DE102004028995A1 - Synergistic pesticidal combination of thiodicarb and chloronicotinoyl compound, e.g. thiacloprid, useful as insecticide, acaricide, nematocide, ectoparasiticide or antifouling agent - Google Patents

Abstract

Compositions (A) containing synergistic amounts of thiodicarb (I) and at least one chloronicotinoyl compound (II) are new. An independent claim is included for the preparation of pesticidal compositions, by blending the synergistic mixture of (I) and (II) with extenders and/or surfactants. ACTIVITY : Insecticide; Acaricide; Nematocide; Parasiticide; Antifouling. In tests against Phaedon cochleariae larvae on cabbage leaves, the degree of mortality after 6 days was 15% using (I) at 100 ppm, 0% using thiacloprid (IIa) at 4 ppm and 65% (compared with a predicted value of 15%) using a combination of (I) at 100 ppm and (IIa) at 4 ppm. MECHANISM OF ACTION : None given in the source material.

Description

The The present invention relates to novel drug combinations which as active ingredients thiodicarb and another active ingredient from the series containing chloronicotinyls and very good insecticidal properties have.

It it is already known that thiodicarb is used to control animal pests, In particular, insects can be used. It is also known that chloronicotinyls such as e.g. Imidacloprid, thiacloprid, clothianidin, Thiamethoxam, acetamiprid, nitenpyram and dinotefuran to combat animal pests, especially insects are suitable.

The The effectiveness of these compounds is good, but at low application rates or against individual pests in some cases to be desired.

It has now been found that mixtures containing thiodicarb and respectively a compound from the series of Chlornicotinyle synergistic are effective and fight against animal pests suitable. Due to this synergism significantly lower amounts of active ingredient be used, i. the effect of the mixture is greater than the effect of the individual components.

The compounds mentioned are known, for example from "The Pesticide Manual", 11 ^th Edition, 1997, published by the British Crop Protection Conweil, see page 1195 for thiodicarb, page 706 for imidacloprid, page 9 for acetamiprid and page 880 for nitenpyram.

und ist bekannt aus EP 0 580 553 .Thiamethoxan has the formula

and is known from EP 0 580 553 ,

und ist bekannt aus EP 0 376 279 .Clothianidin has the formula

and is known from EP 0 376 279 ,

und ist bekannt aus der EP 0 235 725 .Thiacloprid has the formula

and is known from the EP 0 235 725 ,

und ist bekannt aus EP 0 649 845 .Dinotefuran has the formula

and is known from EP 0 649 845 ,

The relationship the active ingredients used, as well as the total amount to be applied The mixture depends on the species and the occurrence of the insects. The optimal conditions and total amounts can be determined by test series for each application.

A particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and imidacloprid. In the mixture, the weight ratio of both Active ingredients to each other, preferably between 100 to 1 and 1 to 50 and more preferably between 25 to 1 and 1 to 5, where here as hereinafter called thiodicarb in the proportions each first is.

A Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and acetamiprid. In the mixture, the weight ratio of both Active ingredients, preferably between 100 to 1 and 1 to 50 and especially preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and nitenpyram. In the mixture, the weight ratio of both Active ingredients, preferably between 100 to 1 and 1 to 50 and especially preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and dinotefuran. In the mixture, the weight ratio of both Active ingredients, preferably between 100 to 1 and 1 to 50 and especially preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and thiamethoxam. In the mixture, the weight ratio of both Active ingredients, preferably between 100 to 1 and 1 to 50 and especially preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and clothianidin. In the mixture, the weight ratio of both Active ingredients, preferably between 100 to 1 and 1 to 50 and especially preferably between 25 to 1 and 1 to 5.

A Another particularly preferred mixture according to the invention contains the active ingredients Thiodicarb and thiacloprid. In the mixture, the weight ratio of both Active ingredients, preferably between 100 to 1 and 1 to 50 and especially preferably between 25 to 1 and 1 to 5.

The active substance combinations are suitable for good plant tolerance and favorable toxicity to warm-blooded animals for controlling animal pests, in particular insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stored products and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:
From the order of the Isopoda eg Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
From the order of Diplopoda eg Blaniulus guttulatus.
From the order of Chilopoda eg Geophilus carpophagus, Scutigera spp.
From the order of Symphyla eg Scutigerella immaculata.
From the order of Thysanura eg Lepisma saccharina.
From the order of the Collembola eg Onychiurus armatus.
From the order of the Orthoptera eg Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
From the order Blattaria orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
From the order of the Dermaptera eg Forficula auricularia.
From the order of the Isoptera eg Reticulitermes spp.
From the order of Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
From the order of Thysanoptera eg Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis.
From the order of Heteroptera eg Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
From the order of Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp. Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.
From the order of Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysonhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp , Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella , Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.
From the order Coleoptera eg Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp. , Sitophilus spp., Otionhynchus sulcatus, Cosmopolites sordidus, Ceuthonhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
From the order of Hymenoptera eg Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
From the order of Diptera eg Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp , Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp ,
From the order of Siphonaptera eg Xenopsylla cheopis, Ceratophyllus spp.
From the class Arachnida eg Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp , Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

To the plant parasite Nematodes belong e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne Spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

According to the invention, all Plants and parts of plants are treated. Among plants are here understood all plants and plant populations, as desired and undesirable Wild plants or crops (including naturally occurring crops). Crops can Be plants by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or Combinations of these methods can be obtained, including transgenic ones Plants and including protected by plant variety rights or non-protectable plant varieties. Under plant parts are all above ground and underground Parts and organs of plants, such as shoot, leaf, flower and root By way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and Seeds as well as roots, tubers and rhizomes. To the plant parts belongs also harvested material as well as vegetative and generative propagation material, For example, cuttings, tubers, rhizomes, offshoots and seeds.

It should be emphasized in this case the particularly advantageous effect of the inventive composition outlook used in cereal crops, such as wheat, oats, barley, spelled, triticale and rye, but also in maize, millet, rice, sugar cane, soya, sunflower, potatoes, cotton, oilseed rape, canola, tobacco, beet, beet, asparagus Hops and fruit plants (including pome fruit such as apples and pears, stone fruits such as peaches, nectarines, cherries, plums and apricots, citrus fruits such as oranges, grapefruit, limes, lemons, kumquats, mandarins and satsumas, nuts such as pistachios, almonds, walnuts and pecans, tropical fruits such as mango, papaya, pineapple, dates and bananas, and grapes) and vegetables (including leafy vegetables such as endives, corn salad, tubers, head and vinegar lettuce, chard, spinach and chicory salad, cabbage vegetables such as cauliflower, Broccoli, Chinese cabbage, kale (winter or kale), kohlrabi, brussels sprouts, red cabbage, cabbage and savoy cabbage, fruit vegetables such as aubergines, cucumbers, peppers, squash, tomatoes, zucc hini and sweetcorn, root vegetables such as celeriac, carrots, carrots, yellow beets, radishes, radishes, beets, salsify and celery, legumes such as peas and beans and onions such as leeks and onions).

The Treatment according to the invention the plants and plant parts are carried out with the active ingredient combinations directly or by acting on their environment, habitat or Storage room after the usual Treatment methods, e.g. by dipping, spraying, evaporating, misting, Sprinkle, spread and propagate material, in particular in seeds, continue by one or multi-layer wrapping.

Especially the mixtures according to the invention are suitable for the treatment of seeds. This is how much of the damage caused by pests Damage to crops already by the infestation of the seed while storage and after placing the seed in the soil as well while and immediately after the germination of the plants. This phase is special critical, as the roots and shoots of the growing plant are particularly are sensitive and already a small damage to death lead the whole plant can. There is therefore a particular interest in the seed and the germinating plant by the use of suitable means protect.

The fight of pests By treating the seed of plants has long been known and is subject to more permanent Improvements. Nevertheless, in the treatment of seed emerge a set of problems that are not always solved solved can. So it is worthwhile, procedures for the protection of the seed and To develop the germinating plant, the additional application of pesticides make it redundant after sowing or after emergence of the plants. It is still desirable, the amount of the active ingredient used to optimize that the seed and the germinating plant before attack by pests best possible protected is, but without the plant itself by the active ingredient used to harm. In particular, seed treatment methods should also include intrinsic insecticidal properties of transgenic plants, for optimal protection of the seed and the germinating plant to achieve a minimum of pesticides.

The The present invention therefore more particularly relates to Method for protecting seed and germinating plants from the Infestation of pests, by treating the seed with an agent according to the invention. The invention also relates to the use of the agents according to the invention for the treatment of seed for the protection of seed and germinating Plant against pests. Farther The invention relates to seed which is used to protect against pests with an agent according to the invention was treated.

one the advantages of the present invention is that due to the particular systemic properties of the agents according to the invention the treatment of the seed with these means not only the seed itself, but also the resulting plants after the Emerge from pests protects. On This way can be the immediate treatment of the culture at the time the sowing or shortly thereafter omitted.

One Another advantage is the synergistic increase of insecticidal activity of the agents according to the invention over the respective single active substance, over the sum of the efficacy of the two individually applied agents goes. This will optimize the amount of active ingredient used allows.

It is likewise to be regarded as advantageous that the mixtures according to the invention can also be used in particular in the case of transgenic seed, wherein the plants resulting from this seed are capable of expressing a protein directed against pests. By treating such Seeds with the agents according to the invention certain pests can already be controlled by the expression of eg insecticidal protein, and it additionally surprisingly comes to a synergistic effect supplement with the inventive compositions, which improves the effectiveness of the protection against pest infestation again.

The agents according to the invention are suitable for the protection of seed of any plant variety as already above called in agriculture, in the greenhouse, in forests, in horticulture or used in wine-growing. In particular, it is including seeds of maize, peanut, canola, rape, poppy, olive, coconut, Cocoa, soy, cotton, turnip (for example, sugar beet and fodder beet), Rice, millet, wheat, barley, oats, rye, sunflower, sugarcane or tobacco. The agents according to the invention are also suitable for the treatment of seeds of fruit plants and vegetables as already mentioned above. Of particular importance is the treatment seed of corn, soy, cotton, wheat and canola or rapeseed to. Thus, for example, the mixture according to the invention comprising the active ingredients Methiocarb and imidacloprid, in particular for the treatment of the seed of corn.

As already mentioned above, is also the treatment of transgenic seeds with an agent of the invention a special meaning too. This is the seed of plants, which usually contain at least one heterologous gene, the expression of a polypeptide with in particular insecticidal Features controls. The heterologous genes in transgenic seeds can from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. The present invention is particularly suitable for the treatment of transgenic seed containing at least one heterologous gene, the from Bacillus sp. and its gene product activity against European corn borer and / or corn rootworm. It is particularly preferred this is a heterologous gene derived from Bacillus thuringiensis comes.

in the Within the scope of the present invention is the agent according to the invention applied alone or in a suitable formulation on the seed. Preferably, the seed is treated in a state in which so stable is that no damage occur during treatment. In general, the treatment can of the seed at any time between harvesting and sowing respectively. Usually seed separated from the plant and used by flasks, Shells, stalks, shell Wool or pulp was freed.

in the In general, care must be taken when treating the seed be that the amount of applied to the seed agent of the invention and / or other additives is chosen so that germination of the seed or the resulting plant is not damaged. This is especially important in the case of active ingredients, which are certain Application rates can show phytotoxic effects.

The agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to the person skilled in the art and are described, for example, in the following documents: US 4,272,417 A . US 4,245,432 A . US 4,808,430 A . US 5,876,739 A , US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2.

The Drug combinations can in the usual Formulations are transferred, like solutions, emulsions, Wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, Suspension emulsion concentrates, drug-impregnated Natural and synthetic substances as well as ultrafine encapsulations in polymers Substances.

These Formulations are prepared in a known manner, e.g. by Mixing the active ingredients with extenders, ie liquid solvents and / or solid carriers, optionally using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.

In the case of using water as extender, for example, organic solvents can also be used as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol as well as de ren ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

Suitable solid carriers are:
For example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules in question: eg broken and fractionated natural rocks such Calcite, marble, pear, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: for example lignin-sulphite liquors and methylcellulose.

It can in the formulations adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped Polymers such as gum arabic, polyvinyl alcohol, Polyvinyl acetate, as well as natural Phospholipids such as cephalins and lecithins and synthetic phospholipids. Other additives can mineral and vegetable oils be.

It can Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, Ferrocyan blue and organic dyes such as alizarin, azo and Metal phthalocyanine dyes and trace nutrients such as salts of iron, Manganese, boron, copper, cobalt, molybdenum and zinc are used.

The Formulations generally contain between 0.1 and 95% by weight Active ingredient, preferably between 0.5 and 90%.

The active compound combinations according to the invention can optionally in commercial Formulations and in those prepared from these formulations Forms of use mixed with other active substances, such as insecticides, Attractants, sterilants, bactericides, acaricides, nematicides, Fungicides, growth regulators or herbicides. To the insecticides count for example, phosphoric acid esters, Carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, by microorganisms Fabrics u.a.

Especially favorable Mixing partners are e.g. the following:

fungicides:

• Aldimorph, ampropylfos, ampropylfos-potassium, andoprim, anilazine, azaconazole, azoxystrobin, benalaxyl, benodanil, benomyl, benzamacril, benzamacrylisobutyl, bialaphos, binapacryl, biphenyl, bertertanol, blasticidin-S, bromuconazole, bupirimat, buthiobate, calcium polysulfide, capsimycin, Captafol, captan, carbendazim, carboxin, carvone, quinomethionate (quinomethionate), chlobenthiazone, chlorfenazole, chloroneb, chloropicrin, chlorothalonil, chlozolinate, clozylacon, cufraneb, cymoxanil, cyproconazole, cyprodinil, cyprofuram, debacarb, dichlorophen, diclobutrazole, diclofluanide, diclomecine, dicloran , Diethofencarb, Difenoconazole, Dimethirimol, Dimethomorph, Diniconazole, Diniconazole-M, Dinocap, Diphenylamine, Dipyrrithione, Ditalimfos, Dithianone, Dodemorph, Dodine, Drazoxolone, Ediphenphos, Epoxiconazole, Etaconazole, Ethirimol, Etridiazole, Famoxadone, Fenapanil, Fenarimol, Fenbuconazole, Fenfuram , Fenitropan, fenpiclonil, fenpropidin, fenpropimorph, fentin acetate, fentin hydroxide, ferbam, ferimzone, fluazina m, flumetover, fluoromide, fluquinconazole, flurprimidol, flusilazole, flusulfamide, flutolanil, flutriafol, folpet, fosetyl-alminium, fosetyl-sodium, fthalide, fuberidazole, furalaxyl, furametpyr, furcarbonil, furconazole, furconazole-cis, furmecyclox, guazatine, hexachlorobenzene, Hexaconazole, hymexazole, imazalil, imibenconazole, iminoctadine, iminoctadinealbesilate, iminoctadine triacetate, iodocarb, ipconazole, ipprobenfos (IBP), iprodione, irumamycin, isoprothiolane, isovaledione, kasugamycin, kresoxim-methyl, copper preparations such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulphate , Copper oxide, oxine-copper and Bordeaux mixture, mancopper, mancozeb, maneb, meferimzone, mepanipyrim, mepronil, metalaxyl, metconazole, methasulfocarb, methfuroxam, metiram, metomeclam, metsulfovax, mildiomycin, myclobutanil, myclozoline, nickel dimethyldithiocarbamate, nitrothal isopropyl , Nuarimol, Ofurace, Oxadixyl, Oxamocarb, Oxolinicacid, Oxycarboxime, Oxyfenthiine, Paclobutrazole, Pefurazoate, Penconazole, Pencycuron, Phosdiphene, Pimaricin, Piperaline, Polyoxin, Polyoxorim, Properazole, Prochlorazole, Procymidone, Propamocarb, Propanosine Sodium, Propiconazole, Propineb, Pyrazophos, Pyrifenox, Pyrimethanil, pyroquilon, pyroxyfur, quinconazole, quintozene (PCNB), sulfur and sulfur preparations, tebuconazole, tecloftalam, tecnazene, tetcyclacis, tetraconazole, thiabendazole, thicyofen, thiflucamides, thiophanate-methyl, thiram, tioxymide, tolclofos-methyl, tolylfluanid, triadimefon , Triadimenol, triazobutyl, triazoxide, trichlamide, tricyclazole, tridemorph, triflumizole, triforin, triticonazole, uniconazole, validamycin A, vinclozolin, viniconazole, zarilamide, zineb, ziram, and dagger G, OK-8705, OK-8801, α- (1, 1-dimethylethyl) -β- (2-phenoxyethyl) -1H-1,2,4-triazole-1-ethanol, α- (2,4-dichlorophenyl) -β-fluoro-b-propyl-1H-1,2 , 4-triazole-1-ethanol, α- (2,4-dichlorophenyl) -β-methoxy-α-methyl-1H-1,2,4-tr iazole-1-ethanol, α- (5-methyl-1,3-dioxan-5-yl) -β - [[4- (trifluoromethyl) -phenyl] -methylene] -1H-1,2,4-triazole 1-ethanol, (5RS, 6RS) -6-hydroxy-2,2,7,7-tetramethyl-5- (1H-1,2,4-triazol-1-yl) -3-octanone, (E) - a- (methoxyimino) -N-methyl-2-phenoxy-phenylacetamide, {2-methyl-1 - [[[1- (4-methylphenyl) -ethyl] -amino] -carbonyl] -propyl} -carbamic acid-1 isopropyl ester 1- (2,4-dichlorophenyl) -2- (1H-1,2,4-triazol-1-yl) -ethanone-O- (phenylmethyl) -oxime, 1- (2-methyl-1-naphthalenyl) 1 H -pyrrole-2,5-dione, 1- (3,5-dichlorophenyl) -3- (2-propenyl) -2,5-pynolidinedione, 1 - [(diiodomethyl) sulfonyl] -4-methylbenzene , 1 - [[2- (2,4-dichlorophenyl) -1,3-dioxolan-2-yl] -methyl] -1H-imidazole, 1 - [[2- (4-chlorophenyl) -3-phenyloxiranyl] - methyl] -1H-1,2,4-triazole, 1- [1- [2 - [(2,4-dichlorophenyl) -methoxy] -phenyl] -ethenyl] -1H-imidazole, 1-methyl-5-nonyl -2- (phenylmethyl) -3-pyrrolidinol, 2 ', 6'-dibromo-2-methyl-4'-trifluoromethoxy-4'-trifluoro-methyl-1,3-thiazole-5-carboxanilide, 2,2-dichloro -N- [1- (4-chlorophenyl) ethyl] -1-ethyl-3-methylcyclopropanecarboxamide, 2,6-dic Hlor-5- (methylthio) -4-pyrimidinyl thiocyanate, 2,6-dichloro-N- (4-trifluoromethylbenzyl) benzamide, 2,6-dichloro-N - [[4- (trifluoromethyl) phenyl] methyl ] benzamide, 2- (2,3,3-triiodo-2-propenyl) -2H-tetrazole, 2 - [(1-methylethyl) sulfonyl] -5- (trichloromethyl) -1,3,4-thiadiazole, 2 - [[6-deoxy-4-O- (4-O-methyl-β-D-glucopyranosyl) -α-D-glucopyranosyl] amino] -4-methoxy-1H-pyrrolo [2,3-d] pyrimidine-5-carbonitrile, 2-aminobutane, 2-bromo-2- (bromomethyl) -pentendinitrile, 2-chloro-N- (2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl ) -3-pyridinecarboxamide, 2-chloro-N- (2,6-dimethylphenyl) -N- (isothiocyanatomethyl) acetamide, 2-phenylphenol (OPP), 3,4-dichloro-1- [4- (difluoromethoxy) - phenyl] -1H-pyrrole-2,5-dione, 3,5-dichloro-N- [cyano [(1-methyl-2-propynyl) oxy] methyl] benzamide, 3- (1,1-dimethylpropyl 1-oxo) -1H-indene-2-carbonitrile, 3- [2- (4-chlorophenyl) -5-ethoxy-3-isoxazolidinyl] -pyridine, 4-chloro-2-cyano-N, N-dimethyl- 5- (4-methylphenyl) -1H-imidazole-1-sulfonamide, 4-methyl-tetrazolo [1,5-a) quinazolin-5 (4H) -one, 8- (1,1-dimethyl-ethyl) -N-ethyl -N-propyl -1,4-dioxaspiro [4.5] decane-2-methanamine, 8-hydroxyquinoline sulfate, 9H-xanthene-9-carboxylic acid 2 - [(phenylamino) carbonyl] hydrazide, bis (1-methylethyl) -3-methyl -4 - [(3-methylbenzoyl) oxy] -2,5-thiophenedicarboxylate, cis-1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) -cycloheptanol, cis -4- [3- [4- (1,1-dimethylpropyl) -phenyl-2-methylpropyl] -2,6-dimethyl-morpholine hydrochloride, ethyl [(4-chlorophenyl) -azo] cyanoacetate, potassium bicarbonate, Methanetrathiol sodium salt, methyl 1- (2,3-dihydro-2,2-dimethyl-1H-inden-1-yl) -1H-imidazole-5-carboxylate, Methyl N- (2,6-dimethylphenyl) -N- (5-isoxazolylcarbonyl) -DL-alaninate, methyl N- (chloroacetyl) -N- (2,6-dimethylphenyl) -DL-alaninate, N- (2 , 3-dichloro-4-hydroxyphenyl) -1-methyl-cyclohexanecarboxamide. N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3-furanyl) -acetamide, N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2 -oxo-3-thienyl) -acetamide, N- (2-chloro-4-nitrophenyl) -4-methyl-3-nitro-benzenesulfonamide, N- (4-cyclohexylphenyl) -1,4,5,6-tetrahydro- 2-pyrimidineamine, N- (4-hexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidineamine, N- (5-chloro-2-methylphenyl) -2-methoxy-N- (2-oxo-3 -oxazolidinyl) -acetamide, N- (6-methoxy) -3-pyridinyl) -cyclopropanecarboxamide, N- [2,2,2-trichloro-1 - [(chloroacetyl) -amino] -ethyl] -benzamide, N- [ 3-Chloro-4,5-bis (2-propynyloxy) -phenyl] -N'-methoxy-methanimidamide, N-formyl-N-hydroxy-DL-alanine sodium salt, O, O-diethyl [2- (2- dipropylamino) -2-oxoethyl] -ethylphosphoramidothioate, O-methyl-S-phenyl-phenylpropylphosphoramidothioate, S-methyl-1,2,3-benzothiadiazole-7-carbothioate, spiro [2H] -1-benzopyran-2,1 '( 3 'H) -isobenzofuran] -3'-one.

bactericides:

• Bronopol, dichlorophen, nitrapyrin, nickel dimethyldithiocarbamate, Kasugamycin, octhilinone, furancarboxylic acid, oxytetracycline, probenazole, Streptomycin, tecloftalam, copper sulphate and other copper preparations.

Insecticides / acaricides / Nematicides

• 1. Acetylcholinesterase (AChE) inhibitors 1.1 Carbamate, for example Alanycarb, aldicarb, aldoxycarb, allyxycarb, Aminocarb, Bendiocarb, Benfuracarb, Bufencarb, Butacarb, Butocarboxime, Butoxycarboxime, carbaryl, carbofuran, carbosulfan, cloethocarb, Dimetilane, ethiofencarb, fenobucarb, fenothiocarb, formetanate, Furathiocarb, isoprocarb, metam-sodium, methiocarb, methomyl, metolcarb, Oxamyl, pirimicarb, promecarb, propoxur, thiodicarb, thiofanox, Trimethacarb, XMC, xylylcarb Triazamate 1.2 organophosphates, for example Acephates, azamethiphos, azinphos (-methyl, -ethyl), Bromophos-ethyl, Bromfenvinfos (-methyl), Butathiofos, Cadusafos, Carbophenothion, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos (-methyl / -ethyl), coumaphos, cyanofenphos, cyanophos, chlorfenvinphos, Demeton-S-methyl, Demeton-S-methyl sulphone, Dialifos, Diazinon, Dichlofenthione, Dichlorvos / DDVP, Dicrotophos, Dimethoates, Dimethylvinphos, Dioxabenzofos, Disulfoton, EPN, Ethion, Ethoprophos, Etrimfos, Famphur, Fenamiphos, Fenitrothion, Fensulfothion, Fenthion, Flupyrazofos, Fonofos, Formothion, Fosmethilane, Fosthiazate, Heptenophos, iodofenofen, Iprobenfos, Isazofos, Isofenphos, isopropyl O-salicylates, isoxathione, malathion, mecarbam, methacrifos, methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion (-methyl / -ethyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidone, phosphocarb, phoxim, pirimiphos (-methyl / -ethyl), Profenofos, Propaphos, Propetamphos, Prothiofos, Prothoate, Pyraclofos, Pyridaphenthion, Pyridathion, Quinalphos, Sebufos, Sulfotep, Sulprofos, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, triclorfone, vamidothione
• 2. Sodium Channel Modulators / Voltage-Dependent Sodium Channel Blockers 2.1 Pyrethroids, for example Acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentyl isomer, Bioethanomethrin, biopermethrin, bioresmethrin, chlovaporthrin, Cis-cypermethrin, cis-resmethrin, cis-permethrin, clocythrin, cycloprothrin, Cyfluthrin, cyhalothrin, cypermethrin (alpha, beta, theta, zeta), Cyphenothrin, Deltamethrin, Empenthrin (1R-isomer), Esfenvalerate, Etofenprox, fenfluthrin, fenpropathrin, fenpyrithrin, fenvalerate, flubrocythrinates, Flucythrinates, Flufenprox, Flumethrin, Fluvalinate, Fubfenprox, Gamma-cyhalothrin, imiprothrin, kadethrin, lambda-cyhalothrin, metofluthrin, Permethrin (cis-, trans-), phenothrin (1R-trans isomer), prallethrin, Profuthrin, protrifenbute, pyresmethrin, resmethrin, RU 15525, Silafluofen, tau-fluvalinate, tefluthrin, terallethrin, tetramethrin (-1R isomer), tralomethrin, transfluthrin, ZXI 8901, pyrethrins (Pyrethrum) DDT 2.2 Oxadiazines, for example indoxacarb
• 3. Acetylcholine Receptor Agonists / Antagonists 3.1 Chloronicotinyls, for example Acetamiprid, Clothianidin, Dinotefuran, Imidacloprid, Nitenpyram, Nithi azines, thiacloprid, thiamethoxam 3.2 Nicotine, Bensultap, Cartap
• 4. Acetylcholine receptor modulators 4.1 Spinosyn, to Example spinosad
• 5. GABA-driven chloride channel antagonists 5.1 Cyclodienes Organochlorines, for example Camphechlor, chlordane, endosulfan, Gamma-HCH, HCH, heptachlor, lindane, methoxychlor 5.2 Fiprole, for example Acetoprole, ethiprole, fipronil, vaniliprole
• 6. Chloride Channel Activators 6.1 Mectins, for example avermectin, Emamectin, Emamectin benzoate, Ivermectin, Milbemycin
• 7. Juvenile hormone mimetics, for example Diofenolane, Epofenonane, Fenoxycarb, Hydroprene, Kinoprene, Methoprene, Pyriproxifen, Triprene
• 8. ecdysonagonists / disruptors 8.1 Diacylhydrazines, for example Chromafenozide, Halofenozide, Methoxyfenozide, Tebufenozide
• 9. Inhibitors of chitin biosynthesis 9.1 benzoylureas, for example Bistrifluron, Chlofluazuron, Diflubenzuron, Fluazuron, Flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, Noviflumuron, Penflurone, Teflubenzuron, Triflumuron 9.2 Buprofezin 9.3 cyromazine
• 10. Inhibitors of oxidative phosphorylation, ATP disruptors 10.1 diafenthiuron 10.2 Organotins, for example azocyclotin, cyhexatin, Fenbutatin oxide
• 11. Decoupling of oxidative phosphorylation by interruption of the H proton gradient 11.1 Pyrroles, for example Chlorfenapyr 11.2 Dinitrophenols, for example binapacyrl, dinobutone, dinocap, DNOC
• 12. Side-I Electron Transport Inhibitors 12.1 METI's, for example Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad, Tolfenpyrad 12.2 hydramethylnon 12.3 Dicofol
• 13. Side II Electron Transport Inhibitors Rotenone
• 14. Side III Electron Transport Inhibitors acequinocyl, fluacrypyrim
• 15. Microbial disruptors of insect intestinal membrane Bacillus thuringiensis strains
• 16. Inhibitors of fat synthesis Tetronic acids, for example Spirodiclofen, spiromesifen Tetramic acids, for example 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] dec-3-en-4-yl ethyl carbonate (also known as: Carbonic acid, 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] dec-3-en-4-yl ethyl ester, CAS Reg. No .: 382608-10-8) and carbonic acid, cis-3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1-azaspiro [4.5] dec-3 -en-4-yl ethyl ester (CAS Reg. No .: 203313-25-1)
• 17. Carboxamides, for example flonicamide
• 18. Octopaminergic agonists, for example, amitraz
• 19. Inhibitors of magnesium-stimulated ATPase, for example propargite
• 20. BDCAs, for example N 2 - [1,1-dimethyl-2- (methylsulfonyl) ethyl] -3-iodo-N 1 - [2-methyl-4- [1,2,2,2-tetrafluoro-1- ( trifluoromethyl) ethyl] phenyl] -1,2-benzenedicarboxamides (CAS Reg. No .: 272451-65-7)
• 21. Nereistoxin analogs, for example thiocyclam hydrogen oxalate, Thiosultap-sodium
• 22. Biologics, hormones or pheromones, for example azadirachtin, Bacillus spec., Beauveria spec., Codlemone, Metarrhicon spec., Paecilomyces spec., Thuringiensin, Verticillium spec.
• 23. Active substances with unknown or nonspecific modes of action 23.1 Fumigants, for example aluminum phosphides, methyl bromides, sulfuryl fluorides 23.2 Selective feeding inhibitors, for example Cryolites, Flonicamid, Pymetrozines 23.3 Mite Growth Inhibitors, for example Clofentezine, Etoxazole, Hexythiazox 23.4 Amidoflumet, Benclothiazole, Benzoximate, Bifenazate, Bromopropylate, Buprofezin, Chinomethionate, Chlordimeform, Chlorobenzilate, Chloropicrin, Clothiazoben, Cycloprene, Dicyclanil, Fenoxacrim, Fentrifanil, Flubenzimine, Flufenerim, Flutenzin, Gossyplure, Hydramethylnone, Japonilure, Metoxadiazone, Petroleum, Piperonylbutoxide, Potassium oleate, Pyralidyl, Sulfluramid, Tetradifon, Tetrasul, Triarathene, Verbutin, furthermore (1R-cis) - [5- (phenylmethyl) -3-furanyl] -methyl 3 - [(dihydro-2-oxo-3 (2H) -furanylidene) -methyl] -2,2-dimethylcyclopropanecarboxylate (3-phenoxyphenyl) -methyl-2,2,3,3-tetramethylcyclopropanecarboxylate 1 - [(2- Chloro-5-thiazolyl) methyl] tetrahydro-3,5-dimethyl-N-nitro-1,3,5-triazine-2 (1H) -imin 2- (2-chloro-6-fluorophenyl) -4- [4 - (1,1-dimethylethyl) phenyl] -4,5-dihydrooxazole 2- (acetoxy) -3-dodecyl-1,4-naphthalenedione 2-Chloro-N - [[[4- (1-phenylethoxy) -] phenyl] amino] carbonyl] - benzamide 2-Chloro-N - [[[4- (2,2-dichloro-1,1-difluoroethoxy) -phenyl] -amino] -carbonyl] -benzamide 3-Methylphenyl-propylcarbamate 4- [4- (4-Ethoxyphenyl ) -4-methylpentyl] -1-fluoro-2-phenoxybenzene 4-Chloro-2- (1,1-dimethylethyl) -5 - [[2- (2,6-dimethyl-4-phenoxyphenoxy) ethyl] thio ] -3 (2H) -pyridazinone 4-Chloro-2- (2-chloro-2-methylpropyl) -5 - [(6-iodo-3-pyridinyl) methoxy] -3 (2H) -pyridazinone 4-chloro-5 - [(6-chloro-3-pyridinyl) methoxy] -2- (3,4-dichlorophenyl) -3 (2H) -pyridazinone Bacillus thuringiensis strain EG-2348 Benzoic acid [2-benzoyl-1- (1,1-dimethyl-ethyl ) -hydrazide butanoic acid 2,2-dimethyl-3- (2,4-dichlorophenyl) -2-oxo-1-oxaspiro [4.5] dec-3-en-4-yl-ester [3 - [(6-chloro) 3-pyridinyl) methyl] -2-thiazolidinylidene] cyanamide dihydro-2- (nitromethylene) -2H-1,3-thiazine-3 (4H) -carboxaldehyde ethyl [2 - [[1,6-dihydro-6- oxo-1- (phenylmethyl) -4-pyridazinyl] oxy] ethyl] carbamate N- (3,4,4-trifluoro-1-oxo-3-butenyl) -glycine N- (4-chlorophenyl) -3- [ 4- (difluoromethoxy) phenyl] -4,5-dihydro-4-phenyl-1H-pyrazole-1-carboxamide N-methyl-N '- (1-methyl-2-propenyl) -1 , 2-hydrazinedicarbothioamide N-methyl-N'-2-propenyl-1,2-hydrazinedicarbothioamide O, O -diethyl- [2- (dipropylamino) -2-oxoethyl] ethylphosphoramidothioate

Also a mixture with other known active substances, such as herbicides or with fertilizers and growth regulators is possible.

The active compound combinations according to the invention can also when used as insecticides in their commercial Formulations and in those prepared from these formulations Application forms in mixture with synergists are present. synergists are compounds that increase the effect of the active ingredients without the added synergist itself being active got to.

Of the Active substance content prepared from the commercial formulations Application forms can vary widely. The drug concentration the application forms may range from 0.0000001 up to 95% by weight of active ingredient, preferably between 0.0001 and 1 wt .-%.

The Application is done in a custom forms adapted to the applications Wise.

at the application against hygiene and storage pests are characterized by the drug combinations an excellent residual effect on wood and clay as well as by a good alkali stability on limed Documents out.

The active compound combinations of the invention not only against plant, hygiene and storage pests, but also in the veterinary sector against animal parasites (ectoparasites) such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, Featherlings and fleas. These parasites include:
From the order of the Anoplurida eg Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
From the order of Mallophagida and the suborders Amblycerina and Ischnocerina eg Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Tri chodectes spp., Felicola spp.
From the order Diptera and the suborders Nematocerina and Brachycerina eg Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp. , Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora Spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
From the order of the siphon adapter eg Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
From the order of the Heteropterida eg Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
From the order Blattarida eg Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
From the subclass of Acari (Acarina) and the orders of meta and mesostigmata eg Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma Spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.
From the order of Actinedida (Prostigmata) and Acaridida (Astigmata) eg Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp. Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active compound combinations according to the invention are also suitable for fighting of arthropods, farm animals, e.g. Bovine, Sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, Chicken, Turkeys, ducks, geese, Bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, e.g. Hamster, guinea pig, Rats and mice affected. By fighting These arthropods are said to be deaths and reductions in performance (in the case of meat, milk, wool, hides, eggs, Honey, etc.) are reduced, so that through the use of the active compound combinations according to the invention a more economical and easier animal husbandry is possible.

The Application of the active compound combinations according to the invention happens in the veterinary sector in a known manner by enteral administration in the form of, for example Tablets, capsules, potions, Drenchen, granules, pastes, boluses, the feed-through process, of suppositories, by parenteral administration, such as by injections (Intramuscular, subcutaneously, intravenously, intraperitoneal, etc.), implants, by nasal application dermal application in the form of, for example, diving or bathing (Dipping), spraying (Spray), infusion (Pour-on and spot-on), washing, powdering and with help of active substance-containing moldings, like collars, Ear tags, tail tags, limb bands, halters, marking devices etc.

at the application for Livestock, poultry, Pets etc. can be the active ingredients as formulations (for example Powders, emulsions, flowable agents), containing the active ingredients in an amount of 1 to 80% by weight, apply directly or after 100 to 10 000 dilution or as use chemical bath.

It was also found that the drug combinations of the invention show a high insecticidal activity against insects, the technical Destroy materials.

By way of example and preferably without limiting however, the following insects are mentioned:
Beetle like
Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
Hymenoptera like
Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.
Termites like
Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
Bristle tails like Lepisma saccharina.

Under technical materials are non-living in the present context Materials, such as preferably plastics, adhesives, Glues, papers and cartons, leather, wood, woodworking products and paints.

All it is particularly preferable for the insect infestation protected Material around wood and woodworking products.

By wood and woodworking products, which can be protected by the composition according to the invention or mixtures containing it, is to be understood by way of example:
Timber, wooden beams, railway sleepers, bridge parts, boat jetties, wooden vehicles, crates, pallets, containers, telephone poles, wooden cladding, wooden windows and doors, plywood, chipboard, carpentry or wood products, which are generally used in home construction or joinery.

The Drug combinations can as such, in the form of concentrates or general Formulations such as powders, granules, solutions, suspensions, emulsions or pastes are applied.

The mentioned formulations in a manner known per se, e.g. by mixing the active ingredients with at least one solvent or diluent, Emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccative and UV stabilizers and optionally Dyes and pigments and other processing aids.

The insecticides used for the protection of wood and wood-based materials Agents or concentrates contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60% by weight.

The Amount of funds used or concentrates is of the type and depending on the occurrence of the insects and on the medium. The optimal application rate can be determined in each case by test series become. In general, however, it is sufficiently from 0.0001 to 20% by weight, preferably 0.001 to 10 wt .-%, of the active ingredient, based on the to be protected Material to use.

When solvent and / or diluents serves an organic-chemical solvent or solvent mixture and / or an oily one or oily heavy volatile organic-chemical solvent or Solvent mixture and / or a polar organic-chemical solvent or solvent mixture and / or water and optionally an emulsifier and / or wetting agent.

When organic-chemical solvents are preferably oily or oil-like solvent with an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C used. As such low-volatility, water-insoluble, oily and oily solvent become appropriate mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably White spirit, petroleum and / or alkylbenzene used.

Advantageous get mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range from 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics from Boiling range of 160 to 280 ° C, turpentine and the like. For use.

In a preferred embodiment become liquid aliphatic hydrocarbons having a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and / or locker oil and / or Monochloronaphthalene, preferably α-monochloronaphthalene.

The organic low volatility oily or oily solvent with an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C, can partially by light or medium volatile organic-chemical solvents be replaced, with the proviso that the solvent mixture also an evaporation number over 35 and a flash point above 30 ° C, preferably above 45 ° C, having and that the insecticide-fungicide mixture in this solvent mixture soluble or is emulsifiable.

In a preferred embodiment, a portion of the organic chemical solvent or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent mixture. Preferably, hydroxyl and / or ester and / or ether groups containing aliphatic organic chemical solvents such as glycol ethers, esters or the like. For use.

When Organic-chemical binders are used in the present Invention the known water-dilutable and / or in the used organic chemical solvents soluble or dispersible or emulsifiable synthetic resins and / or binding drying oils, in particular Binder consisting of or containing an acrylate resin, a vinyl resin, e.g. Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, Polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, Hydrocarbon resin such as indene coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / or Resin used.

The Resin used as a binder may be in the form of an emulsion, Dispersion or solution, be used. Bitumen or bituminous substances can also be used as binders up to 10% by weight. In addition, known dyes, Pigments, water repellents, scents and inhibitors or corrosion inhibitors and the like. Be used.

Prefers is according to the invention as organic-chemical binder at least one alkyd resin or modified alkyd resin and / or a drying vegetable oil on average or in the concentrate. Preferred according to the invention Alkyd resins with an oil content of more than 45% by weight, preferably 50 to 68% by weight.

The mentioned Binder may be wholly or partly by a fixative (mixture) or a plasticizer (mixture) are replaced. These additives should a volatilization prevent the active ingredients and crystallization or precipitation. Preferably, they replace 0.01 to 30% of the binder (based on 100% of the binder used).

The Plasticizers come from the chemical classes of phthalates such as dibutyl, dioctyl or Benzylbutylphthalat, phosphoric acid esters such as tributyl phosphate, adipic acid ester such as di (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, Oleates such as butyl oleate, glycerol ethers or higher molecular weight glycol ethers, Glycerol ester and p-toluenesulfonic acid ester.

fixative are chemically based on polyvinyl alkyl ethers such as e.g. polyvinyl methyl or ketones such as benzophenone, ethylene benzophenone.

When solvent or diluent In particular, water is also suitable, if appropriate as a mixture with one or more of the above organic chemical solvent or diluents, Emulsifiers and dispersants.

One particularly effective wood protection is achieved by large-scale impregnation e.g. Vacuum, double vacuum or printing process achieved.

The ready to use means optionally further insecticides and optionally also contain one or more fungicides.

at the same time can the active compound combinations according to the invention for protection against the growth of objects, in particular hulls, sieves, Nets, structures, wharves and signal systems connected with sea or brackish water are used.

growth by sessile Oligochaeten, like Kalkröhrenwürmer as well as by shells and Species of the group Ledamorpha (barnacles), like different lepas and scalpel species, or by species of the group Balanomorpha (barnacles), like Balanus or Pollicipes species, increases the frictional resistance of Ships and guides increased in consequence by Energy consumption and above Beyond frequent Dry dock stays at a significant increase in operating costs.

Next the vegetation by algae, for example Ectocarpus sp. and ceramium sp., comes in particular from the vegetation by sessile Entomostraken groups, which are summarized under the name cirripedia (cirriped crayfish), special importance.

It was now surprisingly found that the drug combinations of the invention a have excellent antifouling (antifouling) effect.

By Use of active compound combinations according to the invention may indicate the use of heavy metals, e.g. in bis (trialkyltin) sulfides, Tri-n-butyltin laurate, tri-n-butyltin chloride, copper (I) oxide, triethyltin chloride, Tri-n-butyl (2-phenyl-4-chlorophenoxy) -tin, tributyltin oxide, molybdenum disulfide, Antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, Tri-n-butylzinnfluorid, Manganese ethylene bis-thiocarbamate, zinc dimethyldithiocarbamate, zinc ethylene bis-thiocarbamate, Zinc and copper salts of 2-pyridinethiol-1-oxide, bisdimethyldithiocarbamoylzincethylenebisthiocarbamate, Zinc oxide, copper (I) ethylene-bisdithiocarbamate, copper thiocyanate, Copper naphthenate and Tributylzinnhalogeniden be omitted or the concentration of these compounds are decisively reduced.

The ready-to-use antifouling paints may possibly have others Active ingredients, preferably algicides, fungicides, herbicides, molluscicides or other antifouling agents.

Suitable combination partners for the antifouling agents according to the invention are preferably:
Algicides like
2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophene, diuron, endo thal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn;
Fungicides like
Benzo [b] thiophenecarboxylic cyclohexylamide-S, S-dioxide, dichlorofluanide, fluoro-folpet, 3-iodo-2-propynyl-butylcarbamate, tolylfluanid and azoles as
Azaconazole, cyproconazole, epoxyconazole, hexaconazole, metconazole, propiconazole and tebuconazole;
Molluscicides like
Fe complexing agents, fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and tri-methacarb;
or conventional antifouling agents such as
4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinethiol-1 oxide, pyridine-triphenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) -pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4,6-trichlorophenylmaleimide.

The antifouling agents used contain the active ingredient in one Concentration of 0.001 to 50 wt .-%, in particular from 0.01 to 20% by weight.

The Antifouling agents further include the usual ingredients such as e.g. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Antifouling paints Contain besides the algicides, fungicides, molluscicides and insecticides especially binders.

Examples for recognized Binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, Acrylic resins in a solvent system especially in an aqueous one System, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous Dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying oils, like flaxseed oil, Resin esters or modified hard resins in combination with tar or Bitumens, asphalt and epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

Possibly Paint also contains inorganic pigments, organic Pigments or dyes which are preferably insoluble in seawater. Furthermore, can Coating materials, such as rosin, contain a controlled Allow release of the active ingredients. The paintings can also Plasticizers, modifiers which influence the rheological properties as well as other conventional ones Contain ingredients. Even in self-polishing antifouling systems, the active compound combinations according to the invention be incorporated.

The active compound combinations according to the invention are also suitable for controlling animal pests, in particular insects, arachnids and mites, which are used in enclosed spaces, such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests, alone or in combination with other active ingredients and adjuvants in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
From the order of Scorpionidea eg Buthus occitanus.
From the order of Acarina, for example, Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyci phagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
From the order of the Araneae eg Aviculariidae, Araneidae.
From the order of the Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
From the order of the Isopoda eg Oniscus asellus, Porcellio scaber.
From the order of the Diplopoda eg Blaniulus guttulatus, Polydesmus spp.
From the order of Chilopoda eg Geophilus spp.
From the order of Zygentoma eg Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
From the order of the Blattaria eg Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
From the order of Saltatoria eg Acheta domesticus.
From the order of the Dermaptera eg Forficula auricularia.
From the order of the Isoptera eg Kalotermes spp., Reticulitermes spp.
From the order of Psocoptera eg Lepinatus spp., Liposcelis spp.
From the order of Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
From the order of Diptera eg Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria , Simulium spp., Stomoxys calcitrans, Tipula paludosa.
From the order of Lepidoptera eg Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
From the order of Anoplura eg Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The Application in the field of household insecticides may also be combined with other suitable active substances such as phosphoric acid esters, carbamates, pyrethroids, Growth regulators or agents from other known insecticide classes respectively.

The Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, Fog machines, foggers, foams, Gels, evaporator products with evaporator plates made of cellulose or plastic, Liquid evaporators, Gel and membrane evaporators, propeller-driven evaporators, energy-free or passive evaporation systems, moth papers, moth bags and Moth gels as granules or dusts, in straw baits or Bait stations.

At the Use of the active compound combinations according to the invention can the application rates within a larger range, depending on the type of application be varied. In the treatment of plant parts are the Application rates of active ingredient combination generally between 0.1 and 10 000 g / ha, preferably between 10 and 1000 g / ha.

The good insecticidal activity of the active compound combinations according to the invention is apparent from the examples below. While the individual active ingredients weaknesses in effect show the combinations have an effect over a simple effect summation goes beyond.

The expected effect for a given combination of two drugs (see COLBY, S.R .; "Caculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 15, p 20-22, 1967); be calculated:

X

= den Abtötungsrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m ppm,

Y

= den Abtötungsrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes B in einer Aufwandmenge von n ppm,

E

= den Abtötungsrad, ausgedruckt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A und B in Aufwandmengen von m und n ppmbedeutet,

dann ist

If

X

= the kill rate, expressed in% of the untreated control, when using the active substance A at a rate of m ppm,

Y

= the rate of destruction, expressed as% of the untreated control, when using the active substance B at an application rate of n ppm,

e

= the rate of destruction, expressed in% of the untreated control, when using the active compound A and B in amounts of m and n ppm meaning,

then

is the actual insecticidal kill rate greater than calculated, the combination is over-additive in its kill, i. it lies synergistic effect. In this case, the actually observed kill rate to be taller as the one from the above Formula calculated value for the expected kill rate (E).

Example A

Myzus persicae test

• Solvent: 7 parts by weight of dimethylformamide
• Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea), which is strongly affected by the green Peach aphid (Myzus persicae) are attacked by dipping treated in the preparation of active compound of the desired concentration.

To the desired Time will be the killing determined in%. 100% means that all aphids have been killed; 0% means no aphids killed were. The determined mortality values are charged one after the Colby formula.

at This test showed the following active ingredient combination according to the present invention Sign a synergistic enhanced efficacy in comparison to the individual active ingredients used:

Table A Plant damaging insects Myzus persicae test

Table A Plant damaging insects Myzus persicae test

Example B

Phaedon cochleariae larval test

• Solvent: 7 parts by weight of dimethylformamide
• Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea) are dipped in the preparation of active compound of the desired concentration treated and with larvae of horseradish beetle (Phaedon cochleariae) occupied as long as the leaves are still wet.

To the desired Time will be the killing determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae killed were. The determined kill values you calculate according to the Colby formula.

at This test showed the following active ingredient combination according to the present invention Sign a synergistic enhanced efficacy in comparison to the individual active ingredients used:

Table B Plant Harmful Insects Phaedon cochleariae larval test

Table B Plant Harmful Insects Phaedon cochleariae larval test

Table B Plant Harmful Insects Phaedon cochleariae larval test

Table B Plant Harmful Insects Phaedon cochleariae larval test

Example C

Plutella xylostella test (resistant strain)

• Solvent: 7 parts by weight of dimethylformamide
• Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea) are dipped in the preparation of active compound of the desired concentration treated and with larvae of the cabbage (Plutella xylostella, resistant Trunk) as long as the leaves are still wet.

To the desired Time will be the killing determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill rates you calculate according to the Colby formula.

at This test showed the following active ingredient combination according to the present invention Sign a synergistic enhanced efficacy in comparison to the individual active ingredients used:

Table D Plant injurious insects Pluteller xylostella (resistant strain) test

Table D Plant injurious insects Pluteller xylostella (resistant strain) test

Claims (10)

Agent containing a synergistically effective mixture of thiodicarb of the formula

and at least one compound from the chloronicotinyl series. Agent containing a synergistically effective mixture of thiodicarb and imidacloprid. Agent containing a synergistically effective mixture of thiodicarb and acetamiprid. Agent containing a synergistically effective mixture of thiodicarb and nitenpyram. Agent containing a synergistically effective mixture of thiodicarb and thiamethoxam. Agent containing a synergistically effective mixture of thiodicarb and clothianidin. Agent containing a synergistically effective mixture of thiodicarb and thiacloprid. Agent containing a synergistically effective mixture of thiodicarb and dinotefuran. Use of agents according to one of claims 1 to 8 to combat of animal pests. Process for the production of pesticides, characterized in that a synergistically effective mixture according to one the claims 1 to 8 mixed with extenders and / or surface-active substances.