DE1692792C - Process for the production of condiments - Google Patents

Description

The I rliiidung relates to a process for producing seasonings, which consist essentially of .venigstens two components, wherein a Würzstoffkomponente is coated with one or more of the other Würzstoffkomponenten and is dried in a very specific way.

It is known that with simultaneous venous dune ·. a 5'-nucleotide with monosodium glutamate, which is effective as a seasoning, shows a strong increase and development the taste of food and luxury foods is achieved as a result of the synergistic effect and that when using common salt with the 5'-nucleotide effective as a seasoning in a suitable Mixing ratio a particularly taste-enhancing effect is achieved.

Of the seasonings with the above-mentioned ingredients, those are currently preferred, at 6u where monosodium glutamate is coated with a 5'-nucleotide that is effective as a flavoring, and sodium chloride is coated with monosodium glutamate and / or the 5'-nucleotide effective as a flavoring. In the Belgian Patent specification 650 407 such a wort z. B. by homogeneously mixing sodium glutamate with 5'-N'ucleotides produced in the presence of water vapor.

In the procedure of the British Patcmschr.fi 7S9 565 becomes a liquid wrapping agent first! towards that enveloping material, e.g. B. sprayed glutamic acid and then a solid Umhüllungsm.ttel z. B. table salt, «Slightly mixed in. The materials treated in this way are then introduced in the usual way by hot air or by external heating in a "coating point!" rotary dryer or in a Dried fluidized bed column.

However, these methods have certain disadvantages:

It can e.g. B. not the next spray can be anticipated before the sprayed material has not dried. there both the spraying as well as drying on the same plate. in the same column or in the same dryer is accepted. As it is used to order a desired large amount of the wrapping agent on the / u enveloping material necessary in the the above measures often / u repeat. "result inevitably -he Working hours for wrapping. However, it is used to achieve a high level of effectiveness If hot air at a high temperature is used, it may decompose.! Er Damage to the material to be encased or the lubricant come about. Win! : .igeeen the amount of hot air to be introduced increases. then the material to be wrapped. rscattered or split.

If you have a large amount of Umhüllu ·, <> means .. 'sprayed at once to be encased in May il, often found agglomeration de u encapsulating material to large pieces <vt. and this agglomerated material is dried in d.ccr form and leads to an unbearable massive sales profit.

The subject matter of the invention is a method / ur production of one from several components such as 5'-nucleotides and amino acids existing Wü.ze. in the case of at least one seasoning component superficially with one or more of the other seasoning components in the presence of a solvent and by feeding a moist hot gas and then dried by means of warm air, which characterized in that about 1 to 20 parts by weight of one or more Besehichiur.gskomponenten with about 80 to 90 parts by weight of the / u coating seasoning component in the presence of water or a hydrophilic solvent. with amino acids as the respective components. 5'-nucleotides and / or sodium chloride are used be, the wet mixture, which is about 1 to 6 percent by weight Solvent, based on the component to be coated, contains a with in the upper part a column equipped with a stirrer in countercurrent with that supplied from the lower end of the column hot air or inert gas, its relative humidity after passing through the to be dried Mixture of substances in the lower part of the column is 80 to 95%, merges and the treated in this way Mixture of substances then in the lower part of the column with the hot gas of about 30 to 100 C and one relative humidity of about 1 to 85 ° / "dries in a known manner in countercurrent.

The method according to the invention enables the production of uniformly structured seasoning mixtures. It effectively prevents agglomeration and

caking of the particles to be coated during the drying process. Hs does not cause damage the wrapping material, and the wrapping material. The time required to carry out the procedure effectively is l.ur /. The procedure according to the invention enables the manufacture !!!! a seasoning in which compared to the, well-known products eii.e much smoother oil coating on the core is upset. what in particular uünstii; on a EleichmäTice distribution of the sausage mixture home Loosening affects.

As enveloping materials and as enveloping agents, 5-nucleotides and sodium chloride, effective as spices, are used in the process of discovery. Examples of these amino acids are Monnr.atriüiv.giüiü'mat. Alanine. Glycine. Monosodium aspnnate and examples of the S'-Nueieu effective as a seasoning, the diirium salts of 5-liiosir \ saur .. u; ü r;> n the above ger.-ui .-- each: -. .! \ ■ ■ · .-, eire than iu to be sheathed M - · _(| J-.rere the other of these \ he vRdi *, ι ngimittel use !. .msec Bv;> p ^ e \ measured seasoning produced let the wrapping agent adhere to the surface of the material to be wrapped.

Here Läsungsmitieimer.ge. those in the wet hh i

"Earth
or
tmh.
manure

■ eonin. Ie are

'gen as ^ n erlin-

c Wort, which consists of white numglutamate, which is / are surrounded by 5'-inosinic acid and • ire.
-.e wort, which in the wes -.- i ιΐκή. lorid. the one with a month in ml ·. . consists.

■ iie wort, which essentially consists of \ airmmlivid. that is coated with Mononaimuiuhilanuit and Oiiiritinisal / s of 5-lnosips; 'ire and oiler ^ς -Cmiv! acid, insist!

ni method of the invention L ¹ de material first with the:

is contained is about 1 to 6 percent by weight, expediently between about 3 and 4 percent by weight of the material to be coated. The concentration iind or the amount of the solution or suspension of the coating agent or the amount used the one used for wetting the material to be coated. Solvent is adjusted accordingly.

If the amount of solvent contained in the material to be coated is too small, an effective one is used Wrapping not possible because the material is not moist enough. If, on the other hand, the amount is too large, it can a smooth product cannot be obtained because the material to be wrapped comes off and becomes large pieces agglomerated, which are then dried in this form.

Mixing the material to be coated with the Enveloping agents can be made with conventional equipment. Mixing is preferred carried out with stirring and with aeration. The material to be coated according to the invention is preferably in powder form or granular form is used, in particular in a particle size which is not smaller than the SiehcröL'e 150 µ

N ₁ JiIiIiM- If powdery or granular coating

iiher / Kiii- '! ³ ° ^mute ' ⁿⁱ ' ^{1 is} mixed with the powdery or granular material that has to be coated and previously wetted with one of the above solvents. the mean diameter of the coating agent is preferably not more than approximately one third of the particle diameter of the material to be coated. The amount of the coating agent is chosen so that it is sufficient to coat the material. Leine amount is about 1 to 20 percent by weight, based on the material to be wrapped.

* o As a second stage of the process according to the invention the moist material produced in the first stage is -behandelt heiEem with wet gas under conditions such that almost a dynamic balance between the amount of solvent. which is evaporated from the product by heating it with the hot gas, and the amount of liquid. which is condensed from the dry moist gas is maintained. In order to effectively maintain the dynamic equilibrium, this is done in the first

! ■ - ■ '"from M'.Mion '■■'. Dinatriiim- ■ "j'-r 5'-Guan \! -

Ii from Vuritmi-

! Illi.lt

becomes the / u uin-I mhü'lluiursmittel

humid conditions, d. b. in the presence of a Solvent mixed. This operation can »Org ^ ncmmen, for example by adding the to encapsulating material with a solution or suspension, in which the Umluillungsmittei dissolved or suspended! is. mix or the material to be coated wetted with a liquid and the wetted material mixed with a powdery coating agent »As a solvent for dissolving or suspending of the enveloping material are suitable for example

wise water. Methanol. Ethanol. Acetone or their y g

Mixtures. Of these, water is preferred. Moist product obtained as a liquid 50 stage at a temperature wedge for wetting the material to be coated are ν., Η not less than 20 C treated with a gas, the water and hydrophilic organic solvent, which has a relative humidity of about 80 to 95 ^u "used. Lower aliphatic hats, for example, are suitable. In the present description and in the analcohols such as methanol, ethanol. Iropanol, Bu'anol Sprüche is under the expression »relative etc. and aliphatic ketones (e.g. acetone). Before moisture is the ratio of the vapor pressure to which these solvents are added, water. Liquid (including water) in gas to steam

When using monosodium glutamate (MSG) pressure the liquid at saturation at the same as the material to be coated can be understood as mixing the temperature. Treatment is pre-MSG and the coating agent preferably worked through for about 15 minutes to about 1 hour be that the Uirhüllungsmiltel leads with a 60. The upper limit of the treatment temperature the MSG-containing slurry mixed may be at the highest temperature at which the that in the course of the production of MSG by the material to be coated or the coating material Fermentation or by slow cooling · one is not yet decomposed or damaged in any way. the Solution of MSG in a solvent (e.g. upper limit is preferably about 1,100 C. Im Water, a mixture of water and methanol, 65 general is the efficiency of the special dry ethanol, Propanol, Pülanol or acetone) the better the maintenance process of the second stage and the mixture is filtered. The contact temperature used is higher. In the a moist material is obtained in this way, but in practice the treatment at a tempc-

5 J 6

raliir in the ltcrcich from about 25 to 70 ° C. In detail a hot gas. that one temperature

will. of at least about 30 ° C, suitably from about 40 ° C

As the hot humid gas, air is most advantageous, up to i'.O'C, and a relative humidity of about

However, other inert gases, for example, nitrogen 7. 1 His 70 ° / _0, purpose idle from about 2 to 25 "/ ,, has. con-

and COj. be used. In the second stage 5 is continuous from bottom to top through the column with

guided on the surface of the material to be wrapped at a speed that is approximately at or

adhesive coating agent fused with it, so that something under you * to whirl up the imported

firmly adhere the two materials together. minimum speed required for moist product

The third stage of the method according to the invention is wedge and generally about 0.5 to 300 cm /

consists in drying the product treated in this way to a second. That dealt with in the first stage

by heating with a hot gas. As a hot gas, moist product that is a solvent in a lot

air is expediently used, but from about 1 to 6 percent by weight, preferably from

other inert gases, e.g. B. nitrogen and CO ₂ . uses about 3 to 4 percent by weight, based on the

will. Drying can be carried out. enveloping material, containing, is continuously of

by treating the product with hot gas, 15 passed up through the column downwards. The access

That a relative humidity of about 1 to 85 ° / ₀ , conduction of the wet product is preferred

suitably from about 2 to 82 ° / ₀ , and a temperature chosen so that the total time of contact between

from about 30 to 100 ° C., suitably not less than the product and the hot gas in the column about

about 30 C. The working time can be about 30 minutes, 1 to 3 hours. That way it becomes

last up to 2 hours. ao moist product continuously in the stream of

The second stage and third stage of the process gc- the hot gas flows through the column. in the

According to the invention, it is most expedient for the hot gas to flow through the lower part of the column

Only carried out by the wetted product continuously the moist product after this :.

from the first stage has passed continuously in countercurrent with the process that cnt-

dcm hot humid gas is brought together. 25 speaks where> on the product under the above bc

Here the hot gas comes first with the product being dried under the same conditions. After

in contact, the contact described above corresponding to the second stage is the hot one

Treatment, which gives the product gas the properties (temperature and relative I Vu-ii-

gcirocknci has been bestowed while the humidity of the hot tigkeit), which for the second stage mt-

Gas increased and its temperature slightly decreased 30 are written. In this state, it continues to flow

will. After the hot gas this product through- up to the upper part of the column, in which the gas

flows, it will come into contact with the moist product from the continuously with the moist product

first stage brought into contact that has not yet been brought into contact, whereby the product of a treatment,

Treatment of the second stage which corresponds to the second stage, under the above bc-

is. 35 is subject to the conditions set out below.

For example, the method according to the invention is used. If necessary, the internal temperature can be used Advantageously using a standing upper part of the column by heating or cooling Mixing column carried out, the moist product from the outside to a desired value in the Bcrciui of from the first stage at the upper part continuously to about 10 to 80 "C, is performed while the hot gas is continuously 40 The desired wort in which one component is introduced at the foot of the column under the aforementioned conditions, firmly and smoothly with one or more other Koniganz certain conditions, where components is enveloped, is continuously from the soot withdrawn by the product continuously in countercurrent with the column.

comes into contact with the hot gas. The aforementioned continuous execution The method according to the invention can also be an embodiment of the method according to the invention

can be carried out in batches by setting the temperature below with reference to the figures of devices

rature. and the relative humidity of the described at the bottom, which is suitable for carrying out the v'er-

Part of the column introduced hot gas is suitable according to the invention,

can be set to speak. Fig. 1 shows in cross section the main part of a

When the method is carried out continuously, the device is an embodiment;

using an upright mixing column, F i g. 2 shows in cross section a complete, con-

the moist product from the first stage of the column continuously operating device;

fed at the upper end and in the upper part of FIG. 3 shows a continuous in cross section

Column of a processing multi-stage coating device corresponding to the second stage, subject to action, whereupon it is in the lower part 55 In these figures I is a filling funnel into which the

the column falls, in which it is filled with a treatment to be encased material. For dosage

is thrown, the above-described third stage of this material is used by the feed device 2. The

is equivalent to. Tank 3 contains that used for spraying

In order to carry out these processes effectively, it is necessary to use a solvent and the reservoir 4 to be coated. to adjust the working conditions to 60 medium. The coating agent is dispensed

that each of the two processes under the above direction 5 abandoned. In column 6 it becomes

Conditions is carried out. For this purpose, the enveloping material is wetted with the solvent

'The working conditions, such as moisture from and mixed with the coating agent. Dk * column

the column above fed product, relative contains an impeller 7 and a slot 8. In the The humidity, temperature and feed rate of the .65 column9 are those of the second stage and those of the

hot gas introduced at the foot of the column and, third stage, appropriate treatments

if necessary, take the time of contact of the "moist. Dk column 9 contains agitator blades 10 and 11,

Product !, and the hot gas, selected accordingly. a Kdzmantei! 2, a perforated plate or

a plane 13 as a support for the stirrer axis, a discharge opening 14 for the finished product and an inlet 15 for a hot gas. The system includes a Water tank 16, a heat exchanger 17. an air charging device 18, a dust separator 19, a circulation pump 20 and a fan 21.

The materia to be enveloped! the column 6 through the funnel 1 and the metering device 2 fed. A solvent for wetting the material to be coated is taken from the storage container 3 in the column 6 sprayed, in which the material is wetted with the solvent and with the coating agent is mixed.

The material wetted and mixed in this way is fed to the column 9 through the slot 8. A coating agent is introduced into the column 6 or 9 from the filling funnel 4 and the metering device 5.

A hot gas is introduced through inlet 15 and rises in column 9 to the top. In part A of the column 9, the material to be coated is mixed with the coating agent, a moist product being obtained, to the particles of which the coating agent adheres. The product obtained in this way reaches part B and then part C of the column 9, which is kept at the desired temperature with the aid of the heating jacket 12.

The moist product fed into part B is traversed by the hot gas, which has increasing relative humidity and which has risen through part C, with constant stirring. In this way, the treatment corresponding to the second stage is carried out.

After this treatment, the product reaches part C, where it is mixed with that from the lower part of the column 9 rising hot gas is brought into contact, whereby that of the third stage corresponding Treatment is made. The finished product is discharged from the discharge opening 14 deducted.

Using this apparatus, the process of the invention is carried out continuously, the above conditions being appropriately set, namely the ratio of Amount of the solvent fed to the column 6 to the amount of the material to be coated, the Verao because of the material to be coated and the coating agent in the column, the temperature, relative Moisture and amount of hot gas introduced into the column at the bottom.

The method of the invention is described in US Pat Use of the device described above under the conditions given in the table below accomplished.

Betspiel

Material to be wrapped
Coating agents

Solvent for wetting

Hot gas temperature
at the entry to the column

Relative humidity of the gas

in the entry to the column
Amount of hot gas supplied

Total duration of the touch of the to
enveloping material with the
hot gas

Temperature during the treatment of the second stage

Relative humidity during the
corresponding to the second stage
treatment

Quantity of product deducted

* MSG - monosatrine glutamate
Ribo = - mixture of rich amounts of MSG (149 to 590 μ)
1.0 kg / minute

Ribo * (passage through
149 ^ sieve) 80 g / minute

g HjO / minute
80 ° C

2%

NaCl (149 to 500 µ) 1.0 kg / minute

MSG and Ribo * [weight ratio 2: 1] (passage through 105 ^ sieve) 176 g / minute

60 g H ₂ O / minute 60 ^° C

7%

63.0 Nm ³ / hour
(14 cm / second)
1.5 hours 158 Nm ³ / hour
(35 cm / second)
2 hours 50 ^c C 35 ° C j 95% 1.08 kg / minute 1.18 kg / minute

of the disodium salt of 5'-inosinic acid and of the disodium salt of 5'-guanylic acid.

example 1

Using the methods shown in FIG. 1 to 3, monosodium glutamate with a particle size of 0.15 to 0.59 mm is continuously fed to the column 6 (diameter about 40 cm, height about 150 cm) at a rate of 1 kg / minute and stirred while it is being stirred with Wa 'acr wird- ig sprayed in an amount of "/ min the thus obtained wet bodies of the MonoBatriumglutamats be the top of the column 9 ^x eil {diameter of about 150 cm) kg about 40 cm, height 65 in an amount of 1.04 / minute fed.

In the column 9, the material is stirred while a hot gas that has a temperature of 80 ° C and

has a relative humidity of 2%, in an amount that has a temperature of 50 ⁰ C and a relative

of 63.0 Nm * / hour through inlet 15 and a humidity of 8%, in an amount of

Powder of 5'-ribonucleotide (a mixture of the same 18 Nm ³ / hour was introduced

Amounts of the disodium salt of 5'-inosinic acid and 320 g of a 25% aqueous solution of sodium

of the disodium salt of 5'-guanylic acid), which sprayed a 5 glutamate into the column.

Has particle size below 149 μ, in an amount of After spraying is carried out the

80 g / minute in the upper part of the column 9 - air continued with stirring for 50 minutes. Here

will lead. becomes a dry product made from sodium chloride

With the hot introduced at the foot of the column 9, the I weight percent monosodium

Gas and the heating mantle 12 is part B of the io glutamate (based on the total amount of dry

Column 9 at a temperature of 50 ° C and a product) is coated, in a yield of 96 ° / ₀

relative humidity maintained at 80%. Obtained on this, based on the total amount used

Way can be a dried product made from monosodium chloride and monosodium glutamate.
sodium glutamate, which is 7.4 percent by weight

5'-ribonucleotide (based on the total amount of the 15 B e 1 s ρ 1 e 1 3

Product) is coated continuously in an amount Using the same column as in the

of 1.08 kg / minute from the foot of the column 9 - Example 2 9.4 kg of monosodium glutamate (MSG)

be pulled. a particle size of 0.210 to 0.710 mm treated.

The dry product obtained in this way is converted into 1 liter of 70% aqueous methanol with stirring

keeps 98.0% of the amount of ao used (vol./vol.) sprayed into the column as a coating. With the so

5'-ribonucleotide. The portion of the dried Pro-traded MSG will be 600 g of 5'-ribonucleotide

duct, which is mixed with a sieve with a mesh size of 0.194 to a particle size of 74 to 105 μ. Subsequently

0.840 mm is 97%, based on the Ge. A hot gas with a temperature of 50 ^° C

total amount of dried product. and has a relative humidity of 8%, in one

_R ·. ,, »5 amount of 35 Nm ³ (about 8 cm / seconds) at the Fui3

s ρ _{the Ko} | introduced _onne. Ventilation is 1 hour

In this experiment only the upper column was continued with stirring.

the device shown in Fig. 3 is used. In this way, 9.9 kg of dry product are in From this column, 8 kg of sodium chloride were obtained in a yield of about 99% based on

Particle size from 0.149 to 0.500 mm fed. 30 the total amount of monosodium used

A hot gas passed through the bottom of the column. glutamate and S'-Rjbonuclcoiid

1 sheet of drawings

Claims (2)

Patent claims: 1. Process for the production of a wort consisting of several components such as 5'-nucleotides and amino acids, in which at least one wort component is coated on the surface with one or more of the other wort / components in the presence of a solvent and by supplying a moist hot gas and then by means of warm air is dried, characterized in that about 1 to 20 parts by weight of one or more coating components are mixed with about 80 to 99 parts by weight of the seasoning component to be coated in the presence of water or a hydrophilic solvent, the respective components being amino acids, 5'-nucleotides and or Sodium chloride are used, the moist mixture, which contains about 1 to 6 percent by weight of solvent, based on the component to be coated, in the upper part of a column equipped with a stirrer in countercurrent with hot air or inert gas supplied from the lower end of the column, whose r elative humidity after passing through the / u-drying material mixture in the lower part of the column SO amounts to 95 ° _0, brings together and the thus treated Stoffiii.schung then in the lower part of the column with the hot: n Ga of about 30 to 100 C and a relative humidity of about 1 to 85 ° ο dries in a known manner in countercurrent. 2. The method according to claim 1, characterized in that there is used as the component to be coated Monosodium glulamate and, as a coating, dinatriuric salts on 5'-inosinic acid and or 5'-guanylic acid or that one uses table salt as the core and monosodium glutamate as the coating agent used.