DE102017218727A1 - Portioned washing or cleaning agent with bluing agent precursor - Google Patents

Abstract

The present invention relates to a portioned detergent or cleaning agent in a container made of water-soluble material having at least two separate chambers. The portion contains separately prepared Bläuungsmittel precursor compounds which form a bluing agent when used in the wash liquor to compensate for the yellowing of the laundry.

Description

The present invention relates to a portioned detergent or cleaning agent in a container made of water-soluble material having at least two separate chambers.

Detergents or cleaners are now available to the consumer in a variety of forms. In addition to washing powder and granules, this offer also includes, for example, detergent concentrate in the form of extruded or tabletted compositions. These fixed, concentrated or compressed forms of supply are characterized by a reduced volume per dosing unit and thus reduce the costs for packaging and transport. In particular, the washing or cleaning agent tablets additionally meet the consumer's desire for simple dosing.

In essence, liquid detergents and solid detergents are frequently distinguished. In this case, liquid detergents are increasingly desired by the consumer. These have the advantage that they leave no detergent residues on the textiles, which are particularly unpleasant in dark clothing. These are builders, zeolites (water softeners) and auxiliaries that are not found in liquid detergents. Disadvantage of liquid detergents is that they do not contain bleach. As a result, certain stains which are usually removed by bleaching (bleach-sensitive stains), such as fruit, coffee, red wine, tea or vegetable stains, are worse washed out than with solid detergents. In addition, a graying of white laundry is observed. To counteract this, some liquid detergents are added optical display.

Heavy-duty detergents usually contain bleaches, so that bleach-sensitive stains can be better removed and also a graying of white laundry is prevented. At higher temperatures, heavy-duty detergents also act against germs. The frequently occurring detergent residues can be avoided by a precise dosage of the detergent.

It has proved to be advantageous, in order to increase the perceived whiteness of the textile, to add to the detergents, in particular the liquid detergents, at least one bluing agent. A blueing agent is a blue to violet dye that visibly compensates for the yellowing of a substrate, especially a textile, to the eye, thereby enhancing the whiteness.

A disadvantage of the use of bluing agents is that the detergent itself is always colored bluish to violet. The supply of brilliant yellow, red or colorless detergents is not possible with the use of bluing agents.

Furthermore, it is unfavorable if, after repeated use of the bluing agent-containing detergent on the substrate manifests a visible bluish color. On the substrate, although to compensate for a sufficient compensation of yellowing bluing agents, but a visible blue coloration after repeated use, a so-called build-up effect, should be avoided.

In addition, a bluing agent at local excess concentration in the wash liquor can lead to undesirable stained stains of the substrate, in particular of the textile. This is particularly the case when the substrate treatment agent in the form of a concentrate is applied directly to the substrate prior to its dilution to an application solution or otherwise directly contacts the substrate. This is the case, for example, in textile treatments in which the textile treatment agent is metered into the washing drum together with the textiles, and subsequently the application solution (liquid liquor) is formed by adding solvents, in particular water.

It is known to dose textile treatment agent in pre-portioned form directly together with the textile in the drum of the washing machine. Said portions are, for example, detergents which are provided with a water-soluble coating. It has been found that, particularly in the coating of liquid detergents, the bluing agent contained in the liquid detergent can migrate through the casing into other portions or into other chambers of the same portion. Such unwanted migration effects, for example, in lines 14-24 of page 1 of the document WO 2014/089386 A1 described and can be avoided if necessary by the use of special solvent systems.

It was now the object of the present invention to provide compositions with bluing functionality without having a restriction in the choice of intrinsic color by the presence of the bluing functionality. The color of the composition should be stable, especially during storage in a multi-compartment portion provided with a water-soluble coating. The solution is the use of at least two bluing agent precursor compounds, which are formulated separately in one portion and, upon contact with each other in a chemical reaction, can form a bluing agent.

1. (i) einen Behälter aus wasserlöslichem Material mit mindestens zwei voneinander getrennten Kammern und
2. (ii) ein in besagtem Behälter konfektioniertes Wasch- oder Reinigungsmittel, enthaltend auf dessen Gesamtgewicht bezogen eine Gesamtmenge von 20 bis 70 Gew.-% Tensid, wobei besagtes Wasch- oder Reinigungsmittel mindestens zwei, in besagten Kammern getrennt voneinander konfektionierte Zusammensetzungen umfasst,

wobei sich die Portion dadurch gekennzeichnet, dass in besagtem Behälter

1. (a) in mindestens einer Kammer eine Zusammensetzung, enthaltend mindestens eine erste Bläuungsmittel-Vorläuferverbindung, und
2. (b) in mindestens einer hiervon verschiedenen weiteren Kammer, eine Zusammensetzung, enthaltend mindestens eine reaktive Carbonylverbindung, insbesondere mindestens einen Aldehyd, als zweite Bläuungsmittel-Vorläuferverbindung

enthalten ist, mit der Maßgabe, dass besagte erste und zweite Bläuungsmittel-Vorläuferverbindungen in besagtem Behälter getrennt voneinander konfektioniert sind.A first subject of the invention is therefore a portion comprising

1. (I) a container of water-soluble material having at least two separate chambers and
2. (ii) a detergent prepared in said container containing, based on the total weight thereof, a total amount of from 20 to 70% by weight of surfactant, said washing or cleaning composition comprising at least two compositions separately packaged in said chambers;

the portion being characterized in that in said container

1. (A) in at least one chamber, a composition containing at least a first Bluuungsmittel precursor compound, and
2. (B) in at least one further different chamber, a composition containing at least one reactive carbonyl compound, in particular at least one aldehyde, as a second bluencer precursor compound

with the proviso that said first and second bluencer precursor compounds are packaged separately in said container.

Unless otherwise stated, in the present application% data refers to% a.s., ie percent active substance or perfume. Active substance here means the proportion that is active, ie effective, in the washing or cleaning agent. If ranges are specified, then the values in between are to be regarded as disclosed.

A "blueing agent" is a blue to violet dye that turns blue to violet to enhance the whiteness of white textiles. One method of determining the presence of a blueing agent is the colorimetric measurement of the Lab values, as described in the document WO 2014/089386 A1 on page 7, line 20 to page 9, line 6, to which reference is expressly made. A blueing agent is present, for example, when the blue to violet dye on the textile causes a DE * value of at least 2.0 DE * units, preferably at least 3.0 DE * units, particularly preferably at least 4.0 DE * units, according to the abovementioned test method ,

It is inventively preferred if the dye in solution or dispersion (ethanol, at 20 ° C) has an absorption maximum in a wavelength range of 510 and 640 nm, more preferably from 530 to 620 nm.

The bluing agent is preferably a dye whose maximum extinction coefficient in a wavelength range of 400 to 750 nm is preferably larger than 1,000 L / mol / cm.

A "blue-dye precursor compound" alone is not a blueing agent but serves as a reactant for at least one other bleach precursor compound which together form a blueing agent in a chemical reaction with each other.

It is preferred according to the invention if the portion contains, as the first bluencer precursor compound, at least one CH-acidic compound.

As "CH-acidic compounds" are generally considered those compounds which carry a hydrogen atom bonded to an aliphatic carbon atom, wherein in aqueous solution due to electron-withdrawing substituents, activation of the corresponding carbon-hydrogen bond is effected. CH-acidic compounds are known in particular from aldol condensations or Michael additions as reactants.

worin

• • R⁶ steht für eine lineare oder cyclische (C₁ bis C₆)-Alkylgruppe, eine (C₂ bis C₆)-Alkenylgruppe, eine gegebenenfalls substituierte Arylgruppe, eine gegebenenfalls substituierte Heteroarylgruppe, eine Aryl-(C₁ bis C₆)-alkylgruppe, eine (C₁ bis C₆)-Hydroxyalkylgruppe, eine (C₂ bis C₆)-Polyhydroxyalkylgruppe, eine (C₁ bis C₆)-Alkoxy-(C₁ bis C₆)-alkylgruppe, eine Gruppe R^IR^IIN-(CH₂)_m-, worin R^I und R^II stehen unabhängig voneinander für ein Wasserstoffatom, eine (C₁ bis C₄)-Alkylgruppe, eine (C₁ bis C₄)-Hydroxyalkylgruppe oder eine Aryl-(C₁ bis C₆)-alkylgruppe, wobei R^I und R^II gemeinsam mit dem Stickstoffatom einen 5-, 6- oder 7-gliedrigen Ring bilden können und m steht für eine Zahl 2, 3, 4, 5 oder 6,
• • R⁷ steht für eine (C₁ bis C₆)-Alkylgruppe, insbesondere für eine Methylgruppe,
• • der Zyklus der Formel (I) repräsentiert alle Ringstrukturen, die zusätzlich weitere Heteroatome wie Stickstoff, Sauerstoff oder Schwefel enthalten können und ferner ankondensierte Ringstrukturen tragen können, wobei alle diese Ringsstrukturen zusätzliche Substituenten tragen können,
• • X^- steht für ein physiologisch verträgliches Anion.

It has proved to be preferred according to the invention if at least one compound of the formula (I) is contained in the portions as the first bluencer precursor compound

wherein

• R ⁶ is a linear or cyclic (C ₁ to C ₆ ) alkyl group, a (C ₂ to C ₆ ) alkenyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an aryl (C ₁ to C ₆ ) alkyl group, a (C ₁ to C ₆ ) hydroxyalkyl group, a (C ₂ to C ₆ ) polyhydroxyalkyl group, a (C ₁ to C ₆ ) alkoxy (C ₁ to C ₆ ) alkyl group, a group R ^I R ^{II is} N- (CH ₂ ) _m -, in which R ^I and R ^II independently of one another represent a hydrogen atom, a (C ₁ to C ₄ ) -alkyl group, a (C ₁ to C ₄ ) -hydroxyalkyl group or an aryl- ( C ₁ to C ₆ ) -alkyl group, wherein R ^I and R ^II together with the nitrogen atom can form a 5-, 6- or 7-membered ring and m is a number 2, 3, 4, 5 or 6,
• R ⁷ is a (C ₁ to C ₆ ) -alkyl group, in particular a methyl group,
• The cycle of the formula (I) represents all ring structures which may additionally contain further heteroatoms such as nitrogen, oxygen or sulfur and may further carry fused ring structures, all of these ring structures being able to carry additional substituents,
• • X ^- stands for a physiologically compatible anion.

The compounds according to formula (I) and (I-1) (vide infra) are CH-acidic compounds. From the cationic compounds of the formula (I), it is possible by targeted addition of a base which promotes the splitting off of a proton to represent the corresponding uncharged enamine form. Exemplary of compounds according to formula (I), the representation of the enamine form is illustrated below with reference to the formulas (IA) and (IB) with R ⁷ = CH ₃ . The corresponding enamine forms of the CH-acidic compounds according to formula (I) are bluencer precursor compounds according to the invention.

worin

• • R⁸ und R⁹ stehen unabhängig voneinander für eine lineare oder cyclische C₁-C₆-Alkylgruppe, eine C₂-C₆-Alkenylgruppe, eine gegebenenfalls substituierte Arylgruppe, eine gegebenenfalls substituierte Heteroarylgruppe, eine Aryl-C₁-C₆-alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe, eine C₂-C₆-Polyhydroxyalkylgruppe, eine C₁-C₆-Alkoxy-C₁-C₆-alkylgruppe, eine Gruppe R^IR^IIN-(CH₂)_m-, worin R^I und R^II stehen unabhängig voneinander für ein Wasserstoffatom, eine C₁-C₄-Alkylgruppe, eine C₁-C₄-Hydroxyalkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe, wobei R^I und R^II gemeinsam mit dem Stickstoffatom einen 5-, 6- oder 7-gliedrigen Ring bilden können und m steht für eine Zahl 2, 3, 4, 5 oder 6,
• • R¹⁰ und R¹² stehen unabhängig voneinander für ein Wasserstoffatom oder eine C₁-C₆-Alkylgruppe, wobei mindestens einer der Reste R¹⁰ und R¹² eine C₁-C₆-Alkylgruppe bedeutet,
• • R¹¹ steht für ein Wasserstoffatom, eine C₁-C₆-Alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe, eine C₂-C₆-Polyhydroxyalkylgruppe, eine C₁-C₆-Alkoxygruppe, eine C₁-C₆-Hydroxyalkoxygruppe, eine Gruppe R^IIIR^IVN-(CH₂)_q-, worin R^III und R^IV stehen unabhängig voneinander für ein Wasserstoffatom, eine C₁-C₆-Alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe und q steht für eine Zahl 1, 2, 3, 4, 5 oder 6, wobei der Rest R¹¹ zusammen mit einem der Reste R¹⁰ oder R¹² einen 5- oder 6-gliedrigen aromatischen Ring bilden kann, der gegebenenfalls mit einem Halogenatom, einer C₁-C₆-Alkylgruppe, einer C₁-C₆-Hydroxyalkylgruppe, einer C₂-C₆-Polyhydroxyalkylgruppe, einer C₁-C₆-Alkoxygruppe, einer C₁-C₆-Hydroxyalkoxygruppe, einer Nitrogruppe, einer Hydroxygruppe, einer Gruppe R^VR^VIN-(CH₂)_s-, worin R^V und R^VI stehen unabhängig voneinander für ein Wasserstoffatom, eine C₁-C₆-Alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe und s steht für eine Zahl 0, 1, 2, 3, 4, 5 oder 6 substituiert sein kann,
• • Y steht für ein Sauerstoffatom, ein Schwefelatom oder eine Gruppe NR^VII, worin R^VII steht für ein Wasserstoffatom, eine Arylgruppe, eine Heteroarylgruppe, eine C₁-C₆-Alkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe,
• • X- steht für ein physiologisch verträgliches Anion,
• • Het steht für einen gegebenenfalls substituierten Heteroaromaten,
• • X¹ steht für eine direkte Bindung oder eine Carbonylgruppe.

Particularly preferred portion containing as the first Bluuungsmittel precursor compound at least one compound of formula (I-1) is contained

wherein

• R ⁸ and R ⁹ independently of one another represent a linear or cyclic C ₁ -C ₆ -alkyl group, a C ₂ -C ₆ -alkenyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an aryl-C ₁ -C ₆ - alkyl group, a C ₁ -C ₆ hydroxyalkyl group, a C ₂ -C ₆ polyhydroxyalkyl group, a C ₁ -C ₆ alkoxy-C ₁ -C ₆ alkyl group, a group R ^I R ^II N- (CH ₂ ) _m in which R ^I and R ^II independently of one another represent a hydrogen atom, a C ₁ -C ₄ -alkyl group, a C ₁ -C ₄ -hydroxyalkyl group or an aryl-C ₁ -C ₆ -alkyl group, where R ^I and R ^II together with the nitrogen atom can form a 5-, 6- or 7-membered ring and m is a number 2, 3, 4, 5 or 6,
• R ¹⁰ and R ¹² independently of one another represent a hydrogen atom or a C ₁ -C ₆ -alkyl group, where at least one of the radicals R ¹⁰ and R ¹² denotes a C ₁ -C ₆ -alkyl group,
• R ¹¹ is hydrogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ hydroxyalkyl, C ₂ -C ₆ polyhydroxyalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ -Hydroxyalkoxygruppe, a group R ^III R ^IV N- (CH ₂ ) _q -, wherein R ^III and R ^IV independently represent a hydrogen atom, a C ₁ -C ₆ alkyl group, a C ₁ -C ₆ hydroxyalkyl group or a Aryl-C ₁ -C ₆ -alkyl group and q is a number 1, 2, 3, 4, 5 or 6, wherein the radical R ¹¹ together with one of the radicals R ¹⁰ or R ^{12 is} a 5- or 6-membered aromatic Ring optionally containing a halogen atom, a C ₁ -C ₆ -alkyl group, a C ₁ -C ₆ -hydroxyalkyl group, a C ₂ -C ₆ -polyhydroxyalkyl group, a C ₁ -C ₆ -alkoxy group, a C ₁ - C ₆ -hydroxyalkoxy group, a nitro group, a hydroxy group, a group R ^V R ^VI N- (CH ₂ ) _s -, wherein R ^V and R ^VI independently of one another represent a hydrogen atom, a C ₁ -C ₆ -alkyl group, a C ₁ -C ₆ -hydroxyalkyl group or an aryl-C ₁ -C ₆ -alkyl group and s is a number 0, 1, 2, 3, 4, 5 or 6 may be substituted,
• Y is an oxygen atom, a sulfur atom or a group NR ^VII , in which R ^VII represents a hydrogen atom, an aryl group, a heteroaryl group, a C ₁ -C ₆ -alkyl group or an aryl-C ₁ -C ₆ -alkyl group,
• X- represents a physiologically acceptable anion,
• Het is an optionally substituted heteroaromatic,
• • X ¹ represents a direct bond or a carbonyl group.

If a radical is referred to as optionally substituted, this radical may carry at least one radical selected from a C ₁ -C ₆ -alkyl group, a C ₂ -C ₆ -alkenyl group, a C ₁ -C _6, instead of at least one of its carbon-bonded hydrogen atoms -Hydroxyalkyl group, a C ₂ -C ₆ -polyhydroxyalkyl group, a C ₁ -C ₆ -alkoxy group, a C ₁ -C ₆ -hydroxyalkoxy group, a halogen atom.

An aryl-C ₁ -C ₆ -alkyl group is, for example, benzyl. An aryl group is, for example, phenyl or naphthyl. A heteroaryl group is, for example, pyridinyl, pyrazolyl, furyl.

At least one group R ¹⁰ or R ¹² according to formula (I-1) is necessarily a (C ₁ to C ₆ ) alkyl group. This alkyl group preferably carries at least two hydrogen atoms on its α-carbon atom. Particularly preferred alkyl groups are the methyl, ethyl, propyl, n-butyl, iso-butyl, n-pentyl, neo-pentyl, n-hexyl group. Most preferably, R ¹⁰ and R ¹² are each independently hydrogen or a methyl group, wherein at least one group R ¹⁰ or R ^{12 is} a methyl group.

In a preferred embodiment, Y of the formula (I-1) represents an oxygen or a sulfur atom, more preferably an oxygen atom.

The radical R ^{8 of} the formula (I-1) is preferably selected from a (C ₁ to C ₆ ) -alkyl group (particularly preferably a methyl group), a (C ₂ to C ₆ ) -alkenyl group (in particular an allyl group), a ( C ₂ to C ₆ ) hydroxyalkyl group (especially a 2-hydroxyethyl group) or an optionally substituted benzyl group.

R ^{11 of} the formula (I-1) is preferably a hydrogen atom.

Particularly preferred in formula (I-1) are the radicals R ⁹ , R ¹⁰ and R ^{12 is} a methyl group, the radical R ^{11 is} a hydrogen atom, Y is an oxygen or sulfur atom and the radical R ⁸ is selected from a ( C ₁ to C ₆ ) alkyl group (particularly preferably a methyl group), a (C ₂ to C ₆ ) alkenyl group (especially an allyl group), a (C ₂ to C ₆ ) hydroxyalkyl group (especially a 2-hydroxyethyl group) or a optionally substituted benzyl group.

wobei

• • R für eine Allylgruppe, eine Hydroxy-(C₂- bis C₆)-alkylgruppe oder eine gegebenenfalls substituierte Benzylgruppe steht,
• • X- ein physiologisch verträgliches Anion bedeutet

Again, preference is given to those CH-acidic compounds which are selected from at least one compound of the formula I-2,

in which

• R is an allyl group, a hydroxy (C ₂ to C ₆ ) alkyl group or an optionally substituted benzyl group,
• • X- means a physiologically acceptable anion

Examples of hydroxy (C _{2 to} C ₆ ) -alkyl groups of the formula (I) or (I-1) or (I-2) are 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 4-hydroxybutyl, and 6-hydroxyhexyl. Preferred hydroxy (C _{2 to} C ₆ ) -alkyl groups according to formula (I) or (I-1) or (I-2) are 2-hydroxyethyl, 2-hydroxypropyl and 3-hydroxypropyl, more preferably 2- Hydroxypropyl and 3-hydroxypropyl.

It is preferred if X ^{- in} accordance with formula (I) and according to formula (I-1) and according to formula (I-2) is selected from halide, benzenesulfonate, p-toluenesulfonate, (C ₁ - to C ₄ ) -alkanesulfonate, Trifluoromethanesulfonate, perchlorate, 0.5 sulfate, hydrogen sulfate, tetrafluoroborate, hexafluorophosphate or Tetrachlorozinkat. Particularly preferably, X ^- is chloride, bromide or hydrogen sulfate.

R of the formula (I-2) is preferably an allyl group, a 3-hydroxypropyl group, a 2-hydroxypropyl group, a 2-hydroxyethyl group or a benzyl group.

It is very particularly preferred if the portion contains, as the first bluencer precursor compound, at least one compound from a group of salts with physiologically compatible counterion X ^- , which is formed from salts of the
1,2-dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-diethyl-4,6-dimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-dipropyl-4,6-dimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-di (2-hydroxyethyl) -4,6-dimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-diphenyl-4,6-dimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3,4-trimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-diethyl-4-methyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-dipropyl-4-methyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-di (2-hydroxyethyl) -4-methyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3-diphenyl-4-methyl-2-oxo-pyrimidiniums,
1-allyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1- (2-hydroxyethyl) -3,4,6-trimethyl-2-oxo-pyrimidiniums,
1,2-dihydro-1,3,4,6-tetramethyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-diethyl-4,6-dimethyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-dipropyl-4,6-dimethyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-di (2-hydroxyethyl) -4,6-dimethyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-diphenyl-4,6-dimethyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3,4-trimethyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-diethyl-4-methyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-dipropyl-4-methyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-di (2-hydroxyethyl) -4-methyl-2-thioxo-pyrimidiniums,
1,2-dihydro-1,3-diphenyl-4-methyl-2-thioxo-pyrimidiniums,
1,2-dihydro-3,4-dimethyl-2-oxo-chinazoliniums,
1,2-dihydro-1- (3-hydroxypropyl) -3,4,6-trimethyl-2-oxopyrimidiniums,
1-Benzyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidinium and
1,2-dihydro-3,4-dimethyl-2-thioxo-chinazoliniums.

Most preferred is when the first bluencer precursor compound portion contains at least one compound of a physiologically acceptable counterion X salt group of salts formed from salts of 1-allyl-1,2-dihydro-3,4,6 trimethyl-2-oxo-pyrimidiniums (in particular X ^- is bromide) and 1,2-dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidiniums (in particular, X ^- = hydrogen sulfate).

A preferred portion according to the invention is characterized in that the washing or cleaning agent contains the first bluing agent precursor compound in a total amount of 0.0001 to 50 mmol, in particular from 0.001 to 30 mmol. In this case, it has again turned out to be preferred if the washing or cleaning agent contains not more than 15 mmol, in particular not more than 10 mmol, particularly preferably not more than 5 mmol of the first bluing agent precursor compound.

The portion according to the invention contains as second bluencer precursor compound at least one reactive carbonyl compound.

Reactive carbonyl compounds in the context of the invention have at least one carbonyl group as a reactive group which reacts with the first bluencer precursor compound (in particular in the form of a CH-acidic compound) to form a covalent bond and form a bluing agent.

Reactive carbonyl compound as bluing agent precursor and CH-acidic compound as Bluuungsmittel precursor are packaged separately in the inventive portion in different chambers, so that the respective precursor compounds do not react in the portion with each other to a bluing agent. The corresponding blueing agent is formed only when the portion is used in an aqueous medium.

Preferred reactive carbonyl compounds are selected from compounds which carry at least one formyl group and / or at least one keto group, in particular at least one formyl group.

1. a) von Aminen und deren Derivate unter Bildung von Iminen oder Oximen als Additionsverbindung
2. b) von Alkoholen unter Bildung von Acetalen oder Ketalen als Additionsverbindung
3. c) von Wasser unter Bildung von Hydraten als Additionsverbindung (die reaktive Carbonylverbindung leitet sich in diesem Fall c) von einem Aldehyd ab)

an das Kohlenstoffatom der Carbonylgruppe der reaktiven Carbonylverbindung.Furthermore, according to the invention, those compounds which are derivatized or masked as second bluencer precursor compound in which the reactive carbonyl group is derivatized or masked such that the reactivity of the carbon atom of the derivatized carbonyl group with respect to the CH-acidic compound is always present can also be used. These derivatives are preferably addition compounds

1. a) amines and derivatives thereof to form imines or oximes as addition compound
2. b) of alcohols to form acetals or ketals as addition compound
3. c) of water to form hydrates as addition compound (the reactive carbonyl compound is derived in this case c) from an aldehyde)

to the carbon atom of the carbonyl group of the reactive carbonyl compound.

Preferred among the reactive carbonyl compounds of the agent A are compounds selected from compounds of the following group: benzaldehyde and its derivatives, naphthaldehyde and its derivatives, cinnamaldehyde and its derivatives, 2-formylmethylene-1,3,3-trimethylindoline (Fischer's aldehyde or tribasic aldehyde) , 2-indolealdehyde, 3-indolealdehyde, 1-methylindole-3-aldehyde, 2-methylindole-3-aldehyde, 2- (1 ', 3', 3'-trimethyl-2-indolinylidene) -acetaldehyde, 1-methylpyrrole 2-aldehyde, pyridoxal, antipyrin-4-aldehyde, furfural, 5-nitrofurfural, chromon-3-aldehyde, 3- (5'-nitro-2'-furyl) -acrolein, 3- (2'-furyl) -acrolein and imidazole-2-aldehyde, 5- (4-dimethylaminophenyl) -penta-2,4-dienal, 5- (4-diethylaminophenyl) -penta-2,4-dienal, 5- (4-methoxyphenyl) -penta-2,4- dienal, 5- (3,4-dimethoxyphenyl) penta-2,4-dienal, 5- (2,4-dimethoxyphenyl) penta-2,4-dienal, 5- (4-piperidinophenyl) penta-2,4-dienal , 5- (4-morpholinophenyl) penta-2,4-dienal, 5- (4-pyrrolidinophenyl) penta-2,4-dienal, 5- (4-dimethylamino-1-naphthyl) penta-3,5-diena 1, piperonal, 6-nitropiperonal, 2-nitropiperonal, 5-nitrovanillin, 2,5-dinitrosalicylaldehyde, 5-bromo-3-nitrosalicylaldehyde, 3-nitro-4-formylbenzenesulfonic acid, 4-formyl-1-methylpyridinium, 2-formyl 1-methylpyridinium, 4-formyl-1-ethylpyridinium, 2-formyl-1-ethylpyridinium, 4-formyl-1-benzylpyridinium, 2-formyl-1-benzylpyridinium, 4-formyl-1,2- dimethyl pyridinium, 4-formyl-1,3-dimethyl pyridinium, 4-formyl-1-methyl-quinolinium, 2-formyl-1-methyl-quinolinium, 5-formyl-1-methyl-quinolinium, 6-formyl-1-methyl-quinolinium, 7-formyl-1-methylquinolinium, 8-formyl-1-methylquinolinium, 5-formyl-1-ethylquinolinium, 6-formyl-1-ethylquinolinium, 7-formyl-1-ethylquinolinium, 8-formyl-1 ethylquinolinium, 5-formyl-1-benzyl-quinolinium, 6-formyl-1-benzyl-quinolinium, 7-formyl-1-benzyl-quinolinium, 8-formyl-1-benzyl-quinolinium, 5-formyl-1-allyl-quinolinium, 6-formyl 1-allyl-quinolinium, 7-formyl-1-allyl-quinolinium and 8-formyl-1-allyl-quinolinium-benzenesulfonate, p-toluenesulfonate, methanesulfonate onat, perchlorate, sulfate, chloride, bromide, iodide, tetrachlorozincate, methylsulfate, trifluoromethanesulfonate, tetrafluoroborate, isatin, 1-methyl-isatin, 1-allyl-isatin, 1-hydroxymethyl-isatin, 5-chloro-isatin, 5-methoxy-isatin, 5-nitro-isatin, 6- Nitro-isatin, 5-sulfoisatin, 5-carboxyisatin, quinisatin, 1-methylquinisatin, and any mixtures of the above compounds.

worin

• • R¹, R² und R³ stehen unabhängig voneinander für ein Wasserstoffatom, ein Halogenatom, eine C₁-C₆-Alkylgruppe, eine Hydroxygruppe, eine C₁-C₆-Alkoxygruppe, eine C₁-C₆-Dialkylaminogruppe, eine Di(C₂-C₆-hydroxyalkyl)aminogruppe, eine Di(C₁-C₆-alkoxy-C₁-C₆-alkyl)aminoguppe, eine C₁-C₆-Hydroxyalkyloxygruppe, eine Sulfonylgruppe, eine Carboxygruppe, eine Sulfonsäuregruppe, eine Sulfonamidogruppe, eine Sulfonamidgruppe, eine Carbamoylgruppe, eine C₂-C₆-Acylgruppe oder eine Nitrogruppe,
• • Z' steht für eine direkte Bindung oder eine Vinylengruppe,
• • R⁴ und R⁵ stehen für ein Wasserstoffatom oder bilden gemeinsam, zusammen mit dem Restmolekül einen 5- oder 6-gliederigen aromatischen oder aliphatischen Ring.

A portion according to the invention which contains as at least one compound of the formula (II) as the second bluencer precursor compound is particularly preferred.

wherein

• R ¹ , R ² and R ³ are each independently hydrogen, halogen, C ₁ -C ₆ alkyl, hydroxy, C ₁ -C ₆ alkoxy, C ₁ -C ₆ dialkylamino, etc. Di (C ₂ -C ₆ hydroxyalkyl) amino group, di (C ₁ -C ₆ alkoxy-C ₁ -C ₆ alkyl) amino group, C ₁ -C ₆ hydroxyalkyloxy group, sulfonyl group, carboxy group, sulfonic acid group , a sulfonamido group, a sulfonamide group, a carbamoyl group, a C ₂ -C ₆ acyl group or a nitro group,
• Z 'is a direct bond or a vinylene group,
• R ⁴ and R ⁵ represent a hydrogen atom or together form, together with the remainder of the molecule, a 5- or 6-membered aromatic or aliphatic ring.

It is particularly preferred if, as reactive carbonyl compound, at least one compound is selected from at least one of the compounds of the group consisting of 4-hydroxy-3-methoxybenzaldehyde, 3,5-dimethoxy-4-hydroxybenzaldehyde, 4-hydroxy-1-naphthaldehyde, 4 -Hydroxy-2-methoxybenzaldehyde, 3,4-dihydroxy-5-methoxybenzaldehyde, 3,4,5-trihydroxybenzaldehyde, 3,5-dibromo-4-hydroxybenzaldehyde, 4-hydroxy-3-nitrobenzaldehyde, 3-bromo-4-hydroxybenzaldehyde , 4-hydroxy-3-methylbenzaldehyde, 3,5-dimethyl-4-hydroxybenzaldehyde, 5-bromo-4-hydroxy-3-methoxybenzaldehyde, 4-diethylamino-2-hydroxybenzaldehyde, 4-dimethylamino-2-methoxybenzaldehyde, 3- [ (Dimethylamino) methyl) -4-hydroxy-5-methoxybenzaldehyde, 2-methoxybenzaldehyde, 3-methoxybenzaldehyde, 4-methoxybenzaldehyde, 2-ethoxybenzaldehyde, 3-ethoxybenzaldehyde, 4-ethoxybenzaldehyde, 4-hydroxy-2,3-dimethoxybenzaldehyde, 4- Hydroxy-2,5-dimethoxybenzaldehyde, 4-hydroxy-2,6-dimethoxybenzaldehyde, 4-hydroxy-2-methylbenzaldehyde, 4-hydroxy-2,3-dimethylbenzaldeh yd, 4-hydroxy-2,5-dimethylbenzaldehyde, 4-hydroxy-2,6-dimethylbenzaldehyde, 3,5-diethoxy-4-hydroxybenzaldehyde, 2,6-diethoxy-4-hydroxybenzaldehyde, 3-hydroxy-4-methoxybenzaldehyde, 2-hydroxy-4-methoxybenzaldehyde, 2-ethoxy-4-hydroxybenzaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, 4-ethoxy-2-hydroxybenzaldehyde, 4- Ethoxy-3-hydroxybenzaldehyde, 2,3-dimethoxybenzaldehyde, 2,4-dimethoxybenzaldehyde, 2,5-dimethoxybenzaldehyde, 2,6-dimethoxybenzaldehyde, 3,4-dimethoxybenzaldehyde, 3,5-dimethoxybenzaldehyde, 2,3,4- Trimethoxybenzaldehyde, 2,3,5-trimethoxybenzaldehyde, 2,3,6-trimethoxybenzaldehyde, 2,4,6-trimethoxybenzaldehyde, 2,4,5-trimethoxybenzaldehyde, 2,5,6-trimethoxybenzaldehyde, 2-hydroxybenzaldehyde, 3-hydroxybenzaldehyde, 4-hydroxybenzaldehyde, 2,3-dihydroxybenzaldehyde, 2,4-dihydroxybenzaldehyde, 2,4-dihydroxy-3-methylbenzaldehyde, 2,4-dihydroxy-5-methylbenzaldehyde, 2,4-dihydroxy-6-methyl- benzaldehyde, 2,4-dihydroxy-3-methoxy-benzaldehyde, 2,4-dihydroxy-5-methoxy-benzaldehyde, 2,4-dihydroxy-6-methoxy-benzo aldehyde, 2,5-dihydroxybenzaldehyde, 2,6-dihydroxybenzaldehyde, 3,4-dihydroxybenzaldehyde, 3,4-dihydroxy-2-methylbenzaldehyde, 3,4-dihydroxy-5-methylbenzaldehyde, 3,4-dihydroxy- 6-methylbenzaldehyde, 3,4-dihydroxy-2-methoxybenzaldehyde, 3,4-dihydroxy-5-ethoxybenzaldehyde, 3,5-dihydroxybenzaldehyde, 2,3,4-trihydroxybenzaldehyde, 2,3,5-trihydroxybenzaldehyde, 2,3,6-trihydroxybenzaldehyde, 2,4,6-trihydroxybenzaldehyde, 2,4,5-trihydroxybenzaldehyde, 2,5,6-trihydroxybenzaldehyde, 4-dimethylaminobenzaldehyde, 4-diethylaminobenzaldehyde, 4-dimethylamino-2-hydroxybenzaldehyde, 4- Pyrrolidinobenzaldehyde, 4-morpholinobenzaldehyde, 2-morpholinobenzaldehyde, 4-piperidinobenzaldehyde, 2,3,6,7-tetrahydro-5H- [1,4] oxazino [2,3,4-ij] quinoline-9-carbaldehyde, 3, 5-dichloro-4-hydroxybenzaldehyde, 4-hydroxy-3,5-diiodobenzaldehyde, 3-chloro-4-hydroxybenzaldehyde, 5-chloro-3,4-dihydroxybenzaldehyde, 5-bromo-3,4-dihydroxybenzaldehyde, 3 Chloro-4-hydroxy-5-methoxybenzaldehyde, 4-hydroxy-3-iodo-5-methoxybenzaldehyde, 2-bromo-4,5-dihydroxybenzaldeh yd, 2-methoxy-1-naphthaldehyde, 4-methoxy-1-naphthaldehyde, 2-hydroxy-1-naphthaldehyde, 2,4-dihydroxy-1-naphthaldehyde, 4-hydroxy-3-methoxy-1-naphthaldehyde, 2- hydroxy-4-methoxy-1- naphthaldehyde, 3-hydroxy-4-methoxy-1-naphthaldehyde, 2,4-dimethoxy-1-naphthaldehyde, 3,4-dimethoxy-1-naphthaldehyde, 4-dimethylamino-1-naphthaldehyde, 3-hydroxy-4-nitrobenzaldehyde, 2-hydroxy-3-methoxy-5-nitrobenzaldehyde, 5-nitrovanillin, 2,5-dinitrosalicylaldehyde, 5-bromo-3-nitrosalicylaldehyde, 2-dimethylaminobenzaldehyde, 2-chloro-4-dimethylaminobenzaldehyde, 4-dimethylamino-2-methylbenzaldehyde, 4-diethylamino-cinnamaldehyde, 4-dibutylaminobenzaldehyde, 3-carboxy-4-hydroxybenzaldehyde, 5-carboxyvanillin, 3-carboxy-4-hydroxy-5-methylbenzaldehyde, 3-carboxy-5-ethoxy-4-hydroxybenzaldehyde, 3-carboxy-4-hydroxybenzaldehyde, 5-carboxyvanillin, 3-carboxy-4-hydroxy-5-methylbenzaldehyde, 3-carboxy-5-ethoxy-4-hydroxybenzaldehyde, 3-allyl-4-hydroxybenzaldehyde, 3-allyl-4 hydroxy-5-methoxybenzaldehyde, 3-allyl-4-hydroxy-5-methylbenzaldehyde, 3-allyl-5-bromo-4-hydroxybenzaldehyde, 3,5-diallyl-4-hydroxybenzaldehyde, 3-allyl-5-carboxy-4 hydroxybenzaldehyde (3-allyl-5-formyl-2-hydroxybenzoic acid) and 3-allyl-4-hydroxy-5-f ormylbenzaldehyde, 4-hydroxy-5-methoxyisophthalaldehyde or (5-allyl-4-hydroxyisophthalaldehyde) is used.

Most preferably, the reactive carbonyl compound is selected from at least one compound of the group 4-hydroxy-3-methoxybenzaldehyde, 4-hydroxy-3-methoxy-5- (2-propenyl) benzaldehyde, 3,5-dimethoxy-4-hydroxybenzaldehyde, 4 -Hydroxy-1-naphthaldehyde, 4-hydroxy-2-methoxybenzaldehyde, 3,4-dihydroxy-5-methoxybenzaldehyde, 3,4-dihydroxy-5-ethoxybenzaldehyde, 3,4,5-trihydroxybenzaldehyde, 4-hydroxy-5-methoxyisophthalaldehyde , 3 - [(dimethylamino) methyl] -4-hydroxy-5-methoxybenzaldehyde, 5-bromo-3,4-dihydroxybenzaldehyde, 5-chloro-3,4-dihydroxybenzaldehyde, 2-bromo-4,5-dihydroxybenzaldehyde, 2,3,6,7-Tetrahydro-5H- [1,4] oxazino [2,3,4-ij] quinoline-9-carbaldehyde, 3,5-dibromo-4-hydroxybenzaldehyde, 4-hydroxy-3- nitrobenzaldehyde, 3-bromo-4-hydroxybenzaldehyde, 4-hydroxy-3-methylbenzaldehyde, 3,5-dimethyl-4-hydroxybenzaldehyde, 5-bromo-4-hydroxy-3-methoxybenzaldehyde, 4-diethylamino-2-hydroxybenzaldehyde and 4-Dimethylamino-2-methoxybenzaldehyde (most preferably from at least one compound of the 2,4-dihydric group hydroxybenzaldehyde, 4-hydroxy-3-methoxybenzaldehyde, 3,5-dimethoxy-4-hydroxybenzaldehyde, 3,4-dihydroxybenzaldehyde, 3,5-dimethyl-4-hydroxybenzaldehyde, 4-hydroxy-1-naphthaldehyde, 3,4-dihydroxy- 5-methoxybenzaldehyde, 3,4,5-trihydroxybenzaldehyde. Most preferably, the reactive carbonyl compound is selected from at least one of 3,4,5-trihydroxybenzaldehyde, 3,4-dihydroxy-5-methoxybenzaldehyde, 4-hydroxy-3-methoxy-5- (2-propenyl) benzaldehyde, 4 Hydroxy-5-methoxyisophthalaldehyde, 3 - [(dimethylamino) methyl] -4-hydroxy-5-methoxybenzaldehyde, 5-bromo-3,4-dihydroxybenzaldehyde, 3,4-dihydroxy-5-ethoxybenzaldehyde, 2,3, 6,7-Tetrahydro-5H- [1,4] oxazino [2,3,4-ij] quinoline-9-carbaldehyde, 5-chloro-3,4-dihydroxybenzaldehyde, 2-bromo-4,5-dihydroxybenzaldehyde.

It is particularly preferred according to the invention to employ as CH-acidic compound at least one compound of the formula (I-1) and as the reactive carbonyl compound at least one compound of the formula (II). It is very particularly preferred to use as CH-acidic compound at least one compound of the formula (I-2) and as the reactive carbonyl compound at least one compound of the formula (II). Again, the preferred reactive carbonyl compounds of the formula (II) mentioned in the abovementioned lists are likewise preferred.

A portion preferred according to the invention is characterized in that the washing or cleaning agent contains the second bluing agent precursor compound in a total amount of from 0.0001 to 50 mmol, in particular from 0.001 to 30 mmol. In this case, it has once again turned out to be preferred if the washing or cleaning agent contains not more than 20 mmol, in particular not more than 10 mmol, of the second bluing agent precursor compound.

It has been found preferable if the washing or cleaning agent contains the first bluing agent precursor compound and the second bluing agent precursor compound in a molar ratio range from 2: 1 to 1: 2, preferably from 1.5: 1 to 1: 1.5, contains.

The color development from the bluing agent precursor compounds preferably proceeds in an alkaline medium. For this reason, it is preferred according to the invention that a solution of 2.0 g of the washing or cleaning agent in 1 liter of water has a pH (20 ° C.) of from pH 7 to pH 10, in particular from pH 7.5 to pH 9 , 5, owns.

The washing or cleaning agent contained in the portion according to the invention preferably contains at least one alkalizing agent. Alkalizing agents are preferably selected from at least one compound of the group formed from alkali hydroxides, alkanolamines, alkali metal metasilicates, urea, morpholine, N-methylglucamine, imidazole, alkali phosphates and alkali hydrogen phosphates. The alkali metal ions used are preferably lithium, sodium, potassium, in particular sodium or potassium.

The alkali metal hydroxides which can be used as the alkalizing agent according to the invention are preferably selected from the group formed from sodium hydroxide and potassium hydroxide.

The alkanolamines which can be used as alkalizing agents according to the invention are preferably selected from primary amines having a C ₂ -C ₆ -alkyl basic body which carries at least one hydroxyl group. Particularly preferred alkanolamines are selected from the group formed from 2-aminoethan-1-ol (monoethanolamine), 3-aminopropan-1-ol, 4-aminobutan-1-ol, 5-aminopentan-1-ol, 1 -Aminopropan-2-ol, 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol, 3-amino-2-methylpropan-1-ol , 1-amino-2-methylpropan-2-ol, 3-aminopropane-1,2-diol, 2-amino-2-methylpropane-1,3-diol. Very particularly preferred alkanolamines according to the invention are selected from the group consisting of 2-aminoethane-1-ol, 2-amino-2-methylpropan-1-ol and 2-amino-2-methylpropane-1,3-diol.

Particularly preferably, the alkalizing agent is selected from at least one compound from the group formed from ammonia, 2-aminoethanol, 2-amino-2-methylpropan-1-ol, 2-amino-2-methyl-propane-1,3- diol, potassium hydroxide and sodium hydroxide.

The washing or cleaning agent of the portion according to the invention comprises in at least two chambers separately prepared compositions. Said compositions may be solid or liquid. It is preferred according to the invention if the composition comprising at least one first bluing agent precursor compound and the compound containing at least one second bluing agent precursor compound are liquid.

The washing or cleaning agent of the portion according to the invention contains from 20 to 70% by weight of surfactant. The group of surfactants includes nonionic, anionic, cationic and amphoteric surfactants. According to the invention, the washing or cleaning agent may comprise one or more of the surfactants mentioned. It particularly preferably comprises at least one or more anionic surfactants (anionic surfactants) which preferably contain in a total amount of from 20 to 50% by weight, in particular from 25 to 35% by weight, based in each case on the total weight of the washing or cleaning agent are.

The at least one anionic surfactant is preferably selected from the group consisting of C _9-13 alkyl benzene sulfonates, olefin sulfonates, C _12-18 alkane sulfonates, ester sulfonates, alk (en) yl sulfates, Fettalkohohlethersulfaten and mixtures thereof. It has been found that these sulfonate and sulfate surfactants are particularly suitable for the preparation of stable liquid compositions with yield point. Liquid compositions, the anionic surfactant C ₉ - ₁₃ include alkyl benzene sulfonates and fatty alcohol ether sulfates, have particularly good dispersing properties. As surfactants of the sulfonate type are preferably C ₉ - ₁₃ alkylbenzenesulfonates, Olefinsulfonate, that is mixtures of alkene and hydroxyalkanesulfonates and disulfonates, such as those from C ₁₂ - ₁₈ monoolefins with terminal or internal double bond by sulfonation with gaseous Sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation obtained. Also suitable are C _12-18 alkane sulfonates and the esters of α-sulfofatty acids (ester sulfonates), for example, the α-sulfonated Methylester of hydrogenated coconut, palm kernel or tallow fatty acids.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-alkyl sulfates are also suitable anionic surfactants.

Also fatty alcohol ether sulfates, such as the Schwefelsäuremonoester with 1 to 6 moles of ethylene ethoxylated straight-chain or branched C _7-21 alcohols, such as 2-methyl-branched C _9-11 alcohols containing on average 3.5 mol ethylene oxide (EO) or C ₁₂ - ₁₈ fatty alcohols with 1 to 4 EO, are suitable.

It is preferred that the washing or cleaning agent contains a mixture of sulfonate and sulfate surfactants. ₁₃ alkyl benzene sulfonates and fatty alcohol ether sulfates as the anionic surfactant - in a particularly preferred embodiment, the composition contains C _9.

In addition to the anionic surfactant, the composition may also contain soaps. Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.

The anionic surfactants and the soaps may be in the form of their sodium, potassium or magnesium or ammonium salts. Preferably, the anionic surfactants are in the form of their sodium salts. Further preferred counterions for the anionic surfactants are also the protonated forms of choline, triethylamine, monoethanolamine or methylethylamine.

The composition may also comprise at least one nonionic surfactant in addition to the anionic surfactant. The nonionic surfactant includes alkoxylated fatty alcohols, alkoxylated fatty acid alkyl esters, fatty acid amides, alkoxylated fatty acid amides, polyhydroxy fatty acid amides, alkylphenol polyglycol ethers, amine oxides, alkyl polyglucosides, and mixtures thereof.

The nonionic surfactant used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 4 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical may be linear or preferably methyl-branched in the 2-position or may contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates having linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example coconut, palm, tallow or oleyl alcohol, and on average 5 to 8 EO per mole of alcohol are preferred. Preferred ethoxylated alcohols include, for example, C _12-14 alcohols with 7 EO or 4 EO, _C9-11 alcohol containing 7 EO, C _13-15 alcohols with 5 EO, 7 EO or 8 EO, C _12-18 Alcohols with 5 EO or 7 EO and mixtures of these. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO. Nonionic surfactants which contain EO and PO (propylene oxide) groups together in the molecule can also be used according to the invention. Also suitable are also a mixture of a (more) branched ethoxylated fatty alcohol and an unbranched ethoxylated fatty alcohol, such as a mixture of a C16-18 fatty alcohol with 7 EO and 2-propylheptanol with 7 EO. Most preferably, the washing, cleaning, post-treatment or detergent builder contains a C _12-18 fatty alcohol with 7 EO, or C _13-15 oxo alcohol with 7 EO as non-ionic surfactant.

The washing or cleaning agent may further comprise one or more solvents. These may be water and / or non-aqueous solvents. Preferably, the composition contains water as the main solvent. The composition may further comprise non-aqueous solvents. Suitable non-aqueous solvents include monohydric or polyhydric alcohols, alkanolamines or glycol ethers. Preferably, the solvents are selected from ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycol, propyldiglycol, butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, Diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether, di-n-octyl ether and mixtures thereof Solvent.

The composition may further comprise builders according to the invention. As builders, for example, polymeric polycarboxylates are suitable. These are, for example, the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example, those having a molecular weight of 600 to 750,000 g / mol.

Suitable polymers are in particular polyacrylates, which preferably have a molecular weight of from 1,000 to 15,000 g / mol. Because of their superior solubility, the short-chain polyacrylates, which have molecular weights of from 1,000 to 10,000 g / mol, and particularly preferably from 1,000 to 5,000 g / mol, may again be preferred from this group.

Also suitable are copolymeric polycarboxylates, in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. To improve the water solubility, the polymers may also contain allylsulfonic acids, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer.

In a preferred embodiment, the washing or cleaning agent according to the invention further comprises at least one enzyme. In principle, all enzymes known from the state of the art for textile treatment are suitable as enzyme for use as an additive. Preferably, it is one or a plurality of enzymes capable of exhibiting a catalytic activity as an additive of a detergent, in particular a protease, amylase, lipase, cellulase, hemicellulase, mannanase, pectin-splitting enzyme, tannase, xylanase, xanthanase, β-glucosidase, carrageenase, perhydrolase, oxidase, oxidoreductase as well as their mixtures. Preferred hydrolytic enzymes include in particular proteases, amylases, in particular α-amylases, cellulases, lipases, hemicellulases, in particular pectinases, mannanases, β-glucanases, and mixtures thereof. Proteases, amylases and / or lipases and mixtures thereof are particularly preferred, and proteases are particularly preferred. These enzymes are basically of natural origin; Starting from the natural molecules, improved variants are available for use in detergents or cleaning agents, which are preferably used accordingly.

Among the proteases, those of the subtilisin type are preferable. Examples of these are the subtilisins BPN 'and Carlsberg, the protease PB92, the subtilisins 147 and 309, the alkaline protease from Bacillus lentus, subtilisin DY and the enzymes thermitase, proteinase K and the subtilases, but not the subtilisins in the narrower sense Proteases TW3 and TW7 Subtilisin Carlsberg is available in a further developed form under the trade name Alcalase® from Novozymes A / S, Bagsvaerd, Denmark. The subtilisins 147 and 309 are sold under the trade names Esperase®, and Savinase® by the company Novozymes. From the protease from Bacillus lentus DSM 5483 derived under the name BLAP® protease variants derived. Further useful proteases are, for example, those under the trade names Durazym®, Relase®, Everlase®, Nafizym®, Natalase®, Kannase® and Ovozyme® from Novozymes, which are available under the trade names, Purafect®, Purafect® OxP, Purafect® Prime, Excellase® and Properase® from Genencor, sold under the trade name Protosol® by Advanced Biochemicals Ltd., Thane, India, under the trade name Wuxi® by Wuxi Snyder Bioproducts Ltd., China, under the trade names Proleather ® and Protease P® from Amano Pharmaceuticals Ltd., Nagoya, Japan, and the enzyme available under the name Proteinase K-16 from Kao Corp., Tokyo, Japan. Particular preference is also given to using the proteases from Bacillus gibsonii and Bacillus pumilus.

Examples of amylases which can be used according to the invention are the α-amylases from Bacillus licheniformis, B. amyloliquefaciens or B. stearothermophilus and their further developments improved for use in detergents or cleaners. The B. licheniformis enzyme is available from Novozymes under the name Termamyl® and from Genencor under the name Purastar®ST. Further development products of this α-amylase are available from Novozymes under the trade name Duramyl® and Termamyl®ultra, from Genencor under the name Purastar®OxAm and from Daiwa Seiko Inc., Tokyo, Japan, as Keistase®. B. amyloliquefaciens α-amylase is sold by Novozymes under the name BAN®, and variants derived from B. stearothermophilus α-amylase under the names BSG® and Novamyl®, also from Novozymes. Furthermore, for this purpose, the α-amylase from Bacillus sp. A 7-7 (DSM 12368) and the cyclodextrin glucanotransferase (CGTase) from B. agaradherens (DSM 9948). Likewise, fusion products of all the molecules mentioned can be used. In addition, the further developments of the α-amylase from Aspergillus niger and A. oryzae available under the trade name Fungamyl® from the company Novozymes are suitable. Further advantageously usable commercial products are, for example, the Amylase-LT®, as well as Stainzyme® or Stainzyme ultra® or Stainzyme plus®, the latter also from the company Novozymes. Also variants of these enzymes obtainable by point mutations can be used according to the invention.

Examples of lipases or cutinases which can be used according to the invention, which are contained in particular because of their triglyceride-cleaving activities, but also in order to generate in situ peracids from suitable precursors, are the lipases which are originally obtainable from Humicola lanuginosa (Thermomyces lanuginosus) or further developed, in particular those with the amino acid exchange D96L. They are sold for example by the company Novozymes under the trade names Lipolase®, Lipolase®Ultra, LipoPrime®, Lipozyme® and Lipex®. Furthermore, for example, the cutinases can be used, which were originally isolated from Fusarium solani pisi and Humicola insolens. Lipases which are likewise useful are sold by Amano under the names Lipase CE®, Lipase P®, Lipase B® or Lipase CES®, Lipase AKG®, Bacillus sp. Lipase®, Lipase AP®, Lipase M-AP® and Lipase AML®. By Genencor, for example, the lipases or cutinases can be used, the initial enzymes were originally isolated from Pseudomonas mendocina and Fusarium solanii. Other important commercial products are the preparations M1 Lipase.RTM. And Lipomax.RTM. Originally sold by Gist-Brocades and the enzymes marketed by Meito Sangyo KK, Japan, under the name Lipase MY-30®, Lipase OF® and Lipase PL® to mention also the product Lumafast® from the company Genencor.

Depending on the purpose, cellulases may be present as pure enzymes, as enzyme preparations or in the form of mixtures in which the individual components advantageously complement each other in terms of their various performance aspects. These performance aspects include in particular the contributions of the cellulase to the primary washing performance of the composition (cleaning performance), to the secondary washing performance of the composition (anti-redeposition effect or graying inhibition), to softening (fabric effect) or to the exercise of a "stone washed" effect. A useful fungal endoglucanase (EG) -rich cellulase preparation or its further developments is offered by Novozymes under the trade name Celluzyme®. The products Endolase® and Carezyme®, which are also available from Novozymes, are based on the 50 kD EG or the 43 kD EG from H. insolens DSM 1800. Further commercial products of this company are Cellusoft®, Renozyme® and Celluclean®. Also usable are, for example, the 20 kD-EG from Melanocarpus available from AB Enzymes, Finland, under the trade names Ecostone® and Biotouch®. Further commercial products of AB Enzymes are Econase® and Ecopulp®. Other suitable cellulases are from Bacillus sp. CBS 670.93 and CBS 669.93, those derived from Bacillus sp. CBS 670.93 from the company Genencor under the trade name Puradax® is available. Further commercial products of Genencor are "Genencor detergent cellulase L" and lndiAge®Neutra. Also variants of these enzymes obtainable by point mutations can be used according to the invention. Particularly preferred cellulases are Thielavia terrestris cellulase variants, cellulases from melanocarpus, in particular melanocarpus albomyces, cellulases of the EGIII type from Trichoderma reesei or variants obtainable therefrom.

Furthermore, in particular for the removal of certain problem soiling, further enzymes can be used, which are summarized by the term hemicellulases. These include, for example, mannanases, xanthan lyases, xanthanases, xyloglucanases, xylanases, pullulanases, pectin-splitting enzymes and β-glucanases. The β-glucanase obtained from Bacillus subtilis is available under the name Cereflo® from Novozymes. Hemicellulases which are particularly preferred according to the invention are mannanases which are sold, for example, under the trade names Mannaway® by the company Novozymes or Purabrite® by the company Genencor. The pectin-destroying enzymes in the context of the present invention are also counted enzymes with the designations pectinase, pectate lyase, pectin esterase, pectin methoxylase, pectin methoxylase, pectin methyl esterase, pectase, pectin methyl esterase, pectin esterase, pectin-pectin hydrolase, pectin-polymerase, endopolygalacturonase, pectolase, pectin hydrolase, pectin-polygalacturonase, Endo-polygalacturonase, poly-α-1,4-galacturonide glycanohydrolase, endogalacturonase, endo-D-galacturonase, galacturan 1,4-α-galacturonidase, exopolygalacturonase, poly (galacturonate) hydrolase, exo-D-galacturonase, exo-D Galacturonanase, exopoly-D-galacturonase, exo-poly-α-galacturonosidase, exopolygalacturonosidase or exopolygalacturanosidase. Examples of enzymes suitable for this purpose are, for example, under the name Gamanase®, Pektinex AR®, X-Pect® or Pectaway® from Novozymes, under the name Rohapect UF®, Rohapect TPL®, Rohapect PTE100®, Rohapect MPE®, Rohapect MA plus HC, Rohapect DA12L®, Rohapect 10L®, Rohapect B1L® from AB Enzymes and available under the name Pyrolase® from Diversa Corp., San Diego, CA, USA.

Of all these enzymes, particular preference is given to those which have been stabilized per se with respect to oxidation in a comparatively stable manner or, for example, via point mutagenesis. These include, in particular, the already mentioned commercial products Everlase® and Purafect®OxP as examples of such proteases and Duramyl® as an example of such an α-amylase.

According to the invention it is also possible that several different enzymes are included. In a particularly preferred embodiment, the at least one enzyme is in a total amount of 0.001 to 4 wt .-%, more preferably from 0.01 to 3 wt .-%, even more preferably from 0.05 to 1.25 wt .-% and more preferably from 0.2 to 1.0% by weight.

In a particularly preferred embodiment, the at least one enzyme is present as granules. In particular, enzyme granules are contained in a total amount of 4 to 15 wt .-%, preferably from 7 to 12 wt .-%, each based on 100 wt .-% of the total n washing or cleaning agent.

It is preferred that the washing or cleaning agent additionally contains at least one optical brightener, more preferably from the substance classes of the distyrylbiphenyls, the stilbenes, the 4,4'-diamino-2,2'-stilbenedisulfonic acids, the coumarins, the dihydroquinolinones, the 1,3-diarylpyrazolines, the naphthalimides, the benzoxazole systems, the benzisoxazole systems, the benzimidazole systems, the heterocyclic substituted pyrene derivatives, and mixtures thereof. These substance classes at optical Brighteners have high stability, high light and oxygen resistance, and high affinity for fibers.

Particularly good and stable, the following optical brightener, which consists of the group consisting of disodium 4,4'-bis (2-morpholino-4-anilino-s-triazin-6-ylamino) stilbene disulfonate, disodium 2,2 '- bis (phenyl-styryl) disulfonate, 4,4'-bis [(4-anilino-6- [bis (2-hydroxyethyl) amino] -1,3,5-triazin-2-yl) amino] stilbene 2,2'-disulfonic acid, hexasodium 2,2 '- [vinylenebis [(3-sulphonato-4,1-phenylene) imino [6- (diethylamino) -1,3,5-triazine-4,2-diyl ] imino]] bis (benzene-1,4-disulfonate), 2,2 '- (2,5-thiophenediyl) to [5-1,1-dim are incorporated.

The washing or cleaning agent may additionally contain one or more other components described in the prior art, such as complexing agents, bleaching agents, bleach activators, antioxidants, enzyme stabilizers, antimicrobial agents, graying inhibitors, anti-redeposition agents, pH adjusters, electrolytes, detergency boosters, vitamins, Proteins, foam inhibitors and / or UV absorbers have.

According to the invention, the portioned washing or cleaning agent is in a container (pouch) of water-soluble material. This container comprises at least two spatially separate chambers (Mehrkammerpouch). These chambers are separated from one another such that the compositions of the washing or cleaning agent contained do not come into contact with each other. This separation can for example be done by a wall, which consists of the same material as the container itself.

The water-soluble material may comprise a polymer, a copolymer or mixtures thereof. Water-soluble polymers in the context of the invention are those polymers which are soluble in water at room temperature in excess of 2.5% by weight.

Preferred water-soluble materials preferably comprise at least partially at least one of (acetalated) polyvinyl alcohol, polyvinylpyrrolidone, polyethylene oxide, gelatin, sulphate, carbonate and / or citrate substituted polyvinyl alcohols, polyalkylene oxides, acrylamides, cellulose esters, cellulose ethers, cellulose amides, cellulose, polyvinyl acetates , Polycarboxylic acids and their salts, polyamino acids or peptides, polyamides, polyacrylamides, copolymers of maleic acid and acrylic acid, copolymers of acrylamides and (meth) acrylic acid, polysaccharides such as starch or guar derivatives, gelatin and under the INCI name Polyquaternium 2, Polyquaternium 17 , Polyquaternium 18 and Polyquaternium 27. Most preferably, the water-soluble material comprises polyvinyl alcohol.

In one embodiment of the invention, the water-soluble material comprises mixtures of different substances, for example copolymers. Such mixtures allow adjustment of the mechanical properties of the container and can influence the degree of water solubility.

die in geringen Anteilen (ca. 2%) auch Struktureinheiten des Typs

enthalten.The water-soluble material preferably contains at least one polyvinyl alcohol and / or at least one polyvinyl alcohol copolymer. "Polyvinyl alcohol" (abbreviation PVAL or PVA occasionally also PVOH) is the name for polymers of the general structure

in small proportions (about 2%) also structural units of the type

contain.

Commercially available polyvinyl alcohols, which are offered as white-yellowish powders or granules with degrees of polymerization in the range of about 100 to 2500 (molar masses of about 4000 to 100,000 g / mol), have degrees of hydrolysis of 98 to 99 mol% and 87 to 89 mol%, so still contain a residual content of acetyl groups. The polyvinyl alcohols are characterized by the manufacturers by indicating the degree of polymerization of the starting polymer, the degree of hydrolysis, the saponification number or the solution viscosity.

Depending on the degree of hydrolysis, polyvinyl alcohols are soluble in water and a few highly polar organic solvents (formamide, dimethylformamide, dimethyl sulfoxide); They are not attacked by (chlorinated) hydrocarbons, esters, fats and oils. Polyvinyl alcohols are classified as toxicologically safe and are biologically at least partially degradable. The water solubility can be reduced by aftertreatment with aldehydes (acetalization), by complexation with Ni or Cu salts or by treatment with dichromates, boric acid or borax. The coatings of polyvinyl alcohol are largely impermeable to gases such as oxygen, nitrogen, helium, hydrogen, carbon dioxide, but allow water vapor to pass through.

In the present invention, it is preferable that the water-soluble material at least partially comprises a polyvinyl alcohol whose degree of hydrolysis is 70 to 100 mol%, preferably 80 to 90 mol%, more preferably 81 to 89 mol%, and especially 82 to 88 mol -% is. In a preferred embodiment, the water-soluble material is at least 20 wt .-%, more preferably at least 40 wt .-%, most preferably at least 60 wt .-% and in particular at least 80 wt .-% of a polyvinyl alcohol, the Hydrolysis degree 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.

The polyvinyl alcohols described above are widely available commercially, for example under the trademark Mowiol® (Clariant). Polyvinyl alcohols which are particularly suitable for the purposes of the present invention are, for example, Mowiole 3-83, Mowiol® 4-88, Mowiol® 5-88, Mowiol® 8-88 and L648, L734, Mowiflex LPTC 221 ex KSE and the compounds from Texas Polymers such as for example, Vinex 2034.

Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers. Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and mixtures thereof, with itaconic acid being preferred.

Likewise preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters. Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.

The water solubility of polyvinyl alcohol polymer can be altered by post-treatment with aldehydes (acetalization) or ketones (ketalization). As particularly preferred and particularly advantageous due to their pronounced cold water solubility, polyvinyl alcohols have proven to be acetalized or ketalized with the aldehyde or keto groups of saccharides or polysaccharides or mixtures thereof.

Furthermore, the water solubility can be changed by complexing with Ni or Cu salts or by treatment with dichromates, boric acid, borax and thus set specifically to desired values. Films made of PVAL are largely impermeable to gases such as oxygen, nitrogen, helium, hydrogen, carbon dioxide, but allow water vapor to pass through.

In addition to polyvinyl alcohol or polyvinyl alcohol copolymer, the film material suitable as water-soluble material may additionally comprise polymers selected from the group comprising acrylic acid-containing polymers, polyacrylamides, oxazoline polymers, polystyrenesulfonates, polyurethanes, polyesters, polyether polylactic acid, and / or mixtures of the above Polymers or copolymers thereof may be added.

Suitable water-soluble films for use as the water-soluble material of the water-soluble potion according to the invention are films sold under the name Monosol M8630 by MonoSol LLC. Other suitable films include films named Solublon® PT, Solublon® KA, Solublon® KC or Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray.

Another object of the invention relates to the use of the portion according to the invention for cleaning, in particular washing, of textiles. For the purposes of the present invention, textiles are, in particular, textile fabrics, such as, for example, items of clothing, bath or bath Linen textiles. These may include natural and / or synthetic fibers such as silk, linen, cotton, polyester, polyamide or acetate fibers. The fibers can be treated or untreated. Furthermore, such textile fabrics are comprised, which consist of woven or non-woven materials such as felts or nonwovens.

Another object of the invention relates to a process for textile cleaning, wherein at least one portion of the first subject of the invention is placed in the drum of a washing machine together with the laundry, by adding 5 to 40 liters of water per portion inserted a wash liquor is provided, the resulting wash liquor and the laundry is in contact for a period of 20 to 120 minutes, preferably 30 to 90 minutes, the wash liquor is removed and the laundry is rinsed.

The laundry is textiles as defined above (vide supra).

According to the invention, the aqueous liquor in the washing machine containing the washing or cleaning agent and the water added for dilution is considered to be the wash liquor.

It is preferable that, based on the volume of added water, the concentration of the first bluencer precursor compound in the wash liquor is 0.00005 to 3.0 mmol / L, especially 0.0005 to 1.8 mmol / L.

Further, it is preferable that, based on the volume of the added water, the concentration of the second bluencer precursor compound in the wash liquor is 0.0005 to 3.0 mmol / L, especially 0.0005 to 1.8 mmol / L.

In this case, it is again preferred if the wash liquor contains the first bluencer precursor compound and the second bluencer precursor compound in a molar ratio range from 2: 1 to 1: 2, preferably from 1.5: 1 to 1: 1.5.

The wash liquor preferably has a pH of from 7 to 10, in particular from 7.5 to 9.5.

1. 1. Portion, umfassend
   • (i) einen Behälter aus wasserlöslichem Material mit mindestens zwei voneinander getrennten Kammern und
   • (ii) ein in besagtem Behälter konfektioniertes Wasch- oder Reinigungsmittel, enthaltend auf dessen Gesamtgewicht bezogen eine Gesamtmenge von 20 bis 70 Gew.-% Tensid, wobei besagtes Wasch- oder Reinigungsmittel mindestens zwei, in besagten Kammern getrennt voneinander konfektionierte Zusammensetzungen umfasst, dadurch gekennzeichnet, dass in besagtem Behälter
   • (a) in mindestens einer Kammer eine Zusammensetzung, enthaltend mindestens eine erste Bläuungsmittel-Vorläuferverbindung, und
   • (b) in mindestens einer hiervon verschiedenen weiteren Kammer, eine Zusammensetzung, enthaltend mindestens eine reaktive Carbonylverbindung, insbesondere mindestens einen Aldehyd, als zweite Bläuungsmittel-Vorläuferverbindung enthalten ist, mit der Maßgabe, dass besagte erste und zweite Bläuungsmittel-Vorläuferverbindungen in besagtem Behälter getrennt voneinander konfektioniert sind.
2. 2. Portion nach Punkt 1, dadurch gekennzeichnet, dass als erste Bläuungsmittel-Vorläuferverbindung mindestens eine CH-acide Verbindung enthalten ist.
3. 3. Portion nach Punkt 1 oder 2, dadurch gekennzeichnet, dass als erste Bläuungsmittel-Vorläuferverbindung mindestens eine Verbindung der Formel (I) enthalten ist
   
   worin
   • • R⁶ steht für eine lineare oder cyclische (C₁ bis C₆)-Alkylgruppe, eine (C₂ bis C₆)-Alkenylgruppe, eine gegebenenfalls substituierte Arylgruppe, eine gegebenenfalls substituierte Heteroarylgruppe, eine Aryl-(C₁ bis C₆)-alkylgruppe, eine (C₁ bis C₆)-Hydroxyalkylgruppe, eine (C₂ bis C₆)-Polyhydroxyalkylgruppe, eine (C₁ bis C₆)-Alkoxy-(C₁ bis C₆)-alkylgruppe, eine Gruppe R^IR^IIN-(CH₂)_m-, worin R^I und R^II stehen unabhängig voneinander für ein Wasserstoffatom, eine (C₁ bis C₄)-Alkylgruppe, eine (C₁ bis C₄)-Hydroxyalkylgruppe oder eine Aryl-(C₁ bis C₆)-alkylgruppe, wobei R^I und R^II gemeinsam mit dem Stickstoffatom einen 5-, 6- oder 7-gliedrigen Ring bilden können und m steht für eine Zahl 2, 3, 4, 5 oder 6,
   • • R⁷ steht für eine (C₁ bis C₆)-Alkylgruppe, insbesondere für eine Methylgruppe,
   • • der Zyklus der Formel (I) repräsentiert alle Ringstrukturen, die zusätzlich weitere Heteroatome wie Stickstoff, Sauerstoff oder Schwefel enthalten können und ferner ankondensierte Ringstrukturen tragen können, wobei alle diese Ringsstrukturen zusätzliche Substituenten tragen können,
   • • X^- steht für ein physiologisch verträgliches Anion.
4. 4. Portion nach einem der Punkte 1 bis 3, dadurch gekennzeichnet, dass als erste Bläuungsmittel-Vorläuferverbindung mindestens eine Verbindung der Formel (I-1) enthalten ist
   
   worin
   • • R⁸ und R⁹ stehen unabhängig voneinander für eine lineare oder cyclische C₁-C₆-Alkylgruppe, eine C₂-C₆-Alkenylgruppe, eine gegebenenfalls substituierte Arylgruppe, eine gegebenenfalls substituierte Heteroarylgruppe, eine Aryl-C₁-C₆-alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe, eine C₂-C₆-Polyhydroxyalkylgruppe, eine C₁-C₆-Alkoxy-C₁-C₆-alkylgruppe, eine Gruppe R^IR^IIN-(CH₂)_m-, worin R^I und R^II stehen unabhängig voneinander für ein Wasserstoffatom, eine C₁-C₄-Alkylgruppe, eine C₁-C₄-Hydroxyalkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe, wobei R^I und R^II gemeinsam mit dem Stickstoffatom einen 5-, 6- oder 7-gliedrigen Ring bilden können und m steht für eine Zahl 2, 3, 4, 5 oder 6,
   • • R¹⁰ und R¹² stehen unabhängig voneinander für ein Wasserstoffatom oder eine C₁-C₆-Alkylgruppe, wobei mindestens einer der Reste R¹⁰ und R¹² eine C₁-C₆-Alkylgruppe bedeutet,
   • • R¹¹ steht für ein Wasserstoffatom, eine C₁-C₆-Alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe, eine C₂-C₆-Polyhydroxyalkylgruppe, eine C₁-C₆-Alkoxygruppe, eine C₁-C₆-Hydroxyalkoxygruppe, eine Gruppe R^IIIR^IVN-(CH₂)_q-, worin R^III und R^IV stehen unabhängig voneinander für ein Wasserstoffatom, eine C₁-C₆-Alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe und q steht für eine Zahl 1, 2, 3, 4, 5 oder 6, wobei der Rest R¹¹ zusammen mit einem der Reste R¹⁰ oder R¹² einen 5- oder 6-gliedrigen aromatischen Ring bilden kann, der gegebenenfalls mit einem Halogenatom, einer C₁-C₆-Alkylgruppe, einer C₁-C₆-Hydroxyalkylgruppe, einer C₂-C₆-Polyhydroxyalkylgruppe, einer C₁-C₆-Alkoxygruppe, einer C₁-C₆-Hydroxyalkoxygruppe, einer Nitrogruppe, einer Hydroxygruppe, einer Gruppe R^VR^VIN-(CH₂)_s-, worin R^V und R^VI stehen unabhängig voneinander für ein Wasserstoffatom, eine C₁-C₆-Alkylgruppe, eine C₁-C₆-Hydroxyalkylgruppe oder eine Aryl-C₁-C₆-alkylgruppe und s steht für eine Zahl 0, 1, 2, 3, 4, 5 oder 6 substituiert sein kann,
   • • Y steht für ein Sauerstoffatom, ein Schwefelatom oder eine Gruppe NR^VII, worin R^VII steht für ein Wasserstoffatom, eine Arylgruppe, eine Heteroarylgruppe, eine C₁-C₆-Alkylgruppe oder eine C₁-C₆-Arylalkylgruppe,
   • • X- steht für ein physiologisch verträgliches Anion,
   • • Het steht für einen gegebenenfalls substituierten Heteroaromaten,
   • • X¹ steht für eine direkte Bindung oder eine Carbonylgruppe.
5. 5. Portion nach einem der Punkte 1 bis 4, dadurch gekennzeichnet, dass als erste Bläuungsmittel-Vorläuferverbindung mindestens eine Verbindung aus einer Gruppe von Salzen mit physiologisch verträglichem Gegenion X^- enthält, die gebildet wird aus Salzen des 1,2-Dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-diethyl-4,6-dimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-dipropyl-4,6-dimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-di(2-hydroxyethyl)-4,6-dimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-diphenyl-4,6-dimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3,4-trimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-diethyl-4-methyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-dipropyl-4-methyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-di(2-hydroxyethyl)-4-methyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3-diphenyl-4-methyl-2-oxo-pyrimidiniums, 1-Allyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1-(2-hydroxyethyl)-3,4,6-trimethyl-2-oxo-pyrimidiniums, 1,2-Dihydro-1,3,4,6-tetramethyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-diethyl-4,6-dimethyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-dipropyl-4,6-dimethyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-di(2-hydroxyethyl)-4,6-dimethyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-diphenyl-4,6-dimethyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3,4-trimethyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-diethyl-4-methyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-dipropyl-4-methyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-di(2-hydroxyethyl)-4-methyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-1,3-diphenyl-4-methyl-2-thioxo-pyrimidiniums, 1,2-Dihydro-3,4-dimethyl-2-oxo-chinazoliniums und 1,2-Dihydro-1-(3-hydroxypropyl)-3,4,6-trimethyl-2-oxopyrimidiniums, 1-Benzyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidiniums und 1,2-Dihydro-3,4-dimethyl-2-thioxo-chinazoliniums.
6. 6. Portion nach einem der Punkte 1 bis 5, dadurch gekennzeichnet, dass als zweite Bläuungsmittel-Vorläuferverbindung mindestens eine Verbindung der Formel (II) enthalten ist,
   
   worin
   • • R¹, R² und R³ stehen unabhängig voneinander für ein Wasserstoffatom, ein Halogenatom, eine C₁-C₆-Alkylgruppe, eine Hydroxygruppe, eine C₁-C₆-Alkoxygruppe, eine C₁-C₆-Dialkylaminogruppe, eine Di(C₂-C₆-hydroxyalkyl)aminogruppe, eine Di(C₁-C₆-alkoxy-C₁-C₆-alkyl)aminoguppe, eine C₁-C₆-Hydroxyalkyloxygruppe, eine Sulfonylgruppe, eine Carboxygruppe, eine Sulfonsäuregruppe, eine Sulfonamidogruppe, eine Sulfonamidgruppe, eine Carbamoylgruppe, eine C₂-C₆-Acylgruppe oder eine Nitrogruppe,
   • • Z' steht für eine direkte Bindung oder eine Vinylengruppe,
   • • R⁴ und R⁵ stehen für ein Wasserstoffatom oder bilden gemeinsam, zusammen mit dem Restmolekül einen 5- oder 6-gliederigen aromatischen oder aliphatischen Ring.
7. 7. Portion nach einem der Punkte 1 bis 6, dadurch gekennzeichnet, dass als zweite Bläuungsmittel-Vorläuferverbindung mindestens eine Verbindung enthalten ist, ausgewählt aus 4-Hydroxy-3-methoxybenzaldehyd, 3,5-Dimethoxy-4-hydroxybenzaldehyd, 4-Hydroxy-1-naphthaldehyd, 4-Hydroxy-2-methoxybenzaldehyd, 3,4-Dihydroxy-5-methoxybenzaldehyd, 3,4,5-Trihydroxybenzaldehyd, 3,5-Dibrom-4-hydroxybenzaldehyd, 4-Hydroxy-3-nitrobenzaldehyd, 3-Brom-4-hydroxybenzaldehyd, 4-Hydroxy-3-methylbenzaldehyd, 3,5-Dimethyl-4-hydroxybenzaldehyd, 5-Brom-4-hydroxy-3-methoxybenzaldehyd, 4-Diethylamino-2-hydroxybenzaldehyd, 4-Dimethylamino-2-methoxybenzaldehyd, 3-[(Dimethylamino)methyl)-4-hydroxy-5-methoxy-benzaldehyd, 2-Methoxybenzaldehyd, 3-Methoxybenzaldehyd, 4-Methoxybenzaldehyd, 2-Ethoxybenzaldehyd, 3-Ethoxybenzaldehyd, 4-Ethoxybenzaldehyd, 4-Hydroxy-2,3-dimethoxy-benzaldehyd, 4-Hydroxy-2,5-dimethoxy-benzaldehyd, 4-Hydroxy-2,6-dimethoxy-benzaldehyd, 4-Hydroxy-2-methyl-benzaldehyd, 4-Hydroxy-2,3-dimethyl-benzaldehyd, 4-Hydroxy-2,5-dimethyl-benzaldehyd, 4-Hydroxy-2,6-dimethyl-benzaldehyd, 3,5-Diethoxy-4-hydroxy-benzaldehyd, 2,6-Diethoxy-4-hydroxy-benzaldehyd, 3-Hydroxy-4-methoxybenzaldehyd, 2-Hydroxy-4-methoxy-benzaldehyd, 2-Ethoxy-4-hydroxy-benzaldehyd, 3-Ethoxy-4-hydroxy-benzaldehyd, 4-Ethoxy-2-hydroxy-benzaldehyd, 4-Ethoxy-3-hydroxy-benzaldehyd, 2,3-Dimethoxybenzaldehyd, 2,4-Dimethoxybenzaldehyd, 2,5-Dimethoxybenzaldehyd, 2,6-Dimethoxybenzaldehyd, 3,4-Dimethoxybenzaldehyd, 3,5-Dimethoxybenzaldehyd, 2,3,4-Trimethoxybenzaldehyd, 2,3,5-Trimethoxybenzaldehyd, 2,3,6-Trimethoxybenzaldehyd, 2,4,6-Trimethoxybenzaldehyd, 2,4,5-Trimethoxybenzaldehyd, 2,5,6-Trimethoxybenzaldehyd, 2-Hydroxybenzaldehyd, 3-Hydroxybenzaldehyd, 4-Hydroxybenzaldehyd, 2,3-Dihydroxybenzaldehyd, 2,4-Dihydroxybenzaldehyd, 2,4-Dihydroxy-3-methyl-benzaldehyd, 2,4-Dihydroxy-5-methyl-benzaldehyd, 2,4-Dihydroxy-6-methyl-benzaldehyd, 2,4-Dihydroxy-3-methoxy-benzaldehyd, 2,4-Dihydroxy-5-methoxy-benzaldehyd, 2,4-Dihydroxy-6-methoxybenzaldehyd, 2,5-Dihydroxybenzaldehyd, 2,6-Dihydroxybenzaldehyd, 3,4-Dihydroxybenzaldehyd, 3,4-Dihydroxy-2-methyl-benzaldehyd, 3,4-Dihydroxy-5-methylbenzaldehyd, 3,4-Dihydroxy-6-methyl-benzaldehyd, 3,4-Dihydroxy-2-methoxy-benzaldehyd, 3,4-Dihydroxy-5-ethoxybenzaldehyd, 3,5-Dihydroxybenzaldehyd, 2,3,4-Trihydroxybenzaldehyd, 2,3,5-Trihydroxybenzaldehyd, 2,3,6-Trihydroxybenzaldehyd, 2,4,6-Trihydroxybenzaldehyd, 2,4,5-Trihydroxybenzaldehyd, 2,5,6-Trihydroxybenzaldehyd, 4-Dimethylaminobenzaldehyd, 4-Diethylaminobenzaldehyd, 4-Dimethylamino-2-hydroxybenzaldehyd, 4-Pyrrolidinobenzaldehyd, 4-Morpholinobenzaldehyd, 2-Morpholinobenzaldehyd, 4-Piperidinobenzaldehyd, 2,3,6,7-Tetrahydro-5H-[1,4]oxazino-[2,3,4-ij]chinolin-9-carbaldehyd, 3,5-Dichlor-4-hydroxybenzaldehyd, 4-Hydroxy-3,5-diiod-benzaldehyd, 3-Chlor-4-hydroxybenzaldehyd, 5-Chlor-3,4-dihydroxybenzaldehyd, 5-Brom-3,4-dihydroxybenzaldehyd, 3-Chlor-4-hydroxy-5-methoxybenzaldehyd, 4-Hydroxy-3-iod-5-methoxybenzaldehyd, 2-Brom-4,5-dihydroxybenzaldehyd, 2-Methoxy-1-naphthaldehyd, 4-Methoxy-1-naphthaldehyd, 2-Hydroxy-1-naphthaldehyd, 2,4-Dihydroxy-1-napthaldehyd, 4-Hydroxy-3-methoxy-1-naphthaldehyd, 2-Hydroxy-4-methoxy-1-naphthaldehyd, 3-Hydroxy-4-methoxy-1-naphthaldehyd, 2,4-Dimethoxy-1-naphthaldehyd, 3,4-Dimethoxy-1-naphthaldehyd, 4-Dimethylamino-1-naphthaldehyd, 3-Hydroxy-4-nitrobenzaldehyd, 2-Hydroxy-3-methoxy-5-nitrobenzaldehyd, 5-Nitrovanillin, 2,5-Dinitrosalicylaldehyd, 5-Brom-3-nitrosalicylaldehyd, 2-Dimethylaminobenzaldehyd, 2-Chlor-4-dimethylaminobenzaldehyd, 4-Dimethylamino-2-methylbenzaldehyd, 4-Diethylamino-zimtaldehyd, 4-Dibutylamino-benzaldehyd, 3-Carboxy-4-hydroxy-benzaldehyd, 5-Carboxyvanillin, 3-Carboxy-4-hydroxy-5-methylbenzaldehyd, 3-Carboxy-5-ethoxy-4-hydroxybenzaldehyd, 3-Carboxy-4-hydroxybenzaldehyd, 5-Carboxyvanillin, 3-Carboxy-4-hydroxy-5-methylbenzaldehyd, 3-Carboxy-5-ethoxy-4-hydroxybenzaldehyd, 3-Allyl-4-hydroxybenzaldehyd, 3-Allyl-4-hydroxy-5-methoxybenzaldehyd, 3-Allyl-4-hydroxy-5-methylbenzaldehyd, 3-Allyl-5-brom-4-hydroxybenzaldehyd, 3,5-Diallyl-4-hydroxybenzaldehyd, 3-Allyl-5-carboxy-4-hydroxybenzaldehyd (3-Allyl-5-formyl-2-hydroxybenzoesäure), 4-Hydroxy-5-methoxyisophthalaldehyd und 3-Allyl-4-hydroxy-5-formylbenzaldehyd (5-Allyl-4-hydroxyisophthalaldehyd).
8. 8. Portion nach einem der Punkte 1 bis 7, dadurch gekennzeichnet, dass das Wasch- oder Reinigungsmittel die erste Bläuungsmittel-Vorläuferverbindung in einer Gesamtmenge von 0,0001 bis 50 mmol, insbesondere von 0,001 bis 30 mmol, enthält.
9. 9. Portion nach einem der Punkte 1 bis 8, dadurch gekennzeichnet, dass das Wasch- oder Reinigungsmittel die zweite Bläuungsmittel-Vorläuferverbindung in einer Gesamtmenge von 0,0001 bis 50 mmol, insbesondere von 0,001 bis 30 mmol, enthält.
10. 10. Portion nach einem der Punkte 1 bis 9, dadurch gekennzeichnet, dass das Wasch- oder Reinigungsmittel die erste Bläuungsmittel-Vorläuferverbindung und die zweite Bläuungsmittel-Vorläuferverbindung in einem Molverhältnisbereich von 2:1 bis 1:2, bevorzugt von 1,5 zu 1 bis 1 zu 1,5, enthält.
11. 11. Portion nach einem der Punkte 1 bis 10, dadurch gekennzeichnet, dass das Wasch- oder Reinigungsmittel mindestens ein Alkalisierungsmittel enthält.
12. 12. Portion nach einem der Punkte 1 bis 11, dadurch gekennzeichnet, dass eine Lösung von 2,0 g des Wasch- oder Reinigungsmittel in 1 Liter Wasser einen pH-Wert (20°C) von 7 bis 10, insbesondere von 7,5 bis 9,5, besitzt.
13. 13. Portion nach einem der Punkte 1 bis 12, dadurch gekennzeichnet, dass das Wasch- oder Reinigungsmittel Aniontensid in einer Gesamtmenge von 20 bis 50 Gew.-%, insbesondere von 25 bis 35 Gew.-%, jeweils bezogen auf das Gesamtgewicht des Wasch- oder Reinigungsmittels, enthält.
14. 14. Portion nach einem der Punkte 1 bis 13, dadurch gekennzeichnet, dass das wasserlösliche Material Polyvinylalkohol umfasst.
15. 15. Verfahren zur Textilreinigung, dadurch gekennzeichnet, dass mindestens eine Portion der Punkte 1 bis 14 in die Trommel einer Waschmaschine gemeinsam mit dem Waschgut gegeben wird, durch Zugabe von 5 bis 40 Liter Wasser pro eingesetzter Portion eine Waschlauge bereitgestellt wird, die resultierende Waschlauge und das Waschgut über einen Zeitraum von 20 bis 120 Minuten, bevorzugt 30 bis 90 Minuten, in Kontakt stehen, die Waschlauge entfernt und das Waschgut gespült wird.
16. 16. Verfahren nach Punkt 15, dadurch gekennzeichnet, dass bezogen auf das Volumen des zugegebenen Wassers die Konzentration der ersten Bläuungsmittel-Vorläuferverbindung in der Waschlauge 0,0005 bis 3,0 mmol/L, insbesondere 0,0005 bis 1,8 mmol/L, beträgt.
17. 17. Verfahren nach Punkt 15 oder 16, dadurch gekennzeichnet, dass bezogen auf das Volumen des zugegebenen Wassers die Konzentration der zweiten Bläuungsmittel-Vorläuferverbindung in der Waschlauge 0,0005 bis 3,0 mmol/L, insbesondere 0,0005 bis 1,8 mmol/L, beträgt.
18. 18. Verfahren nach einem der Punkte 15 bis 18, dadurch gekennzeichnet, dass die Waschlauge einen pH-Wert von 7 bis 10, insbesondere von 7,5 bis 9,5 aufweist.

A preferred embodiment is characterized by the following points:

1. 1st portion, comprising
   • (I) a container of water-soluble material having at least two separate chambers and
   • (ii) a detergent prepared in said container containing, based on its total weight, a total amount of from 20 to 70% by weight of surfactant, said washing or cleaning agent comprising at least two compositions formulated separately in said chambers, characterized in that said container
   • (A) in at least one chamber, a composition containing at least a first Bluuungsmittel precursor compound, and
   • (b) in at least one further different chamber, a composition containing at least one reactive carbonyl compound, in particular at least one aldehyde, as second blusher precursor compound, with the proviso that said first and second bluencer precursor compounds in said vessel are separated from each other are made up.
2. 2. Portion according to item 1, characterized in that the first bluing agent precursor compound is at least one CH-acidic compound.
3. 3. Portion according to item 1 or 2, characterized in that the first bluing agent precursor compound is at least one compound of formula (I)
   
   wherein
   • R ⁶ is a linear or cyclic (C ₁ to C ₆ ) alkyl group, a (C ₂ to C ₆ ) alkenyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an aryl (C ₁ to C ₆ ) alkyl group, a (C ₁ to C ₆ ) hydroxyalkyl group, a (C ₂ to C ₆ ) polyhydroxyalkyl group, a (C ₁ to C ₆ ) alkoxy (C ₁ to C ₆ ) alkyl group, a group R ^I R ^{II is} N- (CH ₂ ) _m -, in which R ^I and R ^II independently of one another represent a hydrogen atom, a (C ₁ to C ₄ ) -alkyl group, a (C ₁ to C ₄ ) -hydroxyalkyl group or an aryl- ( C ₁ to C ₆ ) -alkyl group, wherein R ^I and R ^II together with the nitrogen atom can form a 5-, 6- or 7-membered ring and m is a number 2, 3, 4, 5 or 6,
   • R ⁷ is a (C ₁ to C ₆ ) -alkyl group, in particular a methyl group,
   • The cycle of the formula (I) represents all ring structures which may additionally contain further heteroatoms such as nitrogen, oxygen or sulfur and may further carry fused ring structures, all of these ring structures being able to carry additional substituents,
   • • X ^- stands for a physiologically compatible anion.
4. 4. Portion according to one of the items 1 to 3, characterized in that at least one compound of the formula (I-1) is contained as the first bluencer precursor compound
   
   wherein
   • R ⁸ and R ⁹ independently of one another represent a linear or cyclic C ₁ -C ₆ -alkyl group, a C ₂ -C ₆ -alkenyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an aryl-C ₁ -C ₆ - alkyl group, a C ₁ -C ₆ hydroxyalkyl group, a C ₂ -C ₆ polyhydroxyalkyl group, a C ₁ -C ₆ alkoxy-C ₁ -C ₆ alkyl group, a group R ^I R ^II N- (CH ₂ ) _m in which R ^I and R ^II independently of one another represent a hydrogen atom, a C ₁ -C ₄ -alkyl group, a C ₁ -C ₄ -hydroxyalkyl group or an aryl-C ₁ -C ₆ -alkyl group, where R ^I and R ^II together with the nitrogen atom can form a 5-, 6- or 7-membered ring and m is a number 2, 3, 4, 5 or 6,
   • R ¹⁰ and R ¹² independently of one another represent a hydrogen atom or a C ₁ -C ₆ -alkyl group, where at least one of the radicals R ¹⁰ and R ¹² denotes a C ₁ -C ₆ -alkyl group,
   • R ¹¹ is hydrogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ hydroxyalkyl, C ₂ -C ₆ polyhydroxyalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ -Hydroxyalkoxy group, a group R ^III R ^IV N- (CH ₂ ) _q -, in which R ^III and R ^IV independently of one another represent a hydrogen atom, a C ₁ -C ₆ -alkyl group, a C ₁ - C ₆ -Hydroxyalkylgruppe or an aryl-C ₁ -C ₆ -alkyl group and q is a number 1, 2, 3, 4, 5 or 6, wherein the radical R ¹¹ together with one of the radicals R ¹⁰ or R ^{12 is} a 5 or 6-membered aromatic ring optionally substituted by a halogen atom, a C ₁ -C ₆ -alkyl group, a C ₁ -C ₆ -hydroxyalkyl group, a C ₂ -C ₆ -polyhydroxyalkyl group, a C ₁ -C ₆ - Alkoxy group, a C ₁ -C ₆ -hydroxyalkoxy group, a nitro group, a hydroxy group, a group R ^V R ^VI N- (CH ₂ ) _s -, wherein R ^V and R ^VI independently represent a hydrogen atom, a C ₁ -C _6- alkyl group, a C ₁ -C ₆ -hydroxyalkyl group or an aryl-C ₁ -C ₆ -alkyl group and s is a number 0, 1, 2, 3, 4, 5 or 6 may be substituted,
   • Y is an oxygen atom, a sulfur atom or a group NR ^VII , in which R ^VII represents a hydrogen atom, an aryl group, a heteroaryl group, a C ₁ -C ₆ -alkyl group or a C ₁ -C ₆ -arylalkyl group,
   • X- represents a physiologically acceptable anion,
   • Het is an optionally substituted heteroaromatic,
   • • X ¹ represents a direct bond or a carbonyl group.
5. 5. Portion according to one of the items 1 to 4, characterized in that contains as first Bläuungsmittel precursor compound at least one compound from a group of salts with physiologically acceptable counterion X ^- , which is formed from salts of 1,2-dihydro-1, 3,4,6-tetramethyl-2-oxopyrimidinium, 1,2-dihydro-1,3-diethyl-4,6-dimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3-dipropyl 4,6-dimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4,6-dimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3 -diphenyl-4,6-dimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3,4-trimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3-diethyl-4-methyl 2-oxo-pyrimidinium, 1,2-dihydro-1,3-dipropyl-4-methyl-2-oxo-pyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4-methyl 2-oxo-pyrimidinium, 1,2-dihydro-1,3-diphenyl-4-methyl-2-oxo-pyrimidinium, 1-allyl-1,2-dihydro-3,4,6-trimethyl-2-oxo pyrimidinium, 1,2-dihydro-1- (2-hydroxyethyl) -3,4,6-trimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3,4,6-tetramethyl-2-thi oxo-pyrimidinium, 1,2-dihydro-1,3-diethyl-4,6-dimethyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-dipropyl-4,6-dimethyl-2-thioxo pyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4,6-dimethyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-diphenyl-4,6-dimethyl-2 -thioxo-pyrimidinium, 1,2-dihydro-1,3,4-trimethyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-diethyl-4-methyl-2-thioxo-pyrimidinium, 1,2 Dihydro-1,3-dipropyl-4-methyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4-methyl-2-thioxo-pyrimidinium, 1,2- Dihydro-1,3-diphenyl-4-methyl-2-thioxopyrimidinium, 1,2-dihydro-3,4-dimethyl-2-oxo-quinazolinium and 1,2-dihydro-1- (3-hydroxypropyl) - 3,4,6-trimethyl-2-oxopyrimidinium, 1-benzyl-1,2-dihydro-3,4,6-trimethyl-2-oxopyrimidinium and 1,2-dihydro-3,4-dimethyl-2- thioxo-chinazoliniums.
6. 6. Portion according to one of the items 1 to 5, characterized in that as the second bluencer precursor compound at least one compound of the formula (II) is contained,
   
   wherein
   • R ¹ , R ² and R ³ are each independently hydrogen, halogen, C ₁ -C ₆ alkyl, hydroxy, C ₁ -C ₆ alkoxy, C ₁ -C ₆ dialkylamino, etc. Di (C ₂ -C ₆ hydroxyalkyl) amino group, di (C ₁ -C ₆ alkoxy-C ₁ -C ₆ alkyl) amino group, C ₁ -C ₆ hydroxyalkyloxy group, sulfonyl group, carboxy group, sulfonic acid group , a sulfonamido group, a sulfonamide group, a carbamoyl group, a C ₂ -C ₆ acyl group or a nitro group,
   • Z 'is a direct bond or a vinylene group,
   • R ⁴ and R ⁵ represent a hydrogen atom or together form, together with the remainder of the molecule, a 5- or 6-membered aromatic or aliphatic ring.
7. 7. Portion according to one of the items 1 to 6, characterized in that the second bluing agent precursor compound is at least one compound selected from 4-hydroxy-3-methoxybenzaldehyde, 3,5-dimethoxy-4-hydroxybenzaldehyde, 4-hydroxy 1-naphthaldehyde, 4-hydroxy-2-methoxybenzaldehyde, 3,4-dihydroxy-5-methoxybenzaldehyde, 3,4,5-trihydroxybenzaldehyde, 3,5-dibromo-4-hydroxybenzaldehyde, 4-hydroxy-3-nitrobenzaldehyde, 3 Bromo-4-hydroxybenzaldehyde, 4-hydroxy-3-methylbenzaldehyde, 3,5-dimethyl-4-hydroxybenzaldehyde, 5-bromo-4-hydroxy-3-methoxybenzaldehyde, 4-diethylamino-2-hydroxybenzaldehyde, 4-dimethylamino-2-ol methoxybenzaldehyde, 3 - [(dimethylamino) methyl] -4-hydroxy-5-methoxybenzaldehyde, 2-methoxybenzaldehyde, 3-methoxybenzaldehyde, 4-methoxybenzaldehyde, 2-ethoxybenzaldehyde, 3-ethoxybenzaldehyde, 4-ethoxybenzaldehyde, 4-hydroxy-2 , 3-dimethoxy-benzaldehyde, 4-hydroxy-2,5-dimethoxybenzaldehyde, 4-hydroxy-2,6-dimethoxybenzaldehyde, 4-hydroxy-2-methylbenzaldehyde, 4-hydroxy-2,3-dimethyl -benza aldehyde, 4-hydroxy-2,5-dimethylbenzaldehyde, 4-hydroxy-2,6-dimethylbenzaldehyde, 3,5-diethoxy-4-hydroxybenzaldehyde, 2,6-diethoxy-4-hydroxybenzaldehyde, 3-hydroxy-4-methoxybenzaldehyde, 2-hydroxy-4-methoxybenzaldehyde, 2-ethoxy-4-hydroxybenzaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, 4-ethoxy-2-hydroxybenzaldehyde, 4- Ethoxy-3-hydroxybenzaldehyde, 2,3-dimethoxybenzaldehyde, 2,4-dimethoxybenzaldehyde, 2,5-dimethoxybenzaldehyde, 2,6-dimethoxybenzaldehyde, 3,4-dimethoxybenzaldehyde, 3,5-dimethoxybenzaldehyde, 2,3,4- Trimethoxybenzaldehyde, 2,3,5-trimethoxybenzaldehyde, 2,3,6-trimethoxybenzaldehyde, 2,4,6-trimethoxybenzaldehyde, 2,4,5-trimethoxybenzaldehyde, 2,5,6-trimethoxybenzaldehyde, 2-hydroxybenzaldehyde, 3-hydroxybenzaldehyde, 4-hydroxybenzaldehyde, 2,3-dihydroxybenzaldehyde, 2,4-dihydroxybenzaldehyde, 2,4-dihydroxy-3-methylbenzaldehyde, 2,4-dihydroxy-5-methylbenzaldehyde, 2,4-dihydroxy-6-methyl- benzaldehyde, 2,4-dihydroxy-3-methoxybenzaldehyde, 2,4-dihydroxy-5-methoxybenzaldehyde, 2,4-dihydroxy-6-methoxybe aldehyde, 2,5-dihydroxybenzaldehyde, 2,6-dihydroxybenzaldehyde, 3,4-dihydroxybenzaldehyde, 3,4-dihydroxy-2-methylbenzaldehyde, 3,4-dihydroxy-5-methylbenzaldehyde, 3,4-dihydroxy-6- methyl-benzaldehyde, 3,4-dihydroxy-2-methoxybenzaldehyde, 3,4-dihydroxy-5-ethoxybenzaldehyde, 3,5-dihydroxybenzaldehyde, 2,3,4-trihydroxybenzaldehyde, 2,3,5-trihydroxybenzaldehyde, 2, 3,6-trihydroxybenzaldehyde, 2,4,6-trihydroxybenzaldehyde, 2,4,5-trihydroxybenzaldehyde, 2,5,6-trihydroxybenzaldehyde, 4-dimethylaminobenzaldehyde, 4-diethylaminobenzaldehyde, 4-dimethylamino-2-hydroxybenzaldehyde, 4-pyrrolidinobenzaldehyde, 4-morpholinobenzaldehyde, 2-morpholinobenzaldehyde, 4-piperidinobenzaldehyde, 2,3,6,7-tetrahydro-5H- [1,4] oxazino [2,3,4-ij] quinoline-9-carbaldehyde, 3.5- Dichloro-4-hydroxybenzaldehyde, 4-hydroxy-3,5-diiodobenzaldehyde, 3-chloro-4-hydroxybenzaldehyde, 5-chloro-3,4-dihydroxybenzaldehyde, 5-bromo-3,4-dihydroxybenzaldehyde, 3-chloro 4-hydroxy-5-methoxybenzaldehyde, 4-hydroxy-3-iodo-5-methoxybenzaldehyde, 2-bromo-4,5-dihydroxybenzaldehyde ehy, 2-methoxy-1-naphthaldehyde, 4-methoxy-1-naphthaldehyde, 2-hydroxy-1-naphthaldehyde, 2,4-dihydroxy-1-naphthaldehyde, 4-hydroxy-3-methoxy-1-naphthaldehyde, 2- Hydroxy-4-methoxy-1-naphthaldehyde, 3-hydroxy-4-methoxy-1-naphthaldehyde, 2,4-dimethoxy-1-naphthaldehyde, 3,4-dimethoxy-1-naphthaldehyde, 4-dimethylamino-1-naphthaldehyde, 3-hydroxy-4-nitrobenzaldehyde, 2-hydroxy-3-methoxy-5-nitrobenzaldehyde, 5-nitrovanillin, 2,5-dinitrosalicylaldehyde, 5-bromo-3-nitrosalicylaldehyde, 2-dimethylaminobenzaldehyde, 2-chloro-4-dimethylaminobenzaldehyde, 4-dimethylamino-2-methylbenzaldehyde, 4-diethylamino-cinnamaldehyde, 4-dibutylaminobenzaldehyde, 3-carboxy-4-hydroxy-benzaldehyde, 5-carboxyvanillin, 3-carboxy-4-hydroxy-5-methylbenzaldehyde, 3-carboxy 5-ethoxy-4-hydroxybenzaldehyde, 3-carboxy-4-hydroxybenzaldehyde, 5-carboxyvanillin, 3-carboxy-4-hydroxy-5-methylbenzaldehyde, 3-carboxy-5-ethoxy-4-hydroxybenzaldehyde, 3-allyl-4 hydroxybenzaldehyde, 3-allyl-4-hydroxy-5-methoxybenzaldehyde, 3-allyl-4-hydroxy-5-methylbenzaldehyde, 3-allyl-5-bromo-4-hydroxybenzaldehyde, 3,5-diallyl-4-hydroxybenzaldehyde, 3-allyl-5-carboxy-4-hydroxybenzaldehyde (3-allyl-5-formyl-2-hydroxybenzoic acid), 4-hydroxy 5-methoxyisophthalaldehyde and 3-allyl-4-hydroxy-5-formylbenzaldehyde (5-allyl-4-hydroxyisophthalaldehyde).
8. 8. Portion according to one of the items 1 to 7, characterized in that the washing or cleaning agent contains the first bluing agent precursor compound in a total amount of 0.0001 to 50 mmol, in particular from 0.001 to 30 mmol.
9. 9. Portion according to one of the items 1 to 8, characterized in that the washing or cleaning agent contains the second bluing agent precursor compound in a total amount of 0.0001 to 50 mmol, in particular from 0.001 to 30 mmol.
10. 10. Portion according to one of the items 1 to 9, characterized in that the washing or cleaning agent, the first Bluuungsmittel precursor compound and the second Bläuungsmittel precursor compound in a molar ratio range of 2: 1 to 1: 2, preferably from 1.5 to 1 to 1 to 1.5.
11. 11. Portion according to one of the items 1 to 10, characterized in that the washing or cleaning agent contains at least one alkalizing agent.
12. 12. Portion according to one of the items 1 to 11, characterized in that a solution of 2.0 g of the detergent or cleaning agent in 1 liter of water has a pH (20 ° C) of 7 to 10, in particular of 7.5 to 9.5, owns.
13. 13. Portion according to one of the items 1 to 12, characterized in that the washing or cleaning agent anionic surfactant in a total amount of 20 to 50 wt .-%, in particular from 25 to 35 wt .-%, each based on the total weight of the wash - or cleaning agent containing.
14. 14. Portion according to one of the items 1 to 13, characterized in that the water-soluble material comprises polyvinyl alcohol.
15. 15. A method for textile cleaning, characterized in that at least a portion of the points 1 to 14 is placed in the drum of a washing machine together with the laundry, by adding 5 to 40 liters of water per portion inserted a wash liquor is provided, the resulting wash liquor and the laundry is in contact for a period of 20 to 120 minutes, preferably 30 to 90 minutes, the wash liquor is removed and the laundry is rinsed.
16. 16. The method according to item 15, characterized in that based on the volume of the added water, the concentration of the first Bläuungsmittel precursor compound in the wash liquor 0.0005 to 3.0 mmol / L, in particular 0.0005 to 1.8 mmol / L. , is.
17. 17. The method according to item 15 or 16, characterized in that based on the volume of the added water, the concentration of the second Bläuungsmittel precursor compound in the wash liquor 0.0005 to 3.0 mmol / L, in particular 0.0005 to 1.8 mmol / L, is.
18. 18. The method according to any one of points 15 to 18, characterized in that the wash liquor has a pH of 7 to 10, in particular from 7.5 to 9.5.

In the following exemplary embodiments, the portion according to the invention is explained by way of example.

Examples:

Preparation of the test detergent portions

For the preparation of detergent portions, liquid compositions L1 and L2 were prepared according to Table 2. Per unit of blueness precursor compound pair according to Table 1 was used.

A1

1,2-Dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidinium-chlorid

A2

1,2-Dihydro-1,3,4-trimethyl-2-oxo-pyrimidinium-chlorid

A3

1,2-Dihydro-4,6-dimethyl-1,3-dipropyl-2-oxo-pyrimidinium-chlorid

A4

1,2-Dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidinium-hydrogensulfat

A5

1-Allyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidinium-bromid

A6

1,2-Dihydro-1-(2-hydroxyethyl)-3,4,6-trimethyl-2-oxopyrimidinium-p-toluolsulfonat

Tabelle 1 Erste Bläuungsmittel-Vorläuferverbindung Zweite Bläuungsmittel-Vorläuferverbindung Farbton einer Lösung der Portion (10 L Wasser bei pH 7-9) A1 4-Hydroxy-3-methoxybenzaldehyd leuchtend violett A1 3,5-Dimethoxy-4-hydroxy-benzaldehyd intensiv dunkelblau A2 4-Hydroxy-3-methoxybenzaldehyd leuchtend violett A2 3,4-Dihydroxybenzaldehyd intensiv dunkelblau A2 3,5-Dimethyl-4-hydroxybenzaldehyd violett A3 4-Hydroxy-3-methoxybenzaldehyd intensiv violett A3 3,5-Dimethoxy-4-hydroxy-benzaldehyd intensiv dunkelblau A4 4-Hydroxy-3-methoxybenzaldehyd mittelblau A4 3,5-Dimethoxy-4-hydroxy-benzaldehyd dunkelblau/türkis A4 3,4-Dihydroxy-5-methoxybenzaldehyd intensiv dunkelblau A5 4-Hydroxy-3-methoxybenzaldehyd leuchtend violett A5 3,5-Dimethoxy-4-hydroxy-benzaldehyd intensiv dunkelblau A5 4-Hydroxy-1-naphthaldehyd intensiv dunkelblau A5 3,4,5-Trihydroxybenzaldehyd intensiv dunkelblau A5 3,4-Dihydroxy-5-methoxybenzaldehyd intensiv dunkelblau A6 3,5-Dimethoxy-4-hydroxy-benzaldehyd intensiv dunkelblau Tabelle 2: Flüssige Zusammensetzungen L1 [Gew.-%] L2 [Gew.-%] C_11-13-Alkylbenzolsulfonsäure 23,0 23,0 C_13-15-Alkylalkohol ethoxyliert mit 8 Mol Ethylenoxid 24,0 24,0 Glyzerin 9,0 9,0 2-Aminoethanol 6,8 6,8 ethoxyliertes Polyethylenimin 4,0 4,0 C_12-18-Fettsäure 7,5 7,5 Diethylentriamin-N,N,N',N',N''- penta(methylenphosphonsäure), Heptanatriumsalz (Natrium DTPMP) 3,5 3,5 1,2-Propylenglykol 4,5 4,5 Ethanol 4,0 4,0 Soil-Release Polymer aus Ethylenterephthalat und Polyethylenoxid-terephthalat 1,0 1,0 Erste Bläuungsmittel-Vorläuferverbindung (Tabelle 1) 0,61 - Zweite Bläuungsmittel-Vorläuferverbindung (Tabelle 1) - 0,42 Parfum 1,7 1,7 Wasser ad 100 ad 100 First Blueness Precursor Compound (Table 1):

A1

1,2-dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidinium chloride

A2

1,2-dihydro-1,3,4-trimethyl-2-oxo-pyrimidinium chloride

A3

1,2-dihydro-4,6-dimethyl-1,3-dipropyl-2-oxo-pyrimidinium chloride

A4

1,2-dihydro-1,3,4,6-tetramethyl-2-oxo-pyrimidinium hydrogensulphate

A5

1-allyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidinium bromide

A6

1,2-dihydro-1- (2-hydroxyethyl) -3,4,6-trimethyl-2-oxopyrimidinium-p-toluenesulfonate

Table 1 First bluencer precursor compound Second bluencer precursor compound Color of a solution of the portion (10 L of water at pH 7-9) A1 4-Hydroxy-3-methoxybenzaldehyde bright violet A1 3,5-dimethoxy-4-hydroxy-benzaldehyde intense dark blue A2 4-Hydroxy-3-methoxybenzaldehyde bright violet A2 3,4-dihydroxy benzaldehyde intense dark blue A2 3,5-dimethyl-4-hydroxybenzaldehyde violet A3 4-Hydroxy-3-methoxybenzaldehyde intense violet A3 3,5-dimethoxy-4-hydroxy-benzaldehyde intense dark blue A4 4-Hydroxy-3-methoxybenzaldehyde mittelblau A4 3,5-dimethoxy-4-hydroxy-benzaldehyde dark blue / turquoise A4 3,4-dihydroxy-5-methoxybenzaldehyde intense dark blue A5 4-Hydroxy-3-methoxybenzaldehyde bright violet A5 3,5-dimethoxy-4-hydroxy-benzaldehyde intense dark blue A5 4-Hydroxy-1-naphthaldehyde intense dark blue A5 3,4,5-trihydroxybenzaldehyde intense dark blue A5 3,4-dihydroxy-5-methoxybenzaldehyde intense dark blue A6 3,5-dimethoxy-4-hydroxy-benzaldehyde intense dark blue Table 2: Liquid Compositions L1 [% by weight] L2 [% by weight] C _11-13 alkyl benzene sulfonic acid 23.0 23.0 C _13-15 alkyl alcohol ethoxylated with 8 moles of ethylene oxide 24.0 24.0 glycerin 9.0 9.0 2-aminoethanol 6.8 6.8 ethoxylated polyethyleneimine 4.0 4.0 C _12-18 fatty acid 7.5 7.5 Diethylenetriamine-N, N, N ', N', N "-penta (methylenephosphonic acid), heptasodium salt (sodium DTPMP) 3.5 3.5 1,2-propylene glycol 4.5 4.5 ethanol 4.0 4.0 Soil-release polymer of ethylene terephthalate and polyethylene terephthalate 1.0 1.0 First Blueness Precursor Compound (Table 1) 0.61 - Second bleach precursor compound (Table 1) - 0.42 Perfume 1.7 1.7 water ad 100 ad 100

Making pouch

For this purpose, a film M8630 Fa. Monosol (88 microns, incorporated with the film material 1500 ppm denatonium benzoate) was clamped on a heatable mold with Doppelkavität. The stretched film was heated at 105 ° C for a period of 2400 ms and then pulled into the cavity by a vacuum. Subsequently, 10 ml of the composition L1 were filled into the first cavity by means of a syringe and then 10 ml of the liquid composition L2 were introduced by means of a syringe into the second cavity. Thereafter, a top film (M8630, 90 microns) was placed to seal the cavities and heat-sealed (150 ° C, 1000 ms) with the first film. After breaking the vacuum, the portion of the cavity was removed.

washing tests

A portion of the bulking agent precursors 1,2-dihydro-1,3,4,6-tetramethyl-2-oxopyrimidinium hydrogensulfate (A4) and 3,4-dihydroxy-5-methoxybenzaldehyde according to Tables 1 and 2 of Item 1.0 ( vide supra) and dissolved in 15 L of water. White cotton lumps were added to the resulting solution and left in the solution for 1 hour at 25 ° C. Finally, the lobules were rinsed with water and dried hanging.

The dry lobes were visually evaluated by 5 persons in a blind test against an unwashed reference cotton lobe. All persons rated the lobules washed with the portion according to the invention as whiter compared to the reference.

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• WO 2014/089386 A1 [0009, 0013]

Claims (10)

Portion comprising (i) a container of water-soluble material having at least two separate compartments and (ii) a detergent or conditioner packaged in said container containing, based on its total weight, a total of from 20 to 70% by weight of surfactant Detergent or cleaning agent comprises at least two, in said chambers separately formulated compositions, characterized in that in said container (a) in at least one chamber, a composition containing at least a first Bläuungsmittel precursor compound, and (b) in at least one of them another chamber, a composition containing at least one reactive carbonyl compound, in particular at least one aldehyde, is included as a second bluencer precursor compound, with the proviso that said first and second Bluuungsmittel precursor compounds in said container separately confection are iert. Portion after Claim 1 , characterized in that the first bluing agent precursor compound is at least one CH-acidic compound. Portion after Claim 1 or 2 , characterized in that at least one compound of the formula (I) is contained as the first bluencer precursor compound

wherein R ⁶ represents a linear or cyclic (C ₁ to C ₆ ) alkyl group, a (C ₂ to C ₆ ) alkenyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an aryl (C ₁ to C ₆ ) alkyl group, a (C ₁ to C ₆ ) hydroxyalkyl group, a (C ₂ to C ₆ ) polyhydroxyalkyl group, a (C ₁ to C ₆ ) alkoxy (C ₁ to C ₆ ) alkyl group, a group R ^I R ^{II is} N- (CH ₂ ) _m -, in which R ^I and R ^II independently of one another represent a hydrogen atom, a (C ₁ to C ₄ ) -alkyl group, a (C ₁ to C ₄ ) -hydroxyalkyl group or an aryl- (C ₁ to C ₆ ) -alkyl group, wherein R ^I and R ^II together with the nitrogen atom can form a 5-, 6- or 7-membered ring and m is a number 2, 3, 4, 5 or 6, R ⁷ is a (C ₁ to C ₆ ) -alkyl group, in particular a methyl group, • the cycle of formula (I) represents all ring structures which additionally contain further heteroatoms such as nitrogen, oxygen or sulfur e can nthalten and can carry further fused-ring structures, all of these ring structures may carry additional substituents, • X ^- represents a physiologically acceptable anion. Serving one of the Claims 1 to 3 , characterized in that at least one compound of the formula (I-1) is contained as the first bluing agent precursor compound

wherein R ⁸ and R ⁹ independently of one another represent a linear or cyclic C ₁ -C ₆ -alkyl group, a C ₂ -C ₆ -alkenyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an aryl-C ₁ -C ₆ - alkyl group, a C ₁ -C ₆ hydroxyalkyl group, a C ₂ -C ₆ polyhydroxyalkyl group, a C ₁ -C ₆ alkoxy-C ₁ -C ₆ alkyl group, a group R ^I R ^II N- (CH ₂ ) _m - in which R ^I and R ^II independently of one another represent a hydrogen atom, a C ₁ -C ₄ -alkyl group, a C ₁ -C ₄ -hydroxyalkyl group or an aryl-C ₁ -C ₆ -alkyl group, where R ^I and R ^{II are taken} together with the nitrogen atom can form a 5-, 6- or 7-membered ring and m is a number 2, 3, 4, 5 or 6, • R ¹⁰ and R ¹² independently represent a hydrogen atom or a C ₁ -C _6- alkyl group, wherein at least one of R ¹⁰ and R ^{12 is} a C ₁ -C ₆ alkyl group, • R ¹¹ is a hydrogen atom, a C ₁ -C ₆ alkyl group e, a C ₁ -C ₆ hydroxyalkyl group, a C ₂ -C ₆ polyhydroxyalkyl group, a C ₁ -C ₆ alkoxy group, a C ₁ -C ₆ hydroxyalkoxy group, a group R ^III R ^IV N- (CH ₂ ) _q -, wherein R ^III and R ^IV independently represent a hydrogen atom, a C ₁ -C ₆ alkyl group, a C ₁ -C ₆ hydroxyalkyl group or an arylC ₁ -C ₆ alkyl group, and q represents a number 1, 2, 3, 4, 5 or 6, wherein the radical R ¹¹ together with one of the radicals R ¹⁰ or R ^{12 can form} a 5- or 6-membered aromatic ring which is optionally substituted by a halogen atom, a C ₁ -C _6- alkyl group, a C ₁ -C ₆ -hydroxyalkyl group, a C ₂ -C ₆ -polyhydroxyalkyl group, a C ₁ -C ₆ -alkoxy group, a C ₁ -C ₆ -hydroxyalkoxy group, a nitro group, a hydroxy group, a group R ^V R ^{VI is} N- (CH ₂ ) _s -, wherein R ^V and R ^VI independently of one another represent a hydrogen atom, a C ₁ -C ₆ -alkyl group, a C ₁ -C ₆ -hydroxyalkyl group or an aryl-C ₁ -C ₆ alkyl group and s is a number 0, 1, 2, 3, 4, 5 or 6, Y is an oxygen atom, a sulfur atom or a group NR ^VII , wherein R ^VII is a hydrogen atom, an aryl group, a heteroaryl group, a C ₁ -C ₆ -alkyl group or a C ₁ -C ₆ -arylalkyl group, • X - represents a physiologically acceptable anion, • Het represents an optionally substituted heteroaromatic radical, • X ¹ represents a direct bond or a carbonyl group. Serving one of the Claims 1 to 4 , characterized in that as first bluing agent precursor compound contains at least one compound from a group of salts with physiologically compatible counterion X ^- , which is formed from salts of 1,2-dihydro-1,3,4,6-tetramethyl-2 oxo-pyrimidinium, 1,2-dihydro-1,3-diethyl-4,6-dimethyl-2-oxo-pyrimidinium, 1,2-dihydro-1,3-dipropyl-4,6-dimethyl-2-oxo pyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4,6-dimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3-diphenyl-4,6-dimethyl-2 oxo-pyrimidinium, 1,2-dihydro-1,3,4-trimethyl-2-oxo-pyrimidinium, 1,2-dihydro-1,3-diethyl-4-methyl-2-oxo-pyrimidinium, 1,2 Dihydro-1,3-dipropyl-4-methyl-2-oxopyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4-methyl-2-oxopyrimidinium, 1,2- Dihydro-1,3-diphenyl-4-methyl-2-oxo-pyrimidinium, 1-allyl-1,2-dihydro-3,4,6-trimethyl-2-oxo-pyrimidinium, 1,2-dihydro-1 (2-hydroxyethyl) -3,4,6-trimethyl-2-oxopyrimidinium, 1,2-dihydro-1,3,4,6-tetramethyl-2-thioxopyrimidinium, 1,2-dihydro-1, 3-diet Hyl-4,6-dimethyl-2-thioxopyrimidinium, 1,2-dihydro-1,3-dipropyl-4,6-dimethyl-2-thioxopyrimidinium, 1,2-dihydro-1,3-di ( 2-hydroxyethyl) -4,6-dimethyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-diphenyl-4,6-dimethyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3 , 4-trimethyl-2-thioxopyrimidinium, 1,2-dihydro-1,3-diethyl-4-methyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-dipropyl-4-methyl-2 thioxo-pyrimidinium, 1,2-dihydro-1,3-di (2-hydroxyethyl) -4-methyl-2-thioxo-pyrimidinium, 1,2-dihydro-1,3-diphenyl-4-methyl-2-ol thioxo-pyrimidinium, 1,2-dihydro-3,4-dimethyl-2-oxo-quinazolinium and 1,2-dihydro-1- (3-hydroxypropyl) -3,4,6-trimethyl-2-oxopyrimidinium, 1 Benzyl-1,2-dihydro-3,4,6-trimethyl-2-oxopyrimidinium and 1,2-dihydro-3,4-dimethyl-2-thioxo-quinazolinium. Serving one of the Claims 1 to 5 , characterized in that as the second bluing agent precursor compound at least one compound of the formula (II) is contained,

in which R ¹ , R ² and R ³ independently of one another represent a hydrogen atom, a halogen atom, a C ₁ -C ₆ -alkyl group, a hydroxy group, a C ₁ -C ₆ -alkoxy group, a C ₁ -C ₆ -dialkylamino group, a di (C ₂ -C ₆ hydroxyalkyl) amino group, a di (C ₁ -C ₆ alkoxy-C ₁ -C ₆ alkyl) amino group, a C ₁ -C ₆ hydroxyalkyloxy group, a sulfonyl group, a carboxy group, a Sulfonic acid group, a sulfonamido group, a sulfonamide group, a carbamoyl group, a C ₂ -C ₆ acyl group or a nitro group, • Z 'represents a direct bond or a vinylene group, • R ⁴ and R ⁵ represent a hydrogen atom or together form together with the remainder of the molecule a 5- or 6-membered aromatic or aliphatic ring. Serving one of the Claims 1 to 6 , characterized in that as second bluing agent precursor compound at least one compound is selected, selected from 4-hydroxy-3-methoxybenzaldehyde, 3,5-dimethoxy-4-hydroxybenzaldehyde, 4-hydroxy-1-naphthaldehyde, 4-hydroxy-2-one 3-bromo-4-hydroxybenzaldehyde 3-methylbenzaldehyde, 3,5-dimethyl-4-hydroxybenzaldehyde, 5-bromo-4-hydroxy-3-methoxybenzaldehyde, 4-diethylamino-2-hydroxybenzaldehyde, 4-dimethylamino-2-methoxybenzaldehyde, 3 - [(dimethylamino) methyl) -4-hydroxy-5-methoxybenzaldehyde, 2-methoxybenzaldehyde, 3-methoxybenzaldehyde, 4-methoxybenzaldehyde, 2-ethoxybenzaldehyde, 3-ethoxybenzaldehyde, 4-ethoxybenzaldehyde, 4-hydroxy-2,3-dimethoxybenzaldehyde, 4 -Hydroxy-2,5-dimethoxybenzaldehyde, 4-hydroxy-2,6-dimethoxybenzaldehyde, 4-hydroxy-2-methylbenzaldehyde, 4-hydroxy-2,3-dimethylbenzaldehyde, 4-hydroxy-2,5 dimethyl-benzalde hyd, 4-hydroxy-2,6-dimethylbenzaldehyde, 3,5-diethoxy-4-hydroxybenzaldehyde, 2,6-diethoxy-4-hydroxybenzaldehyde, 3-hydroxy-4-methoxybenzaldehyde, 2-hydroxybenzaldehyde 4-methoxybenzaldehyde, 2-ethoxy-4-hydroxybenzaldehyde, 3-ethoxy-4-hydroxybenzaldehyde, 4-ethoxy-2-hydroxybenzaldehyde, 4-ethoxy-3-hydroxybenzaldehyde, 2,3- Dimethoxybenzaldehyde, 2,4-dimethoxybenzaldehyde, 2,5-dimethoxybenzaldehyde, 2,6-dimethoxybenzaldehyde, 3,4-dimethoxybenzaldehyde, 3,5-dimethoxybenzaldehyde, 2,3,4-trimethoxybenzaldehyde, 2,3,5-trimethoxybenzaldehyde, 2, 3,6-trimethoxybenzaldehyde, 2,4,6-trimethoxybenzaldehyde, 2,4,5-trimethoxybenzaldehyde, 2,5,6-trimethoxybenzaldehyde, 2-hydroxybenzaldehyde, 3-hydroxybenzaldehyde, 4-hydroxybenzaldehyde, 2,3-dihydroxybenzaldehyde, 2, 4-dihydroxybenzaldehyde, 2,4-dihydroxy-3-methylbenzaldehyde, 2,4-dihydroxy-5-methylbenzaldehyde, 2,4-dihydroxy-6-methylbenzaldehyde, 2,4-dihydroxy-3-methoxy- benzaldehyde, 2,4-dihydroxy-5-methoxybenzaldehyde, 2,4-dihydroxy-6-methoxybenzaldehyde, 2,5-dihydroxybenzaldehyde, 2, 6-dihydroxybenzaldehyde, 3,4-dihydroxybenzaldehyde, 3,4-dihydroxy-2-methylbenzaldehyde, 3,4-dihydroxy-5-methylbenzaldehyde, 3,4-dihydroxy-6-methylbenzaldehyde, 3,4-dihydroxy- 2-methoxybenzaldehyde, 3,4-dihydroxy-5-ethoxybenzaldehyde, 3,5-dihydroxybenzaldehyde, 2,3,4-trihydroxybenzaldehyde, 2,3,5-trihydroxybenzaldehyde, 2,3,6-trihydroxybenzaldehyde, 2,4, 6-trihydroxybenzaldehyde, 2,4,5-trihydroxybenzaldehyde, 2,5,6-trihydroxybenzaldehyde, 4-dimethylaminobenzaldehyde, 4-diethylaminobenzaldehyde, 4-dimethylamino-2-hydroxybenzaldehyde, 4-pyrrolidinobenzaldehyde, 4-morpholinobenzaldehyde, 2-morpholinobenzaldehyde, 4- Piperidinobenzaldehyde, 2,3,6,7-tetrahydro-5H- [1,4] oxazino [2,3,4-ij] quinoline-9-carbaldehyde, 3,5-dichloro-4-hydroxybenzaldehyde, 4-hydroxy 3,5-diiodobenzaldehyde, 3-chloro-4-hydroxybenzaldehyde, 5-chloro-3,4-dihydroxybenzaldehyde, 5-bromo-3,4-dihydroxybenzaldehyde, 3-chloro-4-hydroxy-5-methoxybenzaldehyde, 4- Hydroxy-3-iodo-5-methoxybenzaldehyde, 2-bromo-4,5-dihydroxybenzaldehyde, 2-methoxy-1-naphthaldehyde, 4-meth oxy-1-naphthaldehyde, 2-hydroxy-1-naphthaldehyde, 2,4-dihydroxy-1-naphthaldehyde, 4-hydroxy-3-methoxy-1-naphthaldehyde, 2-hydroxy-4-methoxy-1-naphthaldehyde, 3- Hydroxy-4-methoxy-1-naphthaldehyde, 2,4-dimethoxy-1-naphthaldehyde, 3,4-dimethoxy-1-naphthaldehyde, 4-dimethylamino-1-naphthaldehyde, 3-hydroxy-4-nitrobenzaldehyde, 2-hydroxy 3-methoxy-5-nitrobenzaldehyde, 5-nitrovanillin, 2,5-dinitrosalicylaldehyde, 5-bromo-3-nitrosalicylaldehyde, 2-dimethylaminobenzaldehyde, 2-chloro-4-dimethylaminobenzaldehyde, 4-dimethylamino-2-methylbenzaldehyde, 4-diethylamino cinnamic aldehyde, 4-dibutylaminobenzaldehyde, 3-carboxy-4-hydroxybenzaldehyde, 5-carboxyvanillin, 3-carboxy-4-hydroxy-5-methylbenzaldehyde, 3-carboxy-5-ethoxy-4-hydroxybenzaldehyde, 3-carboxy- 4-hydroxybenzaldehyde, 5-carboxyvanillin, 3-carboxy-4-hydroxy-5-methylbenzaldehyde, 3-carboxy-5-ethoxy-4-hydroxybenzaldehyde, 3-allyl 4-hydroxybenzaldehyde, 3-allyl-4-hydroxy-5-methoxybenzaldehyde, 3-allyl-4-hydroxy-5-methylbenzaldehyde, 3-allyl-5-bromo-4-hydroxybenzaldehyde, 3,5-diallyl-4-hydroxybenzaldehyde, 3-allyl-5-carboxy-4-hydroxybenzaldehyde (3-allyl-5-formyl-2-hydroxybenzoic acid), 4-hydroxy-5-methoxyisophthalaldehyde and 3-allyl-4-hydroxy-5-formylbenzaldehyde (5-allyl-4 -hydroxyisophthalaldehyd). Serving one of the Claims 1 to 7 , characterized in that the washing or cleaning agent contains the first bluing agent precursor compound and / or the second bluing agent precursor compound in a total amount of 0.0001 to 50 mmol, in particular from 0.001 to 30 mmol. Serving one of the Claims 1 to 8th , characterized in that the washing or cleaning agent contains the first bluing agent precursor compound and the second bluing agent precursor compound in a molar ratio range of 2: 1 to 1: 2, preferably 1.5 to 1 to 1 to 1.5. Serving one of the Claims 1 to 9 , characterized in that a solution of 2.0 g of the washing or cleaning agent in 1 liter of water has a pH (20 ° C) of 7 to 10, in particular from 7.5 to 9.5, possesses.