DE1804962A1 - Device for generating a constant overpressure in high-pressure gas electrodes for electrometric measurements in measuring media with fluctuating pressure - Google Patents

Device for generating a constant overpressure in high-pressure gas electrodes for electrometric measurements in measuring media with fluctuating pressure

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Publication number
DE1804962A1
DE1804962A1 DE19681804962 DE1804962A DE1804962A1 DE 1804962 A1 DE1804962 A1 DE 1804962A1 DE 19681804962 DE19681804962 DE 19681804962 DE 1804962 A DE1804962 A DE 1804962A DE 1804962 A1 DE1804962 A1 DE 1804962A1
Authority
DE
Germany
Prior art keywords
pressure
generating
constant
overpressure
measuring media
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19681804962
Other languages
German (de)
Other versions
DE1804962C3 (en
DE1804962B2 (en
Inventor
Eberhard Michel
Dipl-Ing Karl-Heinz Papst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Priority to DE1804962A priority Critical patent/DE1804962C3/en
Publication of DE1804962A1 publication Critical patent/DE1804962A1/en
Publication of DE1804962B2 publication Critical patent/DE1804962B2/en
Application granted granted Critical
Publication of DE1804962C3 publication Critical patent/DE1804962C3/en
Expired legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/36Glass electrodes
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D16/00Control of fluid pressure
    • G05D16/14Control of fluid pressure with auxiliary non-electric power
    • G05D16/18Control of fluid pressure with auxiliary non-electric power derived from an external source
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D16/00Control of fluid pressure
    • G05D16/028Controlling a pressure difference

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Automation & Control Theory (AREA)
  • Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Measuring Fluid Pressure (AREA)

Description

Einrichtung zur Erzeugung eines konstanten Überdrucks in Hochdruck-Glaselektroden für elektrometrische Messungen in Meßmedien schwankenden Drucks Dic Erfindung betrifft eine Einrichtung zur Erzeugung eines konstanten Überdrucks in Hochdruck-Glaselektroden für elektrometrische Messungen in Meßmedien schwankenden Drucks In derartigen Glas elektroden muß der Innendruck stets um einen kleinen Betrag höher scin als der Druck des MeEmediums, um das Eindringen des Meßmediums durch das Glasdiaphragma in die Elektroden zu verhindern. Bei einer Reihe von Anwendungsfällen schwankt jedoch der Druck des Meßmediums in größerem Umfang häufig um mehr als 100 . Es kann dabei der Ball austreten, daß der Druck des Meßmediums höher liegt als der Innendruck der Glaselektrode, so daß das Medium in die Elektrode eindringt und die Messung stört, andererseits kann der Druck des Meßmediums auch so weit absinken, daß der Innendruck zu groß wird und die Elektrode zerstört.Device for generating a constant overpressure in high-pressure glass electrodes for electrometric measurements in measuring media of fluctuating pressure Dic invention relates a device for generating a constant overpressure in high-pressure glass electrodes for electrometric measurements in measuring media with fluctuating pressure in such glass electrodes, the internal pressure must always be a small amount higher than the pressure of the MeE medium to prevent the measuring medium from penetrating through the glass diaphragm into the To prevent electrodes. In a number of use cases, however, the fluctuates Pressure of the measuring medium to a large extent, often by more than 100. It can be the Ball emerge that the pressure of the measuring medium is higher than the internal pressure of the Glass electrode, so that the medium penetrates the electrode and interferes with the measurement, on the other hand, the pressure of the measuring medium can also drop so far that the internal pressure becomes too big and destroys the electrode.

Es besteht daher die Aufgabe, den Überdruck in Hochdruck-Glaselektroden konstant zu halten und ihn zu diesem Zwecke von den Druckschwankungen des Meßmediums her mit cinfacnen Mitteln zu führen.There is therefore the task of reducing the overpressure in high-pressure glass electrodes to keep constant and for this purpose from the pressure fluctuations of the measuring medium to conduct it with cinfacnene means.

Als Lösung der Aufgabe wird eine Einrichtung gemäß der Erfindung zur Erzeugung eines konstanten Überdrucks in Hochdruck-Glaselektroden zu elektrometrische Messungen in i4eßmedien schwankenden Drucks vorgeschlagen, die gekennzeichnet ist durch einen Durchflußregler zur Konstanthaltung einer dem Meßmedium ständig zugefUhrten Gasmenge; einer einstellbare Drossel zur Erzeugung eines Differenzdrucks in der geregelten Strecke der Gasleitung; eine Verbindungsleitung des Innenraums der Glaselektrode mit der Seite höheren Drucks der Drossel in der Gasleitung.As a solution to the problem, a device according to the invention is used Generating a constant overpressure in high pressure glass electrodes to electrometric Measurements in measuring media of fluctuating pressure are suggested, which is marked by means of a flow regulator to keep a constant one of the medium to be measured Amount of gas; an adjustable throttle to generate a differential pressure in the regulated stretch of gas pipe; a connecting line of the interior of the glass electrode with the higher pressure side of the throttle in the gas line.

Die Erfindung wird anhand des in der Figur dargestellten schematischen Ausführungsbeispiels wie folgt erläutert.The invention is based on the schematic shown in the figure Embodiment explained as follows.

In einer Rohrleitung 1 wird als Meßmedium beispielsweise Faulschalmm gefördert, dessen pH-Wert mittels der Meßelektrode 2, die über den Meßverstärker 3 auf das Registriergerät 4 arbeitet, gemessen werden soll. Zum einwandfreien Bctricb der pH-Wert-Meßeinrichtung ist es nötig, daß im Innern der Glaselektrode ein leichter Überdruck gegenüber dem MeEmcdium herrscht. Da der Druck in der Rohrleitung 1 stark schwankt, beispielsweise zwischen 10 und 20 kp/cm2, rnuß der Überdruck in der Elektrode 2 vom Druck des Meßmediums her geführt werden. Zu diesem Zcck ist eine Gasleitung 5 vorgesehen, in der ein mechanischer Regler R, der den Durchfluß des Gases auf einem konstanten möglichst niedrigen Wert hält, der zwischen 1,5 und 2 Nl/h liegt, und die einstcllbarc Drosscl 6, beispielsweise ein Nadelventil, angeordnet sind. Die Leitung 5 führt ein mit dem Meßmedium nicht reagierendes Gas, beispielsweise Stickstoff, mit einem Druck, der höher liegt als der höchste vorkommendc Druck in der Rohrleitung 1. Der vom Regler R eingestellte konstante Durchfluß ist so gering, daß das Gas gerade in das Meßmedium einperlt. Bs herrscht an dr Mündung und damit auch an der der Mündung zugekehrten Seite der Drossel 6 etwa der Druck des Meßmediums. Mittels der einstellbaren Drossel 6 kann unter Zuhilfenahme des Anzeigeinstruments 7 ein Differenzdruck # p eingestellt werden, der dem gewünschten Überdruck in der Glaselektrode 2 entspricht.In a pipeline 1, for example, foul noise is used as the measuring medium promoted, its pH value by means of the measuring electrode 2, which is via the measuring amplifier 3 works on the recording device 4, is to be measured. To the impeccable Bctricb the pH value measuring device, it is necessary that a light inside the glass electrode There is overpressure compared to the MeEmcdium. Since the pressure in the pipe 1 is strong if the overpressure in the electrode fluctuates, for example between 10 and 20 kp / cm2 2 are guided by the pressure of the medium to be measured. For this purpose there is a gas pipe 5 provided, in which a mechanical regulator R, which controls the flow of the gas keeps a constant as low as possible value between 1.5 and 2 Nl / h, and the adjustable throttle 6, for example a needle valve, are arranged. The line 5 carries a gas which does not react with the medium to be measured, for example Nitrogen, at a pressure higher than the highest pressure occurring in of the pipeline 1. The constant flow rate set by the regulator R is so low that that the gas is just bubbling into the measuring medium. Bs prevails at the mouth and with it also on the side of the throttle 6 facing the mouth, approximately the pressure of the medium to be measured. By means of the adjustable throttle 6, with the aid of the display instrument 7 a differential pressure # p can be set which corresponds to the desired overpressure in the Glass electrode 2 corresponds.

Der Differenzdruck # p liegt bei dem Ausführungsbeispiel bei etwa 0,5 bis 2 kp/cm² je nach Ausführung der Glaselektrode. Die Seite höheren Drucks der geregelten Strecke der Gasleitung 5 ist mit dem Inneren der Glaselektrode 2 über die Leitung 7 verbunden. Es herrscht also bei allen Druck schwankungen des Meßmedums ein dem eingestellten Differenzdruck # p entsprechender Überdruck im Innern der Elektrode 2. Als Regler R kann ein mechanischer Durchflußregler vorgesehen worden, so daß der Aufwand für die gesamteEinrichtung zur Konstanthaltung des Überdrucks in der Hochdruck-Glaselektrodo 2 sehr klein gehalten wcrden kann.In the exemplary embodiment, the differential pressure # p is approximately 0.5 to 2 kp / cm² depending on the design of the glass electrode. The side of higher pressure the regulated distance of the gas line 5 is with the interior of the glass electrode 2 connected via line 7. So there are fluctuations in all pressure Measurement medium an overpressure in the interior corresponding to the set differential pressure # p of electrode 2. A mechanical flow regulator can be provided as regulator R, so that the effort for the entire facility to keep it constant the overpressure in the high-pressure glass electrode 2 can be kept very small.

1 Patentanspruch 1 31. Zelchnungen1 Claim 1 31. Invoices

Claims (1)

Patentanspruch Einrichtung zur Erzeugung eines konstanten Überdrucks in Hochdruck-Glaselektroden für elektrometrische Messungen in Meßmedien schwankenden Drucks, g c k e n n z e i c h -net durch einen Durchflußregler (R) zur Konstanthaltung eincr dem Meßmedium ständig zugeführten Gasmenge; eine einstellbare Drossel (6) zur Erzeugung eines Differenzdrucks # p in der geregelten Strecke der Gaslcitung (5); eine Verbindungsleitung (7) des Innenraums der Glaselektrode (2) mit der Seite höheren Drucks der Drosscl (6) in der Gasleitung (5). Device for generating a constant overpressure in high pressure glass electrodes for electrometric measurements in measuring media fluctuating Pressure, g c k e n n z e i c h -net by a flow regulator (R) to keep it constant an amount of gas constantly supplied to the medium to be measured; an adjustable throttle (6) to generate a differential pressure # p in the regulated section of the gas line (5); a connecting line (7) of the interior of the glass electrode (2) with the side higher pressure of the throttle (6) in the gas line (5).
DE1804962A 1968-10-24 1968-10-24 Device for generating a constant overpressure in high-pressure glass electrodes for electrometric measurements Expired DE1804962C3 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE1804962A DE1804962C3 (en) 1968-10-24 1968-10-24 Device for generating a constant overpressure in high-pressure glass electrodes for electrometric measurements

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1804962A DE1804962C3 (en) 1968-10-24 1968-10-24 Device for generating a constant overpressure in high-pressure glass electrodes for electrometric measurements

Publications (3)

Publication Number Publication Date
DE1804962A1 true DE1804962A1 (en) 1970-06-11
DE1804962B2 DE1804962B2 (en) 1974-06-12
DE1804962C3 DE1804962C3 (en) 1975-01-30

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ID=5711403

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1804962A Expired DE1804962C3 (en) 1968-10-24 1968-10-24 Device for generating a constant overpressure in high-pressure glass electrodes for electrometric measurements

Country Status (1)

Country Link
DE (1) DE1804962C3 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1427194B1 (en) * 1960-07-27 1970-05-27 Peddinghaus Paul Ferd Fa Hold-down device for profile steel scissors with knife slots at right angles to each other
DE4035447A1 (en) * 1990-10-29 1992-04-30 Forsch Kurt Schwabe Meinsberg Pressure-compensating electrode holder - esp. for potentiometric measuring systems and electrochemical gas sensors

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1427194B1 (en) * 1960-07-27 1970-05-27 Peddinghaus Paul Ferd Fa Hold-down device for profile steel scissors with knife slots at right angles to each other
DE4035447A1 (en) * 1990-10-29 1992-04-30 Forsch Kurt Schwabe Meinsberg Pressure-compensating electrode holder - esp. for potentiometric measuring systems and electrochemical gas sensors
DE4035447C2 (en) * 1990-10-29 1999-07-01 Kurt Schwabe Inst Fuer Mes Und Electrode holder for pressure compensation on electrochemical measuring systems

Also Published As

Publication number Publication date
DE1804962C3 (en) 1975-01-30
DE1804962B2 (en) 1974-06-12

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E771 Valid patent as to the heymanns-index 1977, willingness to grant licences
EHJ Ceased/non-payment of the annual fee