DE1916798A1 - Drawing ptfe coated wires in the cold - Google Patents
Drawing ptfe coated wires in the coldInfo
- Publication number
- DE1916798A1 DE1916798A1 DE19691916798 DE1916798A DE1916798A1 DE 1916798 A1 DE1916798 A1 DE 1916798A1 DE 19691916798 DE19691916798 DE 19691916798 DE 1916798 A DE1916798 A DE 1916798A DE 1916798 A1 DE1916798 A1 DE 1916798A1
- Authority
- DE
- Germany
- Prior art keywords
- coating
- alloys
- cold
- takes place
- plastic coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M7/00—Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C9/00—Cooling, heating or lubricating drawing material
- B21C9/02—Selection of compositions therefor
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/06—Perfluorinated compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/02—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen and halogen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/08—Solids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metal Extraction Processes (AREA)
Abstract
Description
Verfahren zum Drahtæiehen und Ziehen von Stählen und eisenhaltigen legierungen sowie nicht eisenhaltigen legierungen Die vorliegende Erfindung betrifft ein Verfahren zum Drshtziehen und zum Ziehen von Stählen und von Eisenlegierungen und Nicht-Eisenlegierungen Das Drahtziehen und das Ziehen von korrisionsfesten Stählen, feuerfesten Stählen, Eisen- und Nicht-Eisenlegierungen wird im allgemeinen ausgehend von einer schmierenden Trägerschicht durchgeführt.Process for wire drawing and drawing of steels and ferrous ones alloys and non-ferrous alloys The present invention relates to a method of twist drawing and drawing of steels and iron alloys and non-ferrous alloys Wire drawing and drawing of corrosion-resistant steels, Refractory steels, ferrous and non-ferrous alloys is generally used as a starting point carried out by a lubricating carrier layer.
Diese Trägerschichten können, ae nach dem zu verwirklichenden Verformungsgrad: metallische Stoffe (Blei, Kupfer usw.) oder chemische Verbindungen (Oxalate, Phosphate, oder dergl.) sein.These carrier layers can, depending on the degree of deformation to be achieved: metallic substances (lead, copper, etc.) or chemical compounds (oxalates, phosphates, or the like).
Diese Trägerschichten haben die folgenden Nachteile: a) bei ihrer Anwendung: schlechte Haftung, Unregelmäßigkeit der Auftragung, Giftigkeit, Veränderungen während der Einlagerung, Schwierigkeiten bei der Entfernung, und dergleichen.These backing layers have the following disadvantages: a) in their application: poor adhesion, irregular application, toxicity, Changes during storage, difficulties with removal, and the like.
b) in ihrer Wirksamkeit: mehr oder weniger begrenzte Verformungen, beschränkte Verformungsgeschwindigkeiten, körnige Oberflächen, Ungleichmäßigkeiten und dergleichen.b) in their effectiveness: more or less limited deformations, limited deformation speeds, grainy surfaces, irregularities and the same.
Gewisse Legierungen können wegen ihres Aushärtens bei relativ niedrigen Temperaturen nicht als Trägerstoffe für metallische Überzüge hoher Temperaturen dienen.Certain alloys can age at relatively low Temperatures are not used as carriers for high-temperature metallic coatings to serve.
Andere (insbesondere Titan und itanlegierungen) fressen sich mit den Trägerstoffen klassischer Schmiermittel.Others (especially titanium and itan alloys) eat their way with the Carriers of classic lubricants.
Diese Legierungen können nur unter Schwierigkeiten und immer unter hohen Kosten um das für ihre Verarbeitung notwendig Maß verformt werden.These alloys can only work with difficulty and always under high cost to be deformed to the extent necessary for their processing.
Aufgabe der Erfindung ist daher die Beseitigung dieser Nachteile, Vergrößerung der Geschwindigkeit beim Drahtsiehen und Ziehen und Verringerung des Herstellungspreises.The object of the invention is therefore to eliminate these disadvantages, Increasing the speed of wire drawing and pulling and reducing the Manufacturing price.
Zu diesem Zweck schafft die Erfindung ein Verfahren zum Draht ziehen und Ziehen von Stählen und Eisen-oder tTicht-Eisenverbindungen, das dadurch gekennzeichnet ist, daß das Ziehgut aus Stahl oder anderen Legierungen vorher mit einem örganischen Überzug aus einem Polytetrafluoräthylen (PTFE) oder einem Derivat versehen wird.To this end, the invention provides a method of drawing wire and drawing of steels and ferrous or non-ferrous compounds, which is characterized is that the drawing material made of steel or other alloys beforehand with an organic Coating made of a polytetrafluoroethylene (PTFE) or a derivative is provided.
Die Hauptvorteile dieses Verfahrens sind folgende: die Leichtigkeit seiner i)urchfirung, seine Konstanz, der geringe Preis des in zahlreichen Fällen verwendbaren Schmiermittels, wie Seife, Mineralöl und dergleichen, vergrößerte Verformungsgeschwindigkeiten, die Möglichkeit einer wesentlich größeren Querschnittsverminderung, die lange Lebensdauer der Ziehwerkzeuge, die IIögliclUkeit der Anwendung von Zieheisen aus Karbid anstatt von Zieheisen aus dem wesentlich kostspieligeren Dlamant, die sich wegen des außerordentlich geringeren Reibungskoeffizienten ergibt, die vollkommene Stabilität des Verfahrens, die im Gegensatz zu bestimmten bekannten Stoffen steht, wie z.3. Kupfer und Blei.The main advantages of this procedure are as follows: Ease of use its i) implementation, its constancy, the low price of the in numerous Cases of usable lubricants such as soap, mineral oil and the like Deformation speeds, the possibility of a significantly larger reduction in cross-section, the long service life of the drawing tools, the possibility of using drawing dies made of carbide instead of drawing iron from the much more expensive diamond, the results because of the extraordinarily lower coefficient of friction, the perfect one Stability of the process, which is in contrast to certain known substances, such as 3. Copper and lead.
Das Entfernen dieses Überzuges auf thermischem, chemischem (Säure, Lauge), elektrochemischem Wege oder mit Hilfe eines organischen Lösungsmittels nach dem Ziehen führt zu einer fühlbaren Vereinfachung der Fabrikationsschwierigkeiten und demsufolge zu einer Verringerung der Dauer des Herstellungsprozesses.The removal of this coating on thermal, chemical (acid, Lye), electrochemically or with the help of an organic solvent drawing leads to a noticeable simplification of the manufacturing difficulties and consequently a reduction in the duration of the manufacturing process.
Die Oberflächenbeschaffenheit der mit Hilfe dieses Überzuges geschaffenen Ziehprodukte ist deutlich besser, während die Haftung eines solchen Kunststoffuberzuges, im Gegensatz zu der einer der oben beschriebenen klassischen Trägerschichten, keine vorausgehenden Befestigungsverfahren oder Beizverfahren erfordert, die immer vom Gesichtspunkt des Endproduktes aus nachteilig sind.The surface quality of the created with the help of this coating Drawn products is significantly better, while the adhesion of such a plastic coating, in contrast to one of the classic carrier layers described above, none requires prior fastening or pickling processes, which are always dated Are disadvantageous from the point of view of the end product.
che Industrien, welche gezogene, drahtgezogene oder gewikkelte Produkte verarbeiten, verlangen eine vorherige Oberflächenbehandlung, damit eine Endbearbeitung möglich wird: dies ist insbesondere der Fall bei der Herstellung von Federn.certain industries, which include drawn, wire-drawn or wound products process, require a previous surface treatment, thus a final processing becomes possible: this is especially the case in the manufacture of springs.
Die organischen Überzüge aus PTFE oder dessen Derivaten erlauben im allgemeinen die Lösung der gestellten Probleme durch die direkte Anwendung eines Überzuges, dessen Verformbarkeit und Regelmäßigkeit eine besonders leichte Verformung gewährleisten.The organic coatings made of PTFE or its derivatives allow im generally solving the problems posed the direct Application of a coating, its deformability and regularity a special one ensure slight deformation.
Zum besseren Verständnis der Erfindung wird im folgenden als nicht begrenzendes Ausführungsbeispiel ein vollständiger Ziehvorgang geschrieben, der gemäß dem den Gegenstand der Erfindung bildenden Verfahren durchgeführt ist.For a better understanding of the invention, the following is considered as not limiting embodiment written a complete drawing process that is carried out according to the process forming the subject of the invention.
Bei diesem Beispiel handelt es sich darum, ein Profil aus Stahl mit der folgenden Zusammensetzung: C = 0,10 , Itn = 1,02 1 Si = 0,73 %, Ni = 8,1 %, Cr = 17,3 %, von 5,5 mm Stärke auf 3,2 mm Stärke zu ziehen.In this example it is a question of using a steel profile of the following composition: C = 0.10, Itn = 1.02 1 Si = 0.73%, Ni = 8.1%, Cr = 17.3%, to be drawn from a thickness of 5.5 mm to a thickness of 3.2 mm.
Dieser Draht wird vorher mit einer mehrere Tausendstel Millimeter (einige >1) dicken Schicht Polytetrafluoräthylen überzogen, welches einfach während des Durchlaufens durch ein Bad aufgebracht und anschließend ebenfalls während des Durchlaufens bei etwa 100 0 C polymerisiert wird. Die Drahtziehgeschwindigkeit beträgt 12 m/Min.This wire is previously made with a thickness of several thousandths of a millimeter (some> 1) thick layer of polytetrafluoroethylene coated which simply during applied by passing through a bath and then also during the Is polymerized at about 100 0 C run through. The wire drawing speed is 12 m / min.
Man beginnt dann mit dem Ziehen, das unter den folgenden Bedingungen vorgenommen wird: Der Grad der Kaltverformung zwischen zwei Stichen liegt etwa bei 32 % anstatt bei höchstens 18 nach dem klasstschen Verfahren.One then begins pulling under the following conditions is carried out: The degree of cold deformation between two stitches is approximately 32% instead of a maximum of 18 according to the klasst method.
Die Ziehgeschwindigkeit beträgt 170 m/Min. mindestens anstatt 80 m/Nin. höchstens bei bekannten Verfahren.The pulling speed is 170 m / min. at least instead of 80 m / Nin. at most with known processes.
Das Ziehwerkzeug aus Wolframkarbid kostet viel weniger als ein Ziehwerkzeug aus Diamant. Bei dem erfindungsgemäßen Verfahren ist seine Lebensdauer mindestens dreimal so groß wie die Lebensdauer eines Ziehwerkzeuges gleicher BaschaffenheSt, welches nicht gemaß der Erfindung verwendet wird.The tungsten carbide drawing tool costs much less than a drawing tool made of diamond. In the method according to the invention, its service life is at least three times as long as the service life of a drawing tool of the same basic type, which is not used according to the invention.
Das Entfernen des Überzuges findet entweder in basischer Umgebung ( 20 - 80 Gewichtsanteile) in der Hitze (bei 50 - 80 Grad C) statt, oder in saurer Umgebung (Nitrofluorwasserstoff: 10 bis 30 % Salpetersäure, 2 bis 10 % Fluorwasserstoffsäure) in der Hitze (bei 50 - 80 Grad C) statt.The removal of the coating takes place either in a basic environment ( 20 - 80 parts by weight) in the heat (at 50 - 80 degrees C), or in sour Environment (hydrofluoric acid: 10 to 30% nitric acid, 2 to 10% hydrofluoric acid) in the heat (at 50 - 80 degrees C).
Der Draht weist danach eine vollkommene Oberflächenbeschaffenheit auf.The wire then has a perfect surface finish on.
- Patentansprüche: - - Patent claims: -
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR146867 | 1968-04-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1916798A1 true DE1916798A1 (en) | 1969-11-06 |
Family
ID=8648540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19691916798 Pending DE1916798A1 (en) | 1968-04-03 | 1969-04-01 | Drawing ptfe coated wires in the cold |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE730806A (en) |
DE (1) | DE1916798A1 (en) |
FR (1) | FR1570609A (en) |
LU (1) | LU58326A1 (en) |
NL (1) | NL6905118A (en) |
-
1968
- 1968-04-03 FR FR146867A patent/FR1570609A/fr not_active Expired
-
1969
- 1969-03-28 LU LU58326D patent/LU58326A1/xx unknown
- 1969-03-31 BE BE730806D patent/BE730806A/xx unknown
- 1969-04-01 DE DE19691916798 patent/DE1916798A1/en active Pending
- 1969-04-02 NL NL6905118A patent/NL6905118A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
BE730806A (en) | 1969-09-01 |
FR1570609A (en) | 1969-06-13 |
LU58326A1 (en) | 1969-07-15 |
NL6905118A (en) | 1969-10-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
SH | Request for examination between 03.10.1968 and 22.04.1971 |