DE102008031893A1 - Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas - Google Patents
Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas Download PDFInfo
- Publication number
- DE102008031893A1 DE102008031893A1 DE102008031893A DE102008031893A DE102008031893A1 DE 102008031893 A1 DE102008031893 A1 DE 102008031893A1 DE 102008031893 A DE102008031893 A DE 102008031893A DE 102008031893 A DE102008031893 A DE 102008031893A DE 102008031893 A1 DE102008031893 A1 DE 102008031893A1
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- Germany
- Prior art keywords
- silver
- contact
- contacting
- paste
- silver compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052709 silver Inorganic materials 0.000 title claims abstract description 45
- 239000004332 silver Substances 0.000 title claims abstract description 44
- 150000003379 silver compounds Chemical class 0.000 title claims abstract description 28
- 229940100890 silver compound Drugs 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 238000001816 cooling Methods 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 21
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910001958 silver carbonate Inorganic materials 0.000 claims abstract description 6
- 239000010953 base metal Substances 0.000 claims abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 48
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000004020 conductor Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000004065 semiconductor Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 description 5
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 4
- 229910000679 solder Inorganic materials 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000007605 air drying Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002146 bilateral effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- MSNOMDLPLDYDME-UHFFFAOYSA-N gold nickel Chemical compound [Ni].[Au] MSNOMDLPLDYDME-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/34—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material comprising compounds which yield metals when heated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3006—Ag as the principal constituent
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- H01L24/83—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
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- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/052—Cooling means directly associated or integrated with the PV cell, e.g. integrated Peltier elements for active cooling or heat sinks directly associated with the PV cells
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/36—Electric or electronic devices
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- H01L2224/05599—Material
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Abstract
Description
Die vorliegende Erfindung betrifft die Befestigung elektrischer Bauteile über Kontakte mit Kontaktierungspasten, insbesondere Silberpasten.The The present invention relates to the attachment of electrical components via Contacts with contacting pastes, in particular silver pastes.
Bekannte Kontaktierungspasten aus in Lösungsmittel dispergierten Silberflocken (Silberflakes) werden unter Druck in der Größenordnung von 30 MPa bei Temperaturen von ungefähr 300°C gesintert, um eine dünne Schicht von ungefähr 50 μm auf ein elektronisches Bauteil (Chip) aufzutragen. Hierbei wird eine zuverlässige Verbindung von Chip und Substrat geschaffen, die Betriebstemperaturen von über 250°C standhält. Die zu verbindenden Flächen müssen edel sein, insbesondere aus Silber oder Gold bestehen.Known Contacting pastes dispersed in solvent Silver flakes (silver flakes) are under pressure of the order of magnitude of 30 MPa at temperatures of about 300 ° C sintered to a thin layer of about 50 microns on an electronic component (chip) apply. This is a reliable connection of the chip and substrate created, the operating temperatures of over 250 ° C. withstand. The surfaces to be joined must be noble, in particular made of silver or gold.
Nach
Die Aufgabe der vorliegenden Erfindung liegt darin, einerseits Kontaktierungen bereitzustellen, die einen Schmelzpunkt möglichst weit oberhalb eines Weichlots aufweisen und andererseits aber möglichst einfach wie mit Weichlot herstellbar sind. Es sollen elektronische Bauteile mit einem Temperaturanwendungsbereich, der sich bis über 200°C und gegebenenfalls sogar über 250°C erstreckt, leichter auf Substraten befestigt werden, insbesondere dafür die Druckbelastung verringert werden. Hierfür soll eine geeignete Kontaktierungspaste geschaffen werden.The Object of the present invention is, on the one hand contacts to provide a melting point as far as possible above a soft solder and on the other hand as simple as possible as can be produced with soft solder. It should be electronic components with a temperature application range that extends to over 200 ° C and possibly even over 250 ° C. extends, easier to be attached to substrates, in particular for the pressure load to be reduced. Therefor should be created a suitable bonding paste.
Die Lösung der Aufgabe erfolgt mit den Merkmalen der unabhängigen Ansprüche. Bevorzugte Ausführungen sind in den abhängigen Ansprüchen beschrieben.The Solution of the task is done with the characteristics of independent Claims. Preferred embodiments are in the dependent claims.
Beim Zusammenfügen mittels einer elektrisch leitfähigen oder einer wärmeleitfähigen Verbindung zur Kontaktierung zweier Elemente wird erfindungsgemäß eine Silberverbindung zu elementarem Silber zwischen den Kontaktflächen umgesetzt. Das Zusammenfügen erfolgt in einem Ofen oder mittels Heizplatte, insbesondere in einem Umluftkammertrockenschrank oder einem Durchlaufofen mit Heizplattensystemen oder mittels Stempel.At the Assembly by means of an electrically conductive or a thermally conductive compound for contacting two elements according to the invention is a silver compound converted to elemental silver between the contact surfaces. The joining takes place in an oven or by means of a heating plate, especially in a circulating air drying oven or a continuous furnace with hotplate systems or by means of stamps.
Maßgeblich für die vorliegende Erfindung ist, dass die mechanische Befestigung von Bauteilen über deren Kontakte erfolgt, die vorzugsweise zusätzlich als elektrische und/oder wärmeleitende Verbindungen nutzbar sind.decisive for the present invention is that the mechanical Attachment of components via their contacts, which preferably additionally as electrical and / or heat-conducting Connections are usable.
Vorzugsweise
- • ist die Silberverbindung eine organische Silberverbindung oder Silberkarbonat;
- • weist eine Kontaktfläche unedles Metall in der Oberfläche auf;
- • liegt die Prozesstemperatur zur Herstellung der Silberverbindung unterhalb von 400°C;
- • erfolgt die Herstellung der Silberverbindung unter Atmosphärendruck;
- • wird eine Paste, die die Silberverbindung aufweist, auf eine Kontaktfläche aufgetragen.
- The silver compound is an organic silver compound or silver carbonate;
- • has a contact surface of base metal in the surface;
- • the process temperature for producing the silver compound is below 400 ° C;
- The preparation of the silver compound is carried out under atmospheric pressure;
- • a paste containing the silver compound is applied to a contact surface.
Die
Paste enthält vorzugsweise ein Gel gemäß
Silberverbindungen, die sich unter 300°C, insbesondere unter 250°C zersetzen und dabei elementares Silber bilden, sind besonders geeignet, Sinterpasten bezüglich ihrer Anwendung erheblich zu verbessern. Erfindungsgemäß werden Kontaktierungspasten bereitgestellt, die leicht zersetzbare Silberverbindungen aufweisen. Diese erfindungsgemäßen Pasten ermöglichen ein Kontaktieren bei niederem Anpressdruck, insbesondere unter 5 bar, vorzugsweise unter 3 bar und eine Prozesstemperatur von ca. 230°C, d. h. unter 250°C, insbesondere unter 240°C.Silver compounds, which is below 300 ° C, especially below 250 ° C. decompose and thereby form elemental silver, are particularly suitable sintered pastes significantly improve their application. According to the invention Contacting pastes provided the easily decomposable silver compounds exhibit. These pastes according to the invention enable a contact at low contact pressure, in particular under 5 bar, preferably below 3 bar and a process temperature of about 230 ° C, d. H. below 250 ° C, especially below 240 ° C.
Die erfindungsgemäße Kontaktierung zwischen den Oberflächen ist bei über 200°C temperaturwechselbeständig, und zwar über 2.000 Zyklen. Damit übertrifft die Kontaktierungspaste die mit Weichlotlegierungen oder Leitklebern erzielbare Temperaturbeständigkeit und Temperatur- Wechselbeständigkeit. Im Rahmen der vorliegenden Erfindung wird es somit ermöglicht, dass die Kontaktierungstemperatur der Kontaktierungspaste unter der Betriebstemperatur der mit der Paste hergestellten Kontakte liegt. Die erfindungsgemäß leicht zersetzlichen Silberverbindungen sind einfacher herstellbar und leichter zu konservieren als Nanosilber. Nanosilber verliert während der Lagerung die gewünschten Eigenschaften, da die Oberfläche durch Agglomeration sich ständig verkleinert und somit zum Fügen nicht mehr geeignet ist.The contacting according to the invention between the surfaces is temperature change resistant at over 200 ° C, over 2,000 cycles. This surpasses the Contact paste with soft solder alloys or conductive adhesives achievable temperature resistance and temperature change resistance. In the context of the present invention, it is thus possible that the contacting temperature of the contacting paste under the operating temperature of the contacts made with the paste lies. The invention easily decomposable Silver compounds are easier to prepare and easier to preserve as nanosilver. Nanosilver loses during storage the desired properties, as the surface Agglomeration constantly shrinking and thus is no longer suitable for joining.
Maßgeblich ist, dass die Paste neben ihren organischen Bestandteilen wie Lösungsmittel und/oder Carbonsäuren 2 bis 20 Gew.-%, insbesondere 5 bis 15 Gew.-% einer leicht zersetzlichen Silberverbindung aufweist, durch die eine Verarbeitung wie mit Weichlot unter 400°C ermöglicht wird. Vorzugsweise bildet die Silberverbindung unter 300°C, insbesondere unter 250°C, metallisches Silber. Geeignete Silberverbindungen sind Silberoxid, Silbercarbonat und insbesondere organische Silberverbindungen. Besonders bewährt hat sich Silberlaktat.It is significant that the paste in addition to its organic constituents such as solvents and / or carboxylic acids from 2 to 20 wt .-%, in particular 5 to 15 wt .-% of a readily decomposable silver compound, which allows processing as with soft solder below 400 ° C. becomes. Preferably, the silver compound forms below 300 ° C, in particular below 250 ° C, metallic silver. Suitable silver compounds are silver oxide, silver carbonate and in particular organic silver compounds. Silver lactate has proven particularly useful.
Es wird vermutet, dass die erfindungsgemäß angewendeten Pasten und Verfahren auf der Bildung von hochreaktivem in situ erzeugtem Silber beruhen, das die Kontaktflächen und die gegebenenfalls in der Paste vorliegenden Feststoffe miteinander verbindet.It it is assumed that the inventively used Pastes and methods based on the formation of highly reactive in situ generated Silver are based on the contact surfaces and, where appropriate in the paste present solids together.
In einer weiteren bevorzugten Ausführung wird eine Paste mit einer leicht zersetzlichen Silberverbindung und Kupferpulver verwendet. Die Teilchengröße des Kupferpulvers beträgt vorzugsweise unter 10 μm.In Another preferred embodiment is a paste with an easily decomposable silver compound and copper powder used. The particle size of the copper powder is preferably less than 10 microns.
Die erfindungsgemäß verwendete Paste eignet sich weiterhin zur Verbindung von unedlen Metalloberflächen, beispielsweise Kupferoberflächen.The Paste used according to the invention is also suitable for the connection of non-precious metal surfaces, for example Copper surfaces.
Erfindungsgemäß wird neben Silberoberflächen auch auf Kupfer- und Nickel-Gold-Oberflächen eine feste Verbindung mit sehr guter elektrischer Leitfähigkeit schon bei ungefähr 230°C gesintert. Die Zugbelastung der Verbindungen beträgt ungefähr 50 MPa.According to the invention in addition to silver surfaces also on copper and nickel-gold surfaces one solid connection with very good electrical conductivity already sintered at about 230 ° C. The tensile load of the compounds is about 50 MPa.
Vorzugsweise
ist die Kontaktierungspaste harzfrei. Insbesondere wird ein Gel
gemäß
Erfindungsgemäß wird eine Niedertemperatur-Sintertechnik (NTV) geschaffen, die die Bonddraht-Technik zurückdrängen wird, da das beidseitige Erwärmen von Bauteilen mit der erfindungsgemäßen Sinterpaste von Vorteil ist.According to the invention A low-temperature sintering technique (NTV) created using the bonding wire technique push back, since the bilateral heating of components with the sintering paste according to the invention is beneficial.
Erfindungsgemäß wird es ermöglicht, dass die Paste anstatt mit Siebdruck mittels Dispensen und insbesondere Schablonendruck oder ein Sprühverfahren aufgetragen wird.According to the invention it allows the paste to be screened instead of screen printed Dispensing and in particular stencil printing or a spraying process is applied.
Im Folgenden wird die Erfindung anhand von Beispielen mit Bezug auf die Abbildungen verdeutlicht.in the Below, the invention will be described by way of example with reference to FIG the pictures clarifies.
Mit
einer erfindungsgemäßen Kontaktierungspaste aus
einem Gel gemäß
Zur Herstellung des Silberkontakts haben sich Umluftkammertrockenschränke oder Durchlauföfen mit Heizplattensystemen oder Stempel (wie Flipchipbonder oder Die Sonder) jeweils mit regelbarem Temperaturprofil unter folgenden Betriebsbedingungen bewährt: Temperaturprofil während der Kontaktierung:
- Aufheizgeschwindigkeit ≥ 0,5 K/s;
- Endtemperatur 230–400°C,
- Prozesszeit vom Aufheizen bis zum Abkühlen 5–60 min
- Ofenatmosphäre: Luft oder Stickstoff (Restsauerstoffgehalt > 1000 ppm) oder Formiergas (Restsauerstoffgehalt > 1000 ppm) oder Vakuum > 10 mbar (Restsauerstoffgehalt > 100 ppm)
- Heating rate ≥ 0.5 K / s;
- Final temperature 230-400 ° C,
- Process time from heating to cooling 5-60 min
- Oven atmosphere: air or nitrogen (residual oxygen content> 1000 ppm) or forming gas (residual oxygen content> 1000 ppm) or vacuum> 10 mbar (residual oxygen content> 100 ppm)
Bei einer Aufheizrate unter 0,3 K/s oder einer Endtemperatur unter 200 oder einer Hitzbehandlung unter 5 Minuten oder einem Vakuum unter 10 mbar erfolgt keine brauchbare Verfestigung, so dass keine belastbare Silberschicht erhalten wird.at a heating rate below 0.3 K / s or a final temperature below 200 or a heat treatment under 5 minutes or a vacuum below 10 mbar is no useful solidification, so no resilient Silver layer is obtained.
Die Höhe der Endtemperatur wird durch die Temperaturempfindlichkeit der Bauteile bestimmt. Luftatmosphäre ist die bevorzugte Sinteratmosphäre. Stickstoff oder Formiergas dienen dem Schutz der Cu-Substratoberfläche vor Oxidation. Vakuum, insbesondere zwischen 100 und 300 mbar vermeidet zusätzlich Lufteinschlüsse.The Height of the final temperature is determined by the temperature sensitivity determined the components. Air atmosphere is the preferred Sintering atmosphere. Nitrogen or forming gas serve the Protection of the Cu substrate surface from oxidation. Vacuum, in particular between 100 and 300 mbar avoids additionally Air pockets.
Zur
Herstellung einer Si-Chip-Befestigung nach
Mit
einer erfindungsgemäßen Kontaktierungspaste aus
einem Gel gemäß
Analog
zum Beispiel gemäß
Analog
zu
Mit
einer erfindungsgemäßen Kontaktierungspaste aus
einem Gel gemäß
Analog
zu
In
Nach
In
In
Insbesondere
bei Solarzellen ist eine zuverlässige elektrische, thermische
und mechanische Verbindung
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - WO 2004/026526 [0003] WO 2004/026526 [0003]
- - US 6951666 [0004] - US 6951666 [0004]
- - DE 102005053553 A1 [0010, 0018, 0028, 0032, 0033, 0034, 0035, 0036] - DE 102005053553 A1 [0010, 0018, 0028, 0032, 0033, 0034, 0035, 0036]
Claims (12)
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008031893A DE102008031893A1 (en) | 2008-07-08 | 2008-07-08 | Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas |
EP08016620.0A EP2042260B1 (en) | 2007-09-28 | 2008-09-22 | Method and paste for contacting metal surfaces |
DK08016620.0T DK2042260T3 (en) | 2007-09-28 | 2008-09-22 | METHOD AND FIT FOR ESTABLISHING CONTACT BETWEEN METAL SURFACES |
KR1020080094083A KR101102214B1 (en) | 2007-09-28 | 2008-09-25 | Method and paste for contacting of metal surfaces |
US12/237,660 US20090134206A1 (en) | 2007-09-28 | 2008-09-25 | Process and Paste for Contacting Metal Surfaces |
CN201110312205.XA CN102430875B (en) | 2007-09-28 | 2008-09-28 | Method and mastic for multiple metal covering contactings |
CN2008101688371A CN101431038B (en) | 2007-09-28 | 2008-09-28 | Method and paste for contacting metal surfaces |
JP2008250495A JP5156566B2 (en) | 2007-09-28 | 2008-09-29 | Metal surface connection method and paste therefor |
US12/615,516 US20100055828A1 (en) | 2007-09-28 | 2009-11-10 | Process and paste for contacting metal surfaces |
KR1020110060009A KR20110088477A (en) | 2007-09-28 | 2011-06-21 | Method and paste for contacting of metal surfaces |
HRP20140178AT HRP20140178T1 (en) | 2007-09-28 | 2014-02-27 | Method and paste for contacting metal surfaces |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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DE102008031893A DE102008031893A1 (en) | 2008-07-08 | 2008-07-08 | Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas |
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DE102008031893A1 true DE102008031893A1 (en) | 2010-01-14 |
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DE102008031893A Withdrawn DE102008031893A1 (en) | 2007-09-28 | 2008-07-08 | Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas |
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Cited By (1)
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WO2013156570A1 (en) | 2012-04-20 | 2013-10-24 | Technische Universität Berlin | Solder material, method for the production thereof, and use thereof to join metal substrates without pressure |
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DE102005053553A1 (en) | 2005-11-08 | 2007-05-16 | Heraeus Gmbh W C | Solder pastes with resin-free flux |
DE102007046901A1 (en) * | 2007-09-28 | 2009-04-09 | W.C. Heraeus Gmbh | Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas |
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2008
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DE2542669B2 (en) * | 1974-09-27 | 1979-06-13 | General Electric Co., Schenectady, N.Y. (V.St.A.) | Circuit board, process for its manufacture and its use |
DE3346050A1 (en) * | 1983-12-20 | 1985-06-27 | Siemens AG, 1000 Berlin und 8000 München | Connection lead for an electrical component having a ceramic body |
US6951666B2 (en) | 2001-10-05 | 2005-10-04 | Cabot Corporation | Precursor compositions for the deposition of electrically conductive features |
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DE102005053553A1 (en) | 2005-11-08 | 2007-05-16 | Heraeus Gmbh W C | Solder pastes with resin-free flux |
DE102007046901A1 (en) * | 2007-09-28 | 2009-04-09 | W.C. Heraeus Gmbh | Production of electrically conductive or heat-conductive component for producing metallic contact between two elements e.g. cooling bodies or solar cells, comprises forming elemental silver from silver compound between contact areas |
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WO2013156570A1 (en) | 2012-04-20 | 2013-10-24 | Technische Universität Berlin | Solder material, method for the production thereof, and use thereof to join metal substrates without pressure |
DE102012206587A1 (en) | 2012-04-20 | 2013-11-07 | Technische Universität Berlin | Solder material, process for its production and its use for pressure-free joining of metallic substrates |
US10065273B1 (en) | 2012-04-20 | 2018-09-04 | Nano-Join Gmbh | Solder material, method for the production thereof and use thereof to join metal substrates without pressure |
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