DE166768C - - Google Patents
Info
- Publication number
- DE166768C DE166768C DENDAT166768D DE166768DA DE166768C DE 166768 C DE166768 C DE 166768C DE NDAT166768 D DENDAT166768 D DE NDAT166768D DE 166768D A DE166768D A DE 166768DA DE 166768 C DE166768 C DE 166768C
- Authority
- DE
- Germany
- Prior art keywords
- sulfonic acid
- dioxynaphthalene
- acids
- dyes
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000975 dye Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 5
- 210000002268 Wool Anatomy 0.000 claims description 4
- 150000008049 diazo compounds Chemical class 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000007747 plating Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 240000000358 Viola adunca Species 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 230000002378 acidificating Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- GPUMPJNVOBTUFM-UHFFFAOYSA-N naphthalene-1,2,3-trisulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC2=C1 GPUMPJNVOBTUFM-UHFFFAOYSA-N 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
- C09B45/16—Monoazo compounds containing chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Im Patent 157786, Kl. 22 a sind o-Oxymonoazofarbstoffe beschrieben worden, die beim Nachchromieren schwarze Farblacke von tadelloser Pottingechtheit zu liefern vermögen. Es sind dies die Farbstoffe, die aus ο -Amidophenolsulf osäuren und deren Derivaten einerseits und I · 5 - Dioxynaphtalin andererseits erhalten werden.In patent 157786, cl. 22a, o-oxymonoazo dyes are have been described, which are able to deliver black colored lacquers of impeccable potting fastness when chromium plating. These are the dyes that are made from ο -amidophenolsulfonic acids and their derivatives on the one hand and I · 5 - dioxynaphthalene on the other hand can be obtained.
Es hat sich nun weiter herausgestellt, daß ίο auch diejenigen Farbstoffe aus o-Amido-. phenolsulfosäuren und deren Derivaten, zu deren Herstellung an Stelle des genannten Dioxynaphtalins dessen Monosulfosäuren verwendet werden, beim Nachchromieren derartige hervorragend echte Farblacke zu liefern vermögen. Durch diese Echtheitseigenschaften unterscheiden sich die neuen Produkte vorteilhaft von den bisher bekannt gewordenen ο-Oxyazo farbstoff en aus isomeren Dioxynaphtalinsulfosäuren (vergl. z. B. die Patentschrift 131527 und die britische Patentschrift 11437/98).It has now been found that ίο also those dyes from o-amido-. phenolsulfonic acids and their derivatives, for their preparation in place of the above Dioxynaphthalene whose monosulphonic acids are used, such as those used in post-chrome plating able to deliver excellent real color lacquers. Through these authenticity properties the new products differ advantageously from those previously known ο-Oxyazo dyes from isomeric dioxynaphthalene sulfonic acids (See e.g. Patent 131527 and British Patent 11437/98).
Beispiel. 19kg o-Amidophenol-p-sulfosäure werden in gewöhnlicher Weise in die Diazoverbindung übergeführt und diese zu einer eiskalten Lösung von 26,5 kg des sauren Natronsalzes der 1 · 5 - Dioxynaphtalin - 3-sulfosäure (die z. B. durch Verschmelzen der 1:3: 5-Naphtalintrisulfosäure mit Ätzalkalien gewonnen werden kann) zugegeben.. Es wird sodann Natronlauge in geringem Überschuß zugefügt. Nach mehrstündigem Rühren ist die Farbstoffbildung vollendet. Die überschüssige Natronlauge wird durch Zugabe von Salzsäure abgestumpft, der Farbstoff ausgesalzen, filtriert, gepreßt und getrocknet. Er färbt Wolle in saurem Bade in blaustichig roten Tönen an. Beim Nachchromieren wird ein tiefes, pottingechtes Blauschwarz erhalten.Example. 19kg o-amidophenol-p-sulfonic acid are converted in the usual way into the diazo compound and this into a ice-cold solution of 26.5 kg of the acidic sodium salt of 1 · 5 - dioxynaphthalene - 3-sulfonic acid (e.g. obtained by fusing 1: 3: 5 naphthalene trisulfonic acid with caustic alkalis can be obtained) added. Sodium hydroxide solution is then added in a slight excess. After several hours Stirring the dye formation is complete. The excess caustic soda gets through Addition of hydrochloric acid blunted, the dye salted out, filtered, pressed and dried. He dyes wool in an acid bath in bluish red tones. When re-chrome plating a deep, potting-fast blue-black is obtained.
Die Darstellung der anderen nach dem vorliegenden Verfahren erhältlichen Farbstoffe geschieht in vollkommen analoger Weise.The representation of the other dyes obtainable by the present process happens in a completely analogous way.
In folgender Tabelle sind die Nuancen einer Anzahl der nach dem vorliegenden Verfahren erhältlichen Produkte angeführt.In the table below are the nuances of a number of those made by the present process available products are listed.
ti,Dye from:
ti,
ungeheizte WolleColors
unheated wool
sulfosäure (Patent 68344)o-Amidophenol-p-sulfonic acid - \ - 1 · 5 - Dioxynaphthalene - 2 -
sulfonic acid (patent 68344)
sulfosäure0-amido-o-cresol-p-sulfonic acid -j- 1 · 5 - dioxynaphthalene - 2 -
sulfonic acid
ungeheizte WolleColors
unheated wool
sulfosäureo-Amidophenol-p-sulfonic acid - \ - ι · 5-Dioxynaphthalene-3-
sulfonic acid
talin - 3 - sulf osäureο - amido - ο - nitrophenol - ρ - sulfonic acid + 1 * 5- Dioxynaph-
taline - 3 - sulfonic acid
naphtalin - 3 - sulf osäureo-amidophenol-p-chloro-o-sulfonic acid + ϊ 5-dioxy-
naphthalene - 3 - sulfonic acid
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE166768C true DE166768C (en) |
Family
ID=432141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT166768D Active DE166768C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE166768C (en) |
-
0
- DE DENDAT166768D patent/DE166768C/de active Active
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