DE102016220085A1 - odor-reducing body care products - Google Patents

Abstract

Cosmetic compositions containing in a cosmetically acceptable vehicle at least one metal organic framework (MOF) are capable of effectively reducing body odor. Thus, a variety of cosmetic products can be provided with odor-reducing properties. In deodorants, an effective formulation without Alumiumhalogenide is possible.

Description

The invention relates to preparations for cosmetic use on the human body that reduce odors, in particular body odor.

Overall, most body odors are perceived as unpleasant. As a body odor, all the scentable body exhalations of people on the skin and in the broader sense of other body orifices, such as bad breath, or by excrement (urine, faeces, flatus) caused odors referred. The most noticeable is usually the smell of sweat, with the vast majority of the secretions, especially their decomposition products, the smell of apocrine sweat glands, sitting mainly in the armpits. In the bacterial decomposition of the substances contained in axillary sweat, among others so-called precursors for high-reaching short-chain linear and / or branched and / or saturated and / or unsaturated fatty acids and / or sulfanyl alcohols and endogenous fats and proteins, odors arise which are unpleasant and often even be perceived as repugnant.

Mainly responsible for the body odor, especially for the sweat odor, are unsaturated or hydroxy-branched fatty acids, such as 3-methyl-2-hexanoic acid or 3-hydroxy-3-methylhexanoic acid, or sulfanyl alcohols such as 3-methyl-sulfanylhexan-1-ol. The body odor itself is influenced by different bacteria that represent the skin flora. These have enzymes that decompose the precursors of the odorous substances and thus release body odor. These include so-called lipases, which degrade the so-called fatty acids into small molecules, such as butanoic acid (butyric acid). Propanoic acid (propionic acid) is also a common component of sweat. This arises when amino acids are degraded by so-called propionic acid bacteria. Other enzymes may include: aminoacylase, cystathionine β-lyase, lipid peroxidase, arylsulfatase, β-glucuronidase, 5α-reductase and others.

In order to reduce perceptible body odor, different approaches are pursued. These range from perfuming to deodorization to antiperspirants that reduce sweat secretion. During perfuming, bad odors are drowned out, usually with perfume oils. These ensure that malodors are only noticeable to humans after a certain period of time. However, allergic reactions to individual components of different formulations are increasing today, including perfume oils. There is therefore also a need for formulations with the lowest possible content of perfume oils. In addition, it is desirable not to drown out malodors, but to at least partially and preferably completely reduce or avoid them, i. absorb and thus remove from the body.

Deodorant agents are odor absorbers, deodorizing ion exchangers, germ-inhibiting agents, prebiotic components and enzyme inhibitors or, more preferably, combinations of said active ingredients. These act either via the absorption or adsorption of odorous compounds or intervene in the enzymatic decomposition process, which leads to the odors.

Antiperspirants are predominantly aluminum chlorohydrates or aluminum zirconium chlorohydrates. They have a narrowing effect on the sweat glands and reduce or stop perspiration. However, there is an increasing consumer interest in aluminum-free cosmetics.

The object of the present invention is therefore to provide a cosmetic composition which is capable of effectively reducing body odor.

Surprisingly, it has been found that MOFs (Metal Organic Frameworks) are able to include off-odors and thus reduce the odor strength of the off-odors or even completely avoided.

The present invention therefore relates to cosmetic compositions containing, in a cosmetically acceptable carrier, at least one Metal Organic Framework (MOF).

Cosmetic compositions are used for the care of the body or the maintenance, restoration or improvement of the beauty of the human body. In this case, the beauty of the body also means its fragrance.

• • Mittel zur Reinigung, Pflege und zum Schutz: Dies sind beispielsweise Reinigungsmittel zum Waschen, Baden und Duschen (Seife, Duschgel und Badezusätze); Pflegeprodukte für Gesicht, Körper, Hände oder Füße (Hautcreme, Lotion, Körpermilch, Gel, Maske); Rasier- und Haarentfernungsmittel (Rasierschaum, Rasierseife, Rasierwasser); Produkte zum Schutz vor UV-Strahlung und Mückenstichen (Sonnenmilch, Sonnencreme, Repellent).
• • Mittel zur Zahn- und Mundpflege: Hierzu gehören beispielsweise Zahnpasta, Mundwasser, Zahnseide, Zungenreiniger und Mittel zur Pflege des Zahnersatzes (Reinigung, Haftung).
• • Mittel zur Haarbehandlung: Zu diesem Segment zählen Haarwaschmittel (Shampoo), Haarverformungsmittel (Dauerwelle), Haarfestiger, Haarfärbemittel, Blondiermittel, Haarpflegmittel bzw. Haarstyling Mittel
• • Haarfarben
• • Mittel für Dekorative Anwendungen: Typische Vertreter dieses Segmentes sind Gesichts-Make-up (Rouge), Augenpflegemittel (Mascara, Lidschatten), Lippenpflegemittel (Lippenstift, Lipgloss), Nagellack sowie Selbstbräunungsmittel.
• • Mittel zur Beeinflussung des Körpergeruchs: Hierzu gehören Parfüm, Eau de Toilette, Deodorant und Antitranspirant.

Depending on the type of odor that is to be reduced (sweat, bad breath, bad odor due to malodorous adhesions to the skin or hair, etc.) and depending on the site and type of application means of the invention may belong to different groups, for example

• • cleansing, care and protection products such as detergents for washing, bathing and showering (soap, shower gel and bath products); Care products for the face, body, hands or feet (skin cream, lotion, body milk, gel, mask); Shaving and hair removing preparations (shaving cream, shaving soap, aftershave); Products for protection against UV radiation and mosquito bites (sunscreen, sunscreen, repellent).
• • Dental and oral care products: These include, for example, toothpaste, mouthwash, dental floss, tongue cleaners, and denture care products (cleaning, adhesion).
• • Hair treatment products: This segment includes shampoo, permanent hair conditioner, hair fixative, hair dye, bleach, hair care and hair styling products
• • hair colors
• • Means for decorative applications: Typical representatives of this segment are facial make-up (rouge), eye care (mascara, eyeshadow), lip balm (lipstick, lip gloss), nail varnish and self-tanning.
• • Body Odor Control: These include perfume, toilet water, deodorant and antiperspirant.

Particularly preferred are compositions according to the invention for use under armpit with effect against body odor and / or underarm wetness.

Regardless of the nature of the composition according to the invention, preference is given to those cosmetic compositions which, based on their weight, contain from 0.00001 to 10% by weight of Metal Organic Framework (s) (MOFs).

Metal-organic frameworks (MOFs) are microporous crystalline materials that are built up of metal nodes, the so-called SBUs (Secondary Building Units) and organic molecules (linkers), as connecting elements between the nodes. One-, two- and three-dimensional networks can be formed, one- and two-dimensional structures being more likely to be regarded as coordination polymers since they have no pores like the three-dimensional structures. The pores are filled after synthesis with guest molecules (eg, solvents or unreacted linkers). By removing the guest molecules, the pores can be made accessible, but this also causes some networks to collapse.

For possible applications as catalysts, the large internal surface area (up to more than 4500 m ² / g in the MOF-177) is important. The pore size can be precisely determined by the size of the organic ligands, so that only reactants of a certain size fit into it. As a result, a high selectivity can be expected.

In contrast to zeolites, ie inorganic crystals with pores of similar size, MOF are less temperature resistant. However, it is expected that the diverse possibilities of organic chemistry will result in a greater variety of materials than zeolites, and also the lower mass density will be beneficial for some applications.

The preparation of the MOFs is usually in the form of particles containing MOF. These particles are obtained by gelling a MOF gel Precusorlösung and subsequent drying, and the particles produced are in the form of a dried gel, in particular a xerogel or an airgel.

Advantageously, the gelation takes place without additives of binder. In particular, no silanes, silicates, graphite, aluminum-containing components, kaolin (or other ceramic binders), polysiloxanes, polymethyl methacrylate, polyvinyl alcohol, polyacrylic acid, starch (or other synthetic or natural polymers) are added.

The MOF gel Precusorlösung contains at least one metal salt, at least one linker, preferably an organic linker, and at least one, preferably polar, solvent.

The metal salt in the MOF gel Precusorlösung is preferably selected from salts of the metals Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi and lanthanides, preferably Fe, Al, Zn, Cu, Ni, Pd, Pt, Ru, Rh, Co, Ce and La. Preferred metal ions are selected from Mg ²⁺ , Ca ²⁺ , Sr ²⁺ , Ba ²⁺ , Sc ³⁺ , Y ³⁺ , Ti ⁴⁺ , V ⁴⁺ , V ³⁺ , V ²⁺ , Nb ³⁺ , Ta ³⁺ , Cr ³⁺ , Mo ³⁺ , W ³⁺ , Mn ³⁺ , Mn ²⁺ , Re ³⁺ , Re ²⁺ , Fe ³⁺ , Fe ²⁺ , Ru ²⁺ , Os ³⁺ , Os ²⁺ , Co ³⁺ , Co ²⁺ , Rh ²⁺ , Rh ⁺ , Ir ²⁺ , Ir ⁺ , Ni ²⁺ , Ni ⁺ , Pd ²⁺ , Pd ⁺ , Pt ²⁺ , Pt ⁺ , Cu ²⁺ , Cu ⁺ , Ag ⁺ , Au ⁺ , Zn ²⁺ , Cd ²⁺ , Hg ²⁺ , Al ³⁺ , Ga ³⁺ , In ³⁺ , Tl ³⁺ , Si ⁴⁺ , Si ²⁺ , Ge ⁴⁺ , Ge ²⁺ , Sn ⁴⁺ , Sn ²⁺ , Pb ⁴⁺ , Pb ²⁺ , As ⁵⁺ , As ³⁺ , As ⁺ , Sb ⁵⁺ , Sb ³⁺ , Sb ⁺ , Bi ⁵⁺ , Bi ³⁺ , Bi ⁺ , Ce ³⁺ , Ce ⁴⁺ and La ³⁺ .

Metal salts of the metals are particularly preferably selected from Fe (as Fe ³⁺ or Fe ²⁺ ), Al (as Al ³⁺ ) and Cu (as Cu ²⁺ or Cu ⁺ ), preferably as nitrate, acetate, sulfate or halide.

As a metallic component (metal center), the MOF most preferably comprises aluminum, titanium, zirconium, iron, zinc, bismuth or oxoclusters, hydroxo clusters, hydroxyoxy clusters or mixtures thereof. Most preferably, the MOF comprises aluminum and / or iron. Accordingly, cosmetic compositions according to the invention are preferred in which the metal organic framework contains as metallic component aluminum, titanium, zirconium, iron, zinc, bismuth or oxo cluster, hydroxo clusters, hydroxyoxy clusters or mixtures thereof.

As already mentioned, the linker in the MOF gel precursor solution is preferably an organic linker.

Cosmetic compositions preferred according to the invention are characterized in that the organic ligand (s) (linker) of the Metal Organic Framework is / are selected from linkers of the formulas (Li-1) to (Li-36)

in welchen R¹, R², R³ und R⁴ jeweils unabhängig voneinander-H, -COOH, -COO^-, -OH oder -NH₂ sind.Preferably, ligands of the type HOOC-A-COOH, wherein A is selected from

in which R ¹ , R ² , R ³ and R ^{4 are} each independently H, -COOH, -COO ^- , -OH or -NH ₂ .

wobei R¹ R², R³ und R⁴ in der allgemeinen Formel (Li) unabhängig voneinander für -H, -COOH, - COO^-, -OH oder -NH₂ stehen. The ligand (organic bridging molecule, linker) of the MOF is most preferably selected from the following general formula (Li)

wherein R ¹ R ² , R ³ and R ⁴ in the general formula (Li) are independently -H, -COOH, - COO ^- , -OH or -NH ₂ .

Most preferably, the organic ligand of the MOF is selected from 1,4-benzenedicarboxylic acid (BDC), 1,3,5-benzenetricarboxylic acid (BTC), 2-amino-1,4-benzenedicarboxylic acid (ABDC), fumaric acid, the one-two- or trivalent anions or mixtures thereof. According to the invention, a MOF may have several different organic ligands or only one organic ligand.

wobei R¹ bis R⁴ in der allgemeinen Formel (Li) unabhängig voneinander für-H, -COOH, -COO^-, - OH oder -NH₂ stehen.Cosmetic compositions preferred according to the invention are characterized in that the organic ligand (s) of the Metal Organic Framework is / are selected from the general formula (Li)

wherein R ¹ to R ⁴ in the general formula (Li) are independently -H, -COOH, -COO ^- , - OH or -NH ₂ .

In the synthesis of the MOFs, the precursor mixtures may contain individual linkers, but also mixtures of linkers. In addition, a mixture of linkers with so-called co-linkers is possible.

Preferred co-linkers are selected from polar substituted aromatic dicarboxylic acids, in particular 5-substituted isophthalic acid. Preferred polar substituents are selected from amino, hydroxy, nitro groups and halides, in particular bromide. Particularly preferred co-linkers are selected from 5-aminoisophthalic acid, 5-hydroxyisophthalic acid, 5-nitroisophthalic acid, 5-cyanoisophthalic acid and 5-bromoisophthalic acid.

Cosmetic compositions preferred according to the invention are therefore characterized in that the Metal Organic Framework (MOF) additionally contains co-linkers, preferred co-linkers being selected from those of the formulas (CoLi-1) to (CoLi-5):

The Co. linkers are also ionically bound in the MOFs via the carboxylate groups, ie they are not present as isolated molecules.

Particularly preferred MOFs are listed in the table below with regard to the metal ions, linkers and any co-linkers present:

The concentration of metal salt in the MOF gel precursor solution is preferably in the range from 0.01 mol / l to 10 mol / l, preferably from 0.05 to 5 mol / l, particularly preferably from 0.1 to 2 mol / l. The concentration of linker in the MOF gel precursor solution is preferably in the range 0.01 mol / l to 10 mol / l, preferably 0.05 to 5 mol / l, particularly preferably 0.1 to 2 mol / l. The concentration of mixtures of linkers and co-linkers in the MOF gel precursor solution is preferably in the range from 0.01 mol / l to 10 mol / l, preferably from 0.05 to 5 mol / l, particularly preferably from 0.1 to 2 minor.

The preparation of the MOFs from the precursor solution can be carried out, for example, by dropping it into a fluid immiscible with the solution (preferably silicone oil). In this case, the duration of the gelation can be controlled by the temperature of the fluid. This temperature is usually between -20 ° C (very slow gelation) and 78 ° C (fast gelation) The temperature is generally chosen below the boiling point of the solvent used. The gelled MOF gel beads thus formed are then separated from the immiscible fluid, washed and dried.

Advantageously, all substances that are required for the preparation are already present in the precursor solution. The reaction to the MOF and the solidification of the gel set in due to a temperature increase and in a short time. The immiscible fluid is used exclusively for shaping (droplet formation). In addition to a faster reaction rate, this offers the advantages of a definable particle size adjustment, the possibility of using gases as immiscible fluid (for example in a spray tower) and the possibility of circulating the immiscible fluid without having to clean it (ecological and economical advantage). Advantageously, such a process can be carried out at atmospheric pressure.

This process variant produces a particle in which the MOFs are present in the form of an airgel or xerogel. An airgel is preferably produced by drying with supercritical carbon dioxide or other supercritical medium. The xerogel is obtained by a common drying (preferably at 40 ° C to 100 ° C).

The gelation of the MOF precursor solution can also be carried out by gelling in pores of a macroporous matrix. For this, the MOF Precusorlösung is poured into a macroporous matrix, gels there and fills the pores (almost) out. The macroporous matrix is preferably completely filled with the MOF precursor solution. The gelation is preferably carried out by incubation at temperatures between -40 and 150 ° C, preferably 20 to 120 ° C, particularly preferably 20 to 80 ° C. The higher the temperature, the faster the gelation. The incubation time is preferably at least 1 second and more preferably at least 2 Hours, and preferably not more than 72 hours. In principle, there are no limits to the incubation time, but for economic reasons it is preferably up to 70 hours, more preferably up to 40 hours. Subsequently, the formed gel is preferably washed and dried, thereby reducing the size of the particles. Optionally, before or after drying, the gels or particles are washed to remove unreacted starting materials which might otherwise clog the pores. The drying takes place (depending on the solvent used) preferably at temperatures between 10 and 160 ° C, preferably 30 to 80 ° C under atmospheric pressure or vacuum After drying, the particles are separated from the matrix.

The MOF are preferably incorporated as particles in the cosmetic compositions according to the invention. The particle size is preferably 2 to 100 .mu.m, in particular 5 to 70 .mu.m, preferably 10 to 50 microns.

The particles are preferably binder-free. They preferably contain less than 1% by weight, preferably less than 0.1% by weight, of binder. In particular, they contain no silanes, silicates, graphite, aluminum-containing components, kaolin (or other ceramic binders), polysiloxanes, polymethyl methacrylate, polyvinyl alcohol, polyacrylic acid, starch (or other synthetic or natural polymers) or only traces of these components, preferably less than 1 wt. %> preferably below 0.1% by weight (based on the particle weight and the sum of these components).

The particles are preferably microporous and / or mesoporous, ie the pores preferably have a diameter of <2 nm or <50 nm. The micropore volume of the particles is preferably 0.1-6 cm ³ / g, particularly preferably 0.3-2 , 3 cm ³ / g. The total pore volume of the particles is preferably 0.1-20 cm ³ / g, particularly preferably 0.5-10 cm ³ / g. The BET surface area is preferably in the range 50-3000 m ² / g, more preferably 700-2400 m ² / g. The determination of these parameters is preferably carried out by means of nitrogen adsorption (in particular by the BET method according to DIN 66131 ).

As already mentioned, the agents according to the invention can be formulated for different cosmetic applications. Accordingly, in addition to the cosmetic carrier and the MOF (s), they contain other ingredients depending on the nature of the agent.

An important field of application of the present invention are deodorizing or antiperspirant agents. In combination with antiperspirants, the odor-reducing effect of the MOFs and the antiperspirant activity of the antiperspirant active ingredients can complement each other very well.

Antiperspirant active ingredients which are preferred according to the invention are selected from the aluminum chlorohydrates, in particular the aluminum chlorohydrates having the general formula [Al ₂ (OH) ₅ Cl ▪ 2-3 H ₂ O] _n , which may be present in unactivated or in activated (depolymerized) form Further, aluminum sesquichlorohydrate, aluminum chlorohydrex-propylene glycol (PG) or polyethylene glycol (PEG), aluminum sesquichlorohydrex PG or PEG, aluminum PG-dichlorhydrex or aluminum PEG-dichlorhydrex, aluminum hydroxide further selected from the aluminum zirconium chlorohydrates such as aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate , Aluminum zirconium octachlorohydrate, aluminum zirconium chlorohydrate glycine complexes such as aluminum zirconium trichlorohydrex glycine, aluminum zirconium tetrachlorohydrex glycine, aluminum zirconium pentachlorohydrex glycine, aluminum zirconium octachlorohydrex glycine, potassium aluminum sulfate (KAl (SO ₄ ) ₂ ▪ 12H ₂ O, alum), aluminum undecylenoyl collagen amino acid, sodium aluminum lactate + aluminum sulfate, sodium aluminum chlorhydroxylactate, aluminum bromohydrate, aluminum chloride, the complexes of zinc and sodium salts, the complexes of lanthanum and cerium, the aluminum salts of lipoamino acids, aluminum sulfate, aluminum lactate, aluminum chlorohydrate allantoinate, sodium aluminum chlorhydroxylactate, Zinc chloride, zinc sulfocarbolate, zinc sulfate and zirconium chlorohydrate. According to the invention, water solubility is understood as meaning a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the antiperspirant active are soluble in 95 g of water at 20 ° C. The antiperspirant active ingredients can be used as aqueous solutions.

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one antiperspirant active ingredient is present in a total amount of 3 to 25 wt.%, Preferably 5 to 22 wt.% And in particular 10 to 20 wt. contained, based on the total weight of the active substance in the overall composition.

In a particularly preferred embodiment, the composition contains an astringent aluminum salt, in particular aluminum chlorohydrate, which is, for example, in powder form as Micro ^Dry® Ultrafine from Reheis, in the form of an aqueous solution as Locron ^® L from Clariant, as Chlorhydrol ^® and is marketed in activated form as Reach ^® 501 from Reheis. Under the name ^Reach® 301 an aluminum sesquichlorohydrate from Reheis is offered, which is likewise particularly preferred. The use of aluminum zirconium tetrachlorohydrex glycine complexes, which are, for example, by Reheis under the name Rezal ^® 36G commercially, may be particularly preferred according to the invention.

In a further particularly preferred embodiment, the compositions according to the invention can contain both at least one deodorant and at least one antiperspirant active ingredient.

As already mentioned, halides and / or hydroxy halides of aluminum and / or zirconium in combination with the acidic pH of these antiperspirants may cause unpleasant skin reactions in some users. In addition, the use of the aforementioned antiperspirant compounds can lead to staining on clothing.

The term "halides and / or hydroxyhalides of aluminum and / or zirconium" in the context of the present invention, in particular chlorides, bromides and iodides of aluminum and zirconium and compounds of the formulas Al (OH) _y X and Zr (OH) _z X understood, where X in the aforementioned formulas is a halide ion.

For sensitive users it is therefore appropriate to formulate agents according to the invention without such compounds. Cosmetic compositions preferred according to the invention are characterized in that they contain no halides and / or hydroxy halides of aluminum and / or zirconium.

The cosmetic compositions of the invention may contain at least one deodorant active ingredient.

Deodorant active ingredients which are preferred according to the invention are odor absorbers, deodorizing ion exchangers, germ-inhibiting agents, prebiotic components and enzyme inhibitors or, particularly preferred, combinations of said active substances.

Silicates serve as odor absorbers, which at the same time advantageously support the rheological properties of the composition according to the invention. The silicates which are particularly preferred according to the invention include, in particular, phyllosilicates and, among these, in particular montmorillonite, kaolinite, IIit, beidellite, nontronite, saponite, hectorite (also hydrophobically modified), bentonite, smectite and talcum. Other preferred odor absorbers are, for example, zeolites, Zinkricinoleat, cyclodextrins, certain metal oxides, such as. As alumina, and chlorophyll. They are preferably used in an amount of 0.1-10% by weight, more preferably 0.5-7% by weight and most preferably 1-5% by weight, based in each case on the total composition.

According to the invention, germ-inhibiting or antimicrobial active ingredients are understood as meaning those active substances which reduce the number of skin germs participating in the formation of the odor or inhibit their growth. These organisms include, among others, various species from the group of staphylococci, the group of Corynebacteria, anaerococci and micrococci.

Preferred antimicrobial or antimicrobial agents according to the invention are in particular organohalogen compounds and halides, quaternary ammonium compounds, a number of plant extracts and zinc compounds. These include triclosan, chlorhexidine and chlorhexidine gluconate, 3,4,4'-trichlorocarbanilide, bromochlorophene, dichlorophen, chlorothymol, chloroxylenol, hexachlorophene, dichloro-m-xylenol, dequalinium chloride, domiphenbromide, ammonium phenolsulfonate, benzalkonium halides, benzalkonium cetyl phosphate, benzalkonium saccharinates, benzethonium chloride, cetylpyridinium chloride, Laurylpyridinium chloride, laurylisoquinolinium bromide, methylbenzethonium chloride. Furthermore, phenol, phenoxyethanol, benzylheptanol, disodium dihydroxyethylsulfosuccinylundecylenate, sodium bicarbonate, zinc lactate, sodium phenolsulfonate and zinc phenolsulfonate, ketoglutaric acid, terpene alcohols such as. As farnesol, chlorophyllin copper complexes, α-monoalkyl glycerol ether with a branched or linear saturated or unsaturated, optionally hydroxylated C ₆ - C ₂₂ alkyl, particularly preferably α- (2-ethylhexyl) glycerol ether, commercially available as Sensiva ^® SC 50 (ex Schülke & Mayr), carboxylic esters of mono-, di- and triglycerin (eg glycerol monolaurate, diglycerol monocaprinate), lantibiotics and plant extracts (eg green tea and components of lime blossom oil).

Further preferred deodorant active substances are selected from so-called prebiotic active components, which according to the invention are to be understood as meaning those components which inhibit only or at least predominantly the odor-causing germs of the skin microflora, but not the desired ones, that is to say the non-odor-causing germs belonging to a healthy skin microflora. Explicit examples of this are conifer extracts, in particular from the group of Pinaceae, and plant extracts from the group of Sapindaceae, Araliaceae, Lamiaceae and Saxifragaceae, in particular extracts from Picea spp., Paullinia sp., Panax sp., Lamium album or Ribes nigrum and mixtures thereof Substances, with.

Further preferred deodorant active ingredients are selected from the germ-inhibiting active perfume oils and Deosafe ^® -Parfümölen that, Haarmann and Reimer, by the company Symrise previously available.

The enzyme inhibitors include substances which inhibit the enzymes responsible for the sweat decomposition, in particular arylsulfatase, β-glucuronidase, aminoacylase, cystathionine β-lyase, esterases, lipases and / or lipoxigenase, e.g. As trialkyl, especially triethyl, benzylheptanol, C ₃ -C ₁₀ diols or zinc glycinate.

Preferred deodorant compositions according to the invention are characterized in that the at least one deodorant active ingredient is selected from arylsulfatase inhibitors, β-glucuronidase inhibitors, aminoacylase inhibitors, cystathionine-β-lyase inhibitors, esterase inhibitors, lipase inhibitors and lipoxigenase inhibitors. Inhibitors, α-Monoalkylglycerinethern with a branched or linear saturated or unsaturated, optionally hydroxylated C ₆ - C ₂₂ alkyl, especially α- (2-ethylhexyl) glycerol ether, phenoxyethanol, germ-inhibiting perfume oils, Deosafe ^® -Parfümölen (Deosafe ^® is a registered Trademark of the company Symrise, formerly Haarmann & Reimer), prebiotic active, Trialkylcitronensäureestem, especially triethyl citrate, drugs that reduce the number of participating in the odor skin germs from the group of staphylococci, corynebacteria, anaerococci and micrococci or inhibit their growth, zinc compounds, in particular zinc phenolsulfonate, zinc citrate or gluconate and zinc ricinoleate, organohalogen compounds, in particular triclosan, chlorhexidine, chlorhexidine gluconate and benzalkonium halides, quaternary ammonium compounds, in particular cetylpyridinium chloride, odor absorbers, in particular silicates and zeolites, sodium bicarbonate, lantibiotics, and mixtures of the abovementioned substances.

Further preferred deodorant compositions according to the invention are characterized in that the at least one deodorant active ingredient in a total amount of 0.1 to 10 wt .-%, preferably 0.2 to 7 wt .-%, particularly preferably 0.3 to 5 wt %, and most preferably 0.4 to 1.0% by weight, based in each case on the total weight of the active substance of the deodorant active ingredient or of the deodorant active ingredients in the overall composition.

Preferred compositions according to the invention contain - based on their weight - 0.0001 to 5 wt .-% perfume (s).

As perfume component perfumes, perfume oils or perfume oil ingredients can be used. Perfume oils or fragrances can according to the invention individual fragrance compounds, eg. As the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are known e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmecyclate. The ethers include, for example, benzyl ethyl ether and ambroxane, to the aldehydes e.g. the linear alkanals of 8 - 18 C atoms, citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, lilial and bourgeonal, to the ketones e.g. the ionones, alpha-isomethylionone and methylcedryl ketone, the alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, the hydrocarbons mainly include the terpenes such as limonene and pinene. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.

Such perfume oils may also contain natural fragrance mixtures such as are available from vegetable sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muskateller sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroli oil, orange peel oil and sandalwood oil.

In order to be perceptible, a fragrance must be volatile, whereby besides the nature of the functional groups and the structure of the chemical compound, the molecular weight also plays an important role. For example, most odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of a perfume or fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note", "middle note or body" and "base note" (end note or dry out). Since odor perception is also largely based on the odor intensity, the top note of a perfume or fragrance does not consist solely of volatile compounds, while the base note consists for the most part of less volatile, ie adherent fragrances. For example, in the composition of perfumes, more volatile fragrances can be bound to certain fixatives, preventing them from evaporating too quickly. In the subsequent classification of the fragrances in "more volatile" or "adherent" fragrances so nothing about the olfactory impression and whether the corresponding fragrance is perceived as a head or middle note, nothing said. Adhesion-resistant fragrances which can be used in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, bergamot oil, Champacablütenöl, Edel fir oil, Edeltannenzapfen oil, Elemiöl, eucalyptus oil, fennel oil, spruce needle oil, galbanum oil, geranium oil, ginger grass oil, Guaiac wood oil, gurdy balm oil, helichrysum oil, ho oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine oil, copaia balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemongrass oil, lime oil, tangerine oil, lemon balm oil, Musk Grain Oil, Myrrh Oil, Clove Oil, Neroli Oil, Niaouli Oil, Olibanum Oil, Orange Oil, Origanum Oil, Palmarosa Oil, Patchouli Oil, Peru Balsam Oil, Petitgrain Oil, Pepper Oil, Peppermint Oil, Pimento Oil, Pine Oil, Rose Oil, Rosemary Oil, Sandalwood Oil, Celery Oil, Spik Oil, Star Aniseed Oil, Turpentine Oil, Thuja Oil, Thyme oil, verb ena oil, vetiver oil, juniper berry oil, wormwood oil, wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil and cypress oil. But also the higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention as adherent fragrances or fragrance mixtures, ie fragrances. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate, borneol , Bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol , Isoeugenol methyl ether, isosafrole, jasmon, camphor, karvakrol, karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthyl ketone, methyl-n nonylacetaldehyde, methyl n-nonyl ketone, Muskon, β-Na phthol ethyl ether, β-naphthol methyl ether, nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde dimethyacetal, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, hexyl salicylate, cyclohexyl salicylate, Santalol, skatole, terpineol, thymen, thymol, γ-undelactone, vaniline, veratrum aldehyde, cinnamaldehyde, cimat alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester.

The more volatile fragrances include in particular the lower-boiling fragrances of natural or synthetic origin, which can be used alone or in mixtures. Examples of more volatile fragrances are alkyl isothiocyanates (alkylmustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

Particularly preferred deodorant compositions according to the invention are characterized in that at least one perfume component is contained in a total amount of 0.0001 to 4 wt .-%, preferably 0.5 to 2 wt .-%, each based on the total composition.

Depending on the desired mode of application, the compositions according to the invention can be formulated in various product forms. Compositions which are preferred according to the invention are characterized in that the cosmetically or dermatologically compatible carrier is present as powder, in stick form, as aerosol spray, pump spray, liquid or gel roll-on application, cream, lotion, solution, gel or on a substrate.

Further preferred embodiments of the invention are characterized in that the cosmetically or dermatologically acceptable carrier is present as powder, in stick form, as aerosol spray, pump spray, liquid or gel roll-on application, cream, lotion, solution, gel or applied to a substrate.

Deodorant or antiperspirant sticks can be in gelled, anhydrous, based on a W / O emulsion, based on an O / W emulsion, based on a water-oil multiple emulsion, based on a nanoemulsion and on Basis of a microemulsion, wherein the oil phase contain at least one silicone component or may consist of at least one silicone component. Furthermore, the compositions according to the invention, which are formulated as deodorant or antiperspirant sticks, can be based on a water-free fat-based, polyol-in-oil emulsion based on an oil-in-polyol emulsion based on a polyol-oil emulsion. Multiple emulsion, based on a nanoemulsion and based on a microemulsion, wherein the polyol phase may be anhydrous or may have only a low water content. Gel sticks can be formulated on the basis of fatty acid soaps, dibenzylidene sorbitol, N-acyl amino acid amides, 12-hydroxystearic acid, polyamides, polyamide derivatives, polysaccharides such as xanthan, polyglucomannans, guar, konjac, celluloses or starches, polyacrylates, polyacrylate derivatives, and other gellants. Aerosol sprays, pump sprays, roll-on applications and creams can be described as water-in-oil emulsion, oil-in-water emulsion, silicone oil-in-water emulsion, water-in-silicone oil-emulison, water-in-oil Microemulsion, oil-in-water microemulsion, silicone oil-in-water microemulsion, polyol-in-oil emulsion, oil-in-polyol emulsion, polyol-oil multiple emulsion, anhydrous suspension, preferably anhydrous oil-based suspension , alcoholic solution, in particular ethanolic solution, hydroalcoholic solution, in particular solutions with more than 50 wt .-% of a water-ethanol mixture, glycolic solution, in particular as a solution in propylene glycol, glycerol, dipropylene glycol and (under normal conditions) liquid polyethylene glycols, hydroglycolic solution , Polyol solution, water-polyol solution, aqueous gel, lipogel and oil. All said compositions may be thickened, for example, based on fatty acid soaps, dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, carbomer and carbopol type polyacrylates, polyacrylamides and polysaccharides, which may be chemically and / or physically modified.

The compositions may be transparent, translucent or opaque.

Lipid or wax matrix

If the compositions according to the invention are in the form of a stick, they preferably contain a lipid or wax matrix comprising at least one lipid or wax component with a melting point> 50 ° C.

In general, waxes are of solid to brittle hard consistency, coarse to fine crystalline, translucent to opaque, but not glassy, and melt above 50 ° C without decomposition. They are already slightly above the melting point low viscosity and show a strong temperature-dependent consistency and solubility.

Preference according to the invention, for example, natural vegetable waxes, z. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. Beeswax, shellac wax and spermaceti. For the purposes of the invention, it may be particularly preferred to use hydrogenated or hardened waxes. As a wax component and chemically modified waxes, especially the hard waxes, such as. As montan ester waxes, hydrogenated jojoba waxes and Sasol waxes used. The synthetic waxes which are likewise preferred according to the invention include, for example, polyalkylene waxes and polyethylene glycol waxes, C ₂₀ -C ₄₀ -dialkyl esters of dimer acids, C _30-50 -alkyl beeswax and alkyl and alkylaryl esters of dimer fatty acids.

A particularly preferred wax component is selected from at least one ester of a saturated, monohydric C ₁₆ -C ₆₀ -alcohol and a saturated C ₈ -C ₃₆ -monocarboxylic acid. According to the invention, lactides, the cyclic double esters of α-hydroxycarboxylic acids of the corresponding chain length, also belong thereto. Esters of fatty acids and long-chain alcohols have been found to be particularly advantageous for the composition of the present invention because they give the antiperspirant preparation excellent sensory properties and overall high stability to the pin. The esters are composed of saturated branched or unbranched monocarboxylic acids and saturated branched or unbranched monohydric alcohols. Also esters of aromatic carboxylic acids or hydroxycarboxylic acids (eg 12-hydroxystearic acid) and saturated branched or unbranched alcohols can be used according to the invention, provided that the wax component has a melting point> 50 ° C. It is particularly preferred to choose the wax components from the group of esters of saturated branched or unbranched alkanecarboxylic acids having a chain length of 12 to 24 carbon atoms and the saturated branched or unbranched alcohols having a chain length of 16 to 50 carbon atoms and having a melting point> 50 ° C have. In particular, C _{16-36 alkyl} stearates and C _18-38 alkyl hydroxystearoyl stearates, C _20-40 alkyl erucates and cetearyl behenate may be advantageous as the wax component. The wax or the wax components have a melting point> 50 ° C, preferably> 60 ° C, on.

A particularly preferred embodiment of the invention contains as wax component a C ₂₀ -C ₄₀ alkyl stearate. This ester is known under the name Kester ^® K82H or Kesterwachs ^® K80H and is sold by Koster Keunen Inc.. It is the synthetic imitation of the monoester fraction of beeswax and is characterized by its hardness, oil gelability and broad compatibility with lipid components. This wax can be used as a stabilizer and consistency regulator for W / O and O / W emulsions. Kester wax has the advantage that it has an excellent oil gelability even at low concentrations and so does not make the pencil mass too heavy and allows a velvety abrasion. A further particularly preferred embodiment of the invention contains as wax component cetearyl behenate, ie mixtures of cetyl behenate and stearyl behenate. This ester is known under the name Kester ^® K62 and is sold by Koster Keunen Inc..

Further preferred lipid or wax components with a melting point> 50 ° C are the triglycerides of saturated and optionally hydroxylated C _12-30 fatty acids, such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl tri-12- hydroxystearate, further synthetic Vollester of fatty acids and glycols or polyols containing 2 - 6 carbon atoms as long as they have a melting point above 50 ° C, for example, preferably C ₁₈ - C ₃₆ acid triglyceride (Syncrowax HGL-C ^®). According to the hydrogenated castor oil as a wax component, available for example as a commercial product Cutina ^® HR, is particularly preferred.

Further preferred lipid or wax components with a melting point> 50 ° C are the saturated linear C ₁₄ - C ₃₆ carboxylic acids, in particular myristic acid, palmitic acid, stearic acid and behenic acid and mixtures of these compounds, eg. B. Syncrowax ^® AW 1C (C ₁₈ - C ₃₆ fatty acids) or Cutina ^® FS 45 (palmitic and stearic acid).

Preferred deodorant or antiperspirant sticks according to the invention are characterized in that the lipid or wax component a) is selected from esters of a saturated, monohydric C ₁₆ -C ₆₀ -alkanol and a saturated C ₈ -C ₃₆ -monocarboxylic acid, in particular cetylbehenate, Stearyl behenate and C ₂₀ -C ₄₀ alkyl stearate, Glycerintriestern of saturated linear C ₁₂ - C ₃₀ carboxylic acids which may be hydroxylated, candelilla wax, carnauba wax, beeswax, saturated linear C ₁₄ - C ₃₆ carboxylic acids and mixtures of the aforementioned substances. Particularly preferred lipid or wax component mixtures a) are selected from mixtures of cetyl behenate, stearyl behenate, hardened castor oil, palmitic acid and stearic acid. Further particularly preferred lipid or wax component mixtures a) are selected from mixtures of C ₂₀ -C ₄₀ -alkyl stearate, hardened castor oil, palmitic acid and stearic acid.

Further preferred deodorant or antiperspirant sticks according to the invention are characterized in that the lipid or wax component (s) (FP> 50 ° C.) is used in total in amounts of 1 to 20% by weight, preferably 1.5 to 15% by weight. , based on the total composition. In a particularly preferred embodiment, the ester (s) is / are comprised of a saturated C ₁₆ -C ₆₀ monohydric alcohol and a C ₈ -C ₃₆ saturated monocarboxylic acid which is / are the lipid or wax component (s) of a total of 2-10 wt .-%, preferably 2-6 wt .-%, based on the total composition.

In addition to the lipid or wax components having a melting point> 50 ° C, lipid and wax components with a melting point of <50 ° C may be present, preferably esters or fatty alcohols or mono, di, triglycerides.

Oil-in-water emulsifiers

Are needed for emulsions, microemulsions, nanoemulsions, gels, creams, aqueous clear, opaque or turbid solutions, aqueous alcoholic solutions, aqueous glycolic solutions eg. For roll, ons, pump atomizers, impregnation solutions for substrates, pens, creams and aerosols.

The compositions according to the invention which are formulated as an emulsion, in particular as an oil-in-water emulsion or a polyol-in-water emulsion, preferably comprise at least one nonionic oil-in-water emulsifier having an HLB value of more than 7 These are emulsifiers generally known to the person skilled in the art, as are described, for example, in US Pat Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd ed., 1979, Vol. 8, pp. 913-916 , are listed. For ethoxylated products, the HLB value decreases of the formula HLB = (100-L): 5, where L is the weight fraction of the lipophilic groups, that is the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.

In selecting nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the stability of the stick compositions according to the invention. The individual emulsifier components thereby deliver a proportion to the total HLB value or average HLB value of the oil-in-water emulsifier mixture in accordance with their proportion of the total amount of the oil-in-water emulsifiers. According to the invention, the average HLB value of the oil-in-water emulsifier mixture is 10-19, preferably 12-18 and particularly preferably 14-17. In order to achieve such average HLB values, preference is given to oil-in-water emulsifiers HLB value ranges 10 - 14, 14 - 16 and possibly 16 - 19 combined. Of course, the oil-in-water emulsifier mixtures may also contain nonionic emulsifiers with HLB values in the range of> 7-10 and 19-20; Such emulsifier mixtures may also be preferred according to the invention. However, in another preferred embodiment, the deodorant or antiperspirant compositions of the present invention may also contain only a single oil-in-water emulsifier having an HLB in the range of 10-19.

Preferred deodorant or antiperspirant compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C ₈ -C ₂₄ -alkanols having an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C ₈ -C ₂₄ - Carboxylic acids with an average of 10 to 100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols esterified with 2 to 10 glycerol units and with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C ₈ -C ₃₀ fatty acid residues, provided that they have an HLB value of more than 7, and mixtures of the aforementioned substances.

The ethoxylated C ₈ -C ₂₄ -alkanols have the formula R ¹ O (CH ₂ CH ₂ O) _n H, where R ¹ is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the middle one Number of ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, moles of ethylene oxide to 1 mole of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, Petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. Also, adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol, are suitable.

The ethoxylated C ₈ -C ₂₄ -carboxylic acids have the formula R ¹ (OCH ₂ CH ₂ ) _n OH, where R ¹ is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide Units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, Gadoleic acid, behenic acid, erucic acid and brassidic acid and their technical mixtures. Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.

Particular preference is given to using the C ₁₂ -C ₁₈ -alkanols or the C ₁₂ -C ₁₈ -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, steareth- 12, Steareth-20, Steareth-30, Laureth-12 and Beheneth-20.

Furthermore, preference is given to using C ₈ -C ₂₂ -alkyl mono- and -oligoglycosides. C ₈ -C ₂₂ -alkyl mono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms. With regard to the glycoside radical, monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable. The degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ^®, a glucosidically bonded C ₈ -C ₁₆ alkyl group containing at an oligoglucoside whose average degree of oligomerization at 1 -2, in particular at from 1.1 to 1.4, is located. Particularly preferred C ₈ -C ₂₂ alkyl mono- and oligoglycosides are selected from Octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof. The glucamine-derived acylglucamides are also suitable as non-ionic oil-in-water emulsifiers.

Ethoxylated sterols, in particular ethoxylated soy sterols, are suitable oil-in-water emulsifiers according to the invention. The degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7. Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.

Furthermore, preferably partial esters of polyglycerols with 2 to 10 glycerol units and with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C ₈ - C ₃₀ fatty acid esters esterified used, if they have an HLB value of more than 7. Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetraglycerinmonocaprylat, Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocaprylat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglycerinmonocaprat, hexa are glycerol, Hexaglycerinmonomyristat, Hexaglycerinmonostearat, Decaglycerinmonocaprylat, Decaglycerinmonocaprat, decaglyceryl monolaurate, decaglyceryl monomyristate, Decaglycerinmonoisostearat, decaglycerol monostearate, Decaglycerinmonooleat, Decaglycerinmonohydroxystearat, Decaglycerindicaprylat, Decaglycerindicaprat, Decaglycerindilaurat, Decaglycerindimyristat, Decaglycerindiisostearat, Decaglycerindistearat, Decaglycerindioleat, Decaglycerindihydroxystearat, Decaglycerintricaprylat, Decaglycerintricaprat, Decaglycerintrilaurat, Decaglycerintrimyristat, Decaglycerintriisostearat, Decaglycerintristearat, Decaglyce rintrioleate and decaglycerol trihydroxystearate.

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the nonionic oil-in-water emulsifier in a total amount of 0.5 to 10 wt .-%, particularly preferably 1 to 4 wt .-% and most preferably 1 , 5 - 3 wt .-%, based on the total composition is included.

Water-in-oil emulsifiers

Preferred compositions according to the invention, which are formulated as emulsion (cream, roll on, gel, aerosol) or stick, preferably furthermore comprise at least one nonionic water-in-oil emulsifier having an HLB value greater than 1.0 and less than or equal to 7, O, selected from the mono and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids having 12-30, in particular 14-22 carbon atoms, which may be hydroxylated, and mixtures thereof, as Bodying agent and / or water binder. According to the invention, the mono- and diesters are preferred. C ₁₂ -C ₃₀ fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue. Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0 and less than or equal to 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate and mixtures thereof. According to the invention, particularly preferred water-in-oil emulsifiers having an HLB value greater than 1.0 and less than / equal to 7.0, for example as commercial products Cutina ^® PES (INCI: Pentaerythrityl distearate), Cutina ^® AGS (INCI: Glycol Distearate) or Cutina ^® EGMS (INCI: glycol stearate) available. These commercial products are already mixtures of mono- and diesters (the pentaerythrityl esters also contain tri- and tetraesters). According to the invention, it may be preferable to use only a single water-in-oil emulsifier. In another preferred embodiment, the compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers. A commercial product such as Cutina ^® PES is meant, for example, a technical mixture.

In addition to the stated water-in-oil emulsifiers based on the ethylene glycol or pentaerythrityl esters, in a preferred embodiment, at least one further nonionic water-in-oil emulsifier having an HLB value greater than 1.0 and less than or equal to 7, 0 should be included, the proportion of the total weight of nonionic water-in-oil emulsifiers with an HLB value greater than 1.0 and less than or equal to 7.0 but preferably should not be greater than 80%. In a particularly preferred embodiment, the compositions according to the invention contain the at least one additional water-in-oil emulsifier having an HLB value greater than 1.0 and less than or equal to 7.0 only in a proportion by weight of not more than 10% or are free of additional water -in-oil emulsifiers. Some of these additional suitable emulsifiers are described, for example, in Kirk-Othmer, "Encyclopaedia of Chemical Technology", 3rd ed. 1979, Vol. 8, page 913. For ethoxylated adducts, the HLB value, as already mentioned, can also be calculated.

• - lineare gesättigte Alkanole mit 12 - 30 Kohlenstoffatomen, insbesondere mit 16 - 22 Kohlenstoffatomen, insbesondere Cetylalkohol, Stearylalkohol, Arachidylalkohol, Behenylalkohol und Lanolinalkohol oder Gemische dieser Alkohole, wie sie bei der technischen Hydrierung von pflanzlichen und tierischen Fettsäuren erhältlich sind,
• - Ester und insbesondere Partialester aus einem Polyol mit 3 - 6 C-Atomen und linearen gesättigten und ungesättigten Fettsäuren mit 12 - 30, insbesondere 14 - 22 C-Atomen, die hydroxyliert sein können. Solche Ester oder Partialester sind z. B. die Mono- und Diester von Glycerin oder die Monoester von Propylenglycol mit linearen gesättigten und ungesättigten C₁₂ - C₃₀-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen mit Palmitin- und Stearinsäure, die Sorbitanmono-, -di- oder -triester von linearen gesättigten und ungesättigten C₁₂ - C₃₀-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen von Myristinsäure, Palmitinsäure, Stearinsäure oder von Mischungen dieser Fettsäuren und die Methylglucosemono- und -diester von linearen gesättigten und ungesättigten C₁₂ - C₃₀-Carbonsäuren, die hydroxyliert sein können;
• - Sterine, also Steroide, die am C3-Atom des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine, z. B. Cholesterin, Lanosterin) wie auch aus Pflanzen (Phytosterine, z. B. Ergosterin, Stigmasterin, Sitosterin) und aus Pilzen und Hefen (Mykosterine) isoliert werden und die niedrig ethoxyliert (1 - 5 EO) sein können;
• - Alkanole und Carbonsäuren mit jeweils 8 - 24 C-Atomen, insbesondere mit 16 - 22 C-Atomen, in der Alkylgruppe und 1 - 4 Ethylenoxid-Einheiten pro Molekül, die einen HLB-Wert größer 1,0 und kleiner/gleich 7,0 aufweisen,
• - Glycerinmonoether gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter Alkohole einer Kettenlänge von 8 - 30, insbesondere 12 - 18 Kohlenstoffatomen.
• - Partialester von Polyglycerinen mit n = 2 bis 10 Glycerineinheiten und mit 1 bis 5 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydroxylierten C₈ - C₃₀-Fett-säureresten verestert, sofern sie einen HLB-Wert von kleiner/gleich 7 aufweisen,
• - sowie Mischungen der vorgenannten Substanzen.

As water-in-oil emulsifier are preferably suitable:

• linear saturated alkanols having from 12 to 30 carbon atoms, in particular from 16 to 22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids,
• - Esters and in particular partial esters of a polyol having 3 to 6 carbon atoms and linear saturated and unsaturated fatty acids having 12 to 30, in particular 14 to 22 carbon atoms, which may be hydroxylated. Such esters or partial esters are, for. The monoesters and diesters of glycerine or the monoesters of propylene glycol with linear saturated and unsaturated C ₁₂ -C ₃₀ carboxylic acids which may be hydroxylated, especially those with palmitic and stearic acid, the sorbitan mono-, di- or triesters linear saturated and unsaturated C ₁₂ -C ₃₀ carboxylic acids which may be hydroxylated, in particular those of myristic acid, palmitic acid, stearic acid or mixtures of these fatty acids and the methyl glucose mono- and diesters of linear saturated and unsaturated C ₁₂ -C ₃₀ carboxylic acids which may be hydroxylated;
• Sterols, ie steroids, which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol ) and from fungi and yeasts (mycosterols) and which may be low ethoxylated (1-5 EO);
• Alkanols and carboxylic acids each having 8-24 carbon atoms, in particular 16-22 carbon atoms, in the alkyl group and 1-4 ethylene oxide units per molecule having an HLB value greater than 1.0 and less than or equal to 7, Have 0,
• Glycerol monoethers of saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8-30, in particular 12-18 carbon atoms.
• Esterified partial esters of polyglycerols with n = 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C ₈ -C ₃₀ fatty acid residues, if they have an HLB value of less than or equal to 7,
• - And mixtures of the aforementioned substances.

According to the invention, it may be preferable to use only a single additional water-in-oil emulsifier. In another preferred embodiment, the compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two additional water-in-oil emulsifiers. For example, a commercial product such as Cutina GMS ^® is understood to be a technical mixture, which is a mixture of glyceryl monostearate and glyceryl distearate.

Particularly advantageously usable additional water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, in particular in the form of the commercial products Cutina ^® GMS and Cutina ^® MD (ex Cognis), glyceryl distearate, glyceryl monocaprinate, glyceryl monocaprylate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monohydroxystearate, glyceryl monooleate , Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl dioleate, propylene glycol monostearate, propylene glycol monolaurate, sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, Sorbitansesquistearat, sorbitan distearate, sorbitan dioleate, sorbitan sesquioleate, sucrose distearate, arachidyl alcohol, behenyl alcohol, polyethylene glycol (2) stearyl ether (steareth-2), steareth 5, oleth-2, diglycerol monostearate, diglycerol monoisostearate, diglycerol monooleate, diglycerol dihydroxystearate, diglycerol distearate, diglycerol dioleate, triglycerol distearate, tetraglycer inmonostearate, tetraglycerol distearate, tetraglycerol tristearate, decaglycerol pentastearate, decaglycerin pentahydroxystearate, decaglycerol pentaisostearate, decaglycerol pentaoleate, soy sterol, PEG-1 soy sterol, PEG-5 soy sterol, PEG-2 monolaurate and PEG-2 monostearate.

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that at least one water-in-oil emulsifier is present in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1 to 4 wt .-%, based on the total composition, are included. Furthermore, amounts of from 2 to 3% by weight, based on the total weight of the composition, according to the invention may also be extremely preferred.

The following table summarizes various oil-in-water emulsifiers and water-in-oil emulsifiers and their HLB values. However, the HLB values can also be calculated according to Griffin, as described, for example, in the RÖMPP Chemie Lexikon, in particular in the online version of November 2003, and the manuals cited there under the heading "HLB system" by Fiedler, Kirk-Othmer and Janistyn is represented or tabulated. If there are different details in the literature about the HLB value of a substance, that HLB value should be used for the teaching according to the invention which comes closest to the value calculated according to Griffin. If no definite HLB value can be determined in this way, the HLB value which the manufacturer of the emulsifier specifies must be used for the teaching according to the invention. If this is not possible, the HLB value must be determined experimentally.

1

Triglyceride gesättigter Fettsäuren Glyceryltrioleat

1,5

Ethylenglycoldistearat

1,6

Pur-Cellinöl

1,8

Sorbitantrioleat Glycerindioleat

2,1

Sorbitantristearat

2,4

Propylenglycollactostearat

2,7

Glycerinmonooleat Sorbitdioleat

2,8

Glycerinmonostearat Propylenglycolmono-/distearat, nicht selbstemulgierend

2,9

Ethylenglycolmonostearat

3,0

Decaglycerindecaoleat Decaglycerindecastearat Generol 122 (Rapeseed Sterols) Sucrosedistearat

3,1

Decaglycerindecaoleat Glycerylmonoricinoleat Pentaerythritylmonostearat Pentaerythritylsesquioleat

3,2

Ethylenglycolmonodistearat, nicht selbstemulgierend Glycolstearat

3,3

Glycerinmonolaurat

3,4

Propylenglycolmonostearat

3,5

Ethylenglycolmonostearat Pentaerythrilylmonooleat Polyethylenglycol(100)monooleat

3,6

Glycerinmono-/dioleat, nicht selbstemulgierend Monoethoxylaurylether

3,7

Sorbitansesquioleat (Dehymuls SSO)

3,8

Glycerinmonodistearat, nicht selbstemulgierend Polyethylenglycol(100)monostearat Diglycerinsesquioleat N,N-Dimethylcaproamid Pentaerythritmonotallat Propylenglycolmonolaurat

4,0

Decaglycerinoctaoleat

4,3

Sorbitanmonooleat (Dehymuls SMO) Diethylenglycolmonostearat

4,4

1.2-Propylenglycolmonodistearat, selbstemulgierend

4,5

Glycerinmonostearatpalmitat (90 %), nicht selbstemulgierend Propylenglycolmonolaurat

4,7

Sorbitanmonostearat (Dehymuls SMS) Diethylenglycolmonooleat

4,8

Pentaerythritmonolaurat

4,9

Polyoxyethylen(2)oleylalkohol (Polyoxyethylen(2)oleylether) Polyoxyethylen(2)stearylalkohol (Polyoxyethylen(2)stearylether)

5,0

Ethylenglycolmonodistearat Generol 122 E 5 (PEG-5 Soy Sterol) Polyethylenglycol(100)monoricinoleat Polyethylenglycol(200)distearat Polyglyceryl-3-isostearate (z. B. Isolan GI 34 von Tego)

5,9

Polyethylenglycol(200)dilaurat

6,0

Decaglycerintetraoleat Polyethylenglycol(100)monolaurat Polyethylenglycol(200)dioleat

6,1

Diethylenglycolmonolaurat (Diglycollaurat)

6,3

Polyethylenglycol(300)dilaurat

6,4

Glycerinmonoricinoleat Glycerinsorbitanmonolaurat

6,5

Diethylenglycolmonolaurat Natriumstearoyl-2-lactylat

6,7

Sorbitanmonopalmitat

6,8

Glycerinmonococoat Glycerinmonolaurat

7,0

Polyoxyethylen(2)C₁₀-C₁₄-fettalkoholether, Laureth-2 (Dehydol LS 2) Saccharosedistearat

7,2

Polyethylenglycol(400)dioleat Saccharosedioleat

7,4

Polyethylenglycol(100)monolaurat Saccharosedipalmitat

7,5

Saccharosedipalmitat

7,6

Glycerinsorbitanlaurat

7,8

Polyethylenglycol(400)distearat

7,9

Polyethylenglycol(200)monostearat Polyoxyethylen(3)tridecylalkohol

8-8,2

Polyethylenglycol(400)distearat

8,0

Polyoxyethylen(3)C₁₀-C₁₄-fettalkoholether, Laureth-3 (Dehydol LS 3) N.N-Dimethyllauramid Natriumlauroyllactylat, Natriumlauroyl-2-lactylat Polyethylenglycol(200) monooleat Polyethylenglycol(220) monotallat Polyethylenglycol(1500)dioleat Polyoxyethylen(4)oleylalkohol Polyoxyethylen(4)stearylcetylether

8,2

Triglycerinmonooleat

8,3

Diethylenglycolmonolaurat

8,4

Polyoxyethylen(4)cetylether Polyoxyethylenglycol(400)dioleat

8,5

Natriumcaproyllactylat Polyethylenglycol(200)monostearat Sorbitanmonooleat

8,6

Sorbitanmonolaurat (Dehymuls SML) Polyethylenglycol(200)monolaurat

8,8

Polyoxyethylen(4)myristylether Polyethylenglycol (400)dioleat

8,9

Nonylphenol, polyoxyethyliert mit4 Mol EO

9,0

Oleth-5 (z. B. Eumulgin O 5)

9,2 - 9,7

Polyoxyethylen(4)laurylalkohol (je nach Handelsprodukt, z. B. Brij 30, Dehydol LS 4)

9,3

Polyoxyethylen(4)tridecylalkohol

9,6

Polyoxyethyten(4)sorbitanmonostearat

9,8

Polyethylenglycol (200)monolaurat

10-11

Polyethylenglycol(400)monooleat

10,0

Didodecyldimethylammoniumchlorid

10,0

Polyethylenglycol(200)monolaurat Polyethylenglycol(400)dilaurat Polyethylenglycol(600)dioleat Polyoxyethylen(4)sorbitanmonostearat Polyoxyethylen(5)sorbitanmonooleat

10,2

Polyoxyethylen(40)sorbitol hexaoleat

10,4 -10,6

Polyoxyethylenglycol(600)distearat

10,5

Polyoxyethylen(20)sorbitantristearat

10,6

Saccharosemonostearat

10,7

Saccharosemonooleat

11 - 11,4

Polyethylenglycol(400)monooleat

11,0

Polyethylenglycol(350)monostearat Polyethylenglycol(400)monotallat Polyoxyethylenglycol(7)monostearat Polyoxyethylenglycol(8)monooleat Polyoxyethylen(20)sorbitantrioleat Polyoxyethylen(6)tridecylalkohol

11,1

Polyethylenglycol(400)monostearat

11,2

Polyoxyethylen(9)monostearat Saccharosemonooleat Saccharosemonostearat

11,4

Polyoxyethylen(50)sorbitol hexaoleat Saccharosemonotallat Saccharosestearatpalmitat

11,6

Polyoxyethylenglycol(400)monoricinoleat

11,7

Saccharosemonomyristat Saccharosemonopalmitat

12,0

PEG-10 Soy Sterol (z. B. Generol 122 E 10) Triethanolaminoleat

12,2-12,3

Nonylphenol, ethoxyliert mit 8 Mol EO

12,2

Saccharosemonomyristat

12,4

Saccharosemonolaurat Polyoxyethylen(10)oleylalkohol, Polyoxyethylen(10)oleylether Polyoxyethylen(10)stearylalkohol, Polyoxyethylen(10)stearylether

12,5

Polyoxyethylen(10)stearylcetylether

12,7

Polyoxyethylen(8)tridecylalkohol

12,8

Polyoxyethylenglycol(400)monolaurat Saccharosemonococoat

12,9

Polyoxyethylen(10)cetylether

13

Glycerinmonostearat, ethoxyliert (20 Mol EO)

13,0

Eumulgin O 10 Eumulgin 286 Eumulgin B 1 (Ceteareth-12)

13,0

C12-Fettamine, ethoxyliert (5 Mol EO)

13,1

Nonylphenol, ethoxyliert (9,5 Mol EO)

13,2

Polyethylenglycol(600)monostearat Polyoxyethylen(16)tallöl

13,3

Polyoxyethylen(4)sorbitanmonolaurat

13,5

Nonylphenol, ethoxyliert (10,5 Mol EO) Polyethylenglycol(600)monooleat

13,7

Polyoxyethylen(10)tridecylalkohol Polyethylenglycol(660)monotallat Polyethylenglycol(1500)monostearat Polyoxyethylenglycol(1500)dioleat

13,9

Polyethylenglycol(400)monococoat Polyoxyethylen(9)monolaurat

14-16

Eumulgin HRE 40 (Ricinusöl, mit 40 EO ethoxyliert und hydriert)

14,0

Polyoxyethylen(12)laurylether Polyoxyethylen(12)tridecylalkohol

14,2

Polyoxyethylen(15)stearylalkohol

14,3

Polyoxyethylen(15)stearylcetylether

14,4

Gemisch aus C12-C15-Fettalkoholen mit 12 Mol EO

14,5

Polyoxyethylen(12)laurylalkohol

14,8

Polyoxyethylenglycol(600)monolaurat

14,9 - 15,2

Sorbitanmonostearat, mit 20 EO ethoxyliert (z. B. Eumulgin SMS 20)

15 - 15,9

Sorbitanmonooleat, mit 20 EO ethoxyliert (z. B. Eumulgin SMO 20)

15,0

PEG-20 Glyceryl stearate (z. B. Cutina E 24) PEG-40 Castor Oil (z. B. Eumulgin RO 40) Decylglucosid (Oramix NS 10) Dodecylglucosid (Plantaren APG 600) Dodecyltrimethylammoniumchlorid Nonylphenol, ethoxyliert mit 15 Mol EO Polyethylenglycol(1000)monostearat Polyoxyethylen(600)monooleat

15-17

Eumulgin HRE 60 (Ricinusöl, mit 60 EO ethoxyliert und hydriert)

15,3

C12-Fettamine, polyoxyethyliert mit 12 Mol EO Polyoxyethylen(20)oleylalkohol, Polyoxyethylen(20)oleylether

15,4

Polyoxyethylen(20)stearylcetylether (z. B. Eumulgin B 2 (Ceteareth-20))

15,5

Polyoxyethylen(20)stearylalkohol

15,6

Polyoxyethylenglycol(1000)monostearat Polyoxyethylen(20)sorbitanmonopalmitat

15,7

Polyoxyethylen(20)cetylether

15,9

Dinatriumtriethanolamindistearylheptaglycolethersulfosuccinat

16,0

Nonylphenol ethoxyliert mit 20 Mol EO Polyoxyethylen(25)propylenglycolstearat

16 - 16,8

Polyoxyethylen(30)monostearat

16,3-16,9

Polyoxyethylen(40)monostearat

16,5 - 16,7

Polyoxyethylen(20)sorbitanmonolaurat (z. B. Eumulgin SML 20)

16,6

Polyoxyethylen(20)sorbit

16,7

C18-Fettamine, polyoxyethyliert mit 5 Mol EO Polyoxyethylen(23) laurylalkohol

17,0

Ceteareth-30, z. B. Eumulgin B 3 Octylglucosid (Triton CG 110) Polyoxyethylen(30)glycerylmonolaurat

17,1

Nonylphenol, ethoxyliert mit 30 Mol EO

17,4

Polyoxyethylen(40)stearylalkohol

HLB value Chemical name
(out H. Janistyn, Handbook of cosmetics and fragrances, Hüthig-Verlag Heidelberg, 3rd edition, 1978, Volume 1, page 470 and Volume 3, pages 68-78 ))

1

Triglycerides of saturated fatty acids glyceryl trioleate

1.5

Ethylene glycol

1.6

Pur-Celli oil

1.8

Sorbitan trioleate glycerol dioleate

2.1

sorbitan

2.4

Propylenglycollactostearat

2.7

Glycerol monooleate sorbitol dioleate

2.8

Glycerol monostearate Propylene glycol mono- / distearate, not self-emulsifying

2.9

ethylene glycol

3.0

Decaglycerol decaoleate Decaglycerol decastate Generol 122 (rapeseed sterols) sucrose distearate

3.1

Decaglycerol decaoleate Glyceryl monoricinoleate Pentaerythrityl monostearate Pentaerythrityl sesquioleate

3.2

Ethylene glycol monodistearate, non self-emulsifying glycol stearate

3.3

glycerol

3.4

propylene glycol

3.5

Ethylene glycol monostearate pentaerythrilyl monooleate polyethylene glycol (100) monooleate

3.6

Glycerol mono- / dioleate, not self-emulsifying monoethoxylauryl ether

3.7

Sorbitan sesquioleate (Dehymuls SSO)

3.8

Glycerol monodistearate, not self-emulsifying Polyethylene glycol (100) Monostearate Diglycerol sesquioleate N, N-dimethyl caproamide Pentaerythritol monotallate Propylene glycol monolaurate

4.0

Decaglycerinoctaoleat

4.3

Sorbitan monooleate (Dehymuls SMO) diethylene glycol monostearate

4.4

1.2-propylene glycol monodistearate, self-emulsifying

4.5

Glycerol monostearate palmitate (90%), non-self-emulsifying propylene glycol monolaurate

4.7

Sorbitan monostearate (Dehymuls SMS) Diethylene glycol monooleate

4.8

Pentaerythritmonolaurat

4.9

Polyoxyethylene (2) oleyl alcohol (polyoxyethylene (2) oleyl ether) polyoxyethylene (2) stearyl alcohol (polyoxyethylene (2) stearyl ether)

5.0

Ethylene glycol monodistearate Generol 122 E5 (PEG-5 soy sterol) polyethylene glycol (100) monoricinoleate polyethyleneglycol (200) distearate polyglyceryl-3-isostearate (eg Isolan GI 34 from Tego)

5.9

Polyethylene glycol (200) dilaurate

6.0

Decaglycerin tetraoleate Polyethylene glycol (100) Monolaurate Polyethylene glycol (200) Dioleate

6.1

Diethylene glycol monolaurate (diglycollaurate)

6.3

Polyethylene glycol (300) dilaurate

6.4

Glycerol monoricinoleate Glycerol sorbitan monolaurate

6.5

Diethylene glycol monolaurate Sodium stearoyl-2-lactylate

6.7

sorbitan

6.8

Glycerol monococoate glycerol monolaurate

7.0

Polyoxyethylene (2) C ₁₀ -C ₁₄ fatty alcohol ether, Laureth-2 (Dehydol LS 2) sucrose distearate

7.2

Polyethylene glycol (400) dioleate sucrose dioleate

7.4

Polyethylene glycol (100) monolaurate sucrose dipalmitate

7.5

Saccharosedipalmitat

7.6

Glycerinsorbitanlaurat

7.8

Polyethylene glycol (400) distearate

7.9

Polyethylene glycol (200) monostearate polyoxyethylene (3) tridecyl alcohol

8-8.2

Polyethylene glycol (400) distearate

8.0

Polyoxyethylene (3) C ₁₀ -C ₁₄ fatty alcohol ether, Laureth-3 (Dehydol LS 3) N, N-dimethyllauramide Sodium lauroyl lactylate, Sodium lauroyl 2-lactylate Polyethylene glycol (200) Mono oleate Polyethylene glycol (220) Mono-pallate Polyethylene glycol (1500) Dioleate Polyoxyethylene (4) oleyl alcohol polyoxyethylene (4) stearylcetylether

8.2

triglycerol

8.3

Diethylenglycolmonolaurat

8.4

Polyoxyethylene (4) cetyl ether polyoxyethylene glycol (400) dioleate

8.5

Sodium caproyl lactylate polyethylene glycol (200) monostearate sorbitan monooleate

8.6

Sorbitan monolaurate (Dehymuls SML) Polyethylene glycol (200) monolaurate

8.8

Polyoxyethylene (4) myristyl ether polyethylene glycol (400) dioleate

8.9

Nonylphenol, polyoxyethylated with 4 moles of EO

9.0

Oleth-5 (eg Eumulgin O 5)

9.2 - 9.7

Polyoxyethylene (4) lauryl alcohol (depending on the commercial product, eg Brij 30, Dehydol LS 4)

9.3

Polyoxyethylene (4) tridecyl alcohol

9.6

Polyoxyethyten (4) sorbitan monostearate

9.8

Polyethylene glycol (200) monolaurate

10-11

Polyethylene glycol (400) monooleate

10.0

didodecyldimethylammonium

10.0

Polyethylene glycol (200) Monolaurate Polyethylene glycol (400) Dilaurate Polyethylene glycol (600) Dioleate Polyoxyethylene (4) sorbitan monostearate Polyoxyethylene (5) sorbitan monooleate

10.2

Polyoxyethylene (40) sorbitol hexaoleate

10.4 -10.6

Polyoxyethylene glycol (600) distearate

10.5

Polyoxyethylene (20) sorbitan tristearate

10.6

sucrose monostearate

10.7

sucrose monooleate

11 - 11,4

Polyethylene glycol (400) monooleate

11.0

Polyethylene glycol (350) Monostearate Polyethylene glycol (400) Mono-taratate Polyoxyethylene glycol (7) Monostearate Polyoxyethylene glycol (8) Mono-oleate Polyoxyethylene (20) sorbitan trioleate Polyoxyethylene (6) tridecyl alcohol

11.1

Polyethylene glycol (400) monostearate

11.2

Polyoxyethylene (9) monostearate sucrose monooleate sucrose monostearate

11.4

Polyoxyethylene (50) sorbitol hexaoleate sucrose monotallate sucrose stearate palmitate

11.6

Polyoxyethylene (400) monoricinoleate

11.7

Sucrose monomyryrate sucrose monopalmitate

12.0

PEG-10 soy sterol (eg, Generol 122 E 10) triethanolamine oleate

12.2 to 12.3

Nonylphenol, ethoxylated with 8 moles of EO

12.2

Saccharosemonomyristat

12.4

Sucrose monolaurate polyoxyethylene (10) oleyl alcohol, polyoxyethylene (10) oleyl ether polyoxyethylene (10) stearyl alcohol, polyoxyethylene (10) stearyl ether

12.5

Polyoxyethylene (10) stearylcetylether

12.7

tridecyl alcohol polyoxyethylene (8)

12.8

Polyoxyethylene glycol (400) monolaurate sucrose monococoate

12.9

Polyoxyethylene (10) cetyl ether

13

Glycerol monostearate, ethoxylated (20 mol EO)

13.0

Eumulgin O 10 Eumulgin 286 Eumulgin B 1 (Ceteareth-12)

13.0

C12 fatty amines, ethoxylated (5 moles EO)

13.1

Nonylphenol, ethoxylated (9.5 mol EO)

13.2

Polyethylene glycol (600) monostearate polyoxyethylene (16) tall oil

13.3

Polyoxyethylene (4) sorbitan monolaurate

13.5

Nonylphenol, ethoxylated (10.5 mol EO) Polyethylene glycol (600) monooleate

13.7

Polyoxyethylene (10) tridecyl alcohol polyethylene glycol (660) monotalate polyethylene glycol (1500) monostearate polyoxyethylene glycol (1500) dioleate

13.9

Polyethylene glycol (400) monococoate polyoxyethylene (9) monolaurate

14-16

Eumulgin HRE 40 (castor oil, ethoxylated with 40 EO and hydrogenated)

14.0

Polyoxyethylene (12) lauryl ether polyoxyethylene (12) tridecyl alcohol

14.2

Polyoxyethylene (15) stearyl alcohol

14.3

Polyoxyethylene (15) stearylcetylether

14.4

Mixture of C12-C15 fatty alcohols with 12 moles EO

14.5

Polyoxyethylene (12) lauryl alcohol

14.8

Polyoxyethylene glycol (600) monolaurate

14.9 - 15.2

Sorbitan monostearate ethoxylated with 20 EO (eg Eumulgin SMS 20)

15 - 15.9

Sorbitan monooleate, ethoxylated with 20 EO (eg Eumulgin SMO 20)

15.0

PEG-20 glyceryl stearate (eg Cutina E24) PEG-40 castor oil (eg Eumulgin RO 40) decyl glucoside (Oramix NS10) dodecyl glucoside (Plantaren APG 600) dodecyltrimethylammonium chloride nonylphenol ethoxylated with 15 moles EO polyethylene glycol ( 1000) monostearate polyoxyethylene (600) monooleate

15-17

Eumulgin HRE 60 (castor oil, ethoxylated with 60 EO and hydrogenated)

15.3

C12 fatty amines polyoxyethylated with 12 moles EO polyoxyethylene (20) oleyl alcohol, polyoxyethylene (20) oleyl ethers

15.4

Polyoxyethylene (20) stearyl cetyl ether (eg, eumulgin B 2 (ceteareth-20))

15.5

stearyl polyoxyethylene (20)

15.6

Polyoxyethylene glycol (1000) monostearate polyoxyethylene (20) sorbitan monopalmitate

15.7

Polyoxyethylene (20) cetyl ether

15.9

Dinatriumtriethanolamindistearylheptaglycolethersulfosuccinat

16.0

Nonylphenol ethoxylated with 20 moles of EO polyoxyethylene (25) propylene glycol stearate

16 - 16.8

Polyoxyethylene (30) monostearate

16.3 to 16.9

Polyoxyethylene (40) monostearate

16.5 - 16.7

Polyoxyethylene (20) sorbitan monolaurate (eg Eumulgin SML 20)

16.6

sorbitol polyoxyethylene (20)

16.7

C18 fatty amines, polyoxyethylated with 5 moles EO polyoxyethylene (23) lauryl alcohol

17.0

Ceteareth-30, z. B. Eumulgin B 3 Octylglucoside (Triton CG 110) Polyoxyethylene (30) glyceryl monolaurate

17.1

Nonylphenol, ethoxylated with 30 moles of EO

17.4

Polyoxyethylene (40) stearyl alcohol

Further preferred compositions according to the invention are characterized in that the total content of nonionic and ionic emulsifiers and / or surfactants with an HLB value above 8 not more than 20 wt .-%, preferably at most 15 wt .-%, particularly preferably at most 10 wt .-% , particularly preferably at most 7 wt .-%, more preferably at most 4 wt .-% and most preferably at most 3 wt .-%, each based on the total composition of the invention is.

oils

Preferred compositions of the present invention, which are in the form of an emulsion, suspension or stick, preferably further contain at least one oil which is liquid at 20 ° C and which is not a perfume component and is not an essential oil. Oils preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction. Preferred alcohol oils are Hexyldecanol (Eutanol ^® G 16, Guerbitol ^® T 16) Octyldodecanol (Eutanol ^® G, Guerbitol ^® 20), 2-ethylhexyl alcohol and the commercial products Guerbitol ^® 18, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb 12 ^{®, ®} Isocarb 16 or Isocarb ^® 24. Further preferred oil components are mixtures of Guerbet alcohols and Guerbet alcohol esters, for example the commercial product Cetiol ^® PGL (hexyldecanol and hexyldecyl laurate).

Further oils preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C _8-30 fatty acids. Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, olive oil, rapeseed oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like. But are also synthetic triglyceride oils, in particular Capric / Caprylic triglycerides, z. As the commercial products Myritol ^® 318, Myritol ^® 331 (Cognis) or Miglyol ^® 812 (Hüls) with unbranched fatty acid residues and glyceryl triisostearin and the commercial products Estol ^® GTEH 3609 (Uniqema) or Myritol ^® GTEH (Cognis) with branched fatty acid residues.

Further oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di- (2-) ethylhexyl) adipate, dioctyl adipate, diethyl / di-n-butyl / dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di- (2-hexyldecyl) succinate.

Further oils which are particularly preferred _{according to the} invention are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (Witconol APM ^®).

Further oil components preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated. These include, hexyldecyl stearate (Eutanol ^® G 16 S), hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate (Cegesoft ^® C 24) and 2-ethylhexyl stearate (Cetiol ^® 868). Also conditionally suitable are isopropyl palmitate, isopropyl stearate, isopropyl, isopropyl oleate, isooctyl, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl, cetearyl, 2-ethylhexyl, 2-ethylhexyl, 2-ethylhexyl cocoate, 2-octyldodecyl, butyloctanoic-2-butyl octanoate, Diisotridecylacetat, n-butyl stearate, n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, ethylene glycol dioleate and dipalmitate.

Further oil components preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monohydric or polyhydric C _3-22 alkanols, such as butanol, butanediol, myristyl alcohol and stearyl alcohol, eg. As PPG-14 butyl ether (Ucon Fluid ^® AP), PPG-9-butyl ether (Breox B25 ^®), PPG-10 butanediol (Macol ^® 57) and PPG-15 stearyl ether (Arlamol ^® E).

Further preferred oil components according to the invention are selected from the C ₈ -C ₂₂ -fatty alcohol esters of monohydric or polyhydric C ₂ -C ₇ -hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid. Such esters based on linear C _14/15 alkanols, eg. B. C ₁₂ -C ₁₅ alkyl lactate, and branched in the 2-position C _12/13 alkanols can be obtained under the trademark Cosmacol ^® by the company Nordmann, Rassmann GmbH & Co, Hamburg, in particular the commercial products Cosmacol ^® ESI , Cosmacol® ^® EMI and Cosmacol® ^® EIT.

Further inventively preferred oil components are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. As glycerol carbonate, dicaprylyl carbonate (Cetiol ^® CC) or the esters of DE 197 56 454 A1 ,

Further preferred oil components according to the invention are selected from the esters of dimers of unsaturated C ₁₂ -C ₂₂ -fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C ₂ -C ₁₈ -alkanols or with polyvalent linear or branched C ₂ -C ₆ -alkanols.

It may be extraordinarily preferred according to the invention to use mixtures of the abovementioned oils.

Further oil components preferred according to the invention are selected from silicone oils and hydrocarbon oils.

Silicone oils preferred according to the invention are selected from among dialkyl and alkylaryl siloxanes, such as, for example, cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also include hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane. Further inventively preferred silicone oils are selected from volatile silicone oils which may be cyclic, such as. For example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane and mixtures thereof, as described for. B. in the commercial products DC 244, 245, 344 and 345 of Dow Corning, or linear, z. As hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), any two and three mixtures of L ₂ , L ₃ and / or L ₄ , as described, for. B. in the commercial products DC 2-1184, Dow Corning ^® 200 (0, 65 cSt), and Dow Corning ^® 200 (1.5 cSt) from Dow Corning are included.

Further inventively preferred silicone oils are selected from non-volatile higher molecular weight linear dimethylpolysiloxanes, commercially available z. Example under the name Dow Corning ^® 190, Dow Corning ^® 200 fluid having viscosities in the range of 5-100 cSt, preferably 5-50 cSt, or even 5 - 10 cSt, and Baysilon ^® 350 M.

According to the invention preferred natural and synthetic hydrocarbons are selected from paraffinic oils, isohexadecane, isoeicosane, polyisobutenes and polydecenes, the ^®, for example, under the designation Emery ^® 3004, 3006, 3010 or under the name Ethylflo ^® from Albemarle or Nexbase 2004G from Nestle are available, as well as 1 , 3-di- (2-ethylhexyl) -cyclohexane (Cetiol ^® S).

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the oil (s) liquid at 20 ° C. in a total amount of 0.1-95% by weight, preferably 2-20% by weight, more preferably 3-15 wt .-%, each based on the total weight of the composition, is / are included.

In a further preferred embodiment of the invention, a proportion of the oil components of at least 80% by weight has a refractive index n _D of 1.39-1.51. It is particularly preferred if 5-40-50% by weight, even more preferably 10-12-25-30% by weight, of the oil components have a refractive index n _D of 1.43-1.51, preferably 1.44-1 , 49, more preferably 1.45 - 1.47 - 1.485, at 20 ° C (measured at λ = 589 nm).

Particularly preferred compositions according to the invention, which are formulated as a water-in-oil emulsion, preferably further comprise at least one water-in-oil emulsifier. The at least one water-in-oil emulsifier is preferably in an amount of 0.5 to 5 wt .-%, particularly preferably 1.0 to 1.5 to 2.5 wt .-%, each based on the total weight of Emulsion, included.

A particularly preferred group of water-in-oil emulsifiers according to the invention are the poly (C ₂ -C ₃ ) alkylene glycol-modified silicones whose previous INCI name was Dimethicone Copolyol, with the current INCI names PEG-x Dimethicone (with x = 2-20, preferably 3-17, more preferably 11-12), bis-PEG-y dimethicones (with y = 3-25, preferably 4-20), PEG / PPG a / b dimethicones (where a and b independently of one another represent numbers from 2 to 30, preferably from 3 to 30 and particularly preferably from 12 to 20, in particular from 14 to 18,), bis-PEG / PPG-c / d dimethicone (where c and d independently of one another represent numbers of 10) 25, preferably 14-20 and more preferably 14-16) and bis-PEG / PPG-e / f PEG / PPG g / h dimethicones (where e, f, g and h independently of one another represent numbers of 10-20, preferably 14-18 and more preferably 16, stand). Particular preference is given to PEG / PPG-18/18 dimethicones, which are commercially available in a 1: 9 mixture with cyclomethicone as DC 3225 C or DC 5225 C, PEG / PPG-4/12 dimethicone, sold under the name Abil B 8852 is available as well as Bis-PEG / PPG-14/14 Dimethicone, which is commercially available in a mixture with Cyclomethicone as Abil EM 97 (Goldschmidt), Bis-PEG / PPG-20/20 Dimethicone, under the name Abil B 8832 is available, PEG / PPG-5/3 trisiloxanes (Silsoft 305), and PEG / PPG-20/23 dimethicones (Silsoft 430 and Silsoft 440).

Further preferred W / O emulsifiers according to the invention are poly (C ₂ -C ₃ ) alkylene glycol-modified silicones which are hydrophobically modified with C ₄ -C ₁₈ -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 dimethicones (previously: Cetyl dimethicone copolyol, available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone copolyols and alkyl dimethicone ethoxy glucosides.

Compositions which are particularly preferred according to the invention furthermore preferably contain at least one skin-cooling active substance. Skin-cooling active ingredients suitable according to the invention are, for example, menthol, isopulegol and menthol derivatives, eg. Menthyl lactate, menthyl glycolate, menthyl pyrrolidone carboxylic acid, menthyl methyl ether, menthoxypropanediol, menthone glycerol acetal (9-methyl-6- (1-methylethyl) -1,4-dioxaspiro (4.5) decane-2-methanol), monomethyl succinate and 2-hydroxymethyl-3,5 , 5-trimethylcyclohexanol. Preferred skin-cooling active ingredients are menthol, isopulegol, menthyl lactate, menthoxypropanediol and menthylpyrrolidonecarboxylic acid, and mixtures of these substances, in particular mixtures of menthol and menthyl lactate, menthol, menthol glycolate and menthyl lactate, menthol and menthoxypropanediol or menthol and isopulegol. Menthyl Ethyl Oxamate According to the invention, it is particularly preferred that at least one skin-cooling active ingredient be present in a total amount of 0.01-1% by weight, more preferably 0.02-0.5% by weight and most preferably 0.05-0.2% by weight. %, in each case based on the total weight of the composition.

Particularly preferred compositions according to the invention, which are formulated as a propellant-driven aerosol, contain at least one propellant. Preferred propellants (propellants) are propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane, isopentene, methane, ethane, dimethyl ether, nitrogen, air, oxygen, nitrous oxide, 1,1,1,3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1,1-difluoroethane, both individually and in combination. Also hydrophilic propellants, such as As carbon dioxide, can be used advantageously in the context of the present invention, when the proportion of hydrophilic gases is selected low and lipophilic propellant gas (eg., Propane / butane) is present in excess. Particularly preferred are propane, n-butane, isobutane and mixtures of these propellants. It has been found that the use of n-butane as the only propellant gas according to the invention can be particularly preferred.

The amount of blowing agent is preferably 2-95%, preferably 20-85% by weight, more preferably 30-75% by weight and most preferably 40-50% by weight, based in each case on the total weight of the preparation consisting of the inventive composition Composition and the propellant.

Suitable gas cylinders are vessels made of metal (aluminum, tinplate, tin), protected or non-splittemdem plastic or glass, which is coated with plastic on the outside, in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic Aspects, handiness, printability etc. play a role. Special internal protective lacquers ensure corrosion resistance to the composition according to the invention.

As mentioned above, the compositions according to the invention can be formulated in various forms, for example as (optionally oil and fat-free) gel, as cream, in stick form, as a liquid or gel roll-on application, as a soaked flexible substrate (pad), but also as powder or spray.

Compositions of the invention may be in solid, semi-solid, liquid, disperse, emulsified, suspended or gel form. Furthermore, the agents according to the invention can be formulated as an aerosol, that is, they are packaged in a pressure vessel, from which they can be sprayed with the aid of a propellant. Furthermore, the agents according to the invention can be sprayed as a propellant-free pump spray or systems in which the pressure is built up mechanically or electrically.

Depending on the dosage form, the compositions according to the invention contain further active ingredients and / or adjuvants.

polyols

Preferred compositions according to the invention also comprise at least one water-soluble polyhydric C ₂ -C ₉ -alkanol having 2-6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3-20 ethylene oxide units and mixtures thereof. Preferably, these components are selected from 1,2-propylene glycol, 2-methyl-1,3-propanediol, glycerol, butylene glycols such as 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol, pentylene glycols such as 1,2- Pentanediol and 1,5-pentanediol, hexanediols such as 1,6-hexanediol, hexanetriols such as 1,2,6-hexanetriol, 1,2-octanediol, 1,8-octanediol, dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol and Mixtures of the aforementioned substances. Suitable water-soluble polyethylene glycols are selected from PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred.

Preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one water-soluble polyhydric C ₂ -C ₉ -alkanol with 2-6 hydroxyl groups and / or at least one water-soluble polyethylene glycol with 3-20 ethylene oxide units is selected from 1,2 Propylene glycol, 2-methyl-1,3-propanediol, glycerin, butylene glycols such as 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol, pentylene glycols such as 1,2-pentanediol and 1,5-pentanediol, hexanediols such as 1,6-hexanediol, hexanetriols such as 1,2,6-hexanetriol, 1,2-octanediol, 1,8-octanediol, dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol and mixtures of the aforementioned substances.

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one water-soluble polyhydric C ₂ -C ₉ -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in total amounts of 3 - 40 wt .-%, preferably 8 - 25 wt .-%, particularly preferably 10-18 wt .-%, each based on the total composition, is included.

water

Preferred compositions according to the invention contain water. The proportion of water is preferably 0.1-99 wt .-%, particularly preferably 3 to 90 wt .-%, most preferably 10 to 80 wt .-%, further preferably 15 - 60 wt .-%, 20 - 50 wt .-%, 30- 40 wt .-%, each based on the total composition.

Low-melting lipid or wax component

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that at least one lipid or wax component having a melting point in the range of 25-50 ° C selected from coconut fatty acid glycerol mono-, di- and triesters, Butyrospermum Parkii (Shea Butter ) and esters of saturated, monohydric C ₈ -C ₁₈ alcohols with saturated C ₁₂ -C ₁₈ monocarboxylic acids and mixtures of these substances. These lower melting lipid or wax components allow consistency optimization of stick-shaped or creamy products and minimization of visible residue on the skin. Especially preferred are products sold under the INCI name Cocoglycerides, in particular the commercial products Novata ^® (ex Cognis), particularly preferably Novata AB ^®, a mixture of C ₁₂ -C ₁₈ mono-, di- and triglycerides, which is in the range of 30 - 32 ° C, as well as the products of the Softisan series (Sasol Germany GmbH) with the INCI name Hydrogenated Cocoglycerides, in particular Softisan 100, 133, 134, 138, 142. Further preferred esters of saturated, monohydric C ₁₂ -C ₁₈ - alcohols with saturated C ₁₂ -C ₁₈ monocarboxylic acids are stearyl laurate, cetearyl (z. B. Crodamol ^® CSS), cetyl palmitate (z. B. Cutina ^® CP) and myristyl myristate (z. B. Cetiol ^® MM).

Further particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one lipid or wax component having a melting point in the range of from 25 to 50 ° C. in amounts of from 0.01 to 20% by weight, preferably 3 to 10% by weight. 20 wt .-%, more preferably 5 to 18 wt .-% and most preferably 6 to 15 wt .-%, based on the total composition, is included.

fillers

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that they further contain at least one solid, water-insoluble particulate filler for improving the pen consistency and the sensory properties. In a highly preferred embodiment of this filler is selected from optionally modified starches (for. Example, of corn, rice, potatoes) and starch derivatives, which are, if desired, pregelatinized, in particular starch derivatives of type DRY FLO ^®, cellulose and cellulose derivatives, silica, silicic acids, e.g. , As Aerosil ^® types, spherical Polyalkylsesquisiloxan particles (especially Aerosil ^® R972 and Aerosil ^® 200V from Degussa), silica gels, talc, kaolin, clays, z. Bentonites, magnesium aluminum silicates, boron nitride, lactoglobulin derivatives, e.g. As sodium C _8-16 -Isoalkylsuccinyllactoglobulinsulfonat from Brooks Industries available as a commercial product Biopol ^® OE, glass powders, polymer powders, in particular of polyolefins, polycarbonates, polyurethanes, polyamides, z. As nylon, polyesters, polystyrenes, polyacrylates, (meth) acrylate or (meth) acrylate-vinylidene copolymers, which may be crosslinked, or silicones, and mixtures of these substances.

Polymer powder based on a polymethacrylate copolymer are z. B. as a commercial product Polytrap ^® 6603 (Dow Corning) available. Other polymer powders, e.g. Example based on polyamides, obtainable under the name Orgasol ^® 1002 (polyamide-6) and Orgasol ^® 2002 (polyamide-12) from Elf Atochem. Other polymer powders which are suitable for the purpose according to the invention are, for. B. polymethacrylates (Micro Pearl ^® M from SEPPIC or Plastic PowderA of NIKKOL), styrene-divinylbenzene copolymers (Plastic Powder FP of NIKKOL), polyethylene and polypropylene powder (ACCUREL ^® EP 400 from AKZO), or silicone polymers (Silicone Powder X2 -1605 from Dow Corning).

Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that they contain at least one solid, water-insoluble particulate filler in a total amount of 0.01 to 30% by weight, preferably 5 to 20% by weight, more preferably 8 to 15 Wt .-%, each based on the total composition included.

Compositions of the invention may be in solid, semi-solid, liquid, disperse, emulsified, suspended or gel form.

In a particularly preferred embodiment, the compositions according to the invention are in liquid or in viscous, flowable form. The application can preferably be carried out with a roller ball applicator. Such scooters have a ball mounted in a ball bed which can be moved by movement over a surface. The ball absorbs some of the agent to be distributed and conveys this to the surface to be treated. The packaging for the compositions according to the invention may be opaque, but also transparent or translucent. For the purposes of the invention, the term liquid also includes any solid dispersions in liquids. Compositions according to the invention may also be present as pastes, ointments, lotions or creams. Fixed funds can be present, for example, as a pencil.

The application can also be carried out with substrates which are acted upon by an agent according to the invention. Especially preferred are wet wipes, i. prefabricated for the user, preferably individually packaged, wet wipes, such as. B. from the field of glass cleaning or from the field of wet toilet paper are well known. Such wet wipes, which may advantageously also contain preservatives, are then preferably impregnated or applied with an agent according to the invention, preferably they are individually packaged. You can z. B. be used as a deodorant cloth, which is particularly interesting for use on the go.

Preferred substrate materials are preferably selected from porous sheet-like cloths. They can be made of a fibrous or cellular flexible material which has sufficient mechanical stability and softness for application to the skin. These wipes include cloths of woven and non-woven synthetic and natural fibers, felt, paper or foam, such as hydrophilic polyurethane foam.

Preferably, conventional cloths made of non-woven material (nonwovens) are used here. Nonwovens are generally defined as adhesively bonded fibrous products having a mat or layered fibrous structure, or those comprising fibrous mats in which the fibers are randomly or randomly distributed. The fibers may be natural such as wool, silk, jute, hemp, cotton, flax, sisal or ramie; or synthetically, such as rayon, cellulose esters, polyvinyl derivatives, polyolefins, polyamides or polyesters. In general, any fiber diameter or titer is suitable for the present invention. The nonwoven fabrics employed herein tend not to rupture or disintegrate due to the random or random arrangement of fibers in the nonwoven material which impart excellent strength in all directions. Examples of nonwoven fabrics suitable as substrates in the present invention include, for example WO 98/18441 known. Preferred porous and flat cleaning cloths consist of one or different fiber materials, in particular of cotton, refined cotton, polyamide, polyester or mixtures of these. The substrates in fabric form preferably have an area of from 10 to 400 cm ² , preferably from 50 to 300 cm ² , more preferably from 100 to 200 cm ² . The grammage of the cloth material is usually 20 to 1000 g / m ² , preferably 30 to 500 g / m ² and in particular 50 to 150 g / m ² . Deodorizing or antiperspirant substrates which are preferred according to the invention can be obtained by impregnation or impregnation or else by melting a composition according to the invention onto a substrate.

The agents according to the invention, preferably liquid agents, may also be multiphase, the phases may e.g. horizontally, so one above the other, or vertically, so next to each other, be arranged. It may also be a disperse system in which e.g. the solid constituents are distributed inhomogeneously in the liquid matrix, so that such a dispersed system should be shaken before use.

With particular preference these compositions according to the invention are present as a roll-on composition, which is preferably packaged in a roller ball applicator and which particularly preferably has a dynamic viscosity in the range from 300 to 10,000 mPas, preferably 800 to 7,500 mPas, particularly preferably 1,000 to 5,000 mPas , measured with a Brookfield viscometer, spindle RV 4, 20 s ^-1 , without helipath, at 20 ° C ambient temperature and 20 ° C sample temperature.

In a further preferred embodiment, the agents according to the invention are characterized in that they are present as a water-in-oil emulsion.

Hydrogel-forming substances which are preferred according to the invention are selected from cellulose ethers, in particular hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, furthermore xanthan gum, sclerotium gum, succinoglucans, polygalactomannans, in particular guar gum and locust bean gum (Locust Bean Gum), especially guar gum and locust Bean gum itself and the nonionic hydroxyalkyl guar derivatives and locust bean gum derivatives such as hydroxypropyl guar, carboxymethylhydroxypropyl guar, hydroxypropylmethyl guar, hydroxyethyl guar and carboxymethylguar, pectins, agar, carrageenan, tragacanth, gum arabic, karaya gum, tara gum, gellan, gelatin, casein, propylene glycol alginate, Alginic acids and their salts, in particular sodium alginate, potassium alginate and calcium alginate, furthermore polyvinylpyrrolidones, polyvinyl alcohols, polyacrylamides, furthermore - albeit less preferred - physically (eg by Vorverkleisterung) and / or chemically modified starches, in particular hydroxypropylated starch phosphates and Octenylstärkesuccinaten and their aluminum -, calcium or sodium salts, further - also less preferred - acrylic acid-acrylate copolymers, acrylic acid-acrylamide copolymers, acrylic acid-vinylpyrrolidone copolymers, acrylic acid-vinyl formamide copolymers and polyacrylates n. Particularly preferred hydrogel formers are selected from cellulose ethers, especially from hydroxyalkylcelluloses, in particular from hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose and methylhydroxyethylcellulose, and mixtures thereof. An exceptionally preferred hydrogel generator is hydroxyethylcellulose.

In a further preferred embodiment, the agents according to the invention are characterized in that they contain water in a total amount of 20-90% by weight, preferably 25-75% by weight, particularly preferably 30-60% by weight, most preferably 35% 50 wt .-%, further ethanol in a total amount of 5 - 50 wt .-%, preferably 10 - 40 wt .-%, particularly preferably 15 - 35 wt .-%, most preferably 20 - 30 wt .-%, and Hydroxyethyl cellulose in a total amount of 0.01 to 2 wt .-%, preferably 0.1 to 1 wt .-%, preferably 0.2 to 0.7 wt .-%, most preferably 0.3 to 0.5 wt. %, the weight percentages in each case referring to the total weight of the composition according to the invention; With particular preference these compositions according to the invention are present as a roll-on composition, which is preferably packaged in a roller ball applicator and particularly preferably has a dynamic viscosity in the range from 300 to 10,000 mPas, preferably 800 to 7,500 mPas, particularly preferably 1,000 to 5,000 mPas , measured with a Brookfield viscometer, spindle RV 4, 20 s ^-1 , without helipath, at 20 ° C ambient temperature and 20 ° C sample temperature.

Further inventively preferred agents are therefore characterized in that additionally at least one chelating agent, which is selected from ethylenediaminetetraacetic acid (EDTA) and its salts and nitrilotriacetic acid (NTA) and mixtures of these substances, in a total amount of 0.01-0.5 wt. -%, preferably 0.02 - 0.3 wt .-%, particularly preferably 0.05 - 0.1 wt .-%, is contained, wherein the wt .-% - in each case based on the total weight of the composition.

Preferred compositions according to the invention which are present as gels, emulsions, suspensions or sticks preferably furthermore comprise at least one cosmetic liquid which is liquid under normal conditions and which is not a fragrance and is not an essential oil.

The cosmetic oil is liquid under normal conditions. Essential oils according to the invention are understood to mean mixtures of volatile components which are prepared by steam distillation from vegetable raw materials, such as. B. citrus oils.

The total quantity of cosmetic oils which are liquid under normal conditions and which are not fragrance and no essential oil is 1 to 70% by weight, preferably 1.5 to 40% by weight, more preferably 2 to 20% by weight, in preferred compositions according to the invention. %, most preferably 3 - 6 wt .-%, wherein the amounts are based on the weight of the composition.

In the case of cosmetic oils, a distinction is made between volatile and non-volatile oils. Non-volatile oils are understood as meaning oils having a vapor pressure of less than 2.66 Pa (0.02 mm Hg) at 20 ° C and an ambient pressure of 1013 hPa. Volatile oils are understood to mean those oils which, at 20 ° C. and an ambient pressure of 1013 hPa, have a vapor pressure of 2.66 Pa - 40,000 Pa (0.02 mm - 300 mm Hg), preferably 10 - 12000 Pa (0.1-0.200 Pa). 90 mm Hg), more preferably 13-3000 Pa, most preferably 15-500 Pa.

Volatile cosmetic oils are usually selected from cyclic silicone oils having the INCI name Cyclomethicone. The INCI name cyclomethicones is understood to mean, in particular, cyclotrisiloxane (hexamethylcyclotrisiloxane), cyclotetrasiloxane (octamethylcyclotetrasiloxane), cyclopentasiloxane (decamethylcyclopentasiloxane) and cyclohexasiloxane (dodecamethylcyclohexasiloxane). These oils have a vapor pressure of about 13-15 Pa at 20 ° C. Cyclomethicones are well-known in the art as oils for cosmetic compositions, in particular for deodorant compositions, like pins, known. Due to their persistence in the environment, it may be preferred according to the invention to dispense with the use of cyclomethicones. In a particularly preferred embodiment, the compositions according to the invention and used according to the invention contain from 0 to less than 1% by weight, preferably at most 0.1% by weight, of cyclomethicones, based on the weight of the composition.

An invention according to preferred Cyclomethicone substitute is a mixture of C ₁₃ -C ₁₆ -lsoparaffinen, C ₁₂ - C ₁₄ isoparaffins and C ₁₃ - C ₁₅ alkanes, the viscosity at 25 ° C in the range of 2 - 6 mPas is located and a vapor pressure at 20 ° C in the range of 10-150 Pa, preferably 100-150 Pa. Such a mixture is z. B. under the name SiClone SR-5 from Presperse Inc. available.

Further preferred volatile silicone oils are selected from volatile linear silicone oils, in particular volatile linear silicone oils having 2-10 siloxane units, such as hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), as described e.g. B. in the commercial products DC 2-1184, Dow Corning ^® 200 (0.65 cSt), and Dow Corning ^® 200 (1.5 cSt) from Dow Corning are contained, and low molecular weight phenyl trimethicone having a vapor pressure at 20 ° C of about 2000 Pa, as it is z. From GE Bayer Silicones / Momentive under the name Baysilone Fluid PD 5.

Preferred antiperspirant compositions of the present invention contain at least one volatile silicone oil, which may be cyclic or linear, because of the drier skin feel and faster drug release.

Other preferred compositions of the present invention contain at least one volatile non-silicone oil because of the drier skin feel and faster release of the antiperspirant active. Preferred volatile non-silicone oils are selected from C ₈ -C ₁₆ isoparaffins, in particular from isononane, isodecane, isoundecane, isododecane, isotridecane, isotetradecane, isopentadecane and isohexadecane, and mixtures thereof. Preference is given to C ₁₀ -C ₁₃ isoparaffin mixtures, in particular those having a vapor pressure at 20 ° C. of from 10 to 400 Pa, preferably from 13 to 100 Pa.

This at least one C ₈ -C ₁₆ isoparaffin is preferably in a total amount of 1-50% by weight, preferably 1.5-20% by weight, more preferably 2-10% by weight, most preferably 3-6 Wt .-%, in each case based on the total weight of the composition. Further preferred compositions according to the invention comprise at least one non-volatile cosmetic oil selected from nonvolatile silicone oils and non-volatile non-silicone oils. Residues of components which are insoluble in the composition, such as talc, but also the antiperspirant active substances (= antiperspirant aluminum salts) dried on the skin, can be successfully masked with a nonvolatile oil. In addition, with a mixture of different oils, especially non-volatile and volatile oils, parameters such as skin feel, residue visibility and stability of the composition of the invention can be finely regulated and better adapted to consumer needs.

Agents preferred according to the invention are characterized in that the cosmetic oil, which is not a perfume and an essential oil, at least a volatile oil with a vapor pressure of 10 - 3000 Pa at 20 ° C, which is no perfume and no essential oil, in a total amount from 10 to 100 wt .-%, particularly preferably 30 to 80 wt .-%, each based on the total weight of the cosmetic oils comprises.

Of course, it is also possible to formulate compositions according to the invention with a low proportion of volatile oils - that is to say with 0.5 - 15% by weight of volatile oils, based on the total weight of the composition - or even without volatile oils.

Oils which are particularly preferred according to the invention are esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated. It should be noted that some esters of linear or branched C ₁ -C ₂₂ -alkanols or C ₁₄ -C ₂₂ -alkenols and some triesters of glycerol with linear or branched C ₂ -C ₂₂ -carboxylic acids, which may be saturated or unsaturated, under normal conditions, such as cetyl stearate or glycerol tristearate (= stearin). According to the invention, these esters which are solid under normal conditions do not constitute cosmetic oils, since they do not fulfill the condition "liquid under normal conditions". The assignment of whether such an ester is liquid or solid under normal conditions is within the general knowledge of those skilled in the art. Preference is given to esters of linear or branched saturated fatty alcohols having 2-5 carbon atoms with linear or branched saturated or unsaturated fatty acids having 3-18 carbon atoms which may be hydroxylated. Preferred examples of these are isopropyl palmitate, isopropyl stearate, isopropyl myristate, 2- Hexyldecyl stearate, 2-hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate and 2-ethylhexyl stearate. Also preferred are isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate, n-hexyl laurate , n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, ethylene glycol dioleate, ethylene glycol dipalmitate, n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, C ₁₂ -C ₁₅ alkyl lactate and di-C ₁₂ -C ₁₃ alkyl malate and the Benzoic acid esters of linear or branched C _8-22 -alkanols. Particularly preferred are benzoic acid C ₁₂ -C ₁₅ alkyl esters, for. B. available as a commercial product Finsolv ^® TN (C ₁₂ -C ₁₅ alkyl benzoate), and isostearyl benzoate, z. As available as Finsolv ^® SB, 2-ethylhexyl, z. B. available as Finsolv ^® EB, and benzoic acid 2-octyldodecylester, z. As available as Finsolv ^® BOD.

Further preferred oil components according to the invention are selected from the C ₈ -C ₂₂ -fatty alcohol esters of monohydric or polyhydric C ₂ -C ₇ -hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid. Such esters based on linear C _14/15 alkanols, eg. B. C ₁₂ -C ₁₅ -alkyllactate, and of branched in the 2-position C _12/13 alkanols are under the trade name Cosmacol ^® by the company Nordmann, Rassmann GmbH & Co, Hamburg, to obtain, in particular the commercial products Cosmacol ^® ESI , Cosmacol® ^® EMI and Cosmacol® ^® EIT.

As a particularly advantageous, for. As for the drug release, the use of isopropyl esters of C ₁₂ -C ₁₈ carboxylic acids, in particular the use of isopropyl myristate, and particularly preferred mixtures of isopropyl myristate with C ₁₀ -C ₁₃ isoparaffin mixtures, the latter preferably with a vapor pressure at 20 ° C of 10 - 400 Pa, proved.

Agents preferred according to the invention comprise at least one ester of linear or branched saturated or unsaturated fatty alcohols containing 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids containing 2 to 30 carbon atoms, which may be hydroxylated, in a total amount of 1 to 60% by weight. , preferably 2 - 26 wt .-%, particularly preferably 4 - 24 wt .-%, most preferably 6 - 17 wt .-%, each based on the weight of the total composition.

Another particularly preferred ester oil is triethyl citrate. Further preferred products according to the invention include triethyl citrate and at least one C ₈ -C ₁₆ isoparaffin selected from isononane, isodecane, isoundecane, isododecane, isotridecane, isotetradecane, isopentadecane and isohexadecane and mixtures of these isoparaffins. Further inventively preferred products include triethyl citrate and at least one C ₈ -C ₁₆ isoparaffin selected from isononane, isodecane, isoundecane, isododecane, isotridecane and mixtures of these C ₈ -C ₁₆ isoparaffins. Further inventively preferred products include triethyl citrate and a mixture of isodecane, isoundecane, isododecane and isotridecane.

Further non-volatile non-silicone oils which are preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction. Preferred alcohol oils are 2-hexyldecanol, 2-octyldodecanol and 2-ethylhexyl alcohol. Also preferred is isostearyl alcohol. Other preferred nonvolatile oils are selected from mixtures of Guerbet alcohols and Guerbet alcohol esters, e.g. For example, 2-hexyldecanol and 2-hexyldecyl laurate.

The term "triglyceride" used hereinafter means "glycerol triester". Further preferred nonvolatile oils according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C _8-30 -fatty acids, provided that they are liquid under normal conditions. Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like. Particularly preferred are synthetic triglyceride oils, in particular Capric / Caprylic triglycerides, z. As the commercial products Myritol ^® 318 or Myritol ^® 331 (BASF / BASF) with unbranched fatty acid residues and glyceryl triisostearin and glyceryl tri (2-ethylhexanoate) with branched fatty acid residues. Such triglyceride oils preferably account for less than 50% by weight of the total weight of all cosmetic oils in the composition of the invention. The total weight of triglyceride oils is particularly preferably 0.5-25% by weight, preferably 1-5% by weight, in each case based on the total composition.

Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, in particular diisopropyl adipate, Di-n-butyl adipate, di- (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n-butyl / dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyl decyl) ) succinate.

Further inventively particularly preferred non-volatile non-silicone oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. PPG-2 myristyl ether and PPG-3 myristyl ether.

Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monohydric or polyhydric C _3-22 alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, z. PPG-14 butyl ether, PPG-9 butyl ether, PPG-10-butanediol and PPG-15 stearyl ether.

Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the symmetrical, unsymmetrical or cyclic esters of carbonic acid with C ₆ -C ₂₀ -alcohols, eg. As di-n-caprylylcarbonat (Cetiol ^® CC) or di- (2-ethylhexyl) carbonate (Tegosoft DEC). Carbonic acid esters with C ₁ -C ₅ -alcohols, e.g. As glycerol carbonate or propylene carbonate, however, are not suitable as a cosmetic oil compounds.

Further oils which may be preferred according to the invention are selected from the esters of dimers of unsaturated C ₁₂ -C ₂₂ -fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C ₂ -C ₁₈ -alkanols or with polyvalent linear or branched C ₂ - C ₆ alkanols. The total weight of dimer fatty acid esters is particularly preferably 0.5-10% by weight, preferably 1-5% by weight, in each case based on the total composition.

Other cosmetic oils which are particularly preferred according to the invention are selected from nonvolatile silicone oils. Preferred nonvolatile silicone oils according to the invention are selected from linear polyalkylsiloxanes having a kinematic viscosity at 25 ° C. of at least 5 cSt to 2000 cSt, in particular selected from linear polydimethylsiloxanes having a kinematic viscosity at 25 ° C. of from 5 cSt to 2000 cSt, preferably from 10 to 350 cSt , particularly preferably 50 - 100 cSt, as z. B. under the trade names Dow Corning ^® 200 and Xiameter PMX Dow Corning or Xiameter are available. Further preferred nonvolatile silicone oils are phenyltrimethicones having a kinematic viscosity at 25 ° C. of from 10 to 100 cSt, preferably from 15 to 30 cSt, and also cetyldimethicones.

Natural and synthetic hydrocarbons preferred according to the invention are selected from paraffin oils, isohexadecane, isoeicosane, polyisobutenes and polydecenes, which, for example, are disclosed in US Pat. B. under the name Emery ^® 3004, 3006, 3010 or under the name Nexbase ^® 2004G are available from Nestle, and 1,3-di- (2-ethylhexyl) cyclohexane.

The compositions according to the invention and used according to the invention optionally contain further excipients, auxiliaries and active substances.

Antiperspirant sticks according to the invention may be in gelled form, based on a W / O emulsion based on an O / W emulsion, based on a water-oil multiple emulsion, based on a nanoemulsion and based on a microemulsion, wherein the oil phase contain at least one silicone component or may consist of at least one silicone component. Gel sticks can be formulated on the basis of fatty acid soaps, dibenzylidene sorbitol, N-acyl amino acid amides, 12-hydroxystearic acid, polyamides, polyamide derivatives, polysaccharides such as xanthan, polyglucomannans, guar, konjac, celluloses or starches, polyacrylates, polyacrylate derivatives, and other gellants.

Roll-on applications and creams can be as water-in-oil emulsion, oil-in-water emulsion, silicone oil-in-water emulsion, water-in-oil microemulsion, oil-in-water microemulsion, silicone oil in-water microemulsion, alcoholic solution, in particular ethanolic solution, hydroalcoholic solution, in particular solutions with more than 50 wt .-% of a water-ethanol mixture, glycolic solution, in particular as a solution in 1,2-propylene glycol, glycerol, dipropylene glycol and (under normal conditions) liquid polyethylene glycols, hydroglycolic solution, polyol solution, water-polyol solution and as an aqueous gel. All said compositions may be thickened, for example based on fatty acid soaps, dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, polyacrylates of the Carbomer and Carbopol type, polyacrylamides and polysaccharides, which may be chemically and / or physically modified. The agents may be transparent, translucent or opaque.

If the compositions according to the invention are in the form of a stick, they preferably contain a lipid or wax matrix comprising at least one lipid or wax component with a melting point> 50 ° C.

Preference according to the invention, for example, natural vegetable waxes, z. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. Beeswax, shellac wax and spermaceti. For the purposes of the invention, it may be particularly preferred to use hydrogenated or hardened waxes. As a wax component and chemically modified waxes, especially the hard waxes, such as. As montan ester waxes, hydrogenated jojoba waxes and Sasol waxes used. The synthetic waxes which are likewise preferred according to the invention include, for example, polyalkylene waxes and polyethylene glycol waxes, C ₂₀ -C ₄₀ -dialkyl esters of dimer acids, C _30-50 -alkyl beeswax and alkyl and alkylaryl esters of dimer fatty acids.

A particularly preferred wax component is selected from at least one ester of a saturated, monohydric C ₁₆ -C ₆₀ -alcohol and a saturated C ₈ -C ₃₆ -monocarboxylic acid. According to the invention, lactides, the cyclic double esters of α-hydroxycarboxylic acids of the corresponding chain length, also belong thereto. Esters of fatty acids and long-chain alcohols have been found to be particularly advantageous for the composition of the present invention because they give the antiperspirant preparation excellent sensory properties and overall high stability to the pin. The esters are composed of saturated branched or unbranched monocarboxylic acids and saturated branched or unbranched monohydric alcohols. Also esters of aromatic carboxylic acids or hydroxycarboxylic acids (eg 12-hydroxystearic acid) and saturated branched or unbranched alcohols can be used according to the invention, provided that the wax component has a melting point> 50 ° C. It is particularly preferred to choose the wax components from the group of esters of saturated branched or unbranched alkanecarboxylic acids having a chain length of 12 to 24 carbon atoms and the saturated branched or unbranched alcohols having a chain length of 16 to 50 carbon atoms and having a melting point> 50 ° C have. In particular, C _{16-36 alkyl} stearates and C _18-38 alkyl hydroxystearoyl stearates, C _20-40 alkyl erucates and cetearyl behenate may be advantageous as the wax component. The wax or the wax components have a melting point> 50 ° C, preferably> 60 ° C, on. A particularly preferred embodiment of the invention contains as wax component a C ₂₀ -C ₄₀ alkyl stearate. A further particularly preferred embodiment of the invention contains as wax component cetearyl behenate, ie mixtures of cetyl behenate and stearyl behenate.

Further preferred lipid or wax components with a melting point> 50 ° C are the triglycerides of saturated and optionally hydroxylated C _12-30 fatty acids, such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl tri-12- hydroxystearate, further synthetic Vollester of fatty acids and glycols or polyols containing 2 - 6 carbon atoms as long as they have a melting point above 50 ° C, for example, preferably C ₁₈ - C ₃₆ acid triglyceride (Syncrowax HGL-C ^®). According to the hydrogenated castor oil as a wax component, available for example as a commercial product Cutina ^® HR, is particularly preferred.

Further preferred lipid or wax components having a melting point> 50 ° C. are the saturated linear C ₁₄ -C ₃₆ -carboxylic acids, in particular myristic acid, palmitic acid, stearic acid and behenic acid, and also mixtures of these compounds.

Preferred antiperspirant sticks according to the invention contain a lipid or wax component selected from esters of a saturated, monohydric C ₁₆ -C ₆₀ alkanol and a saturated C ₈ -C ₃₆ monocarboxylic acid, in particular cetyl behenate, stearyl behenate and C ₂₀ -C ₄₀ Alkyl stearate, glycerol triesters of saturated linear C ₁₂ -C ₃₀ -carboxylic acids which may be hydroxylated, candelilla wax, carnauba wax, beeswax, saturated linear C ₁₄ -C ₃₆ -carboxylic acids and mixtures of the abovementioned substances. Particularly preferred lipid or wax component mixtures are selected from mixtures of cetyl behenate, stearyl behenate, hardened castor oil, palmitic acid and stearic acid. Further particularly preferred lipid or wax component mixtures are selected from mixtures of C ₂₀ -C ₄₀ -alkyl stearate, hardened castor oil, palmitic acid and stearic acid. Further preferred antiperspirant sticks according to the invention contain lipid or wax component (s) in total in amounts of 0.5-30% by weight, preferably 1-25 Wt .-%, based on the total composition. With particular preference the agents according to the invention additionally comprise at least one emulsifier and / or at least one surfactant.

Emulsifiers and surfactants which are suitable according to the invention are preferably selected from anionic, cationic, nonionic, amphoteric, in particular ampholytic and zwitterionic, emulsifiers and surfactants.

Surfactants are amphiphilic (bifunctional) compounds which consist of at least one hydrophobic and at least one hydrophilic moiety. The hydrophobic moiety is preferably a hydrocarbon chain of 8-28 carbon atoms, which may be saturated or unsaturated, linear or branched. Particularly preferably, this C ₈ -C ₂₈ -alkyl chain is linear.

Basic properties of the surfactants and emulsifiers are the oriented absorption at interfaces and the aggregation to micelles and the formation of lyotropic phases.

By anionic surfactants are meant surfactants with exclusively anionic charges; they contain z. As carboxyl groups, sulfonic acid groups or sulfate groups. Particularly preferred anionic surfactants are alkyl sulfates, alkyl ether sulfates, acyl glutamates and C8-C24-carboxylic acids and their salts, the so-called soaps.

Cationic surfactants are understood as meaning surfactants with exclusively cationic charges; they contain z. B. quaternary ammonium groups. Preference is given to cationic surfactants of the quaternary ammonium compounds, esterquats and amidoamines type. Preferred quaternary ammonium compounds are ammonium halides and the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83. Further cationic surfactants which can be used according to the invention are the quaternized protein hydrolysates. Preferred esterquats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. The cationic surfactants are contained in the preferred compositions according to the invention preferably in proportions of 0.05 to 10 wt .-%, based on the total agent.

The amphoteric surfactants are subdivided into ampholytic surfactants and zwitterionic surfactants. Ampholytic surfactants are understood as meaning those surface-active compounds which have both acidic (for example -COOH or -SO ₃ H groups) and basic hydrophilic groups (for example amino groups) and thus behave acidic or basic depending on the condition. Zwitterionic surfactants are understood by the person skilled in the art to be surfactants which carry both a negative and a positive charge in the same molecule.

Examples of preferred zwitterionic tenides are the betaines, the N-alkyl-N, N-dimethylammonium glycinates, the N-acyl-aminopropyl-N, N-dimethylammoniumglycinate and the 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazoline with each 8 to 24 carbon atoms in the alkyl group. Examples of preferred ampholytic surfactants are N-alkylglycines, N-alkylaminopropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having 8 to 24 C Atoms in the alkyl group.

Compositions which are particularly preferred according to the invention furthermore preferably contain at least one skin-cooling active substance. Skin-cooling active ingredients suitable according to the invention are, for example, menthol, isopulegol and menthol derivatives, eg. Menthyl lactate, menthyl glycolate, menthyl pyrrolidone carboxylic acid, menthyl methyl ether, menthoxypropanediol, menthone glycerol acetal (9-methyl-6- (1-methylethyl) -1,4-dioxaspiro (4.5) decane-2-methanol), monomenthyl succinate, 2-hydroxymethyl-3,5 , 5-trimethylcyclohexanol and menthyl ethyl oxamate. Preferred skin-cooling active ingredients are menthol, isopulegol, menthyl lactate, menthoxypropanediol and menthylpyrrolidonecarboxylic acid, and mixtures of these substances, in particular mixtures of menthol and menthyl lactate, menthol, menthol glycolate and menthyl lactate, menthol and menthoxypropanediol or menthol and isopulegol.

It is particularly preferred according to the invention for at least one skin-cooling active substance to be present in a total amount of 0.01-2% by weight, more preferably 0.02-0.5% by weight and most preferably 0.05-0.2% by weight. %, in each case based on the total weight of the composition.

Preferred compositions according to the invention also comprise at least one water-soluble polyhydric C ₂ -C ₉ -alkanol having 2-6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3-20 ethylene oxide units and mixtures thereof. Preferably, these components are selected from 1,2-propylene glycol, 1,3-propanediol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, pentylene glycols such as 1,2-pentanediol and 1,5-pentanediol, hexanediols such as 1,2-hexanediol and 1,6-hexanediol, hexanetriols such as 1,2,6-hexanetriol, 1,2-octanediol, 1,8-octanediol, dipropylene glycol, Tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol, cis-1,4-dimethylolcyclohexane, trans-1,4-dimethylolcyclohexane, any isomeric mixtures of cis and trans-1,4-dimethylolcyclohexane, and mixtures of the aforementioned substances. Suitable water-soluble polyethylene glycols are selected from PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred. Particularly preferred antiperspirant compositions according to the invention comprise at least one water-soluble polyhydric C ₂ -C ₉ -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in a total amount of 3 to 30% by weight, preferably 8 to 25 wt .-%, particularly preferably 10 to 18 wt .-%, in each case based on the total weight of the composition.

Particularly preferred antiperspirant agents according to the invention are characterized in that at least one lipid or wax component having a melting point in the range of 25-50 ° C selected from coconut fatty acid glycerol mono-, di- and triesters, Butyrospermum Parkii (Shea butter) and esters saturated, monohydric C ₈ -C ₁₈ alcohols with saturated C 12 -C ₁₈ monocarboxylic acids and mixtures of these substances. These lower melting lipid or wax components allow consistency optimization of stick-shaped or creamy products and minimization of visible residue on the skin. Especially preferred are products sold under the INCI name Cocoglycerides, in particular the commercial products Novata ^® (ex BASF), particularly preferably Novata AB ^®, a mixture of C ₁₂ -C ₁₈ mono-, di- and triglycerides, which is in the range of 30 - 32 ° C, as well as the products of the Softisan series (Sasol Germany GmbH) with the INCI name Hydrogenated Cocoglycerides, in particular Softisan 100, 133, 134, 138, 142. Further preferred esters of saturated, monohydric C ₁₂ -C ₁₈ - alcohols with saturated C ₁₂ -C ₁₈ monocarboxylic acids are stearyl laurate, cetearyl (z. B. Crodamol ^® CSS), cetyl palmitate (z. B. Cutina ^® CP) and myristyl myristate (z. B. Cetiol ^® MM).

Further particularly preferred antiperspirant compositions according to the invention are characterized in that the at least one lipid or wax component having a melting point in the range from 25 to 50 ° C. in amounts of from 0.01 to 20% by weight, preferably from 3 to 20% by weight. %, more preferably 5 to 18% by weight and most preferably 6 to 15% by weight, based on the total composition.

Particularly preferred antiperspirant compositions according to the invention furthermore contain at least one solid, water-insoluble particulate filler for strengthening the consistency and for improving the sensory properties. In a highly preferred embodiment of this filler is selected from optionally modified starches (for. Example, of corn, rice, potatoes) and starch derivatives, which are, if desired, pregelatinized, in particular starch derivatives of type DRY FLO ^®, cellulose and cellulose derivatives, silica, silicic acids, e.g. , As Aerosil ^® types, spherical Polyalkylsesquisiloxan particles (especially Aerosil ^® R972 and Aerosil ^® 200V from Degussa), silica gels, talc, kaolin, clays, z. Bentonites, magnesium aluminum silicates, boron nitride, lactoglobulin derivatives, e.g. As sodium C _8-16 -Isoalkylsuccinyllactoglobulinsulfonat from Brooks Industries available as a commercial product Biopol ^® OE, glass powders, polymer powders, in particular of polyolefins, polycarbonates, polyurethanes, polyamides, z. As nylon, polyesters, polystyrenes, polyacrylates, (meth) acrylate or (meth) acrylate-vinylidene copolymers, which may be crosslinked, or silicones, and mixtures of these substances. Polymer powder based on a polymethacrylate copolymer are z. B. as a commercial product Polytrap ^® 6603 (Dow Corning) available. Other polymer powders, e.g. Example based on polyamides, obtainable under the name Orgasol ^® 1002 (polyamide-6) and Orgasol ^® 2002 (polyamide-12) from Elf Atochem. Other polymer powders which are suitable for the purpose according to the invention are, for. B. polymethacrylates (Micro Pearl ^® M from SEPPIC or Plastic Powder A of NIKKOL), styrene-divinylbenzene copolymers (Plastic Powder FP of NIKKOL), polyethylene and polypropylene powder (ACCUREL ^® EP 400 from AKZO), or silicone polymers (Silicone Powder X2-1605 from Dow Corning).

Particularly preferred antiperspirant compositions according to the invention contain at least one solid, water-insoluble particulate filler in a total amount of from 0.01 to 30% by weight, preferably from 5 to 20% by weight, particularly preferably from 8 to 15% by weight, based in each case on the overall composition.

Agents preferred according to the present invention are formulated as a stick, soft solid, cream, roll-on, water-in-oil emulsion gel, dibenzylidenalditol-based gel, loose powder or compacted powder, or lie on a disposable substrate such as a cloth, pad or pad. applied before.

Another object of the present invention is the use of Metal Organic Framework (s) (MOFs) in cosmetic products.

Preferred uses of the invention are uses to combat body odor.

With regard to preferred embodiments of the use according to the invention, what has been said about the agents or compositions according to the invention applies mutatis mutandis.

Another object of the present invention is in methods for the treatment of body odor, characterized in that a preparation according to the invention is applied to the skin.

Also with regard to preferred embodiments of the method according to the invention, mutatis mutandis applies to the compositions of the invention or compositions.

Examples:

Example 1 Synthesis of Organometallic Framework Compounds (MOF) According to the Invention

Synthesis of NH ₂ -MIL-125 (Ti)

Based on literature: S.-N. Kim et al. Catalysis Today 2013, 204, 85-93 ,

A solution of 3 mmol titanium isopropoxide (Ti [OCH (CH ₃ ) ₂ ] ₄ , Aldrich, 97%) and 6 mmol 2-aminoterephthalic acid (H ₂ BDC-NH ₂ , Aldrich, 99%) in 50 mL N, N Dimethylformamide / methanol (1: 1, v / v). This solution was transferred to a 250 mL steel autoclave (DAB-3 from Berghof) with PTFE insert. The autoclave was kept at 150 ° C. for 16 h by means of a convection oven. After cooling to room temperature, the yellow powder was filtered, washed twice with DMF and then with ethanol.

The yield was 760 mg.

After activation of a sample of the material obtained at 120 ° C. and 10 ^-3 mbar, a nitrogen adsorption isotherm ( 1 ) recorded at 77K. At p / po = 0.3, a specific surface area of 1134 m ² / g could be determined from this isotherm using the one-point BET method (DIN ISO 9277: 2014).

The X-ray powder diffractogram ( 2 ) of the sample shows the reflections of NH ₂ -MIL-125 (Ti) at the expected positions.

Synthesis of MIL-100 (Al)

Based on literature: Volkrieger et al., Chem. Mater. 2009, 21, 5695-5697 ,

A mixture of 11.2 mmol of Al (NO ₃ ) ₃ .9H ₂ O (Grüssing, 99%), 9.1 mmol of trimesic acid trimethyl ester (from intrinsic synthesis), 14 mL of 1 M HNO ₃ and 50.4 mL of deionized H ₂ O was transferred to a 250 mL steel autoclave (DAB-3 from Berghof) with PTFE insert. The autoclave was heated for 3 h 30 min at 210 ° C in a drying oven.

After cooling to room temperature, the product was separated from the yellow mother liquor by means of a laboratory centrifuge at 4000 rpm. For washing the precipitate, it was resuspended in 50 ml of ethanol and again centrifuged under the same conditions and the washing solution was discarded. This washing process was then repeated 2 more times. After drying the resulting solid at room temperature at 10 ^-3 mbar for 16 h last so 6.3 g of crude product were obtained.

This crude product contained in the pores trapped impurities that reduce the porosity. To remove these impurities, the product was resuspended in 400 mL of N, N-dimethylformamide and the suspension in a 1 liter Schott bottle inside a drying oven for 4 h at 150 ° C held. The solid was then removed by centrifugation, taken up in 50 ml of deionized water, centrifuged again and the washing water was discarded.

The product thus obtained was finally purified by means of a Soxhlet apparatus using 0.5 L of deionized water for 12 h and then desolvated at 220 ° C. and 10 ^-3 mbar for 4 h.

In this way, 2.0 g of a white, light solid was obtained.

Without further activation of the material, a nitrogen adsorption isotherm ( 3 ) recorded at 77K. At p / po = 0.3, this isotherm could be determined using the one-point BET method ( DIN ISO 9277: 2014 ) a specific surface area of 1637 m ² / g can be determined.

The X-ray powder diffractogram ( 4 ) of the sample shows the reflections of MIL-100 (Al) at the expected positions.

Synthesis of NH ₂ -MIL-101 (Al)

Based on literature: M. Hartmann, M. Fischer, Microporous Mesoporous Mater. 2012, 164, 38-43 ,

30 mmol 2-aminoterephthalic acid (Aldrich, 99%) were dissolved in 1.1 L N, N-dimethylformamide and heated to 110 ° C in a 2-liter three-necked flask at reflux.

60 mmol of AlCl ₃ .6H ₂ O (Fluka, 99%) were divided into seven equal portions. Each portion was dissolved with warming in 14 mL of N, N-dimethylformamide and stored sealed for further use.

At a time interval of 15 minutes and with magnetic stirring, the individual aluminum chloride solutions were added to the hot solution of 2-aminoterephthalic acid. After the last addition, the solution was kept at 110 ° C. for a further 3 h with stirring, then for a further 16 h without stirring.

After cooling to room temperature, the mixture was filtered through a frit G4 and there 1 × 200 mL of N, N-dimethylformamide and washed with 5x200 mL of ethanol.

The product thus obtained was extracted by means of a Soxhlet apparatus using 1 L of ethanol for 12 h and then dried at 90 ° C for 24 h in a drying oven.

There were obtained 6.95 g of product.

After activation of a sample of the material obtained at 120 ° C. and 10 ^-3 mbar, a nitrogen adsorption isotherm ( 5 ) recorded at 77K. At p / po = 0.3, a specific surface area of 2839 m ² / g could be determined from this isotherm using the one-point BET method (DIN ISO 9277: 2014).

The X-ray powder diffractogram ( 6 ) of the sample shows the reflections of NH ₂ -MIL-101 (Al) at the expected positions.

formulations:

The particles produced under 1 were used in the compositions described below: sprayable transparent to opaque antiperspirant and / or deodorant microemulsions according to the invention (amounts in% by weight) 1.1 1.2 1.3 Lauryl glucoside, about 50% AS 1.7 1.7 - Decylglucoside, about 50% AS 1.15 1.4 2.4 Glycerol monooleate 0.7 0.7 - dioctyl 4 4, 0.1 octyldodecanol 1 1 0.02 Perfume 1 1 1 propylene glycol 5 5 - glycerin - - 5 2-Benzylheptanol 0.5 - - triethylcitrate - 0.5 2.0 MIL-100 (Al) 1.0 0.5 2.0 pH adjusters ad pH ad pH ad pH Water, distilled ad 100 ad 100 ad 100

The formulations 1.1 to 1.3 are applied by means of a suitable spraying system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As a propellant, for example Air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutane and dimethyl ether can be used. Antiperspirant and / or Deodorising Cosmetic Compositions According to the Invention in the Form of Emulsions (O / W) (All Quantities in% by Weight) 2.1 2.2 2.3 2.4 2.5 Steareth-2 2.4 2.2 2.2 2.5 2.5 Steareth-21 1.6 1.4 1.4 1.5 1.5 Perfume 1.2 1.0 1.0 1.2 1.2 PPG-15 stearyl ether 0.5 1.5 1.5 2.0 2.0 Aluminum Starch Octenylsuccinate 0.1 - - - - MIL-100 (Al) 1.5 - - 10.0 5.0 NH ₂ -MIL-101 (A1) - 1.0 0.5 - - deodorant active 1 0.5 3 1 1.0 pH adjusters ad pH ad pH ad pH ad pH ad pH Water, distilled ad 100.0 ad 100.0 ad 100.0 ad 100.0 ad 100.00 Deodorant emulsions (O / W) according to the invention (in% by weight) 3.1 3.2 3.3 3.4 Steareth-2 2.4 2.8 3.0 2.5 Steareth-21 1.5 2.0 3.0 4.0 Perfume 1.2 1.0 0.7 1.2 PPG-15 stearyl ether 0.5 3.0 4.0 2.0 propylene glycol 3.0 5.0 2.0 1.0 MIL-100 (Al) 0.5 1.0 0.5 5.0 Tetrasodium EDTA 0.1 0.05 0.08 0.2 benzalkonium chloride 0.1 0.05 0.08 0.1 deodorant active 1 0.5 3 1 Water, distilled ad 100.0 ad 100.0 ad 100.0 ad 100.0

The formulations 3.1 to 3.4 are applied by means of a suitable spraying system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutane and dimethyl ether can be used. Deodorants according to the invention (in% by weight) 4.1 4.2 4.3 Alcohol denate. (96%, cosmetic grade) 55.0 55.0 55.0 triethylcitrate 3.0 3.0 3.0 PEG-40 Hydrogenated Castor Oil, Propylene Glycol 0.5 0.5 0.5 phenoxyethanol 1.0 1.0 1.0 2-Benzylheptanol 0.3 0.1 0.0 Cocamidopropyl PG-Dimonium Chloride Phosphate 0.5 0.3 0.4 MIL-100 (Al) 1.5 1.0 0.5 Perfume 1.0 1.0 1.0 pH adjusters - ad pH - Water, distilled ad 100 ad 100 ad 100

The formulations 4.1 to 4.3 are applied by means of a suitable spray system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutane and dimethyl ether can be used. Antiperspirant and / or deodorant cosmetic compositions according to the invention in the form of W / O emulsions (data in% by weight, based on the propellant-free composition) 5.1 5.2 5.3 C ₁₀ -C ₁₃ isoalkane 8.9 8.9 - cyclopentasiloxane - - 8.9 PEG / PPG-18/18 Dimethicone 1.4 1.4 1.4 Isoceteth-20 0.5 0.5 0.5 Dimethicone 4.2 4.2 4.2 isopropyl 9.0 9.0 9.0 propylene glycol 7.0 25 25 phenoxyethanol 0.5 0.5 0.5 Perfume 2.5 2.5 2.5 MIL-100 (Al) 1.5 1.0 0.5 Water, distilled ad 100 ad 100 ad 100

The formulations 5.1 to 5.3 are applied by means of a suitable spray system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutane and dimethyl ether can be used. In addition, it is possible to apply the formulations 5.1 to 5.3 as an aerosol with high amounts of liquefied gases. For this purpose, 15, 20, 25 or 30 wt .-% of the above formulations each with suitable propellants, such as propane, butane, isobutene, dimethyl ether (individually or in mixtures) (pressure 1.6 to 3.8 bar) to 100 wt. -% filled up. Antiperspirant or deodorant emulsions according to the invention based on phase inversion technology (in% by weight) 6.1 6.2 6.3 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate 5 3.5 5 Ceterath-12 3 13 3 cetearyl 5 6 5 dicaprylyl 5 8th 5 glycerin 0.1 0.2 0.1 Perfume 1 1 1 MIL-100 (Al) 1.5 1.0 0.5 Water, distilled Ad 100 Ad 100 Ad 100

Formulations 6.1 to 6.3 are applied by means of a suitable spraying system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutane and dimethyl ether can be used. Antiperspirant and / or deodorant sticks according to the invention based on O / W emulsions (in% by weight) 7.1 7.2 7.3 7.4 7.5 Ethylene glycol distearate 2.5 2.5 - - - Ethylene glycol monostearate - - 2.5 2.0 - Pentaerythrityl distearate - - - - 2.0 Palmitic acid, stearic acid (1: 1) 3.5 3.5 3.5 3.5 3.5 Ceteareth-20 0.8 0.8 0.8 0.8 0.8 Ceteareth-30 0.8 0.8 0.8 0.8 0.8 diisopropyl 6 6 6 6 6 Cocoglycerides (mp 30-32 ° C) 4 4 4 4 4 cetyl palmitate 5 5 5 5 5 Hydrogenated castor oil 4 4 4 4 4 cetearyl 5 5 5 5 5 talc 10 10 10 10 10 Perfume 1.2 1.2 1.2 1.2 1.2 ethyl hexyl glycerin 0.6 0.6 0.6 0.6 0.6 MIL-100 (Al) 1.5 1.0 0.5 1.0 10.0 propylene glycol 10 10 10 10 10 Water, distilled ad 100.0 ad 100.0 ad 100.0 ad 100.0 ad 100.0 Antiperspirant and / or deodorant emulsions (O / W) according to the invention (in% by weight) 8.1 8.2 8.3 Steareth-2 2.4 2.2 2.2 Steareth-21 1.6 1.4 1.4 Perfume 1.2 1.0 1.0 PPG-15 stearyl ether 0.5 1.5 1.5 Aluminum starch ocetenyl succinate 0.1 - - MIL-100 (Al) 1.5 1.0 0.5 deodorant active 2 1 0.5 pH adjusters ad pH ad pH ad pH Water, distilled ad 100.0 ad 100.0 ad 100.0

The O / W emulsions of formulations 8.1 to 8.3 can be applied by means of a roll-on applicator. Soap-based deodorant sticks according to the invention (in% by weight) 9.1 9.2 9.3 Palmitic acid, stearic acid (1: 1) 4.4 4.4 4.4 1,3-butylene glycol 31.7 31.7 31.7 propylene glycol 21.0 21.0 21.0 octyldodecanol 2.0 2.0 2.0 PPG-5 laureth-5 3.0 3.0 3.0 PEG-40 Hydrogenated Castor Oil, Propylene Glycol 0.05 0.05 0.05 Sodium hydroxide 45% 1.45 1.45 1.45 phenoxyethanol 1.0 1.0 1.0 ethyl hexyl glycerin 0.3 0.3 0.3 Perfume 2.0 1.0 2.0 MIL-100 (Al) 1.5 1.0 5.0 2-Benzylheptanol 0.3 - - deodorant active 0.05 0.5 3.0 Alcohol denate. (96%, cosmetic grade) ad 100 ad 100 ad 100 Antiperspirant and / or deodorant roll-ons according to the invention (in% by weight) 10.1 10.2 10.3 Alcohol denate. (96%, cosmetic grade) 30.0 30.0 30.0 Ceteareth-10 2.0 2.0 2.0 Ceteareth-30 2.0 2.0 2.0 hydroxyethyl 0.5 0.5 0.5 MIL-100 (Al) 1.5 1.0 0.5 Cocamidopropyl PG-Dimonium Chloride Phosphate 0.4 0.4 0.4 Perfume 0.8 0.8 0.8 pH adjusters ad pH ad pH ad pH Water, distilled ad 100 ad 100 ad 100

The O / W emulsions of formulations 10.1 to 10.3 can be applied by means of a roll-on applicator. Solid W / O emulsions according to the invention (in% by weight) 11.1 11.2 11.3 propylene glycol 13.0 13.0 13.0 cyclohexasiloxane 6.0 6.0 6.0 C12-15 alkyl benzoate 8.0 8.0 8.0 Cetyl PEG / PPG-10/1 dimethicone 1.2 1.2 1.2 Polyethylene wax (MW = 500 g / mol, mp = 83 to 81 ° C) 10.0 10.0 10.0 Polyalphaolefin wax (MW = 1800 g / mol, mp = 41 ° C) 0.1 0.1 0.1 polysaccharide 2.00 0.5 0.5 Tetrasodium EDTA - 0.05 0.05 MIL-100 (Al) 1.5 1.0 10.0 deodorant active 1 0.5 3.0 Perfume 1 1 1 Water, distilled 25.0 25.0 25.0 Antiperspirant and / or deodorant gels according to the invention in the form of W / O emulsions (in% by weight) 12.1 12.2 cyclopentasiloxane 14.0 14.0 Bis-PEG / PPG-14/14 Dimethicone 2.5 3.0 Alcohol denate. (96%, cosmetic grade) 10.0 10.0 propylene glycol 20.3 20.3 MIL-100 (Al) 1.5 1.0 deodorant active 1 0.5 Perfume 1.0 1.0 Water, distilled 11.6 11.6

The formulations 12.1 and 12.2 can be applied in a suitable gel applicator, from a tube or a crucible. Antiperspirant and / or Deodorant Emulsion Rolls According to the Invention (in% by Weight) 13.1 13.2 Natriumstearoylglutamat 0.5 0.7 stearyl 2.5 1.5 Caprylic / Capric Triglycerides 2.5 2.5 Polyglyceryl-3-Dicitrate / Stearate 1.0 0.8 hydroxyethyl 0.25 0.25 propylene glycol 5 5 MIL-100 (Al) 1.5 1.0 deodorant active 1 1.0 Perfume 1 1 Water, distilled Ad 100 Ad 100

The O / W emulsions of formulations 13.1 and 13.2 can be applied by means of a roll-on applicator. Antiperspirant and / or deodorant cream according to the invention (in% by weight) 14.1 Ceteareth-10 1.5 Ceteareth-20 1.5 behenyl 43.5 glyceryl stearate 5 Hexyldecanol, hexyldecyl laurate (1: 1) 2.5 Dimethicone (350 Cst) 2 cyclopentasiloxane 1 allantoin 0.3 Perfume 1.3 MIL-100 (Al) 5.0 deodorant active 0.5 Water, distilled Ad 100

The antiperspirant cream 14.1 can be applied from a suitable gel applicator, a tube or a jar. Anhydrous solid antiperspirant and / or deodorant stick matrices according to the invention (in% by weight) 15.1 15.2 15.3 hexyldecanol 10 - - dicaprylyl - 10 15 PPG-14 butyl ether 5 5 5 Hydrogenated Castor Oil 6 6 6 stearyl 20 22 20 Ceteareth-30 3 3 3 crystal water 4 4.5 5 talc 16 7 8th deodorant active 0.00051 0.5 2.0 MIL-100 (Al) 1.0 2.5 5.0 cyclopentasiloxane ad 100.0 ad 100.0 ad 100.0

The solid matrix of Examples 15.1 to 15.3 can be filled for application in a pen holder. Anhydrous solid antiperspirant and / or deodorant stick matrices according to the invention (in% by weight) 16.1 16.2 Hydrogenated Castor Oil 2.8 2.8 stearyl 25 22 cetyl alcohol 0.4 0.4 Arachidylalcohol 0.1 0.1 PPG-14 butyl ether 14.0 14.0 Myristylmyristate 1.9 1.9 talc 10.0 3.0 MIL-100 (Al) 1.0 2.5 cyclopentasiloxane ad 100.0 ad 100.0

The solid matrix of Examples 16.1 and 16.3 can be filled for application in a pen holder. Anhydrous solid antiperspirant and / or deodorant stick matrices according to the invention (in% by weight) 17.1 17.2 17.3 17.4 17.5 17.6 Hydrogenated Castor Oil 1.5 1.5 1.5 1.5 1.5 1.5 stearyl 18 18 18 20 20 20 Cocoglycerides (mp 30-32 ° C) 4 4 4 4 4 4 PPG-14 butyl ether 15.3 15.3 15.3 10 10 10 PEG-40 stearate - 3 - - 3 - talc 10 3 3 0 0 0 Perfume 1 1 1 1 1 1 Ceteareth-10 - - 3 - - 3 deodorant active 0.00051 0.5 2.0 0.00051 0.5 2.0 MIL-100 (Al) 1.0 2.5 5.0 1.0 2.5 5.0 cyclopentasiloxane ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 * average particle size Dso 3 - 20 μm

The solid matrix of Examples 17.1 to 17.6 can be filled for application in a pen holder. Anhydrous deodorant sprays according to the invention (in% by weight) 18.1 18.2 18.3 Alcohol denate. (99.9%, cosmetic grade) 18.0 22.0 25.0 1,2-hexanediol ** 0.1 0.2 0.1 Caprylylglycol ** 0.1 0.2 0.1 triethylcitrate 1.5 2, 5 3.0 Cocamidopropyl PG-dimonium chloride phosphate 0.1 0.1 0.2 ethyl hexyl glycerin 0.3 0.5 0.3 2-Benzylheptanol * 0.1 0.1 0.2 benzyl alcohol *** 0.1 0.1 0.1 phenoxyethanol * 0.4 0.4 1.0 Perfume 0.7 0.7 0.7 MIL-100 (Al) 1.0 2.5 0.5 propane 9.0 12.0 9.0 isobutane 0.0 1.0 2.0 butane ad 100.0 ad 100.0 ad 100.0 * / ** Component of raw material combinations; ** perfume ingredient

The compositions of Examples 18.1 to 18.3 can be applied by means of a suitable spraying system, such as an aerosol with high volumes of liquefied gases. In addition, it is also possible, in addition to the above-mentioned propellants and liquefied propane, butane, isobutene or dimethyl ether used alone or in mixtures. Anhydrous antiperspirant and / or deodorant suspension sprays according to the invention (in% by weight) 19.1 19.2 19.3 isopropyl 1.5 - 1.0 deodorant active 1.0 0.5 13.0 MIL-100 (Al) 1.0 3.5 0.5 ethylhexyl palmitate - 1.0 2.0 L-Menthol 0.07 - - menthyl - 0.07 - propylene carbonate 0.13 0.13 0.2 Disteardimoniumhectorit 0.38 0.38 0.5 Perfume 1.36 1.36 1 propane 12.0 12.0 12.0 n-butane 71.1 71.1 71.1 isobutane 1.5 1.5 1.5 cyclopentasiloxane ad 100 ad 100 ad 100

The compositions of Examples 19.1 to 19.3 can be applied by means of a suitable spraying system, such as an aerosol with high volumes of liquefied gases. In addition, it is also possible to use in addition to the aforementioned propellants and liquefied propane, butane, isobutane or dimethyl ether alone or in mixtures. Anhydrous antiperspirant and / or deodorant suspension sprays according to the invention (in% by weight) 20.1 20.2 20.3 isopropyl 1.0 1.0 0.7 triethylcitrate 0.6 0.6 0.6 MIL-100 (Al) 1.0 1.0 0.5 ethylhexyl palmitate 4.5 4.5 2.5 Dimethicone (5Cst) 1.5 - - Dimethicone (350 Cst) - 1.5 propylene carbonate 0.1 0.1 0.1 Disteardimoniumhectorit 0.4 0.4 0.4 Perfume 1.0 1.0 1.0 propane 10.4 10.4 10.4 n-butane 70.0 70.0 70.0 isobutane 2.1 2.1 2.1 cyclopentasiloxane ad 100 ad 100 ad 100

The compositions of Examples 20.1 to 20.3 can be applied by means of a suitable spraying system, such as an aerosol with high volumes of liquefied gases. In addition, it is also possible to use in addition to the aforementioned propellants and liquefied propane, butane, isobutane or dimethyl ether alone or in mixtures. Anhydrous deodorant concentrates according to the invention (solutions or suspensions) (in% by weight) 21.1 21.2 21.3 triethylcitrate 8th 10 5.0 ethyl hexyl glycerin 1.0 0 2.0 deodorant active 1.0 0.2 3.0 Deodorant agent (powder) 3.0 phenoxyethanol 1.0 2.0 - MIL-100 (Al) 1.0 1.0 0.5 Dimethicone (5Cst) 10.0 5.0 10.0 propylene carbonate - - 0.5 Disteardimoniumhectorit - - 2.0 Perfume 5.0 3.0 4.0 cyclopentasiloxane 60 50.0 60.0 ethylhexyl palmitate ad 100 ad 100 ad 100

The compositions of Examples 20.1 to 20.3 can be applied by means of a suitable spraying system, such as an aerosol with high volumes of liquefied gases. In addition, it is also possible to use in addition to the aforementioned propellants and liquefied propane, butane, isobutane or dimethyl ether alone or in mixtures. In this case, 10 to 30 wt .-% of the concentrate of Examples 20.1 to 20.3 and 70 to 90 wt .-% of the above-mentioned blowing agents are mixed together. Anhydrous antiperspirant and / or deodorant cream (soft solid) according to the invention - suspension type (in% by weight) 22.1 22.2 22.3 C ₂₀ -C ₄₀ alcohols 2.0 2,5- 1.5 Cyclomethicone, Dimethicone Crosspolymer 0.5 0.7 1.0 stearyl 3.0 3.5 2.5 C18-36 Acid triglycerides 1.5 1.2 2.0 silica 0.5 1.0 0.8 talc 15.0 5.0 4.0 Aluminum Starch Octenylsuccinate 10.0 5.0 3.0 PEG-8 distearate 4.2 3.5 4.6 PPG-14 butyl ether 6.0 5.0 8.0 PEG-12 Dimethicone 3.5 4.0 5.0 Perfume 1.2 1.0 1.5 deodorant active 0.5 1.0 3.0 MIL-100 (Al) 1.0 0.5 2.0 cyclopentasiloxane ad 100 ad 100 ad 100

Examples 22.1 to 22.3 can be applied by means of a suitable cream / soft solid applicator, from a tube or a crucible. Anhydrous antiperspirant and / or deodorant roll-ons according to the invention - suspension type (in% by weight) 23.1 23.2 23.3 23.4 Disteardimoniumhectorite 4.0 5.0 3.0 4.0 propylene carbonate 1.0 1.2 2.0 0.7 Perfume 0.5 1.0 0.3 1.5 tocopheryl acetate 0.2 0.05 0.3 0.1 Plantextract hydrophobic 0.5 0.1 1.0 2.0 PPG-14 butyl ether 20 0 0 0 C12-15 alkyl benzoate 0 0 0 20 deodorant active 0.5 1.0 3.0 0.001 MIL-100 (Al) 1.0 0.5 2.0 5.0 cyclopentasiloxane ad 100 ad 100 ad 100 ad 100

The formulations of Examples 23.1 to 23.4 can be applied by means of a roll-on applicator.

Antiperspirant wipes according to the invention (impregnated with all the examples given above except Examples 7.1 to 7.5, 9.1 to 9.3, 11.1 to 11.3, 15.1 to 15.3, 16.1 and 16.2 and 17.1 to 17.6) The wipes may consist of single-layer or multi-layer substrates, such as cellulose, Cotton or viscose be prepared and may for example have a weight of 50 g per m ² . These wipes are soaked with 30 to 100 g per m ^{2 of} the examples given above and cut to a size suitable for use. Sprayable transparent to opaque antiperspirant microemulsions according to the invention (amounts in% by weight) 1.1 1.2 1.3 Lauryl glucoside, about 50% AS 1.7 1.7 - Decyl glucoside, about 50% AS 1.15 1.4 2.4 Glycerol monooleate 0.7 0.7 - dioctyl 4 4, 0.1 octyldodecanol 1 1 0.02 Perfume 1 1 1 aluminum chlorohydrate 8th 5 5 propylene glycol 5 5 - glycerin - - 5 2-Benzylheptanol 0.5 - - triethylcitrate - 0.5 2.0 MIL-100 (Al) 1.0 0.5 2.0 Water, distilled ad 100 ad 100 ad 100

The formulations 1.1 to 1.3 are applied by means of a suitable spraying system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutene and dimethyl ether can be used. Antiperspirant cosmetic agents according to the invention in the form of emulsions (O / W) (all amounts in% by weight) 2.1 2.2 2.3 2.4 2.5 Aluminum Zirconium Tetrachlorohydrex Gly 23.7 - - - - Aluminum chlorohydrate about 50% AS - 40.0 30.0 20.0 - Aluminum sesquichlorohydrate 40% AS - - - - 25.0 Steareth-2 2.4 2.2 2.2 2.5 2.5 Steareth-21 1.6 1.4 1.4 1.5 1.5 Perfume 1.2 1.0 1.0 1.2 1.2 PPG-15 stearyl ether 0.5 1.5 1.5 2.0 2.0 Aluminum Starch Octenylsuccinate 0.1 - - - - MIL-100 (Al) 1.5 1.0 0.5 1.0 1.0 deodorant active 1 0.5 3 1 1.0 Water, distilled ad 100.0 ad 100.0 ad 100.0 ad 100.0 ad 100.00 Antiperspirant cosmetic agents according to the invention in the form of W / O emulsions (data in% by weight, based on the propellant-free composition) 5.1 5.2 5.3 Aluminum chlorohydrate about 50% AS 50 50 - Aluminum sesquichlorohydrate 40% AS - - 40 C ₁₀ -C ₁₃ isoalkane 8.9 8.9 cyclopentasiloxane 8.9 PEG / PPG-18/18 Dimethicone 1.4 1.4 1.4 Isoceteth-20 0.5 0.5 0.5 Dimethicone 4.2 4.2 4.2 isopropyl 9.0 9.0 9.0 propylene glycol 7.0 25 25 phenoxyethanol 0.5 0.5 0.5 Perfume 2.5 2.5 2.5 MIL-100 (Al) 1.5 1.0 0.5 Water, distilled ad 100 ad 100 ad 100

The formulations 5.1 to 5.3 are applied by means of a suitable spray system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutene and dimethyl ether can be used. In addition, it is possible to apply the formulations 5.1 to 5.3 as an aerosol with high amounts of liquefied gases. For this purpose, 15, 20, 25 or 30 wt .-% of the above formulations each with suitable propellants, such as propane, butane, isobutene, dimethyl ether (individually or in mixtures) (pressure 1.6 to 3.8 bar) to 100 wt. -% filled up. Antiperspirant or deodorant emulsions according to the invention based on phase inversion technology (in% by weight) 6.1 6.2 6.3 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate 5 3.5 5 Ceterath-12 3 13 3 cetearyl 5 6 5 dicaprylyl 5 8th 5 glycerin 0.1 0.2 0.1 Perfume 1 1 1 Aluminum chlorohydrate about 50% AS 40 30 - MIL-100 (Al) 1.5 1.0 0.5 Water, distilled Ad 100 Ad 100 Ad 100

Formulations 6.1 to 6.3 are applied by means of a suitable spraying system. Suitable spray systems are pump dispensers and propellant-containing aerosols. As blowing agents, for example, air, nitrogen oxide, nitrogen, carbon dioxide and other compressed gases or liquefied gases such as propane, butane, isobutene and dimethyl ether can be used. Antiperspirant sticks according to the invention based on O / W emulsions (in% by weight) 7.1 7.2 7.3 7.4 7.5 Ethylene glycol distearate 2.5 2.5 - - - Ethylene glycol monostearate - - 2.5 2.0 - Pentaerythrityl distearate - - - - 2.0 Palmitic acid, stearic acid (1: 1) 3.5 3.5 3.5 3.5 3.5 Ceteareth-20 0.8 0.8 0.8 0.8 0.8 Ceteareth-30 0.8 0.8 0.8 0.8 0.8 diisopropyl 6 6 6 6 6 Cocoglycerides (mp 30-32 ° C) 4 4 4 4 4 cetyl palmitate 5 5 5 5 5 Hydrogenated castor oil 4 4 4 4 4 cetearyl 5 5 5 5 5 Aluminum chlorohydrate about 50% AS 40 40 40 40 40 talc 10 10 10 10 10 Perfume 1.2 1.2 1.2 1.2 1.2 ethyl hexyl glycerin 0.6 0.6 0.6 0.6 0.6 MIL-100 (Al) 1.5 1.0 0.5 1.0 2.0 propylene glycol 10 10 10 10 10 Water, distilled ad 100.0 ad 100.0 ad 100.0 ad 100.0 ad 100.0 Antiperspirant emulsions (O / W) according to the invention (in% by weight) 8.1 8.2 8.3 Aluminum zirconium tetrachlorohydrex-Gly 23.7 - - Aluminum chlorohydrate about 50% AS - 30.0 30.0 Steareth-2 2.4 2.2 2.2 Steareth-21 1.6 1.4 1.4 Perfume 1.2 1.0 1.0 PPG-15 stearyl ether 0.5 1.5 1.5 Aluminum starch ocetenyl succinate 0.1 - - MIL-100 (Al) 1.5 1.0 0.5 deodorant active 2 1 0.5 Water, distilled ad 100.0 ad 100.0 ad 100.0

The O / W emulsions of formulations 8.1 to 8.3 can be applied by means of a roll-on applicator. Antiperspirant roll-ons according to the invention (in% by weight) 10.1 10.2 10.3 Alcohol denate. (96%, cosmetic grade) 30.0 30.0 30.0 Ceteareth-10 2.0 2.0 2.0 Ceteareth-30 2.0 2.0 2.0 aluminum chlorohydrate 10.0 20.0 20.0 hydroxyethyl 0.5 0.5 0.5 MIL-100 (Al) 1.5 1.0 0.5 Cocamidopropyl PG-Dimonium Chloride Phosphate 0.4 0.4 0.4 Perfume 0.8 0.8 0.8 Water, distilled ad 100 ad 100 ad 100

The O / W emulsions of formulations 10.1 to 10.3 can be applied by means of a roll-on applicator. Solid W / O emulsions according to the invention (in% by weight) 11.1 11.2 11.3 Aluminum chlorohydrate about 50% AS 35.6 35.6 35.6 propylene glycol 13.0 13.0 13.0 cyclohexasiloxane 6.0 6.0 6.0 C12-15 alkyl benzoate 8.0 8.0 8.0 Cetyl PEG / PPG-10/1 dimethicone 1.2 1.2 1.2 Polyethylene wax (MW = 500 g / mol, mp = 83 to 81 ° C) 10.0 10.0 10.0 Polyalphaolefin wax (MW = 1800 g / mol, mp = 41 ° C) 0.1 0.1 0.1 polysaccharide 2.00 0.5 0.5 Tetrasodium EDTA - 0.05 0.05 MIL-100 (Al) 1.5 1.0 0.5 deodorant active 1 0.5 3.0 Perfume 1 1 1 Water, distilled 25.0 25.0 25.0 Antiperspirant gels according to the invention in the form of W / O emulsions (in% by weight) 12.1 12.2 cyclopentasiloxane 14.0 14.0 Bis-PEG / PPG-14/14 Dimethicone 2.5 3.0 Alcohol denate. (96%, cosmetic grade) 10.0 10.0 Aluminum chlorohydrate about 50% AS 40.0 40.0 propylene glycol 20.3 20.3 MIL-100 (Al) 1.5 1.0 deodorant active 1 0.5 Perfume 1.0 1.0 Water, distilled 11.6 11.6

The formulations 12.1 and 12.2 can be applied in a suitable gel applicator, from a tube or a crucible. Antiperspirant emulsion roll ons according to the invention (in% by weight) 13.1 13.2 Natriumstearoylglutamat 0.5 0.7 stearyl 2.5 1.5 Caprylic / Capric Triglycerides 2.5 2.5 Polyglyceryl-3-Dicitrate / Stearate 1.0 0.8 hydroxyethyl 0.25 0.25 Aluminum chlorohydrate about 50% AS 40 20 propylene glycol 5 5 MIL-100 (Al) 1.5 1.0 deodorant active 1 1.0 Perfume 1 1 Water, distilled Ad 100 Ad 100

The O / W emulsions of formulations 13.1 and 13.2 can be applied by means of a roll-on applicator. Antiperspirant cream according to the invention (in% by weight) 14.1 Ceteareth-10 1.5 Ceteareth-20 1.5 behenyl 43.5 glyceryl stearate 5 Hexyldecanol, hexyldecyl laurate (1: 1) 2.5 Dimethicone (350 Cst) 2 cyclopentasiloxane 1 allantoin 0.3 Aluminum chlorohydrate about 50% AS 16 Perfume 1.3 MIL-100 (Al) 1.5 deodorant active 0.5 Water, distilled Ad 100

The antiperspirant cream 14.1 can be applied from a suitable gel applicator, a tube or a jar. Anhydrous solid antiperspirant stick matrices according to the invention (in% by weight) 15.1 15.2 15.3 hexyldecanol 10 - - dicaprylyl - 10 15 PPG-14 butyl ether 5 5 5 Hydrogenated Castor Oil 6 6 6 stearyl 20 20 20 Ceteareth-30 3 3 3 Aluminum Chlorohydrate (USP) (Powder) 16 18 20 crystal water 4 4.5 5 talc 8th 7 8th deodorant active 0.00051 0.5 2.0 MIL-100 (Al) 1.0 2.5 5.0 cyclopentasiloxane ad 100.0 ad 100.0 ad 100.0

The solid matrix of Examples 15.1 to 15.3 can be filled for application in a pen holder. Anhydrous solid antiperspirant stick matrices according to the invention (in% by weight) 16.1 16.2 Hydrogenated Castor Oil 2.8 2.8 stearyl 22 22 cetyl alcohol 0.4 0.4 Arachidylalcohol 0.1 0.1 PPG-14 butyl ether 14.0 14.0 Myristylmyristate 1.9 1.9 Aluminum Chlorohydrate (USP) (Powder) 18 - Aluminum Zirconium Trichlorohydrey Gly (Powder) - 18 talc 3.0 3.0 MIL-100 (Al) 1.0 2.5 cyclopentasiloxane ad 100.0 ad 100.0

The solid matrix of Examples 16.1 and 16.3 can be filled for application in a pen holder. Anhydrous solid antiperspirant stick matrices according to the invention (in% by weight) 17.1 17.2 17.3 17.4 17.5 17.6 Hydrogenated Castor Oil 1.5 1.5 1.5 1.5 1.5 1.5 stearyl 18 18 18 20 20 20 Cocoglycerides (mp 30-32 ° C) 4 4 4 4 4 4 PPG-14 butyl ether 15.3 15.3 15.3 10 10 10 PEG-40 stearate - 3 - - 3 - Al-Zr-tetrachlorohydrex Gly * (USP) powder 17.6 17.6 17.6 17.6 17.6 17.6 Crystal water and glycine 4.4 4.4 4.4 4.4 4.4 4.4 talc 3 3 3 0 0 0 Perfume 1 1 1 1 1 1 Ceteareth-10 - - 3 - - 3 deodorant active 0.00051 0.5 2.0 0.00051 0.5 2.0 MIL-100 (Al) 1.0 2.5 5.0 1.0 2.5 5.0 cyclopentasiloxane ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 * average particle size Dso 3 - 20 μm

The solid matrix of Examples 17.1 to 17.6 can be filled for application in a pen holder. Anhydrous antiperspirant suspension sprays according to the invention (in% by weight) 19.1 19.2 19.3 isopropyl 1.5 - 1.0 deodorant active 1.0 0.5 13.0 MIL-100 (Al) 1.0 3.5 0.5 ethylhexyl palmitate - 1.0 2.0 L-Menthol 0.07 - menthyl - 0.07 Activated aluminum chlorohydrate (powder) 5.0 5.0 3.0 propylene carbonate 0.13 0.13 0.2 Disteardimoniumhectorit 0.38 0.38 0.5 Perfume 1.36 1.36 1 propane 12.0 12.0 12.0 n-butane 71.1 71.1 71.1 isobutane 1.5 1.5 1.5 cyclopentasiloxane ad 100 ad 100 ad 100

The compositions of Examples 19.1 to 19.3 can be applied by means of a suitable spraying system, such as an aerosol with high volumes of liquefied gases.

In addition, it is also possible, in addition to the above-mentioned propellants and liquefied propane, butane, isobutene or dimethyl ether used alone or in mixtures. Anhydrous antiperspirant suspension sprays according to the invention (in% by weight) 20.1 20.2 20.3 isopropyl 1.0 1.0 0.7 triethylcitrate 0.6 0.6 0.6 MIL-100 (Al) 1.0 1.0 0.5 ethylhexyl palmitate 4.5 4.5 2.5 Dimethicone (5Cst) 1.5 - - Dimethicone (350 Cst) - 1.5 Activated aluminum chlorohydrate 3.5 2.5 - Activated aluminum sesquichlorohydrate (powder) - - 5.0 propylene carbonate 0.1 0.1 0.1 Disteardimoniumhectorit 0.4 0.4 0.4 Perfume 1.0 1.0 1.0 propane 10.4 10.4 10.4 n-butane 70.0 70.0 70.0 isobutane 2.1 2.1 2.1 cyclopentasiloxane ad 100 ad 100 ad 100

The compositions of Examples 20.1 to 20.3 can be applied by means of a suitable spraying system, such as an aerosol with high volumes of liquefied gases. In addition, it is also possible, in addition to the above-mentioned propellants and liquefied propane, butane, isobutene or dimethyl ether used alone or in mixtures. Anhydrous antiperspirant cream (soft solid) according to the invention - suspension type (in% by weight) 22.1 22.2 22.3 C ₂₀ -C ₄₀ alcohols 2.0 2,5- 1.5 Cyclomethicone, Dimethicone Crosspolymer 0.5 0.7 1.0 stearyl 3.0 3.5 2.5 C18-36 Acid triglycerides 1.5 1.2 2.0 silica 0.5 1.0 0.8 talc 6.0 5.0 4.0 Aluminum Starch Octenylsuccinate 4.0 5.0 3.0 PEG-8 distearate 4.2 3.5 4.6 PPG-14 butyl ether 6.0 5.0 8.0 PEG-12 Dimethicone 3.5 4.0 5.0 Aluminum Zirconium Trichlorohydrex GLY (Powder) 25.0 20.0 0.0 Activated aluminum chlorohydrate (powder) 0.0 0.0 20.0 Perfume 1.2 1.0 1.5 deodorant active 0.5 1.0 3.0 MIL-100 (Al) 1.0 0.5 2.0 cyclopentasiloxane ad 100 ad 100 ad 100

Examples 22.1 to 22.3 can be applied by means of a suitable cream / soft solid applicator, from a tube or a crucible. Anhydrous antiperspirant roll-ons according to the invention - suspension type (in% by weight) 23.1 23.2 23.3 23.4 Aluminum zirconium pentachlorohydr. Gly (powder) 20 24 0.0 0.0 Activated aluminum chlorohydrate (powder) 0 0 20.0 20.0 Disteardimoniumhectorite 4.0 5.0 3.0 4.0 propylene carbonate 1.0 1.2 2.0 0.7 Perfume 0.5 1.0 0.3 1.5 tocopheryl acetate 0.2 0.05 0.3 0.1 Plantextract hydrophobic 0.5 0.1 1.0 2.0 PPG-14 butyl ether 20 0 0 0 C12-15 alkyl benzoate 0 0 0 20 deodorant active 0.5 1.0 3.0 0.001 MIL-100 (Al) 1.0 0.5 2.0 5.0 cyclopentasiloxane ad 100 ad 100 ad 100 ad 100

The formulations of Examples 23.1 to 23.4 can be applied by means of a roll-on applicator.

Antiperspirant wipes according to the invention (impregnated with all the examples given above except Examples 7.1 to 7.5, 9.1 to 9.3, 11.1 to 11.3, 15.1 to 15.3, 16.1 and 16.2 and 17.1 to 17.6) The wipes may consist of single-layer or multi-layer substrates, such as cellulose, Cotton or viscose be prepared and may for example have a weight of 50 g per m ² . These wipes are soaked with 30 to 100 g per m ^{2 of} the examples given above and cut to a size suitable for use.

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• DE 19756454 A1 [0108]
• WO 9818441 [0140]

Cited non-patent literature

• DIN 66131 [0041]
• Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd Ed., 1979, Vol. 8, pp. 913-916 [0082]
• H. Janistyn, Handbuch der Kosmetika und Riechstoffe, Hüthig-Verlag Heidelberg, 3rd edition, 1978, volume 1, page 470 and volume 3, pages 68-78 [0099]
• S.-N. Kim et al. Catalysis Today 2013, 204, 85-93 [0202]
• Volkrieger et al., Chem. Mater. 2009, 21, 5695-5697 [0206]
• DIN ISO 9277: 2014 [0212]
• M. Hartmann, M. Fischer, Microporous Mesoporous Mater. 2012, 164, 38-43 [0214]

Claims (11)

Cosmetic composition containing in a cosmetically acceptable carrier at least one Metal Organic Framework (MOF). Cosmetic composition after Claim 1 , characterized in that - based on its weight - 0.00001 to 10 wt .-% Metal Organic Framework (s) (MOFs) contains. Cosmetic composition according to one of Claims 1 or 2 , characterized in that the metal organic framework contains as metallic component aluminum, titanium, zirconium, iron, zinc, bismuth or oxoclusters, hydroxo clusters, hydroxyoxy clusters or mixtures thereof. Cosmetic composition according to one of Claims 1 to 3 , characterized in that the organic ligand (s) (linker) of the Metal Organic Framework is / are selected from linkers of the formulas (Li-1) to (Li-36)

Cosmetic composition according to one of Claims 1 to 4 , characterized in that the organic ligand (s) of the Metal Organic Framework is / are selected from the general formula (Li)

wherein R ¹ to R ⁴ in the general formula (Li) are independently -H, -COOH, -COO ^- , -OH or -NH ₂ . Cosmetic composition according to one of Claims 1 to 5 , characterized in that the Metal Organic Framework (MOF) additionally contains co-linkers, preferred co-linkers being selected from those of the formulas (CoLi-1) to (CoLi-5):

Cosmetic composition according to one of Claims 1 to 6 , characterized in that it contains no halides and / or hydroxy halides of aluminum and / or zirconium. Cosmetic composition according to one of Claims 1 to 7 , characterized in that the cosmetically or dermatologically acceptable carrier is present as a powder, in stick form, as an aerosol spray, pump spray, liquid or gel roll-on application, cream, lotion, emulsion, solution, gel or applied to a substrate. Use of Metal Organic Framework (s) (MOFs) in Cosmetics. Use after Claim 9 to combat body odor. Process for the treatment of body odor, characterized in that a preparation according to one of Claims 1 to 8th is applied to the skin.