DE102017216759A1 - Ductile interlayer bond between ceramic and metallic substrate and process - Google Patents
Ductile interlayer bond between ceramic and metallic substrate and process Download PDFInfo
- Publication number
- DE102017216759A1 DE102017216759A1 DE102017216759.9A DE102017216759A DE102017216759A1 DE 102017216759 A1 DE102017216759 A1 DE 102017216759A1 DE 102017216759 A DE102017216759 A DE 102017216759A DE 102017216759 A1 DE102017216759 A1 DE 102017216759A1
- Authority
- DE
- Germany
- Prior art keywords
- intermediate layer
- metallic
- hybrid component
- ceramic
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
- C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
- C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
- C04B37/026—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of metals or metal salts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
- C04B2237/12—Metallic interlayers
- C04B2237/122—Metallic interlayers based on refractory metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
- C04B2237/12—Metallic interlayers
- C04B2237/123—Metallic interlayers based on iron group metals, e.g. steel
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
- C04B2237/34—Oxidic
- C04B2237/343—Alumina or aluminates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
- C04B2237/38—Fiber or whisker reinforced
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/40—Metallic
- C04B2237/405—Iron metal group, e.g. Co or Ni
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
- C04B2237/59—Aspects relating to the structure of the interlayer
- C04B2237/597—Aspects relating to the structure of the interlayer whereby the interlayer is continuous but porous, e.g. containing hollow or porous particles, macro- or micropores or cracks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/20—Manufacture essentially without removing material
- F05D2230/23—Manufacture essentially without removing material by permanently joining parts together
- F05D2230/232—Manufacture essentially without removing material by permanently joining parts together by welding
- F05D2230/237—Brazing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/90—Coating; Surface treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/10—Metals, alloys or intermetallic compounds
- F05D2300/17—Alloys
- F05D2300/175—Superalloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
- F05D2300/6033—Ceramic matrix composites [CMC]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/612—Foam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/613—Felt
Abstract
Durch die Anordnung einer metallischen, duktilen Zwischenschicht (7) wie einem metallischen, massiven Substrat (4) und einer äußeren CMC-Komponente (10) können thermische Spannungen zwischen der Keramik und dem Metall vermieden werden. The arrangement of a metallic, ductile intermediate layer (7) such as a metallic, solid substrate (4) and an outer CMC component (10) thermal stresses between the ceramic and the metal can be avoided.
Description
Die Erfindung betrifft eine Anordnung aus einer Keramik, die auf einem metallischen Substrat angebunden werden soll, bei dem eine duktile Zwischenschicht aus Metall verwendet wird.The invention relates to an arrangement of a ceramic to be bonded to a metallic substrate, wherein a ductile intermediate layer of metal is used.
Keramik wie CMC-Materialien oder Komponenten sind faserverstärkte Matrixen, bei denen keramische Fasern wie Siliziumkarbidfasern, Aluminiumoxidfasern, Mullitfasern und/oder Aluminiumoxidmullitfasern in einer keramischen Matrix wie Siliziumkarbid, Aluminiumoxid, Mullit oder Aluminiumoxidmullit eingebettet sind. Diese Materialien weisen eine hohe Temperaturfestigkeit auf und werden in Gasturbinen bei Einsatz höherer Temperaturen benötigt.Ceramics such as CMC materials or components are fiber-reinforced matrices in which ceramic fibers such as silicon carbide fibers, alumina fibers, mullite fibers and / or alumina mullite fibers are embedded in a ceramic matrix such as silicon carbide, alumina, mullite or alumina mullite. These materials have a high temperature resistance and are required in gas turbines when using higher temperatures.
In der Regel verwendet man keine massiven Bauteile aus CMC, sondern bringt die CMC nur in dem äußeren Bereich auf, so dass das CMC-Bauteil mit einer metallischen Struktur verbunden werden muss.As a rule, one does not use massive CMC components, but applies the CMC only in the outer area, so that the CMC component must be connected to a metallic structure.
Beim Fügen durch Hochtemperaturlöten von Metall und Keramik entstehen thermisch induzierte Spannungen im Bereich der Lötverbindung, durch das unterschiedliche Wärmeausdehnungsverhalten beider Werkstoffe. Diese Spannungen senken die Festigkeit der Verbindung oder führen gar zur Delamination bzw. Zerstörung insbesondere bei faserverstärkten Keramikwerkstoffen (CMCs).When joining by high-temperature soldering of metal and ceramic arise thermally induced stresses in the solder joint, due to the different thermal expansion behavior of both materials. These stresses reduce the strength of the compound or even lead to delamination or destruction, especially in fiber-reinforced ceramic materials (CMCs).
Das Problem wurde bisher durch die Verwendung von duktilen, massiven Zwischenschichten gelöst, die durch elastische oder gar plastische Verformung eine Relaxation der spannungsbehafteten Lötverbindung herbeiführen. Diese Pufferschichten - auf der Basis Cu / Ag basiert weisen aber eine geringe Oxidationsbeständigkeit auf.The problem has been solved by the use of ductile, massive intermediate layers, which cause elastic or even plastic deformation relaxation of the voltage-sensitive solder joint. These buffer layers - based on Cu / Ag based but have a low oxidation resistance.
Es ist daher Aufgabe der Erfindung oben genanntes Problem zu lösen.It is therefore an object of the invention to solve the above-mentioned problem.
Die Aufgabe wird gelöst durch einen Aufbau gemäß Anspruch 1 und durch ein Verfahren nach Anspruch 2.The object is achieved by a structure according to claim 1 and by a method according to claim 2.
Das Problem wird durch eine duktile Zwischenlage aus metallischen Schäumen oder andere metallische zellulare Strukturen gelöst.The problem is solved by a ductile intermediate layer of metallic foams or other metallic cellular structures.
In den Unteransprüchen sind weitere vorteilhafte Maßnahmen aufgelistet, die beliebig miteinander kombiniert werden können, um weitere Vorteile zu erzielen.In the dependent claims further advantageous measures are listed, which can be combined with each other in order to achieve further advantages.
Die Figur zeigt schematisch den erfindungsgemäßen Aufbau.The figure shows schematically the structure according to the invention.
Die Figur und die Beschreibung stellen nur Ausführungsbeispiele der Erfindung dar.The figure and the description represent only embodiments of the invention.
Durch eine regellose Struktur und die intrinsische Verformbarkeit, insbesondere metallischer Fließe können die durch die thermische Ausdehnung auftretenden Relativbewegungen der zu verbindenden Werkstoffe ausgeglichen werden. Das metallische Fließ wird vorzugsweise mit handelsüblichen Loten an die metallische Komponente gelötet werden und vorzugsweise mittels Aktivlöten mit der Keramischen Komponente verbunden werden.Due to a random structure and the intrinsic deformability, in particular metallic flow, the relative movements of the materials to be joined which occur due to the thermal expansion can be compensated. The metallic flux will preferably be soldered to the metallic component with commercially available solders and preferably connected to the ceramic component by means of active soldering.
Die Unterschiede der thermischen Dehnung beim Abkühlen nach dem Lötprozess kann von dem metallischen Fließ durch dessen Verformungsvermögen kompensiert werden ohne das die Lötverbindung gelöst oder die Keramik (bzw. CMC) beschädigt wird.The differences of the thermal expansion during cooling after the soldering process can be compensated by the metallic flow by its deformability without the solder joint dissolved or the ceramic (or CMC) is damaged.
Die metallischen Fließe können aus verschiedensten Materialien hergestellt werden, wie etwa auf Eisen- und Nickelbasis. Dadurch können diese duktilen Zwischenschichten, anders als jede vollmaterialein auf Basis von Kupfer oder Silber, bei hohen Temperaturen eingesetzt werden. Die Fließe sind in verschiedenen Dicken herstellbar, einfach und präzise zu verarbeiten und gut verfügbar.The metallic flows can be made of a variety of materials, such as iron and nickel based. As a result, these ductile interlayers, unlike any solid based on copper or silver, can be used at high temperatures. The flows can be produced in various thicknesses, simple and precise to process and well available.
Auf makroskopischer Ebene weisen die metallischen Fließe die geforderten mechanischen Eigenschaften für die Spannungskompensation auf.At the macroscopic level, the metallic flows have the required mechanical properties for stress compensation.
Die Erfindung ermöglicht die Verbindung von Metall und Keramik auf eine relativ einfache und fertigungstechnisch gut umsetzbare Art und Weise. Diese Verbindung kann bis zu hohen Temperaturen Einsatz finden.The invention allows the connection of metal and ceramic in a relatively simple and manufacturable well implementable way. This compound can be used up to high temperatures.
In der Figur ist ein erfindungsgemäßes Hybridbauteil
Auf einem metallischen Substrat
Das metallische Substrat
Die duktile Zwischenlage
Das Material der Zwischenlage
Es eignen sich für die Zwischenlage die Werkstoffe 1.4404 (X2CrNiMo17-12-2) und 1.4841 (X15CrNiSi25-21). Neben diesen hochlegierten Stählen sind auch Fließe auf Nickelbasis wie INCONEL
Die metallische Zwischenlage
Vorzugsweise kann durch additive Herstellungsverfahren die Zwischenlage
Claims (11)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017216759.9A DE102017216759A1 (en) | 2017-09-21 | 2017-09-21 | Ductile interlayer bond between ceramic and metallic substrate and process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017216759.9A DE102017216759A1 (en) | 2017-09-21 | 2017-09-21 | Ductile interlayer bond between ceramic and metallic substrate and process |
Publications (1)
Publication Number | Publication Date |
---|---|
DE102017216759A1 true DE102017216759A1 (en) | 2019-03-21 |
Family
ID=65526932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE102017216759.9A Withdrawn DE102017216759A1 (en) | 2017-09-21 | 2017-09-21 | Ductile interlayer bond between ceramic and metallic substrate and process |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE102017216759A1 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5069978A (en) * | 1990-10-04 | 1991-12-03 | Gte Products Corporation | Brazed composite having interlayer of expanded metal |
EP1475567A1 (en) * | 2003-05-08 | 2004-11-10 | Siemens Aktiengesellschaft | Layered structure and method to produce such a layered structure |
US20080274362A1 (en) * | 2007-05-01 | 2008-11-06 | Kramer Daniel P | Method of joining metals to ceramic matrix composites |
EP2322762A1 (en) * | 2009-11-12 | 2011-05-18 | Siemens Aktiengesellschaft | Modular turbine component and method for its manufacture |
DE102016214742A1 (en) * | 2016-08-09 | 2018-02-15 | Siemens Aktiengesellschaft | Method for joining materials and composite material |
-
2017
- 2017-09-21 DE DE102017216759.9A patent/DE102017216759A1/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5069978A (en) * | 1990-10-04 | 1991-12-03 | Gte Products Corporation | Brazed composite having interlayer of expanded metal |
EP1475567A1 (en) * | 2003-05-08 | 2004-11-10 | Siemens Aktiengesellschaft | Layered structure and method to produce such a layered structure |
US20080274362A1 (en) * | 2007-05-01 | 2008-11-06 | Kramer Daniel P | Method of joining metals to ceramic matrix composites |
EP2322762A1 (en) * | 2009-11-12 | 2011-05-18 | Siemens Aktiengesellschaft | Modular turbine component and method for its manufacture |
DE102016214742A1 (en) * | 2016-08-09 | 2018-02-15 | Siemens Aktiengesellschaft | Method for joining materials and composite material |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3345219C1 (en) | Soldering foil for the tension-free connection of ceramic bodies with metal | |
EP3468740B1 (en) | Method of joining materials using a grid structure achieved by additive manufacturing | |
EP2461936B1 (en) | Method of repairing a turbine component | |
EP2456957B1 (en) | Method for coating of turbine blades | |
DE602004006437T2 (en) | ALLOY FOR THE SOLDERING AND USE THEREOF | |
DE102013113736B4 (en) | Method for producing a metal-ceramic substrate | |
DE112014006121T5 (en) | A clad aluminum alloy material and manufacturing method therefor, and the heat exchanger using the clad aluminum alloy material and manufacturing method therefor | |
EP2683523A1 (en) | Nickel-based brazing foil, method for producing a brazing foil, object having a braze joint, and method for brazing | |
DE102013208350A1 (en) | MANUFACTURING PROCESS FOR A COOLER | |
DE10043105A1 (en) | Production of a connection between an insert and a cast metal material comprises coating the insert with a thin layer of a metallic material and casting the cast metal material against the coated surface of the insert | |
US3854194A (en) | Liquid interface diffusion method of bonding titanium and/or titanium alloy structure and product using nickel-copper, silver bridging material | |
DE60211235T2 (en) | Substrate plate for semiconductors and for power modules | |
DE102016119662B4 (en) | METHOD OF WELDING CLAD OVER OPENINGS | |
DE2808106C2 (en) | Process for the production of a solid connection between parts made of stainless steel or superalloy | |
DE3316807A1 (en) | HARD SOLDER ALLOY FOR JOINING OXIDE CERAMICS UNDER OR WITH METALS | |
DE102017216759A1 (en) | Ductile interlayer bond between ceramic and metallic substrate and process | |
DE102010051534A1 (en) | Forming an adapter for connecting blade to rotor base body of turbomachine, comprises applying material layer on connecting surface of blade to form first adapter portion and applying second material on first adapter portion | |
EP3717236A1 (en) | Method for producing a semi-finished metal product, method for producing a metal-ceramic substrate, and metal-ceramic substrate | |
DE10239416B4 (en) | Process for the preparation of a ceramic layer composite body | |
DE102009048957B4 (en) | A method of fusion welding a single crystal workpiece with a polycrystalline workpiece and rotor | |
DE102009051950A1 (en) | Connection between a thermoelectric element and a heat exchanger | |
EP1279457A2 (en) | Manufacturing method of sealing elements | |
DE102017200749A1 (en) | Layer system with two intermediate layers and methods | |
DE102016214208B4 (en) | Method of making a channel structure and component | |
DE102020000913A1 (en) | Lead-free solder foil |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R163 | Identified publications notified | ||
R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |