DE1769483A1 - Mixture for treating textiles and method for treating textiles with this mixture - Google Patents

Description

Dr. Walter Beil
Alfred Hiieppener May 29, 1968

'Rcch'r ..- :: iwä!'. See below: - i.ire

DrI. ::.; Jordrä Wolff Dr. U: -.;: -, Car. ax

Frankfurt a. M.-Höchst

Adeionstrasse 58 - Tel. 301024

Our no.14643

The Procter & Gamble Company Cincinnati, OMo, V.3t.A.

Mixture for treating textiles and method for treating textiles with this mixture .

The invention relates to a mixture of a water-dispersible reaction product of a primary alkyl amine with about 12 to 30 carbon atoms in the alkyl chain with about 1.25 to 2 moles of epichlorohydrin per mole of amine, an additive of borax, urea, anionic detergent or mixtures thereof, optionally a strongly alkaline compound such as Sodium hydroxide, and from water as the remainder and a method for treating fibrous materials, in particular with anionic, optical brighteners treated textiles with this mixture.

The addition of long alkyl chain fractions to fibrous materials takes place, among other things.

a) to improve the fiber-fiber and faner-metal greasing (Lubricity;;

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b) for softening and

c) to increase the water-repellent properties.

In order to achieve this in an economical manner ^1, the application of the product from aqueous media is highly desirable. It is also important that the product applied to the Paser material does not adversely affect the fabric, that is to say that it does not, for example, cause it to yellow or lose strength.

The invention now relates to mixtures for the treatment of textile fabrics, in particular those mixtures which are in the concurrent German patent application P 41446 IV b / 12 qu are revealed. The condensation products of amines and long alkyl chains and epichlorohydrin, as in this one co-pending application are described are far superior to similar, known compounds, as they do not cause the textiles to yellow to the same extent as the previously known compounds. But even these can superior products, some fibers will yellow slightly when used in concentrations that have a lasting emollient effect.

The aim of the invention is therefore to provide improved textile treatment items using Amine-epichlorohydrin reaction products, i.e. of mixtures, which have a reduced yellowing effect on the fibrous materials treated with them.

The cited mixtures of the concurrent registration as well as other amine-epichlorohydrin condensation products are normally most strongly fixed on the fiber when they are applied with alkaline, inorganic catalysts. However, the use of large JVI closely s at such alkaline inorganic catalysts slightly reduced softening effect of the condensation products to the textile material a result, even before it is first i ^v ial washed. Furthermore, the al -

1 Π 9 8 U 3/1 1 4 9

kaiischen, inorganic catalysts intensify the yellowing of the treated fibers.

It is therefore another object of the invention to provide improved compositions that are easy to adopt Add fiber and have better, immediate softening effects (Initial softness).

The textile treatment according to the invention have the following components:

1) about 0.01 to 99 % of a water-dispersible reaction product of a primary alkylamine with about 12 to 30 carbon atoms in the alkyl chain and about 1.25 to 2 moles of epihlorohydrin per mole of amine,

2) about 0.0005 % to 95% of one or other of the following additives:

a) borax,

b) anionic detergent,

c) urea.

3) based on 1), 0 to about 10 wt .- $ of an emulsifier for 1), in the form of the condensation product of a fatty alcohol with 9 to about 18 carbon atoms with about 10 to 60 mol of ethylene oxide or the condensation product of an alkylphenol with about 9 to 15 carbon atoms in the alkyl group having 10 to about 15 moles of ethylene oxide per mole of _t Alkylphehol;

4) 0 to about 20 % of a strongly alkaline compound, for example alkali metal hydroxides, silicates or carbonates or ammonium hydroxide, and

5) water as the rest.

1098A3 / 17Ä9

As amine-epichlorohydrin reaction products, the products described in the above-mentioned, concurrent German patent application P 41446 IV b / 12 qu are preferred. These reaction products are prepared at a temperature between about 27 and 93 ° C. within a reaction time of about 30 minutes to 10 hours and they are neutralized to an acid number of below about 30, preferably between about 5 and 15. This neutralization he follows about 16 to 66 ^° C. Other similar reaction products can also be used, but better color is achieved on the treated fibrous materials with the preferred products. In addition, as stated below, the resulting textile material is further improved by the effects of the additives according to the invention.

For the preparation of the present reaction products, primary alkylamines can be used whose alkyl group from naturally occurring glycerides (e.g. sebum, Coconut oil, palm oil, soybean oil, pork fat, etc.) or can be obtained from petroleum sources and / or olefins such as ethylene polymers. The source is not authoritative. But exist the preferred alkyl groups from primarily straight-chain fractions. There can also be branched-chain alkyl groups or alkyl groups with cydoalipha ti see proportions are used will. The amino group can be attached at any point in the chain, but it is preferably at a terminal point Carbon atom bonded. Mixtures of amines are preferred. Specific examples of amines are dodecyl, tetradecyl, hexadecyl, octadecyl, pentapropylene, hexapropylene, Dodecylcyclohexyl, 12-cyclohexyldodecyl, eicosyl and Docosylamine.

The structure of this reaction product is not known. It seems to be a relatively complex one Act mixture. Similar reaction products as described above contain epoxy groups, but it has been demonstrated that epoxy groups reduce the effectiveness of the fiction, contemporary Affect the reaction product.

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Mixtures suitable for treating textiles normally comprise about 0.05 to 5 wt .- # of the amine-epichlorohydrin reaction product, preferably about 0.05 Ms 1 # of this product, namely if soft fibers are desired. If impregnation is to take place, the mixtures preferably contain about 1 to 5 % of the amine-epichlorohydrin reaction product. Mixtures containing more than this amount are usually diluted with water, while those mixtures containing less than 0.05 % of the reaction product generally result in a diminished effect. But there are more dilute ones

Mixtures for repeated application by exhausting a dormant fleet using relatively long, e.g. about 5 to 30 minutes of dwell times.

The additives according to the invention, which are combined with the amine-epichlorohydrin reaction products described above are for the softening of the fabric at the beginning as well as in the washed state and / or for the color value of the treated fiber is an advantage. The additives can be added together or separately, but correspond the benefits of each additive when used together with other additives in some cases, as below explained, not the advantages that are inherent in the additives when used alone. Below are the different Additions described:

As in the concurrent application P 41446 IV b / 12 qu carried out, strongly alkaline compounds such as alkali metal hydroxides or carbonates and ammonium hydroxide as catalysts to accelerate the conversion of the amine-epiohlorohydrin reaction products with the textile material to be treated, e.g. for more sustainable softness will. It has now been found that borax can be used together with these more alkaline catalysts, practically the same lasting softness is achieved as when using the strongly alkaline one on its own

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aiii w /.

Catalyst, but now the pH of the aqueous Solution is kept at a lower level, so that the tissue and any existing on it, alkaline less damage to sensitive dyes or additives will. Borax can also be used as the catalyst itself, thereby reducing the application of the reaction product on the fibers at a lower pH value and good, sustainable softness can be achieved. When using borax as a catalyst, either alone or in conjunction with more alkaline catalysts, an improved color value of the treated textiles is also achieved.

As will be discussed in more detail, borax and urea can be used in conjunction with one another in order to achieve certain, not obvious advantages. Albeit through the use of borax the The color of the treated fibers seems to be improved to some extent, but the combined use of borax and urea a greater increase in the color value and the softness of the treated textile goods. Usually borax is used in an amount based on the amine - epichlorohydrin reaction product, from about 50 to 150 wt. Amounts below 25 wt. # Will not provide adequate buffering for the achievement of a good, lasting softness, while concentrations above 250 wt .- # have no advantages in terms of bring an improved, permanent softness, while the initial softness of the treated material continues affect. High concentrations of borax also have a negative effect on the slipperiness required for mowing and at high temperatures easily promote yellowing of the treated textile material.

Anionic detergents suitable according to the invention include conventional, water-soluble soaps with carboxyl groups. The cation of the anionic detergents can be used in Form of any water-soluble cation, see B. as an alkali metal cation such as sodium, potassium, ammonium or

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substituted Afflfflonium cation (mono-, di- and triethanolammonium cation) are present. As suitable fatty acid mixtures for the production of the soaps according to the invention For example, those of U.S. Patents 2,954,347-8 can be used. Preferred fatty acids are derived Coconut oil or tallow, e.g. caprylic, oapric, lauric, myristic, palmitic and stearic acid. The soaps contain about 8 to about 18 carbon atoms.

Anionic synthetic detergents are particularly preferred. This class of synthetic detergents can generally be used as water-soluble salts, in particular alkali metal salts of organic sulfuric acids Define reaction products, the latter being an alkyl radical with about 8 to 22 carbon atoms in the molecular structure and a residue of a sulfonic acid or sulfuric acid ester. See from the group of syntheti Detergents are the compounds listed below as examples of importance; so belong to the mixtures preferred according to the invention: sodium or potassium alkyl sulfates, in particular those in sulfation the higher alcohols produced by reducing glycerides obtained from tallow or coconut oiliv sodium or potassium alkylbenzenesulfonates, the alkyl group of which is in In the form of a straight or branched chain with about 9 to 15 carbon atoms, in particular the sulfonates U.S. Patents 2,220,099 and 2,477,383; sulfonated α-olefins having from about 12 to about 18 carbon atoms, Hatriumalkylglyceryläthersulfonate, especially the ethers of the higher, derived from tallow and coconut oil Alcohols; Sodium coconut oil fatty acid monoglyceride sulfate and sulfonates; Sodium or potassium salts of sulfuric acid esters of the reaction product of 1 mole of a higher fatty alcohol (e.g. tallow or coconut oil alcohols) and about 3 moles of ethylene oxide; Sodium or potassium salts of alkylphenol ethylene oxide ether sulfates, the approximately 4 Å "ethylene oxide units 3β molecule and their alkyl radicals about

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Carry 9 carbon atoms; the reaction product of with Isethionic acid esterified and neutralized with sodium hydroxide fatty acids derived e.g. from coconut oil are; Sodium or potassium salts of fatty acid amides of a methyl taurine, the fatty acids for example come from coconut oil; as well as other known substances, some of which are described in U.S. Patents 2,486,921, 2,486,922 and 2,396,278 are specifically listed.

As desired, the alkyl groups contained in the surface-active detergents mentioned can be straight or branched chain and saturated or unsaturated be. The above compilation of surface-active detergents is exemplary, but not restrictive.

These anionic detergents perform when used with the amine-epichlorohydrin reaction products described above to an improvement of the color value of the treated fibers. This preference then falls especially when the treated textiles were also treated with anionic optical brighteners became. The anionic detergent initially improves the color value of the treated textiles, and it improves it even if the fiber has naturally aged, exposed to heat, e.g. in drying or accelerated aging tests, with ultraviolet Irradiated light and / or exposed to nitrogen oxides became.

If large quantities of anionic detergents are used together with urea, this becomes as follows stated the effectiveness of the urea in improving initial softness slightly reduced, but in the absence of urea the initial softness is somewhat promoted as soon as a inorganic catalyst is present.

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As it seems, the optimal amount is anionic Detergent one mole per mole of amine or quaternary ammonium group in the amine-epichlorohydrin reaction products. With concentrations of only a quarter of the stated amount one achieves an improvement in the color value of the treated textiles, during quantities that exceed a molar ratio of 2.5: 1, there is no further noticeable improvement, but the softness of the treated fiber material affect.

The addition of the anionic detergent to the amine-Bpichiorhydrin Reaktiοnsprodukt containing mixture, as well as the reverse addition, should be carried out slowly, in order to avoid the precipitation of a complex compound.

When urea and the amine-epichlorohydrin reaction products are used together, a strong Increased the initial softness of the treated textile material. This increase is particularly noticeable when an inorganic catalyst such as sodium hydroxide and / or borax to achieve improved, sustainable softness is used.

In contrast, urea does not increase the initial softness when, as already explained, large amounts an anionic detergent can also be used.

In addition to the noticeable increase in the initial weakness achieved in the presence of inorganic catalysts using urea in conjunction with borax, an anionic detergent, or both strong improvement of the color value of the treated textile fabric, especially when an anionic optical brightener is used to treat the fabric.

When using urea with the amine-epichlorohydrin reaction product provides the to achieve gUnatigeter

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Results required amount of urea is a critical factor. It was found that for optimal initial softness, based on the amount of amine-Bpichlorhydrin reaction product, 2000 wt .- # urea should be used. At a percentage of approximately 1300 wt .- # a complete drop of the initial softness occurs during at 3000 wt - also starts to drop fully% the initial softness..

The strongly alkaline catalysts used for the mixtures according to the invention are normally alkali metal hydroxides and carbonates and ammonium hydroxide are used. However, other alkaline catalysts can also be used will.

Alkaline catalysts should only be added to mixtures that are to be used as soon as possible, because we will If the product is stored for longer than a few hours, these catalysts tend to form excessively large quantities of epoxy groups in the amine-epichlorohydrin reaction product.

The present mixtures can also contain other ingredients such as organic solvents. In larger quantities, e.g. up to 20 weight-9 (of the mixture these solvents promote the formation of a more fluid product such as that sold in factories.

In addition, inert inorganic salts such as NaCl can be added to the mixtures. Is the NaOl in very concentrated Mixtures in an amount of about 10? T, so the dispersibility of the mixtures in Water improves and thus in turn the production of dilute dispersions suitable for the treatment of fibrous materials relieved. Preferably, however, no more than about 0.5 # NaCl should be in the diluted one for treatment A certain mixture of textiles should be present, i.e. the softness through high concentrations of inorganic salt

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of the treated textile goods, especially when not in use urea.

The tissues to be treated, the methods of application of the mixtures according to the invention, which were required to borrow Amounts of the mixtures, based on the amount of the amine-epichlorohydrin reaction product to be applied to the textile material, as well as the types of reaction products to be used for softening, impregnation, etc. are in concurrent German patent application P 41446 IV b / 12 qu explained. If the present mixtures are used instead of those of the copending application, the same applies Amounts of amine-epichlorohydrin reaction products used will. Likewise, the mixtures can be the textile degreaser the concurrent German patent application P 41 214 IVc / 8k.

The mixtures used for textile treatment are preferably initially - as far as possible - diluted Poim made because in this way interactions between the constituents are reduced.

Unless otherwise noted, all parts, ratios and percentages given here relate on weight.

The following examples further illustrate the invention:

In these examples, "concentrated product" denotes a ready-mixed mixture of the following composition:

Reaction product of tallow alkylamine and epichlorohydrin in a molar ratio of epichlorohydrin to amine of about 1.5: 1, where the reaction takes place at a temperature of about 52 ° C. for about 6 hours; the reaction product using sodium hydroxide

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neutralized to an acid value of about 9, the temperature of the neutralization reaction is kept below about 38 C and the reactions mentioned in isopropyl -

alcohol to be carried: 15 #

Slippery mixture according to example I of the concurrent German patent application P 41 214 IVc / 8k (oxidized Fischer-Tropsch wax and mixed cationic-nonionic emulsification system): 5 %

Sodium chloride: 5 %

Reaction product from coconut fatty alcohol

and 45 moles of ethylene oxide: 1 %

Isopropanol: 4 %

Water: rest

The yardstick for the blue or yellow value of the material are the measured values of the Hunterlab color and color difference meter model D-25 b and b *. The positive b-numbers indicate the yellow value, the negative numbers the blue value (see brochure from Hunter Associates Laboratory, Inc. on the Hunterlab Color and Color Difference Meter, Model D-25, 1966). Smaller, positive values indicate a lower yellow value and larger, negative values indicate a more intense blue value and thus a desirable color. The b values represent the total color of this type. The b ¹ values indicate the same color minus the color masked out by means of an ultraviolet filter. In the case of the b and b ¹ values, 0.5 units signify a significant difference that is readily perceptible to the human eye.

The softness values of the following examples were obtained by hand-grading the fibrous materials according to a

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Scale on which the value 10 indicates very soft and the value 1 indicates a very hard material.

In the following examples, all fabrics are washed out and bleached fine black cotton fabric that has been treated with a customary, anionic optical brightener, Calcofluor EDS, with a pad bath concentration of 0.13 $> 'and a solution absorption of about 70 # has been pretreated.

When the cotton fabric was washed, this was done ten times in a Tide solution using the recommended concentrations. "Tide" is a customary G-built, anionic detergent.

B is ρ ie 1

The values summarized in the table below indicate the effects of the various on fine Black cotton fabrics used for the softness and color of the treated Q-fabric. The rest the mixture consists in each case of water.

The treatment was carried out so that they put the textiles at a temperature of about 26.7 G ⁰ in a mixture, provided with the Füllflotte, so that on the fabric, about 70 wt .- ^ of the mixture were added based. The fabric was then air dried and then heated in an oven to about 1450 degrees for about half a minute.

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Table I.

Mixture in percent by weight

even
Ir.

Concentrated
product

NaOE

borax

urea

Anionic

Medium ²

Softness
before after
washing

b-value of
minus b-value of the
Tissue

b 'value of
1 minus b ♦ value of the
Tissue

b-value of 2 minus b-value des
Tissue

bi value of 2 minus b 'value of the fabric

1 0.0 2 _ ^ 2.5 3 °
co
4 co 2.5
2.5 5 2 2.5 6 22 2.5 ⁷ nights 2.5 S £ 2.5 t 2.5 10 2.5 U 2.5

0.075

0.075

0.075

10 0.2 1 2 -1.0 -2 ,1 -, 2 -1.0 -1.3 -1.7 -1.0 -1 , 2 I. β 4-5 -2.7 -3 ,8th -1.2 -1.8 +0.4 -0 ", 3 +0.1 -0 , 3 5 5-6 -0.6 -2 , 4 +0.1 -1.3 -0.1 -0.3 -0.4 -0 , 2 I. 0.4 10 0.2 4th 6th -1.1 -2 , 4 -1.8 -1.2 +0.5 +1.0 -0.1 -0 ,1 10 9 4-5 -0.1 0 , 0 -0.2 -0.1 -0.2 -0.6 -0.4 -0 , 6 10 0.2 7th 4th -1.2 -2 , 7 -0.6 -1.6 +1.0 +0.3 -0.0 0 , 5 0.4 10 3 6th -0.1 -0 ,8th -0.5 -0.9 + 1.5 +2.2 -0.1 +0 , 6 0.4 9 7-8 +0.7 +0 ,1 -0.2 -0.4 +1.3 +0.4 0.0 -0 , 4 7th 4th +0.3 -1 , 7 -0.2 -1.4 +1.6 +1.7 +0.2 +0 ,1 0.4 9 7th +0.8 +0 , 5 +0.1 -0.9 0.4 5 6th

I 'sodium coconut alkyl glyceryl ether sulfonate. —A

(χ) Values read by the Hunter color difference meter immediately after use. ^

ο ' tO

(y) Haoa aged 40 hours at 82 ° C. Values read by the Hunter color difference meter. ^

- 19 -

As shown in the table above show, both sodium hydroxide and borax improve the softness of the after washing treated fabric, i.e. the permanent softness is increased, but the fabric is that of a treatment with borax or with borax and sodium hydroxide as a catalyst, that with only sodium hydroxide as a catalyst the treated fabric is superior in color. Textiles, those with mixtures with urea content and without content one anionic agent have been treated, even if inorganic catalysts are also present, before Wash on a much better softness. It should be noted, however, that the initial softness is lower when both urea and an anionic detergent are present.

The anionic detergent leads to a significant increase in the color value of the treated fabrics. Regarding If the fiber materials contain anionic optical brighteners, the color will be a combination of urea and anionic Detergent, as well as a combination of urea, anionic Detergent and borax are particularly preferred.

example

The table below shows the results of treating wide cotton fabric with concentrated Product and different amounts of different, anionic detergents compiled. It is clear from this that that the anionic detergent improves the color of the treated fabric, especially after aging will. However, in most cases the softness, especially the permanent softness of the fabric, is something lower when an anionic detergent is present, which is added to the diluted application bath in the specified amounts became.

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Mixture in Weight percent { _A
I TAS ⁴
!
(
i TAE ₅ S ⁵ 0.2 0.4 Tabel CnAGS ² 16 ° -18 ° ^C
Olefin
sulfonate 0.4 0.4 II Values of the Huhter color difference meter b « After 40 hours
diger old man
tion at 82 C. b ' Softness after ten
malignant
To wash i concentrate
treaded
ί product
ι
j CnAS ⁵ 0.4 Immediately after
Application 3.0 b 3.8 un-
to wash 5 5 0.6 b 3.1 -0.8 3.5 8th 6th Yer -
search
No. 5 0.2 -2.5 2.8 -1.6 3.3 8th 4th 1 5 0.4 6th -2.6 3.0 -2.5 3.0 6th 4th 2 5 0.6 -3.2 2.9 2.9 3.2 6th 4th 3 ^ 5 -3.0 2.9 -1.8 2.8 8th 4: 4 ο 5 -2.6 3.1 -2.7 3.0 8th 3 <* 5 co 5 -3.2 2.9 -2.9 3.2 7th 4 ' 6 * "" 5 -3.0 2.7 -2.9 3.1 5 4th 7 ^ 5 '-3.2 3.0 -2.8 3.3 7th 4th 8 -Y 5 -3.3 -2.6 7th 9 pounds -3.2 10

latriua cocoa alkyl lelyceryl ether sulfonate. sodium coconut alkyl sulfate. LatriuBtalg-Alkylsulfat .

Sodium tallow alcohol polyethylene oxide sulfate (3 mol Ethylene oxide per mole of detergent).

Sodium salt of the reaction product of C, g-C, _a -Ct · olefin and SO,.

example

Mixture of the following composition;

Reaction product of tallow alkylamine and epichlorohydrin in a molar ratio of epichlorohydrin to amine of about 1.5: 1 »where the reaction is carried out for about six hours at about 52 ° C, the reaction product is neutralized to an acid value of about 9 using sodium hydroxide, the temperature of the neutralization reaction was kept below about 38 ⁰ C and the reactions mentioned in isopropyl alcohol took place ί 4.5

Urea: 88.5

Borax; 4.5

Sodium cocoalkyl poly (4) ethoxysulfate; 0.6

Slippery mixture according to Example 1 of the concurrent German patent application P 41 214 IVc / 8k (oxidized Fischer-Tropsch wax and mixed cationic nonionic emulsification system): 1.5

example

The following mixture is a valuable, concentrated mixture that can be stored and shipped, which can be diluted and thus results in a mixture suitable for the treatment of textiles,

The amine / bpichlorohydrin reaction product

of the example 5 x 15

The slippery mixture of Example 3: 5

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Ethanol: 10 %

Reaction product from coconut alcohol

and 45 WoI ethylene oxide: 2 %

Isopropanol: 47 %

Sodium coconut alkyl glyceryl ether sulfonate θ %

Example ^:

If the special anionic detergents in the mixtures of Example 2 were replaced on a molar basis by the following anionic detergents, then practically equivalent results were achieved in that the textiles were softened and the color values thereof were improved compared to a textile material treated only with the concentrated product:

Sodium and potassium dodecylbenzenesulfonates, sodium and potassium salts of dodecylphenol-ethylene oxide-ether sulfates with about 4 units of ethylene oxide per molecule , sodium and potassium lauryliaethionates, sodium and potassium salts of coconut fatty acid amides of methyl taurine, as well as sodium, potassium Monoethanolammonium, diethanolammonium and triethanolammonium salts of the aforementioned detergents, as well as the detergents specifically listed in Example 2

Example 6;

In Example 1, the sodium hydroxide was made on the basis of ice completely or partially replaced by potassium and ammonium hydroxides or sodium and potassium carbonates, so were achieved practically equivalent results when the treated textile material had a good, lasting softness.

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Claims (10)

pat dismay: (1) about 0.01 to 99 # of one dispersible in water Reaction product of a primary alkylamine having about 12 to 30 carbon atoms in the alkyl chain with about 1.25 to 2 moles of epichlorohydrin per mole of amine, (2) about 0.0005 to 95 % of one or more of the following additives: (a) borax, (b) anionic detergent, (c) urea; (3) based on (1), 0 to about 10 wt .- # of an emulsifier for (1) in the form of the condensation product of a fatty alcohol with 9 to about 18 carbon atoms with about 10 to 60 MbI ethylene oxide, or the condensation product an alkyl phenol having from about 9 to 15 carbon atoms in the alkyl group having from 10 to about 15 moles of ethylene oxide per mole of alkyl phenol; (4) 0 to about 20 ff, a strongly alkaline compound and 109843/1749 1789483 (5) the remainder of water. 2. textile treatment mixture according to claim 1, characterized in that the reaction product (1) in about 30 minutes to 10 hours at a temperature of about 27 to
93 ⁰ C and neutralized at about 16 to 66 ⁰ C to an acid number of below about 30. 3. textile treatment mixture according to claim 1, characterized in that borax in an amount of about 25 to 250% by weight, based on the reaction product (I), of the anionic detergent in an amount of about 0.25: 1 to about
2.5: 1 mole of anionic detergent per mole of amine or quaternary ammonium group .in the reaction product and the urea, based on the reaction product (1), is present in an amount of about 1300 to 3000 wt .- #. 4. textile treatment mixture according to claim 3, characterized in that about 0.5 to 5 wt .-% of the reaction product (1) are included. 5. Textilbehandlungsgemiseh according to claim 1, characterized in that the anionic detergent consists of a
water-soluble beife with about 8 to 18 carbon atoms
or an anionic synthetic detergent which has an alkyl radical with about 8 to 22 carbon atoms and a radical of a sulfonic acid or sulfuric acid ester in its molecular structure. 6. Textilbehandlungsgemiseh according to claim -3 »thereby characterized in that it contains a mixture of urea and anionic detergent as an additive. 7. Textilbehandlungsgemiseh according to claim 3, characterized in that it is a mixture of as an additive
Contains urea and borax. 109843/174 « 8. textile treatment mixture according to claim 3 »thereby characterized in that it contains a mixture of borax, anionic detergent and urea as an additive. 9. The textile treatment composition according to claim 3 t characterized in that the Iieaktionsprodukt is present in an amount of about 0.05 to 1 i ". 10. A method for treating textiles using the mixture according to claim 4. Pur The Procter * Gamble Company Lawyer 109843/1749