DE1645145A1 - Process for the production of complex compounds from polysilicic acid and fluorocarbon polymers and coating agents - Google Patents

Process for the production of complex compounds from polysilicic acid and fluorocarbon polymers and coating agents

Info

Publication number
DE1645145A1
DE1645145A1 DE1966P0039707 DEP0039707A DE1645145A1 DE 1645145 A1 DE1645145 A1 DE 1645145A1 DE 1966P0039707 DE1966P0039707 DE 1966P0039707 DE P0039707 A DEP0039707 A DE P0039707A DE 1645145 A1 DE1645145 A1 DE 1645145A1
Authority
DE
Germany
Prior art keywords
fluorine
hydroxyl groups
copolymer
alcoholic hydroxyl
polysilicic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE1966P0039707
Other languages
German (de)
Other versions
DE1645145B2 (en
Inventor
Bechtold Max Fredrick
Brasen Wallace Raymond
Fawcett Frank Shumate
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of DE1645145A1 publication Critical patent/DE1645145A1/en
Publication of DE1645145B2 publication Critical patent/DE1645145B2/en
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/02—Polysilicates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/02—Polysilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544—Addition polymer is perhalogenated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)

Claims (7)

1645H5 E.I. du Pont de Nemours CR-6359/6423/P 39 and Company Neue Patentansprüche1645H5 E.I. du Pont de Nemours CR-6359/6423 / P 39 and Company New claims 1. Verfahren zur Herstellung von Komplexverbindungen aus Polykieseisäure und Fluorkohlenstoffpolymerisaten, dadurch gekennzeichnet, dass 10 bis 90 Gew.-% Polykieselsäure, berechnet als SiO^, mit 90 bis 10 Gew.-% eines zuvor aus einem Fluorolefin und alkoholische Hydroxylgruppen enthaltenden äthylenungesättigten, mischpolymerisierbaren Monomeren hergestellten fluorhaltigen Mischpolymerisates umgesetzt werden.1. Process for the preparation of complex compounds Polysilicic acid and fluorocarbon polymers, thereby characterized in that 10 to 90% by weight of polysilicic acid is calculated as SiO ^, with 90 to 10 wt .-% of one of before a fluoroolefin and ethylene-unsaturated copolymerizable monomers containing alcoholic hydroxyl groups produced fluorine-containing copolymers implemented will. 2. Verfahren nach tAnspruch 1, dadurch gekennzeichnet, dass man die Umsetzung mit einem Mischpolymerisat durchführt, welches mindestens 19 Gew.-% Fluor und mehrere alkoholische Hydroxylgruppen enthält, die an nicht, mehr als ein Wasserstoffatom tragende Kohlenstoffatome gebunden sind, während die übrigen Bidungen der betreffenden Kohlenstoffatome an andere Kohlenstoffatome gebunden sind, wobei diese Hydroxylgruppen im wesentlichen die einzigen Hydroxylgruppen in dem Mischpolymerisat sind.2. The method according to t claim 1, characterized in that the reaction is carried out with a copolymer which contains at least 19 wt .-% fluorine and several alcoholic hydroxyl groups which are not bonded to more than one hydrogen atom-bearing carbon atoms, while the rest Bidungen of the carbon atoms in question are bonded to other carbon atoms, these hydroxyl groups being essentially the only hydroxyl groups in the copolymer. 3. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass zur Umsetzung ein Mischpolymerisat verwendet wird, welches 6 bis 65 Gew.-% Fluor und mehrere primäre alkoholische Hydroxylgruppen bei einem Molverhältnis von alkoholischen Hydroxylgruppen zu. Fluoratomen im Bereich von 1 : 1 : 22 und einem Molverhältnis von Fluor zu Kohlenstoff im Bereich von 1 : bis 1,93 : 1 enthält.3. The method according to claim 1, characterized in that a copolymer is used for the reaction, which 6 to 65 wt% fluorine and several primary alcoholic hydroxyl groups at a molar ratio of alcoholic hydroxyl groups. Fluorine atoms in the range of 1: 1: 22 and one Fluorine to carbon molar ratio in the range of 1: to 1.93: 1. Vom Deutschon PD.tsrifcVon Deutschon PD.tsrifc ohne f'v'o #1.·;>Λ--:{:-ί.- teerge- /without f'v'o # 1. ·;> Λ--: { : -ί.- teerge- / Ctf...«·.:.1 i'-\r:. -.;.. iii Vwis Ui"5tar- ". - "-.-Ctf ... «·.:. 1 i '- \ r :. -.; .. iii Vwis Ui "5tar-". - "-.- Ιβο«η, c;. süx ic;ornecha- . 209810/1400 niöchcn Wiöe?ergabe nicht
geeignet sind.Ιβο «η, c ;. süx ic; ornecha- . 209810/1400 not a good result?
are suitable. 4. Überzugsmittel, dadurch gekennzeichnet, dass es in Lösung in einem verträglichen Lösungsmittel eine Komplexverbindung aus 10 bis 90 Gew.-% Polykieselsäure, berechnet als SiOp, und bis 10 Gew.-% eines zuvor hergestellten, Halogen, Kohlenstoff, Sauerstoff und Wasserstoff enthaltenden Mischpolymerisates enthält, welches 6 bis 65 Gew.-% Fluor und mehrere primäre alkoholische Hydroxyl gr up j> en bei einem Molverhältnis von alkoholischen Hydroxylgruppen zu Fluoratomen im Bereich von 1 : 1 bis 1 : 22 und einem Holverhältnis von Fluor zu Kohlenstoff im Bereich von 1 : 17 bis 1,93 : 1 aufweist, wobei die Konzentration der Komplexverbindung in der Lösung etwa 2 bis 25 % beträgt.4. Coating agent, characterized in that it contains, in solution in a compatible solvent, a complex compound of 10 to 90% by weight of polysilicic acid, calculated as SiOp, and up to 10% by weight of a previously prepared containing halogen, carbon, oxygen and hydrogen Copolymer containing 6 to 65 wt .-% fluorine and several primary alcoholic hydroxyl groups with a molar ratio of alcoholic hydroxyl groups to fluorine atoms in the range of 1: 1 to 1:22 and a ratio of fluorine to carbon in the range of 1: 17 to 1.93: 1, the concentration of the complex compound in the solution being about 2 to 25 % . 5· Überzugsmittel nach Anspruch 4, dadruch gekennzeichnet, dass die Lösung außerdem ein Pigment enthält.5 · Coating agent according to claim 4, characterized in that the solution also contains a pigment. 6. Überzugsmittel nach Anspruch 4-, dadurch gekennzeichnet, daß der Fluorgehalt des Mischpolymerisates auf der Anwesenheit, von Tetrafluoräthylen- und bzw. oder Monochlortrifluoräthyleneinheiten beruht.6. Coating agent according to claim 4-, characterized in that the fluorine content of the copolymer is based on the presence, of tetrafluoroethylene and / or monochlorotrifluoroethylene units is based. 7. Überzugsmittel nach Anspruch 4, dadurch gekennzeichnet, daß das Mischpolymerisat ein Polymerisat eines w-Hydroxyalkylvinyläthers ist.7. Coating agent according to claim 4, characterized in that the copolymer is a polymer of a w-hydroxyalkyl vinyl ether is. Vorn Doutsohon Patentamt
ohne }*:·.:Ίο CVw^i::' herge«
stoKi.^ A:.";:»oh.ifi Vviii Unterlagen, dio ;.ί.!Γ fr.tomecha«
nischc-äi Wiedergabe nicht
geeignet sind.In front Doutsohon Patent Office
without } *: ·.: Ίο CVw ^ i :: 'herge «
stoKi. ^ A :. "; : » oh.ifi Vviii documents, dio; .ί.! Γ fr.tomecha «
nischc-äi rendering is not
are suitable. 209810/UOO209810 / UOO
DE1966P0039707 1965-06-15 1966-06-14 COATING AGENT BASED ON POLYSILIC ACID AND A FLUOROUS POLYMERIZATE Granted DE1645145B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US46406365A 1965-06-15 1965-06-15
US46406465A 1965-06-15 1965-06-15

Publications (2)

Publication Number Publication Date
DE1645145A1 true DE1645145A1 (en) 1972-03-02
DE1645145B2 DE1645145B2 (en) 1976-12-23

Family

ID=27040824

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1966P0039707 Granted DE1645145B2 (en) 1965-06-15 1966-06-14 COATING AGENT BASED ON POLYSILIC ACID AND A FLUOROUS POLYMERIZATE

Country Status (4)

Country Link
US (2) US3429845A (en)
DE (1) DE1645145B2 (en)
GB (1) GB1100995A (en)
NL (1) NL151408B (en)

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Publication number Priority date Publication date Assignee Title
US3546318A (en) * 1967-02-09 1970-12-08 Du Pont Polysilicic acid/hydroxyalkyl vinyl ether-polyfluoroolefin copolymer/alkali metal compositions containing cyclic polyethers
US3775171A (en) * 1970-04-28 1973-11-27 Du Pont Article coated with composition of polysilicic acid and silyl-fluoroolefin
US3859330A (en) * 1972-03-15 1975-01-07 Du Pont Ultraviolet absorbing coating compositions
FR2200275B1 (en) 1972-09-15 1978-11-10 Du Pont
US4015057A (en) * 1973-11-14 1977-03-29 E. I. Du Pont De Nemours And Company Abrasion resistant fluoroolefin coating composition
JPS50126722A (en) * 1974-03-26 1975-10-06
US3971872A (en) * 1974-09-30 1976-07-27 American Optical Corporation Process for the production of an abrasion resistant optical element
US4201702A (en) * 1975-10-15 1980-05-06 Blount David H Process to produce allyl halides copolymers
JPS5326832A (en) * 1976-08-25 1978-03-13 Asahi Chem Ind Co Ltd Coating plastic compositions their preparation and applications
US4115622A (en) * 1977-10-07 1978-09-19 Monsanto Company Abrasion resistant coating compositions
US4126601A (en) * 1977-10-07 1978-11-21 Monsanto Company Abrasion resistant coating compositions
JPS6021686B2 (en) * 1980-08-08 1985-05-29 旭硝子株式会社 Fluorine-containing copolymer that can be cured at room temperature
US4556605A (en) * 1982-09-09 1985-12-03 Kabushiki Kaisha Suwa Seikosha Photochromic coating composition and photochromic synthetic resin ophthalmic lens
JPS59138454A (en) * 1983-01-28 1984-08-08 W R Gureesu:Kk Surface treating agent for resin plate
JPS59174657A (en) * 1983-03-25 1984-10-03 Asahi Glass Co Ltd Coating composition
JPS59219372A (en) * 1983-05-27 1984-12-10 Asahi Glass Co Ltd Coating composition
DE3439482A1 (en) * 1984-10-27 1986-05-07 Röhm GmbH, 6100 Darmstadt METHOD FOR COATING SUBSTRATES WITH SCRATCH-RESISTANT, NON-REFLECTIVE COVERS
JPH0757854B2 (en) * 1986-10-28 1995-06-21 旭硝子株式会社 Paint composition
DE3707064C1 (en) * 1987-03-05 1988-03-10 Goldschmidt Ag Th Curable coating agent
DE3882252T2 (en) * 1987-03-10 1994-02-10 Daikin Ind Ltd Vinyl ethers and copolymers containing fluorine produced with them.
US4952653A (en) * 1987-03-10 1990-08-28 Daikin Industries, Ltd. Process for preparing fluorine-containing copolymers
US4855162A (en) * 1987-07-17 1989-08-08 Memtec North America Corp. Polytetrafluoroethylene coating of polymer surfaces
JPS6354469A (en) * 1987-08-14 1988-03-08 Asahi Glass Co Ltd Fluoropolymer for paint
JPH04211482A (en) * 1990-02-23 1992-08-03 Tonen Corp Composition for fluororesin hard coat
US5935401A (en) * 1996-09-18 1999-08-10 Aclara Biosciences Surface modified electrophoretic chambers
US5266455A (en) * 1990-05-23 1993-11-30 Eastman Kodak Company Photographic elements containing protective overcoat compositions
US5179147A (en) * 1990-05-23 1993-01-12 Eastman Kodak Company Protective overcoat compositions and photographic elements containing same
US5037871A (en) * 1990-05-23 1991-08-06 Eastman Kodak Company Protective overcoat compositions and photographic elements containing same
JPH0692555B2 (en) * 1991-10-24 1994-11-16 旭硝子株式会社 Coating composition
US5895713A (en) * 1993-07-14 1999-04-20 Asahi Glass Company Ltd. Method for treating the surface of an outdoor article
US5733644A (en) * 1994-04-15 1998-03-31 Mitsubishi Chemical Corporation Curable composition and method for preparing the same
US6280838B1 (en) * 1997-01-10 2001-08-28 U. S. Philips Corporation Optical element, a display device provided with said optical element, and a method of manufacturing the optical element
US6245428B1 (en) 1998-06-10 2001-06-12 Cpfilms Inc. Low reflective films
WO2000055130A2 (en) * 1999-03-16 2000-09-21 E.I. Du Pont De Nemours And Company Fluoropolymer low reflecting layers for plastic lenses and devices
JP4265887B2 (en) * 2002-05-08 2009-05-20 富士フイルム株式会社 Antireflection film, antireflection film and image display device
JP2005075880A (en) * 2003-08-29 2005-03-24 Du Pont Mitsui Fluorochem Co Ltd Low-electrostatic heat fusable fluororesin composition
US9027635B2 (en) * 2004-08-24 2015-05-12 Waters Technologies Corporation Heat exchange surface including a hydrophobic coating layer
US7332545B2 (en) * 2004-09-30 2008-02-19 Ppg Industries Ohio, Inc. Fluoropolymers, methods for their production, and thermosetting compositions containing them
WO2006039658A2 (en) * 2004-09-30 2006-04-13 Ppg Industries Ohio, Inc. Thermosetting coating compositions comprising a copolymer formed from chlorotrifluoroethylene and methods of making copolymers formed from chlorotrifluoroethylene
US20100186152A1 (en) * 2009-01-24 2010-07-29 Phillip Freeman Light Attenuating Shield for a Motorcycle Helmet Visor
PL2616512T3 (en) 2010-09-17 2015-03-31 Evonik Roehm Gmbh Weather-resistant, dyed molded part having improved shine and wipe resistance
EP3772527A1 (en) 2019-08-08 2021-02-10 Evonik Operations GmbH Transparent composition

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US2317891A (en) * 1939-06-09 1943-04-27 Pittsburgh Plate Glass Co Waterproof adhesive composition
US2600683A (en) * 1947-05-08 1952-06-17 American Viscose Corp Trifluorochloroethylene-vinyl acetate copolymers
US2592147A (en) * 1947-05-23 1952-04-08 Du Pont Codispersions of polytetrafluoroethylene and hydrous oxides
US2906658A (en) * 1958-02-05 1959-09-29 Du Pont Method for the preparation of cementable fluorocarbon polymer surfaces
US3324055A (en) * 1963-02-15 1967-06-06 Alvin M Marks Abrasion resistant coating of organic polymer, inorganic polymer, and monomers reactive therewith

Also Published As

Publication number Publication date
US3429846A (en) 1969-02-25
GB1100995A (en) 1968-01-31
US3429845A (en) 1969-02-25
NL151408B (en) 1976-11-15
DE1645145B2 (en) 1976-12-23
NL6608316A (en) 1966-12-16

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
E77 Valid patent as to the heymanns-index 1977
8339 Ceased/non-payment of the annual fee