DE10327919A1 - Composite laminated glass plate manufacture involves ultraviolet irradiation of resin on a flat plate to effect gelation, placing of a glass plate onto the resin and further irradiation through the glass plate - Google Patents

Composite laminated glass plate manufacture involves ultraviolet irradiation of resin on a flat plate to effect gelation, placing of a glass plate onto the resin and further irradiation through the glass plate Download PDF

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Publication number
DE10327919A1
DE10327919A1 DE10327919A DE10327919A DE10327919A1 DE 10327919 A1 DE10327919 A1 DE 10327919A1 DE 10327919 A DE10327919 A DE 10327919A DE 10327919 A DE10327919 A DE 10327919A DE 10327919 A1 DE10327919 A1 DE 10327919A1
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Prior art keywords
glass
glass plate
resin
layer
atmosphere
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DE10327919A
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German (de)
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KINAST MASCHINENSYSTEME GmbH
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KINAST MASCHINENSYSTEME GmbH
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Priority to DE10327919A priority Critical patent/DE10327919A1/en
Publication of DE10327919A1 publication Critical patent/DE10327919A1/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10706—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer being photo-polymerized
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
    • B32B17/10908—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin in liquid form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2369/00—Polycarbonates

Landscapes

  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

An intermediate layer is applied as a fluid resin onto a rigid base plate and polymerized by irradiating with ultraviolet (UV) light in either normal atmosphere or under a protective gas or gas mixture to produce a gelled base layer. The base layer is now capable of supporting a glass plate which is floated on top in an oxygen free atmosphere. Further curing of the base layer is effected by directing the UV beam through the glass plate onto the layer below. An intermediate layer is applied as a fluid resin onto a rigid base plate and polymerized by irradiating with ultraviolet (UV) light in either normal atmosphere or under a protective gas or gas mixture to produce a gelled base layer. The base layer is now capable of supporting a glass plate which is floated on top in an oxygen free atmosphere. Further curing of the base layer is effected by directing the UV beam through the glass plate onto the layer below. Curing occurs on a flat horizontal base. An edge forming a border around the fluid resin is made of a material which does not adhere to a UV cured casting resin. The edge forms a greater surface area than the layers to be laminated and has a hermetically sealing cover which retains a natural and/or a protective gas atmosphere.

Description

Die Erfindung betrifft Verbundelemente aus Glas oder Kombinationen von Glas mit Kunststoff oder Glas mit plattenförmigen laminierfähigen Materialien, die als Schallschutzglas, Sicherheitsglas oder dekorative Glaselemente Anwendung finden.The The invention relates to composite elements made of glass or combinations of Glass with plastic or glass with plate-shaped laminable materials, as soundproof glass, safety glass or decorative glass elements Find application.

Bericht zum Stand der TechnikReport on State of the art

Die Herstellung von Schichtaufbauten von Glas mit UV-härtenden Polymerschichten ist Stand der Technik und wird bevorzugt ausgeführt, indem eine Glastafel als Grundplatte mit einem den Glasrand umlaufenden elastischen Abstandhalter versehen wird, der eine Glastafel als Deckplatte haftend mit der Grundplatte verbindet (z.B. EP 1244545 A1 ).The production of layered structures of glass with UV-curing polymer layers is state of the art and is preferably carried out by a glass sheet is provided as a base plate with a peripheral edge of the glass elastic spacer which adheres a glass sheet as a cover plate to the base plate (eg EP 1244545 A1 ).

In den Zwischenraum dieses Glasverbundes wird über eine verbliebene Öffnung das Gießharz eingefüllt, die verbliebene Luft entfernt und die Öffnung versiegelt.In the gap of this glass composite is the remaining opening Cast resin filled, the Removes remaining air and seals the opening.

Das gefüllte Scheibenpaar wird dann mit UV-Licht bestrahlt, in dessen Folge die Harzschicht aushärtet und eine dauerelastische Zwischenschicht bildet. Derartige Gläser werden hauptsächlich als Schallschutzglas, Sicherheitsglas niederer Sicherheitsanforderungen oder dekorative Glaselemente eingesetzt.The filled Disc pair is then irradiated with UV light, as a result of the Hardened resin layer and forms a permanently elastic intermediate layer. Such glasses are mainly as soundproof glass, safety glass with low safety requirements or decorative glass elements used.

Für die Verwendung als Sicherheitsglas höherer Sicherheitsanforderungen können mehrschichtige Aufbauten bis zu etwa 70 mm Dicke erzeugt werden, deren Nachteile sowohl in den Abmessungen der Materialdicke als auch in dem daraus resultierenden hohen Eigengewicht liegen.For the use as safety glass higher Security requirements can multi-layered structures up to about 70 mm thick are produced, their disadvantages both in the dimensions of the material thickness as also in the resulting high weight.

Ein weiterer Nachteil dieses Verfahrens besteht darin, dass bei der Befüllung des Scheibenpaares die Schrumpfung des Harzes während der Polymerisation berücksichtigt werden muss. Diese Gießharze schrumpfen im Verlauf des Aushärteprozesses um etwa 9% bis 12% ihres ursprünglichen Volumens, was zur Folge hat, dass der Scheibenverbund um diesen Betrag überfüllt werden muss, damit nach der Aushärtung eine gleichmäßige Polymerschichtdicke erreicht wird.One Another disadvantage of this method is that in the filling of the disk pair takes into account the shrinkage of the resin during the polymerization must become. These casting resins shrink during the curing process about 9% to 12% of their original Volume, which has the consequence that the disc composite around this Amount to be overcrowded must be so after curing achieved a uniform polymer layer thickness becomes.

Diese Schrumpfung im geschlossenen Volumen führt häufig zu inneren Spannungen zwischen Harz und Glas, wodurch Ablösungen zwischen Harz und Glas auftreten können, die zu erheblichen Problemen führen.These Shrinkage in the closed volume often leads to internal stresses between resin and glass, causing delamination between resin and glass may occur, which lead to significant problems.

Eine weitaus günstigere Variante, sofern der Einsatzzweck als Sicherheitsglas gefordert ist, besteht in der Herstellung von Glas/Harz/Polycarbonat-Verbundglas, bei dem weitaus geringere Schichtdicken verbunden mit wesentlich geringerem Eigengewicht erzielt werden können.A much cheaper Variant, if the intended use as safety glass required is, consists in the production of glass / resin / polycarbonate laminated glass, at the much lower layer thicknesses associated with essential lower dead weight can be achieved.

Diese Laminate werden mit chemisch härtenden Polyurethanharzen hergestellt, deren Nachteile einerseits in den Kosten der Harze, und andererseits in deren schwer fließbarer Konsistenz in nicht ausgehärtetem Zustand und somit in der langen Verarbeitungszeit sowohl im Füllprozess, als auch im chemischen Aushärtungsprozess begründet sind.These Laminates are chemically hardened Polyurethane resins produced, the disadvantages of one hand in the Cost of resins, and on the other hand in their difficult flowable consistency in uncured Condition and thus in the long processing time both in the filling process, as well as in the chemical curing process justified are.

Es ist bisher nicht gelungen die kostengünstigeren schnell aushärtenden UV-Gießharze für diesen Zweck einzusetzen.It So far, it has not been possible to achieve the more cost-effective, fast-curing UV casting resins for this Use purpose.

Der Grund dafür liegt neben der chemischen Beständigkeit des Kunststoffes gegenüber einigen Gießharzen hauptsächlich in der Differenz der linearen thermischen Ausdehnungskoeffizienten von Glas und Polycarbonat (Glas: 9,0×10–6/K; Polycarbonat: 65×10–6/K).The reason for this, in addition to the chemical resistance of the plastic to some casting resins, lies mainly in the difference between the linear thermal expansion coefficients of glass and polycarbonate (glass: 9.0 × 10 -6 / K, polycarbonate: 65 × 10 -6 / K).

Die Polyurethanharze sind dauerelastisch und kompensieren von daher die unterschiedliche Ausdehnung.The Polyurethane resins are permanently elastic and therefore compensate the different extent.

Die UV-härtenden Gießharze sind ebenfalls dauerelastisch, lösen sich aber wegen der Volumenkontraktion (Schrumpfung im Aushärteprozeß) und der dabei auftretenden Reaktionsenthalpie bereits während des Aushärtens von der Polycarbonat-Unterlage ab, bzw. delaminieren nach kurzer Zeit des Abkühlens.The UV-curing casting resins are also permanently elastic, solve but because of the volume contraction (shrinkage in the curing process) and the thereby occurring reaction enthalpy already during the curing of the polycarbonate underlay, or delaminate after a short time of cooling.

Ziel der ErfindungObject of the invention

Die Erfindung hat zum Ziel die Nachteile der bisher bekannten Verfahren zu beseitigen um eine homogene Polymerschicht zu erzeugen, die neben guter Haftung zu den zu verbindenden laminatbildenden Schichten, die unterschiedliche thermische Ausdehnung zwischen den laminatbildenden Schichten ausgleicht.The Invention has the aim of the disadvantages of the previously known methods to eliminate a homogeneous polymer layer, in addition to good Adhesion to the laminating layers to be joined, the different compensates thermal expansion between the laminating layers.

Darlegung des Wesens der Erfindungstatement the essence of the invention

Das Ziel der Erfindung ist die Herstellung von Verbundglas mit spannungsfreien Polymerschichten, beispielsweise als Glas/Harz/Glas oder Glas/Harz/Polycarbonat/Harz/Glas- Aufbauten unter Verwendung von UV-härtenden Gießharzen.The The aim of the invention is the production of laminated glass with stress-free Polymer layers, for example as glass / resin / glass or glass / resin / polycarbonate / resin / glass Structures using UV-curing casting resins.

Diese Aufgabenstellung wird erfinderisch dadurch gelöst, indem das Gießharz flüssig auf die Grundplatte aufgebracht wird und unter Bestrahlung mit UV-Licht in einer atmosphärisch offenen-, oder Schutzgas-, oder Gasgemisch- Atmosphäre so weit polymerisiert, dass eine gelierte Grundschicht aufgebaut wird, die in der Lage ist die nachfolgend aufgelegte Glasscheibe schwimmend zu tragen.This task is inventively achieved by the casting resin is applied liquid to the base plate and under irradiation with UV light in an atmosphere open, or protective gas, or gas mixture atmosphere so far polymerizes that a gelled base layer is built, which is able to float the subsequently applied glass sheet.

Die noch flüssige Deckschicht beträgt dabei wenige Zehntel mm, je nach Dauer der Bestrahlungszeit. Zum Zeitpunkt der Ausbildung der gelierten Polymerschicht ist die Reaktion so weit fortgeschritten, dass die reaktionsbedingte Schrumpfung nahezu vollständig stattgefunden hat.The still liquid Cover layer is a few tenths of a millimeter, depending on the duration of the irradiation time. To the Time of formation of the gelled polymer layer is the reaction so far advanced that the reaction-related shrinkage almost complete took place.

Die freie Flüssigkeitsoberfläche wird durch einen Rand fixiert, der eine größere Fläche als die zu laminierende Grundplatte bildet, wodurch eine die Grundplatte umlaufende Pufferzone entsteht, in der das Harz, vergleichbar einem absinkenden Flüssigkeitsspiegel der Schrumpfung nachgibt und eine gleichmäßige Schichtdicke der Polymerschicht bildet. Voraussetzung dafür ist ein ebener Untergrund, der exakt waagerecht justiert ist.The free liquid surface becomes fixed by an edge that has a larger area than the one to be laminated Base plate forms, whereby a base plate surrounding the buffer zone arises in which the resin, comparable to a sinking liquid level the shrinkage yields and a uniform layer thickness of the polymer layer forms. Prerequisite for this is a level surface adjusted exactly horizontally.

Die vollständige Aushärtung erfolgt anschließend nach dem Auflegen der Deckscheibe in sauerstofffreier Atmosphäre zu einer homogenen Polymerschicht, lediglich durch erneute Zuführung von UV-Strahlung. Der verbliebene geringe Anteil der Schrumpfung wird durch die frei schwimmend aufliegende Scheibe vollständig kompensiert.The full curing takes place afterwards After placing the cover plate in an oxygen-free atmosphere to a homogeneous polymer layer, only by renewed supply of UV radiation. The remaining small proportion of shrinkage is released by the floating disc completely compensated.

Wegen des spannungsfreien Aufbaus besteht neben der Herstellung von Verbundgläsern die Möglichkeit der Herstellung von beispielsweise Glas-Polycarbonat Verbundsystemen, die als Sicherheitsglas mit hohen Sicherheitsanforderungen Verwendung finden können.Because of The tension-free construction is possible in addition to the production of laminated glass the production of, for example, glass-polycarbonate composite systems, as Safety glass with high safety requirements find use can.

Darüber hinaus lässt sich das Verfahren auch auf großflächige Glastafel-, bzw. Glas- Polycarbonat-Verbundsysteme anwenden, die mit den klassischen Füllverfahren technisch schwer oder nicht zu beherrschen sind, z.B Jumbo-Formate (6×3,21 m).Furthermore let yourself the method also applies to large-scale glass panel, or glass-polycarbonate composite systems that are compatible with the classic filling technically difficult or impossible to control, for example jumbo formats (6 x 3.21 m).

Ausführungsbeispielembodiment

Es wurden Mehrschichtlaminate des Aufbaus.

  • – 4 mm Floatglas
  • – 3 mm UV-härtendes Gießharz
  • – 2 mm Polycarbonat (Makrolon)
  • – 3 mm UV-härtendes Gießharz
  • – 4 mm Floatglas
hergestellt.There were multilayer laminates of the construction.
  • - 4 mm float glass
  • - 3 mm UV-curing resin
  • - 2 mm polycarbonate (Makrolon)
  • - 3 mm UV-curing resin
  • - 4 mm float glass
produced.

Die Muster zeigten glasartige Transparenz ohne Eintrübungen.The Patterns showed glassy transparency without clouding.

Ablösungen zwischen Harz und Polycarbonat traten nicht auf; die mechanische Haftung entsprach derselben wie zwischen Glas und Harz.Separations between Resin and polycarbonate did not occur; the mechanical adhesion corresponded to the same as between glass and resin.

Als UV-härtende Harzkomponente wurden handelsübliche Acrylatharze mit Bestandteilen an

  • – Methylmetacrylat
  • – Acryliertes Harz
  • – Acrylsäure
  • – Haftvermittler
  • – Initiatoren
verwendet.As the UV-curing resin component, commercial acrylate resins having components were used
  • - methyl methacrylate
  • - Acrylic resin
  • - acrylic acid
  • - bonding agent
  • - Initiators
used.

Claims (9)

Verfahren zur Herstellung von Verbundglaselementen als Schichtaufbau bestehend aus einer Grundplatte aus Glas, glasähnlichem Kunststoff oder zum Verbund geeigneten plattenförmigem Material, einer Zwischenschicht aus einem UV-härtendem Gießharz sowie einer Deckschicht aus Glas als einfachster Laminataufbau, gekennzeichnet dadurch, dass die Zwischenschicht flüssig auf die Grundplatte aufgebracht wird und unter Bestrahlung mit UV-Licht in einer atmosphärisch offenen-, oder Schutzgas-, oder Gasgemisch- Atmosphäre so weit polymerisiert, dass eine gelierte Grundschicht aufgebaut wird, die in der Lage ist die nachfolgend aufgelegte Glasscheibe schwimmend zu tragen und die vollständige Aushärtung anschließend nach dem Auflegen der Deckscheibe in sauerstofffreier Atmosphäre zu einer homogenen Polymerschicht, lediglich durch erneute Zuführung von UV-Strahlung durch die Deckscheibe aus Glas erfolgt.A method for producing laminated glass elements as a layer structure consisting of a base plate made of glass, glass-like plastic or composite plate-like material, an intermediate layer of a UV-curing resin and a cover layer of glass as the simplest laminate structure, characterized in that the intermediate layer liquid on the base plate is applied and polymerized under irradiation with UV light in an atmosphere of open atmosphere, or protective gas, or gas mixture so far that a gelled base layer is built, which is able to float the subsequently applied glass and complete curing then after placing the cover plate in an oxygen-free atmosphere to a homogeneous polymer layer, only by re-supply of UV radiation through the glass cover plate takes place. Verfahren nach Anspruch (1) gekennzeichnet dadurch, dass die Aushärtung auf einem exakt planen und waagerecht ausgeführten Untergrund erfolgt.Method according to claim (1) characterized in that that curing on a precisely plan and horizontally executed underground. Verfahren nach Anspruch (1) und (2) gekennzeichnet dadurch, dass das flüssige Harz durch einen Rand begrenzt wird, dessen Material zu dem UVhärtendem Gießharz keine Bindung aufweist.A method according to claim (1) and (2) in that the liquid Resin is bounded by an edge whose material is hardening to the UV Cast resin has no bond. Verfahren nach Anspruch (1) und (3) gekennzeichnet dadurch, dass der Rand eine größere Fläche als die der zu laminierenden Schichten umfasst.A method according to claim (1) and (3) in that the edge has a larger area than comprising the layers to be laminated. Verfahren nach Anspruch (1), (2) und (3) gekennzeichnet dadurch, dass der begrenzende Rand der Anordnung mit einer hermetisch abschließenden Haube abgedeckt ist.A method according to claim (1), (2) and (3) in that the limiting edge of the arrangement with a hermetic final hood is covered. Verfahren nach Anspruch (1) und (4) gekennzeichnet dadurch, dass unter der Haube atmosphärische Bedingungen und/oder Schutzgasatmosphäre vorhanden sind.A method according to claim (1) and (4) in that under the hood atmospheric conditions and / or Inert gas atmosphere available are. Verfahren nach Anspruch (1) und (3) gekennzeichnet dadurch, dass das flüssige Harz eine offene Schicht innerhalb des Randes bildet.A method according to claim (1) and (3) gekenn characterized in that the liquid resin forms an open layer within the edge. Verfahren nach Anspruch (1) gekennzeichnet dadurch, dass die Grundplatte aus Glas oder glasartigem Kunststoff oder zum Verbund geeigneten plattenförmigem Material besteht.Method according to claim (1) characterized in that that the base plate made of glass or vitreous plastic or the Composite suitable plate-shaped Material exists. Verfahren nach Anspruch (1) gekennzeichnet dadurch, dass die Deckplatte aus Glas besteht.Method according to claim (1) characterized in that that the cover plate is made of glass.
DE10327919A 2003-06-20 2003-06-20 Composite laminated glass plate manufacture involves ultraviolet irradiation of resin on a flat plate to effect gelation, placing of a glass plate onto the resin and further irradiation through the glass plate Withdrawn DE10327919A1 (en)

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DE10327919A DE10327919A1 (en) 2003-06-20 2003-06-20 Composite laminated glass plate manufacture involves ultraviolet irradiation of resin on a flat plate to effect gelation, placing of a glass plate onto the resin and further irradiation through the glass plate

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Application Number Priority Date Filing Date Title
DE10327919A DE10327919A1 (en) 2003-06-20 2003-06-20 Composite laminated glass plate manufacture involves ultraviolet irradiation of resin on a flat plate to effect gelation, placing of a glass plate onto the resin and further irradiation through the glass plate

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006084848A1 (en) * 2005-02-09 2006-08-17 Air Products And Chemicals, Inc. Accelerated uv curing

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3643765C2 (en) * 1985-12-21 1988-02-04 Glasbau Hahn Gmbh & Co Kg, 6000 Frankfurt, De
US4999071A (en) * 1986-11-25 1991-03-12 Nippon Zeon Co., Ltd. Process for manufacturing laminated safety glass
EP0876253B1 (en) * 1995-12-19 1999-08-18 Couttenier, André Method for making a laminate and device for the application of this method
DE10161242C1 (en) * 2001-12-13 2003-03-13 Andreas Peter Galac Production of laminated glass, including safety glass, uses ultraviolet-curable casting resin containing bleachable, photoreactive dye for bonding panes of glass

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3643765C2 (en) * 1985-12-21 1988-02-04 Glasbau Hahn Gmbh & Co Kg, 6000 Frankfurt, De
US4999071A (en) * 1986-11-25 1991-03-12 Nippon Zeon Co., Ltd. Process for manufacturing laminated safety glass
EP0876253B1 (en) * 1995-12-19 1999-08-18 Couttenier, André Method for making a laminate and device for the application of this method
DE69603880T2 (en) * 1995-12-19 2000-01-27 Andre Couttenier METHOD FOR PRODUCING A COMPOSITE DISC AND DEVICE FOR APPLYING THIS METHOD
DE10161242C1 (en) * 2001-12-13 2003-03-13 Andreas Peter Galac Production of laminated glass, including safety glass, uses ultraviolet-curable casting resin containing bleachable, photoreactive dye for bonding panes of glass

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006084848A1 (en) * 2005-02-09 2006-08-17 Air Products And Chemicals, Inc. Accelerated uv curing
US7662867B2 (en) 2005-02-09 2010-02-16 Air Products And Chemicals, Inc. Accelerated UV curing

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