DE193213C - - Google Patents
Info
- Publication number
- DE193213C DE193213C DENDAT193213D DE193213DA DE193213C DE 193213 C DE193213 C DE 193213C DE NDAT193213 D DENDAT193213 D DE NDAT193213D DE 193213D A DE193213D A DE 193213DA DE 193213 C DE193213 C DE 193213C
- Authority
- DE
- Germany
- Prior art keywords
- trinitrotoluene
- liquid
- dinitrotoluene
- percent
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 claims description 19
- 239000000015 trinitrotoluene Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- RMBFBMJGBANMMK-UHFFFAOYSA-N 2,4-Dinitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O RMBFBMJGBANMMK-UHFFFAOYSA-N 0.000 claims description 8
- 210000002268 Wool Anatomy 0.000 claims description 8
- 239000002360 explosive Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 241000251729 Elasmobranchii Species 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 2
- SNIOPGDIGTZGOP-UHFFFAOYSA-N 1,2,3-propanetrioltrinitrate Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000006011 modification reaction Methods 0.000 claims 1
- 240000008975 Styrax benzoin Species 0.000 description 6
- 235000000126 Styrax benzoin Nutrition 0.000 description 6
- 229960002130 Benzoin Drugs 0.000 description 3
- 235000015511 Liquidambar orientalis Nutrition 0.000 description 3
- 239000004870 Styrax Substances 0.000 description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 description 3
- 241000779819 Syncarpia glomulifera Species 0.000 description 3
- 229940036248 Turpentine Drugs 0.000 description 3
- 235000019382 gum benzoic Nutrition 0.000 description 3
- 239000001739 pinus spp. Substances 0.000 description 3
- 241000016649 Copaifera officinalis Species 0.000 description 2
- 241000218652 Larix Species 0.000 description 2
- 235000005590 Larix decidua Nutrition 0.000 description 2
- 240000004119 Melissa officinalis Species 0.000 description 2
- 235000010654 Melissa officinalis Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000865 liniment Substances 0.000 description 2
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N Benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- 241000182341 Cubitermes group Species 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 235000015912 Impatiens biflora Nutrition 0.000 description 1
- 241000218653 Larix laricina Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/001—Fillers, gelling and thickening agents (e.g. fibres), absorbents for nitroglycerine
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
193213 KLASSE 78 c. GRUPPE193213 CLASS 78 c. GROUP
CHRISTIAN EMIL BICHEL in HAMBURG.CHRISTIAN EMIL BICHEL in HAMBURG.
Es ist bekannt, daß das Trinitrotoluol sich sowohl in kristallinischer als geschmolzener, als auch in gepreßter Form seiner verschiedenen zweckmäßigen Eigenschaften wegen zur Füllung von Geschossen, Minen und Torpedos besonders gut eignet. Hierbei macht sich jedoch für die Verwendung, besonders in Geschossen, welche keine Bodenverschraubung besitzen und deren Mundloch enger alsIt is known that trinitrotoluene can be found in both crystalline and molten, as well as in pressed form because of its various useful properties It is particularly suitable for filling projectiles, mines and torpedoes. Here makes However, it is suitable for use, especially in floors that do not have a floor screw connection own and whose mouth hole is narrower than
ίο die Höhlung ist, der Übelstand bemerkbar, daß das Einbringen des Sprengstoffs ohne Hohlräume in gepreßter Form unmöglich, in gegossener Form schwierig und kristallinisch nur unter Staubbildung zu bewirken ist. Es war deshalb wünschenswert, unter Aufrechterhaltung der guten Eigenschaften des Trinitrotoluols, also besonders wegen seiner Unempfindlichkeit gegen Stoß und Schlag, seine Form dahin abzuändern, daß das einzufüllende Material bröckelig plastisch wird, so daß es sich bequem einbringen und feststampfen läßt.ίο the cavity is noticeable, the evil is noticeable, that the introduction of the explosive without cavities in pressed form impossible, in Cast form is difficult and crystalline to effect only with dust formation. It was therefore desirable while maintaining the good properties of trinitrotoluene, so especially because of its insensitivity to shock and impact, to change its shape so that what is to be filled Material becomes crumbly plastic, so that it can be conveniently brought in and tamped down leaves.
Es kam dabei erst in zweiter Linie in Frage, daß dabei ein geringer Verlust an Kraftäußerung eintrat, während es als vorteilhaft für die Minenwirkung angesehen werden muß, wenn die Detonationsgeschwindigkeit etwas herabgesetzt wurde.It was only a secondary question that there was a slight loss of strength occurred, while it must be regarded as beneficial for the mine effect, when the detonation speed has been reduced a little.
Zur Lösung der gestellten Aufgabe werden nach vorliegender Erfindung dem Trinitrotoluol feste, flüssige oder in Lösung gebrachte Harze allein für sich oder unter Beimengung von Dinitrotoluol zugesetzt, und zwar in der Weise, daß bei Anwendung flüssiger Harze, wie z. B. Kopaivabalsam, das kristallinische Trinitrotoluol mit oder ohne Erwärmung zu einem plastischen, gut detonierenden Sprengstoff in geeigneten Mischmaschinen umgearbeitet wird. Gleicherweise lassen sich Harze, welche in flüssigen Kohlen-Wasserstoffen gelöst sind, wie z. B. Lärchenterpentin, verwenden. Endlich kann man auch flüssige oder feste Harze, wie z. B. flüssigen Styrax oder Benzoeharz, mit sogenanntem flüssigen Dinitrotoluol vereinigen, und dieses Produkt mit Trinitrotoluol zu einem plastischen Sprengstoff verarbeiten.According to the present invention, trinitrotoluene is used to solve the problem solid, liquid or dissolved resins alone or with admixture of dinitrotoluene added, in such a way that when using liquid resins such. B. Kopaiva balm, that crystalline trinitrotoluene with or without heating to a plastic, well detonating Explosives are processed in suitable mixing machines. Likewise, resins can be found in liquid hydrocarbons are solved, such as B. larch turpentine, use. Finally, you can also use liquid or solid resins, such as. B. combine liquid styrax or benzoin with so-called liquid dinitrotoluene, and process this product with trinitrotoluene into a plastic explosive.
In allen diesen Fällen kann man die Plastizität noch dadurch erhöhen, daß man entsprechende Mengen von Kollodiumwolle hinzufügt, um eine gelatinöse Plastizität hervorzurufen. In all of these cases the plasticity can be increased by Add appropriate amounts of collodion wool to produce gelatinous plasticity.
Die vorgenannten Körper werden mit oder ohne Zusatz von Kollodiumwolle zunächst ohne Trinitrotoluol gemengt und längere Zeit unter Erwärmen in einem geeigneten Mischgefäß, z. B. in einem Werner & Pf leidererschen Mischtrog umgerührt, so daß sie eine dicke Flüssigkeit bilden. Diese letztere wird alsdann dem Trinitrotoluol hinzugefügt und nochmals im Mischgefäß so lange umgerührt, bis eine homogene bröckelig plastische Masse entsteht.The aforementioned bodies are initially with or without the addition of collodion wool without trinitrotoluene and mixed for a long time with warming in a suitable mixing vessel, z. B. stirred in a Werner & Pf unfortunately mixing trough so that they have a form thick liquid. The latter is then added to the trinitrotoluene and Stirred again in the mixing vessel until a homogeneous, crumbly plastic mass arises.
Geeignet für dieses Verfahren sind sämtliche Harze, sowohl feste wie flüssige und auch das sogenannte flüssige Dinitrotoluol, jedoch wird man gut tun, alle Materialien sorgfältig zu reinigen. Die Kollodiumwolle ■■All resins, both solid and liquid, are suitable for this process also the so-called liquid dinitrotoluene, but all materials will do well to clean carefully. The collodion wool ■■
kann man Sowohl dem Gemisch, welches die Plastizität hervorrufen soll, gleich zu Anfang beimischen oder aber, wenn man die gesamte Mischung noch einmal stärker erwärmt, auch nachträglich. Das fertige Produkt zeichnet sich bei richtig gewählten Mischungsverhältnissen dadurch aus, daß die bröckelig plastische Masse an den Werkzeugen, welche zum Füllen von Geschossen, Minen und TorpedosBoth the mixture that is supposed to produce the plasticity can be found right at the beginning Mix in or, if you heat the entire mixture again more strongly, also retroactively. The finished product is characterized by correctly selected mixing ratios characterized in that the crumbly plastic mass on the tools, which for Filling of projectiles, mines and torpedoes
ίο benutzt werden, nicht haften bleibt, sich gut ohne Hohlräume einstampfen läßt und als-ίο used, does not stick, looks good can be crushed without cavities and as-
, dann ein hohes kubisches Gewicht aufweist., then has a high cubic weight.
Solange das Trinitrotoluol den wesentlichsten Bestandteil des Sprengstoffs bildet, kann man die Mischungsverhältnisse so wählen, daß die Sprengkraft desselben gegen die des reinen Trinitrotoluols nur unerheblich geringer wird.As long as the trinitrotoluene forms the most essential component of the explosive, can you choose the mixing ratios so that the explosive power of the same against that of the pure trinitrotoluene is only insignificantly lower.
Beispiele seien angegeben:Examples are given:
a) 87 Prozent Trinitrotoluol,a) 87 percent trinitrotoluene,
13 - Kopäivabalsam;13 - Kopäiva balsam;
b) 87 Prozent Trinitrotoluol,
12 - Kopaivabalsam,b) 87 percent trinitrotoluene,
12 - Kopaiva balm,
ι ' - Kollodiumwolle.ι '- collodion wool.
a) 85 Prozent Trinitrotoluol,a) 85 percent trinitrotoluene,
15 - Lärchenterpentin;15 - larch turpentine;
b) 85 Prozent .Trinitrotoluol,b) 85 percent trinitrotoluene,
14 - Lärchenterpentin,
ι - Kollodiumwolle.14 - larch turpentine,
ι - collodion wool.
a) 85 Prozent Trinitrotoluol,a) 85 percent trinitrotoluene,
5 - flüssiger Styrax,5 - liquid styrax,
10 - flüssiges Dinitrotoluol;10 - liquid dinitrotoluene;
b) 85,0 Prozent Trinitrotoluol,b) 85.0 percent trinitrotoluene,
4,5 - flüssiger Styrax,4,5 - liquid styrax,
0,5 - Kollodiumwolle,0.5 - collodion wool,
10,0 - flüssiges Dinitrotoluol;10.0 - liquid dinitrotoluene;
c) 85 Prozent Trinitrotoluol,c) 85 percent trinitrotoluene,
5 - Benzoeharz,5 - benzoin,
Io - flüssiges Dinitrotoluol;Io - liquid dinitrotoluene;
d) 85,0 Prozent Trinitrotoluol,d) 85.0 percent trinitrotoluene,
4,5 - Benzoeharz,4,5 - benzoin,
0,5 - Kollodiumwolle,0.5 - collodion wool,
10,0 - flüssiges Dinitrotoluol.10.0 - liquid dinitrotoluene.
Claims (2)
Publications (1)
Publication Number | Publication Date |
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DE193213C true DE193213C (en) |
Family
ID=456470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT193213D Active DE193213C (en) |
Country Status (1)
Country | Link |
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DE (1) | DE193213C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1247701B (en) * | 1962-11-24 | 1967-08-17 | Basf Ag | Method for producing an incendiary device for performing the method for testing plastic parts for short-term exposure to high heat |
US5740782A (en) * | 1996-05-20 | 1998-04-21 | Lowi, Jr.; Alvin | Positive-displacement-metering, electro-hydraulic fuel injection system |
-
0
- DE DENDAT193213D patent/DE193213C/de active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1247701B (en) * | 1962-11-24 | 1967-08-17 | Basf Ag | Method for producing an incendiary device for performing the method for testing plastic parts for short-term exposure to high heat |
US5740782A (en) * | 1996-05-20 | 1998-04-21 | Lowi, Jr.; Alvin | Positive-displacement-metering, electro-hydraulic fuel injection system |
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