DE1553843A1 - Razor blades and process for their manufacture - Google Patents
Razor blades and process for their manufactureInfo
- Publication number
- DE1553843A1 DE1553843A1 DE19661553843 DE1553843A DE1553843A1 DE 1553843 A1 DE1553843 A1 DE 1553843A1 DE 19661553843 DE19661553843 DE 19661553843 DE 1553843 A DE1553843 A DE 1553843A DE 1553843 A1 DE1553843 A1 DE 1553843A1
- Authority
- DE
- Germany
- Prior art keywords
- chromium
- cutting edge
- razor blade
- wira
- blade
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000005520 cutting process Methods 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 8
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000004566 building material Substances 0.000 claims 1
- 150000001844 chromium Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- NIZMMTPPMYSMRK-UHFFFAOYSA-N C=C.O.O.O Chemical group C=C.O.O.O NIZMMTPPMYSMRK-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/60—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5846—Reactive treatment
- C23C14/5853—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/02—Pretreatment of the material to be coated
Description
PatentanwältePatent attorneys
4 Düsseldorf-Oberkassel, den .4.o...Mai... 1.9.6.0.4 Düsseldorf-Oberkassel, May 4th ... 1.9.6.0.
"j 434 Teutonen«nße4"434 Teutons" nße4
Fernnrf 571628Fernnrf 571628
Wilkinson Sword 'Limited , 16 Pall Mall, London SV/ 1», Rasierklinge und Verfahren zu ihrer Herstellung Wilkinson Sword 'Limited, 16 Pall Mall, London SV / 1' , razor blade and method of making it
Die Erfindung besieht sich auf eine Rasierklinge und .auf ein Verfahren zu ihrer Herstellung.The invention relates to a razor blade and a method for making the same.
Gemäss der Erfindung wird eine Rasierklinge geschaffen, die mindestens in der Oberfläche ihrer einen oder aller ihrer Schneidflächen Chromoxyd enthält.According to the invention, a razor blade is created that at least in the surface of its one or all of their cutting surfaces contain chromium oxide.
Die Maßnahme, diese Flächen mit Chromoxyd zu versehen, wird vorgenommen, um der Rasierklinge durch eine Steigerung der Dauerhaftigkeit für die Schneidkante verbesserte Eigenschaften zu geben.The measure to provide these surfaces with chromium oxide, is made to the razor blade by increasing the durability for the cutting edge to give improved properties.
Ein Verfahren zur Herstellung der mit Chromoxyd versehenen Oberfläche besteht erstens darin, diese Oberfläche mit Chrom zu Überziegen, das anschliessend oxydiert wird. Eine weitere Möglichkeit besteht darin, die Oberfläche mit Chromoxyd zu überziehen,wobei der Oxydationsvorgang gespart wird. Bei noch einer weiteren Methode kann der Chromsehalt mindestens im Oberflächen-One method for producing the surface provided with chromium oxide consists firstly in this surface to be coated with chrome, which is then oxidized. Another option is to use the Surface to be coated with chromium oxide, the process of oxidation is saved. In yet another method, the chromium content can be at least in the surface
009883/00U009883 / 00U
teil der oc.ia^ia mte aer Husierklingt aus ro^tii^ie; Stahl mittels Verchronieu mit anschliessenaer Q angereichert werden.part of the oc.ia ^ ia mte aer Husierklingt from ro ^ tii ^ ie; Steel by means of Verchronieu with a connecting Q be enriched.
Eine Möglichkeit sur Herstellung soli in folge,.den mit näheren Einzelheiten beschrieben werüeri. Z-erct weraen die Schneidkanten der Hasierklinge gereinigt, .vorauf aaschliessena eine ^Urme ocaicnt aas 'j.:rjn, ciertn Stärke beispielsweise uüterr.alb 400 Angstrom litgt, au wird. .Die Scniciröstarke liegt vorzugsweise unter 10J Angstrom, jaaac.i wird aie Rasierklinge angdlasie;!, um die Bindung mit aer ^cnicht zu verbesserte Sc^iiesslica wird die Klinge in eineiu OxjdatioLSgas vrärmebe..aadelt. Die Beschicntung mit Ghrcm una die anschliessenae Vergütung kann durchgeführt werden, ohne dai die Säte der Schneidkanten Deeinträchtigt wird. Es ist hierbei möglich, diese beiden Vorgänge in einem Arbeitsgang durchzuführen.One way of producing soli in a row is that with werüeri described in more detail. Z-erct weraen the cutting edges of the chaser blade cleaned, before closing a ^ Urme ocaicnt aas' j.:rjn, ciertn strength for example uüterr.alb 400 Angstrom litgt, au will. The Scnicirestarke is preferably less than 10J Angstrom, jaaac.i is angdlasie aie razor blade;!, Um the binding with aer ^ cnot to be improved Sc ^ iiesslica the blade is heated in an oxydation gas. The supply of Ghrcm and the subsequent remuneration can be done without sowing the seeds Cutting edges is impaired. It is possible to carry out both of these processes in one operation.
Danach kann uie Klinge mit überzügen oder Materialpartikeln versehen werden, um das Rasieren zu erleichtern, wie beispielsweise mit den bekannten oder mit neuen überzügen, wie sie in der Beschreibung des belgischen Patentes 504 784 vom 5.April 1963 auf den Ilameü Wilkinson Sword limited beschrieben sind. Die für die Vulkanisation der Polytetrailuoräthylenschicht erforderliche wärmebehandlung kann in einigen Fällen ausreichend sein, um das AnhaftenThen the blade can have coatings or material particles be provided to facilitate shaving, such as with the known or with new covers, as described in the description of the Belgian patent 504 784 of April 5, 1963 for the Ilameü Wilkinson Sword limited. The heat treatment required for the vulcanization of the polytetrafluoroethylene layer can in some cases be sufficient to prevent the sticking
undand
zwischen dem im Schutzgas aufgebrachten ChronPfäer Rasierklinge sicherzustellen.between the ChronPfäer razor blade applied in protective gas to ensure.
009883/00U009883 / 00U
Bei dem "Verfahren zur Heiui^ung aer Klinge müssen uie· irerkstofieige^schuxten aer Klinge- ueriicksichtigt werden. Zweckmässige Verfahren sind: Eintauchen in ein organisches Lösungsmittel, beis jielsva.iue Yrichlor- :'lthyle-u, -falls erforderlich mit Ultraschallvibration, mit anschließendem Trocknen; Entfetten in einem Triahioräthylengas; j-liaüiei.tladung oder kurzes anodisches Ätzen. ϊ/erm aas letzte Verfahren mit einer wässrigen Lösung von Cromtrioxyd angewendet wira, kann dieses zugleich asu oben beschritb^aen Verehronungsvorgang darstellt:!.In the process of heating the blade must The irrelevant parts of the blade were taken into account will. Convenient procedures are: immersion in an organic solvent, beis jielsva.iue Yrichlor- : 'lthyle-u, if necessary with ultrasonic vibration, with subsequent drying; Degreasing in a trihydrate ethylene gas; j-liaüiei.tladen or short anodic Etching. ϊ / erm as the last method with an aqueous solution of chromium trioxide is used, this can at the same time as the worship process described above represents:!.
Das bevorzugte Verfahren zur Beschichtung der Klinge icaiiii entsprecaeua der besten Eignung für aas benutzte Material ausjewä.ilt werae... j-eispiele für mögliche Verfahren si.:a Gfasaolagerung, /».uisprit^o:,, möglicuer-Wüise ,T.it einem Joiit:.s«ra:ilf .'lersteiieii des tbersuges durch iilektroplautier-w-i oder 3-äsreaktionen.The preferred method for coating the blade icaiiii corresponds to the best suitability for aas used material ausjewä.ilt werae ... j-examples of possible methods si.:a Gfasaolagerung, / ». Uisprit ^ o: ,, möglicuer-Wüise, T. with a joiit: .s «ra: il f .'lersteiieii des tbersuges through iilektroplautier-wi or 3-a-reactions.
As tut ocnliesslich notwendig, eine gesteuerte Oxydation der Metalloberfläche vorzunenmeu. Dies kann erreicht ,viüra^n durch ,iarme^ehandluu^ in eiijer bestimmte:, J-U ..Alle, i., der aer Betrag von verneine"υnem üa^r^iOi':1 ^usm bfcgrcust ist. bais_ islsvieise können aie ■ Klingen aaf 400° G in. L:.it bei einem Drucic von TO"·3 Jorrioeili er.iärit werutn. •ii.ic v/eitti'e -lüglichkeit ubstent in der elcitroiytiichen ieha.idlung in einem It is also necessary to carry out a controlled oxidation of the metal surface. This can be achieved, viüra ^ n by, iarme ^ ehandluu ^ in eiijer certain :, JU ..all, i., The aer amount of negative "υnem üa ^ r ^ iOi ': 1 ^ usm bfcgrcust is. Bais_ islsvieise can aie ■ Blades aaf 400 ° G in. L: .it with a print from TO "· 3 Jorrioeili er.iärit werutn. • ii.ic v / eitti'e -lülichkeit ubstent in the elcitroiytiichen ieha.idlung in one
zihcsices iie'-Z*ol\ ten..zihcsices iie'-Z * ol \ ten ..
bad 009883/OOUbad 009883 / OOU
Die elektrolytische Behandlung Kann auch aurch eine Glimmentladung in Luft bei geringem Druck, beispielsweise einem Druck von 100 Mikron vorgenommen werden. Ein Merkmal der Erfindung besteht aarin, üaß der Betrag an während des Oxydationsvorganges vorhandenem Sauerstoff äusserst genau überwacht wird.Electrolytic treatment can also be carried out by a Glow discharge can be carried out in air at low pressure, for example a pressure of 100 microns. A The feature of the invention consists in the amount of oxygen present during the oxidation process is monitored extremely closely.
rfenn uas Verfahren bei einem rostfreien Stahl angewendet wird, der fin1 die Herstellung von Rasierklingen benutzt werden kanu, beinhaltet dieses vorzugsweise eine Entfettung in Gas, nämlich Trichloräthylen oder Chloroform, eine Beschichtung mit Chrom durch Gras ablagerungen, ein Anlassen im Vakuum zum Binden uer abgelagerten Schicht mit der Schneidflache, eine Oxydation in einer geregelten Gashülle bei Temperaturen bis zu 450° C und aas Auf bringen einer Schicht von Polytetrafluoräthylen.rfenn uas method in a stainless steel is used, the fin 1, the preparation is used by razor blades canoe, includes this preferably a degreasing in gas, namely trichlorethylene or chloroform, a coating with chromium through grass deposits, annealing in vacuum uer for binding deposited Layer with the cutting surface, an oxidation in a regulated gas envelope at temperatures up to 450 ° C and aas on bring a layer of polytetrafluoroethylene.
-5--5-
009883/00 U „ r 009883/00 U " r
Claims (1)
durchgeführt wira.in eii.cm flii sigeu iilfc
performed wira.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1908565 | 1965-05-06 | ||
| GB1908565 | 1965-05-06 | ||
| DEW0041510 | 1966-05-06 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE1553843A1 true DE1553843A1 (en) | 1971-01-14 |
| DE1553843B2 DE1553843B2 (en) | 1976-02-26 |
| DE1553843C3 DE1553843C3 (en) | 1976-10-14 |
Family
ID=
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7152526B2 (en) * | 2002-01-29 | 2006-12-26 | Nihon New Chrome Co., Ltd. | Surface treated doctor blade |
| US7673541B2 (en) * | 2004-06-03 | 2010-03-09 | The Gillette Company | Colored razor blades |
| US8505414B2 (en) | 2008-06-23 | 2013-08-13 | Stanley Black & Decker, Inc. | Method of manufacturing a blade |
| US9393984B2 (en) | 2010-09-10 | 2016-07-19 | Stanley Black & Decker, Inc. | Utility knife blade |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7152526B2 (en) * | 2002-01-29 | 2006-12-26 | Nihon New Chrome Co., Ltd. | Surface treated doctor blade |
| US7673541B2 (en) * | 2004-06-03 | 2010-03-09 | The Gillette Company | Colored razor blades |
| US8505414B2 (en) | 2008-06-23 | 2013-08-13 | Stanley Black & Decker, Inc. | Method of manufacturing a blade |
| US9393984B2 (en) | 2010-09-10 | 2016-07-19 | Stanley Black & Decker, Inc. | Utility knife blade |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1553843B2 (en) | 1976-02-26 |
| US3480483A (en) | 1969-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| E77 | Valid patent as to the heymanns-index 1977 | ||
| EHJ | Ceased/non-payment of the annual fee |