DE139060C - - Google Patents
Info
- Publication number
- DE139060C DE139060C DENDAT139060D DE139060DA DE139060C DE 139060 C DE139060 C DE 139060C DE NDAT139060 D DENDAT139060 D DE NDAT139060D DE 139060D A DE139060D A DE 139060DA DE 139060 C DE139060 C DE 139060C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- salts
- alkalis
- earths
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 9
- 238000004043 dyeing Methods 0.000 claims description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 6
- KRVSOGSZCMJSLX-UHFFFAOYSA-L Chromic acid Chemical compound O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 6
- 150000003608 titanium Chemical class 0.000 claims description 5
- 150000001447 alkali salts Chemical class 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000983 mordant dye Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- KIWUVOGUEXMXSV-UHFFFAOYSA-N Rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 2
- 230000001264 neutralization Effects 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
- 159000000011 group IA salts Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000003086 colorant Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 235000008317 Condalia obovata Nutrition 0.000 description 2
- 244000147935 Condalia obovata Species 0.000 description 2
- 240000007829 Haematoxylum campechianum Species 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- RXCBCUJUGULOGC-UHFFFAOYSA-H dipotassium;tetrafluorotitanium;difluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Ti+4] RXCBCUJUGULOGC-UHFFFAOYSA-H 0.000 description 2
- -1 potassium rhodium Chemical compound 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 240000005020 Acaciella glauca Species 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 241001518926 Cladrastis Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- NFIYTPYOYDDLGO-UHFFFAOYSA-N phosphoric acid;sodium Chemical compound [Na].OP(O)(O)=O NFIYTPYOYDDLGO-UHFFFAOYSA-N 0.000 description 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 1
- MIMJFNVDBPUTPB-UHFFFAOYSA-N potassium hexacyanoferrate(3-) Chemical compound [K+].[K+].[K+].N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N MIMJFNVDBPUTPB-UHFFFAOYSA-N 0.000 description 1
- OCPOWIWGGAATRP-UHFFFAOYSA-N potassium hexacyanoferrate(4-) Chemical compound [K+].[K+].[K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N OCPOWIWGGAATRP-UHFFFAOYSA-N 0.000 description 1
- 235000003499 redwood Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 235000007063 yellowwood Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
- D06P3/3293—Material containing basic nitrogen containing amide groups leather skins mineral dyeing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
/M-V/ M-V
/4'Q/ 4'Q
Im Patent 139059 wurde gezeigt, daß, wenn beim Färben mit Titansalzen und Beizenfarbstoffen gleichzeitig Acetate oder Formiate der Erdalkalien oder Erden oder basische Salze der letzteren angewendet werden, sattere Färbungen erhalten werden, als wenn mit Titansalzen und Beizenfarbstoffen allein gefärbt wird.In patent 139059 it was shown that when dyeing with titanium salts and mordant dyes at the same time acetates or formates of alkaline earths or earths or basic salts of If the latter are used, deeper colors are obtained than when using titanium salts and Mordant dyes alone are colored.
Die weiteren Versuche haben nun ergeben, daß sattere Färbungen auch erhalten werden,The further experiments have now shown that deeper colorations are also obtained,
ίο wenn statt der obigen Salze als Hülfssalze beim Färben angewendet werden:ίο if instead of the above salts as auxiliary salts in the Coloring can be applied:
Alkalien, Schwefelalkalien, Alkalicarbonate, Erdalkalien oder alkalisch reagierende Salze, z. B. Wasserglas, Borax, phosphorsaures Natron oder neutrale Alkalisalze der Essigsäure, Ameisensäure, Chromsäure, Ferrocyan-, Ferricyan-, Rhodan-Wasserstoffsäure, schweflige und unterschweflige Säure, oder von Fettsäuren z. B. Seife. Zur Ausführung des Färbeverfahrens werden die zu färbenden Materialien am besten kalt oder warm imprägniert mit dem Gemisch der Titansalze und Beizenfarbstoffe und dann nachbehandelt mit den kalten oder warmen Lösungen der Hülfssalze.Alkalis, sulfur alkalis, alkali carbonates, alkaline earths or alkaline reacting salts, z. B. water glass, borax, phosphoric acid soda or neutral alkali salts of acetic acid, formic acid, Chromic acid, ferrocyanoic, ferricyanic, rhodanic acid, sulphurous and hyposulphurous acid, or of fatty acids e.g. B. Soap. To carry out the dyeing process, the materials to be dyed are best left cold or warm impregnated with the mixture of titanium salts and stain dyes and then post-treated with cold or warm solutions of auxiliary salts.
So wird z. B. zum Färben von Chromleder das Leder imprägniert durch sechsstündiges Einlegen in eine kalte Mischung von gleichen Teilen einer Lösung von 10 g Titankaliumfluorid und 50 g Blauholz (Auskochung) auf ι 1 Wasser. Nach dem Färben wird ohne zu 40 So z. B. for dyeing chrome leather, the leather is impregnated by six hours of soaking in a cold mixture of equal parts of a solution of 10 g of titanium potassium fluoride and 50 g of logwood (decoction) to 1 water. After dyeing, without becomes 40
4545
spülen 15 Minuten bei 40 ° C. in den Lösungen folgender Chemikalien in 1 1 Wasser nachbehandelt: 20 ecm konzentriertem Ammoniak, 10 g calcinierter Soda oder Kalkmilch, 10 g Natriumbicarbonat, 20 g Natronwasserglas, 20 g Borax, 50 g phosphorsaurem Natron oder thiosulfosaurem, oder schwefligsaurem, oder essigsaurem, oder ameisensaurem Natron, oder 50 g Ferrocyankalium oder Ferricyankalium oder Rhodankalium oder chromsaurem Natron, oder Natronseife, oder auch 10 kg Schwefel natrium.rinse for 15 minutes at 40 ° C. in the solutions of the following chemicals in 1 l of water post-treated: 20 cm of concentrated ammonia, 10 g of calcined soda or milk of lime, 10 g sodium bicarbonate, 20 g soda waterglass, 20 g borax, 50 g phosphoric acid sodium or thiosulphonic acid, or sulphurous acid, or acetic acid, or formic acid soda, or 50 g of potassium ferrocyanide or potassium ferricyanide or potassium rhodium or chromic acid Soda, or soda soap, or 10 kg of sodium sulfur.
Die nachbehandelten Färbungen sind alle bedeutend satter und dunkler als die ursprüngliche, nur mit Wasser gespülte Färbung.The aftertreated colors are all significantly richer and darker than the original, staining rinsed with water only.
Bei Anwendung der Acetate der Alkalien als Hülfsfärbesalze ist es auch vorteilhaft, die zu färbenden Stoffe mit der Mischung des Hülfssalzes und des Farbstoffes vorzubehandeln und dann die Farbe durch Nachbehandlung mit kalter oder warmer Titansalzlösung zu entwickeln. Man legt z. B. für Schwarz lohgares Leder 12 Stunden in eine erkaltete Lösung von 50 g Blauholz und 10 g Natriumacetat im Liter Wasser ein und bringt dann 20 Minuten in eine 40 ° C. warme Lösung von 10 g Titankaliumfluorid im Liter Wasser.When using the acetates of the alkalis as auxiliary coloring salts, it is also advantageous to add the to pretreat coloring substances with the mixture of auxiliary salt and the dye and then develop the color by post-treatment with cold or warm titanium salt solution. One places z. B. for black tanned leather in a cooled solution for 12 hours of 50 g of logwood and 10 g of sodium acetate per liter of water and then takes 20 minutes in a 40 ° C. solution of 10 g of titanium potassium fluoride in liter of water.
Diese Färbung ist bedeutend satter, als wenn der Zusatz von Natriumacetat zum Blauholz unterblieben wäre.This color is considerably richer than when sodium acetate was added to the blue wood would have been omitted.
Manche Farbstoffe, ζ. Β. Blauholz, Rotholz und Gelbholz lösen sich in Gegenwart von Natriumacetat leichter und klarer, und es ergibt sich dadurch ein weiterer Vorteil für 5 obige Ausführungsform des Verfahrens, da wegen der besseren Lösung die Farbstoffe besser und gleichmäßiger aufziehen.Some dyes, ζ. Β. Bluewood, redwood and yellowwood dissolve in the presence of Sodium acetate lighter and clearer, and this gives it another benefit for 5 the above embodiment of the method, since the dyes because of the better solution apply better and more evenly.
Die Mitverwendung der vorgenannten Chemikalien als Hülfsfärbemittel gestattet also, unter ίο sonst gleichen Arbeitsbedingungen, bedeutend sattere Färbungen zu erhalten, sie ist besonders vorteilhaft in den Fällen, wo bei niederen Temperaturen gefärbt werden muß, wie z. B. beim Färben von Leder.The use of the aforementioned chemicals as auxiliary colorants thus allows under ίο otherwise the same working conditions, to get significantly deeper colors, it is special advantageous in cases where dyeing has to be carried out at low temperatures, such as, for. B. when dyeing leather.
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE139060C true DE139060C (en) |
Family
ID=406826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT139060D Active DE139060C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE139060C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5233315A (en) * | 1989-10-16 | 1993-08-03 | Telefonaktiebolaget Lm Ericsson | Coupled regenerative oscillator circuit |
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0
- DE DENDAT139060D patent/DE139060C/de active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5233315A (en) * | 1989-10-16 | 1993-08-03 | Telefonaktiebolaget Lm Ericsson | Coupled regenerative oscillator circuit |
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