DE1444067A1 - Protective agent against textile pests - Google Patents

Protective agent against textile pests

Info

Publication number
DE1444067A1
DE1444067A1 DE19631444067 DE1444067A DE1444067A1 DE 1444067 A1 DE1444067 A1 DE 1444067A1 DE 19631444067 DE19631444067 DE 19631444067 DE 1444067 A DE1444067 A DE 1444067A DE 1444067 A1 DE1444067 A1 DE 1444067A1
Authority
DE
Germany
Prior art keywords
protective agent
agent against
textile pests
pests
against textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19631444067
Other languages
German (de)
Inventor
Libach Dr Ernst
Muth Dr Friedrich
Herhinger Dr Heinz
Langheinrich Dr Klaus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of DE1444067A1 publication Critical patent/DE1444067A1/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

Schutzmittel gegen Textilochädlinge Als Schutzmittel gegen Textilochädlinge, insbesondere gegen die Larven der Kleidermotte (Tineola biselliella) sowie gegen die Larven der Pelz- und Teppichkäfer (Attagenus pleeue und Anthrenus vorax) sind bereits Chlorbenzolaulfonoäure- trifluormethyl-chlor-anilide empfohlen worden (vgl. z.B. die deutsche Auslegesehrift 1 062 238.und die schweizerische Patentschrift 361 275). Protective agent against textile pests As a protective agent against textile pests, in particular against the larvae of the clothes moth (Tineola biselliella) as well as against the larvae of the fur and carpet beetles (Attagenus pleeue and Anthrenus vorax), chlorobenzolaulfonoacid trifluoromethyl-chloro-anilide has already been recommended (see e.g. German Auslegesehrift 1 062 238 and Swiss Patent 361 275).

Es wurde nun gefunden, daso das Trichlorbenzolaulfonsäuretrifluc>rmethyl-chlor-anilid der Formel sich vor den Chlorbenzolaulfonsäure-trifluormethyl-chlor- amilldei4 die bislang als Schutzmittel gegen Textilochädlinge bekarint geworden sind, durch eine überraschend stärkere Wirksamkeit auszeichnet. Die Uberraschend stärkere Wirksamkeit des neuen Trichlorbenzol- oulfonaäzLm-trifluormethyl-ohlor-anilide sei in der folgenden Tabelle durch Gegenüberstellung mit vergleichbaren Ohlorbenzol- mLUoaeinre-trifluormathyl-ohlor-aniliden noch näher erläutert. T a b e 1 1 e Konstitution der verglichenen Bewertung der Schutzwirkung rw'hlorbenzolsulfonsäure-trifluor- methyl-chlor-anilide gegen Kleidermotten gegen Pelzkäfer ci Gl' mangelhaft mangelhaft 01 -CF 3- in der deutschen Auslege- schrift 1 062 238 in Spalte 4, Zeile 16-18 vorbesehriebene Verbindung' ci ci so 2 _NH-i Cl nicht ausreichend mangelhaft in der schweizerischen Patent- schrift 361 275 auf Seite 3, Zeile 105 vorbeschriebene Verbindung ci OF 3 ci-eso 2-NH-cci ungenügend ungenügend ci nicht-voxbeschriebene Verbindung aus Komponenten, die in der schweizerischen 2atentschrift 361 275 auf Seite 2, Zeile 27 und 57 angeführt sind ci ci CF3 Cleso 2. -NE-Ö#-ci nicht ausreichend mangelhaft nicht-vorbesehriebene Verbindung aus Komponenten., die in der 3chweizerischen- 2atentschrift 361.275 auf Sei IX-Pe 29 Zeile 26 und 62 angeführt sind 1 _OF 3 ci so 2 _NH-ö-cl gut gut 01 erfindungsgemäße, nicht- vorbesehriebene Verbin- dung aus Komt'onenten, die in der schweizerischen Patentechrift 361 275 auf Seite 29 Zeile 27 und 62 Di E, P wul-de gemäss den Richtlinien vorgenommen, die von Frey im I'Nachrichtenblatt des Deutschen Pflanzenschutz- dJenEt"4.-ee-" 1-0.Jahrgang (1958) in dem Aufsatz "Die Prüfung vGl-. W 32:.rh-at.-e-Imprägilierungsmitteln gegen Larvenfraß der #t-,i iotte (Tineola tisselliella Hum.) mit Hilfe der oae i . z. i#eu auf Seite 181 - 188 wieder- gegebe.-. v.ind. DiA, Beurteilung erfolgte an Wollproben, die bei der P-rüfung der Schutzwirkung gegen Kleidermotten jeweils 0,01. -% W5r1-#-stoff bE-Zogen auf da.s Wollgewicht und bei der CD Prülung der Schutzwirktin.#, gegen Pelzkäfer jeweils 0,1 % Wirk,#,toff bezogen auf dass Wollgewicht enthielten. Daa erflildu,ngsgemäss züi verwendende Trichlorbenzolaulfonsäure- trifluormethyl-ohlor-anili.d kann aus 2,4,5-Trichlorbenzol- sulfonsäurechlorid und 2-Trifluormethyl-4-chlor-anilin durch Kondensation in Pyridin hergestellt werden; die Verbindung besitzt einen Schmelzpunkt von 125 - 128 0 0. It has now been found that the trichlorobenzenesulfonic acid triflucide> rmethyl-chloro-anilide of the formula before the chlorobenzenesulfonic acid trifluoromethyl chlorine amilldei4 which has been used so far as a means of protection against textile pests have become known by a surprisingly stronger one Effectiveness. The surprisingly stronger effectiveness of the new trichlorobenzene oulfonaäzLm-trifluoromethyl-chloro-anilide is in the following Table by comparison with comparable chlorobenzene mLUoaeinre-trifluoromathyl-chloro-aniliden explained in more detail. T a b e 1 1 e Constitution of the compared evaluation of the protective effect rw'hlorbenzenesulfonsäure-trifluor- methyl-chloro-anilide against clothes moths against fur beetles ci Gl ' inadequate inadequate 01 -CF 3- in the German interpretation Document 1 062 238 in column 4, Lines 16-18 reserved Link' ci ci so 2 _NH-i Cl not sufficiently poor in the Swiss patent font 361 275 on page 3, Line 105 described above link ci OF 3 ci-eso 2-NH-cci insufficient insufficient ci non-vox described Connection of components, those in the Swiss 2 patent 361 275 Page 2, lines 27 and 57 are listed ci ci CF3 Cleso 2. -NE-Ö # -ci not sufficiently insufficient non-pre-approved Connection of components., in the Swiss 2 patent 361,275 Let IX-Pe 29 lines 26 and 62 are listed 1 _OF 3 ci so 2 _NH-ö-cl good good 01 according to the invention, non- pre-designated connection dung from comt'onents, those in the Swiss Patent Document 361 275 on Page 29, lines 27 and 62 Di E, P wul-de made according to the guidelines that von Frey in the I'Newsletter of the German Plant Protection dJenEt "4.-ee-" 1-0th year (1958) in the essay "Dieprüfung see-. W 32: .rh-at.-e-impregilating agents against larval feeding of the # t-, i iotte (Tineola tisselliella Hum.) using the oae i . z. i # eu on pages 181 - 188 again given-. v.ind. DiA, assessment was carried out on wool samples that when testing the protective effect against clothes moths 0.01. -% W5r1 - # - stoff bE pulling on da.s wool weight and at the CD Testing of the protective agent. #, Against fur beetles 0.1% each Active, #, toff based on the weight of wool contained. As a result, according to the trichlorobenzenesulfonic acid trifluoromethyl-ohlor-anili.d can be made from 2,4,5-trichlorobenzene sulfonic acid chloride and 2-trifluoromethyl-4-chloro-aniline Condensation can be made in pyridine; the connection has a melting point of 125 - 128 0 0.

Claims (1)

Patentansprucht Verwendung von Trichlorbenzolsulfonsäure-trifluormäthylchlor-anilid der Formel ale Schutzmittel gegen Textilschädlinge.Claimed use of trichlorobenzenesulfonic acid trifluoromethylchloride of the formula all protective agents against textile pests.
DE19631444067 1963-09-25 1963-09-25 Protective agent against textile pests Pending DE1444067A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0040830 1963-09-25

Publications (1)

Publication Number Publication Date
DE1444067A1 true DE1444067A1 (en) 1968-10-24

Family

ID=7098408

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19631444067 Pending DE1444067A1 (en) 1963-09-25 1963-09-25 Protective agent against textile pests

Country Status (2)

Country Link
BE (1) BE653317A (en)
DE (1) DE1444067A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4219593A (en) * 1978-07-06 1980-08-26 Ciba-Geigy Corporation Method of protecting keratinous material from attack by insects that feed on keratin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4219593A (en) * 1978-07-06 1980-08-26 Ciba-Geigy Corporation Method of protecting keratinous material from attack by insects that feed on keratin

Also Published As

Publication number Publication date
BE653317A (en) 1965-01-18

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