DE102017216759A1 - Ductile interlayer bond between ceramic and metallic substrate and process - Google Patents

Ductile interlayer bond between ceramic and metallic substrate and process Download PDF

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DE102017216759A1
DE102017216759A1 DE102017216759.9A DE102017216759A DE102017216759A1 DE 102017216759 A1 DE102017216759 A1 DE 102017216759A1 DE 102017216759 A DE102017216759 A DE 102017216759A DE 102017216759 A1 DE102017216759 A1 DE 102017216759A1
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intermediate layer
metallic
hybrid component
ceramic
substrate
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Robin Blank
Martin Hahn
Ingo Reinkensmeier
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Siemens AG
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12Blades
    • F01D5/28Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • F01D5/288Protective coatings for blades
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/026Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of metals or metal salts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12Blades
    • F01D5/28Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12Metallic interlayers
    • C04B2237/122Metallic interlayers based on refractory metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12Metallic interlayers
    • C04B2237/123Metallic interlayers based on iron group metals, e.g. steel
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • C04B2237/34Oxidic
    • C04B2237/343Alumina or aluminates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32Ceramic
    • C04B2237/38Fiber or whisker reinforced
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40Metallic
    • C04B2237/405Iron metal group, e.g. Co or Ni
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/59Aspects relating to the structure of the interlayer
    • C04B2237/597Aspects relating to the structure of the interlayer whereby the interlayer is continuous but porous, e.g. containing hollow or porous particles, macro- or micropores or cracks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00Manufacture
    • F05D2230/20Manufacture essentially without removing material
    • F05D2230/23Manufacture essentially without removing material by permanently joining parts together
    • F05D2230/232Manufacture essentially without removing material by permanently joining parts together by welding
    • F05D2230/237Brazing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00Manufacture
    • F05D2230/90Coating; Surface treatment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/10Metals, alloys or intermetallic compounds
    • F05D2300/17Alloys
    • F05D2300/175Superalloys
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/60Properties or characteristics given to material by treatment or manufacturing
    • F05D2300/603Composites; e.g. fibre-reinforced
    • F05D2300/6033Ceramic matrix composites [CMC]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/60Properties or characteristics given to material by treatment or manufacturing
    • F05D2300/612Foam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/60Properties or characteristics given to material by treatment or manufacturing
    • F05D2300/613Felt

Abstract

Durch die Anordnung einer metallischen, duktilen Zwischenschicht (7) wie einem metallischen, massiven Substrat (4) und einer äußeren CMC-Komponente (10) können thermische Spannungen zwischen der Keramik und dem Metall vermieden werden.

Figure DE102017216759A1_0000
The arrangement of a metallic, ductile intermediate layer (7) such as a metallic, solid substrate (4) and an outer CMC component (10) thermal stresses between the ceramic and the metal can be avoided.
Figure DE102017216759A1_0000

Description

Die Erfindung betrifft eine Anordnung aus einer Keramik, die auf einem metallischen Substrat angebunden werden soll, bei dem eine duktile Zwischenschicht aus Metall verwendet wird.The invention relates to an arrangement of a ceramic to be bonded to a metallic substrate, wherein a ductile intermediate layer of metal is used.

Keramik wie CMC-Materialien oder Komponenten sind faserverstärkte Matrixen, bei denen keramische Fasern wie Siliziumkarbidfasern, Aluminiumoxidfasern, Mullitfasern und/oder Aluminiumoxidmullitfasern in einer keramischen Matrix wie Siliziumkarbid, Aluminiumoxid, Mullit oder Aluminiumoxidmullit eingebettet sind. Diese Materialien weisen eine hohe Temperaturfestigkeit auf und werden in Gasturbinen bei Einsatz höherer Temperaturen benötigt.Ceramics such as CMC materials or components are fiber-reinforced matrices in which ceramic fibers such as silicon carbide fibers, alumina fibers, mullite fibers and / or alumina mullite fibers are embedded in a ceramic matrix such as silicon carbide, alumina, mullite or alumina mullite. These materials have a high temperature resistance and are required in gas turbines when using higher temperatures.

In der Regel verwendet man keine massiven Bauteile aus CMC, sondern bringt die CMC nur in dem äußeren Bereich auf, so dass das CMC-Bauteil mit einer metallischen Struktur verbunden werden muss.As a rule, one does not use massive CMC components, but applies the CMC only in the outer area, so that the CMC component must be connected to a metallic structure.

Beim Fügen durch Hochtemperaturlöten von Metall und Keramik entstehen thermisch induzierte Spannungen im Bereich der Lötverbindung, durch das unterschiedliche Wärmeausdehnungsverhalten beider Werkstoffe. Diese Spannungen senken die Festigkeit der Verbindung oder führen gar zur Delamination bzw. Zerstörung insbesondere bei faserverstärkten Keramikwerkstoffen (CMCs).When joining by high-temperature soldering of metal and ceramic arise thermally induced stresses in the solder joint, due to the different thermal expansion behavior of both materials. These stresses reduce the strength of the compound or even lead to delamination or destruction, especially in fiber-reinforced ceramic materials (CMCs).

Das Problem wurde bisher durch die Verwendung von duktilen, massiven Zwischenschichten gelöst, die durch elastische oder gar plastische Verformung eine Relaxation der spannungsbehafteten Lötverbindung herbeiführen. Diese Pufferschichten - auf der Basis Cu / Ag basiert weisen aber eine geringe Oxidationsbeständigkeit auf.The problem has been solved by the use of ductile, massive intermediate layers, which cause elastic or even plastic deformation relaxation of the voltage-sensitive solder joint. These buffer layers - based on Cu / Ag based but have a low oxidation resistance.

Es ist daher Aufgabe der Erfindung oben genanntes Problem zu lösen.It is therefore an object of the invention to solve the above-mentioned problem.

Die Aufgabe wird gelöst durch einen Aufbau gemäß Anspruch 1 und durch ein Verfahren nach Anspruch 2.The object is achieved by a structure according to claim 1 and by a method according to claim 2.

Das Problem wird durch eine duktile Zwischenlage aus metallischen Schäumen oder andere metallische zellulare Strukturen gelöst.The problem is solved by a ductile intermediate layer of metallic foams or other metallic cellular structures.

In den Unteransprüchen sind weitere vorteilhafte Maßnahmen aufgelistet, die beliebig miteinander kombiniert werden können, um weitere Vorteile zu erzielen.In the dependent claims further advantageous measures are listed, which can be combined with each other in order to achieve further advantages.

Die Figur zeigt schematisch den erfindungsgemäßen Aufbau.The figure shows schematically the structure according to the invention.

Die Figur und die Beschreibung stellen nur Ausführungsbeispiele der Erfindung dar.The figure and the description represent only embodiments of the invention.

Durch eine regellose Struktur und die intrinsische Verformbarkeit, insbesondere metallischer Fließe können die durch die thermische Ausdehnung auftretenden Relativbewegungen der zu verbindenden Werkstoffe ausgeglichen werden. Das metallische Fließ wird vorzugsweise mit handelsüblichen Loten an die metallische Komponente gelötet werden und vorzugsweise mittels Aktivlöten mit der Keramischen Komponente verbunden werden.Due to a random structure and the intrinsic deformability, in particular metallic flow, the relative movements of the materials to be joined which occur due to the thermal expansion can be compensated. The metallic flux will preferably be soldered to the metallic component with commercially available solders and preferably connected to the ceramic component by means of active soldering.

Die Unterschiede der thermischen Dehnung beim Abkühlen nach dem Lötprozess kann von dem metallischen Fließ durch dessen Verformungsvermögen kompensiert werden ohne das die Lötverbindung gelöst oder die Keramik (bzw. CMC) beschädigt wird.The differences of the thermal expansion during cooling after the soldering process can be compensated by the metallic flow by its deformability without the solder joint dissolved or the ceramic (or CMC) is damaged.

Die metallischen Fließe können aus verschiedensten Materialien hergestellt werden, wie etwa auf Eisen- und Nickelbasis. Dadurch können diese duktilen Zwischenschichten, anders als jede vollmaterialein auf Basis von Kupfer oder Silber, bei hohen Temperaturen eingesetzt werden. Die Fließe sind in verschiedenen Dicken herstellbar, einfach und präzise zu verarbeiten und gut verfügbar.The metallic flows can be made of a variety of materials, such as iron and nickel based. As a result, these ductile interlayers, unlike any solid based on copper or silver, can be used at high temperatures. The flows can be produced in various thicknesses, simple and precise to process and well available.

Auf makroskopischer Ebene weisen die metallischen Fließe die geforderten mechanischen Eigenschaften für die Spannungskompensation auf.At the macroscopic level, the metallic flows have the required mechanical properties for stress compensation.

Die Erfindung ermöglicht die Verbindung von Metall und Keramik auf eine relativ einfache und fertigungstechnisch gut umsetzbare Art und Weise. Diese Verbindung kann bis zu hohen Temperaturen Einsatz finden.The invention allows the connection of metal and ceramic in a relatively simple and manufacturable well implementable way. This compound can be used up to high temperatures.

In der Figur ist ein erfindungsgemäßes Hybridbauteil 1 dargestellt.In the figure is a hybrid component according to the invention 1 shown.

Auf einem metallischen Substrat 4, insbesondere direkt auf dem metallischen Substrat 4, welches im Falle einer Turbinenschaufel einen metallischen Kern insbesondere mit Kühlluftzuführungen aufweist, ist eine duktile, metallische Zwischenschicht 7 zwischen dem metallischen Substrat 4 und der äußeren Keramik bei Komponenten 10 vorhanden.On a metallic substrate 4 , in particular directly on the metallic substrate 4 which in the case of a turbine blade has a metallic core, in particular with cooling air feeds, is a ductile, metallic intermediate layer 7 between the metallic substrate 4 and the outer ceramic in components 10 available.

Das metallische Substrat 4 ist vorzugweise eine kobalt- oder nickelbasierte Laserlegierung.The metallic substrate 4 is preferably a cobalt or nickel based laser alloy.

Die duktile Zwischenlage 7 ist vorzugsweise ein metallisches Fließ, ein metallischer Schaum oder weist andere zellulare, aber auf jeden Fall poröse Strukturen auf.The ductile liner 7 is preferably a metallic flow, a metallic foam or has other cellular, but in any case porous structures.

Das Material der Zwischenlage 7 kann dasselbe sein wie das des Substrats 4 oder ist von dem Material des Substrats 4 verschieden. Verschieden bedeutet, dass zumindest ein anderes Legierungselement mehr oder weniger vorhanden ist oder die Unterschiede in zumindest einem Legierungselement mindestens 10%, insbesondere 20% betragen.The material of the liner 7 may be the same as that of the substrate 4 or is of the material of the substrate 4 different. Different means that at least one other alloying element is more or less present or the differences in at least one alloying element amount to at least 10%, in particular 20%.

Es eignen sich für die Zwischenlage die Werkstoffe 1.4404 (X2CrNiMo17-12-2) und 1.4841 (X15CrNiSi25-21). Neben diesen hochlegierten Stählen sind auch Fließe auf Nickelbasis wie INCONEL 625, Hastelloy X oder auf Kobaltbasis denkbar und insbesondere bei Hochtemperaturanwendungen zielführend.The materials 1.4404 (X2CrNiMo17-12-2) and 1.4841 (X15CrNiSi25-21) are suitable for the intermediate layer. In addition to these high-alloyed steels are also nickel-based flows such as INCONEL 625 , Hastelloy X or cobalt-based conceivable and in particular in high-temperature applications expedient.

Die metallische Zwischenlage 7 wird vorzugsweise durch ein metallisches Lot mit dem Substrat 4 verbunden.The metallic liner 7 is preferably by a metallic solder with the substrate 4 connected.

Vorzugsweise kann durch additive Herstellungsverfahren die Zwischenlage 7 direkt auf dem Substrat 4 aufgebracht und hergestellt werden, dann insbesondere ohne Verwendung von Metalllot. Dies sind Laser-Auftragschweißverfahren oder Selektive Laser Melting oder Selektive Laser Sintering.Preferably, by additive manufacturing process, the intermediate layer 7 directly on the substrate 4 applied and manufactured, then in particular without the use of Metalllot. These are Laser Deposition Welding or Selective Laser Melting or Selective Laser Sintering.

Claims (11)

Hybridbauteil (1), das zumindest aufweist: ein metallisches Substrat (4), auf dem (4) eine duktile Zwischenlage (7) aus Metall aufgebracht ist, insbesondere direkt auf dem Substrat (4), und eine äußere keramische Komponente (10), insbesondere eine äußerste Komponente (10), auf der duktilen Zwischenlage (7), insbesondere direkt auf der duktilen Zwischenlage (7).Hybrid component (1) comprising at least: a metallic substrate (4), on which (4) a ductile intermediate layer (7) made of metal is applied, in particular directly on the substrate (4), and an outer ceramic component (10), in particular an outermost component (10), on the ductile intermediate layer (7), in particular directly on the ductile intermediate layer (7). Verfahren zur Herstellung eines Hybridbauteils (1), bei dem eine metallische, duktile Zwischenlage (7) mit einem metallischen Substrat (4) verbunden wird und eine äußere keramische Komponente (10) mit der Zwischenlage (7) verbunden wird, insbesondere verlötet wird.Method for producing a hybrid component (1), in which a metallic, ductile intermediate layer (7) is connected to a metallic substrate (4) and an outer ceramic component (10) is joined, in particular soldered, to the intermediate layer (7). Hybridbauteil oder Verfahren nach Anspruch 1 oder 2, bei dem das metallische Substrat (4) eine Nickelbasis- oder Kobaltbasis Superlegierung darstellt.Hybrid component or method according to Claim 1 or 2 in which the metallic substrate (4) is a nickel base or cobalt base superalloy. Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüchen 1, 2 oder 3, bei dem die metallische, duktile Zwischenlage (7) ein metallisches Fließ und/oder, einen Schaum und/oder andere zellulare Strukturen aufweist, insbesondere daraus besteht.Hybrid component or method according to one or more of Claims 1 . 2 or 3 in which the metallic, ductile intermediate layer (7) has a metallic flow and / or, a foam and / or other cellular structures, in particular consists thereof. Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüchen 1, 2, 3 oder 4, bei dem die Keramik (10) ein CMC aufweist, insbesondere eine Siliziumkarbidmatrix und Siliziumkarbidfasern aufweist.Hybrid component or method according to one or more of Claims 1 . 2 . 3 or 4 in which the ceramic (10) has a CMC, in particular a silicon carbide matrix and silicon carbide fibers. Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüche 1, 2, 3 oder 4, bei dem die Keramik (10) ein CMC aus Oxidkeramik und Oxidfasern, insbesondere Aluminiumoxidfasern und Aluminiumoxidmatrix aufweist.Hybrid component or method according to one or more of Claims 1 . 2 . 3 or 4 in which the ceramic (10) comprises a CMC of oxide ceramics and oxide fibers, in particular aluminum oxide fibers and aluminum oxide matrix. Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüche 1, 2, 3, 4, 5 oder 6, bei dem die Keramik (10) durch ein Aktivlot mit der metallischen Zwischenlage (7) verbunden ist oder wird.Hybrid component or method according to one or more of Claims 1 . 2 . 3 . 4 . 5 or 6 in which the ceramic (10) is or becomes connected to the metallic intermediate layer (7) by means of an active solder. Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüche 1, 2, 3 oder 4, bei dem die duktile Zwischenlage (7) durch ein additives Verfahren auf dem Substrat (4) hergestellt wurde.Hybrid component or method according to one or more of Claims 1 . 2 . 3 or 4 in which the ductile intermediate layer (7) has been produced by an additive method on the substrate (4). Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüche 1, 2, 3, 4 oder 8, bei dem das Metall der Zwischenlage (7) verschieden ist von dem Metall des Substrats (4).Hybrid component or method according to one or more of Claims 1 . 2 . 3 . 4 or 8th in which the metal of the intermediate layer (7) is different from the metal of the substrate (4). Hybridbauteil oder Verfahren nach einem oder mehreren der Ansprüche 1, 2, 3, 4 oder 8, bei dem das Metall der Zwischenlage (7) gleich dem des Substrats (4) ist.Hybrid component or method according to one or more of Claims 1 . 2 . 3 . 4 or 8th in which the metal of the intermediate layer (7) is equal to that of the substrate (4). Hybridbauteil oder Verfahren, bei dem für die Zwischenlage (7) die Werkstoffe 1.4404 (X2CrNiMo17-12-2) oder 1.4841 (X15CrNiSi25-21) oder hochlegierte Stähle auf Nickelbasis wie INCONEL 625, Hastelloy X oder Kobaltbasislegierungen verwendet werden.Hybrid component or process using (a) material 1.4404 (X2CrNiMo17-12-2) or 1.4841 (X15CrNiSi25-21) or high nickel-base steels such as INCONEL 625, Hastelloy X or cobalt-base alloys for the intermediate layer (7).
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EP2322762A1 (en) * 2009-11-12 2011-05-18 Siemens Aktiengesellschaft Modular turbine component and method for its manufacture
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