DE1569879C - - Google Patents
Info
- Publication number
- DE1569879C DE1569879C DE1569879C DE 1569879 C DE1569879 C DE 1569879C DE 1569879 C DE1569879 C DE 1569879C
- Authority
- DE
- Germany
- Prior art keywords
- paper
- glue
- label
- labels
- papers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000001035 drying Methods 0.000 claims description 13
- 229920003023 plastic Polymers 0.000 claims description 10
- 239000004033 plastic Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002985 plastic film Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 235000015243 ice cream Nutrition 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 2
- 229920001888 polyacrylic acid Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 239000000123 paper Substances 0.000 claims 17
- 239000003292 glue Substances 0.000 claims 8
- 239000000853 adhesive Substances 0.000 claims 7
- 230000001070 adhesive Effects 0.000 claims 7
- 229920000642 polymer Polymers 0.000 claims 4
- 238000002360 preparation method Methods 0.000 claims 4
- 238000004026 adhesive bonding Methods 0.000 claims 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 3
- 239000000969 carrier Substances 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 239000011111 cardboard Substances 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 2
- 229920002959 polymer blend Polymers 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 239000002023 wood Substances 0.000 claims 2
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- 229910000906 Bronze Inorganic materials 0.000 claims 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N Crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000010974 bronze Substances 0.000 claims 1
- -1 carboxy- Chemical class 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N fumaric acid Chemical compound OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 230000001788 irregular Effects 0.000 claims 1
- 238000002372 labelling Methods 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 239000011528 polyamide (building material) Substances 0.000 claims 1
- 229920002689 polyvinyl acetate Polymers 0.000 claims 1
- 239000011118 polyvinyl acetate Substances 0.000 claims 1
- 229920000131 polyvinylidene Polymers 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 230000000638 stimulation Effects 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000002904 solvent Substances 0.000 description 5
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N Tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-Ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 235000019749 Dry matter Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N Maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- UGAPHEBNTGUMBB-UHFFFAOYSA-N acetic acid;ethyl acetate Chemical compound CC(O)=O.CCOC(C)=O UGAPHEBNTGUMBB-UHFFFAOYSA-N 0.000 description 1
- VFGRALUHHHDIQI-UHFFFAOYSA-N butyl 2-hydroxyacetate Chemical compound CCCCOC(=O)CO VFGRALUHHHDIQI-UHFFFAOYSA-N 0.000 description 1
- RTIAQOLKVLAEAU-UHFFFAOYSA-N hexan-3-yl acetate Chemical compound CCCC(CC)OC(C)=O RTIAQOLKVLAEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
Description
tend wieder getrocknet. An. Stelle der Polymethicrylsäure kann auch ein Copolymerisat aus 90% vlethacrylsäure und1 10% Vinylacetat verwendet -verden. Die Trocknung des Kunststoff-Filmes erfolgt η einer Trockenhänge.tend to dry again. On. Site of Polymethicrylsäure can also be a copolymer of 90% vlethacrylsäure and 1 10% of vinyl acetate used -verden. The drying of the plastic film takes place η a dry slope.
Es wird folgende Kunststofflösung aus einem •arboxylgruppenhaltigen Copolymerisat hergestellt: 8 kg eines Copolymerisate aus 35 % Methacrylsäure ind 65 % Methacrylsäuremethylester werden in einem .ösungsmittelgemisch aus 61,5 kg Äthylglycol und !0,5 kg Tetralin aufgelöst. In diese Lösung rührt nan noch 35,7 kg einer 70%igen Lösung von PoIy-/inylmethyläther (K-Wert: 40) in Toluol ein. Diese Cunststofflösung wird mittels einer Rakel auf die lückseite einer Cambricpapierbahn aufgetragen, wojei der Kunststoffauftrag 12 g/qm, bezogen auf Trockensubstanz, beträgt. Das Lösungsmittel wird lurch Trocknen in einem Trockenkanal verdampft.The following plastic solution is made from a • copolymer containing arboxyl groups: 8 kg of a copolymer of 35% methacrylic acid in 65% methacrylic acid methyl ester are in a Solvent mixture of 61.5 kg of ethyl glycol and 0.5 kg of tetralin dissolved. Stir into this solution nan still 35.7 kg of a 70% solution of poly- / inylmethylether (K value: 40) in toluene. This plastic solution is applied to the applied to the back of a Cambric paper web, wojei the amount of plastic applied is 12 g / m², based on the dry substance. The solvent will evaporated by drying in a drying tunnel.
Eine Kunststofflösung, die gemäß Beispiel 2 hergestellt worden ist, wird mit HiWe einer Rakel auf ine Kunststoffolie aus Polyvinylchlorid, die eine )icke von 40μ besitzt, aufgetragen. Der Kunststoff- -uftrag beträgt 8 g/qm, bezogen auf Trockensubstanz. )as Lösungsmittel wird durch Trocknen im Trockenianal verdampft.A plastic solution produced according to Example 2 has been, with HiWe a doctor blade on a plastic film made of polyvinyl chloride, which is a ) icke of 40μ has, applied. The plastic application is 8 g / m², based on dry substance. ) The solvent is removed by drying in a drying chamber evaporates.
Es wird eine Lösung von 20 kg Polyacrylsäure in einer Mischung aus 40 kg Äthanol und 40 kg Methanol hergestellt. Diese Lösung wird auf die Rückseite einer Papierbahn aus Glacepapier in einer Stärke von 12 g/qm, bezogen auf Trockensubstanz, aufgetragen. Das Lösungsmittel wird durch Trocknen im Trocken kanal verdampft.It is a solution of 20 kg of polyacrylic acid in a mixture of 40 kg of ethanol and 40 kg of methanol manufactured. This solution is applied to the back of a paper web made of ice-cream paper in a thickness of 12 g / qm, based on dry substance, applied. The solvent is made by drying evaporated in the drying tunnel.
Es wird eine Lösung eines Copolymerisate aus Maleinsäureanhydrid, Vinylacetat und Vinylchlorid in einer Estermischung aus gleichen Teilen Äthylacetat und Butylacetat hergestellt. Die Lösung wird mittels einer Rakel auf die Rückseite einer Papierbahn aus Hochglanzglacopapier aufgetragen. Der Kunststoffauftrag beträgt 10 g/qin, bezogen auf Trockensubstanz. Das Lösungsmittel wird durch TrocknenIt becomes a solution of a copolymer of maleic anhydride, vinyl acetate and vinyl chloride produced in an ester mixture from equal parts of ethyl acetate and butyl acetate. The solution will be applied by means of a doctor blade to the back of a paper web made of glossy glass paper. The plastic application is 10 g / qin, based on dry matter. The solvent is made by drying
ao im Trockenkanal verdampft.ao evaporated in the drying tunnel.
Eine Lösung aus 15 kg eines carboxylierten Methacrylsäureesters in 35 kg Glykolsäurebutylester und as 7 kg Tetralin, wird auf die Rückseite einer Papierbahn aus Velourspapier aufgetragen. Der Kunststoffauftrag beträgt 15 g/qm, bezogen auf Trockensubstanz. Das Lösungsmittel wird durch Trocknen in einem Trockenkanal verdampft.A solution of 15 kg of a carboxylated methacrylic acid ester in 35 kg of butyl glycolate and 7 kg of tetralin as is on the back of a paper web Applied from velor paper. The amount of plastic applied is 15 g / m², based on the dry substance. The solvent is evaporated by drying in a drying tunnel.
Hierzu 1 Blatt Zeichnungen 1 sheet of drawings
Claims (1)
daß kein gleichmäßiger Leimauftrag erfolgt und die In der Zeichnung bedeuten 1 bzw. 4 das Träger-Etiketten bzw. Zuschnitte schlecht auf dem beklebten papier, das holzfrei oder holzhaltig sein kann, 3 den Gegenstand haften. 40 Oberflächenveredelungsstrich und 2 bzw. 5 die hydro-Erfindungsgemäß werden diese Nachteile vermieden phile Rückseitenpräparation aus einer carboxyldurch die Verwendung von gegebenenfalls mit einem gruppenhaltigen Verbindung, auf welche bei Ge-Oberflächenveredelungsstrich versehenem Papier oder brauch der Etiketten bzw. der Zuschnitte der Leim von Kunststoffolien, die mit hydrophilen carboxy- aufgetragen wird.Cases and other utensils are used. B. Polyz. B. Chromo or Cambric paper used, the first - acrylic acid, methacrylic acid, maleic acid, crotonic acid at the point of use on their back with and their salts and the like Form of copolymers or based on sions. Polymer mixtures with other carboxyl group-such labels or blanks have the 25-containing vinyl compounds or other compatible disadvantage that they are borrowed when applying the glue, compounds such. B. polyacrylic acid esters, poly-caused by the impact of the moisture of the methacrylic acid esters, polyvinyl chloride, polyvinylidene used adhesive, have a strong tendency to roll, so that chloride, polyvinyl acetate, polyvinyl alkyl ethers, polycycles are often difficult to stick to the vinyl acetate, styrene, etc. The only condition is that that Have the object applied. Another disadvantage of copolymers or polymer mixtures in water, which is often observed, is that the glue is swellable. The arrangement of the individual layers even penetrates through the paper, so that the drawing shows, in the enlarged top side of the label or the blank, on a larger scale A, a cross-section through a label made of natural paper that has been prepared in advance after drying that make the label or the blank unsightly 35 and B a cross-section through a device according to the invention. It also often happens that the pre-prepared label from a surface glue is repelled from the label paper, so that noble paper is displayed,
that there is no uniform application of glue and that in the drawing 1 and 4 mean the carrier labels or blanks badly on the pasted paper, which can be wood-free or wood-containing, 3 the object adhere. 40 surface refinement coating and 2 or 5 the hydro-According to the invention, these disadvantages are avoided. which is applied with hydrophilic carboxy-.
carboxygruppenhaltigen Polymerisat-Präparationen besteht aber vor allem darin, daß das Etikett oder sein Beispiel 1
Zuschnitt noch wasserdampfdurchlässig ist und damitThe entire label surface is assumed to be even. Below are a few examples of how a perfectly perfect bond is obtained. The special advantage of the hydrophilic, 55 page preparation used is listed,
Polymer preparations containing carboxy groups mainly consist in the fact that the label or its example 1
The cut is still permeable to water vapor and thus
Family
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