DE1127886B - Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen - Google Patents

Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen

Info

Publication number
DE1127886B
DE1127886B DEB60673A DEB0060673A DE1127886B DE 1127886 B DE1127886 B DE 1127886B DE B60673 A DEB60673 A DE B60673A DE B0060673 A DEB0060673 A DE B0060673A DE 1127886 B DE1127886 B DE 1127886B
Authority
DE
Germany
Prior art keywords
oxygen
acetylene
hydrocarbons
production
incomplete combustion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEB60673A
Other languages
German (de)
Inventor
Dr Willi Danz
Dr Otto Frey
Dipl-Ing Erich Kittel
Dipl-Ing Ferdinand Markert
Dr Walter Teltschik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DEB60673A priority Critical patent/DE1127886B/en
Publication of DE1127886B publication Critical patent/DE1127886B/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/22Aliphatic unsaturated hydrocarbons containing carbon-to-carbon triple bonds
    • C07C11/24Acetylene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C10G9/38Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours produced by partial combustion of the material to be cracked or by combustion of another hydrocarbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Es ist bekannt, zwecks Herstellung von Acetylen durch partielle Oxydation gas- oder dampfförmiger Kohlenwasserstoffe mit Sauerstoff, den Kohlenwasserstoff und den Sauerstoff getrennt aufzuheizen, die beiden Gase zu mischen und in einer Flammenreaktion miteinander umzusetzen, wobei vor dem Reaktionsraum ein Brennerblock angeordnet ist, der eine Vielzahl paralleler Kanäle besitzt, durch die das Reaktionsmittelgemisch in den Reaktionsraum einströmt und dort mittels einer Zündflamme entzündet wird. Durch den Brennerblock wird die Reaktionsflamme stabilisiert und ein Zurückschlagen der Reaktionsflamme in den Mischraum verhindert. Es ist ferner bekannt, in die Strömungsschatten, die durch den Brennerblock in dem aus Kohlenwasserstoff-Sauerstoff-Gemisch bestehenden Gasstrom entstehen, Sauerstoff einzuführen, um dort die Zündflamme aufrechtzuerhalten. It is known for the purpose of producing acetylene by partial oxidation in gaseous or vaporous form To heat hydrocarbons with oxygen, the hydrocarbon and the oxygen separately, the two To mix gases and to react with one another in a flame reaction, with a burner block being arranged in front of the reaction chamber, which has a plurality has parallel channels through which the reagent mixture flows into the reaction chamber and there is ignited by means of a pilot flame. The reaction flame passes through the burner block stabilized and prevents the reaction flame from flashing back into the mixing chamber. It is further known, in the flow shadow created by the burner block in the hydrocarbon-oxygen mixture existing gas flow arise to introduce oxygen in order to maintain the pilot flame there.

Es wurde nun gefunden, daß man eine bessere Stabilität der Reaktionsflamme und dadurch eine wesentliche Durchsatzsteigerung und bessere Acetylenausbeute erzielt, wenn man einen Brennerblock verwendet, bei dem die Mündungen der Sauerstoffleitungen erweitert sind, so daß Hohlräume entstehen, die zum Reaktionsraum hin offen sind. Für die Gestaltung der erfindungsgemäßen Vorrichtung gibt es verschiedene Möglichkeiten. Beispielsweise können viele einzelne Hohlräume zwischen den Mündungen der Kanäle angeordnet sein. Man kann auch einige große Hohlräume vorsehen, wobei jeder Hohlraum mehrere Sauerstoffzuführungen erhält. Eine weitere Möglichkeit für die Gestaltung des Brennerblocks besteht darin, daß man die Mündungen der Kanäle für die Durchströmung des Kohlenwasserstoff-Sauerstoff-Gemisches an der Seite zum Reaktionsraum hin über den Brennerblock hinausragen läßt, so daß zwischen den Mündungen ein einziger Hohlraum entsteht, in den eine Vielzahl von Sauerstoffleitungen einmünden.It has now been found that you have a better stability of the reaction flame and thereby a Significant increase in throughput and better acetylene yield achieved when using a burner block used, in which the mouths of the oxygen lines are widened, so that cavities arise, which are open to the reaction space. For the design of the device according to the invention there are various possibilities. For example, there can be many individual cavities between the mouths the channels be arranged. One can also provide some large cavities, each cavity receives multiple oxygen supplies. Another option for designing the burner block consists in opening the mouths of the channels for the flow of the hydrocarbon-oxygen mixture can protrude on the side of the reaction chamber over the burner block, so that A single cavity is created between the mouths, in which a multitude of oxygen lines is created merge.

Ein älterer Vorschlag betrifft die Verwendung von Brennkammern zur Erzeugung der Zündflammen. Der Unterschied der erfindungsgemäßen Vorrichtung zu dem älteren Vorschlag besteht darin, daß dort Sauerstoff und ein brennbares Gas durch Kanäle in die Brennkammer eingeführt werden, in der die Zündflamme erzeugt wird, während hier nur Sauerstoff in den Hohlraum eingeleitet wird. Die Zündflamme brennt hierbei im wesentlichen außerhalb desAn older proposal concerns the use of combustion chambers to generate the pilot lights. The difference between the device according to the invention and the older proposal is that there Oxygen and a combustible gas are introduced into the combustion chamber through channels in which the Pilot flame is generated, while here only oxygen is introduced into the cavity. The pilot light burns here essentially outside the

Vorrichtung zur Herstellung von AcetylenApparatus for the production of acetylene

durch unvollständige Verbrennung
von Kohlenwasserstoffen mit Sauerstoff
from incomplete combustion
of hydrocarbons with oxygen

Anmelder:Applicant:

Badische Anilin- & Soda-FabrikAniline & Soda Factory in Baden

Aktiengesellschaft,Corporation,

Ludwigshafen/RheinLudwigshafen / Rhine

Dr. Willi Danz, Dr. Otto Frey,Dr. Willi Danz, Dr. Otto Frey,

Dipl.-Ing. Erich Kittel, Ludwigshafen/Rhein,Dipl.-Ing. Erich Kittel, Ludwigshafen / Rhine,

Dipl.-Ing. Ferdinand Markert, Limburgerhof,Dipl.-Ing. Ferdinand Markert, Limburgerhof,

und Dr. Walter Teltschik, Ludwigshafen/Rhein,and Dr. Walter Teltschik, Ludwigshafen / Rhine,

sind als Erfinder genannt wordenhave been named as inventors

Hohlraumes, weil kein brennbares Gas im Hohlraum vorhanden ist.Cavity because there is no combustible gas in the cavity.

In der Abbildung ist eine erfindungsgemäße Vorrichtung beispielsweise schematisch dargestellt. Durch Kanäle 1 strömt das Kohlenwasserstoff-Sauerstoff-Gemisch. Infolge Wirbelbildung in diesem Gemisch hinter den Mündungen der Kanäle 1 wird die unvollständige Verbrennung im Reaktionsraum 4 stabilisiert, wobei durch die Hohlräume 3, in die durch Leitungen 2 Sauerstoff strömt, die Stabilität verbessert wird.In the figure, a device according to the invention is shown schematically, for example. By Channel 1 flows the hydrocarbon-oxygen mixture. As a result of vortex formation in this mixture behind the mouths of the channels 1, the incomplete combustion in the reaction chamber 4 is stabilized, the stability being improved through the cavities 3 into which oxygen flows through lines 2 will.

Claims (1)

PATENTANSPRUCH:PATENT CLAIM: Vorrichtung zur Herstellung von Acetylen durch unvollständige Verbrennung von Kohlenwasserstoffen mit Sauerstoff, enthaltend einen Mischraum, einen mit einer Vielzahl von Kanälen versehenen Brennerblock und einen Reaktionsraum, wobei der Brennerblock Leitungen für die Einführung von Sauerstoff enthält, die an der am Reaktionsraum befindlichen Seite des Brennerblocks in den Reaktionsraum münden, dadurch gekennzeichnet, daß die Mündungen der Sauerstoffleitungen erweitert sind, so daß Hohlräume entstehen, die zum Reaktionsraum hin offen sind.Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen, containing a mixing chamber, a burner block provided with a plurality of channels and a reaction chamber, the burner block containing lines for the introduction of oxygen, which are located on the side of the burner block located on the reaction chamber open into the reaction space, characterized in that the mouths of the oxygen lines are widened so that cavities are formed which are open to the reaction space. Hierzu 1 Blatt Zeichnungen1 sheet of drawings
DEB60673A 1960-12-29 1960-12-29 Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen Pending DE1127886B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB60673A DE1127886B (en) 1960-12-29 1960-12-29 Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB60673A DE1127886B (en) 1960-12-29 1960-12-29 Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen

Publications (1)

Publication Number Publication Date
DE1127886B true DE1127886B (en) 1962-04-19

Family

ID=6972922

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB60673A Pending DE1127886B (en) 1960-12-29 1960-12-29 Apparatus for the production of acetylene by incomplete combustion of hydrocarbons with oxygen

Country Status (1)

Country Link
DE (1) DE1127886B (en)

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