DE1470999A1 - Process for making hydrocarbon-containing resin products - Google Patents

Description

BATH / KISI, H ¹ . WIK310W Kiverβid · Drive »Cleveland?, Ohio, United

by Acorlka

Process for the production of kohlenfcaaneretofihfiltit.er Kerzpro-

dukes

. The invention relates to the Heretellung faarzartiRer product · FTUS high boiling _t aroir "Kohlcnvasneretiofren-Nazi, inßtosondere from RQcketändea and fractions ßt from the Kohlentoordoetlllstion & nn: s. The invention aims above all to obtain a nouon klaaso from Haraen, which under sebr {Torlncen Xo3ton, compared with the division of übliohoa Harzon and Folycii "rieaten _t wi © Vinylhorsen * Fhonolaldeiiydber * ZQn or? Uranhorsen, which ohrm from coal sources lcicbt "u ^ nslich ur .-: l 'ear prßlav". rdis beef "hersestallt verden klSnnon the" ßrfincJuns bezvßckt voltcrhin the Ccbaffung of heart "dl" Oehr "beständiß; pfiztn ^ crar.ertituroinfltlaße and Chcxaikalion" as Shuren "Bßron and L "sun _; ? snit.töl, sir :: ¹¹ . The, ". Rfin-Jung ocbracht Ilarso, who in Pulvftrfora old?? UliatOi tone

90981 2/0983

. .... J .. "succumbed (Art.7SIAb8» 2No.] SentenceYeseaAncier

BAD Of ^ m ^

IT / K * \ J \ J \ J

to Herntollunr of Forr.kor-pern, auaaiaaon oils suspension sit films "for the production of laminates o ^ he ale melt Xür the laprsgnierunn can be used porous bodies ·

The invention is characterized by the reaction of Caey'-dehydrating agents with hydrocarbons to form natural products. The nature of the starting materials is explained in more detail here aoin when the üiasetsung only partially odor unvollofcäncli}> 1st or which can infusible and relationship-B ^l i8 "ig insoluble and not be volatile" if complete charge "- is hrirtet · Depending on the used VorhOltnie of oxidation" * nittel BU Hydrocarbons can be the heat- resistant, heat-borne, nuoreichond oxidizing agents which are used to achieve a uniform hardening, or they can be thermo-bondable, but not heat-borne, in order to prevent oxidation.

In the following, the expression tech becomes "Eeseichnun"; Carrion of gongmr.aterii "2sverwendet, the old Ernest Oxydetlocsclttel for Ge * 'Guild is urntjöeetat a thermoplastic, or hitzobHrtbsren hitzcgeh'.rteten Uerxee · Sin for dos erfiik'irr, i; _ir:. asse proceeded suitable" pitch can as folct defines Acrdont. '. in solid, semifantcÄ odor viocoae ", liquid jctorial, which contains the usual ilohlonwcn ^ cr materials and is softened by Viirase when we meet us" üchailafc or his Viecoeitat vercinCrt "

909812/0983

BATH ORIGINAL

and (β) 25 ° C gave a specific gravity of 1.02 or high possesses, based on Veoser at 4 ⁰ C, and (b) at "heating for 72 hours at 450 ⁰ C in a genchlosfjenen Gefiiaa in which Oine Deatilletion not "5f: LICB is at least 60 #, be ·· Eogen on d heated s weight see pitch," stainless © substances results that upon further heating at 950 ⁰ C and Atisosphilreniruck, ^ e - ^ c * in Abvae <? nb "lt of oxygen, a Kohler.atoffrückatond result" of at least SO # of the wet Gtofi ^ o i.ua de ~ * Fach bouoeicnota Pcchcrtcn iinden eicii unburdened & n kohlcnvir.asoxw substances, velcho in the chemical terminology

Oils Aroaatil-a b ^ shows wc-rdcn, although not olle eron? ÄtiGchen connections suitable siri. In the nciston filling ötiiraeien ÖIE lech & rten cue the Kohlentoor _whether: -XgIcIi some sweeteners which aue dee Srööl "taiBsen, for the e genüane method seeip; are net · Pie pitches can either RfickstUncJe oiäer fractions eein by distillation" Lö Bunjrasiittol fractionation or have been isolated by other cathodes

To achieve the goal of the polyf * rlofition of the population, Jeuen can Cxydstioncnittfcl organic or enormous, fer.ter «fluo- or ßoeforaicsr! letur used verden · Co vurden at ·

Heifer using the following tel manufactured! a-Dlnitrobenzene, TikrinsKure «

909812/0983
BAD ORK3INAL

Benssoldloulfonettore, Salpetereliure oder Ammoniumnitrat * Toot practical calibrations, so the selection of the Oxydetionanlttols is determined in advance by whether it is old deo Pech in xur Herbffiffihrunc the lelynerieation sufficient Kengea miscible let, and whether the? IQchti £ low lccit that it does not evaporate the bad luck before the implementation of the conversion.More considerations are that there is no great tendency to be more violent or explosive, as is the case with permanganates or chlorines ₉ and that the Gxydetioneycrcögan St unit of weight borrowed as high as ο% is "Organic · Cxydaticnealttel are therefore useful,% m & anter this βΐηβ strong daroh oxidizing Reete" tibstitoierts agent for the United · Tahren after $ rflndung particularly suitable * Very erwSnecht · Oxjd "tioncmlttol fOr the polymerization of pitches among the compounds n- Dinitrobene sol ind the blocks of Kitrlertin sprouts under the raw glue.

Ala example for Ale polymerization of a pitch nit einets detlonsalttel Consider the following erwBhntx Bine Miechung of 80 ropes of a "middle * pitch has ₉ received the" s aas a Teerdeatillatloneanlege _t and 20 parts of M-Dlnltrobensol is • ine Vooh · at £ 05 ° C · erhitet the product is a gl £ nxender _t black, solid * His Oewicbt betrSßv 66 '8% voa weight of the pitch and the n-Kltrobensols or 100.5% of the weight of the pitch used · the product 1st in only one Keng · of 10.0 % in benzene 18slloh | after the »Erhitaen at 950 * 0

809812/0983

BATH ORIGINAL

remain 72.3 % XQbleastoffrUokatand · The material is completely bltsegehlttet and is not a sign of Sehaelsea when heated · laughs when it is made up of a fine powder and heated to 95O ° O, the carbon fruokafcand is a loose powder * no matter what Softening took place asked, the su a «sticking of the particles led please ·

Before the course of the reaction * in which, as described, an exercise in one. Bad luck and n-uinitrobentol χα oincn heat « hardened clay, organic, boron artiβη the product is unrefilled, can ean the XUr a Folynerieation oharaktcrietl hands · » watch wrestling »The printouts *> polynerieleren", "Folynerieatlon", * poljiteriabaren · us «are beer in their broad, all-» common meaning used you should point out, doaa any fora des Kolektllwachatuas before »icb goes, by which the relations & esle small reehm molecules in large HolekQls without foresight of a substantial part of the initial asterisis Qagewsndelt are · PQr Foljoerlsationsreaktlonen is It is characteristic that a with increasing orad of the molecular growth the insanity abniaiat, viocoeitat and schselpunkt increase and the flQebtigkelt abniaet · Eoi of the described Polymerization is the initial phase in the time when sis is raised to reaction temperature as soon as possible, a ratio » ■ Hssig niehtvisoos · casualness · With the passage of time with Resktiossteaperstnr thicken the liquid, becomes to • in a cast, semi-solid material, solidifies itself finely

909812/0983
BADOmQlHAL

let dean also at Beaktioaateaporatar feat *

a lot of "practical affinity asweofce the new Hor * o auias dl · Poljaerieation stopped in a α Zwiochenatadiua dar HHrtang, are · These partially handled products «are because old fillers, * le Asboat, cellulosic fabrics and the like,

or old layers or Bogon XOr the Schichtotorfborotstellung, such as Aobeetf Ilsen or -.ge we bon, Papior, Geweben, Clossuitton and -geweben, Koabinlert · The masses, partially gohtirtetea * hittflhartberoa Bara and ptllletoff, were later made from Fora "bodies further heat in «boiopicle-« ice · in elnor forepreaae oiler «rollers wipe door the layer- • tofXberatellurfj, processed.

VShrend Λ · τ Heratellun? one can qualitatively recognize the desired, partially bSrteteo, hitting-visible ears from the fact that "hoaktlonsBlcchung" at Heaktlonnenporotur in uinen. "Ehr visoosen, gammlartlsen, holbfeaten substance has uagevcndoit, de« turned leg cooling to 25 ⁰ C in a spr3den "shiny * fixed Btoff · PSr the Fraxls child quantitative means necessary, daa Erkennon and F" ststollon of useful, partially gehurteten _The audible Haraa could not be heard. Until the "property of the hearts that are sunk for this purpose" know the solubility, where Benaol is a sveokaSaslgaa

/ O983

BAD LOCATION

The LUalicfckcit an Eoasol is taken, indea nan a · Frobe dee Hartes, which has been so finely processed that it passes through a sieve with a beloved tiasobenuelte of 0.28 (65 tteeh), one hour with IQO ca ** benzene under ι Kückflusa "erhltst according to ärhltsen under Kückfluse brings cum dee undissolved material to a getrogenes filter, dried at 1QO to 11O ⁰ C and weighs" the part-cured "hitsoh &-curable Hard sacB the invention are sti 25 to 60 $, often au 35 to may 4-5 ff in Bonaol löolioh · the vollatändijj gebürteten _f bitseisebSrteten beard, dlo "to either as _f in the attached drove" · ten sample directly barren by veiterea £ rblts "n the partially CQhSr te _th% bltsebUrtbaren Hard rush advises, tremble "ine happiness i"; Bensol iron less than 35 9>, usually veniale 25 $ t «anebaal less« le IO £ ·

When sharing the hearing of the new, bit-sustained Hsrse aues dl Polyaeriaefcion by KGbIoη at the gevUnscbtea degree of partial BSrtuns eeetoppt. The in the described Veiee beetlBiate IiSellobkolt know as Krlterlust star recognition of punk Serve tea, at which the usual degree of partial twisting srrelobt 1st · However, a bit of a rough tteaaung can be worse verblandern, desc the reaction about the desired BBrtune level The result is that “file eobselebarkelt is a reach geneaene Property for these i ^ ok, although the usual Beati «» uneeB «tboden der Sehaelsbarkelt not suitable for this are"

909812/0983

BATH

U70999

The fragility or the melting point are not a property of how the solubility can be determined. Even the commercially available pitches shake before the orfindunscfteaSeeen Uo- "? T8ang For the formation of the polymerization product" no real melting points · They rather soften and evaporate within a temperature range "! The so-called melting points of rakes are determined by empirical rothodes well known in technology. In the case of the present loljraerieetionsradee these empirical methods are not very applicable, although the ability to pinch is still after an oleically far advanced polynerlontion Ee can be used because of the flooding of the Echraclübarkcit from bochpolyEerlsiertcn £ arxen _t even if a quick point can no longer be established with these ₉ different test methods

Cine of these proXcsothodes the "draw point" of the bars "is sieved. To determine the" Kitupanktes "ice kotallblook" the "with a device to keep its temperature easier" is requested to the extent that the "application of a thin layer Or a “dönnen spread de« nerse «tu unlove · Kan lHset the ketallblock then ebktlh · len _f as» η an «echorf« metalspitse upper dl * surface dea l of at riches sees · Σ> 1 · Klcdeötteicporotur, fcoi der An impression made by the metal splits or a ritual oil can be observed is the fourth point of the Hanson. E «

909812/0983

_JAVHötftÖ 0Λ8 SAO

v was found »deae dor sitepoint In a pretty close relationship on other, more common falsehoods, such as the rwtrlchung · or Melting point "der Fllessgoechwindlgkoit uav", otcht. The Eeetlamung des ritpunktoe hot don advantage »that they are in l & on A few minutes can be voreenosaen »« Shroud the polymer ion reaction is carried out.

The partiall whored et en thermosetting resins after the <? Rf charge have sen por8-Ritspunkte within the range ^175-0 although Harse With hits punk sound below 175 ⁰ C for oanehe Vexv wendungestreck · "example f3r di · Iniprüsnierang of Korperv" erwQnecht be · can for dao Vermlechen xlt a iQlletoff and manufacturing Forakurpern lie 13t of Kitspunkt often within dee Pereich · from 200 to 260 ⁰ C · Ge * legent-llch "example" hen a "n a verhHltnlsn ^ never salg" · drlgefl ratio of Her * su filler in a Freennaaß · use and trotsdt "the good? lleeeeifronnc! aften maintained bays" may ea iiOnechenewert oxidase the Ritz point Ia range of 175 bi · 200 ⁰ C his "lies · Venn of Hltzpunkt an extraordinary high value" 1 · 175 ⁰ C has reached "1st progressed the polymerization to below a level" of the Vervendung the door Trodukts the "Eisten practical Verven") ungsswecke ermSgllchti products with a Ritspunkt below 175 ⁰ C ₉ of which e Some even have melting points determined by the usual cathodes "can be useful" if the other processing is carried out in a closed cyete.

909812/0983

BAD OWGlNAL,.

With the described flotb'ode one can beetlmcienBtapanVt · bl · zu otw «300 ⁰ C · Approximately at these» tendrils dl · doors »on which the resin to achieve a satisfactory finish can be heated to» so high «that di * Armor -, the Earsses quickly voranaobreitet and dlo BltspanktMseanff not Beginner reproducible and within acceptable Srensen "inn · fully 1st" the Härtungssrad the nouen _t cnUeder hitaehÄrtbaren or theraoplastischen Karge can such a "bits" point deee above the range of 175 to 275 ° C 1Ι · β * · · · d urine but can clam alzen above 275 ° C ".Ub determine the Sobmelsbeurkelt ia range from 275 to 400 ⁰ C * the following PrUfmethode is used! A Karzprobe # which is a »fine powder» which, for example, rotates through a sieve »with a light cheese world of 0.208 as, and is in a covered crucible or» falls in and out of the air. It is protected from air "Is heated at any tenperary door at which the chair accessory is to be determined". If the resin can be checked, it will go to a SusanjsonhSngonde checkout, or at least "ground the powder""particles stick to each other" if the resin is still present in the form of a fine roll after heating infusible *

The FlÖobtiekeit dor new Hers "can asn bostlaffion by di · equal · procedure" which bility for Beatimnune the fictoels- "used wlr <l _t if dl · Prob · tos and after the ER-

909812/0983

6AO ORIQINAt

heating is weighed · If the heating temperature is significantly above 400 ° C, the resin is converted to carbon. The amount of carbon remaining after heating to 95O ⁰ C is referred to as "carbon ^{residue w} . It is characteristic of the new resins in the fully hardened, heat-hardened state that the carbon content is above 65 " and below 100 "of the weight of the resin investigated When thermoset resins are referred to as "practically insoluble and infusible" it means that the resinous product is fully polymerized and thermoset if it has a benzene solubility less than 35 #, a carbon residue greater than 65 #, and no evidence of meltability.

Approximately 15 parts of m-dinitrobenzene to 85 parts of pitch are used Achieving a complete thermosetting of most commercially available Pitch, which as suitable starting materials according to the The definition given above is sufficient. A slightly lower ratio, for example 14 parts of m-dinitrobenzene 86 parts of bad luck, can be considered by some. Raw materials materials used must be sufficient, especially in the case of the "tough" pitfalls of the trade. On the other hand, if desired, you can Use more than 15 parts per 85 parts pitch, for example to increase the hardening rate or by volatilization to compensate for any losses. The desirable proportions of m-dinitrobenzene for the production of thermosetting

909812/0983

BADOWetNAL ~ ¹² ~

end hite-hardened arsenic »according to the invention, βο can vary from 14 to 25 % of the weight of the Auegangismlschiing. Eel other oxidizing agents B Κδοπβη the proportion · are higher or lower «Depending on whether the Cx ^ dntioning agent is greater or less than that of o-nitrobenzene.

Boi Vi. Ig the necessary 1 * 36 .i-iinitrobonsol, as never given the unmoved example "uiaeetst" oo know the olynerlaation is being completed ", Jo means up to * ur ^ rocböprung the Ox? Datlinealttel" without ecr. reaches the completely JbiteetTchortuten degree of FoIy- "erieatlott · la servant Koiee hergeetollte products are not hit * ebartbere _t eondern therROpl & svlecho Eer" e _v

Well-valid »vi» long teas daa Krhlteen forteetat · Thericopl · «- ettiech · Korse alnd for esanche Verwenaungeeweck · ervnacht» b # i many of the high rituality not necessary let · the connection «it CellcüoGof ailotaren with high teacouple debt * / riraebeet'lnrtie, know beieplelewaiso a thcreoplaatlBcbee beard «with a ßitepanfcfc in the range of!

5: bl «27> ° 0» vortusa white 1 »range from 1 $ 0 to 165 ° C, el · üindealttel. serve · such Theraoplastlaohc iarae know • rbaltea, iodta «to the Kens · an« «Dlnltrobentol« s & f ν the allowance required for compliance is observed.

900012/0983

BAD OffK3JNAL

You can know about 7 »5 weight requirements in this respect herebgoben. .

Si · Reaction aar the production of wood b & rtb & rtb & rtb & rtbormoplentiechen and heat-hardened Hrraan according to the invention, which are made from fibers and oxidizing agents «can never be carried out at a low temperature of 165 ° C * It takes a very long time» even with even deeper Texporetaren · Π ot er ο temperatures »vomu ^ cwöloo la range from 2CO to 25O ⁰ G ₁ nind sur achieving a faster Ueoetsmnf; and "before Vermindorun ^ the IDr the Heratellurg dea Karaes required time for night. ZveoknSaaig is reminiscent of the unsolvation at a poratur twlecbon 165 to 180 ⁰ O and increases the temperature at frr tr? -.reitender fieektion · D ο ο Kaaa der? "Λ voa 'UberleBtingen _t never the 710chti: l: eit des • oils and da« SohBusen nb, velchea by escaping air from the exitaalaehuBg the Kaaktionatellnor or through tn% » « In each case the temperature is increased ao langaaa, that ain nbinaHanl ^ s Sobüii · son is prevented -bas? rhitien is terminated below 40 ° C Horse as well as other organic hars'; su carbon zoraetat are «Vorxugavelsi toendet nan dlο conversion at 25C ° C, because at about this teaperotur the foly ^ erientionereaytion ao quickly wears off, daeo dia X> ankuoe Bclivieri ^ oiten prepares · Di ^rt ^ erse «orden doher 1« range from 165 bio ACO ⁰ C _t voraaßet / elso rwi-

909812/09 & 3
BAD ORfGtNAL

see 185 and 25O ⁰ C, produced during the Kndatufen the Uo-conversion Io the hot-hard state, boiopiclewoleo in the conversion of a forosaeae in -51 non hearing tone Forak & rper under overpressure in a forepreeee, "ground temperatures of about 50O ⁰ O prevent"

If the healing is kept at Höruncotonporaiiur "• o the Folynsrisntlonanoachwindikeit, which you are related to high int" with the zoit decrease and possibly very long νεχ3βη, if the tociporatar does not eat particularly high 1Π5 to 25Q ⁰ C _t die ^ ea ^ tlon ao lan; e run sa laenen _t bi · one »slow hefiktiono ^ aßclvwinJirkoit; reached 1st, and then the use of the menu _m K & n can in theftor Volee convenient hit * ebüitber ^ 'BTZ9 with the same Kijenscharton by Anaeta sa A fed up . LSoat nan boispielawoiso in oiner given Bee ^ tionanleohuns "which is last erhitxt at a Recktionetenperatur of 225 ° to 0, the Uaeetsung run _t bie the BitzpunKt na per hour eneteist 3 ° C, eo is the Harto dea Produktβ3 within acceptable Crensen A neat * au Ansatx rapro showerable

You are Kars · nor the Brlinlun ^ also eeiix f.9Q * n 'do not knzritt · chemical agents; euo air beetehen _t belapielaveiee opposite kauetlsehon zioeuncen "oxidizing rttn ^ like saltpeter""or Ccfcv. Tulaauro, or andoren SHore.-i «wl · Caalgfl8ure _t Chlomeeaerstofr uuil? NoaphoreSuro _t and

909812/0983

• Λ ■ <

tola »like alcohol, Eohlenwneseretoffe and Kotonen. In order to ensure that "the resistance of the manufacturer" against some "is maintained", every method is used as the "method used" as described by WE Adame et al. it or without fill off ο Soraatücke "which auagesetat then Sinwirkung the Prüilöeuneen at steered Tcapereturen" ground * Räch the Hinvirkung verden the Froben Wideratendswert * Sttgeordnot on the base Logo beoonderor Beobachttmgen and Heeeungon that _t to ^ on I ^ rüfetüotcn and don Loaansen which dl ITO-

ben auageeettti% urdtn _t vorgenoaatea wordon are

For the application of the Aflaaa Vldorittandawcrteekala to the Bers according to the invention are a partial r & bärtotee Bors and a carbon filler shaped pieces that are similar those are «who are responsible for the above-mentioned attempts at

against Ltiftoxydatlon tervendot · you «·

Stick are then completely heard at 2JX) ⁰ C and la small

Test samples o with the approximate dept. 9 »525 * 9 * 52 $ X 19iO50 na cereohnltten * used for the evaluation in the π according to Adaaa vev *. tterdea "For the videratandafHhigkeit roe nitric acid and Uatrloflihydroxyd" are obtained Sureheennltta values of venisetcaa $ 0 "" le au "dar folc" nden "ufatstellung emerges

909812/0983

Xonzen- rUften- Weights- Voluoeu- Aueue «Ausoe-

tration peretur inland us change

£ eageoa % ⁰ C the ixobe the Irobe the 4's

frobe

Eohnitt * worth it

Hetrlun

hjrdroxid

Saltpetre
«Cook

«R

20 20 50

5 5

10

15th

100

100

100

100

100
83

93

100

100 100 100

100 100 100 100

100

90

100

100 95

100 100

99.5 96.0

100

98.8

97.0 97.5

: nn «Iso an erria;! un ^ Oßett« aa hergeotolltos Eera practically completely hardened, has a * srt nech Adaas of .-. i $ eten · 90, vena es ßit 20 ^ lrea Iii ^ rius »hy3roxyd and - ait 5 fig nitric acid is handled ^{at 100 0 C}

Ktm represents a Kleehun? 100 parts of the powdered I! he * © «wi? i 100 parts Asbestlelehtsut (floate) duroh about 20 minutes, I / QvOlien the components g in a verifiable rotating GefSaa about · 40 of the Ä" befit-Har * -HiechUQg _t at Zirrsortemperater em a «. Pressure of 211 at zn a slice feprosst, besitst the approximately the erwSnßchte a Kndprodukt Torah nn4 Large, "earth 30 minutes at 50C ⁰ O in an oven ge £ -ebcn · 7u?> Cinn the treatmen development, call the Seapftr /. tur der irorijef orat r Scl.eibe eich 300 ^e C aShort, changes eich dio J * arbe der ßcheil a smoke from rraa to cohwart «wtae 4er Herzfluaa the surface see dta Asbents be ·

909812/0983

BAD OftlÖJNAL

decfct · The disc is a lot soft and BUBacisenpresebar · On the Sch3αββ the oven abendltto ^ hot the preform reaches a state »which for the abochlleesende deformation let» dna get the Aobs & tobore color is covered by a Harsfilsi * dn color like the black ^ n the structure at furnace temperature is not very, very much. but «rain Oe? advanced hardness? Dee Harsea can be bought under pressure, bar. Diones pre-hardened _f heat-hardened product Eeiirt b * »l 3C0 ° C? LastisitSt _t if inen it olnora BruoK of 35« t; * r% # irft _t dege ^ en no r.srviiofce riostizltet. of a Druci: oe from C _f 55 et. Han clbf the prefabricated linji then in a s? Lindrl8Cbo irresrfrrm at 25G ° C _t ISaat before printing 3 kinotes absorb the% 'arce ani on it for an hour act a pressure of 2Ί1 nt at 25O ° C · Si «press-Xorn becomes without cooling f-aoi / net "Bao product 1st and splits a shiny, hard ßchoibo oolbat at frcasteaperatur" which raises the abaesxungen of the Froosforn Cberelnstinat and neither in the case of AbkOhleo on Slaaier temperature nor in purchase "to 50O ⁹ G" changes commendably. The disk does not show any noticeable relaxation when subjected to a pressure of 33 at at 30O ⁰ O.

Xo operations of the invention are far from the world fora

900812/0983

BATH ORIGINAL ^ ¹⁶ "

Claims (1)

Jt Potentangprilch " Process for the production of bariprodocts containing coal, which contain a maximum of 60 $ benaollo'aliehe Beatandteil · daduroh marked, because a kiaehung from an Oxyda * tionant and 3 uinea KohlenwaaEerstoffholtigen Poch, which an apealfiachea weight at 25 ° C of egg imlitatestene ? 2 hours ixbitsen at 4 ^ 0 ⁰ C in a peochlosaenon Ge t3 ^ B ₉ »and a distillate is not possible iat, Binfiosteas 60 jS Test'e substances, based» on the »weight of the Peoha, gives» the » oh tirhitzan at Ataoaphiirendrack in the absence of Sauer "atoff nindcBteno BTohlenatoffrückstand 60%, based on Alm solid sweeteners, yield" erhitit 400 ° C to about 16 $ * etna boi 2 · Traffic according to aneprucb 1 »by doing so,» deaft iraa «la Oxidationatoitt«! a flOoni ^ en or soft fabric used Werfahren according to claim 2, characterized in that «des» sau als Oxidation agent "in Polynifcxobenaol, in particular Dinitrobenaol" % .ie "-Oinitrobenxol" voriueewelae in a Heng "of 7§5 up to 2 ^ »bseondera i ^ bio 20 Gewbensaproxent» sucked on daa Weight of the auagaaganiachung » 4 «Method according to claim 1 to 3» characterized by the fact that « mm an au · coal tar ataaoesdea pitch used. BAt) _ 19 - 5 »The method according to claims Ί to 4 ₉ thereby sakennsceichnet ,, deca man« ine sor complete hardening of the Ferzoo insufficient fcenge the oxidation is old tele used and the mixture remains as long as ₉ ble the ears iron flat point of 150 to 275 ⁰ C ₉ advantages * Velae 1 ^ C ble 16 $ ^o C ₉ & ufwelet 6 · A method according to Ancpruch i to 4 ₉ characterized ^ e ^ ennzolehnet "DOEs SEN a" used for volXetSndÜgQä curing of the H & rzoe ur.ttennsonde Kehge of Oxjdfrtioncnlttfcls and dio: 'l' Chung eo lenge bie the resin no üitspuntct below 275 ⁰ C. zeI ₁ ^ t, but see 275 and 400 ⁰ C is heatable; · 7 · Seduction according to claims i to & * characterized * in that ■; do a sure amount of fortune dee resin auaraiohende amount dee Ox> datlonaslitela vcrvcnJot. 8 * Vi. * Rff.hren according to claim 7 _f d »by frelconnReichnet» daoa csn the Mschang heated for so long, preferably at H85 ble 250 ⁰ C and »uletst; at JOO bia 35C ⁰ C ₉ to: .εη a vBlliß goes: * ON · tetea and unachnclzb & res Hare get hni _v <2rα alndeetens 65 Gi. · * icbtaprcaent KohlenotoXfrilcfcetnnä results in »i.-enlger ala 5 Contains components and boi 375 ⁰ C koine Pliesc- fahi ..: költ 9 ·. A method according to /.nnprucL 3 ₉ characterized K.ekennzolchnet _t DAEA c> ar incorporated in the 'iechung a PüllßtoXX;!. · 909812/0983 BAO LOCAL FINAL 1Q · VerXehren nach & ch claim?, Characterized * that the Kißchuns at 1G5 to 4C0 ° C, preferably at 165 to 2? 5 ° G | bo laiige heated »until asm a hardened r-roduct from 15o to 2? 5 ° C, previously 175 to 275 ⁰ o and 200 to 260 ⁰ C, des 25 to 60 % benzollo ^ licbe üect-aniteilo enthult and at "5 ° C is solid" and ir & zQbtzantcllü dee esterified et β rprodukt at 165 to 4CG ° C _t vöiae 250 to 350 ⁰ C ♦ in particular 275 to 525 ° C »eo -e heated, bie Esa a completely ^ ob« rtctee aod bsi ··; «product that at 575 ⁰ C none. I loosXUhisHeife shows «r ~ has · ■ · ■ · .- ■■■■■ .- .. ^ ₁ ■ '■;·;''■' ■ ^{^:;:} * ^ i.:. 11 · Verfaliron after address 10 »thereby ßokenezoiahnot» deee «en ear Herstolluns dee Torgehartctcn product die Kiechuös eo long bitter, until the Üitspur & t bein Xrhittea at could as * less ele 3 ° C ^ e hour stits » 12. Ve ^ Fehren after Aaspruoh 1E or 11, characterized okenaseichnot, deee "s" or Π · Γβtelluric dee vorgehiirteteu products, the Kl * echoes iun3chet at 165 ⁰ C, later erhitat at 200 bie 225 ⁰ C. · VerXehren nach Claim Λίι bim 12, dodurch gokoimsuichnct, aes »ur Hero toll unt; dee completely gehlfrtatcr * products ιεβ product «it iron« pniletorf 90 9812/09 83 JAMf £) MBO
6AO ORIQiNAt - 21 - ■ '■ 14. The method according to claim 10 to 13t thereby cekennxtlehnet, e «n star production <Jea completely gob & rteton product at overpressure _t for example la a molding press» works « 15 · ancestors still Anopruch 10 to 15 »characterized by ^, daaa oan sur production dee completely; hardened product d 's pre-clu'irtet · Product upper body eeloea Ritzpunlttbereicboa erkitst "ao DEAE that before ^ ehßrtote liars About dea FUllefcoff Xlioml Hera further f.ehBrtet and riücbti'." fabrics weaentliob veraindert vordtn _t and daa Veiter yorgebKrtete rrodulct in the case of a tenure, the product would be completely rebuilt. 16 · Method according to claim 15 »characterized in that there is a total of 250 to 350 ⁰ C vornisot · 17 · The ancestors according to claim 7% are identified by "that" one gets ao lan ^ e "when one has received a pre-hardened" 9 product old a rita point of 150 to 275 ⁰ C has "daa vorgehürtes":; are sit iron oelluloaeboltlßfcn filler frozen _t requested to bia 1? 5 ° C and the Hlaohu & s anacfaXiaaaand under pressure available » 18 · Procedure according to Aneprucb 1J »dadurcb marked» daaa man Jao vorsehartet · Kart nit einoa Füllotoff voraincht and dl « Preserves value at a temperature above dee Ritzpunkteo de “pre-hardened hearts” until “fin · 1η · at3rk”? vorgebflrtete, but looks completely pehBrtot · Foramaee · ten hot, dia later obn "Wfeentllch" C "etn% vieklQH8 will know » 909112/090 $