DE1467816B - Refatting cosmetic and medical preparations - Google Patents
Refatting cosmetic and medical preparationsInfo
- Publication number
- DE1467816B DE1467816B DE1467816B DE 1467816 B DE1467816 B DE 1467816B DE 1467816 B DE1467816 B DE 1467816B
- Authority
- DE
- Germany
- Prior art keywords
- cosmetic
- skin
- preparations
- refatting
- moles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000002537 cosmetic Substances 0.000 title claims description 8
- 239000000203 mixture Substances 0.000 claims description 12
- BVDRUCCQKHGCRX-UHFFFAOYSA-N 2,3-dihydroxypropyl formate Chemical compound OCC(O)COC=O BVDRUCCQKHGCRX-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 210000003491 Skin Anatomy 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000003921 oil Substances 0.000 description 5
- 210000004209 Hair Anatomy 0.000 description 4
- 239000003788 bath preparation Substances 0.000 description 3
- 150000003626 triacylglycerols Chemical class 0.000 description 3
- 230000036740 Metabolism Effects 0.000 description 2
- 210000004080 Milk Anatomy 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 230000035786 metabolism Effects 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- -1 polyoxyethylene monolaurate Polymers 0.000 description 2
- 230000036642 wellbeing Effects 0.000 description 2
- CWLGEPSKQDNHIO-JOBJLJCHSA-N (E)-N-[(E)-benzylideneamino]-1-phenylmethanimine Chemical compound C=1C=CC=CC=1/C=N/N=C/C1=CC=CC=C1 CWLGEPSKQDNHIO-JOBJLJCHSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N (±)-Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 229960000716 TONICS Drugs 0.000 description 1
- 229940088594 Vitamin Drugs 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000002209 hydrophobic Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000002884 skin cream Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000004936 stimulating Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001256 tonic Effects 0.000 description 1
- 235000015961 tonic Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229930003231 vitamins Natural products 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Description
Die kosmetische Hautpflege dient dem Zweck, die normale Beschaffenheit der Haut zu erhalten. Hierfür ist eine große Anzahl von Präparaten entwickelt worden, denen verschiedenartige Funktionen zü-The purpose of cosmetic skin care is to maintain the normal texture of the skin. Therefor a large number of preparations have been developed to which various functions
Einen großen Raum nehmen unter ihnen die kosmetischen Badepräparate ein, die im wesentlichen für den gesunden Körper und die Körperpflege in engerem Sinn gedacht sind, wobei sie aber durchaus auch anregend auf den gesamten Stoffwechsel wirken können, das allgemeine Wohlbefinden steigern und auch leichte hautfunktionell; Störungen zu beseitigen oder zu mindern in. der Lage sind. In erster Linie sollen sie jedoch die reinigende Wirkung des Wassers und der Seife durch'.Enthärten des Wassers unterstützen und beispielsweise durch Zusatz ätherischer öle und Aromastoffe das Gefühl des Gepflegtseins vermitteln. Nicht scharf· von den kosmetischen Badepräparaten sind die, ,medizinischen Zubereitungen zu trennen. Beide Gruppen gehen in Form und Aufgaben ineinander über. Speziell kommt ihnen aber die Aufgabe zu, durch Perkutaneinwirkung den Stoffwechsel des erkrankten Körpers anzuregen oder die Haut günstig zu beeinflussen.A large part of them are the cosmetic bath preparations, which are essentially for The healthy body and body care are intended in a narrower sense, but they are also can have a stimulating effect on the entire metabolism, increase general well-being and also light skin-functional; Eliminate malfunctions or are able to reduce. First and foremost, however, they are intended to enhance the cleansing properties of the water and the soap by softening the water and, for example, by adding essential oils and aromatic substances, the feeling of well-being convey. Not hot · of the cosmetic bath preparations are the,, medicinal preparations too separate. Both groups merge into one another in terms of form and tasks. But this is especially important to them Task to stimulate the metabolism of the diseased body or the To influence the skin favorably.
Die Erfahrung hat nun gezeigt, daß die in die Präparate eingearbeiteten Wirkstoffe und oberflächenaktiven Reinigungsmittel in vielen Fällen eine recht unerwünschte Entfettung der Hautoberfläche zur Folge haben. Man hat dieser Begleiterscheinung durch Zusätze entgegenzuwirken versucht. Es ist z. B. dem Artikel »Die Herstellung von Schaumbädern« in Seifen, Öle, Fette, Wachse (1963), S. 899, zu entnehmen, daß man einem Schaumbad einen Sulfobernsteinsäurehalbester , eines äthoxylierten Alkylolamides zusetzt. E. Scott Pattison beschreibt in »Industrial Fatty Acids and their application« auf S. 114 bis 123 die Verwendung von Polyoxyäthylenmonolaurat in Cremes, Lotions und Hairdressings. In Fette, Seifen, Anstrichmittel (1965), S. 517, werden ebenfalls Ester, und zwar Fettsäurepolyglykolester als Überfetter genannt.Experience has now shown that the active ingredients and surface-active ingredients incorporated into the preparations In many cases, detergents have a very undesirable effect on degreasing the surface of the skin Have consequence. Attempts have been made to counteract this by adding additives. It is Z. B. the Article "The production of foam baths" in Seifen, Öle, Fette, Wachse (1963), p. 899, can be found, that a sulfosuccinic acid half-ester, an ethoxylated alkylolamide, is added to a bubble bath clogs. E. Scott Pattison describes in "Industrial Fatty Acids and their application" on Pages 114 to 123 describe the use of polyoxyethylene monolaurate in creams, lotions and hairdressings. In Fette, Seifen, Anstrichmittel (1965), p. 517, are also esters, namely fatty acid polyglycol esters as Called overfat.
Es war bisher kein Mittel bekannt, welches den Einsatz in den verschiedenartigen kosmetischen und medizinischen Zubereitungen; die sowohl in wäßriger wie auch in öliger Form vorliegen, ermöglicht. In einem solchen Produkt müssen hydrophyle Reste, die die Wasserlöslichkeit bewirken, wie -auch hydrophobe Reste vorhanden sein, die die Ausbildung des gewünschten Fettfilms auf der Haut ermöglichen, ohne daß dieser durch Wasser wieder weggewaschen werden kann.So far, no agent was known which could be used in various cosmetic and medicinal preparations; which are present both in aqueous and in oily form, enables. In Such a product must have hydrophilic residues that cause water solubility, as well as hydrophobic ones There are residues that allow the desired fatty film to form on the skin, without that this can be washed away again by water.
Es wurde gefunden, daß kosmetische und medizinische Zubereitungen rückfettende Eigenschaften besitzen, wenn man ihnen Partialglyceridgemische gesättigter Pflanzensäuren mit 8 bis 14 Kohlenstoffatomen zusetzt, an deren freie OH-Gruppen des Glycerins je 2 bis 8 Mol, vorzugsweise 4 bis 8 Mol, insbesondere 5 Mol Äthylenoxyd angelagert sind, und daß diese Produkte mit gutem Erfolg sowohl bei öligen wie auch bei wäßrigen Zubereitungen Verwendung finden können.It has been found that cosmetic and medical preparations have lipid replenishing properties, if you give them partial glyceride mixtures of saturated vegetable acids with 8 to 14 carbon atoms adds, on the free OH groups of the glycerol each 2 to 8 mol, preferably 4 to 8 mol, in particular 5 moles of ethylene oxide are deposited, and that these products are both successful with oily as well as aqueous preparations can be used.
Ein solches zur Äthoxylierung eingesetztes Partialglyceridgemisch weist etwa folgende Kennzahlen auf:Such a partial glyceride mixture used for ethoxylation has roughly the following key figures:
Säurezahl etwa 1Acid number about 1
Verseifungszahl 250Saponification number 250
Jodzahl unter 1Iodine number below 1
Hydroxylzahl 370Hydroxyl number 370
Monoestergehalt 42%Monoester content 42%
Am besten haben sich Produkte bewährt, an die pr : freie OH-Gruppe des Glycerins 5 Mol Äthylenoxy angelagert wurden.The best products have proven to be those to which 5 moles of ethyleneoxy have been added to the pr: free OH group of the glycerol.
Unter Zugabe dieser Mittel können die !verschit densten Badepräparate hergestellt werden, die nebe der reinigenden auch die oben beschriebene riM fettende Wirkung auf die Haut besitzen. Es könne ferner 10 bis 50% derartiger Mittel den verschk densten kosmetischen Präparaten, z. B. HautmilcherWith the addition of these funds, the ! Various bath preparations are produced which, in addition to the cleansing properties, also have the above-described greasy effect on the skin. It could also be 10 to 50% of such agents in the various cosmetic preparations such. B. Skin milk
ίο Hautsprays, Hautcremes und auch Haut- und Haai waschmitteln. zugesetzt werden. Bei Haarwässern hc sich ein Zusatz von 2 bis 10 % — am günstigsten 5 ° — bewährt. Nachstehend einige Rahmenrezepturen:ίο Skin sprays, skin creams and also skin and hair detergents. can be added. For hair tonics, an addition of 2 to 10% - preferably 5 ° - proven. Below are some basic formulas:
Haarwasser (fettend)Hair lotion (greasy)
Isopropanol Isopropanol
Wasser water
Partialglyceridgemisch mit 4 Mol Äthylenoxyd Partial glyceride mixture with 4 moles of ethylene oxide
(Kennzahlen: SZ 0,2
VZ 120
OHZ 260
Ölhaarwäsche(Key figures: SZ 0.2
VZ 120
OHZ 260
Oil hair wash
Triglyceridgemisch mit 8 bis 12 C-Atomen Partialglyceridgemisch mit 6 Mol Äthylenoxyd Triglyceride mixture with 8 to 12 carbon atoms. Partial glyceride mixture with 6 moles of ethylene oxide
(Kennzahlen: SZ 0,2
VZ 89
OHZ180)
Hauptnährmilch(Key figures: SZ 0.2
VZ 89
OHZ180)
Main nutritional milk
Äthoxyliertes Wollfett Ethoxylated wool fat
Vitaminöl Vitamin oil
Wasser water
Partialglyceridgemisch mit 4 Mol Äthylenoxyd Partial glyceride mixture with 4 moles of ethylene oxide
(Kennzahlen: SZ 0,2(Key figures: SZ 0.2
VZ 120
: OHZ 260)
Hautfettcreme
Triglyceridgemisch aus 60 % C8 bis C12 VZ 120
: OHZ 260)
Skin fat cream
Triglyceride mixture of 60% C 8 to C 12
Wasser water
Partialglyceridgemisch + 4 Mol Äthylenoxyd Partial glyceride mixture + 4 moles of ethylene oxide
(Kennzahlen: SZ 0,2
VZ 120
OHZ 260)
Badeöl(Key figures: SZ 0.2
VZ 120
OHZ 260)
Bath oil
Fichtennadelöl Spruce needle oil
3',6-Dihydroxyfluoran 3 ', 6-dihydroxyfluorane
Partialglyceridgemisch + 5 Mol Äthylenoxyd Partial glyceride mixture + 5 moles of ethylene oxide
(Kennzahlen: SZ 0,1
VZ 96
OHZ 200)
Sonnenöl(Key figures: SZ 0.1
VZ 96
OHZ 200)
Suntan oil
Paraffin liqu. Paraffin liqu.
Dibenzalazin Dibenzalazine
Triglyceridgemisch mit 8 bis 12 C-Atomen Partialglyceridgemisch + 8 Mol Äthylenoxyd Triglyceride mixture with 8 to 12 carbon atoms, partial glyceride mixture + 8 moles of ethylene oxide
(Kennzahlen: SZ 0,1
VZ 65
OHZ130)(Key figures: SZ 0.1
VZ 65
OHZ130)
50 % 45%50% 45%
5% 95%5% 95%
80%80%
15%15%
40%* 30%40% * 30%
30%30%
29% * %29% *%
70%70%
5 % 40%5% 40%
50%50%
Claims (1)
Family
ID=
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2024051A1 (en) * | 1970-05-16 | 1971-12-09 | Henkel & Cie GmbH, 4000 Dusseldorf Holthausen | Cosmetic preparations, in particular cosmetic cleaning agents, with a content of refatting agents |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2024051A1 (en) * | 1970-05-16 | 1971-12-09 | Henkel & Cie GmbH, 4000 Dusseldorf Holthausen | Cosmetic preparations, in particular cosmetic cleaning agents, with a content of refatting agents |
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