DE102006033993A1 - Synergistic insecticidal mixtures - Google Patents

Abstract

The present invention relates to mixtures of neonicotinoids with cadusafos and the use of these mixtures for controlling animal pests.

Description

The The present invention relates to novel drug combinations which as active ingredients Cadusafos and another active ingredient from the series containing neonicotinoids and very good insecticidal properties have.

als Insektizid und Nematizid zur Bekämpfung von tierischen Schädlingen, insbesondere von Insekten eingesetzt werden kann. Weiterhin ist bekannt, dass sich Neonicotinoide wie z.B. Imidacloprid, Thiacloprid, Clothianidin, Acetamiprid, Nitenpyram, Imidaclothiz und Dinotefuran zur Bekämpfung von tierischen Schädlingen, insbesondere Insekten eignen. Eine Mischung enthaltend Thiamethoxam und Cadusafos ist bereits bekannt geworden ( WO 97/040692 ).It is already known that Cadusafos the formula

can be used as an insecticide and nematicide for the control of animal pests, in particular of insects. Furthermore, it is known that neonicotinoids such as imidacloprid, thiacloprid, clothianidin, acetamiprid, nitenpyram, imidaclothiz and dinotefuran are suitable for controlling animal pests, in particular insects. A mixture containing thiamethoxam and cadusafos has already become known ( WO 97/040692 ).

The Effectiveness of each compound is good, but it is equivalent at low application rates or against individual pests in some cases not the high demands made on insecticides.

It has now been found that mixtures comprising Cadusafos and at least a compound from the series of the following neonicotinoids are synergistically effective and are suitable for controlling animal pests. Because of this synergism can significantly lower levels of drug are used, i. the effect the mix is bigger than the effect of the individual components.

und ist bekannt aus EP A2 0 376 279 .Clothianidin has the formula

and is known from EP A2 0 376 279 ,

und ist bekannt aus der EP A2 0 235 725 .Thiacloprid has the formula

and is known from the EP A2 0 235 725 ,

und ist bekannt aus EP A1 0 649 845 .Dinotefuran has the formula

and is known from EP A1 0 649 845 ,

und ist bekannt aus WO A1 91/04965 .Acetamiprid has the formula

and is known from WO A1 91/04965 ,

und ist bekannt aus EP A2 0 302 389 .Nitenpyram has the formula

and is known from EP A2 0 302 389 ,

und ist bekannt aus EP A1 0 192 060 .Imidacloprid has the formula

and is known from EP A1 0 192 060 ,

und ist bekannt aus „Modem Agrochemicals", Vol. 4, No. 3, June 2005 Imidaclothiz has the formula

and is known from "Modem Agrochemicals", Vol. 4, No. 3, June 2005

Cadusafos has the formula shown at the beginning and is known from "The Pesticide Manual", 13th Edition, 2003, published by the British Crop Protection Council, page 129 ,

The ratio of the active ingredients used to each other, as well as the total amount of the mixture to be applied depends on the nature and the occurrence of the insects. The optimal ratios and total amounts can be determined in each application by test series.

A particularly preferred mixture according to the invention comprises the active ingredients Cadusafos and Imidacloprid. In these mixtures, the weight ratio of respective active substances to each other between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50 and more preferably between 25 to 1 and 1 to 5, here as in the following Cadusafos in the conditions is named first.

A Another particularly preferred mixture according to the invention comprises the active substances Cadusafos and acetamipride. In the mixture, the weight ratio of both Active ingredients between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50, and more preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention comprises the active substances Cadusafos and Nitenpyram. In the mixture, the weight ratio of both Active ingredients between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50, and more preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention comprises the active substances Cadusafos and Dinotefuran. In the mixture, the weight ratio of both Active ingredients between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50, and more preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention comprises the active substances Cadusafos and Thiacloprid. In the mixture, the weight ratio of both Active ingredients between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50, and more preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention comprises the active substances Cadusafos and Imidaclothiz. In the mixture, the weight ratio of both Active ingredients between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50, and more preferably between 25 to 1 and 1 to 5.

A particularly preferred mixture according to the invention comprises the active ingredients Cadusafos and Clothianidin. In the mixture, the weight ratio of both Active ingredients to each other between 1000 to 1 and 1 to 125, preferably between 125 to 1 and 1 to 50, and more preferably between 25 to 1 and 1 to 5, wherein, as above, Cadusafos in the proportions is named first.

Preferably contain the above-mentioned preferred mixtures no another insecticidally active ingredient.

The Active ingredient combinations are suitable for good plant tolerance and cheaper Warmblood toxicity to combat animal pests, especially insects, arachnids and nematodes used in agriculture, in forestry, in storage and material protection as well as in the hygiene sector occurrence. You can preferably as a plant protection product in foliar and soil treatment be used.

They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:
From the order of the Isopoda eg Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of Diplopoda eg Blaniulus guttulatus. From the order of Chilopoda eg Geophilus carpophagus, Scutigera spp. From the order of Symphyla eg Scutigerella immaculata. From the order of Thysanura eg Lepisma saccharina. From the order of the Collembola eg Onychiurus armatus. From the order of the Orthoptera eg Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria. From the order Blattaria orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica. From the order of the Dermaptera eg Forficula auricularia. From the order of the Isoptera eg Reticulitermes spp. From the order of Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp. From the order of Thysanoptera eg Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis. From the order of Heteroptera eg Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp. From the order of Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp. Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta Padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp. Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana Cnaphalocerus spp., Oulema oryzae. From the order Coleoptera eg Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp. , Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus. From the order of Hymenoptera eg Diprion spp., Hoplocampa spp., Lasius spp., Monomonium pharaonis, Vespa spp. From the order of Diptera eg Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp , Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp .. From the order of Siphonaptera eg Xenopsylla cheopis, Ceratophyllus spp .. From the class of Arachnida eg Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp. , Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp ..

To the plant parasite Nematodes belong e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne Spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

The Active ingredient combinations are particularly suitable for controlling Nematodes and insects.

According to the invention, all Plants and parts of plants are treated. Being under plants understood here all plants and plant populations, as desired and undesirable Wild plants or crops (including naturally occurring crops). Crops can Be plants by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or Combinations of these methods can be obtained, including transgenic plants and including those estimable by plant variety rights or unpredictable Plant varieties. Under plant parts are all above ground and underground Parts and organs of plants, such as shoot, leaf, flower and root By way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and Seeds as well as roots, tubers and rhizomes. To the plant parts belongs also harvested material as well as vegetative and generative propagation material, For example, cuttings, tubers, rhizomes, offshoots and seeds.

highlighted In this case, be the particularly advantageous effect of the agents according to the invention for use in cereal plants, e.g. Wheat, oats, barley, Spelled, triticale and rye, but also in corn, millet, rice, sugar cane, Soy, sunflower, potatoes, cotton, canola, canola, tobacco, sugar beets, Fodder beet, Asparagus, hops and fruit plants (comprising pome fruit such as e.g. Apple and pears, stone fruit such as Peaches, nectarines, cherries, Plums and apricots, citrus fruits such as. Oranges, grapefruit, limes, lemons, kumquats, mandarins and satsumas, nuts such as. Pistachios, almonds, walnuts and pecans, tropical fruit such as. Mango, papaya, pineapple, dates and bananas, and grapes) and vegetables (comprising leafy vegetables, such as. Endives, corn salad, tubers, head and pickles, Swiss chard, spinach and chicory salad, cabbage vegetables, e.g. Cauliflower, broccoli, Chinese cabbage, kale (Winter or Krauskohl), Kohlrabi, Brussels sprouts, red cabbage, cabbage and Savoy cabbage, fruit vegetables such as. Eggplants, cucumbers, peppers, squash, tomatoes, zucchini and Sweetcorn, root vegetables such as. Celeriac, mayonnaise, carrots, Yellow beets, Radishes, radish, beets, salsify and celery, legumes like e.g. Peas and beans and onion vegetables such as Leeks and onions). The combinations according to the invention are particularly suitable for the treatment of corn seed and Sunflowers.

The treatment according to the invention of the plants and plant parts with the active substance combinations is carried out directly or by acting on their environment, habitat or storage space the usual treatment methods, for example by dipping, spraying, vaporizing, atomizing, spreading, brushing and in propagating material, especially in seeds, further by single or multi-layer wrapping.

Especially the mixtures according to the invention are suitable in particular, the combination of the active ingredients imidacloprid and Cadusafos as well as Clothianidin and Cadusafos, for the treatment of seeds. This creates a big one Part of by pests caused damage to crops already by the infestation of seed during storage and after placing the seed in the soil as well while and immediately after the germination of the plants. This phase is especially critical as the roots and shoots of the growing plant are particularly sensitive are and already a small damage to the death of the whole plant to lead can. There is therefore a particular interest in the seed and the germinating plant by the use of suitable means protect.

The fight of pests By treating the seed of plants has long been known and is subject to more permanent Improvements. Nevertheless, in the treatment of seed emerge a series of problems that are not always solved satisfactorily can. So It is desirable to have procedures for the protection of the seed and the to develop germinating plant, which is the additional application of pesticides make it redundant after sowing or after emergence of the plants. It is also desirable, the amount of the active ingredient used to optimize that the seed and the germinating plant best protected against infestation by pests, but without the plant itself by the active ingredient used to harm. In particular, seed treatment methods should also include intrinsic insecticidal properties of transgenic plants, for optimal protection of the seed and the germinating plant to achieve a minimum of pesticides.

The The present invention therefore more particularly relates to Process for the protection of seeds and for the protection of plants, in particular of germinating plants, from the infestation of pests, adding the seed with an agent according to the invention is treated. The invention also relates to the use the agents according to the invention for the treatment of seed for the protection of the seed and the resulting resulting plants from pests. Furthermore, the invention relates to seed, which for protection against pests treated with an agent according to the invention has been.

one the advantages of the present invention is that due to the particular systemic properties of the agents according to the invention the treatment of the seed with these means not only the seed itself, but also the resulting plants after the Emerge from pests protects. In this way, the immediate treatment of the culture for Time of sowing or shortly thereafter omitted.

One Another advantage is the synergistic increase of insecticidal activity of the agents according to the invention over the respective single active substance, over the sum of the efficacy of the two individually applied agents goes. This will optimize the amount of used Drug allows.

As well it is to be regarded as advantageous that the mixtures according to the invention especially in transgenic seed can be used, wherein the resulting from this seed plants for the expression of a against pests targeted protein are. By treating such seeds with the agents according to the invention can certain pests already by the expression of e.g. insecticidal protein and, surprisingly, in addition to a synergistic effect supplement with the inventive compositions comes, what the effectiveness protection against pest infestation once again improved.

The agents according to the invention are suitable for the protection of seed of any plant variety as already referred to above, in agriculture, in the greenhouse, used in forestry or horticulture. In particular, acts seeds of maize, peanut, canola, rape, poppy, Soy, cotton, turnip (for example, sugar beet and fodder beet), Rice, millet, wheat, barley, oats, rye, sunflower or tobacco. The agents according to the invention are also suitable for the treatment of seeds of fruit plants and vegetables as already mentioned above. Of particular importance is the treatment of corn, soya, cotton, wheat, sugar beet, vegetables and canola or seeds Rapeseed too. Thus, for example, the mixture according to the invention comprising the Active ingredients Cadusafos and Imidacloprid or Clothianidin and Cadusafos in particular for the treatment of the seed of maize, of the seed of cotton and beets.

As already mentioned above, the treatment of transgenic seed with an agent according to the invention is of particular importance. These are the seeds of plants which usually contain at least one heterologous gene which is the expression of a polypeptide having in particular insecticidal properties controls. The heterologous genes in transgenic seed can come from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. The present invention is particularly useful for the treatment of transgenic seed containing at least one heterologous gene derived from Bacillus sp. and whose gene product shows activity against corn borer and / or corn rootworm. Most preferably, this is a heterologous gene derived from Bacillus thuringiensis. Again, the combination of the invention are particularly suitable for the seed of corn.

in the Within the scope of the present invention is the agent according to the invention applied alone or in a suitable formulation on the seed. Preferably, the seed is treated in a state in which so stable is that no damage occur during treatment. In general, the treatment can of the seed at any time between harvesting and sowing respectively. Usually seed separated from the plant and used by flasks, Shells, stalks, shell Wool or pulp was freed.

in the In general, care must be taken when treating the seed be that the amount of applied to the seed agent of the invention and / or other additives is chosen so that germination of the seed or the resulting plant is not damaged. This is especially important in the case of active ingredients, which are certain Application rates can show phytotoxic effects.

The agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to the person skilled in the art and are described, for example, in the following documents: US 4,272,417 A . US 4,245,432 A . US 4,808,430 A . US 5,876,739 A . US 2003/0176428 A1 . WO 2002/080675 A1 . WO 2002/028186 A2 ,

The Drug combinations can in the usual Formulations are transferred, like solutions, Emulsions, wettable powders, suspensions, powders, dusts, Pastes, soluble Powders, granules, suspension-emulsion concentrates, drug-impregnated Natural and synthetic substances as well as ultrafine encapsulations in polymers Substances.

These Formulations are prepared in a known manner, e.g. by Mixing the active ingredients with extenders, ie liquid solvents and / or solid carriers, optionally using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.

in the Traps of using water as diluent may be e.g. also organic solvents as auxiliary solvent be used. As liquid solvent are essentially in question: aromatics, such as xylene, toluene, or Alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic Hydrocarbons, such as chlorobenzenes, chloroethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, Alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, as well as water.

Suitable solid carriers are:
For example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules in question: eg broken and fractionated natural rocks such Calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: for example lignin-sulphite liquors and methylcellulose.

It can in the formulations adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped Polymers such as gum arabic, polyvinyl alcohol, Polyvinyl acetate, as well as natural Phospholipids such as cephalins and lecithins and synthetic phospholipids. Other additives can mineral and vegetable oils be.

It can Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, Ferrocyan blue and organic dyes such as alizarin, azo and Metal phthalocyanine dyes and trace nutrients such as salts of iron, Manganese, boron, copper, cobalt, molybdenum and zinc are used.

The formulations generally include NEN between 0.1 and 95 wt .-% active ingredient, preferably between 0.5 and 90%.

The active compound combinations according to the invention contain preferably in addition Cadusafos and said neonicotinoids no other active ingredients.

The active compound combinations according to the invention can optionally in commercial Formulations and in those prepared from these formulations Forms of use mixed with other active substances such as insecticides, Attractants, sterilants, bactericides, acaricides, nematicides, Fungicides, growth regulators or herbicides. To the insecticides count for example, phosphoric acid esters, Carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, by microorganisms Fabrics u.a.

Especially favorable Mixing partners are e.g. the following:

fungicides:

• Aldimorph, ampropylfos, ampropylfos-potassium, andoprim, anilazine, azaconazole, azoxystrobin, benalaxyl, benodanil, benomyl, benzamacril, benzamacrylisobutyl, bialaphos, binapacryl, biphenyl, bertertanol, blasticidin-S, bromuconazole, bupirimat, buthiobate, calcium polysulfide, capsimycin, Captafol, captan, carbendazim, carboxin, carvone, quinomethionate (quinomethionate), chlobenthiazone, chlorfenazole, chloroneb, chloropicrin, chlorothalonil, chlozolinate, clozylacon, cufraneb, cymoxanil, cyproconazole, cyprodinil, cyprofuram, debacarb, dichlorophen, diclobutrazole, diclofluanide, diclomecine, dicloran , Diethofencarb, Difenoconazole, Dimethirimol, Dimethomorph, Diniconazole, Diniconazole-M, Dinocap, Diphenylamine, Dipyrrithione, Ditalimfos, Dithianone, Dodemorph, Dodine, Drazoxolone, Ediphenphos, Epoxiconazole, Etaconazole, Ethirimol, Etridiazole, Famoxadone, Fenapanil, Fenarimol, Fenbuconazole, Fenfuram , Fenitropan, fenpiclonil, fenpropidin, fenpropimorph, fentin acetate, fentin hydroxide, ferbam, ferimzone, fluazina m, Flumetover, Fluoromide, Fluquinconazole, Flurprimidol, Flusilazole, Flusulfamide, Flutolanil, Flutriafol, Follow, Fosetyl-Alminium, Fosetyl-Sodium, Fthalide, Fuberidazole, Furalaxyl, Furametpyr, Furcarbonil, Furconazole, Furconazole-cis, Furmecyclox, Guazatine, Hexachlorobenzene, Hexaconazole, hymexazole, imazalil, imibenconazole, iminoctadine, iminoctadinealbesilate, iminoctadine triacetate, iodocarb, ipconazole, ipprobenfos (IBP), iprodione, irumamycin, isoprothiolane, isovaledione, kasugamycin, kresoxim-methyl, copper preparations such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulphate , Copper oxide, oxine-copper and Bordeaux mixture, mancopper, mancozeb, maneb, meferimzone, mepanipyrim, mepronil, metalaxyl, metconazole, methasulfocarb, methfuroxam, metiram, metomeclam, metsulfovax, mildiomycin, myclobutanil, myclozoline, nickel dimethyldithiocarbamate, nitrothal isopropyl , Nuarimol, Ofurace, Oxadixyl, Oxamocarb, Oxolinicacid, Oxycarboxime, Oxyfenthiin, Paclobutrazole, Pefurazoate, Penconaz ol, pencycuron, phosphodiphene, pimaricin, piperaline, polyoxin, polyoxorim, probenazole, prochloraz, procymidone, propamocarb, propanosine sodium, propiconazole, propynol, pyrazophos, pyrifenox, pyrimethanil, pyroquilon, pyroxyfur, quinconazole, quintozene (PCNB), sulfur and sulfur Preparations, tebuconazole, tecloftalam, tecnazene, tetcyclacis, tetraconazole, thiabendazole, thicyofen, thifluzamide, thiophanate-methyl, thiram, tioxymide, tolclofos-methyl, tolylfluanid, triadimefon, triadimol, triazobutyl, triazoxide, trichlamide, tricyclazole, tridemorph, triflumizole, triforin , Triticonazole, uniconazole, validamycin A, vinclozolin, viniconazole, zarilamide, zineb, ziram, and Dagger G, OK-8705, OK-8801, α- (1,1-dimethylethyl) -β- (2-phenoxyethyl) -1H- 1,2,4-triazole-1-ethanol, α- (2,4-dichlorophenyl) -β-fluoro-β-propyl-1H-1,2,4-triazole-1-ethanol, α- (2,4 Dichlorophenyl) -β-methoxy-α-methyl-1H-1,2,4-triazole-1-ethanol, α- (5-methyl-1,3-dioxan-5-yl) -β - [4- (trifluoromethyl) phenyl] methylene] -1H-1,2,4-triazo 1-1-ethanol, (5RS, 6RS) -6-hydroxy-2,2,7,7-tetramethyl-5- (1H-1,2,4-triazol-1-yl) -3-octanone, (E. ) -α- (methoxyimino) -N-methyl-2-phenoxy-phenylacetamide, {2-methyl-1 - [[[1- (4-methylphenyl) ethyl] amino] carbonyl] propyl} -carbamic acid-1 isopropyl ester 1- (2,4-dichlorophenyl) -2- (1H-1,2,4-triazol-1-yl) ethanone O- (phenylmethyl) oxime, 1- (2-methyl-1-naphthalenyl ) -1H-pyrrole-2,5-dione, 1- (3,5-dichlorophenyl) -3- (2-propenyl) -2,5-pyrrolidinedione, 1 - [(diiodomethyl) sulfonyl] -4-methylbenzene, 1 - [[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] -methyl] -1H-imidazole, 1 - [[2- (4-chlorophenyl) -3-phenyloxiranyl] -methyl ] -1H-1,2,4-triazole, 1- [1- [2 - [(2,4-dichlorophenyl) methoxy] -phenyl] -ethenyl] -1H-imidazole, 1-methyl-5-nonyl-2 - (phenylmethyl) -3-pyrrolidinol, 2 ', 6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoro-methyl-1,3-thiazole-5-carboxanilide, 2,2-dichloro-N [1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide, 2,6-dichloro-5- (methylthio) -4-pyrimidinyl thiocyanate, 2,6-dichloro-N- ( 4-trifluoromethylbenzyl) benzamide, 2,6-dichloro rN - [[4- (trifluoromethyl) phenyl] methyl] benzamide, 2- (2,3,3-triiodo-2-propenyl) -2H-tetrazole, 2 - [(1-methylethyl) sulfonyl] -5- (trichloromethyl) -1,3,4-thiadiazole, 2 - [[6-deoxy-4-O- (4-omethyl-β-D-glycopyranosyl) -α-D-glucopyranosyl] amino] -4-methoxy 1H-pyrrolo [2,3-d] pyrimidine-5-carbonitrile, 2-aminobutane, 2-bromo-2- (bromomethyl) -pentendinitrile, 2-chloro-N- (2,3-dihydro-1,1,3 trimethyl-1H-inden-4-yl) -3-pyridinecarboxamide, 2-chloro-N- (2,6-dimethylphenyl) -N- (isothiocyanatomethyl) acetamide, 2-phenylphenol (OPP), 3,4-dichloro 1- [4- (difluoromethoxy) -phenyl] -1H-pyrrole-2,5-dione, 3,5-dichloro-N- [cy [(1-methyl-2-propynyl) oxy] methyl] benzamide, 3- (1,1-dimethylpropyl-1-oxo) -1H-indene-2-carbonitrile, 3- [2- (4- Chlorophenyl) -5-ethoxy-3-isoxazolidinyl] pyridine, 4-chloro-2-cyano-N, N-dimethyl-5- (4-methylphenyl) -1H-imidazole-1-sulfonamide, 4-methyltetrazolo [1 , 5-a] quinazolin-5 (4H) -one, 8- (1,1-dimethylethyl) -N-ethyl-N-propyl-1,4-dioxaspiro [4.5] decane-2-methanamine, 8-hydroxyquinoline sulfate, 9H-Xanthene-9-carboxylic acid 2 - [(phenylamino) carbonyl] hydrazide, bis (1-methylethyl) -3-methyl-4 - [(3-methylbenzoyl) oxy] -2,5-thiophenedicarboxylate, cis-1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) -cycloheptanol, cis-4- [3- [4- (1,1-dimethylpropyl) -phenyl-2 -methylpropyl] -2,6-dimethylmorpholine hydrochloride, ethyl - [(4-chlorophenyl) -azo] cyanoacetate, potassium hydrogencarbonate, methanetetrathiol sodium salt, methyl 1- (2,3-dihydro-2,2-dimethyl-1H-indene -1-yl) -1H-imidazole-5-carboxylate, methyl N- (2,6-dimethylphenyl) -N- (5-isoxazolylcarbonyl) -DL-alaninate, methyl-N- (chloroacetyl) -N- (2 , 6-dimethylphenyl) -DL-alaninate, N- (2,3-dichloro-4-hydroxyp henyl) -1-methylcyclohexanecarboxamide, N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-furanyl) -acetamide, N- (2,6-dimethylphenyl) -2-methoxy N- (tetrahydro-2-oxo-3-thienyl) -acetamide, N- (2-chloro-4-nitrophenyl) -4-methyl-3-nitro-benzenesulfonamide, N- (4-cyclohexylphenyl) -1,4 , 5,6-tetrahydro-2-pyrimidinamine, N- (4-hexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidineamine, N- (5-chloro-2-methylphenyl) -2-methoxy-N - (2-oxo-3-oxazolidinyl) -acetamide, N- (6-methoxy) -3-pyridinyl) -cyclopropanecarboxamide, N- [2,2,2-trichloro-1 - [(chloroacetyl) -amino] -ethyl ] benzamide, N- [3-chloro-4,5-bis (2-propynyloxy) -phenyl] -N'-methoxymethanimidamide, N-formyl-N-hydroxy-DL-alanine sodium salt, O, O-diethyl [ 2- (dipropylamino) -2-oxoethyl] -ethylphosphoramidothioate, O-methyl-S-phenyl-phenylpropylphosphoramidothioate, S-methyl-1,2,3-benzothiadiazole-7-carbothioate, spiro [2H] -1-benzopyran-2, 1 '(3'H) -isobenzofuran] -3'-one.

bactericides:

• Bronopol, dichlorophen, nitrapyrin, nickel dimethyldithiocarbamate, Kasugamycin, octhilinone, furancarboxylic acid, oxytetracycline, probenazole, Streptomycin, tecloftalam, copper sulphate and other copper preparations.

Insecticides / acaricides / nematicides:

• Abamectin, Acephate, Acetamiprid, Acrinathrin, Alanycarb, Aldicarb, Aldoxycarb, Alpha-Cypermethrin, Alphamethrin, Amitraz, Avermectin, AZ 60541, Azadirachtin, Azamethiphos, Azinphos A, Azinphos M, Azocyclotin, Bacillus popilliae, Bacillus sphaericus, Bacillus subtilis, Bacillus thuringiensis , Baculoviruses, Beauveria bassiana, Beauveria tenella, Bendiocarb, Benfuracarb, Bensultap, Benzoximate, Betacyfluthrin, Bifenazates, Bifenthrin, Bioethanomethrin, Biopermethrin, BPMC, Bromophos A, Bufencarb, Buprofezin, Butathiofos, Butocarboxim, Butylpyridaben, Cadusafos, Carbaryl, Carbofuran, Carbophenothion, Carbosulfan, Cartap, Chloethocarb, Chlorethoxyfos, Chlorfenapyr, Chlorfenvinphos, Chlorfluazuron, Chlormephos, Chlorpyrifos, Chlorpyrifos M, Chlovaporthrin, Cis-Resmethrin, Cispermethrin, Clocythrin, Cloethocarb, Clofentezine, Clothianidin, Cyanophos, Cycloprene, Cycloprothrin, Cyfluthrin, Cyhalothrin, Cyhexatin, Cypermethrin , Cyromazine, deltamethrin, Demeton M, Demeton S, Demeton S-methyl, Di afenthiuron, diazinon, dichlorvos, diflubenzuron, dimethoate, dimethylvinphos, diofenolan, disulfonate, docusate-sodium, dofenapine, eflusilanate, emamectin, empenthrin, endosulfan, entomophthora spp., esfenvalerate, ethiofencarb, ethiprole, ethion, ethoprophos, etofenprox, etoxazole, etrimfos, Fenamiphos, fenazaquin, fenbutatin oxide, fenitrothion, fenothiocarb, fenoxacrim, fenoxycarb, fenpropathrin, fenpyrad, fenpyrithrin, fenpyroximate, fenvalerate, fipronil, fluazinam, fluazuron, flubrocythrinates, flucycloxuron, flucythrinate, flufenoxuron, flotenzine, fluvalinate, fonophos, fosmethilane, fosthiazate, fubfenprox , Furathiocarb, Granuloseviruses, Halofenozide, HCH, Heptenophos, Hexaflumuron, Hexythiazox, Hydroprene, Imidacloprid, Indoxacarb, Isazofos, Isofenphos, Isoxathion, Ivermectin, Kernpolyederviren, Lambda-cyhalothrin, Lufenuron, Malathion, Mecarbam, Metaldehyde, Methamidophos, Metarhizium anisopliae, Metarhizium flavoviride , Methidathion, Cadusafos, Methomyl, Methoxyfenozide, Metolcar b, Metoxadiazone, Mevinphos, Milbemectin, Monocrotophos, Naled, Nitenpyram, Nithiazines, Novaluron, Omethoat, Oxamyl, Oxydemethon M, Paecilomyces fumosoroseus, Parathion A, Parathion M, Permethrin, Phenthoate, Phorat, Phosalone, Phosmet, Phosphamidone, Phoxim, Pirimicarb, Pirimiphos A, Pirimiphos M, Profenofos, Promecarb, Propargite, Propoxur, Prothiofos, Prothoate, Pymetrozine, Pyraclofos, Pyresmethrin, Pyrethrum, Pyridaben, Pyridathion, Pyrimidifen, Pyriproxyfen, Quinalphos, Ribavirin, Salithion, Sebufos, Silafluofen, Spinosad, Spirodiclofen, Spiromesifen, Sulfotep, Sulprofos, Taufluvalinate, Tebufenozide, Tebufenpyrad, Tebupirimiphos, Teflubenzuron, Tefluthrin, Temephos, Temivinphos, Terbufos, Tetrachlorvinphos, Theta-cypermethrin, Thiacloprid, Thiamethoxam, Thiapronil, Thiatriphos, Thiocyclam hydrogen oxalate, Thiodicarb, Thiofanox, Thuringiensin, Tralocythrin, Tralomethrin, triarathene, triazamate, cadusafos, triazuron, trichlorophenidine, trichlorofon, triflumuron, trimethacarb, vamido thion, vaniliprole, verticillium lecanii, YI 5302, zeta-cypermethrin, zolaprofos, and (1R-cis) - [5- (phenylmethyl) -3-furanyl] methyl-3 - [(dihydro-2-oxo-3 (2H ) -furanylidene) -methyl] -2,2-dimethylcyclopropanecarboxylate, (3-phenoxyphenyl) -methyl-2,2,3,3-tetramethylcyclopropanecarboxylate, 1 - [(2-chloro-5-thiazolyl) methyl] tetrahydro-3, 5-dimethyl-N-nitro-1,3,5-triazine-2 (1H) -imin, 2- (2-chloro-6-fluorophenyl) -4- [4- (1,1-dimethyls ethyl) phenyl] -4,5-dihydrooxazole, 2- (acetoxy) -3-dodecyl-1,4-naphthalenedione, 2-chloro-N - [[[4- (1-phenylethoxy) -phenyl] -amino ] -carbonyl] -benzamide, 2-chloro-N - [[[4- (2,2-dichloro-1,1-difluoroethoxy) -phenyl] -amino] -carbonyl] -benzamide, 3-methylphenyl-propylcarbamate, 4 - [4- (4-ethoxyphenyl) -4-methylpentyl] -1-fluoro-2-phenoxybenzene, 4-chloro-2- (1,1-dimethylethyl) -5 - [[2- (2,6- dimethyl-4-phenoxyphenoxy) ethyl] thio] -3 (2H) -pyridazinone, 4-chloro-2- (2-chloro-2-methylpropyl) -5 - [(6-iodo-3-pyridinyl) methoxy] -3 (2H) -pyridazinone, 4-chloro-5 - [(6-chloro-3-pyridinyl) methoxy] -2- (3,4-dichlorophenyl) -3 (2H) -pyridazinone, Bacillus thuringiensis strain EG-2348, benzoic acid [2-benzoyl-1- (1,1-dimethylethyl) -hydrazide, butanoic acid 2,2-dimethyl-3- (2,4-dichlorophenyl) -2-oxo-1-oxaspiro [4.5] dec-3-ene 4-yl ester, [3 - [(6-chloro-3-pyridinyl) methyl] -2-thiazolidinylidene] -cyanamide, dihydro-2- (nitromethylene) -2H-1,3-thiazine-3 (4H) - carboxaldehyde, ethyl [2 - [[1,6-dihydro-6-oxo-1- (phenylmethyl) -4-pyridazinyl] oxy] ethyl] carbamate, N- (3,4,4-trifluoro-1-oxo o-3-butenyl) glycine, N- (4-chlorophenyl) -3- [4- (difluoromethoxy) phenyl] -4,5-dihydro-4-phenyl-1H-pyrazole-1-carboxamide, N-methyl- N '- (1-methyl-2-propenyl) -1,2-hydrazinedicarbothioamide, N -methyl-N'-2-propenyl-1,2-hydrazinedicarbothioamide, O, O -diethyl- [2- (dipropylamino) -2 -oxoethyl] -ethylphosphoramidothioat.

Also a mixture with other known active substances, such as herbicides or with fertilizers and Growth regulators is possible.

The active compound combinations according to the invention can also when used as insecticides in their commercial Formulations and in those prepared from these formulations Application forms in mixture with synergists are present. synergists are compounds that increase the effect of the active ingredients without the added synergist itself being active got to.

Of the Active substance content prepared from the commercial formulations Application forms can vary widely. The drug concentration the application forms may range from 0.0000001 up to 95% by weight of active ingredient, preferably between 0.0001 and 1 wt .-%.

The Application is done in a custom forms adapted to the applications Wise.

at The application against hygiene and storage pests are characterized by the drug combinations by an excellent residual effect on wood and clay as well by a good alkali stability on limed Documents out.

The active compound combinations according to the invention not only work against plant, hygiene and storage pests, but also on the veterinary Sector against animal parasites (ectoparasites) like ticks, Leather ticks, mange mites, Walking mites, flies (stinging and licking), parasitic fly larvae, Lice, Hair pieces, featherlings and fleas.

The active compound combinations according to the invention are also suitable for fighting of arthropods, farm animals, e.g. Bovine, Sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, Chicken, Turkeys, ducks, geese, bees, other pets such as Dogs, cats, caged birds, aquarium fish and so-called experimental animals, e.g. Hamsters, guinea pigs, rats and mice affected. By fighting this Arthropods are said to be deaths and reductions (in the case of meat, milk, wool, skins, eggs, Honey, etc.) are reduced, so that through the use of the active compound combinations according to the invention a more economical and easier animal husbandry is possible.

The Application of the active compound combinations according to the invention happens in the veterinary sector in known manner by enteral administration in the form of, for example Tablets, capsules, potions, Drenchen, granules, pastes, boluses, the feed-through process, of suppositories, by parenteral administration, such as by injections (Intramuscular, subcutaneously, intravenously, intraperitoneal, etc.), implants, by nasal application dermal application in the form of, for example, diving or bathing (Dipping), spraying (spray), brew (Pour-on and spot-on), washing, powdering and with the aid of active ingredient Moldings, like collars, Ear tags, tail tags, limb bands, halters, marking devices etc.

at the application for Livestock, poultry, Pets etc. can be the active ingredients as formulations (for example Powders, emulsions, flowable agents), containing the active ingredients in an amount of 1 to 80 wt .-%, apply directly or after 100 to 10 000 dilution or as use chemical bath.

It was also found that the drug combinations of the invention show a high insecticidal activity against insects, the technical Destroy materials.

Under technical materials are non-living in the present context Materials, such as preferably plastics, adhesives, Glues, papers and cartons, leather, wood, woodworking products and paints.

It is very particularly preferable in the case of material to be protected from insect infestation, wood and woodworking products.

By wood and woodworking products, which can be protected by the composition according to the invention or mixtures containing it, is to be understood by way of example:
Timber, wooden beams, railway sleepers, bridge parts, boat jetties, wooden vehicles, crates, pallets, containers, telephone poles, wooden cladding, wooden windows and doors, plywood, chipboard, carpentry or wood products, which are generally used in home construction or joinery.

The Drug combinations can as such, in the form of concentrates or general Formulations such as powders, granules, solutions, suspensions, emulsions or pastes are applied.

The mentioned formulations in a manner known per se, e.g. by mixing the active ingredients with at least one solvent or diluent, Emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments and other processing aids.

The insecticides used for the protection of wood and wood-based materials Agents or concentrates contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60% by weight.

The Amount of funds used or concentrates is of the type and depending on the occurrence of the insects and on the medium. The Optimal use can be made by using test series be determined. In general, however, it is sufficiently 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the protected Material to use.

When solvent and / or diluent is used an organic-chemical solvent or solvent mixture and / or an oily one or oily heavy volatile organic-chemical solvent or solvent mixture and / or a polar organic-chemical solvent or solvent mixture and / or water and optionally an emulsifier and / or wetting agent.

When organic-chemical solvents are preferably oily or oil-like Solvent with an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C used. As such low-volatility, water-insoluble, oily and oily solvent become appropriate mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably White spirit, petroleum and / or alkylbenzene used.

Advantageous get mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range from 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics from Boiling range of 160 to 280 ° C, turpentine oil and the like. for use.

In a preferred embodiment become liquid aliphatic hydrocarbons having a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and / or locker oil and / or Monochloronaphthalene, preferably α-monochloronaphthalene.

The organic low volatility oily or oily solvent with an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C, can partially by light or medium volatile organic-chemical solvents be replaced, with the proviso that the solvent mixture also an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C, having and that the insecticide-fungicide mixture in this solvent mixture soluble or emulsifiable.

To a preferred embodiment a part of the organic chemical solvent or solvent mixture by an aliphatic polar organic chemical solvent or Solvent mixture replaced. Preferably, hydroxyl and / or ester and / or Ether group-containing aliphatic organic-chemical solvents such as glycol ethers, esters or the like. For use.

When Organic-chemical binders are used in the present Invention the known water-dilutable and / or in the used organic-chemical solvents soluble or dispersible or emulsifiable synthetic resins and / or binders drying oils, in particular binder consisting of or containing an acrylate resin, a vinyl resin, e.g. Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, Phenolic resin, hydrocarbon resin such as indene cumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying Binder based on a natural and / or synthetic resin used.

The resin used as a binder can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In addition, known dyes, pigments, water repellents, odor correctors and inhibitors or corrosion inhibitors and the like can be used.

Prefers is according to the invention as organic-chemical binder at least one alkyd resin or modified alkyd resin and / or a drying vegetable oil on average or in the concentrate. Alkyd resins are preferred according to the invention with an oil content of more than 45% by weight, preferably 50 to 68% by weight.

The mentioned Binder may be wholly or partly by a fixative (mixture) or a plasticizer (mixture) are replaced. These additives should a volatilization prevent the active ingredients and crystallization or precipitation. Preferably replace 0.01 to 30% of the binder (based on 100% of the binder) used binder).

The Plasticizers come from the chemical classes of phthalates such as dibutyl, dioctyl or Benzyl butyl phthalate, phosphoric acid esters such as Tributyl phosphate, adipic acid ester such as di (2-ethylhexyl) adipate, Stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, Glycerol ether or higher molecular weight Glycol ethers, glycerol esters and p-toluenesulfonic acid esters.

fixative are chemically based on polyvinyl alkyl ethers such as e.g. polyvinyl methyl or ketones such as benzophenone, ethylene benzophenone.

When solvent or diluent In particular, water is also suitable, if appropriate as a mixture with one or more of the above organic chemical solvent or diluents, Emulsifiers and dispersants.

One particularly effective wood protection is achieved by large-scale impregnation e.g. Vacuum, double vacuum or printing process achieved.

The ready to use means optionally further insecticides and optionally also contain one or more fungicides.

at the same time can the active compound combinations according to the invention for protection against the growth of objects, in particular hulls, sieves, Nets, structures, wharves and signal systems connected with sea or brackish water are used.

growth by sessile Oligochaeten, like Kalkröhrenwürmer as well as by shells and Species of the group Ledamorpha (barnacles), like different lepas and scalpel species, or by species of the group Balanomorpha (barnacles), like Balanus or Pollicipes species, increases the frictional resistance of Ships and guides increased in consequence by Energy consumption and above Beyond frequent Dry dock stays at a significant increase in operating costs.

Next the vegetation by algae, for example Ectocarpus sp. and ceramium sp., comes in particular from the vegetation by sessile Entomostraken groups, which are summarized under the name cirripedia (cirriped crayfish), special importance.

The active compound combinations according to the invention are also suitable for fighting of animal pests, In particular of insects, arachnids and mites, which in closed spaces, such as For example, apartments, factory buildings, offices, vehicle cabins, etc. occurrence. You can for fighting of these pests alone or in combination with other active ingredients and excipients in household insecticide products be used. They are against sensitive and resistant species as well effective against all stages of development.

The Application in the field of household insecticides may also be combined with other suitable active substances such as phosphoric acid esters, carbamates, pyrethroids, Growth regulators or agents from other known insecticide classes respectively.

The Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, Fog machines, foggers, foams, Gels, evaporator products with evaporator plates made of cellulose or plastic, Liquid evaporators, gel and membrane evaporators, propeller driven evaporators, energyless or passive evaporation systems, moth papers, moth bags and Moth gels as granules or dusts, in straw baits or Bait stations.

At the Use of the active compound combinations according to the invention can the application rates within a larger range, depending on the type of application be varied. In the treatment of plant parts are the Application rates of active ingredient combination generally between 0.1 and 10 000 g / ha, preferably between 10 and 1000 g / ha.

The good insecticidal activity of the active compound combinations according to the invention is evident from the examples below. While the individual active ingredients in the effect of weaknesses aufwei sen, the combinations show an effect that goes beyond a simple sum of effects.

Calculation formula for the kill rate a combination of two active ingredients

The expected effect for a given combination of two drugs can (see. COLBY, SR; "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15 pp. 20-22, 1967 ); be calculated:

X

= den Abtötungsrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m ppm,

Y

= den Abtötungsrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes B in einer Aufwandmenge von n ppm,

E

= den Abtötungsrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A und B in Aufwandmengen von m und n ppm bedeutet,

dann ist

If

X

= the kill rate, expressed in% of the untreated control, when using the active substance A at a rate of m ppm,

Y

= the rate of destruction, expressed as% of the untreated control, when using the active substance B at an application rate of n ppm,

e

= the kill rate, expressed in% of the untreated control, when using the active compound A and B in amounts of m and n ppm,

then

is the actual insecticidal kill rate greater than calculated, the combination is over-additive in its kill, i. it lies synergistic effect. In this case, the actually observed kill rate to be taller as the one from the above Formula calculated value for the expected kill rate (E).

Claims (9)

Agent comprising a synergistically effective mixture of Cadusafos of the formula

and at least one compound selected from imidacloprid, clothianidin, thiacloprid, acetamiprid, nitenpyram, imidaclothiz and dinotefuran. An agent comprising a synergistically effective mixture from Cadusafos and Thiacloprid. An agent comprising a synergistically effective mixture of cadusafos and acetamipride. An agent comprising a synergistically effective mixture from Cadusafos and Nitenpyram. An agent comprising a synergistically effective mixture of cadusafos and dinotefuran. An agent comprising a synergistically effective mixture from Cadusafos and Clothianidin. An agent comprising a synergistically effective mixture from Cadusafos and Imidacloprid. An agent comprising a synergistically effective mixture from Cadusafos and Imidaclothiz. Use of an agent according to one of claims 1 to 8 to combat of animal pests.