DE102017218987A1 - Solid perfumed composition - Google Patents

Abstract

The present invention relates to a solid, particulate composition comprising at least one water-soluble carrier material, at least one perfume and at least one bittering agent, wherein the carrier material is a hydrous salt (hydrate) whose water vapor partial pressure at a certain temperature in the range of 30 to 100 ° C. corresponds to the H ₂ O partial pressure of the saturated solution of this salt, so that the salt melts at this temperature in its own water of crystallization. Furthermore, the invention relates to processes for the preparation of the solid composition, as well as a washing or cleaning agent containing the solid composition. Moreover, the present invention also relates to the use of such a washing or cleaning agent for cleaning textiles or hard surfaces and corresponding methods for cleaning textiles or hard surfaces using such a washing or cleaning agent.

Description

The present invention relates to a solid, particulate composition comprising at least one water-soluble carrier material and at least one perfume, wherein the carrier material is a hydrous salt (hydrate) whose water vapor partial pressure at a certain temperature in the range of 30 to 100 ° C the H ₂ O. Partial pressure of the saturated solution of this salt corresponds, so that the salt melts at this temperature in its own water of crystallization. The composition is characterized in that it has a significantly improved water solubility over known compositions based on polyethylene glycol. Furthermore, the invention relates to processes for the preparation of the solid composition, as well as a washing or cleaning agent containing the solid composition. Moreover, the present invention also relates to the use of such a washing or cleaning agent for cleaning textiles or hard surfaces and corresponding methods for cleaning textiles or hard surfaces using such a washing or cleaning agent.

In the use of detergents and cleaners, the consumer not only aims to wash, cleanse or care for the objects to be treated, but also desires that the treated objects, e.g. Textiles, after the treatment, for example after the wash, smell pleasant. For this reason in particular, most commercially available detergents and cleaners contain fragrances.

Often fragrances are used in the form of perfume particles either as an integral part of a washing or cleaning agent, or dosed directly into the washing drum at the beginning of a wash cycle in a separate form. In this way, the consumer can control the fragrance of the laundry to be washed by individual dosage.

In the perception of the preparations, in particular caused by an aesthetic packaging, optionally in conjunction with aromatic fragrances, the consumer may associate the composition according to the invention with a stimulant. By this association, in particular in children, an oral ingestion or a swallowing of the composition can in principle not be completely ruled out. Therefore, it is important to largely suppress the oral intake of the moldings, motivated by an attractive packaging and in particular the pleasant fragrance of the moldings.

The main constituent of such fragrance pastilles known in the art is typically a water-soluble or at least water-dispersible carrier polymer, such as polyethylene glycol (PEG), which serves as a vehicle for the integrated fragrances and which becomes more or less complete during the waxing process in the wash liquor dissolves, so as to release the fragrances contained and optionally other components in the wash liquor. For the preparation of the known fragrance pastilles, a melt is produced from the carrier polymer, which contains the other ingredients or these are then added, and the resulting melt is then fed to a shaping process, in the course of which it cools, it solidifies and assumes the desired shape.

The known products have the disadvantage that the polymer materials used, in particular PEG, have a delayed solubility, which can lead to residues on the laundry or in the washing machine, in particular in the case of short wash cycles, low temperature or other unfavorable conditions.

It was therefore an object of the present invention to identify an alternative composition which exhibits a suitable processing range and at the same time has improved water solubility in the customary temperature ranges in which work is carried out and is formulated in such a way that oral intake of the shaped bodies, in particular by children , is avoided as far as possible.

The object has been achieved according to the invention by a formulation for fusible bodies, which comprises a carrier material, a bittering agent and one or more fragrances, wherein the carrier material is a hydrous salt (hydrate) whose water vapor partial pressure at a certain temperature in the range of 30 to 100 ° C corresponds to the H ₂ O partial pressure of the saturated solution of this salt at the same temperature, so that the salt dissolves at this temperature in its own water of crystallization, a process which phenomenologically can be described as melting, which is thermodynamically a dissolution process is.

1. (a) 20 bis 95 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines wasserlöslichen Trägermaterials ausgewählt aus wasserhaltigen Salzen, deren Wasserdampf-Partialdruck bei einer bestimmten Temperatur im Bereich von 30 bis 100°C dem H₂O-Partialdruck der gesättigten Lösung dieses Salzes entspricht, vorzugsweise Natriumacetat-Trihydrat (Na(CH₃COO) · 3H₂O);
2. (b) 0,1 bis 20 Gew.-% mindestens eines Duftstoffs,
3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines Emulgators, vorzugsweise eines Emulgators aus der Gruppe der Fettalkohole, Fettamidethoxylate, Allylpolyglycoside, Fettsäuresorbitanester, Alkylaminoxide, Alkylbetaine oder Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon;
6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
8. (h) optional mindestens einen Farbstoff.

In a first aspect, therefore, the present invention is directed to a solid, particulate composition

1. (A) 20 to 95 wt .-%, based on the total weight of the composition, of at least one water-soluble carrier material selected from hydrous salts whose water vapor partial pressure at a certain temperature in the range of 30 to 100 ° C the H ₂ O partial pressure of saturated solution of this salt, preferably sodium acetate trihydrate (Na (CH ₃ COO) .3H ₂ O);
2. (b) 0.1 to 20% by weight of at least one perfume,
3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
5. (E) optionally up to 25 wt .-%, based on the total weight of the composition, of an emulsifier, preferably an emulsifier from the group of fatty alcohols, fatty amide ethoxylates, allyl polyglycosides, fatty acid sorbitan esters, alkylamine oxides, alkyl betaines or fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkylbenzenesulfonates or combinations from that;
6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
8. (h) optionally at least one dye.

1. (a) 20 bis 95 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Natriumacetat und/oder ein Hydrat davon sowie optional Wasser, mit der Maßgabe, dass wenn Natriumacetat eingesetzt wird, Wasser in einer Menge eingesetzt wird, die, bezogen auf die Menge die theoretisch notwendig wäre, um sicherzustellen, dass mindestens 60 Gew.-% der Gesamtmenge an Natriumacetat und dessen Hydraten in Form von Natriumacetat-Trihydrat vorliegt, beträgt;
2. (b) 0,1 bis 20 Gew.-% mindestens eines Duftstoffs,
3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines Emulgators, vorzugsweise eines Emulgators aus der Gruppe der Fettalkohole, Fettamidethoxylate, Allylpolyglycoside, Fettsäuresorbitanester, Alkylaminoxide, Alkylbetaine oder Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon;
6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
8. (h) optional mindestens einen Farbstoff.

In a second aspect, the invention is directed to a solid, particulate composition

1. (A) 20 to 95 wt .-%, based on the total weight of the composition, sodium acetate and / or a hydrate thereof and optionally water, with the proviso that when sodium acetate is used, water is used in an amount which, based on the amount theoretically necessary to ensure that at least 60% by weight of the total amount of sodium acetate and its hydrates are in the form of sodium acetate trihydrate;
2. (b) 0.1 to 20% by weight of at least one perfume,
3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
5. (E) optionally up to 25 wt .-%, based on the total weight of the composition, of an emulsifier, preferably an emulsifier from the group of fatty alcohols, fatty amide ethoxylates, allyl polyglycosides, fatty acid sorbitan esters, alkylamine oxides, alkyl betaines or fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkylbenzenesulfonates or combinations from that;
6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
8. (h) optionally at least one dye.

1. (a) 12 bis 57 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Natriumacetat;
2. (b) 0,1 bis 10 Gew.-% mindestens eines Duftstoffs;
3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines Emulgators, vorzugsweise eines Emulgators aus der Gruppe der Fettalkohole, Fettamidethoxylate, Allylpolyglycoside, Fettsäuresorbitanester, Alkylaminoxide, Alkylbetaine oder Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon;
6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
8. (h) optional mindesten einen Farbstoff;
9. (i) Wasser in einer Menge, welche ausreichend ist, um mindestens 60 Gew.-%, vorzugsweise mindestens 70 Gew.-%, noch bevorzugter mindestens 80 Gew.-%, am meisten bevorzugt mindestens 100 Gew.-% des Natriumacetats (a) in Natriumacetat-Trihydrat zu überführen.

In a third aspect, the invention is directed to a solid, particulate composition comprising

1. (a) 12 to 57% by weight, based on the total weight of the composition, of sodium acetate;
2. (b) 0.1 to 10% by weight of at least one perfume;
3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
5. (E) optionally up to 25 wt .-%, based on the total weight of the composition, of an emulsifier, preferably an emulsifier from the group of fatty alcohols, fatty amide ethoxylates, allyl polyglycosides, fatty acid sorbitan esters, alkylamine oxides, alkyl betaines or fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkylbenzenesulfonates or combinations from that;
6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
8. (h) optionally at least one dye;
9. (i) water in an amount sufficient to be at least 60% by weight, preferably at least 70% by weight, more preferably at least 80% by weight, most preferably at least 100% by weight of the sodium acetate (a ) into sodium acetate trihydrate.

1. (a) 20 bis 95 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Natriumacetat-Trihydrat;
2. (b) 0,1 bis 10 Gew.-% mindestens eines Duftstoffs;
3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines Emulgators, vorzugsweise eines Emulgators aus der Gruppe der Fettalkohole, Fettamidethoxylate, Allylpolyglycoside, Fettsäuresorbitanester, Alkylaminoxide, Alkylbetaine oder Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon;
6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
8. (h) optional mindesten einen Farbstoff.

In a fourth aspect, the invention is directed to a solid, particulate composition comprising

1. (a) from 20 to 95% by weight, based on the total weight of the composition, of sodium acetate trihydrate;
2. (b) 0.1 to 10% by weight of at least one perfume;
3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
5. (E) optionally up to 25 wt .-%, based on the total weight of the composition, of an emulsifier, preferably an emulsifier from the group of fatty alcohols, fatty amide ethoxylates, allyl polyglycosides, fatty acid sorbitan esters, alkylamine oxides, alkyl betaines or fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkylbenzenesulfonates or combinations from that;
6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
8. (h) optionally at least one dye.

In yet another aspect, the present invention is directed to the use of the solid composition as described herein as a fabric care agent, preferably a fragrance, for scenting fabrics.

In yet another aspect, the present invention is further directed to a laundry or cleaning composition comprising a solid composition as described herein.

These and other aspects, features, and advantages of the invention will become apparent to those skilled in the art from a study of the following detailed description and claims. Any feature of one aspect of the invention may be employed in any other aspect of the invention. In particular, it is intended that all preferred embodiments described herein be transferable to and combinable with all aspects of the invention. This is especially true for the first to fourth aspects of the invention as described above. Furthermore, it is to be understood that the examples contained herein are the To describe and illustrate invention, but not limit, and in particular the invention is not limited to these examples.

All percentages are by weight unless otherwise specified. Numeric ranges indicated in the format "from x to y" include the above values. If multiple preferred numeric ranges are specified in this format, it is understood that all ranges resulting from the combination of the various endpoints are also captured.

"At least one" as used herein refers to 1 or more, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or more. In particular, this indication refers to the type of agent / compound and not the absolute number of molecules. "At least one perfume" therefore means that at least one type of perfume is detected but may also contain 2 or more different types of perfume.

"About" or "approximately" as used herein in connection with a numerical value means the numerical value ± 10%, preferably ± 5%. A temperature of about 50 ° C thus means 45-55 ° C, preferably 47.5-52.5 ° C.

"Water-soluble" as used herein means a solubility in water at 20 ° C of at least 1 g / L, preferably at least 10 g / L, more preferably at least 50 g / L.

The solid particulate composition as described herein is prepared from a solution of the carrier material in the water / water of crystallization contained in the composition, wherein for such a solution the term "melt" is also used herein, in contrast to the established use, to designate the state in which the carrier material dissolves by the elimination of water in its own water of crystallization and thus forms a liquid. The term "melt" as used herein thus refers to the liquid state of the composition which results when the temperature is exceeded at which the support material splits off water of crystallization and then dissolves in the water contained in the composition. The corresponding dispersion containing the herein described (solid) substances dispersed in the melt of the carrier material is thus also the subject of the invention. Thus, when reference is made below to the solid, particulate composition, the corresponding melt / melt dispersion from which it is obtainable is always included. Since these do not differ in composition except for the state of matter, the terms are used interchangeably herein.

Herein, the term "fusible body" is used to describe the solid particles obtainable from the liquid composition upon cooling by solidification / remelting.

The major component of the solid particulate composition as described herein is at least one water-soluble carrier material. The at least one support material is characterized in that it is selected from hydrous salts whose water vapor partial pressure at a temperature in the range of 30 to 100 ° C corresponds to the H ₂ O partial pressure of the saturated solution of this salt at the same temperature. As a result, the corresponding hydrous salt, also referred to herein as a "hydrate", dissolves on reaching or exceeding this temperature in its own water of crystallization, thereby changing from a solid to a liquid state of matter. Preferably, the support materials of the invention exhibit this behavior at a temperature in the range of 40 to 90 ° C, more preferably between 50 and 85 ° C, even more preferably between 55 and 80 ° C.

The water-soluble carrier materials from the group of hydrous salts described above include in particular the sodium acetate trihydrate (Na (CH ₃ COO) .3H ₂ O), the Glauber salt (Na ₂ SO ₄ .10H ₂ O), the trisodium phosphate dodecahydrate (Na ₃ PO ₄ x 12 H ₂ O) and the strontium chloride hexahydrate (SrCl ₂ .6H ₂ O).

A particularly suitable hydrate is sodium acetate trihydrate (Na (CH ₃ COO) .3H ₂ O), since it dissolves in its own water of crystallization in the particularly preferred temperature range of 55 to 80 ° C, concretely at about 58 ° C. The sodium acetate trihydrate can be used directly as such, but it is alternatively possible to use anhydrous sodium acetate in combination with free water, the trihydrate then forming in situ. In such embodiments, the amount of water used is in less than or more than stoichiometric amount, based on the amount necessary to convert all the sodium acetate to sodium acetate trihydrate, preferably in an amount of at least 60% by weight, preferably at least 70% by weight %, more preferably at least 80%, most preferably 90%, 100% by weight % or more, the amount theoretically required to convert all of the sodium acetate to sodium acetate trihydrate (Na (CH ₃ COO) .3H ₂ O). Particularly preferred is the superstoichiometric use of water. With respect to the compositions according to the invention, this means that when (anhydrous) sodium acetate is used alone or in combination with a hydrate thereof, preferably the trihydrate, water is also used, the amount of water being at least equal to the stoichiometrically necessary amount, to ensure that at least 60% by weight of the total amount of sodium acetate and its hydrates, preferably at least 70% by weight, more preferably at least 80% by weight, even more preferably at least 90% by weight, most preferably at least 100 wt .-%, in the form of sodium acetate trihydrate. As already described above, it is particularly preferred that the amount of water exceeds the amount that would theoretically be necessary to convert all of the sodium acetate to the corresponding trihydrate. This means, for example, that a composition containing 50% by weight of anhydrous sodium acetate and no hydrate thereof, at least 19.8% by weight of water (60% of 33% by weight, which would theoretically be necessary to remove all of the sodium acetate into the trihydrate).

All of the embodiments described below can be explicitly combined with both of the aforementioned alternatives.

In various embodiments, the at least one support material is employed in an amount such that the resulting fusible body, i. the perfume, from 30 to 95 wt .-%, preferably from 40 to 90 wt .-%, for example 45 to 90 wt .-%, based on the total weight of the fusible body, of the carrier material.

Another component of the particulate solid composition as described herein is at least one perfume. A fragrance is an odor-causing chemical substance. In order to stimulate the sense of smell, the chemical substance should be at least partially redistributable in the air, i. the perfume should be at least slightly volatile at 25 ° C. If the fragrance is now very volatile, the odor intensity then quickly decreases again. However, with lower volatility the odor impression is more sustainable, i. he does not disappear so fast. In one embodiment, therefore, the perfume has a melting point in the range of -100 ° C to 100 ° C, preferably from -80 ° C to 80 ° C, more preferably from -20 ° C to 50 ° C, especially of 30 ° C to 20 ° C. In a further embodiment, the perfume has a boiling point ranging from 25 ° C to 400 ° C, preferably from 50 ° C to 380 ° C, more preferably from 75 ° C to 350 ° C, especially from 100 ° C to 330 ° C is located.

Overall, a chemical substance should not exceed a certain molecular weight to act as a fragrance, since too high molecular weight, the required volatility can no longer be ensured. In one embodiment, the fragrance has a molecular weight of 40 to 700 g / mol, more preferably 60 to 400 g / mol.

The smell of a fragrance is perceived by most people as pleasant and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses and roots. Thus, fragrances can also be used to superimpose unpleasant odors or even to provide a non-smelling substance with a desired odor. As perfumes, individual perfume compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used.

Fragrance compounds of the aldehyde type are, for example, adoxal (2,6,10-trimethyl-9-undecenal), anisaldehyde (4-methoxybenzaldehyde), cymal (3- (4-isopropyl-phenyl) -2-methylpropanal), ethylvanillin, florhydral ( 3- (3-isopropylphenyl) butanal), helional (3- (3,4-methylenedioxyphenyl) -2-methylpropanal), heliotropin, hydroxycitronellal, lauraldehyde, lyral (3- and 4- (4-hydroxy-4-methylpentyl) - 3-cyclohexene-1-carboxaldehyde), methylnonylacetaldehyde, lilial (3- (4-tert-butylphenyl) -2-methylpropanal), phenylacetaldehyde, undecylenealdehyde, vanillin, 2,6,10-trimethyl-9-undecenal, 3-dodecene 1-al, alpha-n-amylcinnamaldehyde, melonal (2,6-dimethyl-5-heptenal), 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde (triplalite), 4-methoxybenzaldehyde, benzaldehyde, 3 (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenyl) propanal, 2-methyl-4- (2,6,6-timethyl-2 (1) -cyclohexen-1-yl) butanal , 3-phenyl-2-propenal, cis- / trans-3,7-dimethyl-2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-) dimethyl-6-octenyl) oxy] acetaldeh yd, 4-isopropylbenzylaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2- Methyl 3- (isopropylphenyl) propanal, 1-decanal, 2,6-dimethyl-5-heptenal, 4- (tricyclo [5.2.1.0 (2,6)] decylidene-8) -butanal, octahydro-4,7 -methane-1H-indenecarboxaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alphadimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) -hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamic aldehyde, m-cymene-7-carboxaldehyde, alpha-methylphenylacetaldehyde, 7-hydroxy-3,7-dimethyloctanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3 ) (4-methyl-3-pentenyl) -3-cyclohexene carboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7 -Methoxy-3,7-dimethyloctane-1-al, 2-methyl-undecanal, 2-methyldecanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3 - (4-tert-butyl) propanal, dihydrocinnamaldehyde, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5- or 6-methoxy-hexahydro-4,7-methanindan-1 - or 2-carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecene-1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3 cyclohexene carboxaldehyde, 7-hydroxy-3J-dimethyl-octanal, trans-4-decenal, 2,6-nonadienal, para-tolylacetaldehyde, 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-) cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde, 3,5,6-trim ethyl 3-cyclohexene carboxaldehyde, 3-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde, 5,9-dimethyl-4,8-decadienal, peonyaldehyde (6,10-dimethyl-3-oxa-5,9- undecadien-1-al), hexahydro-4,7-methanindan-1-carboxaldehyde, 2-methyloctanal, alpha-methyl-4- (1-methylethyl) benzene-acetaldehyde, 6,6-dimethyl-2-norpinen-2-propionaldehyde, para-methylphenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1-al, 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propyl-bicyclo- [2.2.1 ] hept-5-en-2-carbaldehyde, 9-decenal, 3-methyl-5-phenyl-1-pentanal, methylnonylacetaldehyde, hexanal and trans-2-hexenal.

For example, ketone-type perfume compounds are methyl-beta-naphthyl ketone, muskedanone-1-one (1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H-inden-4-one), Tonalid (6-acetyl-1,1,2,4,4,7-hexamethyltetralin), alpha-damascone, beta-damascone, delta-damascone, iso-damascone, damascenone, methyldihydrojasmonate, menthone, carvone, camphor, koavon (3 , 4,5,6,6-pentamethylhept-3-en-2-one), fenchone, alpha-ionone, beta-ionone, gamma-methyl-ionone, fleuramon (2-heptylcyclopentanone), dihydrojasmon, cis-jasmone , Iso-E-Super (1- (1,2,3,4,5,6J, 8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl) -ethan-1-one (and isomers) ), Methyl cienyl ketone, acetophenone, methyl acetophenone, para-methoxy acetophenone, methyl beta-naphthyl ketone, benzyl acetone, benzophenone, para-hydroxyphenyl butanone, celery ketone (3-methyl-5-propyl-2-cyclohexenone), 6-isopropyldecahydro-2-naphthone , Dimethyloctenone, Frescomenthe (2-butan-2-yl-cyclohexan-1-one), 4- (1-ethoxyvinyl) -3,3,5,5-tetramethylcyclohexanone, methylheptenone, 2- (2- (4-methyl) 3-cyclohe xen-1-yl) propyl) cyclopentanone, 1- (p-menthene-6 (2) yl) -1-propanone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 2-acetyl-3, 3-dimethylnorbornane, 6,7-dihydro-1,1,2,3,3-pentamethyl-4 (5H) -indanone, 4-damascol, dulcinyl (4- (1,3-benzodioxol-5-yl) butane 2-one), hexalon (1- (2,6,6-trimethyl-2-cyclohexene-1-yl) -1,6-heptadien-3-one), isocyclone E (2-acetonaphthone-1,2,3, 4,5,6,7,8-octahydro-2,3,8,8-tetramethyl), methylnonyl ketone, methylcyclocitron, methyllavedelketone, orivone (4-tert-amylcyclohexanone), 4-tert-butylcyclohexanone, dolphon (2- pentyl cyclopentanone), Muscon (CAS 541-91-3), neobutenone (1- (5,5-dimethyl-1-cyclohexenyl) pent-4-en-1-one), Plicaton (CAS 41724-19-0) , Velouton (2,2,5-trimethyl-5-pentylcyclopentan-1-one), 2,4,4,7-tetramethyl-oct-6-en-3-one and tetrameran (6,10-dimethylundecene-2-one) on).

Fragrance compounds of the alcohol type are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butycyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenylpentanol, 3-octanol, 3-phenyl-propanol, 4-heptenol, 4-isopropylcyclohexanol, 4-tert-butycyclohexanol, 6 , 8-dimethyl-2-nonanol, 6-nonene-1-ol, 9-decen-1-ol, α-methylbenzyl alcohol, α-terpineol, amyl salicylate, benzyl alcohol, benzyl salicylate, β-terpineol, butyl salicylate, citronellol, cyclohexyl salicylate , Decanol, di-hydromyrcenol, dimethylbenzylcarbinol, dimethylheptanol, dimethyloctanol, ethylsalicylate, ethylvaniline, eugenol, farnesol, geraniol, heptanol, hexylsalicylate, isobomeol, isoeugenol, isopulegol, linalool, menthol, myrtenol, n-hexanol, nerol, nonanol, octanol, p -Methane-7-ol, phenylethyl alcohol, phenol, phenyl salicylate, tetrahydrogeraniol, tetrahydrolinalool, thymol, trans-2-cis-6-nonadicnol, trans-2-nonen-1-ol, trans 2-octenol, undecanol, vanillin, champiniol, hexenol and cinnamyl alcohol.

Fragrance type ester compounds are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmacyclate.

Ethers include, for example, benzyl ethyl ether and ambroxan. The hydrocarbons mainly include terpenes such as limonene and pinene.

Preference is given to using mixtures of different fragrances which together produce an attractive fragrance. Such a mixture of perfumes may also be referred to as perfume or perfume oil. Such perfume oils may also contain natural perfume mixtures as are available from plant sources.

Fragrances of plant origin include essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champacilla oil, citrus oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, pine needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, gurdy balm oil, helichrysum oil, Ho oil , Ginger oil, iris oil, jasmin oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanaga oil, cardamom oil, cassia oil, pine oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, labdanum oil, lavender oil, lemongrass oil, lime blossom oil, lime oil, tangerine oil, lemon balm oil, mint oil, musk oil , Muscatel oil, Myrrh oil, Clove oil, Neroli oil, Niaouli oil, Olibanum oil, Orange blossom oil, Orange peel oil, Origanum oil, Palmarosa oil, Patchouli oil, Peru balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sage oil, Sandalwood oil, Celery oil, Spik oil, Star anise oil, turpentine oil, thuja oil, thyme oil, verbena oil, vetiver oil, juniper berry oil, wormwood oil, wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil and cypress oil and ambrettolide, ambroxan, alpha-amylcinnamaldehyde, anethole, anisaldehyde, Anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol, bornyl acetate, Boisambrene forte, alpha-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol , Famesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmone, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p Methoxyacetophenone, methyl-n-amyl ketone, methylanthranilic acid methyl ester, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-beta-naphthylketone, methyl-n-nonylacetaldehyde, methyl-n-nonyl ketone, muscone, beta-naphtholethyl ether, beta-naphthol methyl ether, nerol, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, beta-phenylethyl alcohol, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, hexyl salicylate, cyclohexyl salicylate, santalol, sandelice, skatole, terpineol, thymes, thymol, troenan, gamma undelactone, vanillin, Veratraldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester, diphenyloxide, limonene, linalool, linalyl acetate and propionate, melusate, menthol, menthone, methyl-n-heptenone, pinene, phenylacetaldehyde, terpinyl acetate, citral, citronellal, and mixtures thereof.

In one embodiment, it may be preferred that at least a portion of the perfume is used as a perfume precursor or in encapsulated form (perfume capsules), especially in microcapsules. However, it is also possible to use the entire fragrance in encapsulated or non-encapsulated form. The microcapsules may be water-soluble and / or water-insoluble microcapsules. For example, melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used. "Perfume precursor" refers to compounds that do not release the actual perfume until after chemical conversion / cleavage, typically by exposure to light or other environmental conditions such as pH, temperature, etc. Such compounds are often referred to as fragrance storage or "pro-fragrance".

Regardless of the form in which they are used, the amount of perfume in the composition is preferably between 1 to 20 wt .-%, preferably 1 to 15 wt .-%, in particular from 3 to 12 wt .-%, based on the total weight the composition. It is a feature of the present invention that the perfume or perfume particles are homogeneously distributed in the carrier material and in particular is not present as a coating of a core of carrier material.

In various embodiments, the composition of the invention does not contain a polyethylene glycol (PEG) solid at room temperature (25 ° C) in the form of a coating, more preferably the composition as a whole does not contain a solid PEG at room temperature (25 ° C). the content of PEG solid at room temperature (25 °) is less than 1% by weight of the composition.

In further embodiments, the composition of the invention does not contain any polyethylene glycol (PEG) in the form of a coating, more preferably the composition as a whole does not contain any PEG, i. the content of room temperature solid as liquid PEG is less than 1 wt .-% based on the composition.

The composition may further contain an inorganic substance, preferably fumed silica, for adjusting the viscosity / rheological properties of the melt. This is preferably in an amount of 0.1 to 20% by weight, preferably 0.5 to 3% by weight, more preferably 1 to 2.5% by weight, still more preferably 1.2 to 2.0% by weight. -% in the composition. The silicas used are preferably highly disperse silicic acids, for example those having BET surface areas of more than 50 m ² / g, preferably more than 100 m ² / g, more preferably 150 to 250 m ² / g, in particular 175 to 225 m ² / g ,

Suitable silicas are commercially available from Evonik under the tradenames Aerosil® and Sipernat®. Particularly preferred is Aerosil® 200.

In various embodiments, the composition may additionally or alternatively contain further (at 20 ° C and 1 bar) solid or liquid ingredients which may be used to adjust desired properties of the composition. Such properties may also be the viscosity or the rheological properties of the melt. Such substances are, for example, organic rheology modifiers, preferably cellulose, in particular microfibrillated cellulose (MFC, nanocellulose). Particularly suitable as cellulose are MFCs, such as, for example, Exilva (Borregaard) or Avicel® (FMC), which are commercially available. In addition or as an alternative to the abovementioned substances, it is possible for further solids or fillers to be present which differ from the abovementioned substances.

Microfibrillated cellulose (MFC) is preferably used in amounts of up to 5% by weight, more preferably 0.1 to 3% by weight, more preferably 0.3 to 2% by weight, based in each case on the total weight of the composition, used.

Also suitable as ingredients are emulsifying substances such as fatty alcohols, for example stearyl alcohol, fatty alcohol alkoxylates, such as fatty alcohol ethoxylates used as nonionic surfactants, fatty alcohol and fatty alcohol ether sulfates and alkylbenzenesulfonates, especially those which are also used as anionic surfactants. Suitable fatty alcohol ethoxylates are in particular the C10-22 fatty alcohol ethoxylates with up to 50 EO, very particularly preferably the C12-18 alkyl ethers with 5-8, preferably 7EO, or the C16-18 alkyl ethers with up to 30 EO. Suitable fatty alcohol ether sulfates are the sulfates of the abovementioned fatty alcohol ethers, suitable fatty alcohol sulfates, in particular the C10-18 fatty alcohol sulfates, very particularly the C12-16 fatty alcohol sulfates. As alkylbenzenesulfonates in particular the linear C10-13 alkylbenzenesulfonates are suitable. In summary, emulsifiers from the group of fatty alcohols, fatty alcohol alkoxylates, fatty amide ethoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkylbenzenesulfonates, allylpolyglycosides, fatty acid sorbitan esters, alkylamine oxides, alkylbetaines or combinations thereof are preferred.

The composition may contain further solids or fillers (f) other than components (a) to (e). The proportion by weight of these solids or fillers in the total weight of the composition is for example up to 25 wt .-%, preferably up to 20 wt .-%, more preferably up to 18 wt .-%, in particular up to 15 wt .-% based on the total weight of Composition, are used.

The composition according to any one of the preceding claims, characterized in that the components (c) (d), (e) and (f) together in amounts of 0 to 25 wt .-%, preferably 1 to 20 wt .-%, further preferably 2 to 18 wt .-%, in particular 3 to 15 wt .-% based on the total weight of the composition are contained therein.

The composition further contains at least one bittering agent in an amount of from 0.0001 to 0.1% by weight, based on the total weight of the composition. Particularly preferred amounts are from 0.0005 to 0.02 wt .-%. According to the present invention, those bitter substances are particularly preferred which are soluble in water at 20 ° C to at least 5 g / l. With regard to an undesirable interaction with the fragrance components also contained in the composition, in particular a change in the scent perceived by the consumer, the ionogenic bitter substances have proved superior to the nonionic.

Ionogenic bittering agents consisting of organic cation (s) and organic anion (s) are consequently preferred for the composition according to the invention.

In various embodiments, therefore, the at least one bittering agent is an ionogenic bittering agent.

Quaternary ammonium compounds which contain an aromatic group both in the cation and in the anion are outstandingly suitable in the context of the present invention. Thus, in various embodiments, the at least one bittering agent is a quaternary ammonium compound.

A suitable quaternary ammonium compound is, for example, without limitation, benzyldiethyl ((2,6-xylylcarbamoyl) methyl) ammonium benzoate commercially available, for example, under the trade names Bitrex® and Indigo-stin®. This compound is also known by the name Denatonium Benzoate. In various embodiments, the at least one bittering agent is benzyldiethyl ((2, 6-xylylcarbamoyl) methyl) ammonium benzoate (Bitrex®). If Bitrex® is used, most amounts up to 0.002 wt% are preferred. The data are in each case based on the active substance content.

In order to improve the aesthetic impression of the composition, it can be dyed with suitable dyes. Preferred dyes, the selection of which presents no difficulty to the skilled person, should have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them. Such dyes are known in the art and are typically used in concentrations of 0.001 to 0.5 wt%, preferably 0.01 to 0.3 wt%.

Eventually, as described above, the composition may also contain free water. The term "free water" as used herein refers to water which is not bound as water of crystallization in any of the salts contained in the composition.

A composition as described herein may for example be used in the wash cycle of a laundry cleaning process and thus already transport the perfume directly to the laundry at the beginning of the washing process. Furthermore, the composition according to the invention is simpler and easier to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to edges on the substrate during subsequent storage of the bottle or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during dosing. The spilled amount can also be removed easier and cleaner. A process for the treatment of textiles, in the course of which a composition according to the invention is metered into the wash liquor of a textile washing machine, is a further subject of this application.

The composition may optionally contain other conventional ingredients, for example those which improve the performance and / or aesthetic properties.

• - 1 bis 15, insbesondere 2 bis 8 Gew.-% Parfümöl und/oder Duftstoffkapseln
• - 0,00 bis <1 Gew.-% Farbstoff(e)
• - 0,0001 bis 0,05 Gew.-% Bitterstoff
• - 1,0 bis 2,5, insbesondere 1,2 bis 2,0 Gew.-% pyrogene Kieselsäure (BET 175-225) oder 0,1 bis 3,0, insbesondere 0,1 bis 2 Gew.-% mikrofibrillierte Cellulose
• - ad 100 Gew.-% Trägermaterial, wie hierin definiert, insbesondere Natriumacetat-Trihydrat.

Example formulations of suitable compositions include the following ingredients:

• - 1 to 15, in particular 2 to 8 wt .-% perfume oil and / or perfume capsules
• From 0.00 to <1% by weight of dye (s)
• - 0.0001 to 0.05 wt .-% bittering agent
• - 1.0 to 2.5, in particular 1.2 to 2.0 wt .-% fumed silica (BET 175-225) or 0.1 to 3.0, in particular 0.1 to 2 wt .-% of microfibrillated cellulose
• ad 100% by weight of carrier material as defined herein, especially sodium acetate trihydrate.

The composition of some preferred compositions can be seen from the following tables (% by weight based on the total weight of the composition unless otherwise specified). The bitter substance used is preferably Bitrex®. formula 1 Formula 2 Formula 3 Formula 4 Formula 5 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 6 Formula 7 Formula 8 Formula 9 Formula 10 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume oil 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 11 Formula 12 Formula 13 Formula 14 Formula 15 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 16 Formula 17 Formula 18 Formula 19 Formula 20 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume oil and perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 21 Formula 22 Formula 23 Formula 24 Formula 25 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 26 Formula 27 Formula 28 Formula 29 Formula 30 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume oil 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 31 Formula 32 Formula 33 Formula 34 Formula 35 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 36 Formula 37 Formula 38 Formula 39 Formula 40 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume oil and perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 41 Formula 42 Formula 43 Formula 44 Formula 45 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 46 Formula 47 Formula 48 Formula 49 Formula 50 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume oil 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 51 Formula 52 Formula 53 Formula 54 Formula 55 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 56 Formula 57 Formula 58 Formula 59 Formula 60 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume oil and perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 61 Formula 62 Formula 63 Formula 64 Formula 65 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 66 Formula 67 Formula 68 Formula 69 Formula 70 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume oil 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 71 Formula 72 Formula 73 Formula 74 Formula 75 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 76 Formula 77 Formula 78 Formula 79 Formula 80 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume oil and perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 81 Formula 82 Formula 83 Formula 84 Formula 85 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 86 Formula 87 Formula 88 Formula 89 Formula 90 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 perfume oil 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 91 Formula 92 Formula 93 Formula 94 Formula 95 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0, 1 to 10 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100 Formula 96 Formula 97 Formula 98 Formula 99 Formula 100 Sodium acetate trihydrate 20 to 95 30 to 95 30 to 95 40 to 90 45 to 90 Perfume oil and perfume capsules 0.1 to 20 0.1 to 20 1.0 to 15 1.0 to 15 3.0 to 12 pyrogenic silica 1.0 to 2.5 1.0 to 2.5 1.0 to 2.5 1.2 to 2.0 1.2 to 2.0 (microfibrillated) cellulose 0.1 to 25 0.1 to 20 0.1 to 18 0.1 to 15 0.1 to 10 Fatty alcohol ethoxylate with 5 to 50 EO 0.1 to 10 0.1 to 5.0 0.2 to 5.0 0.2 to 3.0 0.5 to 2.0 Bittern 0.0001 to 0.1 0.0005 to 0.02 0.001 to 0.01 0.002 to 0.005 0.005 to 0.004 Misc ad 100 ad 100 ad 100 ad 100 ad 100

The composition according to the present invention is a solid, particulate composition. The individual particles of the composition can be referred to as a melting body, which are solid at room temperature and temperatures up to 30 ° C, preferably up to 40 ° C.

In various embodiments of the invention, the enamel bodies according to the invention are coated. Suitable coating compositions are, for example, tablet coatings known from the pharmaceutical literature. The lozenges can also be waxed, i. coated with a wax, or powdered with a powdery material, such as a release agent, to prevent caking (agglomeration). It is preferred that the coating does not consist of PEG or comprises it in any appreciable amount (> 10% by weight, based on the coating).

1. (a) Erzeugen, vorzugsweise kontinuierliches Erzeugen und Fördern, einer Schmelze umfassend das mindestens eine wasserlösliche Trägermaterial
2. (b) gegebenenfalls Zudosieren weiterer optionaler Inhaltsstoffe;
3. (c) Zudosieren, vorzugsweise kontinuierliches Zudosieren, des mindestens einen Duftstoffs, des mindestens einen Bitterstoffs und optional eines Farbstoffs zu der Schmelze;
4. (d) Mischen der Schmelze und des mindestens einen Duftstoffs; und
5. (e) Abkühlen und optional Umformen der Mischung um parfümhaltige Schmelzkörper zu erhalten.

A method of making such fuses may include the following steps:

1. (a) producing, preferably continuously producing and conveying, a melt comprising the at least one water-soluble carrier material
2. (b) optionally dosing in further optional ingredients;
3. (c) metering, preferably continuously dosing, the at least one perfume, the at least one bittern and optionally a dye to the melt;
4. (d) mixing the melt and the at least one perfume; and
5. (e) cooling and optionally forming the mixture to obtain perfume-containing fusible bodies.

The fusible bodies produced in this way can have any desired shape. The shaping takes place in particular in step (d) of the described method. Preferred are solid, particulate forms, such as substantially spherical, figural, scale, cuboid, cylinder, cone, kugelkalotten- or lens, hemispheres, disc or acicular particles. For example, the particles may have a gummy-like, figurative design. Because of their packaging properties and their performance profile, hemispherical particles are particularly preferred.

It is furthermore preferred if the composition consists of at least 20% by weight, preferably at least 40% by weight, more preferably at least 60% by weight and especially preferably at least 80% by weight, of particles which are present in each Have any spatial direction a spatial extent between 0.5 to 10 mm, in particular 0.8 to 7 mm and more preferably 1 to 3 mm. Due to their aesthetics, corresponding particles are characterized by increased customer acceptance.

Finally, it has proved to be advantageous for the dosage and the scent effect, if the composition is at least 20 wt .-%, preferably at least 40 wt%, more preferably at least 60 wt .-% and particularly preferably at least 80 wt. % consists of particles having a particle weight between 2 and 150 mg, preferably between 4 and 60 mg and in particular between 5 and 10 mg.

In various embodiments, producing a melt, the melt, in step (a) of the processes described herein, is carried out by heating to a temperature not more than 20 ° C above the temperature of the support material at which the water vapor partial pressure of the hydrate H ₂ O partial pressure of the saturated solution of this salt corresponds. As already described above, the carrier material can already be used as a hydrate or the hydrate is by combining the anhydrous salt and water in a stoichiometric, stoichiometric or superstoichiometric amount, preferably stoichiometric or superstoichiometric amount, based on the amount required for the conversion of the total salt in the desired hydrate, generated in situ before step (a) or in step (a).
The melting can be carried out using all customary methods and devices known to the person skilled in the art. The melt which contains the at least one support material is, for example, continuously produced by reacting the at least one support material, the bitter substance and optionally further optional constituents of the melt body, such as, for example, fumed silica, cellulose, fatty alcohols, fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, Alkylbenzenesulfonates or a solid or filler alone or in combinations continuously supplied to a corresponding device in which it is heated and the melt thus produced further promoted, for example, is pumped.

However, the melt can also be prepared separately, for example in a batch process. According to the invention, embodiments are also included in which the constituents of the melt are mixed together at any time prior to carrying out the process according to the invention and the mixture is stored until the process is carried out in molten or cooled solid form. The melt thus produced can be used as a masterbatch, which then in the following step, depending on the needs, different fragrances and possibly also other ingredients, such as dyes, are added.

In a next step, the at least one perfume is then added continuously to the melt. For this purpose, the at least one perfume is preferably used in liquid form, for example as perfume oil, solution in a suitable solvent or as a slurry of perfume capsules in a, typically water-containing, solvent. "Liquid" as used in this context means liquid under the conditions of use, preferably liquid at 20 ° C. In addition to the fragrance, a dye can also be dosed in this step. For example, the dye may be indicative of the type of perfume, i. for a particular perfume / perfume mixture, a special dye or dye mixture is used to make the pastilles obtained directly visually distinguishable.

During production, the flow can optionally be measured by measuring the flow rate of the individual metered streams, i. the melt, the perfume stream and possibly other ingredient streams are controlled. This also allows, for example, adjust the proportions of the individual components. The ingredients in addition to the carrier material and the fragrances can be produced either directly together with the carrier material as a melt, are added together with the fragrances or separately to the melt. In the latter alternative, the metered addition can take place before or after the addition of the fragrances.

In some embodiments, the process according to the invention is characterized in that at least one optional constituent of the melting body, such as fumed silica, cellulose, fatty alcohols, fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkylbenzenesulfonates, or a solid or filler alone or in combinations with the in Step (a) produced and conveyed melt are metered and / or already contained in the produced and promoted in step (a) melt.

The mixing of the combined metering streams can then be carried out in each case directly after metering or downstream after metering in several or all of the ingredients with suitable mixers, such as customary static or dynamic mixing units.

After mixing, the melt containing the fragrance and optionally solids and optionally further ingredients and the carrier material is cooled and optionally fed to the forming, where the melt solidifies and obtains its final shape. Suitable methods for shaping are known to the person skilled in the art. Usual forms have already been described above.

The invention also relates to the enamel bodies obtainable by means of the processes described herein and to their use as textile care agents, preferably fragrancing agents for tufting textile fabrics. The enamel bodies may be a textile treatment agent, such as, for example, a fabric softener or a part of such an agent.

Furthermore, the invention relates to a washing or cleaning agent comprising the fused bodies produced according to the invention.

By introducing the fragrance-containing enamel body according to the invention into a washing or cleaning agent, the consumer is provided with a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) and he does not need to dose two agents and no separate rinse. Since the compositions according to the invention are perfumed, the washing or cleaning agent does not have to be perfumed. Not only does this result in lower costs, it is also beneficial for consumers with sensitive skin and / or allergies.

The fused-state compositions described herein are particularly suitable for scenting textile fabrics and are brought into contact with the textile fabrics together with a conventional washing or cleaning agent in the (main) wash cycle of a conventional washing and cleaning process.

If the enamel-body composition according to the invention is part of a washing or cleaning agent, a solid washing or cleaning agent may preferably be mixed with from 1 to 20% by weight, in particular from 5 to 15% by weight, of the composition according to the invention.

The preferred embodiments described in connection with the methods according to the invention are also transferable to the fusible elements as such, the detergents and cleaning agents containing them and the uses described herein, and vice versa.

1. 1. Eine feste, partikuläre Zusammensetzung umfassend
   1. (a) 20 bis 95 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines wasserlöslichen Trägermaterials ausgewählt aus wasserhaltigen Salzen, deren Wasserdampf-Partialdruck bei einer bestimmten Temperatur im Bereich von 30 bis 100°C dem H₂O-Partialdruck der gesättigten Lösung dieses Salzes bei derselben Temperatur entspricht,
   2. (b) 0,1 bis 20 Gew.-% mindestens eines Duftstoffs,
   3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
   4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
   5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Fettalkohole, Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon
   6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
   7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
   8. (h) optional mindesten einen Farbstoff.
2. 2. Zusammensetzung nach Punkt 1, dadurch gekennzeichnet, dass das wasserlösliche Trägermaterial ausgewählt wird aus wasserhaltigen Salzen, deren Wasserdampf-Partialdruck bei einer Temperatur im Bereich von 40 bis 90°C, vorzugsweise von 50 bis 85 °C, noch bevorzugter von 55 bis 80 °C, dem H₂O-Partialdruck der gesättigten Lösung dieses Salzes entspricht, vorzugsweise Natriumacetat-Trihydrat (Na(CH₃COO) · 3H₂O) ist.
3. 3. Zusammensetzung nach einem der Punkte 1 oder 2, dadurch gekennzeichnet, dass das wasserlösliche Trägermaterial in einer Menge von 30 bis 95 Gew.-%, vorzugsweise von 40 bis 90 Gew.-%, insbesondere von 45 bis 90 Gew.-%, basierend auf dem Gesamtgewicht der Zusammensetzung, in dieser enthalten ist.
4. 4. Eine feste, partikuläre Zusammensetzung, umfassend
   1. (a) 12 bis 57 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Natriumacetat;
   2. (b) 0,1 bis 10 Gew.-5 mindestens eines Duftstoffs;
   3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
   4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
   5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Fettalkohole, Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon;
   6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
   7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
   8. (h) optional mindesten einen Farbstoff;
   9. (i) Wasser in einer Menge, welche ausreichend ist, um mindestens 60 Gew.-%, vorzugsweise mindestens 70 Gew.-%, noch bevorzugter mindestens 80 Gew.-%, am meisten bevorzugt mindestens 100 Gew.-% des Natriumacetats (a) in Natriumtriacetat-Trihydrat zu überführen.
5. 5. Zusammensetzung nach Punkt 4, dadurch gekennzeichnet, dass das Natriumacetat in einer Menge von 18 bis 57 Gew.-%, vorzugsweise von 24 bis 48 Gew.-%, insbesondere von 27 bis 45 Gew.-%, basierend auf dem Gesamtgewicht der Zusammensetzung, in dieser enthalten ist.
6. 6. Eine feste, partikuläre Zusammensetzung, umfassend
   1. (a) 20 bis 95 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Natriumacetat-Trihydrat;
   2. (b) 0,1 bis 10 Gew.-5 mindestens eines Duftstoffs;
   3. (c) optional bis 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines anorganischen Rheologiemodifikators, vorzugsweise eines anorganischen Rheologiemodifkators aus der Gruppe der pyrogenen Kieselsäuren;
   4. (d) optional bis zu 25 Gew.-%, vorzugsweise 0,5 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, eines organischen Rheologiemodifikators, vorzugsweise eines organischen Rheologiemodifikators aus der Gruppe der Cellulosen, vorzugsweise mikrofibrillierten Cellulosen;
   5. (e) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, Fettalkohole, Fettalkoholalkoxylate, Fettalkoholsulfate, Fettalkoholethersulfate, Alkylbenzolsulfonate oder Kombinationen davon;
   6. (f) optional bis zu 25 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, mindestens eines von (c), (d) und (e) unterschiedlichen Fest- oder Füllstoffs;
   7. (g) 0,0001 bis 0,05 Gew.-%, vorzugsweise 0,0005 bis 0,02 Gew.-%, mindestens eines Bitterstoffs; und
   8. (h) optional mindesten einen Farbstoff.
7. 7. Zusammensetzung nach Punkt 6, dadurch gekennzeichnet, dass das Natriumacetat-Trihydrat in einer Menge von 30 bis 95 Gew.-%, vorzugsweise von 40 bis 90 Gew.-%, insbesondere von 45 bis 90 Gew.-%, basierend auf dem Gesamtgewicht der Zusammensetzung, in dieser enthalten ist.
8. 8. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass der mindestens eine Duftstoff in einer Menge von 1 bis 20 Gew.-%, vorzugsweise 1 bis 15 Gew.-%, noch bevorzugter 3 bis 12 Gew.-% in der Zusammensetzung enthalten ist.
9. 9. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass der mindestens eine Duftstoff in Form von Duftstoffkapseln und/oder Parfümölen eingesetzt wird.
10. 10. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass der anorganische Rheologiemodifikator, insbesondere die pyrogene Kieselsäure, bezogen auf das Gesamtgewicht der Zusammensetzung, in einer Menge von 1 bis 2,5 Gew.-%, bevorzugter 1,2 bis 2,0 Gew.-% in der Zusammensetzung enthalten ist.
11. 11. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die pyrogene Kieselsäure eine BET-Oberfläche von mehr als 50 m²/g, vorzugsweise mehr als 100 m²/g, weiter bevorzugt 150 bis 250 m²/g, insbesondere 175 bis 225 m²/g aufweist.
12. 12. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die der organische Rheologiemodifikator, insbesondere die Cellulose, vorzugsweise die mikrofibrillierte Cellulose, bezogen auf das Gesamtgewicht der Zusammensetzung, in einer Menge von 1 bis 2,5 Gew.-%, bevorzugter 1,2 bis 2,0 Gew.-% in der Zusammensetzung enthalten ist.
13. 13. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Komponenten (d), (e) und (f) unabhängig voneinander in Mengen von 0 bis 25 Gew.-%, vorzugsweise bis 20 Gew.-%, weiter bevorzugt bis 18 Gew.-%, insbesondere bis 15 Gew.-% bezogen auf das Gesamtgewicht der Zusammensetzung, in dieser enthalten sind.
14. 14. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung ferner mindestens einen Farbstoff enthält, vorzugsweise in einer Konzentration von 0,001 bis 0,5 Gew.-%, besonders bevorzugt 0,01 bis 0,3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung.
15. 15. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung kein bei Raumtemperatur (25°C) festes Polyethylenglycol in Form einer Beschichtung enthält.
16. 16. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung weniger als 1 Gew.-%, bezogen auf das Gesamtgewicht, an bei beim Raumtemperatur (25°C) festem Polyethylenglycol enthält.
17. 17. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung ferner freies Wasser enthält.
18. 18. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass der mindestens eine Bitterstoff ein ionogener Bitterstoff, vorzugsweise eine quartäre Ammoniumverbindung, noch bevorzugter Benzyldiethyl((2,6-xylylcarbamoyl)methyl)ammoniumbenzoat ist.
19. 19. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung in Form hemisphärischer Partikel vorliegt
20. 20. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung zu mindestens 20 Gew.-%, vorzugsweise zu mindestens 40 Gew-%, besonders bevorzugt zu mindestens 60 Gew.-% und insbesondere bevorzugt zu mindestens 80 Gew.-% aus Partikeln besteht, welche in jeder beliebigen Raumrichtung eine räumliche Ausdehnung zwischen 0,5 bis 10 mm, insbesondere 0,8 bis 7 mm und besonders bevorzugt 1 bis 3 mm aufweisen.
21. 21. Zusammensetzung nach einem der voranstehenden Punkte, dadurch gekennzeichnet, dass die Zusammensetzung zu mindestens 20 Gew.-%, vorzugsweise zu mindestens 40 Gew-%, besonders bevorzugt zu mindestens 60 Gew.-% und insbesondere bevorzugt zu mindestens 80 Gew.-% aus Partikeln besteht, welche ein Partikelgewicht zwischen 2 und 150 mg, vorzugsweise zwischen 4 und 60 mg und insbesondere zwischen 5 und 10 mg aufweisen.
22. 22. Verwendung der festen Zusammensetzung gemäß einem der Punkte 1 bis 21 als Textilpflegemittel zum Beduften von textilen Flächengebilden.
23. 23. Wasch- oder Reinigungsmittel, umfassend eine feste Zusammensetzung gemäß einem der Punkte 1 bis 21.
24. 24. Ein Verfahren zur Herstellung der Zusammensetzung nach einem der Punkte 1 bis 21, umfassend
    1. (a) Erzeugen einer Schmelze umfassend das mindestens eine wasserlösliche Trägermaterial
    2. (b) gegebenenfalls Zudosieren weiterer optionaler Inhaltsstoffe;
    3. (c) Zudosieren des mindestens einen Duftstoffs, des mindestens einen Bitterstoffs und optional eines Farbstoffs zu der Schmelze;
    4. (d) Mischen der Schmelze und des mindestens einen Duftstoffs; und
    5. (e) Abkühlen und optional Umformen der Mischung um parfümhaltige Schmelzkörper zu erhalten.
25. 25. Verfahren zur Behandlung von Textilien, in dessen Verlauf eine Zusammensetzung nach einem der Punkte 1 bis 21 in die Waschflotte einer Textilwaschmaschine eindosiert wird.

In summary, the present invention provides, inter alia:

1. 1. comprising a solid, particulate composition
   1. (A) 20 to 95 wt .-%, based on the total weight of the composition, of at least one water-soluble carrier material selected from hydrous salts whose water vapor partial pressure at a certain temperature in the range of 30 to 100 ° C the H ₂ O partial pressure of saturated solution of this salt at the same temperature,
   2. (b) 0.1 to 20% by weight of at least one perfume,
   3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
   4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
   5. (e) optionally up to 25% by weight, based on the total weight of the composition, fatty alcohols, fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl benzene sulfonates or combinations thereof
   6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
   7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
   8. (h) optionally at least one dye.
2. 2. Composition according to item 1, characterized in that the water-soluble carrier material is selected from hydrous salts whose water vapor partial pressure at a temperature in the range of 40 to 90 ° C, preferably from 50 to 85 ° C, more preferably from 55 to 80 ° C, the H ₂ O partial pressure of the saturated solution of this salt corresponds, preferably sodium acetate trihydrate (Na (CH ₃ COO) · 3H ₂ O).
3. 3. Composition according to one of the items 1 or 2, characterized in that the water-soluble carrier material in an amount of 30 to 95 wt .-%, preferably from 40 to 90 wt .-%, in particular from 45 to 90 wt .-%, based on the total weight of the composition contained in this.
4. 4. A solid, particulate composition comprising
   1. (a) 12 to 57% by weight, based on the total weight of the composition, of sodium acetate;
   2. (b) 0.1 to 10% by weight of at least one perfume;
   3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
   4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
   5. (e) optionally up to 25% by weight, based on the total weight of the composition, fatty alcohols, fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl benzene sulfonates or combinations thereof;
   6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
   7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
   8. (h) optionally at least one dye;
   9. (i) water in an amount sufficient to be at least 60% by weight, preferably at least 70% by weight, more preferably at least 80% by weight, most preferably at least 100% by weight of the sodium acetate (a ) in sodium triacetate trihydrate.
5. 5. The composition according to item 4, characterized in that the sodium acetate in an amount of 18 to 57 wt .-%, preferably from 24 to 48 wt .-%, in particular from 27 to 45 wt .-%, based on the total weight of Composition, contained in this.
6. 6. A solid, particulate composition comprising
   1. (a) from 20 to 95% by weight, based on the total weight of the composition, of sodium acetate trihydrate;
   2. (b) 0.1 to 10% by weight of at least one perfume;
   3. (c) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an inorganic rheology modifier, preferably an inorganic rheology modifier from the group of pyrogenic silicic acids;
   4. (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses;
   5. (e) optionally up to 25% by weight, based on the total weight of the composition, fatty alcohols, fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl benzene sulfonates or combinations thereof;
   6. (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler;
   7. (g) 0.0001 to 0.05 wt%, preferably 0.0005 to 0.02 wt%, of at least one bittering agent; and
   8. (h) optionally at least one dye.
7. 7. The composition according to item 6, characterized in that the sodium acetate trihydrate in an amount of 30 to 95 wt .-%, preferably from 40 to 90 wt .-%, in particular from 45 to 90 wt .-%, based on the Total weight of the composition contained in this.
8. 8. Composition according to one of the preceding points, characterized in that the at least one perfume in an amount of 1 to 20 wt .-%, preferably 1 to 15 wt .-%, more preferably 3 to 12 wt .-% in the composition is included.
9. 9. Composition according to one of the preceding points, characterized in that the at least one fragrance is used in the form of perfume capsules and / or perfume oils.
10. 10. The composition according to one of the preceding points, characterized in that the inorganic rheology modifier, in particular the fumed silica, based on the total weight of the composition, in an amount of 1 to 2.5 wt .-%, more preferably 1.2 to 2, 0 wt .-% is contained in the composition.
11. 11. Composition according to one of the preceding points, characterized in that the fumed silica has a BET surface area of more than 50 m ² / g, preferably more than 100 m ² / g, more preferably 150 to 250 m ² / g, in particular 175 to 225 m ² / g.
12. 12. Composition according to one of the preceding points, characterized in that the organic rheology modifier, in particular the cellulose, preferably the microfibrillated cellulose, based on the total weight of the composition, in an amount of 1 to 2.5 wt .-%, more preferably 1 , 2 to 2.0 wt .-% is contained in the composition.
13. 13. The composition according to one of the preceding points, characterized in that the components (d), (e) and (f) independently in amounts of 0 to 25 wt .-%, preferably to 20 wt .-%, more preferably to 18 wt .-%, in particular up to 15 wt .-% based on the total weight of the composition are contained in this.
14. 14. The composition according to one of the preceding points, characterized in that the composition further contains at least one dye, preferably in a concentration of 0.001 to 0.5 wt .-%, particularly preferably 0.01 to 0.3 wt .-%, based on the total weight of the composition.
15. 15. Composition according to one of the preceding points, characterized in that the composition does not contain at room temperature (25 ° C) solid polyethylene glycol in the form of a coating.
16. Composition according to any one of the preceding claims, characterized in that the composition contains less than 1% by weight, relative to the total weight, of polyethylene glycol which is solid at room temperature (25 ° C).
17. 17. Composition according to one of the preceding points, characterized in that the composition also contains free water.
18. 18. Composition according to one of the preceding points, characterized in that the at least one bitter substance is an ionogenic bittering agent, preferably a quaternary ammonium compound, more preferably benzyldiethyl ((2,6-xylylcarbamoyl) methyl) ammonium benzoate.
19. 19. Composition according to one of the preceding points, characterized in that the composition is in the form of hemispherical particles
20. 20. Composition according to one of the preceding points, characterized in that the composition is at least 20 wt .-%, preferably at least 40 wt%, especially preferably at least 60 wt .-% and particularly preferably at least 80 wt .-% consists of particles which in any spatial direction, a spatial extent between 0.5 to 10 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
21. 21. Composition according to one of the preceding points, characterized in that the composition is at least 20 wt .-%, preferably at least 40 wt%, more preferably at least 60 wt .-% and particularly preferably at least 80 wt .-% consists of particles having a particle weight between 2 and 150 mg, preferably between 4 and 60 mg and in particular between 5 and 10 mg.
22. 22. Use of the solid composition according to any one of items 1 to 21 as a textile care agent for scenting textile fabrics.
23. 23. A washing or cleaning composition comprising a solid composition according to any one of items 1 to 21.
24. 24. A process for producing the composition according to any one of items 1 to 21, comprising
    1. (a) producing a melt comprising the at least one water-soluble carrier material
    2. (b) optionally dosing in further optional ingredients;
    3. (c) adding the at least one perfume, the at least one bittering agent and optionally a dye to the melt;
    4. (d) mixing the melt and the at least one perfume; and
    5. (e) cooling and optionally forming the mixture to obtain perfume-containing fusible bodies.
25. 25. A process for the treatment of textiles, in the course of which a composition according to any one of items 1 to 21 is metered into the wash liquor of a textile washing machine.

Examples

example 1

The following table gives an example of a formulation according to the invention (all data in% by weight). TABLE 1 Compositions Sodium acetate trihydrate 84,70 Sodium acetate (anhydrous) 56.0 Hydrophilic Fumed Silica (Aerosil 200) 1.50 C16 / 18 fatty alcohol 30 EO 0.80 Microfibrillated cellulose (2% in water) 29.2 Perfume 4.5 0.9 Perfume capsule slurry (50%) 5.5 5.8 Bitter, preferably Bitrex® 0,002 0,002 dye 0.1% water ad 100 ad 100

To prepare the sodium acetate trihydrate was heated to a temperature of 70 ° C and largely dissolved with stirring in his split-off water of crystallization. Subsequently, the other ingredients were incorporated. Using anhydrous acetate, the solution was prepared by stirring it with the formulation water and the microfibrillar cellulose containing 98% water at 70 ° C. Droppers were prepared by dropping the liquid mixture ("melt") to a cooled to room temperature (23 ° C) cooling plate.

The fragrance pastilles of the invention thus prepared were then tested for their water solubility by dissolving 0.4 g of the lozenges in 150 mL of deionized water in a 400 mL beaker with magnetic stirring at 300 rpm and 20 ° C, and the time to reach full resolution was stopped. For comparison, commercial PEG pastilles ("unstoppables") of comparable size were used.

While the lozenges according to the invention dissolved in the stated conditions in 110 seconds, the PEG pellets took 480 seconds. It can be clearly seen that the water-solubility of the pastilles according to the invention is markedly increased compared to the known pastilles.

Claims (10)

A solid, particulate composition comprising (a) 20 to 95% by weight, based on the total weight of the composition, of at least one water-soluble carrier material selected from hydrous salts whose water vapor partial pressure at a particular temperature in the range of 30 to 100 ° C H ₂ O partial pressure of the saturated solution of this salt at the same temperature corresponds, (b) 0.1 to 20 wt .-% of at least one perfume, (c) optionally up to 25 wt .-%, preferably 0.5 to 3 wt. %, based on the total weight of the composition, of an inorganic rheology modifier, preferably of an inorganic rheology modifier from the group of pyrogenic silicic acids; (d) optionally up to 25% by weight, preferably 0.5 to 3% by weight, based on the total weight of the composition, of an organic rheology modifier, preferably an organic rheology modifier from the group of celluloses, preferably microfibrillated celluloses; (e) optionally up to 25% by weight of an emulsifier, preferably an emulsifier selected from the group of fatty alcohols, fatty amide ethoxylates, allyl polyglycosides, fatty acid sorbitan esters, alkylamine oxides, alkyl betaines or fatty alcohol alkoxylates, fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl benzene sulfonates or combinations thereof; (f) optionally up to 25% by weight, based on the total weight of the composition, of at least one of (c), (d) and (e) different solid or filler; (g) 0.0001 to 0.05% by weight, preferably 0.0005 to 0.02% by weight, of at least one bittering agent, and (h) optionally at least one dye. The composition after Claim 1 characterized in that the water-soluble carrier material (A) is selected from hydrous salts whose water vapor partial pressure is at a temperature in the range from 40 to 90 ° C, preferably from 50 to 85 ° C, more preferably from 55 to 80 ° C, corresponding to the H ₂ O partial pressure of the saturated solution of this salt, preferably sodium acetate trihydrate (Na (CH ₃ COO) .3H ₂ O); and / or (B) in an amount of 30 to 95 wt .-%, preferably from 40 to 90 wt .-%, for example 45 to 90 wt .-%, based on the total weight of the composition, in this is contained. The composition according to any one of the preceding claims, characterized in that the at least one perfume (A) in an amount of 1 to 20 wt .-%, preferably 1 to 15 wt .-%, more preferably 3 to 12 wt .-% in the composition is included; and / or (B) is used in the form of perfume capsules and / or perfume oils. The composition according to any one of the preceding claims, characterized in that fumed silica (A) is contained in an amount of from 1 to 2.5% by weight, more preferably from 1.2 to 2.0% by weight in the composition; and / or (B) has a BET surface area of more than 50 m ² / g, preferably more than 100 m ² / g, more preferably 150 to 250 m ² / g, in particular 175 to 225 m ² / g. The composition according to any one of the preceding claims, characterized in that the at least one bittering agent is an ionogenic bittering agent, preferably a quaternary ammonium compound, more preferably benzyldiethyl ((2,6-xylylcarbamoyl) methyl) ammonium benzoate. The composition according to any one of the preceding claims, characterized in that the composition further contains at least one dye, preferably in a concentration of 0.001 to 0.5 wt .-%, particularly preferably 0.01 to 0.3 wt .-%, based on the total weight of the composition. The composition according to any one of the preceding claims, characterized in that the composition further contains free water. A process for preparing the composition according to any one of Claims 1 to 7 composition comprising: (a) producing a melt comprising the at least one water-soluble carrier material (b) optionally metering in additional optional ingredients; (c) adding the at least one perfume, the at least one bittering agent and optionally a dye to the melt; (d) mixing the melt and the at least one perfume; and (e) cooling and optionally forming the mixture to obtain perfume-containing fusible bodies. Use of the solid composition according to any one of Claims 1 to 8th as a textile care agent for the scenting of textile fabrics. A washing or cleaning composition comprising a solid composition according to any one of Claims 1 to 8th ,