DE102007037428A1 - Hair treatment agent for increasing volume - Google Patents

Abstract

It describes the cosmetic use of an enzymatic combination of active ingredients, which consists of i. an oxidase, ii. a substrate for the oxidase and iii. a peroxidase, and is ideal for increasing the volume of keratinous fibers, especially human hair.

Description

The The invention relates to the use of an enzymatic combination of active substances to increase the volume of keratinic fibers. The invention relates furthermore an agent based on the enzymatic combination of active substances and another, the hair volume-enhancing agent, as well a method for increasing the volume of keratinic fibers using the agent according to the invention.

conditioned environmental problems and pollution and its consequences the awareness of the people in terms of use and the Composition of cosmetic products changed in recent years. So is no longer a wealth of hair and skin treatment products but optimally only one or two remedies, the a large part of the requirements for cleaning, Care, styling, coloring and bleaching meet should. In addition, mild natural cosmetic products sought, at least largely biological are degradable and a gentle treatment of the skin and / or the Ensure hair without a predominant To contain proportion of aggressive chemical agents, which the skin and / or the hair can negatively burden.

By These requirements for cosmetic products are constantly arising new problems and difficulties in their production.

Fine, smooth hair is prone to lack of volume and therefore faster Regrease. Furthermore, can be fine and too smooth hair only poorly styling, so that aids such as mousse or Hairsprays, often combined with additional Hair dryer, and / or Dauerwellbehandlungen be used. By using these aids, however, the hair structure be attacked, which, especially with more frequent Repeat, a hair damage can be caused can.

So There has been a shortage of efforts recently, To provide hair volume boosters that are predominantly based on hair-friendly, natural ingredients, but there is still a need for mild drug combinations, who do not have the aforementioned problems, and a permanent one Ensure volume increase of human hair, without cause damage to the hair structure.

Completely surprising It has now been found that the use of a special enzymatic Active ingredient combination meets the above requirements to a high degree Fulfills.

• i. einer Oxidase,
• ii. einem Substrat für die Oxidase sowie
• iii. einer Peroxidase

zur Volumensteigerung keratinischer Fasern, insbesondere menschlicher Haare.The invention therefore relates to the cosmetic use of an enzymatic combination of active substances consisting of

• i. an oxidase,
• ii. a substrate for the oxidase as well
• iii. a peroxidase

for increasing the volume of keratinic fibers, especially human hair.

aid the use of the invention, the volume could fine and smooth hair can be increased sustainably, resulting in The hair was also easier to style without the classic Hairdressing tools had to be applied. In addition, hair obtained a volume improvement by the use according to the invention, which is equivalent to a volume improvement after a permanent wave treatment, without being oxidized, chemically aggressive agents or Fönhitze had to be resorted to. Furthermore was the hair structure of the hair compared to the use commercial means far less impaired.

Especially is under an inventively suitable oxidase Glucose oxidase, under a suitable according to the invention Substrate for the oxidase D-glucose and under a suitable according to the invention Understood peroxidase lactoperoxidase.

It may be preferred according to the invention that the Substrate ii) - based on its total weight - continue contains at most 1 wt .-% iodide and Thiocyanationen.

According to the invention preferred is the use of components i), ii) and iii) in the active ingredient combination in a ratio of (0.1-1) :( 10-50) :( 0.1-1), preferably from 0.5: 20: 0.5.

According to the invention preferred is also the use of the invention Combination of active ingredients in a keratinizing agent Fibers in an amount of 0.01 to 10 wt .-%, preferably 0.1 to 5 wt .-% and in particular 0.5 to 2.0 wt .-% - related on the total weight of the agent.

The The active ingredient combination according to the invention can be used in a one-component agent may be used, however Care must be taken that the substrate is separate from the oxidase and the peroxidase in the invention to be used Means must be incorporated. For some inventive However, it may be preferred for uses that the enzymatic Combination of active ingredients in a 2-component volume-increasing agent keratinischer fibers is used, wherein the components i) and iii) physically separate from component ii), and just before application to the keratinic fibers with each other be mixed.

According to the invention preferred is furthermore the use of a combination of the enzymatic combination of active ingredients with at least one other, the hair volume increasing Active substance that differs from the enzymatic combination of active ingredients.

This further hair volume-increasing active ingredient is preferably selected from nonionic, cationic, anionic or ampholytic Polymers, terpene-containing plant extracts, proteins and / or protein derivatives.

The respective preferred components b) and further preferred embodiments of the invention are in the context of the "second subject of the invention ", but they apply unrestricted also for the first object the invention.

• a) eine enzymatische Wirkstoffkombination und
• b) mindestens einen von a) verschiedenen, das Haarvolumen erhöhenden Wirkstoff.

A second object of the invention is means for increasing the volume of keratinic fibers containing

• a) an enzymatic combination of active ingredients and
• b) at least one of a) different, the hair volume-increasing active ingredient.

In a preferred embodiment of the agent are the Components a) and b) in a ratio of 0.1: 10 to 20: 0.1 used.

• i. einer Oxidase,
• ii. einem Substrat für die Oxidase und
• iii. einer Lactoperoxidase

zusammen und der Wirkstoff b) ist erfindungsgemäß ausgewählt aus nichtionischen, kationischen, anionischen oder ampholytischen Polymeren, terpenhaltigen Pflanzenextrakten, Proteinen und/oder Proteinderivaten.The enzymatic combination of active ingredients is according to the invention

• i. an oxidase,
• ii. a substrate for the oxidase and
• iii. a lactoperoxidase

together and the active ingredient b) according to the invention is selected from nonionic, cationic, anionic or ampholytic polymers, terpene-containing plant extracts, proteins and / or protein derivatives.

A Particularly preferred component according to the invention i. is glucose oxidase. For the components ii. and iii. These it is preferably D-glucose and lactoperoxidase.

Under According to the invention, preferred active compounds b) are first of all to understand polymers. these can cationic, nonionic, anionic and / or amphotytic.

Cationic polymers which are suitable according to the invention are polymers which have groups in the main and / or side chain which may be "temporary" or "permanent" cationic. According to the invention, "permanently cationic" refers to those polymers which have a cationic group independently of the pH of the agent These are generally polymers which contain a quaternary nitrogen atom, for example in the form of an ammonium group Preferred cationic groups are quaternary ammonium groups In particular, those polymers in which the quaternary ammonium group is bonded via a C _1-4 hydrocarbon group to a polymer main chain composed of acrylic acid, methacrylic acid or derivatives thereof have proven to be particularly suitable.

in der R¹⁷ = -H oder -CH₃ ist, R¹⁸, R¹⁹ und R²⁰ unabhängig voneinander ausgewählt sind aus C_1-4-Alkyl-, -Alkenyl- oder -Hydroxyalkylgruppen, m = 1, 2, 3 oder 4, n eine natürliche Zahl und X ein physiologisch verträgliches organisches oder anorganisches Anion ist, sowie Copolymere, bestehend im wesentlichen aus den in Formel (III) aufgeführten Monomereinheiten sowie nichtionogenen Monomereinheiten, sind besonders bevorzugte kationische Polymere. Im Rahmen dieser Polymere sind diejenigen erfindungsgemäß bevorzugt, für die mindestens eine der folgenden Bedingungen gilt:

• – R¹⁷ steht für eine Methylgruppe
• – R¹⁸, R¹⁹ und R²⁰ stehen für Methylgruppen
• – m hat den Wert 2.

Homopolymers of the general formula (VI),

where R ^{17 is} -H or -CH ₃ , R ¹⁸ , R ¹⁹ and R ^{20 are} independently selected from C _1-4 alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4 , n is a natural number and X is a physiologically acceptable organic or inorganic anion, as well as copolymers consisting essentially of the monomer units listed in formula (III) and nonionic monomer units, are particularly preferred cationic polymers. In the context of these polymers, preference is given to those according to the invention for which at least one of the following conditions applies:

• - R ¹⁷ is a methyl group
• - R ¹⁸ , R ¹⁹ and R ²⁰ are methyl groups
• - m has the value 2.

Suitable physiologically tolerated counterions X ^- include, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Preference is given to halide ions, in particular chloride.

One suitable homopolymer is, if desired, crosslinked, Poly (methacryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium-37. The networking can, if desired, with Help multiply olefinically unsaturated compounds, for example Divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallylether, Polyallylpolyglycerylether, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylenebisacrylamide is a preferred one Crosslinking agent.

The homopolymer is preferably used in the form of a nonaqueous polymer dispersion which should not have a polymer content of less than 30% by weight. Such polymer dispersions are (under the names Salcare ^® SC 95 about 50% polymer content, additional components: mineral oil (INCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene-ether (INCI name: PPG-1 trideceth-6) ) and Salcare ^® SC 96 (about 50% polymer content, additional components: mixture of diesters of propylene glycol (with a mixture of caprylic and capric acid INCI name: propylene glycol Dicaprylate / Dicaprate) and Tridecylpolyoxypropylen polyoxyethylene ether (INCI name : PPG-1-trideceth-6)) are commercially available.

Copolymers having monomer units of the formula (VI) contain as nonionic monomer units preferably acrylamide, methacrylamide, acrylic acid-C _1-4 -alkyl esters and methacrylic acid-C _1-4 -alkyl esters. Among these nonionic monomers, the acrylamide is particularly preferred. These copolymers can also be crosslinked, as described above in the case of the homopolymers. A copolymer preferred according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer. Such copolymers in which the monomers are present in a weight ratio of about 20:80, are commercially available as approximately 50% non-aqueous polymer dispersion 92 under the name Salcare ^® SC.

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind. Die Verbindungen Celquat^® H 100, Celquat^® L 200 und Polymer JR^® 400 sind bevorzugte quaternierte Cellulose-Derivate,
• – hydrophob modifizierte Cellulosederivate, beispielsweise die unter dem Handelsnamen SoftCat^® vertriebenen kationischen Polymere,
• – kationische Alkylpolyglycoside,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^® 50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^® Guar und Jaguar^® vertriebenen Produkte,
• – Polysiloxane mit quaternären Gruppen, wie beispielsweise die im Handel erhältlichen erhältlichen Produkte Q2-7224 (Hersteller: Dow Corning; ein stabilisiertes Trimethylsilylamodimethicon), Dow Corning^® 929 Emulsion (enthaltend ein hydroxyl-aminomodifiziertes Silicon, das auch als Amodimethicone bezeichnet wird), SM-2059 (Hersteller: General Electric), SLM-55067 (Hersteller: Wacker) sowie Abil^®-Quat 3270 und 3272 (Hersteller: Th. Goldschmidt; diquaternäre Polydimethylsiloxane, Quaternium-80),
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^® 100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^® 550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^® 734 und Gafquat^® 755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol, sowie die unter den Bezeichnungen
• – Polyquaternium 2,
• – Polyquaternium 17,
• – Polyquaternium 18 und
• – Polyquaternium 27 bekannten Polymeren mit quartären Stickstoffatomen in der Polymerhauptkette.

Further preferred cationic polymers are, for example

• - Quaternized cellulose derivatives, such as those under the names Celquat ^® and Polymer JR ^® commercially available. The compounds Celquat ^® H 100, Celquat L 200 and Polymer JR ^{® ®} 400 are preferred quaternized cellulose derivatives
• - hydrophobically modified cellulose derivatives, for example those sold under the trade name SOFTCAT ^® cationic polymers,
• Cationic alkyl polyglycosides,
• - cationized honey, for example the commercial product Honeyquat ^® 50,
• - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ^® Guar and Jaguar ^®,
• - polysiloxanes with quaternary groups, such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Corning ^® 929 Emulsion (containing a hydroxylamino-modified silicone which is also known as amodimethicone), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® quat 3270 and 3272 (manufacturer: Th Goldschmidt; diquaternary polydimethylsiloxanes, quaternium-80).,
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,
• - vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,
• - Quaternized polyvinyl alcohol, as well as those under the names
• - Polyquaternium 2,
• - Polyquaternium 17,
• - Polyquaternium 18 and
• Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.

Can be used as cationic polymers are sold under the names Polyquaternium-24 (commercial product z. B. Quatrisoft ^® LM 200), known polymers. , Gaffix ^® VC 713 (manufactured by ISP): Also according to the invention can be used the copolymers of vinylpyrrolidone, such as the commercial products Copolymer 845 (ISP manufacturer) are Gafquat ^® ASCP 1011, Gafquat ^® HS 110, Luviquat ^® 8155 and Luviquat ^® MS 370 available are.

Other cationic polymers of the present invention, the "temporarily cationic" polymers. These polymers are usually contain an amino group present at certain pH values as a quaternary ammonium group and hence cationic. For example, chitosan and its derivatives are preferred, such as for example, under the trade designations Hydagen ^® CMF, Hydagen® ^® HCMF, Kytamer ^® PC and Chitolam ^® NB / 101 are freely available commercially. chitosans are deacetylated, in different degrees of deacetylation and varying degrees of degradation (molecular weights) are commercially available. Their preparation is z. B. DE 44 40 625 A1 and in DE 1 95 03 465 A1 described.

Particularly suitable chitosans have a degree of deacetylation of at least 80% and a molecular weight of 5 × 10 ⁵ to 5 × 10 ⁶ (g / mol).

to Preparation of preparations according to the invention must be Chitosan be converted into the salt form. This can by dissolving in dilute aqueous Acids take place. As acids are both mineral acids such as Hydrochloric acid, sulfuric acid and phosphoric acid as well as organic acids, eg. B. low molecular weight carboxylic acids, Polycarboxylic acids and hydroxycarboxylic acids suitable. Furthermore, higher molecular weight alkyl sulfonic acids or alkyl sulfuric acids or organophosphoric acids used, as far as these are the required physiological Have compatibility. Suitable acids for transfer of chitosan in the salt form are z. Acetic acid, glycolic acid, Tartaric acid, malic acid, citric acid, Lactic acid, 2-pyrrolidinone-5-carboxylic acid, benzoic acid or salicylic acid. Preference is given to low molecular weight hydroxycarboxylic acids such as As glycolic acid or lactic acid used.

In a particularly preferred embodiment of the invention, the cationic polymer used is at least one polymer from the group of cationic guar derivatives and / or polyquaternium-7 (Merquat 550), polyquaternium-6, polyquaternium-10, polyquaternium-37, polyquaternium-67 (SoftCat ^® polymers) and / or a chitosan in the hair treatment compositions.

The or the cationic polymer (s) is (are) in the invention Resources - in relation to the total budget - in Contained amounts of 0.1 to 5 wt .-%. Amounts of 0.2 to 3, in particular from 0.5 to 2.5 wt .-%, are particularly preferred.

According to the invention suitable anionic polymers are anionic polymers which carboxylate and / or Have sulfonate groups. Examples of anionic monomers, which may consist of such polymers are acrylic acid, Methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. It can the acidic groups in whole or in part as sodium, potassium, ammonium, Mono- or triethanolammonium salt present. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer, where the sulfonic acid group is completely or partially unsaturated, have proved to be particularly effective may be partially present as sodium, potassium, ammonium, mono- or triethanolammonium salt.

More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid, which is available for example under the name Rheothik ^® 11-80 is commercially.

Within In this embodiment, it may be preferable to use copolymers from at least one anionic monomer and at least one nonionic Use monomer. Regarding the anionic monomers Reference is made to the substances listed above. preferred non-ionic monomers are acrylamide, methacrylamide, acrylic esters, Methacrylic acid esters, vinylpyrrolidone, vinyl ethers and vinyl esters.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with sulfonic acid-containing monomers. A particularly preferred anionic copolymer consists of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, wherein the sulfonic acid group is wholly or partly in the form of sodium, potassium, ammonium, mono- or triethanolammonium Salt is present. This copolymer may also be crosslinked, with crosslinking agents preferably polyolefinically unsaturated compounds such as tetraallyloxyethane, allylsucrose, allylpentaerythritol and methylene-bisacrylamide are used. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC. The use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C ₁₃ -C ₁₄ isoparaffin) and a nonionic emulsifier (laureth-7), has proved to be particularly advantageous within the scope of the teaching according to the invention.

Also sold under the name Simulgel ^® 600 as a compound with isohexadecane and polysorbate-80 Natriumacryloyldimethyltaurat copolymers have proved to be particularly effective according to the invention.

Likewise preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene may be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-retaining polymers. A with 1,9-decadiene crosslinked maleic acid-methyl vinyl ether copolymer is commercially available under the name Stabileze® ^® QM.

Furthermore, amphoteric polymers can be used as polymers to increase the activity of the preparations according to the invention. The term amphoteric polymers includes both those polymers which contain in the molecule both free amino groups and free -COOH or SO ₃ H groups and are capable of forming internal salts, as well as zwitterionic polymers which in the molecule have quaternary ammonium groups and -COO ^- or -SO ₃ ^- groups, and summarized those polymers containing -COOH or SO ₃ H groups and quaternary ammonium groups.

An example of the present invention amphopolymer suitable is the acrylic resin commercially available as Amphomer ^® is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Represents methacrylic acid and its simple esters.

• (a) Monomeren mit quartären Ammoniumgruppen der allgemeinen Formel (G3-I), R¹-CH=CR²-CO-Z-(C_nH_2n)-N⁽⁺⁾R³R⁴R⁵A^(–) (G3-I)in der R¹ und R² unabhängig voneinander stehen für Wasserstoff oder eine Methylgruppe und R³, R⁴ und R⁵ unabhängig voneinander für Alkylgruppen mit 1 bis 4 Kohlenstoffatomen, Z eine NH-Gruppe oder ein Sauerstoffatom, n eine ganze Zahl von 2 bis 5 und A^(–) das Anion einer organischen oder anorganischen Säure ist, und
• (b) monomeren Carbonsäuren der allgemeinen Formel (G3-II), R⁶-CH=CR⁷-COOH (G3-II)in denen R⁶ und R⁷ unabhängig voneinander Wasserstoff oder Methylgruppen sind.

Preferably used amphoteric polymers are those polymers which are composed essentially

• (a) monomers having quaternary ammonium groups of the general formula (G3-I), R ¹ -CH = CR ² -CO-Z- (C _n H _2n ) -N ⁽⁺⁾ R ³ R ⁴ R ⁵ A ^(-) (G ³ -I) in which R ¹ and R ² independently of one another are hydrogen or a methyl group and R ³ , R ⁴ and R ⁵ independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer from 2 to 5 and A ^{(-) is} the anion of an organic or inorganic acid, and
• (b) monomeric carboxylic acids of the general formula (G3-II), R ⁶ -CH = CR ⁷ -COOH (G3-II) in which R ⁶ and R ^{7 are} independently hydrogen or methyl groups.

These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention. With regard to the details of the preparation of these polymers is expressly based on the content of German patent application 39 29 973 Referenced. Very particular preference is given to those polymers in which monomers of the type (a) are used in which R ³ , R ⁴ and R ^{5 are} methyl groups, Z is an NH group and A ^{(-) is} a halide, methoxysulfate or ethoxysulfate Ion is; Acrylamidopropyl trimethyl ammonium chloride is a particularly preferred monomer (a). Acrylic acid is preferably used as monomer (b) for the stated polymers.

• – Vinylpyrrolidon/Vinylester-Copolymere, wie sie beispielsweise unter dem Warenzeichen Luviskol^® (BASF) vertrieben werden. Luviskol^® VA 64 und Luviskol^® VA 73, jeweils Vinylpyrrolidon/Vinylacetat-Copolymere, sind ebenfalls bevorzugte nichtionische Polymere.
• – Celluloseether, wie Hydroxypropylcellulose, Hydroxyethylcellulose und Methylhydroxypropylcellulose, wie sie beispielsweise unter den Warenzeichen Culminal^® und Benecel^® (AQUALON) vertrieben werden.
• – Schellack
• – Polyvinylpyrrolidone, wie sie beispielsweise unter der Bezeichnung Luviskol^® (BASF) vertrieben werden.
• – Siloxane. Diese Siloxane können sowohl wasserlöslich als auch wasserunlöslich sein. Geeignet sind sowohl flüchtige als auch nichtflüchtige Siloxane, wobei als nichtflüchtige Siloxane solche Verbindungen verstanden werden, deren Siedepunkt bei Normaldruck oberhalb von 200°C liegt. Bevorzugte Siloxane sind Polydialkylsiloxane, wie beispielsweise Polydimethylsiloxan, Polyalkylarylsiloxane, wie beispielsweise Polyphenylmethylsiloxan, ethoxylierte Polydialkylsiloxane sowie Polydialkylsiloxane, die Amin- und/oder Hydroxy-Gruppen enthalten.
• – Glycosidisch substituierte Silicone gemäß der EP 0612759 B1 .

Suitable nonionic polymers are, for example:

• - Vinylpyrrolidone / vinyl ester copolymers, such as those sold under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.
• - cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methylhydroxypropyl cellulose, as for example under the trademark Culminal® ^® and Benecel ^® (AQUALON).
• - shellac
• - polyvinylpyrrolidones, as for example under the name Luviskol ^® (BASF).
• - siloxanes. These siloxanes can be both water-soluble and water-insoluble. Both volatile and nonvolatile siloxanes are suitable, nonvolatile siloxanes being understood as meaning those compounds whose boiling point is above 200 ° C. under normal pressure. Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
• - Glycosidically substituted silicones according to the EP 0612759 B1 ,

It It is also possible according to the invention that the Preparations according to the invention more, in particular two different polymers of the same charge and / or one each ionic and an amphoteric and / or nonionic polymer included.

The Polymers are in the inventive compositions preferably in amounts of 0.01 to 10 wt .-%, based on the total Means, included. Amounts from 0.05 to 5, especially from 0.1 to 3% by weight are particularly preferred.

When further active ingredient suitable according to the invention b) terpene-containing plant extracts can serve. These can be selected from the leaves or plant parts of the genera Leptospermum and Melaleuca, from the family of Myrtaceae, but especially tea tree oil, Extracts and / or oils of carnation, thyme, peppermint, of the aniseed, the eucalyptus leaves, the spruce needles, of lavender, lemongrass, roses, rosemary, sandalwood, stinging nettle, water lily and / or melissa.

Particularly according to the invention preferred are water lily extracts and / or nettle extracts. she are in the inventive compositions - related on the total weight of the agent - in an amount of 0.01 to 5 wt .-%, preferably from 0.05 to 3 wt .-% and in particular of 0.1 to 2 wt .-% used.

After all may be the active ingredient b) in a preferred embodiment The invention may also be a protein and / or a protein derivative. These include protein hydrolysates according to the invention and / or amino acids and their derivatives (H). Protein hydrolysates are product mixtures that are acidic, basic or enzymatically catalyzed degradation of proteins (proteins) to be obtained. The term protein hydrolyzates according to the invention also Total hydrolyzates and individual amino acids and their derivatives as well Mixtures of different amino acids understood. Farther are inventively amino acids and amino acid derivatives built-up polymers under the term Understood protein hydrolysates. For example, the latter are Polyalanine, polyasparagine, polyserine, etc. Further Examples of usable according to the invention Compounds are L-alanyl-L-proline, polyglycine, glycyl-L-glutamine or D / L-methionine-S-methylsulfonium chloride. Of course can according to the invention also β amino acids and their derivatives such as β-alanine, anthranilic acid or hippuric acid. The molecular weight of the Protein hydrolysates which can be used according to the invention is between 75, the molecular weight of glycine, and 200,000, preferably, the molecular weight is 75 to 50,000 and quite more preferably 75 to 20,000 daltons.

According to the invention Protein hydrolyzates both vegetable and animal or marine or synthetic origin.

Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois® ^® (Interorgana) Collapuron ^® (Cognis), Nutrilan® ^® (Cognis), Gelita-Sol ^® (German Gelatinefabriken Stoess & Co), Lexein ^® (Inolex) and kerasol tm ^® (Croda) sold.

Preferred according to the invention is the use of protein hydrolysates of plant origin, eg. Soybean, almond, pea, potato and wheat protein hydrolysates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), Diahin ^® (Diamalt) ^® (Inolex), Hydrosog ^® (Croda), hydro Lupine ^® (Croda), hydro Sesame ^® (Croda), Hydro tritium ^® (Croda) and Crotein ^® (Croda) available.

Although the use of the protein hydrolysates is preferred as such, amino acid mixtures otherwise obtained may be used in their place, if appropriate. Also possible is the use of derivatives of protein hydrolysates, for example in the form of their fatty acid condensation products. Such products are sold, for example, under the names Lamepon® ^® (Cognis), Lexein ^® (Inolex), Crolastin ^® (Croda) or crotein ^® (Croda).

According to the invention especially Wheat and keratin hydrolysates are suitable.

The Protein hydrolysates and / or their derivatives are in the inventive Preparations preferably in amounts of 0.01 to 10 wt .-%, based on the entire remedy, included. Amounts from 0.05 to 5% by weight and especially from 0.1 to 3 wt .-% are particularly preferred.

In a particularly preferred, further embodiment may in particular the hair-sparing effect of the invention Means by the additional content of a haarstrukturverbessernden and / or a hair conditioning agent further optimized. Especially with very thin hair, the besipielsweise is pre-damaged as a result of permanent wave treatments it is advantageous, the inventive compositions Add one or more of the following components to to avoid further hair damage and existing ones Mitigate damage.

Examples of such hair structure-improving and / or hair-conditioning active ingredients are vitamins and their derivatives or precursors. Especially preferred according to the invention are panthenol and its physiologically tolerated derivatives. Such derivatives are in particular the esters and ethers of panthenol as well as cationically derivatized panthenols. Individual representatives are for example the Panthenoltriacetat, the Panthenolmonoethylether and its monoacetate as well as in the WO 92/13829 A1 disclosed cationic panthenol derivatives. An inventively preferred panthenol derivative is also its precursor pantolactone. Panthenol is preferred within this group. Another example of a structurally improving vitamin is pyridoxine (vitamin B6).

Farther is also polyvinylpyrrolidone (PVP) for its fiber structure improving Properties known and preferred according to the invention.

Further, According to the invention, particularly effective, structurally improving Compounds are the aldehydes. Particularly preferred example are formaldehyde and formaldehyde-releasing compounds, such as Methoxymethyl esters, dimethylol (thio) urea derivatives, oxazolidine derivatives, N-hydroxymethylmaleimide, hexamethylenetetramine and its derivatives, Hydantoin derivatives, pyridinium-substituted dimethyl ethers, imidazolidinyl urea derivatives, Isothiazolinone, 2-bromo-2-nitropropane-diol and 5-bromo-5-nitro-1,3-dioxane. Further particularly preferred aldehydes are acetaldehyde, glyoxal, Glyceraldehyde and glutaric dialdehyde.

A Another suitable group of structurally improving agents (non-terpene or low level) plant extracts.

Usually These extracts are produced by extraction of the whole plant. However, it may also be preferred in individual cases, the Extracts of flowers and / or leaves only to produce the plant.

With regard to the plant extracts which can be used according to the invention, particular reference is made to the extracts which are described on page 44 of the 3rd edition of the guideline for the ingredient declaration of cosmetic products, issued by the Industrial Association for Personal Care and Detergents e. V. (IKW), Frankfurt, beginning Table are listed.

According to the invention especially the extracts of oak bark, stinging nettle, witch hazel, hops, Chamomile, burdock root, horsetail, hawthorn, lime blossom, Almond, aloe vera, spruce needle, horse chestnut, sandalwood, Juniper, coconut, mango, apricot, lime, wheat, kiwi, Melon, orange, grapefruit, sage, rosemary, birch, mallow, meadowfoam, Quenelles, Yarrow, Thyme, Melissa, Toadstool, Coltsfoot, Marshmallow, Meristem, green tea, ginseng and ginger root are preferred.

Especially preferred are the extracts of oak bark, stinging nettle, hamamelis, Hops, chamomile, burdock root, horsetail, lime blossom, Almond, aloe vera, coconut, mango, apricot, lime, wheat, Kiwi, melon, orange, grapefruit, sage, rosemary, birch, meadowfoam, Quenelles, yarrow, toe, meristem, green tea, ginseng and ginger root.

All especially for the agents according to the invention suitable are the extracts of almond, aloe vera, coconut, Mango, apricot, lime, wheat, kiwi, melon and green Tea.

When Extraction agent for the preparation of said plant extracts may be used water, alcohols and mixtures thereof become. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant also in mixture with water, preferred. Plant extracts based of water / propylene glycol in the ratio 1:10 to 10: 1 proved to be particularly suitable.

The Plant extracts can according to the invention both be used in pure as well as in diluted form. If used in diluted form, contain they usually about 2-80 wt .-% of active substance and as a solvent used in their extraction Extracting agent or extractant mixture.

Farther it may be preferred in the inventive Mixtures of several, especially two, different Use plant extracts.

Also according to the invention as structure-improving agents preferred are honey extracts. These extracts are in analog Wise way to get the plant extracts and usually contain 1-10 wt .-%, in particular 3-5 wt .-%, of active substance. Water / propylene glycol mixtures may also be preferred here Be extractant.

Also fiber structure-improving agents are mono-, di- and oligosaccharides such as glucose, galactose, fructose, fructose, sucrose and lactose. Furthermore, derivatives of these pentoses, hexoses and heptoses, such as the corresponding on- and uronic acids (sugar acids), sugar alcohols, sugar amines, such as N-glucosamine, and glycosides, and with C ₄ -C ₃₀ fatty alcohols etherified pentoses, hexoses and heptoses to be used according to the invention. The sugar acids can be used according to the invention in free form, in the form of their salts, preferably calcium, magnesium and zinc salts, and in the form of their esters or lactones. Preferred sugar acids are gluconic acid, gluconic acid-γ-lactone, lactobionic acid, glucuronic acid and its mono- or dilactones, pangamic acid, sugar acid, mannose and its mono- or dilactones, as well as mucic acid and its mono- or dilactones. Preferred sugar alcohols are sorbitol, mannitol and dulcitol. Preferred glycosides are the methylglucosides. Glucose, N-glucosamine and gluconic acid are particularly preferred from this group.

Certain amino acids can also be used in the context of the present invention as hair structure-improving active ingredients. Examples are those in the DE-195 22 569 , to which reference is expressly made herein, described amino acids serine, threonine and tyrosine. Further, derivatives of serine, such as the serine phosphate, are also preferred according to the invention. Another structurally-improving amino acid is lysine. Serine is a particularly preferred fiber-structure-improving agent.

Also to improve the structure, certain acids, in particular α-hydroxycarboxylic acids, and their salts be used. According to the invention preferred Structure-improving acids are lactic acid, malic acid, Tartaric acid, glyceric acid and maleic acid. Lactic acid and glyceric acid are particularly preferred. Furthermore, special phosphonic acids and their improve Salts the structure of keratin fibers. According to the invention preferred Phosphonic acids are the n-octylphosphonic acid and the n-decylphosphonic acid.

Farther are lipid-soluble ester alcohols or ester polyols for their structure improving effect known. As lipid-soluble they are to be considered when 5% by weight of these products are in cetyl alcohol clear at 80 ° C.

The According to the invention suitable ester alcohols or Ester polyols are available by reacting an epoxy fatty acid ester with water or mono- or polyhydric alcohols with 1-10 C atoms under opening of the epoxide ring and forming a vicinal dihydroxyethyl or hydroxyalkoxyethyl group. The epoxy fatty acid ester can also be an epoxidation of a technical fatty acid ester with proportions of saturated fatty acids. Of the Epoxy oxygen content should, however, at least 3 wt .-%, preferably 5-10 Wt .-%, amount.

The Epoxy fatty acid esters are either epoxidized fatty acid esters monohydric alcohols, so z. B. epoxidized oleic acid methyl ester, Linoleic acid methyl ester, Ricinolsäuremethylester or epoxidized fatty acid esters of polyhydric alcohols, z. As glycerol monooleate or propylene glycol monooleate or epoxidized Fatty acid triglycerides, e.g. For example, oleic acid triglyceride or unsaturated oils such. Olive oil, Soybean oil, sunflower oil, linseed oil, rapeseed oil.

Technically especially interesting are unsaturated fatty acid methyl ester epoxides from unsaturated vegetable fatty acids. So is as Esterpolyol the reaction product of a vegetable oil fatty acid methyl ester epoxide with a polyol having 2-6 C atoms and 2-6 hydroxyl groups particularly preferred. As polyols can be z. For example, ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, butanediol, pentanediol, hexanediol, Glycerol, trimethylolpropane, pentaerythritol, sorbitol or diglycerol be included.

The reaction product of a vegetable fatty acid methyl ester epoxide with trimethylolpropane and having a hydroxyl number of 350-450 is particularly well suited for the bleaching agents according to the invention as the ester polyol. Such a product based on Sojaölfettsäuremethylester epoxide and trimethylolpropane is available under the trade name Sovermol ^® 760th

Furthermore, vitamin B ₃ can be used as structure-improving active ingredient. Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed. According to the invention, the nicotinic acid amide is preferred.

Also Vitamin H is a structurally improving agent within the meaning of the present Can be used invention. As vitamin H, the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid but for the meantime the trivial name Biotin has prevailed.

Particularly according to the invention preferred structurally-improving agents are selected from panthenol, physiologically tolerated panthenol derivatives, Mono-, di- and oligosaccharides, serine, lactic acid, glyceric acid, Niacinamide, Vitamin B6, Polyvinylpyrrolidone, Glucose, Gluconic Acid, Biotin and the lipid-soluble ester alcohols or ester polyols.

The agents according to the invention contain the one or more structure-improving and / or hair-conditioning agent (s) - related on their total weight - preferably in amounts of 0.01 to 10 wt .-%, preferably from 0.05 to 5 wt .-% and in particular of 0.1 to 2 wt .-%.

In a further, particularly preferred embodiment of the Invention, it is advantageous that the inventive Stabilizing agent containing at least one thickener.

Often Thickening systems used contain polymers.

polymers regardless of their chemical structure and charge generally several functions in cosmetic compositions on. The description of the polymers according to their Function in the compositions according to the invention thus does not necessarily correspond to a rating or Importance of these polymers. Rather, all polymers are in principle as equivalent to use in the invention See compositions, although some of these polymers may be preferred. In the case of using polymers as a thickener, for example, this means that cationic polymers such as cationic cellulose or cationic guar types as well have a stabilizing and thickening function. Yet For the purpose of stabilization and thickening they often have different ones Polymers proved to be more effective. Polymers which are more desired Effects can therefore be particularly preferred when used in the compositions of the invention.

polymers can increase the viscosity of aqueous and increase non-aqueous phases in cosmetic preparations. In aqueous phases, their viscosity is based increasing function on their solubility in water or their hydrophilic nature. They are both surfactant as well as used in emulsion-shaped systems.

The following are some examples of typical polymeric thickeners for aqueous systems:
Acrylamide Copolymer, Acrylamide / Sodium Acrylate Copolymer, Acrylamide / Sodium Acryloyl Dimethyl Taurate Copolymer, Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Beheneth-25 Methacrylate Copolymer, Acrylates / C10-30 Alkyl Acrylate Crosspolymer, Acrylates / Ceteth-20 Itaconate Copolymer, Acrylates / Ceteth- 20 Methacrylate Copolymer, Acrylates / Laureth-25 Methacrylate Copolymer, Acrylates / Palmeth-25 Acrylate Copolymer, Acrylates / Palmeth-25 Itaconate Copolymer, Acrylates / Steareth-50 Acrylate Copolymer, Acrylates / Steareth-20 Itaconate Copolymer, Acrylates / Steareth-20 Methacrylates Copolymer, Acrylates / Stearyl Methacrylate Copolymer, Acrylates / Vinyl Isodecanoate Crosspolymer, Acrylic Acid / Acrylonitrogen Copolymer, Agar, Agarose, Alcaligenes Polysaccharides, Algin, Alginic Acid, Ammonium Acrylates / Acrylonitrogens Copolymer, Ammonium Acrylates Copolymer, Ammonium Acryloyldimethyltaurate / Vinyl Formamide Copolymer, Ammonium Acryloyldimethyltaurate / VP Copolymer, Ammonium Alginate, Ammonia Polyacryloyldimethyl Taurate, Amylopectin, Ascorbyl Methylsilanol Pectinate, Astragalus Gummifer Gum, Attapulgite, Avena Sativa (Oat) Kernel Flour, Bentonite, Butoxy Chitosan, Caesalpinia Spinosa Gum, Calcium Alginate, Calcium Carboxymethyl Cellulose, Calcium Carrageenan, Calcium Potassium Carbomer, Calcium Starch Octenylsuccinate , C20-40 Alkyl Stearate, Carbomer, Carboxybutyl Chitosan, Carboxymethyl Chitin, Carboxymethyl Chitosan, Carboxymethyl Dextran, Carboxymethyl Hydroxyethyl Cellulose, Carboxymethyl Hydroxypropyl Guar, Cellulose Acetate Propionate Carboxylate, Cellulose Gum, Ceratonia Siliqua Gum, Cetyl Hydroxyethyl Cellulose, Cholesterol / HDI / Pullulan Copolymer, Cholesteryl Hexyl Dicarbamate Pullulan, Cyamopsis Tetragonoloba (Guar) Gum, Diglycol / CHDM / Isophthalate / SIP Copolymer, Dihydrogenated Tallow Benzylmonium Hectorite, Dimethicone Crosspolymer-2, Dimethicone Propyl PG-Betaine, DMAPA Acrylates / Acrylic Acid / Acrylonitrogen Copolymer, Ethylene / Sodium Acrylates Copolymer, Gelati Gellan Gum, Glyceryl Alginate, Glycine Soybean Flour, Guar Hydroxypropyltrimonium Chloride, Hectorite, Hydrated Silica, Hydrogenated Potato Starch, Hydroxybutyl Methylcellulose, Hydroxyethyl Acrylate / Sodium Acryloyldimethyl Taurate Copolymer, Hydroxyethyl Cellulose, Hydroxyethyl Chitosan, Hydroxyethyl Ethyl Cellulose, Hydroxypropyl Cellulose, Hydroxypropyl Chitosan, Hydroxypropyl Ethylene Diamine Carbomer, Hydroxypropyl Guar, Hydroxypropyl Methylcellulose, Hydroxypropyl Methylcellulose Stearoxy Ether, Hydroxypropyl Starch, Hydroxypropyl Starch Phosphate, Hydroxypropyl Xanthan Gum, Hydroxystearamide MEA, Isobutylene / Sodium Maleate Copolymer, Lithium Magnesium Silicate, Lithium Magnesium Sodium Silicate, Macrocystis Pyrifera (Kelp ), Magnesium Alginates, Magnesium Aluminum Silicate, Magnesium Silicate, Magnesium Trisilicate, Methoxy PEG-22 / Dodecyl Glycol Copolymer, Methyl Cellulose, Methyl Ethyl Cellulose, Methyl Hydroxyethyl Cellulose, Microcrystalline Cellulose, Montmorillonite, Moroc Can Lava Clay, Natto Gum, Nonoxynyl Hydroxyethyl Cellulose, Octadecenes / MA Copolymer, Pectin, PEG-800, PEG Crosspolymer, PEG-150 / Decyl Alcohol / SMDI Copolymer, PEG-175 Diisostearate, PEG-190 Distearate, PEG-15 Glyceryl Tristearate , PEG-140 Glyceryl Tristearate, PEG-240 / HDI Copolymer Bis-Decyltetradeceth-20 Ether, PEG-100 / IPDI Copolymer, PEG-180 / Laureth-50 / TMMG Copolymer, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-2M, PEG-5M, PEG-7M, PEG-9M, PEG-14M, PEG-20M, PEG-23M, PEG-25M, PEG-45M, PEG-65M, PEG-90M, PEG- 115M, PEG-160M, PEG-120 Methyl Glucose Trioleate, PEG-180 / Octoxynol-40 / TMMG Copolymer, PEG-150 Pentaerythrityl Tetrastearate, PEG-4 Rapeseedamide, PEG-150 / Stearyl Alcohol / SMDI Copolymer, Polyacrylate-3, Polyacrylic Acid, Polycyclopentadiene, Polyether-1, Polyethylene / Isopropyl Maleate / MA Copolyol, Polymethacrylic Acid, Polyquaternium-52, Polyvinyl Alcohol, Potassium Alginate, Potassium Aluminum Polyacrylate, Potassium Carbomer, Potassium Carragee nano, Potassium Polyacrylate, Potato Starch Modified, PPG-14 Laureth-60 Hexyl Dicarbamate, PPG-14 Laureth-60 Isophoryl Dicarbamate, PPG-14 Palmeth-60 Hexyl Dicarbamate, Propylene Glycol Alginate, PVP / Decene Copolymer, PVP Montmorillonite, Rhizobian Gum , Ricinoleic Acid / Adipic Acid / AEEA Copolymer, Sclerotium Gum, Sodium Acrylate / Acryloyl Dimethyl Taurate Copolymer, Sodium Acrylate / Acrolein Copolymer, Sodium Acrylate / Acrylonitrogen Copolymer, Sodium Acrylate Copolymer, Sodium Acrylate / Vinyl Isodecanoate Crosspolymer, Sodium Acrylate / Vinyl Alcohol Copolymer, Sodium Carbomer, Sodium Carboxymethyl Chitin, Sodium Carboxymethyl Beta Glucan, Sodium Carboxymethyl Starch, Sodium Carrageenan, Sodium Cellulose Sulfates, Sodium Cyclodextrin Sulfate, Sodium Hydroxypropyl Starch Phosphate, Sodium Isooctylene / MA Copolymer, Sodium Magnesium Fluorosilicates, Sodium Polyacrylate, Sodium Polyacrylate Starch, Sodium Polyacryloyldimethyl Taurate, Sodium Polymethacrylate, Sodiu m Polystyrene Sulfonates, Sodium Silicoaluminates, Sodium Starch Octenylsuccinates, Sodium Stearoxy PG-Hydroxyethylcellulose Sulfonates, Sodium Styrene / Acrylates Copolymer, Sodium Tauride Acrylates / Acrylic Acid / Acrylonitrogen Copolymer, Solanum Tuberosum (Potato) Starch, Starch / Acrylates / Acrylamide Copolymer, Starch Hydroxypropyltrimonium Chlorides, Steareth-60 Cetyl Ether, Steareth-100 / PEG-136 / HDI Copolymer, Sterculia Urens Gum, Synthetic Fluorophlogopite, Tamarindus Indica Seed Gum, Tapioca Starch, TEA Alginate, TEA Carbomer, Triticum Vulgare (Wheat) Starch, Tromethamine Acrylates / Acrylonitrogen Copolymer, Tromethamine Magnesium Aluminum Silicate, Welan Gum, Xanthan Gum, Yeast Beta Glucan, Yeast Polysaccharides, Zea Mays (Corn) Starch.

A Another way to increase the viscosity of cosmetic products is the thickening of non-aqueous Phase, the lipid phase of the cosmetic products. These are polymers used, which are not water-soluble but compatible with lipids are. They are also used for gelation of cosmetic Agents with high lipid levels used.

Listed below are some of these polymers:
Acrylates / C10-30 Alkyl Acrylate Crosspolymer, Adipic Acid / PPG-10 Copolymer, Allyl Methacrylate Crosspolymer, Alumina Magnesium Metasilicate, Aluminum Starch Octenyl Succinate, Beeswax, Behenyl Methacrylate / Perfluorooctylethyl Methacrylate Copolymer, Bispolyethylene Dimethicone, Butadiene / Acrylonitrile Copolymer, Butylene / Ethylene Copolymer , Butylene / Ethylene / Styrene Copolymer, Butylene Glycol Montanate, Butyrospermum Parkii (Shea Butter), C29-70 Acid, C23-43 Acid Pentaerythritol Tetraester, C20-24 Alkyl Dimethicone, C24-28 Alkyl Dimethicone, C1-5 Alkyl Galactomannan, C18 -38 Alkyl Hydroxystearoyl Stearate, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C30-45 Alkyl Methicone, Candelilla Wax Hydrocarbons, C10-30 Cholesterol / Lanosterol Esters, Cellobiose Octanonanoate, Ceresin, Cerotic Acid, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer , Chlorinated Paraffin, Cholesterol, Cholesteryl Acetate, Cholesteryl Hydroxystearate, Cholesteryl Isostearate, Cholesteryl Macadamiate, Cholesteryl Stearates, C10-40 Hydroxyalkyl Acid Cholesterol Esters, C10-40 Isoalkyl Acid Cholesterol Esters, C10-40 Isoalkyl Acid Octyldodecanol Esters, C10-40 Isoalkyl Acid Phytosterol Esters, C10-40 Isoalkyl Acid Triglycerides, C30-38 Olefin / Isopropyl Maleate / MA Copolymer, Copal, Corn Starch Modified, C6-14 Perfluoroalkylethyl Acrylate / HEMA Copolymer, C6-14 Polyolefin, Decene / Butene Copolymer, Dihydrogenated Tallow Benzylmonium Hectorite, Dilinoleic Acid / Ethylenediamine Copolymer, Dilinoleic Acid / Sebacic Acid / Piperazine / Ethylenediamine Copolymer, Dimethicone Crosspolymer, Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer, Divinyl Dimethicone / Dimethicone Crosspolymer, Dodecanedioic Acid / Cetearyl Alcohol / Glycol Copolymer, Ethyl Cellulose, Ethylene / Acrylic Acid Copolymer, Ethylene / Acrylic Acid / VA Copolymer, Ethylenediamine / Dimer Tallate Copolymer Bis-Hydrogenated Tallow Amide, Ethylenediamine / Stearyl Dimer Dilinoleate Copolymer, Ethylenediamine / Stearyl Dimer Tallate Copolymer, Ethylene / Octene Copolymer, Ethylene / Propylene Copolymer, Ethylene / Propylene / Styrene Copolymer, Euphorbia Cerifera (Candelilla) Wax, Hydrogenated Butylene / Ethylene / Styrene Copolymer, Hydrogenated Ethylene / Propylene / Styrene Copolymer, Hydrogenated Japan Wax, Hydrogenated Polyisobutenes, Hydrogenated Styrene / Butadiene Copolymer, Hydrogenated Styrene / Methyl Styrene / Indene Copolymer, Hydroxypropyl Cellulose, Isobutylene / Isoprene Copolymer, Lithium Oxidized Polyethylene, Methoxy PEG-17 / Dodecyl Glycol Copolymer, Methoxy PEG-22 / Dodecyl Glycol Copolymer, Methyl Methacrylate Crosspolymer, Methylstyrene / Vinyl Tolene Copolymer, Microcrystalline Wax, Montan Acid Wax, Montan Wax, Myrica Cerifera (Bayberry) Fruit Wax, Nylon 611 / Dimethicone Copolymer, Octadecenes / MA Copolymer, Oleic / Linoleic / Linolenic Polyglycerides, Ouricury Wax, Oxidized Beeswax, Oxidiz ed Microcrystalline Wax, Oxidized Polyethylene, Oxidized Polypropylene, Ozokerite, Paraffin, PEG-18 Castor Oil Dioleate, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-5 Hydrogenated Castor Oil Isostearate, PEG-10 Hydrogenated Castor Oil Isostearate, PEG -20 Hydrogenated Castor Oil Isostearate, PEG-30 Hydrogenated Castor Oil Isostearate, PEG-40 Hydrogenated Castor Oil Isostearate, PEG-50 Hydrogenated Castor Oil Isostearate, PEG-58 Hydrogenated Castor Oil Isostearate, PEG-50 Hydrogenated Castor Oil Succinate, PEG-5 PEG-20 Hydrogenated Castor Oil Triisostearate, PEG-20 Hydrogenated Castor Oil Triisostearate, PEG-30 Hydrogenated Castor Oil Triisostearate, PEG-40 Hydrogenated Castor Oil Triisostearate, PEG-60 Hydrogenated Castor Oil Triisostearate, PEG-5 Lanolinamide, PEG-5 Oleamide Dioleate, Phthalic Anhydride / Butyl Benzoic Acid / Propylene Glycol Copolymer, Phthalic Anhydride / Glycer in / glycidyl decanoate copolymer, phthalic anhydrides / trimellitic anhydrides / glycol copolymers, piperylenes / butenes / pentenes copolymers, polybutenes, polybutylenes terephthalates, polycyclopentadienes, polydipentenes, polyethylenes, polyethyleneterephthalates, polyglyceryl-3 polyricinoleates, polyglyceryl-4 polyricinoleates, polyglyceryl-5 polyricinoleates Polyglycerol-10 Polyricinoleates, Polyisobutenes, Polyisoprenes, Polypentene, Polyperfluoroethoxymethoxy Difluoromethyl Distearamide, Polypropylene, Polysilicone-4, Polysilicone-5, Polysilicone-17, Polystyrene, Polyvinyl Butyral, Polyvinyl Laurate, Potassium Oxidized Microcrystalline Wax, Potassium PEG-50 Hydrogenated Castor Oil Succinate, PVM / MA Decadiene Crosspolymer, PVP / Decene Copolymer, Rhus Succedanea Fruit Wax, Rosin, Silica Dimethicone Silylates, Silica Dimethyl Silylates, Simmondsia Chinensis (Jojoba) Seed Wax, Sodium PVM / MA / Decadiene Crosspolymer, Spent Grain Wax, Steareth- 10 allyl ether / acrylate copolymer, steareth-60 cetyl ether, stearoxyme thicone / Dimethicone Copolymer, Stearyl Methacrylate / Perfluorooctylethyl Methacrylate Copolymer, Styrene / Methacrylamide / Acrylates Copolymer, Synthetic Beeswax, Synthetic Candelilla Wax, Synthetic Carnauba, Synthetic Japan Wax, Synthetic Wax, TDI Oxidized Microcrystalline Wax, Tricontanyl PVP, Trifluoropropyl Dimethicone Crosspolymer, Trifluoropropyl Dimethicone / Trifluoropropyl Divinyl Dimethicone Crosspolymer, Trifluoropropyl Dimethicone / Vinyl Trifluoropropyl Dimethicone / Silsesquioxane Crosspolymer, Trimethylpentane Diol / Isophthalic Acid / Trimellitic Anhydride Copolymer, Trimethylsiloxysilicate / Dimethiconol Crosspolymer, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer, VP / Eicosene Copolymer, VP / Hexadecenes Copolymer.

Of course also include the emulsion-stabilizing polymers to the according to the invention preferred polymers. this includes are polymers to understand the construction and stabilization of emulsions (O / W and W / O as well as multiple emulsions) substantially support. Surfactants and emulsifiers are a matter of course the essential ingredients, however, bear the stabilizing Polymers by positively influencing the continuous or the disperse phase to reduce the coalescence of emulsified droplets. This positive influence can be on an electrical repulsion, an increase viscosity or filming on the droplet surface based. These properties of the polymers in question can also in the compositions according to the invention be particularly advantageously used to the inventive Active substances, the modified Titandioxidpartikel, stable in the inventive Keep compositions dispersed.

Examples of such polymers are Acrylamide / Sodium Acryloyl Dimethyl Taurate Copolymer, Acrylates / Amino Acrylates / C10-30 Alkyl PEG-20 Itaconate Copolymer, Acrylates / C10-30 Alkyl Acrylate Crosspolymer, Acrylates / Stearyl Methacrylate Copolymer, Acrylates / Vinyl Isodecanoate Crosspolymer, Alcaligenes Polysaccharides, Allyl Methacrylate Crosspolymer, Ammonium Acryloyldimethyltaurate / Beheneth-25 Methacrylate Crosspolymer, Ammonium Acryloyldimethyltaurate / Vinyl Formamide Copolymer, Ammonium Alginate, Ammonium Phosphatidyl Rapeseedate, Ammonium Polyacrylate, Ammonium Polyacryloyldimethyl Taurate, Ammonium Shellacate, Arachidyl Alcohol, Astragalus Gummifer Gum, Beeswax, Bentonite, Calcium Carboxymethyl Cellulose , Calcium Carrageenan, Calcium Potassium Carbomer, Calcium Starch Octenylsuccinate, C1-5 Alkyl Galactomannan, C18-38 Alkyl Hydroxystearoyl Stearate, Carbomer, Carboxymethyl Hydroxyethylcellulose, Carboxymethyl Hydroxypropyl Guar, Cellulose Acetate Propionate Carboxylate, Cellulose Gu m, Ceratonia Siliqua Gum, Cetyl Hydroxyethyl Cellulose, Chitosan Lauroyl Glycinate, Cholesterol, Cholesterol / HDI / Pullulan Copolymer, Corn Starch / Acrylamide / Sodium Acrylate Copolymer, C12-14 Sec-Pareth-3, C12-14 Sec-Pareth-5, C12 -14 Sec-Pareth-7, C12-14 Sec-Pareth-8, C12-14 Sec-Pareth-9, C12-14 Sec-Pareth-12, C12-14 Sec-Pareth-15, C12-14 Sec-Pareth -20, C12-14 Sec-Pareth-30, C12-14 Sec-Pareth-40, C12-14 Sec-Pareth-50, Cyamopsis Tetragonoloba (Guar) Gum, Dimethicone Crosspolymer, Dimethicone Crosspolymer-2, Dimethicone Ethoxy Glucoside, Euphorbia Cerifera (Candelilla) Wax, Gellan Gum, Hydrolyzed Beeswax, Hydrolyzed Candelilla Wax, Hydrolyzed Carnauba Wax, Hydrolyzed Collagen PG-Propyl Dimethiconol, Hydrolyzed Sunflower Seed Wax, Hydroxybutyl Methylcellulose, Hydroxyethyl Acrylate / Sodium Acryloyldimethyl Taurate Copolymer, Hydroxyethyl Cellulose, Hydroxyethyl Ethyl Cellulose, Hydroxyethyl Isostearyloxy Isopropanolamines, hydroxypropylcellulose, hydroxypropyl cyclodextrin, hydroxypropyl guar, Hydroxypropyl Methylcellulose, Hydroxypropyl Xanthan Gum, Isopropyl Ester of PVM / MA Copolymer, Lanolin, Lanolin Alcohol, Magnesium Alginate, Maltodextrin, Methoxy PEG-17 / Dodecyl Glycol Copolymer, Methoxy PEG-22 / Dodecyl Glycol Copolymer, Methylcellulose, Methyl Hydroxyethylcellulose, Microcrystalline Cellulose , Microcrystalline Wax, Montmorillonite, Moroccan Lava Clay, Myrica Cerifera (Bayberry) Fruit Wax, Octadecenes / MA Copolymer, Oleic / Linoleic / Linolenic Polyglycerides, Ozokerite, Pectin, PEG-350, PEG-400, PEG-500, PEG-12 Carnauba , PEG-12 Dimethicone Crosspolymer, PEG-22 / Dodecyl Glycol Copolymer, PEG-45 / Dodecyl Glycol Copolymer, PEG-6 Hydrogenated Palmamide, PEG-100 / IPDI Copolymer, PEG-2M, PEG-5M, PEG-7M, PEG- 9M, PEG-14M, PEG-20M, PEG-23M, PEG-25M, PEG-45M, PEG-65M, PEG-90M, PEG-115M, PEG-160M, PEG / PPG-20/23 dimethicones, PEG / PPG -23/6 Dimethicone, PEG / PPG-8/3 Laurate, PEG / PPG-10/3 Oleyl Ether Dimethicone, Polyacrylic Acid, Polyethylenes, Polyethylenes / Isopropyl Maleate / MA Copolyol, Polygl yceryl-2 Diisostearate / IPDI Copolymer, Polypropylene Terephthalate, Polysilicone-16, Polyvinyl Acetate, Potassium Alginate, Potassium Carbomer, Potassium Carrageenan, Potassium Dextrin Octenylsuccinate, Potassium Polyacrylate, Potassium Undecylenoyl Alginate, Potassium Undecylenoyl Carrageenan, Potassium Undecylenoyl Hydrolyzed Corn Protein, Potassium Undecylenoyl Hydrolyzed Soy Protein, Potassium Undecylenoyl Hydrolyzed Wheat Protein, PPG-3 C12-14 Sec-Pareth-7, PPG-4 C12-14 Sec-Pareth-5, PPG-5 C12-14 Sec-Pareth-7, PPG-5 C12 -14 sec-pareth-9, PPG-2 tocophereth-5, PPG-5 tocophereth-2, PPG-10 tocophereth-30, PPG-20 tocophereth-50, PVM / MA copolymer, PVP, PVP / decene copolymer, PVP montmorillonite , Pyrus Malus (Apple) Fiber, Saccharated Lime, Sclerotium Gum, Sodium Acrylate / Acryloyldimethyl Taurate Copolymer, Sodium Acrylate / Vinyl Isodecanoate Crosspolymer, Sodium Acrylate / Vinyl Alcohol Copolymer, Sodium Carbomer, Sodium Carboxymethyl Dextran, Sodium Carboxymethyl Starch, Sodium Carrageenan , Sodium Cellulose Sulfate, Sodium C4-12 Olefin / Maleic Acid Copolymer, Sodium Cyclodextrin Sulfate, Sodium Dextrin Octenylsuccinate, Sodium Polyacrylate, Sodium Polyacrylate Starch, Sodium Polyac ryloyldimethyl taurates, sodium polymethacrylates, sodium polynaphthalenesulfonates, sodium polystyrene sulfonates, sodium starch octenyl succinates, sodium / TEA-undecylenoyl alginates, sodium / TEA-undecylenoyl carrageenan, sodium tocopheryl phosphates, Starch hydroxypropyltrimonium chlorides, stearyl vinyl ether / MA copolymer, Sterculia urens gum, styrene / MA Copolymer, Sucrose Polypalmate, Synthetic Beeswax, Synthetic Wax, Tamarindus Indica Seed Gum, TEA Alginates, TEA Dextrin Octenylsuccinate, Undecylenoyl Inulin, Undecylenoyl Xanthan Gum, Welan Gum, Xanthan Gum, Zinc Undecylenoyl Hydrolyzed Wheat Protein.

Particularly preferred thickening and / or suspending polymers are acrylamide copolymer, acrylamide / sodium acrylate copolymer, acrylamide / sodium acryloyldimethyltaurate copolymer, acrylates / beheneth-25 methacrylate copolymer, acrylates / C10-30 alkyl acrylate bulk polymer, acrylates / ceteth-20 itaconate copolymer, chitosan Carbomer, guar hydroxypropyltrimonium chloride, hectorite, Hydrated silica, Hydrogenated Potato Starch, hydroxypropyl starch, hydroxypropyl Starch phosphates, hydroxypropyl xanthan gum, and the products sold under the trade names Carbopol ^®, Pemulen ^®, Jaguar ^®, Acrysol ^® or Salcare ^®.

The Polymers which have a thickening and / or suspending effect are preferred in the compositions of the invention in amounts of from 0.01 to 30% by weight, based on the total composition, contain. Amounts from 0.01 to 25, especially from 0.01 to 15 Wt .-%, are particularly preferred. Highly preferred Amounts of 0.05 wt .-% up to 5.0 wt .-% each based on the entire composition.

The Composition according to the invention for increasing the volume keratinhaltiger fibers, especially human hair, subject in terms of their form of packaging no restrictions and can be used as an emulsion, cream, solution, gel or Mousse be formulated.

preferred Embodiments of the invention By means of shampoos, hair conditioners, hair treatments, hair conditioner, Hair lotions, hair gels, hair sprays, hair foams, Hair fixatives, hair lotions and hair dyes, especially preferred are hair conditioners, hair conditioners, conditioners and shampoos.

The agents according to the invention can continue all active substances, additives known to and auxiliaries. In many cases, the included At least one surfactant, wherein in principle both anionic as well as zwitterionic, ampholytic, nonionic and cationic Surfactants are suitable.

For the case that the agent according to the invention as Rinse-off product such as a hair shampoo formulated is, it has proved to be advantageous, the surfactants from anionic, select zwitterionic or nonionic surfactants.

For the case that the agent according to the invention as Leave-on product such as a hair conditioner, a hair conditioner or a hair conditioner is formulated, it has proven to be beneficial proved to contain at least one cationic surfactant.

For the case that the agent according to the invention as Shampoo is made up, it will continue to contain at least an anionic, amphoteric, zwitterionic and / or nonionic Surfactant.

Of the Total surfactant content in the detergents is 5 to 35%, preferably 7 to 25% and in particular 8 to 15% - related on the total weight of the detergent.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – lineare Alkansulfonate mit 8 bis 24 C-Atomen,
• – lineare Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen,
• – Alkylsulfate und Alkylpolyglykolethersulfate der Formel R-O(CH₂-CH₂O)_x-OSO₃H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 12 ist,
• – Gemische oberflächenaktiver Hydroxysulfonate,
• – sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglykolether gemäß DE-A-37 23 354 ,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen gemäß DE-A-39 26 344 ,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2–15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel (II),
  
  in der R⁶ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R⁷ für Wasserstoff, einen Rest (CH₂CH₂O)_nR⁶ oder X, n für Zahlen von 1 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR⁸R⁹R¹⁰R¹¹, mit R⁸ bis R¹¹ unabhängig voneinander stehend für einen C₁ bis C₄-Kohlenwasserstoffrest, steht,
• – sulfatierte Fettsäurealkylenglykolester der Formel (III), R¹²CO(AlkO)_nSO₃M (III) in der R¹²CO- für einen linearen oder verzweigten, aliphatischen, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 C-Atomen, Alk für CH₂CH₂, CHCH₃CH₂ und/oder CH₂CHCH₃, n für Zahlen von 0,5 bis 5 und M für ein Kation steht, wie sie in der DE-OS 197 36 906.5 beschrieben sind,
• – Monoglyceridsulfate und Monoglyceridethersulfate der Formel (IV),
  
  in der R¹³CO für einen linearen oder verzweigten Acylrest mit 6 bis 22 Kohlenstoffatomen, x, y und z in Summe für 0 oder für Zahlen von 1 bis 30, vorzugsweise 2 bis 10, und X für ein Alkali- oder Erdalkalimetall steht. Typische Beispiele für im Sinne der Erfindung geeignete Mono glycerid(ether)sulfate sind die Umsetzungsprodukte von Laurinsäuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäu remonoglycerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxidaddukte mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vorzugsweise werden Monoglyceridsulfate der Formel (VIII) eingesetzt, in der R¹³CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht.

Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group,

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• - linear alkanesulfonates having 8 to 24 carbon atoms,
• - linear alpha-olefin sulfonates having 8 to 24 carbon atoms,
• Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 C atoms,
• Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H, in which R is a preferably linear alkyl group having 8 to 30 C atoms and x = 0 or 1 to 12,
• Mixtures of hydroxysulfonates,
• - Sulfated Hydroxyalkylpolyethylen- and / or Hydroxyalkylenpropylenglykolether according to DE-A-37 23 354 .
• - Sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344 .
• Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols containing 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula (II),
  
  in the R ^{6 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{7 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ⁶ or X, n is from 1 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ⁸ R ⁹ R ¹⁰ R ¹¹ , where R ⁸ to R ¹¹ independently of one another represent a C ₁ to C ₄ -hydrocarbon radical,
• Sulfated fatty acid alkylene glycol esters of the formula (III), R ¹² CO (AlkO) _n SO ₃ M (III) in the R ¹² CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or CH ₂ CHCH ₃ , n for numbers from 0.5 to 5 and M stands for a cation, as in the DE-OS 197 36 906.5 are described
• Monoglyceride sulphates and monoglyceride ether sulphates of the formula (IV),
  
  in which R ¹³ CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal. Typical examples of suitable within the meaning of the invention, monoglyceride (ether) sulfates are the reaction products of lauric monoglyceride, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäu remonoglyceride and Talgfettsäuremonoglycerid and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Preferably, monoglyceride sulfates of the formula (VIII) are used, in which R ¹³ CO is a linear acyl radical having 8 to 18 carbon atoms.

preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having 10 to 18 carbon atoms in the Alkyl group and up to 12 glycol ether groups in the molecule, Sulfosuccinic acid mono- and dialkyl esters with 8 to 18 C atoms in the alkyl group, Sulfobernsteinsäuremono-alkylpolyoxyethylester with 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups and the alkali and / or ammonium salts of Tridecethsulfats.

Especially preferred anionic surfactants are the alkali or ammonium salts of the lauryl ether sulfate having a degree of ethoxylation of 2 to 4 EO and the alkali metal and / or ammonium salts of Tridecethsulfats.

Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO ^(-) or -SO ₃ ^(-) group. Be particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammoniumglycinate, for example Kokosalkyldimethylammoniumglycinat, N-acyl-aminopropyl-N, N-dimethylammoniumglycinate, for example Kokosacylaminopropyldimethylammoniumglycinat, and 2-alkyl-3-carboxymethyl-3 Hydroxyethyl imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and Kokosacylaminoethylhydroxyethylcarboxymethylglycinat. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Amphoteric surfactants are understood to mean those surface-active compounds which, apart from a C ₈ -C ₂₄ -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO ₃ H group and which are capable of forming internal salts , Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C Atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ acylsarcosine.

• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – mit einem Methyl- oder C₂-C₆-Alkylrest endgruppenverschlossene Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C- Atomen in der Alkylgruppe, wie beispielsweise die unter den Verkaufsbezeichnungen Dehydol^® LS, Dehydol^® LT (Cognis) erhältlichen Typen,
• – C₁₂-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl, beispielsweise Rizinusöl-hydriert+40 EO, wie es beispielsweise unter dem Handelsnamen Cremophor CO 455 von der Firma SHC im Handel erhältlich ist,
• – Polyolfettsäureester, wie beispielsweise das Handelsprodukt Hydagen^® HSP (Cognis) oder Sovermol – Typen (Cognis),
• – alkoxilierte Triglyceride,
• – alkoxilierte Fettsäurealkylester der Formel (V) R¹⁴CO-(OCH₂CHR¹⁵)_wOR¹⁶ (V) in der R¹⁴CO für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 Kohlenstoffatomen, R¹⁵ für Wasserstoff oder Methyl, R¹⁶ für lineare oder verzweigte Alkylreste mit 1 bis 4 Kohlenstoffatomen und w für Zahlen von 1 bis 20 steht,
• – Aminoxide,
• – Hydroxymischether,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise die Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine,
• – Fettsäure-N-alkylglucamide,
• – Alkylpolygykoside entsprechend der allgemeinen Formel RO-(Z)_x wobei R für Alkyl, Z für Zucker sowie x für die Anzahl der Zuckereinheiten steht. Die erfindungsgemäß verwendbaren Al kylpolyglykoside können lediglich einen bestimmten Alkylrest R enthalten. Üblicherweise werden diese Verbindungen aber ausgehend von natürlichen Fetten und Ölen oder Mineralölen herge stellt. In diesem Fall liegen als Alkylreste R Mischungen entsprechend den Ausgangsverbindungen bzw. entsprechend der jeweiligen Aufarbeitung dieser Verbindungen vor.

Nonionic surfactants contain as hydrophilic group z. A polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such compounds are, for example

• - Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• - with a methyl or C ₂ -C ₆ alkyl radical end-capped addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 C atoms and with alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as those available under the trade names Dehydol ^® LS, LT Dehydol ^® types (Cognis),
• C ₁₂ -C ₃₀ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• Addition products of from 5 to 60 mol of ethylene oxide onto castor oil and hydrogenated castor oil, for example castor oil-hydrogenated + 40 EO, as it is commercially available, for example, under the trade name Cremophor CO 455 from SHC,
• - polyol, such as the commercially available product ^® Hydagen HSP (Cognis) or Sovermol - types (Cognis),
• - alkoxylated triglycerides,
• Alkoxylated fatty acid alkyl esters of the formula (V) R ¹⁴ CO- (OCH ₂ CHR ¹⁵ ) _w OR ¹⁶ (V) in the R ¹⁴ CO is a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{15 is} hydrogen or methyl, R ^{16 is} linear or branched alkyl radicals having 1 to 4 carbon atoms and w is a number from 1 to 20 stands,
• - amine oxides,
• - hydroxymix ether,
• Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates,
• Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters,
• Adducts of ethylene oxide with fatty acid alkanolamides and fatty amines,
• Fatty acid N-alkylglucamides,
• - Alkylpolygykoside according to the general formula RO- (Z) _x wherein R is alkyl, Z is sugar and x is the number of sugar units. The alkyl polyglycosides which can be used according to the invention can only contain one particular alkyl radical R. Usually, these compounds but starting from natural fats and oils or mineral oils Herge provides. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds.

• – im wesentlichen aus C₈- und C10-Alkylgruppen,
• – im wesentlichen aus C₁₂- und C₁₄-Alkylgruppen,
• – im wesentlichen aus C₈- bis C₁₆-Alkylgruppen oder
• – im wesentlichen aus C₁₂- bis C₁₆-Alkylgruppen oder
• – im wesentlichen aus C₁₆ bis C₁₈-Alkylgruppen besteht.

Particularly preferred are those alkyl polyglycosides in which R

• Essentially C ₈ and C 10 alkyl groups,
• Essentially of C ₁₂ and C ₁₄ alkyl groups,
• - Essentially from C ₈ - to C ₁₆ alkyl groups or
• - Essentially from C ₁₂ - to C ₁₆ alkyl groups or
• - Consists essentially of C ₁₆ to C ₁₈ alkyl groups.

When Sugar building block Z can be any mono- or oligosaccharides be used. Usually, sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides used. Such sugars are, for example, glucose, fructose, galactose, Arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, Idose, talose and sucrose. Preferred sugar building blocks are glucose, Fructose, galactose, arabinose and sucrose; Glucose is special prefers.

The Alkylpolyglycosides which can be used according to the invention contain on average 1.1 to 5 sugar units. Alkylpolyglykoside with x values of 1.1 to 2.0 are preferred. Very particularly preferred are alkyl glycosides in which x is 1.1 to 1.8.

Also the alkoxylated homologs of said alkyl polyglycosides can used according to the invention. These homologs can average up to 10 ethylene oxide and / or Propylene oxide units per Alkylglykosideinheit included.

When preferred nonionic surfactants are the alkylene oxide addition products saturated linear fatty alcohols and fatty acids with in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Preparations with excellent properties will also be obtained when they are fatty acid esters as nonionic surfactants of ethoxylated glycerol.

These Connections are identified by the following parameters. The alkyl radical R contains 6 to 22 carbon atoms and can be both linear and branched. Preference is given to primary linear and methyl-branched in the 2-position aliphatic radicals. Such Examples of alkyl radicals are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. Particularly preferred are 1-octyl, 1-decyl, 1-Lauryl, 1-myristyl. When using so-called "oxo-alcohols" as starting materials, compounds with an odd predominate Number of carbon atoms in the alkyl chain.

at it may be the compounds with alkyl groups used as surfactant each are uniform substances. It is, however, in usually preferred in the preparation of these substances by native to go out with vegetable or animal raw materials, so that one Substance mixtures with different, from the respective raw material receives dependent alkyl chain lengths.

at the surfactants, the adducts of ethylene and / or propylene oxide represent fatty alcohols or derivatives of these addition products, can both products with a "normal" homolog distribution as well as those with a narrow homolog distribution become. Under "normal" homolog distribution are mixtures understood by homologues who are involved in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts. Narrowed homolog distributions are obtained when, for example Hydrotalcites, alkaline earth metal salts of ether carboxylic acids, Alkaline earth metal oxides, hydroxides or alcoholates as catalysts be used. The use of products with narrow homolog distribution may be preferred.

In some preferred embodiments according to the invention have surfactant mixtures of crosslinked or uncrosslinked anionic Surfactants such as sodium trideceth sulfate, amphoteric surfactants such as sodium lauroamphoacetate and nonionic surfactants such as Cocamide MEA, as for example under the Trade name Miracare SLB 365 MP are commercially available, as a particularly suitable surfactant basis.

in the Within this embodiment of the invention, the inventive means continue at least a preservative selected from the group that is formed from benzoic acid, propionic acid, salicylic acid and / or sorbic acid, as well as from the cosmetically acceptable Salts and esters of these acids, formaldehyl and / or Paraformaldehyde, from benzyl alcohol, Germall, Dowicil, Kathon, Baypival, Methylisothiazolines, quaternary ammonium compounds, Alcohols and / or from essential oils such as tea tree oil, Cineole, eugenol, geraniol, limonene, menthol and / or thymol.

For the case in which the inventive agent as Shampoo is made up, it may be preferred that this at least one antidandruff agent in an amount of 0.05 to 5 Wt .-%, preferably from 0.1 to 3.0 wt .-% and in particular of 0.3 to 2.0 wt .-% (based on the total agent).

This) is (are) for example selected from Piroctone oil amines, Climbazole, zinc pyrithione, ketoconazole, salicylic acid, Sulfur, selenium sulfides, tar preparations, undecenoic acid derivatives, Burdock root extracts, poplar extracts, stinging nettle extracts, walnut shell extracts, Birch extracts, willow bark extracts, rosemary extracts and / or Arnica extracts.

For the case that the agents according to the invention are not as a shampoo (and thus primarily as a cleanser), but as a hair treatment agent with predominantly nourishing properties If they are formulated, they furthermore preferably contain cationic Surfactants. But to increase the care properties can Also, an inventive shampoo a content have cationic surfactants.

Suitable according to the invention cationic surfactants are quaternary ammonium compounds or so-called esterquats.

preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, Dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, z. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, Distearyldimethylammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as those under the INCI names Quaternium-27 and Quaternium-83 known imidazolium compounds. The long alkyl chains of the above surfactants mentioned preferably have 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are marketed under the trade names Stepantex® ^{®, ®} and Dehyquart® Armocare® ^®. The products Armocare ^® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® L80 and Dehyquart ^® AU-35 are examples of such esterquats.

The alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. An inventively particularly suitable compound from this group of substances under the name Tegoamid ^® S 18 commercial stearamidopropyl dimethylamine is.

The cationic surfactants are in the inventive Agents preferably in amounts of 0.05 to 10 wt .-%, based on the entire remedy, included. Amounts of 0.1 to 5 wt .-% are particularly preferred.

invention Hair rinses, hair treatments, hair lotions, hair gels, Hair sprays, hair mousses, hair fixatives, hair lotions and hair dyes can continue in these Means common, components included. For example contains the agent according to the invention further at least one member of the group of water-insoluble Wax and oil components, the UV filter, the amino acids, the water-insoluble silicones, the water-soluble ones Silicones and / or amodimethicones. Also for an inventive Shampoo, which in addition to a good cleaning effect nourishing It may be advantageous to have one or more properties to contain the aforementioned components.

When Water-insoluble oil components are mineral according to the invention or synthetic oils, as well as mixtures of these components.

As mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons. An inventively employable hydrocarbon is for example that available as a commercial product 1,3-di- (2-ethylhexyl) -cyclohexane (Cetiol ^® S).

When Synthetic oils come silicone compounds, in particular Dialkyl and alkylaryl silicones, such as dimethylpolysiloxane and methylphenylpolysiloxane, as well as their hydroxy-terminated, alkoxylated and quaternized analogs. Examples of such Silicones are those of Dow Corning under the designations DC 190, DC 200, DC 344 and DC 345 (cyclomethicone).

As an oil component may continue to serve a dialkyl ether.

Dialkyl ethers which can be used according to the invention are in particular di-n-alkyl ethers with a total of between 12 to 36 C atoms, in particular 12 to 24 C atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl -n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl n-undecyl ether and di-tert-butyl ether, di-iso-pentyl ether, Di-3-ethyldecyl ether, tert-butyl n-octyl ether, iso-pentyl n-octyl ether and 2-methylpentyl-n-octyl ether.

According to the invention particularly preferred is the di-n-octyl ether, which is commercially available under the name Cetiol ^® OE.

The agents according to the invention contain the water-insoluble oil component preferably in an amount range of 0.1 to 5 wt .-%, in particular from 0.5 to 3 wt .-%, based on the total weight of the composition.

In a further preferred embodiment of the invention can the effect of the drug combination of the invention be further optimized by further fatty substances. Among others Fats are understood to be fatty acids as well as natural and synthetic waxes which are both solid and liquid may be present in aqueous dispersion.

As fatty acids can be used linear and / or branched, saturated and / or unsaturated fatty acids with 6-30 carbon atoms. Preferred are fatty acids with 10-22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Further typical examples of such fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic as well as their technical mixtures, the z. As in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from the Roelen oxo synthesis or the dimerization of unsaturated fatty acids. Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

The Use amount is 0.1-15 wt .-%, based on the entire remedy. In a preferred embodiment the amount is 0.5-10 wt .-%, with very special advantageous amounts of 1-5 wt .-% are.

When Natural or synthetic waxes can be used according to the invention be solid paraffins or isoparaffins, carnauba waxes, bee waxes, Candelilla, ozokerite, ceresin, spermaceti, sunflower wax, Fruit waxes such as apple wax or citrus wax, Microwachse made of PE or PP. Such waxes are available for example via the company Kahl & Co., Trittau.

• – Dicarbonsäureester wie Di-n-butyladipat, Di-(2-ethylhexyl)-adipat, Di-(2-ethylhexyl)-succinat und Di-isotridecylacelaat sowie Diolester wie Ethylenglykol-dioleat, Ethylenglykol-di-isotridecanoat, Propylenglykol-di(2-ethylhexanoat), Propylenglykol-di-isostearat, Propylenglykol-di-pelargonat, Butandiol-di-isostearat, Neopentylglykoldicaprylat,
• – symmetrische, unsymmetrische oder cyclische Ester der Kohlensäure mit Fettalkoholen, beispielsweise beschrieben in der DE-OS 197 56 454 , Glycerincarbonat oder Dicaprylylcarbonat (Cetiol^® CC).

Other fatty substances are, for example

• Dicarboxylic acid esters such as di-n-butyl adipate, di (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2 ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol dicaprylate,
• Symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example described in US Pat DE-OS 197 56 454 , Glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC).

The Use amount of other fatty substances is 0.1-20 Wt .-% based on the total agent. Preferred are 0.1-10 Wt .-% and particularly preferably 0.1-5 wt .-%, based on the entire remedy.

The Total amount of oil and fat components in the invention Means is usually 0.01-15 Wt .-%, based on the total agent. Amounts of 0.05-5 % By weight are preferred according to the invention.

Furthermore, in a preferred embodiment of the invention, the effect of the preparations can be increased by UV filters. The UV filters to be used according to the invention are not subject to any general restrictions with regard to their structure and their physical properties. On the contrary, all UV filters which can be used in the cosmetics sector and whose absorption maximum lies in the UVA (315-400 nm), in the UVB (280-315 nm) or in the UVC (<280 nm) range are suitable. UV filter with an absorption maximum in the UVB range, especially in the range of about 280 to about 300 nm, are particularly preferred.

The According to the invention used UV filter for example, be selected from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic esters, Cinnamic acid esters, salicylic acid esters, benzimidazoles and o-arynobenzoic acid esters.

Examples of UV filters which can be used according to the invention are 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline-methylsulfate, 3,3,5-trimethyl-cyclohexylsalicylate (homosalates), 2-hydroxy-4-methoxy-benzophenone (benzophenone-3; Uvinul ^® M 40, Uvasorb MET ^{®, ®} Neo Heliopan BB, Eusolex ^® 4360), 2-phenylbenzimidazole-5-sulfonic acid and potassium, sodium and triethanolamine salts ( Phenylbenzimidazole Sulfonic Acid; Parsol ^® HS; Neo Heliopan Hydro ^®), 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo [2.2.1] hept-1- yl-methane sulfonic acid) and salts thereof, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) Methoxydibenzoylmethane -propane-1,3-dione (butyl; Parsol ^® 1789 Eusolex ^® 9020), α - (2-oxoborn-3-ylidene) toluene-4-sulfonic acid and salts thereof, ethoxylated 4-aminobenzoic acid ethyl ester (PEG-25 PABA; Uvinul ^® P 25), 4-dimethylaminobenzoic acid 2-ethylhexyl (octyl dimethyl PABA; Uvasorb ^® DMO, Escalol ^® 507, Eusolex ^® 6007), salicylic acid-2-ethylhexy ester (octyl salicylate; Escalol ^® 587, Neo Heliopan ^® OS, Uvinul ^® O18), 4-methoxycinnamic acid isopentyl (isoamyl p-methoxycinnamate; Neo Heliopan ^® E 1000), 4-methoxycinnamic acid 2-ethylhexyl ester (Octyl Methoxycinnamate; Parsol ^® MCX, Escalol ^® 557, Neo Heliopan AV ^®), 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone-4; Uvinul ^® MS 40; Uvasorb S 5 ^®), 3- (4'-methylbenzylidene) -D, L-camphor (4-methylbenzylidene camphor; Parsol ^® 5000, Eusolex ^® 6300), 3-benzylidene camphor (3-benzylidene camphor), 4-isopropylbenzyl, 2,4,6-trianilino- (p-carbo-2'- ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl } -acrylamids, 2,4-dihydroxy (benzophenone-1; Uvasorb ^® 20 H, Uvinul ^® 400), 1,1'-Diphenylacrylonitrilsäure-2-ethylhexyl ester (Octocrylene; Eusolex ^® OCR, Neo Heliopan ^® Type 303, Uvinul ^® N 539 SG), o-aminobenzoic acid menthyl ester (Menthyl Anthranilate; Neo He liopan ^® MA), 2,2 ', 4,4'-tetrahydroxy benzophenone (benzophenone-2; Uvinul ^® D-50), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (Benzophenone-6), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sodium sulfonate, and 2-cyano-3, 3-diphenylacrylate 2'-ethylhexyl acrylate. Preference is given to 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methylsulfate, 3,3,5-trimethylcyclohexyl salicylate, 2-hydroxy-4-methoxybenzophenone , 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 3,3 '- (1,4-phenylenedimethylene) bis (7,7-dimethyl-2-oxo-bicyclo [2.2.1] hept -1-yl-methanesulfonic acid) and its salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, α- (2-oxoborn-3-ylidene ) -toluene-4-sulfonic acid and its salts, ethoxylated 4-aminobenzoic acid ethyl ester, 2-ethylhexyl 4-dimethylaminobenzoate, 2-ethylhexyl salicylate, isopentyl 4-methoxycinnamate, 2-ethylhexyl 4-methoxycinnamate, 2- Hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt, 3- (4'-methylbenzylidene) -D, L-camphor, 3-benzylidene-camphor, 4-isopropylbenzyl salicylate, 2,4,6-trianilino- (p-carbo 2'-ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-o xoborn-3-ylidenemethyl] benzyl} acrylamide. Very particularly preferred according to the invention are 2-hydroxy-4-methoxybenzophenone, 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, 4-methoxycinnamic acid 2-ethylhexyl ester and 3- (4'-methylbenzylidene) -D, L-camphor.

Prefers are those UV filters whose molar extinction coefficient at the absorption maximum above 15,000, especially above 20,000.

Farther was found to be structurally similar UV filters in many cases, the water-insoluble Compound within the scope of the teaching of the invention the higher effect over such water-soluble Compounds that are distinguished from it by one or more additionally differentiate ionic groups. As water insoluble Within the scope of the invention, UV filters are to be understood which at 20 ° C to not more than 1 wt .-%, in particular to not more than 0.1% by weight, dissolve in water. Farther These compounds should be used in usual cosmetic oil components at room temperature to at least 0.1, in particular at least 1 wt .-% be soluble). The use of water-insoluble UV filter can therefore be preferred according to the invention be.

According to one Another embodiment of the invention are those UV filters preferably a cationic group, in particular a quaternary Ammonium group.

These UV filters have the general structure U-Q.

The structural part U stands for a UV-absorbing group. This group can be in the Derive principle of the known, usable in the cosmetics sector, above UV filters in which a group, usually a hydrogen atom, of the UV filter is replaced by a cationic group Q, in particular with a quaternary amino function.

• – substituierte Benzophenone,
• – p-Aminobenzoesäureester,
• – Diphenylacrylsäureester,
• – Zimtsäureester,
• – Salicylsäureester,
• – Benzimidazole und
• – o-Aminobenzoesäureester.

Compounds from which the structural part U can derive are, for example

• Substituted benzophenones,
• P-aminobenzoic acid ester,
• - diphenylacrylic acid ester,
• - cinnamic acid ester,
• Salicylic acid ester,
• Benzimidazoles and
• O-aminobenzoic acid ester.

structural parts U, derived from cinnamic acid amide or N, N-dimethylamino-benzoic acid amide derive, are preferred according to the invention.

The Structural parts U can be chosen in principle be that the absorption maximum of the UV filter both in the UVA (315-400 nm) - as well as in the UVB (280-315 nm) - or in UVC (<280 nm) range can be. UV filter with an absorption maximum in the UVB range, especially in the range of about 280 to about 300 nm, are particularly preferred.

Farther becomes the structural part U, also depending on structural part Q, preferably chosen so that the molar extinction coefficient of the UV filter at the absorption maximum above 15,000, in particular above from 20000, lies.

Of the Structural part Q preferably contains as a cationic group a quaternary ammonium group. This quaternary ammonium group can in principle be connected directly to the structural part U, so the structural part U is one of the four substituents of the represents a positively charged nitrogen atom. However, it is preferred one of the four substituents on the positively charged nitrogen atom a group, in particular an alkylene group having 2 to 6 carbon atoms, as the connection between the structural part U and the positively charged Nitrogen atom acts.

Advantageously, the group Q has the general structure - (CH ₂ ) _x -N ⁺ R ¹ R ² R ³ X ^- , in which x is an integer from 1 to 4, R ¹ and R ² independently of one another are C _{1 -4} alkyl groups, R ³ is a C _1-22 alkyl group or a benzyl group and X ^{- is} a physiologically acceptable anion. In the context of this general structure, x preferably represents the number 3, R ¹ and R ² each represent a methyl group and R ^{3 represents} either a methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain having 8 to 22, in particular 10 to 18, carbon atoms.

physiological Compatible anions are, for example, inorganic anions such as halides, especially chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, Tartrate, methosulfate and tosylate.

Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid trimethyl ammonium chloride (Incroquat ^® UV-283) and Dodecyldimethylaminobenzamidopropyl-tosylate (Escalol ^® HP 610).

Of course includes the teaching of the invention also the use of a combination of multiple UV filters. As part of In this embodiment, the combination is at least one water-insoluble UV filter with at least one UV filter preferred with a cationic group.

The UV filters (I) are used in the invention Usually in amounts of 0.1-5% by weight, based on the total mean, included. Amounts of 0.4-2.5 % By weight are preferred.

According to one further preferred embodiment of the invention included the media as well at least one volatile or non-volatile, water-insoluble silicone, water-soluble and / or amino-functionalized silicone.

According to the invention suitable silicones cause a variety of effects. For example, at the same time they influence the dry and wet combability, the grip of dry and wet hair as well as the shine. By the term silicones the skilled person understands several structures of organosilicon compounds.

Dimethiconols (S1) form the first group of silicones which are particularly preferred according to the invention. The dimethiconols according to the invention can be both linear and branched as well as cyclic or cyclic and branched. Linear dimethiconols can be represented by the following structural formula (S1-I): (SiOHR ¹ ₂ ) -O- (SiR ² ₂ -O-) _x - (SiOHR ¹ ₂ ) (S1-I)

Branched dimethiconols can be represented by the structural formula (S1-II):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Preferred as R ¹ and R ² are methyl, phenyl and C ² to C 22 alkyl radicals. Of the C2 to C22 alkyl radicals, lauryl, stearyl and behenyl radicals are particularly preferred. The numbers x, y and z are integers and each run independently from 0 to 50,000. The molecular weights of the dimethicones are between 1000 D and 10,000,000 D. The viscosities are between 100 and 10,000,000 cPs measured at 25 ° C. with the aid of a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 1,000 and 5,000,000 cps, particularly preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.

Of course, the teaching of the invention also includes that the dimethiconols may already be present as an emulsion. In this case, the corresponding emulsion of the dimethiconols can be prepared both after the preparation of the corresponding dimethiconols from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of the dimethiconols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, refer to the Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989 , This reference is expressly incorporated by reference.

If the dimethiconols according to the invention as emulsion are used, then the droplet size is the emulsified particles according to the invention 0.01 microns to 10000 microns, preferably 0.01 to 100 microns, very particularly preferably 0.01 to 20 microns and most preferably 0.01 to 10 μm. The particle size is after determined by the method of light scattering.

If branched dimethiconols are used, it is to be understood that the branching is greater than a random branching, which occurs by impurities of the respective monomers randomly. For the purposes of the present invention, branched dimethiconols are therefore to be understood as meaning that the degree of branching is greater than 0.01%. Preferably, a degree of branching is greater than 0.1% and all more preferably greater than 0.5%. The degree of branching is determined from the ratio of unbranched monomers, that is, the amount of monofunctional siloxane, to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention, both low-branched and highly branched dimethiconols can be very particularly preferred.

When Examples of such products are the following commercial products called: Botanisil NU-150M (Botanigenics), Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Coming 2-9026 Fluid, Ultrapure Dimethiconol (Ultra Chemical), Unisil SF-R (Universal Preserve), X-21-5619 (Shin-Etsu Chemical Co.), Abil OSW 5 (Degussa Care Specialties), ACC DL-9430 Emulsion (Taylor Chemical Company), AEC Dimethiconol & Sodium Dodecylbenzenesulfonate (A & E Connock (Perfumery & Cosmetics) Ltd.), B C Dimethiconol Emulsion 95 (Basildon Chemical Company, Ltd.), Cosmetic Fluid 1401, Cosmetic Fluid 1403, Cosmetic Fluid 1501, Cosmetic Fluid 1401DC (all of the aforementioned Chemsil Silicones, Inc.), Dow Corning 1401 Fluid, Dow Corning 1403 Fluid, Dow Corning 1501 Fluid, Dow Corning 1784 HVF Emulsion, Dow Corning 9546 Silicone Elastomer Blend (all aforementioned Dow Corning Corporation), Dub Gel SI 1400 (Stearinerie Dubois Fils), HVM 4852 Emulsion (Crompton Corporation), Jeesilc 6056 (Jeen International Corporation), Lubrasil, Lubrasil DS (both Guardian Laboratories), Nonychosine E, Nonychosine V (both Exsymol), SanSurf Petrolatum-25, Satin Finish (both Collaborative Laboratories, Inc.), Silatex-D30 (Cosmetic Ingredient Resources), Silsoft 148, Silsoft E-50, Silsoft E-623 (all previously mentioned Crompton Corporation), SM555, SM2725, SM2765, SM2785 (all previously mentioned GE Silicones), Taylor T-Sil CD-1, Taylor TME-4050E (all Taylor Chemical Company), TH V 148 (Crompton Corporation), Tixogel CYD-1429 (Sud-Chemie Performance Additives), Wacker-Belsil CM 1000, Wacker-Belsil CM 3092, Wacker-Belsil CM 5040, Wacker-Belsil DM 3096, Wacker-Belsil DM 3112 VP, Wacker-Belsil DM 8005 VP, Wacker-Belsil DM 60081 VP (all aforementioned Wacker-Chemie GmbH).

If the dimethiconols (S1) are contained in the base composition, so these compositions contain 0.01 to 10 wt .-%, preferably 0.1 to 8 wt .-%, particularly preferably 0.25 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% of dimethiconol based on the composition.

Also particularly suitable according to the invention are the so-called dimethicones (S2). These may be both linear and branched as well as cyclic or cyclic and branched. Linear dimethicones can be represented by the following structural formula (S2-I): (SiR ¹ ₃ ) -O- (SiR ² ₂ -O-) _x - (SiR ¹ ₃ ) (S2-I)

Branched dimethicones can be represented by the structural formula (S2-II):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Preferred as R ¹ and R ² are methyl, phenyl and C ² to C 22 alkyl radicals. Of the C2 to C22 alkyl radicals, lauryl, stearyl and behenyl radicals are particularly preferred. The numbers x, y and z are integers and each run independently from 0 to 50,000.

Especially preferred according to the invention are the linear polydialkylsiloxanes, the polyalkylarylsilo xans, the polydiarylsiloxanes and / or the dihydroxypolydimethylsiloxanes.

The Molweights of the invention suitable Dimethicone lie between 1000 D and 10000000 D.

The Viscosities of the invention suitable Dimethicones are usually between 0.01 and 10,000,000 cPs measured at 25 ° C using a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 0.1 and 5,000,000 cps, very particularly preferred viscosities lie between 0.1 and 3 million cps. The most preferred viscosity range the dimethicone is between 0.6 and 600,000 cps.

Of course, the teaching of the invention also includes that the dimethicones may already be present as an emulsion. In this case, the corresponding emulsion of the dimethicones can be prepared both after the preparation of the corresponding dimethicones from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of dimethicones can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, refer to the Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989 , This reference is expressly incorporated by reference.

If the Dimethicone invention as an emulsion are used, then the droplet size is the emulsified particles according to the invention 0.01 microns to 10000 microns, preferably 0.01 to 100 microns, very particularly preferably 0.01 to 20 microns and most preferably 0.01 to 10 μm. The particle size is after determined by the method of light scattering.

Become used branched dimethicones, so to understand it that the branching is greater than a random one Branching caused by contamination of the respective monomers happens by chance. For the purposes of the present invention is therefore to be understood by branched dimethicones that the degree of branching is greater than 0.01%. Preferred is a degree of branching greater than 0.1%, and most preferably from greater than 0.5%. The degree of branching becomes thereby from the relationship of the unbranched monomers, the is the amount of monofunctional siloxane, to the branching monomers, that is, the amount of tri- and tetrafunctional siloxanes. According to the invention both low branched and highly branched dimethicones entirely particularly preferred.

If the dimethicones (S2) are contained in the base composition, so these compositions contain 0.01 to 10 wt .-%, preferably 0.1 to 8 wt .-%, particularly preferably 0.25 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% of dimethicone, based on the composition.

Dimethicone copolyols (S3) form another group of preferred silicones. Dimethiconols can be represented by the following structural formulas: (SiR ¹ ₃₎ -O- (SiR ² ₂ -O-) _x - (Sirpe-O-) _y - (SiR ¹ ₃₎ (S3-I) or by the following structural formula: PE- (SiR ¹ ₂ ) -O- (SiR ² ₂ -O-) _x - (SiR ¹ ₂ ) -PE (S3-II)

oder durch die Strukturformel (S3-IV):

Branched dimethicone copolyols can be represented by the structural formula (S3-III):

or by the structural formula (S3-IV):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Preferred as R ¹ and R ² are methyl, phenyl and C ² to C 22 alkyl radicals. Of the C2 to C22 alkyl radicals, lauryl, stearyl and behenyl radicals are particularly preferred. PE stands for a polyoxyalkylene radical. Preferred polyoxyalkylene radicals are derived from ethylene oxide, propylene oxide and glycerol. The numbers x, y and z are integers and each run independently from 0 to 50,000. The molecular weights of the dimethicones are between 1000 D and 10,000,000 D. The viscosities are between 100 and 10,000,000 cPs measured at 25 ° C. with the aid of a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 1,000 and 5,000,000 cps, particularly preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.

Of course, the teaching of the invention also includes that the Dimethiconcopolymere can already be present as an emulsion. In this case, the corresponding emulsion of the dimethicone copolyols can be prepared both after the preparation of the corresponding dimethicone copolyols from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of dimethicone copolyols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, refer to the Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989 , This reference is expressly incorporated by reference.

If the dimethicone copolyols according to the invention as Emulsion are used, then is the Tropfchengrolle the emulsified particles according to the invention 0.01 microns to 10000 microns, preferably 0.01 to 100 microns, completely more preferably 0.01 to 20 microns, and most preferably 0.01 to 10 μm. The particle size is determined by the method of light scattering.

Become used branched dimethicone copolyols, it is to be understood as that the branching is greater than a random one Branching caused by contamination of the respective monomers happens by chance. For the purposes of the present invention is therefore to be understood by branched dimethicone copolyols that the degree of branching is greater than 0.01%. Prefers is a degree of branching greater than 0.1% and whole more preferably greater than 0.5%. The degree The branching is thereby from the relationship of the unbranched Monomers, that is, the amount of monofunctional siloxane, to the branching monomers, that is the amount of tri- and tetrafunctional siloxanes. According to the invention both low branched and highly branched dimethicone copolyols be particularly preferred.

If containing dimethicone copolyols (S3) in the base composition are, then these compositions contain 0.01 to 10 wt .-%, preferably 0.1 to 8 wt .-%, particularly preferably 0.25 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% of dimethicone copolyol based on the composition.

Amino-functional Silicones or amodimethicones (S4) are called silicones which have at least one (optionally substituted) amino group.

Such silicones may, for. By the formula (S4-I) M (R _a Q _b SiO _{(4-ab) / 2) x} (R _c SiO _{(4-c) / 2) y} M (S4-I)

Will be described, wherein in the above formula R is a hydrocarbon or a hydrocarbon radical having from 1 to about 6 carbon atoms, Q is a polar radical of the general formula -R ¹ HZ, wherein R ^{1 is} a divalent connecting group attached to hydrogen and the Z is an organic, amino-functional radical containing at least one amino-functional group, carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon, hydrogen and nitrogen atoms; "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 1 to about 3, "a" + "b" is less than or equal to 3, and "c" is a number in the range from about 1 to about 3, and x is a number ranging from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25, and y is a number ranging from about 20 to about 10,000 , preferably from about 125 to about 10,000, and most preferably from about 150 to about 1,000, and M is a suitable silicone end group as known in the art, preferably trimethylsiloxy. Non-limiting examples of the groups represented by R include alkyl groups such as methyl, ethyl, propyl, isopropyl, isopropyl, butyl, isobutyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; preferably R is an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R is methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -.

Z is an organic, amino-functional radical containing at least one functional amino group. A possible formula for Z is NH (CH ₂ ) _z NH ₂ , wherein z is 1 or more. Another possible formula for Z is -NH (CH ₂ ) _z (CH ₂ ) _zz NH, wherein both z and zz are independently 1 or more, which structure includes diamino ring structures, such as piperazinyl. Z is most preferably a -NHCH ₂ CH ₂ NH ₂ radical. Another possible formula for Z is - N (CH ₂ ) _z (CH ₂ ) _zz NX ₂ or -NX ₂ , wherein each X of X _{2 is} independently selected from the group consisting of hydrogen and alkyl groups of 1 to 12 carbon atoms, and z is 0.

Q is most preferably a polar, amine functional group of the formula -CH ₂ CH ₂ CH ₂ NHCH ₂ CH ₂ NH ₂ . In the formulas, "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 2 to about 3, "a" + "b" is less than or equal to 3, and "c "is a number in the range of about 1 to about 3. The molar ratio of the R _a Q _b SiO _{(4-ab) / 2} units to the R _c SiO _{(4-c) / 2} units is in the range of about 1: 2 to 1:65, preferably from about 1: 5 to about 1:65, and most preferably from about 1:15 to about 1:20. When one or more silicones of the above formula are used, the various variable substituents in the above formula may be different for the various silicone components present in the silicone blend.

• – G ist–H, eine Phenylgruppe, -OH, -O-CH₃, -CH₃, -CH₂CH₃, -CH₂CH₂CH₃, -CH(CH₃)₂, -CH₂CH₂CH₂H₃, -CH₂CH(CH₃)₂, -CH(CH₃)CH₂CH₃, -C(CH₃)₃;
• – a steht für eine Zahl zwischen 0 und 3, insbesondere 0;
• – b steht für eine Zahl zwischen 0 und 1, insbesondere 1,
• – m und n sind Zahlen, deren Summe (m + n) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei n vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt,
• – R' ist ein monovalenter Rest ausgewählt aus – -N(R'')-CH₂-CH₂-N(R'')₂ – N(R'')₂ – -N⁺(R'')₃A^– – -N⁺H(R'')₂A^– – -N⁺H₂(R'')A^– – -N(R'')-CH₂-CH₂-N⁺R''H₂A^–, wobei jedes R'' für gleiche oder verschiedene Reste aus der Gruppe -H, -Phenyl, -Benzyl, der C_1-20-Alkylreste, vorzugsweise -CH₃, -CH₂CH₃, -CH₂CH₂CH₃, -CH(CH₃)₂, -CH₂CH₂CH₂H₃, -CH₂CH(CH₃)₂, -CH(CH₃)CH₂CH₃, -C(CH₃)₃, steht und A ein Anion repräsentiert, welches vorzugsweise ausgewählt ist aus Chlorid, Bromid, Iodid oder Methosulfat.

Preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (S4-II) R _'a G _3-a -Si (OSiG _{2) n} - (OSiG _b R' _{2-b) m} -O-SiG _3-a -R _'a (S4-II), contain, in which means:

• G is -H, a phenyl group, -OH, -O-CH ₃ , -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ ) ₃ ;
• A is a number between 0 and 3, in particular 0;
• B is a number between 0 and 1, in particular 1,
• M and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10,
• R 'is a monovalent radical selected from --N (R'') - CH ₂ -CH ₂ -N (R'') ₂ - N (R '') ₂ - N ⁺ (R '') ₃ A ^{- -} - N ⁺ H (R '') ₂ A ^- - - N ⁺ H ₂ (R '') A ^- - - N ( R '') - CH ₂ -CH ₂ -N ⁺ R''H ₂ A ^- , wherein each R "represents identical or different radicals from the group -H, -phenyl, -benzyl, the C _1-20 -alkyl radicals , preferably -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ ) ₃ , and A represents an anion, which is preferably selected from chloride, bromide, iodide or methosulfate.

enthalten, worin m und n Zahlen sind, deren Summe (m + n) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei n vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt.Particularly preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (S4-III)

in which m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.

These Silicones are classified as trimethylsilylamodimethicones according to the INCI declaration designated.

enthalten, worin R für -OH, -O-CH₃ oder eine -CH₃-Gruppe steht und m, n1 und n2 Zahlen sind, deren Summe (m + n1 + n2) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei die Summe (n1 + n2) vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt.Agents according to the invention which are characterized in that they contain an amino-functional silicone of the formula (S4-IV) are also particularly preferred.

in which R is -OH, -O-CH ₃ or a -CH ₃ group and m, n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2,000, preferably between 50 and 150 , where the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.

These Silicones are called amodimethicones according to the INCI declaration.

Independently of which amino-functional silicones are used are agents according to the invention are preferred in which the amino-functional silicone has an amine number above 0.25 meq / g, preferably above 0.3 meq / g and in particular above 0.4 meq / g. The amine number stands for the milliequivalents Amine per gram of amino-functional silicone. It can be done by titration determined and also in the unit mg KOH / g.

If the amodimethicones (S4) are contained in the base composition, so these compositions contain 0.01 to 10 wt .-%, preferably 0.1 to 8 wt .-%, particularly preferably 0.25 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% of amodimethicone based on the composition.

Become different silicones used as a mixture, so is the mixing ratio largely variable. However, all are preferably used for the mixture Silicones in a ratio of 5: 1 to 1: 5 in the case of a used binary mixture. A ratio of 3: 1 to 1: 3 is particularly preferred. Very particularly preferred mixtures contain all the silicones contained in the mixture as much as possible in a ratio of about 1: 1, in each case based on the amounts used in wt .-%.

If the silicone blend are included in the base composition, so these compositions contain 0.01 to 10 wt .-%, preferably 0.1 to 8 wt .-%, particularly preferably 0.25 to 7.5 wt .-% and in particular 0.5 to 5 wt .-% of silicone mixture based on the composition.

• – Anlagerungsprodukte von 4 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – C₁₂-C₂₂-Fettsäuremono- und diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Polyole mit 3 bis 6 Kohlenstoffatomen, insbesondere an Glycerin,
• – Ethylenoxid- und Polyglycerin-Anlagerungsprodukte an Methylglucosid-Fettsäureester, Fettsäurealkanolamide und Fettsäureglucamide,
• – C₈-C₂₂-Alkylmono- und oligoglycoside und deren ethoxylierte Analoga, wobei Oligomerisierungsgrade von 1,1 bis 5, insbesondere 1,2 bis 2,0, und Glucose als Zuckerkomponente bevorzugt sind,
• – Gemische aus Alkyl-(oligo)-glucosiden und Fettalkoholen zu Beispiel das im Handel erhältliche Produkt Montanov^® 68,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Partialester von Polyolen mit 3 bis 6 Kohlenstoffatomen mit gesättigten Fettsäuren mit 8 bis 22 C-Atomen,
• – Sterine. Als Sterine wird eine Gruppe von Steroiden verstanden, die am C-Atom 3 des Steroid-Gerüsts eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine) wie auch aus pflanzlichen Fetten (Phytosterine) isoliert werden. Beispiele für Zoosterine sind das Cholersterin und das Lanosterin. Beispiele geeigneter Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Auch aus Pilzen und Hefen werden Sterine, die sogenannten Mykosterine, isoliert.
• – Phospholipide. Hierunter werden vor allem die Glucose-Phospholipide, die z. B. als Lecithine bzw. Phosphatidylcholine aus z. B. Eidotter oder Pflanzensamen (z. B. Sojabohnen) gewonnen werden, verstanden.
• – Fettsäureestervon Zuckern und Zuckeralkoholen, wie Sorbit,
• – Polyglycerine und Polyglycerinderivate wie beispielsweise Polyglycerin poly-12-hydroxystearat (Handelsprodukt Dehymuls^® PGPH),
• – Lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen und deren Na-, K-, Ammonium-, Ca-, Mg- und Zn-Salze.

In a further preferred embodiment, the effect of the active ingredient combination according to the invention can be increased by emulsifiers. Such emulsifiers are, for example

• - Addition products of 4 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear Fettal alcohols containing 8 to 22 carbon atoms, fatty acids containing 12 to 22 carbon atoms and alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• C ₁₂ -C ₂₂ -fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto polyols having from 3 to 6 carbon atoms, in particular to glycerol,
• Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
• C ₈ -C ₂₂ -alkyl mono- and oligoglycosides and their ethoxylated analogues, preference being given to degrees of oligomerization of from 1.1 to 5, in particular from 1.2 to 2.0, and glucose as the sugar component,
• Glucosides mixtures of alkyl (oligo) and fatty alcohols for example, the commercially available product ^® Montanov 68, -
• Adducts of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,
• Partial esters of polyols having 3 to 6 carbon atoms with saturated fatty acids having 8 to 22 C atoms,
• - sterols. Sterols are understood to mean a group of steroids which have a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols.
• - Phospholipids. Of these, especially the glucose phospholipids z. B. as lecithins or phosphatidylcholines from z. Egg yolks or plant seeds (eg soybeans) are understood.
• Fatty acid esters of sugars and sugar alcohols, such as sorbitol,
• - polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate (commercial product Dehymuls ^® PGPH),
• - Linear and branched fatty acids with 8 to 30 carbon atoms and their Na, K, ammonium, Ca, Mg and Zn salts.

The agents according to the invention contain the emulsifiers preferably in amounts of 0.1-25 wt .-%, in particular 0.5-15 Wt .-%, based on the total agent.

One The third object of the invention is a method for increasing the volume of keratinous fibers, especially human hair, in which an inventive agent on the hair is applied and optionally after an exposure time of 30 seconds to 2 hours, preferably not at all, rinsed out again becomes.

The The following examples are intended to explain the invention in more detail, without restricting it to it.

The listed quantities in the examples relate, Unless indicated otherwise, by weight.

Examples:

1) Rinse-off formulations

Care shampoo 1 2 3 4 Texapon ® ¹ K 14 S 50.0 50.0 50.0 50.0 Dehyton ^®2 K 10.0 10.0 10.0 10.0 Plantacare® ^®3 818 UP 4.0 4.0 4.0 4.0 ^Biovert®4 substrate 1 2 1 0.5 ^Biovert®5 enzymes 0.05 0.1 0.05 0,025 Hydrolized Keratin 0.5 1.0 D-panthenol 0.5 0.5 nicotinamide 0.3 ^Gluadin®6 WQ 1.5 ^Arlypon®7 F 1.2 1.2 1.2 1.2 sodium chloride 1.3 1.3 1.3 1.3 preservation qs qs qs qs water ad 100 ad 100 ad 100 ad 100 Hair Conditioner 1 2 3 4 ^Dehyquart®8 F75 5.0 5.0 5.0 5.0 Dimethicone 200/50 1 1 1 1 ^Crodamol®9 ML 2.0 2.0 2.0 2.0 Isopropyl myristate 2.0 2.0 2.0 2.0 Paraffin oil perliquidum 15 cSt DAB 9 1.5 1.5 1.5 1.5 Dehyquart® ^®10 A CA 5.0 5.0 5.0 5.0 Salcare SC 96 ^®11 1.2 1.2 1.2 1.2 ^Biovert®4 substrate 1 2 1 0.5 ^Biovert®5 enzymes 0.05 0.1 0.05 0,025 Hydrolized Keratin 0.5 1.0 D-panthenol 0.5 0.5 nicotinamide 0.3 ^Gluadin®6 WQ 1.5 preservation qs qs qs qs water ad 100 ad 100 ad 100 ad 100

2) Leave-on formulations

Hair cure leave-on 1 2 3 4 Dow ^Corning®12 49 7 7 7 7 Ethanol denatures 10 10 10 10 glycerin 0.5 0.5 0.5 0.5 Carbopol® ¹³ 980 0.5 0.5 0.5 0.5 Sodium hydroxide (w = 33%) qs qs qs qs ^Biovert®4 substrate 1 2 1 0.5 ^Biovert®5 enzymes 0.05 0.1 0.05 0,025 Hydrolized Kerstin 0.5 1.0 D-panthenol 0.5 0.5 nicotinamide 0.3 ^Gluadin®6 WQ 1.5 preservation qs qs qs qs water ad 100 ad 100 ad 100 ad 100 Hair cure leave-on (2-phase) Phase 1 1 2 3 4 Dow ^Corning®14 939 1 1 1 1 Ethanol denatures 10 10 10 10 glycerin 0.5 0.5 0.5 0.5 Carbopol® ¹³ 980 0.3 0.3 0.3 0.3 Sodium hydroxide (w = 33%) qs qs qs qs ^Biovert®4 substrate 1 2 1 0.5 Hydrolized Kerstin 0.5 1.0 D-panthenol 0.5 0.5 nicotinamide 0.3 ^Gluadin®6 WQ 1.5 preservation qs qs qs qs water ad 100 ad 100 ad 100 ad 100 Phase 2 1 2 3 4 Carbopol® ¹³ 980 0.2 0.2 0.2 0.2 sodium hydroxide qs qs qs qs Nettle extract 0.5 0.5 1 0.2 ^Biovert®5 enzymes 0.05 0.1 0.05 0,025

List of raw materials used:

• ^®1 INCI name: Sodium Myreth Sulfate; Active ingredient: 70%; Cognis
• ^®2 INCI name: Cocamidopropylbetaine; Active substance: about 30%; Cognis
• ^®3 C8-C18 alkyl ^{polyglucosides} ; INCI name: Coco glucosides; approx. 50%; Cognis
• ^®4 INCI name: D-glucose; Arch Chemicals
• ^®5 INCI name: Lactoperoxidase & Glucose Oxidase; Arch Chemicals
• ^®6 INCI name: Aqua, Lauridimonium Hydroxypropyl Hydrolyzed Wheat Protein; Methylparaben, ethylparaben; Cognis
• ^®7 C12-C14 fatty alcohols, ethoxylated (2.5 EO); INCI name: Laureth-2; Cognis
• ^®8 INCI name: Distearoylethyl Hydroxyethylmonium Methosulfate, Cetearyl Alcohol; Active ingredient (cationic surfactant): 65-72%; Cognis
• ^®9 INCI name: ^{Myristyl lactate} ; Croda
• ^®11 INCI name: Polyquaternium-37; Active ingredient: 50%; Ciba
• ^®12 INCI name: Aminodimethicone, Cetrimonium Chloride, Trideceth-12; Dow Corning
• ^®13 INCI name: Carbomer; Lubrizol
• ^®14 INCI name: Amodimethicone, Cetrimonium Chloride, Trideceth-12; Dow Corning

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• - DE 4440625 A1 [0030]
• DE 19503465 A1 [0030]
• - DE 3929973 A [0046]
• - EP 0612759 B1 [0047]
• WO 92/13829 A1 [0060]
• DE 19522569 [0074]
• - DE 3723354 A [0103]
• - DE 3926344 A [0103]
• - DE 19736906 [0103]
• DE 19756454 [0139]

Cited non-patent literature

• - "Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pp. 204-308, John Wiley & Sons, Inc. 1989 [0165]
• - "Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pp. 204-308 , John Wiley & Sons, Inc. 1989 [0176]
• - "Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pp. 204-308, John Wiley & Sons, Inc. 1989 [0183]

Claims (14)

Cosmetic use of an enzymatic combination of active substances, consisting of iv. an oxidase, v. a substrate for the oxidase as well vi. a peroxidase to increase volume keratinic fibers, especially human hair. Use according to claim 1, characterized that the drug combination out i. Glucose oxidase, ii. D-glucose as well iii. lactoperoxidase is composed. Use according to one of claims 1 or 2, characterized in that the weight ratio the components i), ii) and iii) in the active ingredient combination (0.1-1) :( 10-50) :( 0.1-1), preferably 0.5: 20: 0.5. Use according to one of claims 1 to 3, characterized in that the active ingredient combination in a Agent for increasing the volume of keratinous fibers - related on the total weight of the agent - in an amount of - 0.01 to 10 wt .-%, preferably 0.1 to 5 wt .-% and in particular 0.5 to 2.0 wt .-%, is included. Agent according to one of claims 1 to 4, characterized in that the component ii) further maximum 1% by weight, based on component ii), of iodide and thiocyanate ions. Use of the enzymatic combination of active ingredients according to any one of claims 1 to 5 in a 2-component agent for increasing the volume of keratinic fibers, characterized that the components i) and iii) physically from the component ii) be present separately and shortly before application to the keratinic fibers are mixed together. Use according to one of claims 1 to 6, characterized in that the enzymatic combination of active ingredients in combination with at least one other, the hair volume increasing active ingredient is used. Use according to claim 7, characterized that the active ingredient is selected to increase hair volume is made of nonionic, cationic, anionic or ampholytic Polymers, terpene-containing plant extracts, proteins and / or Protein derivatives. Means for increasing the volume of keratinic fibers, containing a) an enzymatic combination of active ingredients and b) at least one of a) different, the hair volume increasing Active ingredient. Agent according to claim 9, characterized that it contains the components a) and b) in a ratio of 0.1: 10 to 20: 0.1. Agent according to one of claims 9 or 10, characterized in that the enzymatic combination of active ingredients a. an oxidase, b. a substrate for the oxidase and c. a lactoperoxidase contains, and the active substance b) is selected from nonionic, cationic, anionic or ampholytic polymers, terpene-containing plant extracts, Proteins and / or protein derivatives. Agent according to one of claims 9 to 11, characterized in that the active ingredient b) water lily extract, nettle extract or an animal or vegetable protein hydrolyzate. Agent according to one of claims 9 to 12, characterized in that it is used as a shampoo, hair conditioner, Hair Conditioner, Hair Conditioner, Hair Gel, Hairspray, Hair Tonic and / or Mousse is made up. Method for increasing the volume keratinhaltiger Fibers, in particular human hair, characterized a means according to any one of claims 9 to 13 to the Hair is applied and, if necessary, after an exposure time from 30 seconds to 2 hours, preferably not at all, rinsed out again becomes.