 9-dimethyl sila] tetradecyl-naphthalene

Beispiel 88Example 88

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[9-,9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [9-, 9-dimethyl sila] tetradecyl-naphthalene

Beispiel 89Example 89

3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[9,9-dimethylsila]-tetradecyl- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [9,9-dimethylsila] tetradecyl- naphthalene

Beispiel 90Example 90

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[9,9-dimet-hylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 91Example 91

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[9,9-dimethy-lsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [9,9-dimethy-isila] tetradecyl naphthalene

Beispiel 92Example 92

3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[9,9-d-imethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene

Beispiel 93Example 93

3,4,5-Trifluor-6-(4-[1 -hexansäureester]-2,3-difluor-phenyl)-2-[9,9-dimethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 94Example 94

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[9,9-dimethylsila]tet-radecyl- naphthalin 3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [9,9-dimethylsila] tet-radecyl- naphthalene  

Beispiel 95Example 95

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[9,9-dimethyl-sila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [9,9-dimethyl-sila] tetradecyl naphthalene

Beispiel 96Example 96

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[9,9-dimethylsi-la]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [9,9-dimethylsi-la] tetradecyl naphthalene

Beispiel 97Example 97

3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[9,9-dime-thylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 98Example 98

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[9,9-dime-thylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 99Example 99

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[9,9-dimethylsila]tetr-adecyl- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [9,9-dimethylsila] tetr-adecyl- naphthalene

Beispiel 100Example 100

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[9,9-dimethyls-ila]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [9,9-dimethyls-ila] tetradecyl- naphthalene

Beispiel 101Example 101

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[9,9-dimethylsil-a]tetradecyl- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [9,9-dimethylsil-a] tetradecyl- naphthalene

Beispiel 102Example 102

3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[9,9-dimet-hylsila]­ tetradecyl-naphthalin 3,4,5-trifluoro-6- (3- [6-oxa-undecyl] -fluoropyridin-6-yl) -2- [9,9-dimet-hylsila] tetradecyl naphthalene  

Beispiel 103Example 103

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[9,9-dimet-hylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 104Example 104

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[9,9-d-methy-lsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [9,9-d-methyl-isila] tetradecyl naphthalene

Beispiel 105Example 105

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[9,9--dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [9,9-dimethyl sila] tetradecyl naphthalene

Beispiel 106Example 106

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[9,9-d-imethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [9,9-d-imethylsila] tetradecyl naphthalene

Beispiel 107Example 107

3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)2-[-9,9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) 2 - [- 9,9-dimethyl sila] tetradecyl naphthalene

Beispiel 108Example 108

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [9.9- dimethylsila] tetradecyl naphthalene

Beispiel 109Example 109

3,4,5-Trifluor-6-(4-[9-cycyclopropylnonyl]-phenyl)-2-[9,9-dimethylsi-la]tetradecyl- naphthalin3,4,5-trifluoro-6- (4- [9-cycyclopropylnonyl] phenyl) -2- [9,9-dimethylsi-la] tetradecyl- naphthalene

Beispiel 110Example 110

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[9,9-dime-thylsila]­ tetradecyl-naphthalin 3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene  

Beispiel 111Example 111

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[9,9-dimeth-ylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [9,9-dimeth-ylsila] tetradecyl naphthalene

Beispiel 112Example 112

3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[9,9--dimethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [9.9 - dimethylsila] tetradecyl naphthalene

Beispiel 113Example 113

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[9,9--dimethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [9.9 - dimethylsila] tetradecyl naphthalene

Beispiel 114Example 114

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[9,9-dimet-hylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [9,9-dimet-hylsila] tetradecyl naphthalene

Beispiel 115Example 115

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[9-,9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [9-, 9-dimethyl sila] tetradecyl naphthalene

Beispiel 116Example 116

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[9,9--dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [9,9-dimethyl sila] tetradecyl naphthalene

Beispiel 117Example 117

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [9.9- dimethylsila] tetradecyl naphthalene

Beispiel 118Example 118

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[9,9- dimethylsila]tetradecyl-naphthalin 3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [9.9- dimethylsila] tetradecyl naphthalene  

Beispiel 119Example 119

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[9,9-dimethylsi-la]tetradecyl- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [9,9-dimethylsi-la] tetradecyl- naphthalene

Beispiel 120Example 120

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[9,9-di-methylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 121Example 121

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[9,9-dime-thylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 122Example 122

3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[9,-9-dimethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [9, -9-dimethylsila] tetradecyl naphthalene

Beispiel 123Example 123

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[9,-9-dimethylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [9, -9-dimethylsila] tetradecyl naphthalene

Beispiel 124Example 124

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[9,9-dimethylsila]t-etradecyl- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [9,9-dimethylsila] t-etradecyl- naphthalene

Beispiel 125Example 125

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[9,9-dimeth-ylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [9,9-dimeth-ylsila] tetradecyl naphthalene

Beispiel 126Example 126

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[9,9-dimethyl-sila]tetradecyl- naphthalin 3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [9,9-dimethyl-sila] tetradecyl- naphthalene  

Beispiel 127Example 127

3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[9,9-di-methylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 128Example 128

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[9,9-di-methylsila]­ tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 129Example 129

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[9,-9-dimethyl­ sila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [9, -9-dimethyl sila] tetradecyl naphthalene

Beispiel 130Example 130

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyrimidin-2-y-l) -2- [9,9- dimethylsila] tetradecyl naphthalene

Beispiel 131Example 131

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[9,9- dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [9,9- dimethylsila] tetradecyl naphthalene

Beispiel 132Example 132

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [9,9-dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 133Example 133

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [9,9-dimethylsila]tetradecyl-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [9,9-dimethylsila] tetradecyl naphthalene

Beispiel 134Example 134

3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[9-cyclopropylnonyl]-naphthal-in 3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [9-cyclopropylnonyl] naphthalene  

Beispiel 135Example 135

3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[9-cyclopropylnonyl]--naphthalin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2- [9-cyclopropylnonyl] naphthalene

Beispiel 136Example 136

3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[9-cycopropylnonyl]-nap-hthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2- [9-cycopropylnonyl] naphtaline

Beispiel 137Example 137

3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[9-cyclopropylnon-yl]-naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [9-cyclopropylnon-yl] naphthalene

Beispiel 138Example 138

3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[9-cyclopropylnon-yl]-naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluorophenyl) -2- [9-cyclopropylnon-yl] naphthalene

Beispiel 139Example 139

3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[9-cyclopropylnonyl]-n-aphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [9-cyclopropylnonyl] -n-aphthaline

Beispiel 140Example 140

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [9-cyclopropyl-nonyl] - naphthalene

Beispiel 141Example 141

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[9-cyclopropylno-nyl]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 142Example 142

3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 143Example 143

3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[9-cyclopr-opylnonyl]- naphthalin 3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [9-cyclopropylnonyl] - naphthalene  

Beispiel 144Example 144

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [9-cyclopropyl-nonyl] - naphthalene

Beispiel 145Example 145

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[9-cyc-lopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [9-cyc-lopropyl nonyl] naphthalene

Beispiel 146Example 146

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[9-cyclo-propylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [9-cyclo-propylnonyl] - naphthalene

Beispiel 147Example 147

3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 148Example 148

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 149Example 149

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [9-cyclopropyl nonyl] - naphthalene

Beispiel 150Example 150

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[9-cyc-lopropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [9-cyc-lopropylnonyl] - naphthalene

Beispiel 151Example 151

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[9-cyclo-propylnonyl]- naphthalin 3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [9-cyclo-propylnonyl] - naphthalene  

Beispiel 152Example 152

3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 153Example 153

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 154Example 154

3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[9-cyclopropylnony-l]- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [9-cyclopropylnony-l] - naphthalene

Beispiel 155Example 155

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [9-cyclopr-opylnonyl] - naphthalene

Beispiel 156Example 156

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[9-cycloprop-ylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [9-cycloprop-ylnonyl] - naphthalene

Beispiel 157Example 157

3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[9-cyc-lopropylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [9-cyc-lopropylnonyl] - naphthalene

Beispiel 158Example 158

3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-[9-cyc-lopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [9-cyc-lopropyl nonyl] naphthalene

Beispiel 159Example 159

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[9-cyclopropylnonyl]--naphthalin 3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [9-cyclopropylnonyl] naphthalene  

Beispiel 160Example 160

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[9-cyclopropy-lnonyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [9-cyclopropy-nonyl] - naphthalene

Beispiel 161Example 161

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[9-cyclopropyln-onyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [9-cyclopropyln-onyl] - naphthalene

Beispiel 162Example 162

3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 163Example 163

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 164Example 164

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[9-cyclopropylnonyl]-n-aphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [9-cyclopropylnonyl] -n-aphthaline

Beispiel 165Example 165

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[9-cyclopropyl-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [9-cyclopropyl-nonyl] - naphthalene

Beispiel 166Example 166

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[9-cyclopropylno-nyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 167Example 167

3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [9-cyclopr-opylnonyl] - naphthalene

Beispiel 168Example 168

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [9-cyclopr-opylnonyl] -  naphthalene

Beispiel 169Example 169

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[9-cycloprop-ylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [9-cycloprop-ylnonyl] - naphthalene

Beispiel 170Example 170

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[9-c-yclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [9-c-yclopropyl nonyl] naphthalene

Beispiel 171Example 171

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[9-cyc-lopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [9-cyc-lopropyl nonyl] naphthalene

Beispiel 172Example 172

3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[9-cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [9-cyclopropyl nonyl] naphthalene

Beispiel 173Example 173

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[9-cyclo­ propylnonyl]-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [9-cyclo propylnonyl] naphthalene

Beispiel 174Example 174

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[9-cyclopropylnon-yl]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [9-cyclopropylnon-yl] - naphthalene

Beispiel 175Example 175

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 176Example 176

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[9-cyclopro-pylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [9-cyclopropylnonyl] -  naphthalene

Beispiel 177Example 177

3,4,5-Trifluor-6-(3-l[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[9-c-yclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (3-l [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [9-c-yclopropyl nonyl] naphthalene

Beispiel 178Example 178

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[9-cy-clopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [9-cy-clopropyl nonyl] naphthalene

Beispiel 179Example 179

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[9-cyclopr-opylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [9-cyclopr-opylnonyl] - naphthalene

Beispiel 180Example 180

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 181Example 181

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[9-c-yclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [9-c-yclopropyl nonyl] naphthalene

Beispiel 182Example 182

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [9- cyclopropylnonyl] naphthalene

Beispiel 183Example 183

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [9- cyclopropylnonyl] naphthalene

Beispiel 184Example 184

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[9-cyclopropyln-onyl]- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [9-cyclopropyln-onyl] -  naphthalene

Beispiel 185Example 185

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[9-cycl-opropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 186Example 186

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[9-cyclop-ropylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 187Example 187

3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 188Example 188

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 189Example 189

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[9-cyclopropylnonyl-]-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [9-cyclopropylnonyl -] - naphthalene

Beispiel 190Example 190

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[9-cyclopro-pylnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 191Example 191

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[9-cyclopropy-lnonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [9-cyclopropy-nonyl] - naphthalene

Beispiel 192Example 192

3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[9-cycl-opropylnonyl]- naphthalin 3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [9-cyclopropylnonyl] - naphthalene  

Beispiel 193Example 193

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[9-cycl-opropylnonyl]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [9-cyclopropylnonyl] - naphthalene

Beispiel 194Example 194

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[9--cyclopropyl­ nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [9 - cyclopropyl nonyl] naphthalene

Beispiel 195Example 195

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyrimidin-2-y-l) -2- [9- cyclopropylnonyl] naphthalene

Beispiel 196Example 196

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[9- cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [9- cyclopropylnonyl] naphthalene

Beispiel 197Example 197

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [9-cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [9-cyclopropylnonyl] naphthalene

Beispiel 198Example 198

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [9-cyclopropylnonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [9-cyclopropylnonyl] naphthalene

Beispiel 199Example 199

3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[6-oxa-undecyl]-naphthalin3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [6-oxa-undecyl] naphthalene

Beispiel 200Example 200

3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[6-oxa-undecyl]-napht-halin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2- [6-oxa-undecyl] naphtaline

Beispiel 201Example 201

3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[6-oxa-undecyl]-naphtha-lin 3,4,5-trifluoro-6- (5-octyloxy-pyridin-2-yl) -2- [6-oxa-undecyl] naphtha-lin  

Beispiel 202Example 202

3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[6-oxa-undecyl]-n-aphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [6-oxa-undecyl] -n-aphthaline

Beispiel 203Example 203

3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[6-oxa-undecyl]-n-aphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluoro-phenyl) -2- [6-oxa-undecyl] -n-aphthaline

Beispiel 204Example 204

3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[6-oxa-undecyl]-naphth-alin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [6-oxa-undecyl] naphth-aline

Beispiel 205Example 205

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [6-oxa-undecyl -] - naphthalene

Beispiel 206Example 206

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [6-oxa-undecyl] naphthalene

Beispiel 207Example 207

3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [6-oxa-and-ecyl] - naphthalene

Beispiel 208Example 208

3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [6-oxa-and-ecyl] - naphthalene

Beispiel 209Example 209

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [6-oxa-undecyl -] - naphthalene

Beispiel 210Example 210

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 211Example 211

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[-6-oxa--undecyl]- naphthalin 3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2 - [- 6-oxa - undecyl] - naphthalene  

Beispiel 212Example 212

3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [6 - oxa-undecyl] - naphthalene

Beispiel 213Example 213

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [6 - oxa-undecyl] - naphthalene

Beispiel 214Example 214

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [6-oxa-undecyl -] - naphthalene

Beispiel 215Example 215

3,4,5-Trifuor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifuor-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 216Example 216

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[6-oxa-u-ndecyl]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [6-oxa-u-decyl] - naphthalene

Beispiel 217Example 217

3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [6 - oxa-undecyl] - naphthalene

Beispiel 218Example 218

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [6 - oxa-undecyl] - naphthalene

Beispiel 219Example 219

3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[6-oxa-undecyl]-na-phthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [6-oxa-undecyl] -na-phthaline

Beispiel 220Example 220

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[6-oxa-und-ecyl]- naphthalin 3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [6-oxa-and-ecyl] - naphthalene  

Beispiel 221Example 221

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[6-oxa-undec-yl]-naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [6-oxa-undec-yl] naphthalene

Beispiel 222Example 222

3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 223Example 223

3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 224Example 224

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[6-oxa-undecyl]-napht-halin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [6-oxa-undecyl] naphtaline

Beispiel 225Example 225

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[6-oxa-undecy-l]-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [6-oxa-undecy-l] naphthalene

Beispiel 226Example 226

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [6-oxa-undecyl] naphthalene

Beispiel 227Example 227

3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [6-oxa-un-decyl] - naphthalene

Beispiel 228Example 228

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [6-oxa-un-decyl] - naphthalene

Beispiel 229Example 229

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[6-oxa-undecyl]-naphth-alin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [6-oxa-undecyl] naphth-aline

Beispiel 230Example 230

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[6-oxa-undecyl-]-naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [6-oxa-undecyl -] - naphthalene

Beispiel 231Example 231

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [6-oxa-undecyl] naphthalene

Beispiel 232Example 232

3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [6-oxa-and-ecyl] - naphthalene

Beispiel 233Example 233

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [6-oxa-and-ecyl] - naphthalene

Beispiel 234Example 234

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[6-oxa-undec-yl]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [6-oxa-undec-yl] - naphthalene

Beispiel 235Example 235

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[6-o-xa-undecyl]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [6-o-xa-undecyl] - naphthalene

Beispiel 236Example 236

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 237Example 237

3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [6-oxa- undecyl] naphthalene

Beispiel 238Example 238

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[6-oxa- undecyl]-naphthalin 3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [6-oxa- undecyl] naphthalene  

Beispiel 239Example 239

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[6-oxa-undecyl]-n-aphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [6-oxa-undecyl] -n-aphthaline

Beispiel 240Example 240

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [6-oxa-un-decyl] - naphthalene

Beispiel 241Example 241

3,4,5-Tifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[6-oxa-undec-yl]- naphthalin3,4,5-tifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [6-oxa-undec-yl] - naphthalene

Beispiel 242Example 242

3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[6-ox-a-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [6-ox-a-undecyl] - naphthalene

Beispiel 243Example 243

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[-6-o-xa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2 - [- 6-o-xa-undecyl] - naphthalene

Beispiel 244Example 244

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[6-oxa-und-ecyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [6-oxa-and-ecyl] - naphthalene

Beispiel 245Example 245

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[6--oxa-undecyl]- naphthalin 3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [6 - oxa-undecyl] - naphthalene  

Beispiel 246Example 246

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[6-o-xa-undecyl]- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [6-o-xa-undecyl] - naphthalene

Beispiel 247Example 247

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [6-oxa- undecyl] naphthalene

Beispiel 248Example 248

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [6-oxa- undecyl] naphthalene

Beispiel 249Example 249

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[6-oxa-undecyl]--naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [6-oxa-undecyl] naphthalene

Beispiel 250Example 250

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 251Example 251

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxyl-pyridin-2-yl)-2-[6-oxa-un-decyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxyl-pyridin-2-yl) -2- [6-oxa-un-decyl] - naphthalene

Beispiel 252Example 252

3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [6 - oxa-undecyl] - naphthalene

Beispiel 253Example 253

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2-3-difluor-phenyl)-2-[6--oxa-undecyl]- naphthalin 3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2-3-difluoro-phenyl) -2- [6 - oxa-undecyl] - naphthalene  

Beispiel 254Example 254

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[6-oxa-undecyl]-nap-hthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [6-oxa-undecyl] napthalene

Beispiel 255Example 255

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[6-oxa-unde-cyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [6-oxa-undecyl] - naphthalene

Beispiel 256Example 256

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[6-oxa-undecy-l]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [6-oxa-undecy-l] - naphthalene

Beispiel 257Example 257

3,4,5-Trifluor-6(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[6-oxa-u-ndecyl]- naphthalin3,4,5-trifluoro-6 (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [6-oxa-u-decyl] - naphthalene

Beispiel 258Example 258

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[6-oxa--undecyl]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [6-oxa - undecyl] - naphthalene

Beispiel 259Example 259

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[6--oxa-undecyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [6 - oxa-undecyl] - naphthalene

Beispiel 260Example 260

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyrimidin-2-y-l)-2-[6-oxa- undecyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxirane-2-carboxylic acid ester] pyrimidin-2-y-l) -2- [6-oxa- undecyl] naphthalene

Beispiel 261Example 261

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[6-oxa- undecyl]-naphthalin 3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [6-oxa- undecyl] naphthalene  

Beispiel 262Example 262

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2-[6- oxa-undecyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [6- oxa-undecyl] naphthalene

Beispiel 263Example 263

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2-[6- oxa-undecyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [6- oxa-undecyl] naphthalene

Beispiel 264Example 264

3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[perfluor-1H,1H-nonyl]-naphth-alin3,4,5-trifluoro-6- (4-octyloxyphenyl) -2- [perfluoro-1H, 1H-nonyl] naphth-aline

Beispiel 265Example 265

3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[perfluor-1H,1H-nonyl-]-naphthalin3,4,5-trifluoro-6- (5-octyloxypyrimidin-2-yl) -2- [perfluoro-1H, 1H-nonyl -] - naphthalene

Beispiel 266Example 266

3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[perfluor-1H,1H-nonyl]--naphthalin3,4,5-trifluoro-6- (5-octyloxypyridin-2-yl) -2- [perfluoro-1H, 1H-nonyl] naphthalene

Beispiel 267Example 267

3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[perfluor-1H,1H-n-onyl]- naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoropyridin-6-yl) -2- [perfluoro-1H, 1H-n-onyl] - naphthalene

Beispiel 268Example 268

3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[perfluor-1H,1H-n-onyl]- naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluorophenyl) -2- [perfluoro-1H, 1H-n-onyl] - naphthalene

Beispiel 269Example 269

3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[perfluor-1H,1H-nonyl]--naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [perfluoro-1H, 1H-nonyl] naphthalene

Beispiel 270Example 270

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[perfluor-1H,1-H-nonyl]- naphthalin 3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [perfluoro-1H, 1-H-nonyl] - naphthalene  

Beispiel 271Example 271

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene

Beispiel 272Example 272

3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 273Example 273

3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 274Example 274

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[perfluor-1H,1-H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [perfluoro-1H, 1-H-nonyl] - naphthalene

Beispiel 275Example 275

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene

Beispiel 276Example 276

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[perfluo-r-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [perfluoro-1H, 1H- nonyl] naphthalene

Beispiel 277Example 277

3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 278Example 278

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin 3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene  

Beispiel 279Example 279

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[perfluor-1H,1-H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [perfluoro-1H, 1-H-nonyl] - naphthalene

Beispiel 280Example 280

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene

Beispiel 281Example 281

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[perfluo-r-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [perfluoro-1H, 1H- nonyl] naphthalene

Beispiel 282Example 282

3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 283Example 283

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 284Example 284

3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[perfluor-1H,1H-no-nyl]- naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [perfluoro-1H, 1H-no-nyl] - naphthalene

Beispiel 285Example 285

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 286Example 286

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[perfluor-1H-,1H-nonyl]- naphthalin 3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [perfluoro-1H-, 1H-nonyl] - naphthalene  

Beispiel 287Example 287

3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[perfu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [perfu-or-1H, 1H- nonyl] naphthalene

Beispiel 288Example 288

3,4,5-Trifluor-6-(4-[1-hexansäureester]-2,3-difluor-phenyl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene

Beispiel 289Example 289

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[perfluor-1H,1H-nonyl-]-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [perfluoro-1H, 1H-nonyl -] - naphthalene

Beispiel 290Example 290

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[perfluor-1H,-1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [perfluoro-1H, -1H-nonyl] - naphthalene

Beispiel 291Example 291

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene

Beispiel 292Example 292

3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 293Example 293

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[perfluor--1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [perfluoro - 1H, 1H- nonyl] naphthalene

Beispiel 294Example 294

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-phenyl)-2-[perfluor-1H,1H-nonyl]--naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] phenyl) -2- [perfluoro-1H, 1H-nonyl] naphthalene

Beispiel 295Example 295

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[perfiuor-1H,1-H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [perfiuor-1H, 1-H-nonyl] -  naphthalene

Beispiel 296Example 296

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene

Beispiel 297Example 297

3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 298Example 298

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 299Example 299

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[perfluor-1H-,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [perfluoro-1H-, 1H-nonyl] - naphthalene

Beispiel 300Example 300

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[per-fluor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [per-fluoro-1H, 1H- nonyl] naphthalene

Beispiel 301Example 301

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[perfl-uor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [perfl-uor-1H, 1H- nonyl] naphthalene

Beispiel 302Example 302

3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [perfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 303Example 303

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [perfluoro-  1H, 1H-nonyl] naphthalene

Beispiel 304Example 304

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[perfluor-1H,1H-n-onyl]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [perfluoro-1H, 1H-n-onyl] - naphthalene

Beispiel 305Example 305

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[perfluor--1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [perfluoro - 1H, 1H- nonyl] naphthalene

Beispiel 306Example 306

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[perfluor-1-H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [perfluoro-1-H, 1H-nonyl] - naphthalene

Beispiel 307Example 307

3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[perf-luor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [perf-luor-1H, 1H- nonyl] naphthalene

Beispiel 308Example 308

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[perf-luor-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [perf-luor-1H, 1H- nonyl] naphthalene

Beispiel 309Example 309

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 310Example 310

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[p-erfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [p-erfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 311Example 311

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[per-fluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [per-fluoro-  1H, 1H-nonyl] naphthalene

Beispiel 312Example 312

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [perfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 313Example 313

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [perfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 314Example 314

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[perfluor-1H,1H--nonyl]- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [perfluoro-1H, 1H - nonyl] - naphthalene

Beispiel 315Example 315

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[perflu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [perfluoro or 1H, 1H- nonyl] naphthalene

Beispiel 316Example 316

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[perfluor--1H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [perfluoro - 1H, 1H-nonyl] - naphthalene

Beispiel 317Example 317

3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[pe-rfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [pe-fluoro- 1H, 1H-nonyl] naphthalene

Beispiel 318Example 318

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[pe-rfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [pe-fluoro- 1H, 1H-nonyl] naphthalene

Beispiel 319Example 319

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[perfluor-1H,1H-non-yl]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [perfluoro-1H, 1H-non-yl] -  naphthalene

Beispiel 320Example 320

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[perfluor-1-H,1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [perfluoro-1-H, 1H-nonyl] - naphthalene

Beispiel 321Example 321

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[perfluor-1H,-1H-nonyl]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [perfluoro-1H, -1H-nonyl] - naphthalene

Beispiel 322Example 322

3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl).2-[perflu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) .2- [perflu-or-1H, 1H- nonyl] naphthalene

Beispiel 323Example 323

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[perflu-or-1H,1H- nonyl]-naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluorophenyl) -2- [perfluoro or 1H, 1H- nonyl] naphthalene

Beispiel 324Example 324

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[pe-rfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [pe-fluoro- 1H, 1H-nonyl] naphthalene

Beispiel 325Example 325

3,4, 5-Trifluor-6-(5-[3-butyloxjran-2-carbonsäureester]-pyrimidin-2-yl)-2--[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxjran-2-carboxylic acid ester] pyrimidin-2-yl) -2 - [perfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 326Example 326

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[perfluor- 1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [perfluoro- 1H, 1H-nonyl] naphthalene

Beispiel 327Example 327

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [perfluor-1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2-  [perfluoro-1H, 1H-nonyl] naphthalene

Beispiel 328Example 328

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [perfluor-1H,1H-nonyl]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [perfluoro-1H, 1H-nonyl] naphthalene

Beispiel 329Example 329

3,4,5-Trifluor-6-(4-octyloxy-phenyl)-2-[2-Fluor-octyloxy]-naphthalin-3,4,5-trifluoro-6- (4-octyloxy-phenyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 330Example 330

3,4,5-Trifluor-6-(5-octyloxy-pyrimidin-2-yl)-2-[2-Fluor-octyloxy]-na-phthalin3,4,5-trifluoro-6- (5-octyloxy-pyrimidin-2-yl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 331Example 331

3,4,5-Trifluor-6-(5-octyloxy-pyridin-2-yl)-2-[2-Fluor-octyloxy]-naph-thalin3,4,5-trifluoro-6- (5-octyloxy-pyridin-2-yl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 332Example 332

3,4,5-Trifluor-6-(3-octyloxy-fluor-pyridin-6-yl)-2-[2-Fluor-octyloxy-]-naphthalin3,4,5-trifluoro-6- (3-octyloxy-fluoro-pyridin-6-yl) -2- [2-fluoro-octyloxy -] - naphthalene

Beispiel 333Example 333

3,4,5-Trifluor-6-(4-octyloxy-2,3-difluor-phenyl)-2-[2-Fluor-octyloxy-]-naphthalin3,4,5-trifluoro-6- (4-octyloxy-2,3-difluoro-phenyl) -2- [2-fluoro-octyloxy -] - naphthalene

Beispiel 334Example 334

3,4,5-Trifluor-6-(4-[2-methylhexyl]-phenyl)-2-[2-Fluor-octyloxy]-nap-hthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] phenyl) -2- [2-fluoro-octyloxy] napthalene

Beispiel 335Example 335

3,4,5-Trifluor-6-(5-[2-methylhexyl]-pyrimidin-2-yl)-2-[2-Fluor-octyl-oxy]- naphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyrimidin-2-yl) -2- [2-fluoro-octyl-oxy] - naphthalene

Beispiel 336Example 336

3,4, 5-Trifluor-6-(5-[2-methylhexyl]-pyridin-2-yl)-2-[2-Fluor-octyloxy]-n-aphthalin3,4,5-trifluoro-6- (5- [2-methylhexyl] pyridin-2-yl) -2- [2-fluoro-octyloxy] -n-aphthaline

Beispiel 337Example 337

3,4,5-Trifluor-6-(3-[2-methylhexyl]-fluor-pyridin-6-yl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (3- [2-methylhexyl] fluoropyridin-6-yl) -2- [2-fluoro-o-ctyloxy] - naphthalene

Beispiel 338Example 338

3,4,5-Trifluor-6-(4-[2-methylhexyl]-2,3-difluor-phenyl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (4- [2-methylhexyl] -2,3-difluorophenyl) -2- [2-fluoro-o-ctyloxy] - naphthalene

Beispiel 339Example 339

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-phenyl)-2-[2-Fluor-octyl-oxy]- naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] phenyl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 340Example 340

3,4,5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyrimidin-2-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 341Example 341

3,4, 5-Trifluor-6-(5-[6-cyclopropyloctyloxy]-pyridin-2-yl)-2-[2-Fluor-oct-yloxy]- naphthalin3,4,5-trifluoro-6- (5- [6-cyclopropyloctyloxy] pyridin-2-yl) -2- [2-fluoro-oct-yloxy] - naphthalene

Beispiel 342Example 342

3,4,5-Trifluor-6-(3-[6-cyclopropyloctyloxy]-fluor-pyridin-6-yl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [6-cyclopropyloctyloxy] fluoropyridin-6-yl) -2- [2 - fluorine octyloxy] naphthalene

Beispiel 343Example 343

3,4,5-Trifluor-6-(4-[6-cyclopropyloctyloxy]-2,3-difluor-phenyl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [6-cyclopropyloctyloxy] -2,3-difluorophenyl) -2- [2 - fluoro- octyloxy] naphthalene

Beispiel 344Example 344

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-phenyl)-2-[2-Fluor-octyl-oxy]- naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonylphenyl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 345Example 345

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyrimidin-2-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyrimidin-2-yl) -2- [2-fluoro-octyloxy] -  naphthalene

Beispiel 346Example 346

3,4,5-Trifluor-6-(5-[5,5-dimethylsila]nonyl-pyridin-2-yl)-2-[2-Fluor--octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [5,5-dimethylsila] nonyl-pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 347Example 347

3,4,5-Trifluor-6-(3-[5,5-dimethylsila]nonyl-fluor-pyridin-6-yl)-2-[2--Fluor-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [5,5-dimethylsila] nonyl-fluoropyridin-6-yl) -2- [2 - fluoro-octyloxy] - naphthalene

Beispiel 348Example 348

3,4,5-Trifluor-6-(4-[5,5-dimethylsila]nonyl-2,3-difluor-phenyl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [5,5-dimethylsila] nonyl-2,3-difluorophenyl) -2- [2 - fluorine octyloxy] naphthalene

Beispiel 349Example 349

3,4,5-Trifluor-6-(4-[1-hexansäureester]-phenyl)-2-[2-Fluor-octyloxy]--naphthalin3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] phenyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 350Example 350

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyrimidin-2-yl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyrimidin-2-yl) -2- [2-fluoro-o-ctyloxy] - naphthalene

Beispiel 351Example 351

3,4,5-Trifluor-6-(5-[1-hexansäureester]-pyridin-2-yl)-2-[2-Fluor-oct-yloxy]- naphthalin3,4,5-trifluoro-6- (5- [1-hexanoic acid ester] pyridin-2-yl) -2- [2-fluoro-oct-yloxy] - naphthalene

Beispiel 352Example 352

3,4,5-Trifluor-6-(3-[1-hexansäureester]-fluor-pyridin-6-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [1-hexanoic acid ester] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 353Example 353

3,4,5-Trifluor-6-(4-[1 -hexansäureester]-2,3-difluor-phenyl)-2-[2-Fluor-octyloxy]- naphthalin 3,4,5-trifluoro-6- (4- [1-hexanoic acid ester] -2,3-difluorophenyl) -2- [2-fluoro-octyloxy] - naphthalene  

Beispiel 354Example 354

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-phenyl)-2-[2-Fluor-octyloxy]-na-phthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] phenyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 355Example 355

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyrimidin-2-yl)-2-[2-Fluor-octy-loxy]- naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 356Example 356

3,4,5-Trifluor-6-(5-[5-oxa-nonyloxy]-pyridin-2-yl)-2-[2-Fluor-octylo-xy]-naphthalin3,4,5-trifluoro-6- (5- [5-oxa-nonyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 357Example 357

3,4,5-Trifluor-6-(3-[5-oxa-nonyloxy]-fluor-pyridin-6-yl)-2-[2-Fluor--octyloxy- naphthalin3,4,5-trifluoro-6- (3- [5-oxa-nonyloxy] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy- naphthalene

Beispiel 358Example 358

3,4,5-Trifluor-6-(4-[5-oxa-nonyloxy]-2,3-difluor-phenyl)-2-[2-Fluor--octyloxy- naphthalin3,4,5-trifluoro-6- (4- [5-oxa-nonyloxy] -2,3-difluorophenyl) -2- [2-fluoro-octyloxy- naphthalene

Beispiel 359Example 359

3,4,5-Trifluor-6-(4-[-6-oxa-undecyl]-phenyl)-2-[2-Fluor-octyloxy]-na-phthalin3,4,5-trifluoro-6- (4 - [- 6-oxa-undecyl] phenyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 360Example 360

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyrimidin-2-yl)-2-[2-Fluor-octyl-oxy- naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyrimidin-2-yl) -2- [2-fluoro-octyl-oxy- naphthalene

Beispiel 361Example 361

3,4,5-Trifluor-6-(5-[6-oxa-undecyl]-pyridin-2-yl)-2-[2-Fluor-octylox-y]-naphthalin3,4,5-trifluoro-6- (5- [6-oxa-undecyl] pyridin-2-yl) -2- [2-fluoro-octylox-y] naphthalene

Beispiel 362Example 362

3,4,5-Trifluor-6-(3-[6-oxa-undecyl]-fluor-pyridin-6-yl)-2-[2-Fluor-o-ctyloxy- naphthalin 3,4,5-trifluoro-6- (3- [6-oxa-undecyl] fluoropyridin-6-yl) -2- [2-fluoro-o-ctyloxy- naphthalene  

Beispiel 363Example 363

3,4,5-Trifluor-6-(4-[6-oxa-undecyl]-2,3-difluor-phenyl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (4- [6-oxa-undecyl] -2,3-difluorophenyl) -2- [2-fluoro-o-ctyloxy] - naphthalene

Beispiel 364Example 364

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-phenyl)-2-[2-Fluor-oct-yloxy]- naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] phenyl) -2- [2-fluoro-oct-yloxy] - naphthalene

Beispiel 365Example 365

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyrimidin-2-yl)-2-[2-F-luor-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyrimidin-2-yl) -2- [2-F-luoro-octyloxy] - naphthalene

Beispiel 366Example 366

3,4,5-Trifluor-6-(5-[perfluor-1H,1H-octyloxy]-pyridin-2-yl)-2-[2-Flu-or-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [perfluoro-1H, 1H-octyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 367Example 367

3,4,5-Trifluor-6-(3-[perfluor-1H,1H-octyloxy]-fluor-pyridin-6-yl)-2--[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [perfluoro-1H, 1H-octyloxy] fluoropyridin-6-yl) -2 - [2-fluoro- octyloxy] naphthalene

Beispiel 368Example 368

3,4,5-Trifluor-6-(4-[perfluor-1H,1H-octyloxy]-2,3-difluor-phenyl)-2--[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [perfluoro-1H, 1H-octyloxy] -2,3-difluorophenyl) -2 - [2-fluoro- octyloxy] naphthalene

Beispiel 369Example 369

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-phenyl)-2-[2-Fluor-octyloxy-]-naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] phenyl) -2- [2-fluoro-octyloxy -] - naphthalene

Beispiel 370Example 370

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyrimidin-2-yl)-2-[2-Fluor--octyloxy]- naphthalin 3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene  

Beispiel 371Example 371

3,4,5-Trifluor-6-(5-[9-cyclopropylnonyl]-pyridin-2-yl)-2-[2-Fluor-oc-tyloxy]- naphthalin3,4,5-trifluoro-6- (5- [9-cyclopropylnonyl] pyridin-2-yl) -2- [2-fluoro-oc-tyloxy] - naphthalene

Beispiel 372Example 372

3,4,5-Trifluor-6-(3-[9-cyclopropylnonyl]-fluor-pyridin-6-yl)-2-[2-Fl-uor-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [9-cyclopropylnonyl] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 373Example 373

3,4,5-Trifluor-6-(4-[9-cyclopropylnonyl]-2,3-difluor-phenyl)-2-[2-Fl-uor-octyloxy]- naphthalin3,4,5-trifluoro-6- (4- [9-cyclopropylnonyl] -2,3-difluorophenyl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 374Example 374

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-phenyl)-2-[2-Fluor-o-ctyloxy]- naphthalin3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] phenyl) -2- [2-fluoro-o-ctyloxy] - naphthalene

Beispiel 375Example 375

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyrimidin-2-yl) -2- [2 - fluorine octyloxy] naphthalene

Beispiel 376Example 376

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-ylmethoxy]-pyridin-2-yl)-2-[2-F-luor-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-ylmethoxy] pyridin-2-yl) -2- [2-F-luoro-octyloxy] - naphthalene

Beispiel 377Example 377

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-ylmethoxy]-fluor-pyridin-6-yl)--2-[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxiran-2-ylmethoxy] fluoropyridin-6-yl) - 2- [2-fluoro- octyloxy] naphthalene

Beispiel 378Example 378

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)--2-[2-Fluor- octyloxy]-naphthalin 3,4,5-trifluoro-6- (4- [3-butyloxiran-2-ylmethoxy] -2,3-difluorophenyl) - 2- [2-fluoro- octyloxy] naphthalene  

Beispiel 379Example 379

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-phenyl)-2-[2-Fluor-octylo-xy]-naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] phenyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 380Example 380

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyrimidin-2-yl)-2-[2-Fluo-r-octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyrimidin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 381Example 381

3,4,5-Trifluor-6-(5-[2,3-difluor-hexyloxy]-pyridin-2-yl)-2-[2-Fluor--octyloxy]- naphthalin3,4,5-trifluoro-6- (5- [2,3-difluoro-hexyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 382Example 382

3,4,5-Trifluor-6-(3-[2,3-difluor-hexyloxy]-fluor-pyridin-6-yl)-2-[2--Fluor-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [2,3-difluoro-hexyloxy] fluoropyridin-6-yl) -2- [2 - fluoro-octyloxy] - naphthalene

Beispiel 383Example 383

3,4,5-Trifluor-6-(4-[2,3-difluor-hexyloxy]-2,3-difluor-phenyl)-2-[2--Fluor-octyloxy]- naphthalin3,4,5-trifluoro-6- (4- [2,3-difluoro-hexyloxy] -2,3-difluoro-phenyl) -2- [2 - fluoro-octyloxy] - naphthalene

Beispiel 384Example 384

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-phenyl)-2-[2-Fluor-octyloxy]--naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] phenyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 385Example 385

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyrimidin-2-yl)-2-[2-Fluor-oc-tyloxy]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyrimidin-2-yl) -2- [2-fluoro-oc-tyloxy] - naphthalene

Beispiel 386Example 386

3,4,5-Trifluor-6-(5-[2-fluor-decyloxy]-pyridin-2-yl)-2-[2-Fluor-octy-loxy]- naphthalin3,4,5-trifluoro-6- (5- [2-fluoro-decyloxy] pyridin-2-yl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 387Example 387

3,4,5-Trifluor-6-(3-[2-fluor-decyloxy]-fluor-pyridin-6-yl)-2-[2-Fluo-r-octyloxy]- naphthalin3,4,5-trifluoro-6- (3- [2-fluoro-decyloxy] fluoropyridin-6-yl) -2- [2-fluoro-octyloxy] -  naphthalene

Beispiel 388Example 388

3,4,5-Trifluor-6-(4-[2-fluor-decyloxy]-2,3-difluor-phenyl)-2-[2-Fluo-r-octyloxy]- naphthalin3,4,5-trifluoro-6- (4- [2-fluoro-decyloxy] -2,3-difluoro-phenyl) -2- [2-fluoro-octyloxy] - naphthalene

Beispiel 389Example 389

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-phenyl)-2-[2--Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] phenyl) -2- [2 - fluoro- octyloxy] naphthalene

Beispiel 390Example 390

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester1-pyrimidin-2-y-l)-2-[2- Fluor-octyloxy]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxirane-2-carboxylic acid ester 1-pyrimidin-2-y-l) -2- [2- Fluoro-octyloxy] naphthalene

Beispiel 391Example 391

3,4,5-Trifluor-6-(5-[3-butyloxiran-2-carbonsäureester]-pyridin-2-yl)--2-[2-Fluor- octyloxy]-naphthalin3,4,5-trifluoro-6- (5- [3-butyloxiran-2-carboxylic acid ester] pyridin-2-yl) - 2- [2-fluoro- octyloxy] naphthalene

Beispiel 392Example 392

3,4,5-Trifluor-6-(3-[3-butyloxiran-2-carbonsäureester]-fluor-pyridin--6-yl)-2- [2-Fluor-octyloxy]-naphthalin3,4,5-trifluoro-6- (3- [3-butyloxirane-2-carboxylic acid ester] fluoropyridine - 6-yl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 393Example 393

3,4,5-Trifluor-6-(4-[3-butyloxiran-2-carbonsäureester]-2,3-difluor-p-henyl)-2- [2-Fluor-octyloxy]-naphthalin3,4,5-trifluoro-6- (4- [3-butyloxirane-2-carboxylic acid ester] -2,3-difluoro-p-henyl) -2- [2-fluoro-octyloxy] naphthalene

Beispiel 394Example 394

2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 395Example 395

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxynaphthalene

Beispiel 396Example 396

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxynaphthalene

Beispiel 397Example 397

2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octyloxy-naphth-alin2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy-naphth-aline

Beispiel 398Example 398

2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy-naphthal-in2- (4-hexyloxy-2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 399Example 399

2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6-octyloxynaphthalene

Beispiel 400Example 400

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 401Example 401

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 402Example 402

2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octylox-y-naphthalin2- (3- [5-Methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octylox-y-naphthalene

Beispiel 403Example 403

2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (4- [5-Methylheptyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 404Example 404

2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-napht-halin2- (4- [6-Cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-napht-haline

Beispiel 405Example 405

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octylo-xy-naphthalene

Beispiel 406Example 406

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin 2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octylo-xy-naphthalene  

Beispiel 407Example 407

2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--octyloxy- naphthalin2- (3- [6-cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 408Example 408

2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (4- [6-cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene

Beispiel 409Example 409

2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-octyloxy-napht-halin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6-octyloxy-napht-haline

Beispiel 410Example 410

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 411Example 411

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-octylo-xy-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 412Example 412

2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--octyloxy- naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 413Example 413

2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene

Beispiel 414Example 414

2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthal-in2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 415Example 415

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin 2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene  

Beispiel 416Example 416

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 417Example 417

2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (3- [1-heptanoic acid ester] -fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene

Beispiel 418Example 418

2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyl-oxy-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyl-oxy-naphthalene

Beispiel 419Example 419

2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 420Example 420

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [4-Oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 421Example 421

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-naph-thalin2- (5- [4-Oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 422Example 422

2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octylox-y-naphthalin2- (3- [4-Oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octylox-y-naphthalene

Beispiel 423Example 423

2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (4- [4-Oxa-nonyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 424Example 424

2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthalin2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 425Example 425

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-napht-halin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphth-haline

Beispiel 426Example 426

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-napht-halin 2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphth-haline  

Beispiel 427Example 427

2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (3- [6-oxa-dodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 428Example 428

2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline

Beispiel 429Example 429

2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-na-phthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 430Example 430

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene

Beispiel 431Example 431

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene

Beispiel 432Example 432

2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-octyloxy- naphthalin2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 433Example 433

2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--octyloxy- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 434Example 434

2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthal-in2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 435Example 435

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin 2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene  

Beispiel 436Example 436

2-(5-[9-Cyclopropylnonyl]-pyrimidi(n-2-yl)-3,4,5-trifluor-6-octyloxy--naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidi (n-2-yl) -3,4,5-trifluoro-6-octyloxy-naphthalene

Beispiel 437Example 437

2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-oct-yloxy- naphthalin2- (3- [9-cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-oct-yloxy- naphthalene

Beispiel 438Example 438

2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octyl-oxy-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyl-oxy-naphthalene

Beispiel 439Example 439

2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline

Beispiel 440Example 440

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene

Beispiel 441Example 441

2-(5-[3-Hexyloxiran-2-ylmethoxyl-pyrimidin-2-yl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxyl-pyrimidin-2-yl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene

Beispiel 442Example 442

2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-octyloxy- naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6-octyloxy- naphthalene

42483 00070 552 001000280000000200012000285914237200040 0002019522195 00004 42364Beispiel 443  42483 00070 552 001000280000000200012000285914237200040 0002019522195 00004 42364 Example 443

2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-octyloxy- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 444Example 444

2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy--naphthalin 2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene  

Beispiel 445Example 445

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-o-ctyloxy- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-o-ctyloxy- naphthalene

Beispiel 446Example 446

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-o-ctyloxy- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-o-ctyloxy- naphthalene

Beispiel 447Example 447

2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-octyloxy- naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 448Example 448

2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-octyloxy- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6-octyloxy- naphthalene

Beispiel 449Example 449

2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-octyloxy-naphthali-n2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6-octyloxy-naphthali-n

Beispiel 450Example 450

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline

Beispiel 451Example 451

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-octyloxy-n-aphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6-octyloxy-n-aphthaline

Beispiel 452Example 452

2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-octy-loxy-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6-octyloxy naphthalene

Beispiel 453Example 453

2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-octylo-xy-naphthalin 2- (4- [2-chloro-hexyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6-octyloxy-naphthalene  

Beispiel 454Example 454

2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-oc-tyloxy- naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6-oc-tyloxy- naphthalene

Beispiel 455Example 455

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-octyl­ oxy-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6-octyl oxy-naphthalene

Beispiel 456Example 456

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-octyl­ oxy-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6-octyl oxy-naphthalene

Beispiel 457Example 457

2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- octyloxy-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- octyloxy-naphthalene

Beispiel 458Example 458

2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- octyloxy-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- octyloxy-naphthalene

Beispiel 459Example 459

2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-naphthalin2- (4-hexyloxyphenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphthalene

Beispiel 460Example 460

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline

Beispiel 461Example 461

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline

Beispiel 462Example 462

2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-methylhexyl]--naphthalin 2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-methylhexyl] naphthalene  

Beispiel 463Example 463

2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-n-aphthalin2- (4-Hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] n-aphthaline

Beispiel 464Example 464

2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline

Beispiel 465Example 465

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexy-1] naphthalene

Beispiel 466Example 466

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexy-1] naphthalene

Beispiel 467Example 467

2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-meth-ylhexyl]- naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-meth-ylhexyl] - naphthalene

Beispiel 468Example 468

2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 469Example 469

2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (4- [6-Cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene

Beispiel 470Example 470

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 471Example 471

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin 2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene  

Beispiel 472Example 472

2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[2-methyl­ hexyl]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [2-methyl hexyl] naphthalene

Beispiel 473Example 473

2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2--methyl­ hexyl]-naphthalin2- (4- [6-Cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene

Beispiel 474Example 474

2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene

Beispiel 475Example 475

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 476Example 476

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 477Example 477

2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[2-methylhexyl]- naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [2-methylhexyl] - naphthalene

Beispiel 478Example 478

2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene

Beispiel 479Example 479

2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-n-aphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] n-aphthaline

Beispiel 480Example 480

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] -  naphthalene

Beispiel 481Example 481

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 482Example 482

2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene

Beispiel 483Example 483

2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-me-thylhexyl]- naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 484Example 484

2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-napht-halin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphtaline

Beispiel 485Example 485

2-(5-[4-Oxa-nonyloxyl-pyrimidin-2-yl)-3,4-5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [4-Oxa-nonyloxyl-pyrimidin-2-yl) -3,4-5-trifluoro-6- [2-methylhexy-l] -naphthalene

Beispiel 486Example 486

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexy-l]-naphthalin2- (5- [4-Oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexy-l] naphthalene

Beispiel 487Example 487

2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-meth-ylhexyl]- naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-meth-ylhexyl] - naphthalene

Beispiel 488Example 488

2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin 2- (4- [4-oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene  

Beispiel 489Example 489

2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-naphth-alin2- (4- [6-oxadodecyl] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphth-aline

Beispiel 490Example 490

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene

Beispiel 491Example 491

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylhexyl-]-naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl -] - naphthalene

Beispiel 492Example 492

2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-methy-lhexyl]- naphthalin2- (3- [6-oxadodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 493Example 493

2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (4- [6-oxadodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene

Beispiel 494Example 494

2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhe-xyl]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 495Example 495

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene

Beispiel 496Example 496

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene

Beispiel 497Example 497

2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[2-methyl- hexyl]-naphthalin 2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [2-methyl- hexyl] naphthalene  

Beispiel 498Example 498

2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[2-methyl­ hexyl]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [2-methyl hexyl] naphthalene

Beispiel 499Example 499

2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-n-aphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] n-aphthaline

Beispiel 500Example 500

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 501Example 501

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 502Example 502

2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2--methylhexyl]- naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2 - methylhexyl] - naphthalene

Beispiel 503Example 503

2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-me-thylhexyl]- naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 504Example 504

2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene

Beispiel 505Example 505

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methyl­ hexyl]-naphthalin 2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene  

Beispiel 506Example 506

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2--methyl­ hexyl]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene

Beispiel 507Example 507

2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[2-methyl­ hexyl]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [2-methyl hexyl] naphthalene

Beispiel 508Example 508

2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[2- methylhexyl]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [2- methylhexyl] naphthalene

Beispiel 509Example 509

2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[2-methyl-hexyl]- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 510Example 510

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-2-methylhexyl]- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 2-methylhexyl] - naphthalene

Beispiel 511Example 511

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-2-methylhexyl]- naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 2-methylhexyl] - naphthalene

Beispiel 512Example 512

2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[2- methylhexyl]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2- methylhexyl] naphthalene

Beispiel 513Example 513

2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[2- methylhexyl]-naphthalin 2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [2- methylhexyl] naphthalene  

Beispiel 514Example 514

2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[2-methylhexyl]-na-phthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [2-methylhexyl] naphthalene

Beispiel 515Example 515

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene

Beispiel 516Example 516

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[2-methylh-exyl]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [2-methylh-exyl] - naphthalene

Beispiel 517Example 517

2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[2-m-ethylhexyl]- naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [2-m-ethylhexyl] - naphthalene

Beispiel 518Example 518

2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[2-met-hylhexyl]- naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [2-methylhexyl] - naphthalene

Beispiel 519Example 519

2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[2--methyl­ hexyl]-naphthalin2- (4- [3-Propyloxiran-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [2 - methyl hexyl] naphthalene

Beispiel 520Example 520

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[2- methylhexyl]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [2- methylhexyl] naphthalene

Beispiel 521Example 521

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[2- methylhexyl]-naphthalin 2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [2- methylhexyl] naphthalene  

Beispiel 522Example 522

2-(3-[3-propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [2-methylhexyl]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [2-methylhexyl] naphthalene

Beispiel 523Example 523

2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [2-methylhexyl]-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [2-methylhexyl] naphthalene

Beispiel 524Example 524

2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctyloxy]-napht-halin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] naphtaline

Beispiel 525Example 525

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] naphthalene

Beispiel 526Example 526

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] naphthalene

Beispiel 527Example 527

2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cyclopropylo-ctyloxy]- naphthalin2- (3-hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclopropylo-ctyloxy] - naphthalene

Beispiel 528Example 528

2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloct-yloxy]- naphthalin2- (4-hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cyclopropyloct-yloxy] - naphthalene

Beispiel 529Example 529

2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]-naphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] naphthalene

Beispiel 530Example 530

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin 2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene  

Beispiel 531Example 531

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene

Beispiel 532Example 532

2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cycl-opropyloctyl­ oxy]-naphthalin2- (3- [5-Methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene

Beispiel 533Example 533

2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin2- (4- [5-Methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene

Beispiel 534Example 534

2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyl-octyloxy] - naphthalene

Beispiel 535Example 535

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyl­ octyloxy]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyl octyloxy] naphthalene

Beispiel 536Example 536

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyl­ octyloxy]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyl octyloxy] naphthalene

Beispiel 537Example 537

2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[6-cyclo­ propyloctyloxy]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [6-cyclo propyloctyloxy] naphthalene

Beispiel 538Example 538

2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin 2- (4- [6-Cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene  

Beispiel 539Example 539

2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene

Beispiel 540Example 540

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyloctyl­ oxy]-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyloctyl oxy] naphthalene

Beispiel 541Example 541

2-(5-[5,5-dimethylsila]octyl-Pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyc-lopropyloctyl­ oxy]-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyc-lopropyloctyl oxy] naphthalene

Beispiel 542Example 542

2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,s-trifiuor-6--[6-cyclopropyl­ octyloxy]-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4, s-trifiuor-6 - [6-cyclopropyl octyloxy] naphthalene

Beispiel 543Example 543

2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 544Example 544

2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloct-yloxy]- naphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloct-yloxy] - naphthalene

Beispiel 545Example 545

2-(5-[1-Heptans-ureester]-Pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin2- (5- [1-heptane ureester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene

Beispiel 546Example 546

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin 2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene  

Beispiel 547Example 547

2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 548Example 548

2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cy-clopropyl­ octyloxy]-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [6-cy-clopropyl octyloxy] naphthalene

Beispiel 549Example 549

2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctylox-y]- naphthalin2- (4- [4-oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctylox-y] - naphthalene

Beispiel 550Example 550

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene

Beispiel 551Example 551

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropy-loctyloxy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropy-loctyloxy] - naphthalene

Beispiel 552Example 552

2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cycl-opropyloctyl­ oxy]-naphthalin2- (3- [4-Oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene

Beispiel 553Example 553

2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin2- (4- [4-Oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene

Beispiel 554Example 554

2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloctyloxy-]-naphthalin 2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy -] - naphthalene  

Beispiel 555Example 555

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene

Beispiel 556Example 556

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopropyl-octyloxy]- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene

Beispiel 557Example 557

2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-cyclo-propyloctyl­ oxy]-naphthalin2- (3- [6-oxa-dodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-cyclo-propyloctyl oxy] naphthalene

Beispiel 558Example 558

2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyl­ oxy]-naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyl oxy] naphthalene

Beispiel 559Example 559

2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopro-pyloctyloxy]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene

Beispiel 560Example 560

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 561Example 561

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 562Example 562

2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[6-cyclo­ propyloctyloxy]-naphthalin 2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [6-cyclo propyloctyloxy] naphthalene  

Beispiel 563Example 563

2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[6-cyclo­ propyloctyloxy]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [6-cyclo propyloctyloxy] naphthalene

Beispiel 564Example 564

2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[6-cyclopropyloct-yloxy]- naphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloct-yloxy] - naphthalene

Beispiel 565Example 565

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene

Beispiel 566Example 566

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopropyloctyl oxy] naphthalene

Beispiel 567Example 567

2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 568Example 568

2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cy-clopropyl­ octyloxy]-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cy-clopropyl octyloxy] naphthalene

Beispiel 569Example 569

2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyl­ oxy]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyl oxy] naphthalene

Beispiel 570Example 570

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin 2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene  

Beispiel 571Example 571

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 572Example 572

2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[6-cyclo­ propyloctyloxy]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [6-cyclo propyloctyloxy] naphthalene

Beispiel 573Example 573

2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[6-cyclo­ propyloctyloxy]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [6-cyclo propyloctyloxy] naphthalene

Beispiel 574Example 574

2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclop-ropyloctyl­ oxy]-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [6-cycloproopyloctyl oxy] naphthalene

Beispiel 575Example 575

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-6-cyclopropyl­ octyloxy]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 6-cyclopropyl octyloxy] naphthalene

Beispiel 576Example 576

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-6-cyclopropyl­ octyloxy]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 6-cyclopropyl octyloxy] naphthalene

Beispiel 577Example 577

2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[6- cyclopropyloctyloxy]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6- cyclopropyloctyloxy] naphthalene

Beispiel 578Example 578

2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[6- cyclopropyloctyloxy]-naphthalin 2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [6- cyclopropyloctyloxy] naphthalene  

Beispiel 579Example 579

2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[6-cyclopropylocty-loxy]- naphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [6-cyclopropyloctyloxy] - naphthalene

Beispiel 580Example 580

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyloxy] - naphthalene

Beispiel 581Example 581

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[6-cyclopr-opyloctyloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [6-cyclopr-opyloctyloxy] - naphthalene

Beispiel 582Example 582

2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[6-c-yclopropyl­ octyloxy]-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [6-c-yclopropyl octyloxy] naphthalene

Beispiel 583Example 583

2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[6-cyc-lopropyl­ octyloxy]-naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [6-cyc-lopropyl octyloxy] naphthalene

Beispiel 584Example 584

2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[6--cyclopropyl­ octyloxy]-naphthalin2- (4- [3-Propyloxirane-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [6 - cyclopropyl octyloxy] naphthalene

Beispiel 585Example 585

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[6- cyclopropyloctyloxy]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [6- cyclopropyloctyloxy] naphthalene

Beispiel 586Example 586

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[6- cyclopropyloctyloxy]-naphthalin 2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [6- cyclopropyloctyloxy] naphthalene  

Beispiel 587Example 587

2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [6-cyclopropyloctyloxy]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [6-cyclopropyloctyloxy] naphthalene

Beispiel 588Example 588

2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [6-cyclopropyloctyloxy]-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [6-cyclopropyloctyloxy] naphthalene

Beispiel 589Example 589

2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]nonyl-napht-halin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl-napht-haline

Beispiel 590Example 590

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene

Beispiel 591Example 591

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene

Beispiel 592Example 592

2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-dimethylsi-la]nonyl- naphthalin2- (3-hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsi-la] nonyl- naphthalene

Beispiel 593Example 593

2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila-]nonyl- naphthalin2- (4-hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila-] nonyl- naphthalene

Beispiel 594Example 594

2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene

Beispiel 595Example 595

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin 2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene  

Beispiel 596Example 596

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene

Beispiel 597Example 597

2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-di-methylsila]­ nonyl-naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 598Example 598

2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 599Example 599

2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethyls-ila] nonyl- naphthalene

Beispiel 600Example 600

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila]­ nonyl-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene

Beispiel 601Example 601

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila]­ nonyl-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene

Beispiel 602Example 602

2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5,5-dimethyl­ sila]nonyl-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5,5-dimethyl sila] nonyl-naphthalene

Beispiel 603Example 603

2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-,5-dimethyl­ sila]nonyl-naphthalin 2- (4- [6-Cyclopropylhexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene  

Beispiel 604Example 604

2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl- naphthalene

Beispiel 605Example 605

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila]­ nonyl-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene

Beispiel 606Example 606

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-d-imethylsila]­ nonyl-naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene

Beispiel 607Example 607

2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5,5-dimethyl­ sila]nonyl-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5,5-dimethyl sila] nonyl-naphthalene

Beispiel 608Example 608

2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-,5-dimethyl­ sila]nonyl-naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene

Beispiel 609Example 609

2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila-]nonyl- naphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila-] nonyl- naphthalene

Beispiel 610Example 610

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 611Example 611

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin 2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene  

Beispiel 612Example 612

2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,-5-dimethyl­ sila]nonyl-naphthalin2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5, -5-dimethyl sila] nonyl-naphthalene

Beispiel 613Example 613

2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5--dimethyl­ sila]nonyl-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5,5-dimethyl sila] nonyl-naphthalene

Beispiel 614Example 614

2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]non-yl-naphthalin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] non-yl-naphthalene

Beispiel 615Example 615

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene

Beispiel 616Example 616

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyl-sila]nonyl- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyl-sila] nonyl- naphthalene

Beispiel 617Example 617

2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-di-methylsila]­ nonyl-naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 618Example 618

2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin2- (4- [4-oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 619Example 619

2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]nony-l-naphthalin2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nony-l-naphthalene

Beispiel 620Example 620

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyls-ila] nonyl-  naphthalene

Beispiel 621Example 621

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimethyls-ila]nonyl- naphthalin2- (5- [6-oxadodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethyls-ila] nonyl- naphthalene

Beispiel 622Example 622

2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5-dim-ethylsila]­ nonyl-naphthalin2- (3- [6-oxadodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 623Example 623

2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-dimet-hylsila]­ nonyl-naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 624Example 624

2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimeth-ylsila]nonyl- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimeth-ylsila] nonyl- naphthalene

Beispiel 625Example 625

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,-5-dimethyl­ sila]nonyl-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5, -5-dimethyl sila] nonyl-naphthalene

Beispiel 626Example 626

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,-5-dimethyl­ sila]nonyl-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5, -5-dimethyl sila] nonyl-naphthalene

Beispiel 627Example 627

2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[5,5- dimethylsila]nonyl-naphthalin2- (3- [perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [5,5- dimethylsila] nonyl-naphthalene

Beispiel 628Example 628

2-(4-[Perfluor-1H,1H-hepyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[5,5- dimethylsila]nonyl-naphthalin2- (4- [Perfluoro-1H, 1H-hepyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [5.5-  dimethylsila] nonyl-naphthalene

Beispiel 629Example 629

2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila-]nonyl- naphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila-] nonyl- naphthalene

Beispiel 630Example 630

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 631Example 631

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 632Example 632

2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,-5-dimethylsila]­ nonyl-naphthalin2- (3- [9-cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5, -5-dimethylsila] nonyl naphthalene

Beispiel 633Example 633

2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5--dimethylsila]­ nonyl-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5 - dimethylsila] nonyl naphthalene

Beispiel 634Example 634

2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimet-hylsila]­ nonyl-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 635Example 635

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-,5-dimethyl­ sila]nonyl-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene

Beispiel 636Example 636

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-,5-dimethyl­ sila]nonyl-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-, 5-dimethyl  sila] nonyl-naphthalene

Beispiel 637Example 637

2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[5,5- dimethylsila]nonyl-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [5,5- dimethylsila] nonyl-naphthalene

Beispiel 638Example 638

2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5,5- dimethylsila]nonyl-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5,5- dimethylsila] nonyl-naphthalene

Beispiel 639Example 639

2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dime-thylsila]­ nonyl-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 640Example 640

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-5,5-dimethyl­ sila]nonyl-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 5,5-dimethyl sila] nonyl-naphthalene

Beispiel 641Example 641

2-(5-[2,3-Chloro-fluor-hepyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-,5-dimethyl­ sila]nonyl-naphthalin2- (5- [2,3-chloro-fluoro-hepyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene

Beispiel 642Example 642

2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[5,5- dimethylsila]nonyl-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5- dimethylsila] nonyl-naphthalene

Beispiel 643Example 643

2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5,5- dimethylsila]nonyl-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5.5- dimethylsila] nonyl-naphthalene

Beispiel 644Example 644

2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[5,5-dimethylsila]-nonyl- naphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl-  naphthalene

Beispiel 645Example 645

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimet-hylsila]nonyl- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimet-hylsila] nonyl- naphthalene

Beispiel 646Example 646

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5,5-dimet-hylsila]nonyl- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5,5-dimet-hylsila] nonyl- naphthalene

Beispiel 647Example 647

2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5,5--dimethylsila]­ nonyl-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5,5-dimethylsila] nonyl naphthalene

Beispiel 648Example 648

2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5,5-d-imethylsila]­ nonyl-naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5,5-d-imethylsila] nonyl naphthalene

Beispiel 649Example 649

2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[5-,5-dimethyl­ sila]nonyl-naphthalin2- (4- [3-Propyloxiran-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [5-, 5-dimethyl sila] nonyl-naphthalene

Beispiel 650Example 650

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5,5- dimethylsila]nonyl-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5,5- dimethylsila] nonyl-naphthalene

Beispiel 651Example 651

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5,5- dimethylsila]nonyl-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5,5- dimethylsila] nonyl-naphthalene

Beispiel 652Example 652

2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [5,5-dimethylsila]nonyl-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6-  [5,5-dimethylsila] nonyl-naphthalene

Beispiel 653Example 653

2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [5,5-dimethylsila]nonyl-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [5,5-dimethylsila] nonyl-naphthalene

Beispiel 654Example 654

2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[1-hexansäureester]-naphthali-n2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthali-n

Beispiel 655Example 655

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline

Beispiel 656Example 656

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline

Beispiel 657Example 657

2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexansäurees-ter]- naphthalin2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 658Example 658

2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexansäureeste-r]-naphthalin2- (4-Hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] r -naphthalene

Beispiel 659Example 659

2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline

Beispiel 660Example 660

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 661Example 661

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin 2- (5- [5-methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene  

Beispiel 662Example 662

2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexa-nsäureester]- naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexa-acid ester] - naphthalene

Beispiel 663Example 663

2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 664Example 664

2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 665Example 665

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäure­ ester]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthalene

Beispiel 666Example 666

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäure­ ester]-naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthalene

Beispiel 667Example 667

2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[1-hexan­ säureester]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [1-hexane acid ester] -naphthalene

Beispiel 668Example 668

2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin2- (4- [6-Cyclopropylhexyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 669Example 669

2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin 2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene  

Beispiel 670Example 670

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäureester]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 671Example 671

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hex-ansäureester]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 672Example 672

2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[1-hexansäure­ ester]-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [1-hexanoic acid ester] -naphthalene

Beispiel 673Example 673

2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 674Example 674

2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[1-hexansäureeste-r]- naphthalin2- (4- [1-heptanoic acid ester] -phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester-r] - naphthalene

Beispiel 675Example 675

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 676Example 676

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 677Example 677

2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin 2- (3- [1-heptanoic acid ester] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -naphthalene  

Beispiel 678Example 678

2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-he-xansäure­ ester]-naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [1-he-xanoic acid ester] -naphthalene

Beispiel 679Example 679

2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäureester]-n-aphthalin2- (4- [4-Oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -n-aphthaline

Beispiel 680Example 680

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 681Example 681

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäure-ester]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 682Example 682

2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexa-nsäureester]- naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexaic acid ester] - naphthalene

Beispiel 683Example 683

2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (4- [4-oxa-nonyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 684Example 684

2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[1 -hexansäureester]-naphthalin2- (4- [6-oxadodecyl] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] naphthalene

Beispiel 685Example 685

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 686Example 686

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansäuree-ster]- naphthalin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] -  naphthalene

Beispiel 687Example 687

2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-hexan-säureester]- naphthalin2- (3- [6-oxadodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 688Example 688

2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 689Example 689

2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäu-reester]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 690Example 690

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 691Example 691

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 692Example 692

2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[1-hexan­ säureester]-naphthalin2- (3- [Perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [1-hexane acid ester] -naphthalene

Beispiel 693Example 693

2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[1-hexan­ säureester]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [1-hexane acid ester] -naphthalene

Beispiel 694Example 694

2-(4-[9-Cyclopropylnonyl]-pheny-)-3,4,5-trifluor-6-[1-hexansäureeste-r]-naphthalin 2- (4- [9-Cyclopropylnonyl] pheny -) - 3,4,5-trifluoro-6- [1-hexanoic acid ester] r -naphthalene  

Beispiel 695Example 695

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 696Example 696

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 697Example 697

2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 698Example 698

2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trjfluor-6-[1-he-xansäure­ ester]-naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-he-xanoic acid ester] -naphthalene

Beispiel 699Example 699

2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 700Example 700

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure ester]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 701Example 701

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1--hexansäure­ ester]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1 - hexanoic acid ester] -naphthalene

Beispiel 702Example 702

2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[1-hexan­ säureester]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [1-hexane acid ester] -naphthalene

Beispiel 703Example 703

2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[1-hexan­ säureester]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [1-hexane acid ester] -naphthalene

Beispiel 704Example 704

2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexans-äureester]- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 705Example 705

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-1-hexansäure­ ester]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 1-hexanoic acid ester] -naphthalene

Beispiel 706Example 706

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-1-hexansäure­ ester]-naphthalin2- (5- [2,3-Chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 1-hexanoic acid ester] -naphthalene

Beispiel 707Example 707

2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[1-hexan­ säureester]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-hexane acid ester] -naphthalene

Beispiel 708Example 708

2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[1-hexan­ säureester]-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [1-hexane acid ester] -naphthalene

Beispiel 709Example 709

2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[1-hexansäureester-]-naphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester -] - naphthalene

Beispiel 710Example 710

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin 2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene  

Beispiel 711Example 711

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[1-hexansä-ureester]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 712Example 712

2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[1-h-exansäure­ ester]-naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [1-h-exanoic acid ester] -naphthalene

Beispiel 713Example 713

2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[1-hex-ansäureester]- naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [1-hexanoic acid ester] - naphthalene

Beispiel 714Example 714

2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[1--hexansäure- ester]-naphthalin2- (4- [3-Propyloxiran-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [1 - hexanoic acid- ester] -naphthalene

Beispiel 715Example 715

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6- [1-hexansäureester]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [1-hexanoic acid ester] naphthalene

Beispiel 716Example 716

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6- [1-hexansäureester]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [1-hexanoic acid ester] naphthalene

Beispiel 717Example 717

2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor- 6-[1-hexansäureester]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro- 6- [1-hexanoic acid ester] naphthalene

Beispiel 718Example 718

2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [1-hexansäureester]-naphthalin 2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [1-hexanoic acid ester] naphthalene  

Beispiel 719Example 719

2-(4-Hexyloxy-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naphthalin2- (4-Hexyloxy-phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 720Example 720

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] naphthalene

Beispiel 721Example 721

2-(5-Hexyloxy-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (5-Hexyloxypyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] naphthalene

Beispiel 722Example 722

2-(3-Hexyloxy-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa-nonyloxy-]-naphthalin2- (3-Hexyloxy-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy -] - naphthalene

Beispiel 723Example 723

2-(4-Hexyloxy-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]--naphthalin2- (4-Hexyloxy-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 724Example 724

2-(4-[5-Methylheptyl]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (4- [5-Methylheptyl] phenyl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] naphthalene

Beispiel 725Example 725

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 726Example 726

2-(5-[5-Methylheptyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]-naphthalin2- (5- [5-Methylheptyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 727Example 727

2-(3-[5-Methylheptyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (3- [5-methylheptyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene

Beispiel 728Example 728

2-(4-[5-Methylheptyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin 2- (4- [5-methylheptyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene  

Beispiel 729Example 729

2-(4-[6-Cyclopropylhexyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]- naphthalin2- (4- [6-cyclopropylhexyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] - naphthalene

Beispiel 730Example 730

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene

Beispiel 731Example 731

2-(5-[6-Cyclopropylhexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (5- [6-Cyclopropylhexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene

Beispiel 732Example 732

2-(3-[6-Cyclopropylhexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5-oxa-nonyl­ oxy]-naphthalin2- (3- [6-Cyclopropylhexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5-oxa-nonyl oxy] naphthalene

Beispiel 733Example 733

2-(4-[6-Cyclopropylhexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5--oxa-nonyl­ oxy]-naphthalin2- (4- [6-Cyclopropylhexyloxy] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyl oxy] naphthalene

Beispiel 734Example 734

2-(4-[5,5-dimethylsila]octyl-phenyl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]-naphthalin2- (4- [5,5-dimethylsila] octylphenyl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] naphthalene

Beispiel 735Example 735

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene

Beispiel 736Example 736

2-(5-[5,5-dimethylsila]octyl-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin 2- (5- [5,5-dimethylsila] octyl-pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene  

Beispiel 737Example 737

2-(3-[5,5-dimethylsila]octyl-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6--[5-oxa-nonyl­ oxy]-naphthalin2- (3- [5,5-dimethylsila] octyl-fluoropyrimidin-6-yl) -3,4,5-trifluoro-6 - [5-oxa-nonyl oxy] naphthalene

Beispiel 738Example 738

2-(4-[5,5-dimethylsila]octyl-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (4- [5,5-dimethylsila] octyl-2,3-difluorophenyl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene

Beispiel 739Example 739

2-(4-[1-Heptansäureester]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]--naphthalin2- (4- [1-heptanoic acid ester] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 740Example 740

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene

Beispiel 741Example 741

2-(5-[1-Heptansäureester]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [1-heptanoic acid ester] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene

Beispiel 742Example 742

2-(3-[1-Heptansäureester]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (3- [1-heptanoic acid ester] -fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene

Beispiel 743Example 743

2-(4-[1-Heptansäureester]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-ox-a-nonyloxy]- naphthalin2- (4- [1-heptanoic acid ester] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-ox-a-nonyloxy] - naphthalene

Beispiel 744Example 744

2-(4-[4-Oxa-nonyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-naph-thalin2- (4- [4-oxa-nonyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 745Example 745

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy-xy] -  naphthalene

Beispiel 746Example 746

2-(5-[4-Oxa-nonyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylo-xy]- naphthalin2- (5- [4-oxa-nonyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy-xy] - naphthalene

Beispiel 747Example 747

2-(3-[4-Oxa-nonyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (3- [4-oxa-nonyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] - naphthalene

Beispiel 748Example 748

2-(4-[4-Oxa-nonyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (4- [4-oxa-nonyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene

Beispiel 749Example 749

2-(4-[6-Oxa-dodecyl]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-napht-halin2- (4- [6-oxa-dodecyl] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphtaline

Beispiel 750Example 750

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]-naphthalin2- (5- [6-Oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] naphthalene

Beispiel 751Example 751

2-(5-[6-Oxa-dodecyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-nonylox-y]-naphthalin2- (5- [6-oxa-dodecyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-nonylox-y] naphthalene

Beispiel 752Example 752

2-(3-[6-Oxa-dodecyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-oxa-n-onyloxy]- naphthalin2- (3- [6-oxa-dodecyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa-n-onyloxy] - naphthalene

Beispiel 753Example 753

2-(4-[6-Oxa-dodecyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (4- [6-oxa-dodecyl] -2,3-difluoro-phenyl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene

Beispiel 754Example 754

2-(4-[Perfluor-1H,1H-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nony-loxy]- naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-nony-loxy] - naphthalene

Beispiel 755Example 755

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene

Beispiel 756Example 756

2-(5-[Perfluor-1H,1H-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (5- [Perfluoro-1H, 1H-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] - naphthalene

Beispiel 757Example 757

2-(3-[Perfluor-1H,1H-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor--6-[5-oxa- nonyloxy]-naphthalin2- (3- [perfluoro-1H, 1H-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro - 6- [5-oxa- nonyloxy] naphthalene

Beispiel 758Example 758

2-(4-[Perfluor-1H,1H-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6--[5-oxa- nonyloxy]-naphthalin2- (4- [Perfluoro-1H, 1H-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6 - [5-oxa- nonyloxy] naphthalene

Beispiel 759Example 759

2-(4-[9-Cyclopropylnonyl]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]--naphthalin2- (4- [9-Cyclopropylnonyl] phenyl) -3,4,5-trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 760Example 760

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene

Beispiel 761Example 761

2-(5-[9-Cyclopropylnonyl]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (5- [9-Cyclopropylnonyl] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene

Beispiel 762Example 762

2-(3-[9-Cyclopropylnonyl]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5--oxa-nonyloxy]- naphthalin2- (3- [9-Cyclopropylnonyl] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyloxy] -  naphthalene

Beispiel 763Example 763

2-(4-[9-Cyclopropylnonyl]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-ox-a-nonyloxy]- naphthalin2- (4- [9-Cyclopropylnonyl] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-ox-a-nonyloxy] - naphthalene

Beispiel 764Example 764

2-(4-[3-Hexyloxiran-2-ylmethoxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene

Beispiel 765Example 765

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-non- oxy]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-non- oxy] naphthalene

Beispiel 766Example 766

2-(5-[3-Hexyloxiran-2-ylmethoxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5--oxa-nonyl- oxy]-naphthalin2- (5- [3-Hexyloxiran-2-ylmethoxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5 - oxa-nonyl- oxy] naphthalene

Beispiel 767Example 767

2-(3-[3-Hexyloxiran-2-ylmethoxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluo-r-6-[5-oxa- nonyloxy]-naphthalin2- (3- [3-Hexyloxiran-2-ylmethoxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-r-6- [5-oxa- nonyloxy] naphthalene

Beispiel 768Example 768

2-(4-[3-Hexyloxiran-2-ylmethoxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5-oxa- nonyloxy]-naphthalin2- (4- [3-Hexyloxiran-2-ylmethoxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5-oxa- nonyloxy] naphthalene

Beispiel 769Example 769

2-(4-[2,3-Chloro-fluor-heptyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-no-nyloxy]- naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa-no-nyloxy] - naphthalene

Beispiel 770Example 770

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-5-oxa- nonyloxy]-naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 5-oxa-  nonyloxy] naphthalene

Beispiel 771Example 771

2-(5-[2,3-Chloro-fluor-heptyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[-5-oxa- nonyloxy]-naphthalin2- (5- [2,3-chloro-fluoro-heptyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6 - [- 5-oxa- nonyloxy] naphthalene

Beispiel 772Example 772

2-(3-[2,3-Chloro-fluor-heptyloxy]-fluor-pyrimidin-6-yl)-3,4,5-triflu-or-6-[5-oxa- nonyloxy]-naphthalin2- (3- [2,3-chloro-fluoro-heptyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-oxa- nonyloxy] naphthalene

Beispiel 773Example 773

2-(4-[2,3-Chloro-fluor-heptyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor--6-[5-oxa- nonyloxy]-naphthalin2- (4- [2,3-chloro-fluoro-heptyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro - 6- [5-oxa- nonyloxy] naphthalene

Beispiel 774Example 774

2-(4-[2-Chloro-hexyloxy]-phenyl)-3,4,5-trifluor-6-[5-oxa-nonyloxy]-n-aphthalin2- (4- [2-chloro-hexyloxy] phenyl) -3,4,5-trifluoro-6- [5-oxa nonyloxy] n-aphthaline

Beispiel 775Example 775

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene

Beispiel 776Example 776

2-(5-[2-Chloro-hexyloxy]-pyrimidin-2-yl)-3,4,5-trifluor-6-[5-oxa-non-yloxy]- naphthalin2- (5- [2-chloro-hexyloxy] pyrimidin-2-yl) -3,4,5-trifluoro-6- [5-oxa-non-yloxy] - naphthalene

Beispiel 777Example 777

2-(3-[2-Chloro-hexyloxy]-fluor-pyrimidin-6-yl)-3,4,5-trifluor-6-[5-o-xa-nonyloxy]- naphthalin2- (3- [2-chloro-hexyloxy] fluoropyrimidin-6-yl) -3,4,5-trifluoro-6- [5-o-xa-nonyloxy] - naphthalene

Beispiel 778Example 778

2-(4-[2-Chloro-hexyloxy]-2,3-difluor-phenyl)-3,4,5-trifluor-6-[5-oxa--nonyloxy]- naphthalin2- (4- [2-chloro-hexyloxy] -2,3-difluorophenyl) -3,4,5-trifluoro-6- [5-oxa - nonyloxy] - naphthalene

Beispiel 779Example 779

2-(4-[3-Propyloxiran-2-carbonsäureester]-phenyl)-3,4,5-trifluor-6-[5--oxa- nonyloxy]-naphthalin2- (4- [3-propyloxirane-2-carboxylic acid ester] phenyl) -3,4,5-trifluoro-6- [5 - oxa- nonyloxy] naphthalene

Beispiel 780Example 780

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5- oxa-nonyloxy]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5- oxa nonyloxy] naphthalene

Beispiel 781Example 781

2-(5-[3-Propyloxiran-2-carbonsäureester]-pyrimidin-2-yl)-3,4,5-trifl-uor-6-[5- oxa-nonyloxy]-naphthalin2- (5- [3-Propyloxiran-2-carboxylic acid ester] pyrimidin-2-yl) -3,4,5-trifl-uor-6- [5- oxa nonyloxy] naphthalene

Beispiel 782Example 782

2-(3-[3-Propyloxiran-2-carbonsäureester]-fluor-pyrimidin-6-yl)-3,4,5--trifluor-6- [5-oxa-nonyloxy]-naphthalin2- (3- [3-propyloxiran-2-carboxylic acid ester] -fluoropyrimidin-6-yl) -3,4,5 - trifluoro-6- [5-oxa-nonyloxy] naphthalene

Beispiel 783Example 783

2-(4-[3-Propyloxiran-2-carbonsäureester]-2,3-difluor-phenyl)-3,4,5-t-rifluor-6- [5-oxa-nonyloxy]-naphthalin.2- (4- [3-propyloxirane-2-carboxylic acid ester] -2,3-difluorophenyl) -3,4,5-t-rifluoro-6- [5-oxa-nonyloxy] naphthalene.

Claims (10)

1. 3,4,5-Trifluornaphthalin-Derivat der Formel (I), R¹(-M¹)a(-A¹)b(-M²)c(-A²)d(-M³)e-B(-M⁴)f(-A³)g(-M⁵)h(-A⁴)i(-M⁶)k-R² (I)in der die Symbole und Indizes folgende Bedeutungen haben:
die Gruppe B ist R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 20 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂- Gruppen durch -O-,-S-,-CO-O-,-O-CO-, -O-CO-O-, -CO-, -CS-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂-, 1,4-Phenylen, trans- 1,4-Cyclohexylen oder trans-1,3-Cyclopentylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome und/oder Schwefelatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -Br, -OR³, -SCN, -OCN oder -N₃ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch): R³, R⁴, R⁵, R⁶, R⁷ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen (mit oder ohne asymmetrisches C-Atom-, wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran-, Butyrolacton- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -S-,-CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO-S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂-O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH=CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂-CH₂- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan- 2,5-diyl, 1,3-Dithian-2,5-diyl, 1,3-Thiazol-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, 1,3-Thiazol-2,5-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Piperazin-1,4-diyl, Piperazin-2,5-diyl, Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Bicyclo[2.2.2]octan- 1,4-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, 1,3-Dioxaborinan-2,5-diyl oder die Gruppe B;
a, b, c, d, e, f, g, h, i, k sind null oder eins.1. 3,4,5-trifluoronaphthalene derivative of the formula (I), R¹ (-M¹) a (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (-A⁴) i (-M⁶) k -R² (I) in which the symbols and indices have the following meanings:
is group B. R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 20 C atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being substituted by -O -, - S -, - CO-O -, - O-CO-, -O-CO-O-, -CO-, - CS-, -CH = CH-, -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂-, 1,4-phenylene, trans-1,4-cyclohexylene or trans-1,3 -Cyclopentylene can be replaced, with the proviso that oxygen atoms and / or sulfur atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical are replaced by -F, -Cl, -Br, -OR³, -SCN , -OCN or -N₃ can be substituted, or one of the following groups (optically active or racemic): R³, R⁴, R⁵, R⁶, R⁷ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom, where also one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ can together also - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran, butyrolactone or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -S -, - CO-, -CO-O-, -O-CO-, -O-CO-O-, -CO- S-, -S-CO-, -CS-O-, -O-CS-, -S-CS-S-, -O-CS-O, -S-CO-S-, -CS-, -CH₂ -O-, -O-CH₂-, -CH₂-S-, -S-CH₂-, -CH = CH-, -C≡C-, -CH₂-CH₂-CO-O-, -O-CO-CH₂ -CH₂- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, 1,3 -Dithiane-2,5-diyl, 1,3-thiazole-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, 1,3-thiazole-2,5-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms by F, Cl and / or CN may be replaced, piperazin-1,4-diyl, piperazin-2,5-diyl, naphthalene-2,6-diyl, it being possible for one or more H atoms to be replaced by F, Cl and / or CN, bicyclo [2.2 .2] octane-1,4-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, 1,3-dioxaborinane-2,5-diyl or the group B;
a, b, c, d, e, f, g, h, i, k are zero or one. 2. Trifluornaphthalinderivat nach Anspruch 1, dadurch gekennzeichnet, daß die Symbole und Indizes in der Formel (I) folgende Bedeutungen haben:
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 18 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O-,-CO-,-CO-O-,-O-CO-, -O-CO-O-, -CH=CH-, -C≡C-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl, -OR³, -OCN oder -N₃ substituiert sein können, oder eine der nachfolgenden Gruppen (optisch aktiv oder racemisch): R³, R⁴, R⁵, R⁶, R⁷ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Oxiran-, Dioxolan-, Tetrahydrofuran-, Tetrahydropyran- oder Valerolacton-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O-, -CH₂-O-, -O-CH₂-, -CH=CH-, -C≡C- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrazin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridazin-3,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl, 1,3-Dioxan- 2,5-diyl, Thiophen-2,4-diyl, wobei ein H-Atom durch F, Cl und/oder CN ersetzt sein kann, Thiophen-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Naphthalin-2,6-diyl, wobei ein oder mehrere H-Atome durch F, Cl und/oder CN ersetzt sein können, oder die Gruppe B;
a, b, c, d, e, f, g, h, i, k sind null oder ein.2. trifluoronaphthalene derivative according to claim 1, characterized in that the symbols and indices in the formula (I) have the following meanings:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 18 C atoms (with or without an asymmetric carbon atom), one or more CH₂ groups also being substituted by -O -, - CO -, - CO-O -, - O-CO-, -O-CO-O-, -CH = CH- , -C≡C-, cyclopropane-1,2-diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F, -Cl, -OR³, -OCN or -N₃, or one of the following groups (optically active or racemic): R³, R⁴, R⁵, R⁶, R⁷ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-16 carbon atoms (with or without an asymmetric carbon atom), where also one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or wherein one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to an oxirane, dioxolane, tetrahydrofuran, tetrahydropyran or valerolactone system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -O-CS-O- , -CH₂-O-, -O-CH₂-, -CH = CH-, -C≡C- or a single bond;
A¹, A², A³, A⁴ are identical or different 1,4-phenylene, where one or more H atoms can be replaced by F, Cl and / or CN, pyrazine-2,5-diyl, one or two H- Atoms can be replaced by F, Cl and / or CN, pyridazine-3,6-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, trans-1,4- Cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) -Thiadiazol-2,5-diyl, 1,3-dioxane-2,5-diyl, thiophene-2 , 4-diyl, where an H atom can be replaced by F, Cl and / or CN, thiophene-2,5-diyl, where one or two H atoms can be replaced by F, Cl and / or CN, naphthalene -2,6-diyl, where one or more H atoms can be replaced by F, Cl and / or CN, or the group B;
a, b, c, d, e, f, g, h, i, k are zero or one. 3. Trifluornaphthalinderivat nach Anspruch 1 und/oder 2, dadurch gekennzeichnet, daß die Symbole und Indizes in der Formel (I) folgende Bedeutungen haben:
R¹, R² sind gleich oder verschieden Wasserstoff, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F oder ein geradkettiger oder verzweigter Alkylrest mit 1 bis 16 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine, zwei oder drei CH₂- Gruppen durch -O-, -CO-, -O-CO-, -CO-O-, -CH=CH-, Cyclopropan-1,2-diyl, -Si(CH₃)₂- oder trans-1,4-Cyclohexylen ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F, -Cl oder -OR³ substituiert sein können, oder auch eine der nachfolgenden Gruppen (optisch aktiv oder racemisch): R³, R⁴, R⁵ sind gleich oder verschieden Wasserstoff oder ein geradkettiger oder verzweigter Alkylrest mit 1-9 C-Atomen (mit oder ohne asymmetrisches C-Atom), wobei auch eine oder mehrere CH₂-Gruppen durch -O- und/oder -CH=CH- ersetzt sein können, mit der Maßgabe, daß Sauerstoffatome nicht unmittelbar miteinander gebunden sein dürfen, und/oder wobei ein oder mehrere H-Atome des Alkylrestes durch -F oder -Cl substituiert sein können; R⁴ und R⁵ können zusammen auch -(CH₂)₄- oder -(CH₂)₅- sein, wenn sie an ein Dioxolan-System gebunden sind;
M¹, M², M³, M⁴, M⁵, M⁶ sind gleich oder verschieden -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, -O-CH₂-, -CH=CH- oder eine Einfachbindung;
A¹, A², A³, A⁴ sind gleich oder verschieden 1,4-Phenylen, wobei ein, zwei oder drei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyridin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, Pyrimidin-2,5-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können, trans-1,4-Cyclohexylen, wobei ein oder zwei H-Atome durch CN und/oder CH₃ ersetzt sein können, (1,3,4)-Thiadiazol-2,5-diyl oder Naphthalin-2,6-diyl, wobei ein oder zwei H-Atome durch F, Cl und/oder CN ersetzt sein können;
a, b, c, d, e, f, g, h, i, k sind null oder eins.3. trifluoronaphthalene derivative according to claim 1 and / or 2, characterized in that the symbols and indices in the formula (I) have the following meanings:
R¹, R² are identical or different hydrogen, -CN, -F, -Cl, -CF₃, -CHF₂, -CH₂F, -OCF₃, -OCHF₂, -OCH₂F or a straight-chain or branched alkyl radical with 1 to 16 C atoms (with or without an asymmetric carbon atom), where also one, two or three CH₂ groups by -O-, -CO-, -O-CO-, -CO-O-, -CH = CH-, cyclopropane-1,2 -diyl, -Si (CH₃) ₂- or trans-1,4-cyclohexylene can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical are used by -F , -Cl or -OR³ may be substituted, or also one of the following groups (optically active or racemic): R³, R⁴, R⁵ are the same or different hydrogen or a straight-chain or branched alkyl radical with 1-9 carbon atoms (with or without an asymmetric carbon atom), with one or more CH₂ groups by -O- and / or -CH = CH- can be replaced, with the proviso that oxygen atoms must not be bonded directly to one another, and / or where one or more H atoms of the alkyl radical can be substituted by -F or -Cl; R⁴ and R⁵ together can also be - (CH₂) ₄- or - (CH₂) ₅- if they are bound to a dioxolane system;
M¹, M², M³, M⁴, M⁵, M⁶ are the same or different -O-, -CO-, -CO-O-, -O-CO-, -O-CO-O-, -CH₂-O-, - O-CH₂-, -CH = CH- or a single bond;
A¹, A², A³, A⁴ are the same or different 1,4-phenylene, where one, two or three H atoms can be replaced by F, Cl and / or CN, pyridine-2,5-diyl, one or two H atoms can be replaced by F, Cl and / or CN, pyrimidine-2,5-diyl, it being possible for one or two H atoms to be replaced by F, Cl and / or CN, trans-1,4-cyclohexylene, where one or two H atoms can be replaced by CN and / or CH₃, (1,3,4) -Thiadiazol-2,5-diyl or naphthalene-2,6-diyl, where one or two H atoms by F , Cl and / or CN can be replaced;
a, b, c, d, e, f, g, h, i, k are zero or one. 4. Trifluornaphthalinderivat nach einem oder mehreren der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die Gruppe (-A¹)b(-M²)c(-A²)d(-M³)e-B(-M⁴)f(-A³)g(-M⁵)h(A⁴)i eine der folgenden Bedeutungen hat: wobei die Abkürzungen
(F)ICH = 3,4,5-Trifluornaphthalin-2-6-diyl,
Phe = 1,4-Phenylen,
Pyr = Pyridin-2,5-diyl,
Pym = Pyrimidin-2,5-diyl,
Diox = 1,3-Dioxan-2,5-diyl,
Naf = Naphthalin-2,6-diyl,
F₂Phe = Difluorbenzol-1,6-diyl,
(F)Pyr = Fluorpyridin-2,5-diyl und
TDZ = (1,3,4)-Thiadiazol-2,5-diyl
bedeuten und M¹, M⁶, R¹, R² die in der Formel (I) angegebenen Bedeutungen haben.4. trifluoronaphthalene derivative according to one or more of claims 1 to 3, characterized in that the group (-A¹) b (-M²) c (-A²) d (-M³) e -B (-M⁴) f (-A³) g (-M⁵) h (A⁴) i has one of the following meanings: with the abbreviations
(F) ICH = 3,4,5-trifluoronaphthalene-2-6-diyl,
Phe = 1,4-phenylene,
Pyr = pyridine-2,5-diyl,
Pym = pyrimidine-2,5-diyl,
Diox = 1,3-dioxane-2,5-diyl,
Naf = naphthalene-2,6-diyl,
F₂Phe = difluorobenzene-1,6-diyl,
(F) Pyr = fluoropyridine-2,5-diyl and
TDZ = (1,3,4) thiadiazole-2,5-diyl
mean and M¹, M⁶, R¹, R² have the meanings given in the formula (I). 5. Verwendung von Trifluornaphthalinderivaten der Formel (I) nach einem oder mehreren der Ansprüche 1 bis 4 als Komponenten flüssigkristalliner Mischungen.5. Use of trifluoronaphthalene derivatives of the formula (I) according to one or more of claims 1 to 4 as components of liquid crystalline Mixtures. 6. Flüssigkristallmischung, enthaltend eine oder mehrere Verbindungen der Formel (I) nach einem oder mehreren der Ansprüche 1 bis 4.6. Liquid crystal mixture containing one or more compounds of Formula (I) according to one or more of claims 1 to 4. 7. Flüssigkristallmischung nach Anspruch 6, dadurch gekennzeichnet, daß sie ferroelektrisch ist.7. Liquid crystal mixture according to claim 6, characterized in that it is ferroelectric. 8. Flüssigkristallmischung nach Anspruch 6 oder 7, dadurch gekennzeichnet, daß sie 0, 1 bis 70 Mol-% einer oder mehrerer Verbindungen der Formel (I) enthält.8. Liquid crystal mixture according to claim 6 or 7, characterized in that that they contain 0.1 to 70 mol% of one or more compounds of the formula (I) contains. 9. Flüssigkristallmischung nach einem oder mehreren der Ansprüche 6 bis 8, dadurch gekennzeichnet, daß sie 1 bis 10 Verbindungen der Formel (I) enthält.9. liquid crystal mixture according to one or more of claims 6 to 8, characterized in that it contains 1 to 10 compounds of formula (I). 10. Schalt- und/oder Anzeigevorrichtung, enthaltend Trägerplatten, Elektroden, mindestens einen Polarisator, mindestens eine Orientierungsschicht sowie ein flüssigkristallines Medium, dadurch gekennzeichnet, daß das flüssigkristalline Medium eine Flüssigkristallmischung nach einem oder mehreren der Ansprüche 6 bis 9 ist.10. Switching and / or display device containing carrier plates, Electrodes, at least one polarizer, at least one orientation layer and a liquid-crystalline medium, characterized in that the  liquid crystalline medium a liquid crystal mixture according to one or more of claims 6 to 9.
DE19522195A 1994-06-20 1995-06-19 Stable 3,4,5-tri:fluoro-naphthalene derivs. useful in liquid crystal mixt. Granted DE19522195A1 (en)

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