DE102005048488C5 - Method and device for high power entrained flow gasifiers - Google Patents
Method and device for high power entrained flow gasifiers Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/466—Entrained flow processes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
- C10J3/845—Quench rings
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/156—Sluices, e.g. mechanical sluices for preventing escape of gas through the feed inlet
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
- C10J2300/1628—Ash post-treatment
- C10J2300/1634—Ash vitrification
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1687—Integration of gasification processes with another plant or parts within the plant with steam generation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Abstract
Vorrichtung zur Durchführung eines Verfahrens nach den Ansprüchen 13 bis 21 zur Vergasung von Brennstaub-Wasser-Slurry oder Brennstaub-Öl-Slurry oder festen Brennstoffen im Flugstrom mit einem freien Sauerstoff enthaltenden Oxidationsmittel durch partielle Oxidation bei Drücken zwischen Umgebungsdruck und 8 MPa, Temperaturen zwischen 1.200 und 1.900°C sowie hohen Reaktorleistungen bei der- ein Hochleistungsvergasungsreaktor (2) mehrere am Kopf angeordnete Vergasungsbrenner (2.1) sowie einen Zünd- und Pilotbrenner (2.2) aufweist,dadurch gekennzeichnet, dass- jedem Vergasungsbrenner (2.1) ein eigenes Brennstoff- Zuführungssystem zugeordnet ist,- eine Anordnung am Vergasungsbrenner (2.1) zum Messen und Regeln der zufließenden Brennstoff- und Sauerstoffmengen gegeben ist und- eine integrale Überwachung und Regelung der dem Vergasungsreaktor (2) insgesamt zufließenden Brennstoff- und Sauerstoffmenge gegeben ist.Device for carrying out a method according to claims 13 to 21 for the gasification of fuel dust-water slurry or fuel dust-oil slurry or solid fuels in flight flow with a free oxygen-containing oxidizing agent by partial oxidation at pressures between ambient pressure and 8 MPa, temperatures between 1,200 and 1,900 ° C and high reactor outputs in which a high-performance gasification reactor (2) has a plurality of gasification burners (2.1) arranged at the head and an ignition and pilot burner (2.2), characterized in that each gasification burner (2.1) is assigned its own fuel supply system - there is an arrangement on the gasification burner (2.1) for measuring and regulating the amount of fuel and oxygen flowing in and - there is an integral monitoring and control of the amount of fuel and oxygen flowing in total to the gasification reactor (2).
Description
Die Erfindung betrifft eine Vorrichtung und ein Verfahren zur Flugstromvergasung sehr hoher Leistung, wie sie zur Synthesegasversorgung von Großsynthesen eingesetzt werden können. Die Erfindung erlaubt, zu Brennstaub aufbereitete Brennstoffe wie Braun- und Steinkohlen, Petrolkokse, feste mahlbare Rückstände aber auch Feststoff-Flüssig-Suspensionen, sogenannte Slurries in Synthesegas umzuwandeln. Dabei wird der Brennstoff bei Temperaturen zwischen 1.200 bis 1.900°C mit einem freien Sauerstoff enthaltenden Vergasungsmittel bei Drucken bis 8 MPa durch Partialoxidation in CO- und H2-haltige Gase umgesetzt. Dies geschieht in einem Vergasungsreaktor, der sich durch eine Mehrbrenneranordnung und durch einen gekühlten Vergasungsraum auszeichnet.The invention relates to a device and a method for entrained-flow gasification of very high power, as can be used for supplying synthesis gas to large-scale syntheses. The invention allows fuels such as lignite and hard coal, petroleum coke, solid milled residues but also solid-liquid suspensions, so-called slurries, to be converted into synthesis gas. The fuel is converted at temperatures between 1,200 and 1,900 ° C with a free oxygen-containing gasifying agent at pressures up to 8 MPa by partial oxidation into gases containing CO and H 2 . This takes place in a gasification reactor, which is characterized by a multi-burner arrangement and by a cooled gasification chamber.
In der Technik der Gaserzeugung ist die autotherme Flugstromvergasung von festen, flüssigen und gasförmigen Brennstoffen langjährig bekannt. Das Verhältnis von Brennstoff zu sauerstoffhaltigen Vergasungsmitteln wird dabei so gewählt, dass aus Gründen der Synthesegasqualität höhere Kohlenstoffverbindungen zu Synthesegaskomponenten wie CO und H2 vollständig aufgespalten werden und die anorganischen Bestandteile als schmelzflüssige Schlacke ausgetragen werden, siehe J. Carl, P. Fritz, NOELL-KONVERSIONSVERFAHREN, EF-Verlag für Energie- und Umwelttechnik GmbH, 1996, S. 33 und S. 73.The autothermal entrained-flow gasification of solid, liquid and gaseous fuels has long been known in the art of gas generation. The ratio of fuel to oxygen-containing gasification agents is chosen so that, for reasons of synthesis gas quality, higher carbon compounds to synthesis gas components such as CO and H2 are completely broken down and the inorganic constituents are discharged as molten slag, see J. Carl, P. Fritz, NOELL CONVERSION PROCESS , EF-Verlag für Energie- und Umwelttechnik GmbH, 1996, p. 33 and p. 73.
Nach verschiedenen in der Technik eingeführten Systemen können dabei Vergasungsgas und schmelzflüssige Schlacke getrennt oder gemeinsam aus dem Reaktionsraum der Vergasungsvorrichtung ausgetragen werden, wie
Von Ch. Higman und M. van der Burgtwird in „Gasification“, Seite 124, Verlag Elsevier 2003, ein Verfahren vorgestellt, bei dem das heiße Vergasungsgas gemeinsam mit der flüssigen Schlacke den Vergaser verlässt und direkt in einen senkrecht darunter angeordneten Abhitzekessel eintritt, in dem das Rohgas und die Schlacke unter Nutzung derIn Ch. Higman and M. van der Burgt, in “Gasification”, page 124, Elsevier Publishing House 2003, a process is presented in which the hot gasification gas, together with the liquid slag, leaves the gasifier and enters directly into a waste heat boiler arranged vertically below which the raw gas and the slag using the
Abwärme zur Dampferzeugung abgekühlt werden. Die Schlacke sammelt sich in einem Wasserbad, das gekühlte Rohgas verlässt den Abhitzekessel seitwärts. Dem Vorteil der Abhitzegewinnung nach diesem System steht eine Reihe von Nachteilen gegenüber. Genannt seien hier besonders die Bildung von Ablagerungen auf den Wärmetauscherrohren, die zur Behinderung des Wärmeüberganges sowie zur Korrosion und Erosion und damit zu mangelnder Verfügbarkeit führen.Waste heat can be cooled to generate steam. The slag collects in a water bath, the cooled raw gas leaves the waste heat boiler sideways. The advantage of waste heat recovery according to this system is offset by a number of disadvantages. The formation of deposits on the heat exchanger tubes, which lead to the obstruction of heat transfer as well as to corrosion and erosion and thus to a lack of availability, should be mentioned here in particular.
Die Leistung der verschiedenen dargelegten Vergasungstechnologien ist auf ca. 500 MW begrenzt. The performance of the various gasification technologies presented is limited to approx. 500 MW.
Ausgehend von diesem Stand der Technik ist es Aufgabe der Erfindung, eine Vorrichtung zur Vergasung von Brennstaub-Wasser-Slurry oder Brennstaub-Öl-Slurry festen Brennstoffen im Flugstrom sowie ein Verfahren zur Durchführung in dieser Vorrichtung zu schaffen, die bei einer zuverlässigen und sicheren Betriebsweise höchste Leistungen von 1.000 bis 1.500 MW erlauben.Based on this prior art, it is an object of the invention to provide a device for the gasification of fuel dust-water slurry or fuel dust-oil slurry solid fuels in the entrained flow, and a method for carrying out this device, which operate in a reliable and safe manner allow maximum outputs from 1,000 to 1,500 MW.
Diese Aufgabe wird durch eine Vorrichtung zur Vergasung von Brennstaub-Wasser-Slurry oder Brennstaub-Öl-Slurry festen Brennstoffen im Flugstrom nach Anspruch 1 sowie ein Verfahren zur Durchführung in dieser Vorrichtung nach Anspruch 13 gelöst. Unteransprüche geben vorteilhafte Ausführungen der Erfindung wieder.This object is achieved by a device for the gasification of fuel dust-water slurry or fuel dust-oil slurry solid fuels in the entrained flow according to
Die Erfindung macht sich die Erkenntnis zu nutze, dass die Brennstoffzuführung zum Vergasungsreaktor einen Engpass für die Leistungsfähigkeit des Vergasungsreaktors bildet.The invention makes use of the knowledge that the fuel supply to the gasification reactor forms a bottleneck for the performance of the gasification reactor.
Das Vergasungsverfahren zur Vergasung von festen aschehaltigen Brennstoffen bei sehr hohen Leistungen mit einem sauerstoffhaltigen Oxidationsmittel basiert auf einem Flugstromreaktor dessen Reaktionsraumkontur durch ein Kühlsystem begrenzt wird, wobei der Druck im Kühlsystem immer höher gehalten wird als der Druck im Reaktionsraum. Für die Vorbereitung des Brennstoffes und die Zuführung zu den Vergasungsbrennern wird wie folgt verfahren: Bei trockener pneumatischer Zuführung nach dem Prinzip der Dichtstromförderung wird der Brennstoff getrocknet, auf eine Körnung < 200 µm zerkleinert und über Betriebsbunker Druckschleusen aufgegeben, in denen durch Zuführung eines nicht kondensierenden Gases wie N2 oder CO2 der staubförmige Brennstoff auf den gewünschten Vergasungsdruck gebracht wird. Es können dabei gleichzeitig verschiedene Brennstoffe eingesetzt werden. Durch Anordnung mehrerer dieser Druckschleusen kann abwechselnd befüllt und mit Druck beaufschlagt werden. Anschließend gelangt der unter Druck gesetzte Staub in Dosiergefäße, in denen im unteren Teil durch Zuführung gleichfalls eines nicht kondensierenden Gases eine sehr dichte Wirbelschicht erzeugt wird, in die ein oder mehrere Förderrohre eintauchen und in den Brennern des Vergasungsreaktors münden. Jedem Hochleistungsbrenner ist dabei ein separates Zuführungs- und Dosiersystem zugeordnet. Durch Anlegen einer Druckdifferenz zwischen den Dosiergefäßen und den Brennern des Vergasungsreaktors fließt der fluidisierte Brennstaub den Brennern zu. Durch Mess- und Überwachungseinrichtungen wird die strömende Brennstaubmenge gemessen, geregelt und überwacht.The gasification process for the gasification of solid ash-containing fuels at very high outputs with an oxygen-containing oxidizing agent is based on an entrained-flow reactor whose reaction space contour is limited by a cooling system, the pressure in the cooling system always being kept higher than the pressure in the reaction space. For the preparation of the fuel and the supply to the gasification burners, the procedure is as follows: In the case of a dry pneumatic supply based on the principle of dense phase conveyance, the fuel is dried, crushed to a grain size of <200 µm and pressure locks are fed into the operating bunker, in which a non-condensing feed is supplied Gas such as N2 or CO2 the dusty fuel is brought to the desired gasification pressure. Different fuels can be used at the same time. By arranging several of these pressure locks, filling and pressure can be applied alternately. The pressurized dust then enters metering vessels in which a very dense fluidized bed is created in the lower part by supplying a non-condensing gas as well, into which one or more delivery tubes are immersed and which open into the burners of the gasification reactor. Each high-performance burner is assigned a separate feed and metering system. By applying a pressure difference between the metering vessels and the burners of the gasification reactor, the fluidized fuel dust flows to the burners. The flowing amount of fuel dust is measured, regulated and monitored by measuring and monitoring devices.
Es besteht mit dem vorgeschlagenen Reaktor auch weiterhin die Möglichkeit, den ungetrockneten Brennstoff ebenfalls auf eine Körnung < 200 µm zu zerkleinern und den Brennstaub mit Wasser oder Öl zu vermischen und als Slurry den Brennern des Vergasungsreaktors zuzuführen. Das Verfahren zur Zuführung, welches an dieser Stelle nicht beschrieben ist, gestaltet der Fachmann nach den ihm bekannten Mitteln aus.With the proposed reactor there is still the possibility of also comminuting the undried fuel to a grain size of <200 μm and mixing the fuel dust with water or oil and supplying it to the burners of the gasification reactor as a slurry. The person skilled in the art designs the method for feeding, which is not described here, using the means known to him.
Den Brennern wird gleichzeitig ein freien Sauerstoff enthaltendes Oxidationsmittel aufgegeben und das Slurry durch partielle Oxidation in ein Rohsynthesegas überführt. Die Vergasung findet bei Temperaturen zwischen 1.200 und 1.900°C bei Drucken bis zu 80 bar statt. Der Reaktor besitzt eine gekühlte Reaktionsraumkontur, die durch einen Kühlschirm gebildet wird. Dieser besteht aus einem gasdicht verschweißten Rohrschirm, der bestiftet und mit einem gut temperaturleitfähigen Material belegt ist.An oxidizing agent containing free oxygen is simultaneously fed to the burners and the slurry is converted into a raw synthesis gas by partial oxidation. Gasification takes place at temperatures between 1,200 and 1,900 ° C at pressures up to 80 bar. The reactor has a cooled reaction space contour, which is formed by a cooling screen. This consists of a gas-tight welded tubular screen, which is pinned and covered with a highly temperature-conductive material.
Das im Vergasungsreaktor erzeugte Rohgas verlässt gemeinsam mit der aus der Brennstoffasche gebildeten flüssigen Schlacke den Vergasungsreaktor und gelangt in einen senkrecht darunter angeordneten Raum, in dem durch Einspritzen von Wasser eine Abkühlung des heißen Rohgases und der flüssigen Schlacke erfolgt. Die Abkühlung kann vollständig bis zum Taupunkt des Gases durch Einspritzen von Wasser im Überschuss erfolgen. In Abhängigkeit vom Druck liegt die Temperatur danach zwischen 180 und 240°C. Es ist jedoch auch möglich, nur eine begrenzte Kühlwassermenge zuzuführen und Rohgas und Schlacke durch eine Teilkühlung auf beispielsweise 700 bis 1.100°C abzukühlen, um anschließend in einem Abhitzekessel die fühlbare Wärme des Rohgases zur Dampferzeugung zu nutzen. Durch die Teilquenchung bzw. Teilkühlung wird die Gefahr des Anbackens von Schlacke an die Rohre des Abhitzekessels verhindert oder stark begrenzt. Das für die vollständige oder Teilkühlung erforderliche Wasser oder rückgeführte Gaskondensat wird über Düsen zugeführt, die sich direkt am Mantel des Kühlraumes befinden. Die abgekühlte Schlacke wird in einem Wasserbad gesammelt und aus dem Verfahren ausgeschleust. Das auf Temperaturen zwischen 200 bis 300°C abgekühlte Rohgas gelangt anschließend in eine Rohgaswäsche, die zweckmäßiger Weise als Venturiwäsche ausgebildet ist.The raw gas generated in the gasification reactor leaves the gasification reactor together with the liquid slag formed from the fuel ash and arrives in a space arranged vertically below, in which the hot raw gas and the liquid slag are cooled by injecting water. The cooling can take place completely up to the dew point of the gas by injecting excess water. Depending on the pressure, the temperature is then between 180 and 240 ° C. However, it is also possible to supply only a limited amount of cooling water and to cool the raw gas and slag by partial cooling to, for example, 700 to 1,100 ° C. in order to then use the sensible heat of the raw gas in a waste heat boiler to generate steam. The partial quenching or partial cooling prevents or severely limits the risk of slag caking on the pipes of the waste heat boiler. The water or recirculated gas condensate required for complete or partial cooling is supplied via nozzles that are located directly on the jacket of the cooling room. The cooled slag is collected in a water bath and removed from the process. The raw gas cooled to temperatures between 200 and 300 ° C. then passes into a raw gas scrubber, which is expediently designed as a venturi scrubber.
Hierbei wird der mitgeführte Staub bis zu einer Korngröße von ca. 20 µm entfernt. Dieser Reinheitsgrad reicht noch nicht aus, um anschließend katalytische Prozesse wie beispielsweise eine Rohgaskonvertierung durchzuführen. Dabei ist weiter zu bedenken, dass zusätzlich Salznebel im Rohgas mitgeführt werden, die während der Vergasung aus dem Brennstaub entbunden und mit dem Rohgas abgeführt werden. Um sowohl den Feinststaub < 20 µm als auch die Salznebel zu entfernen wird das gewaschene Rohgas einer Kondensationsstufe zugeführt, in der das Rohgas indirekt um 5 bis 10°C abgekühlt wird. Dabei wird aus dem wasserdampfgesättigten Rohgas Wasser kondensiert, das die beschriebenen feinen Staub- und Salzpartikel aufnimmt. In einem anschließenden Abscheider wird das die Staub- und Salzpartikel enthaltene kondensierte Wasser aus dem Rohgas entfernt. Das so gereinigte Rohgas kann danach direkt beispielsweise einer Entschwefelungsanlage zugeführt werden.The dust that is carried along is removed up to a grain size of approx. 20 µm. This degree of purity is not yet sufficient to subsequently carry out catalytic processes such as raw gas conversion. It should also be borne in mind that salt mist is also carried in the raw gas, which is released from the fuel dust during the gasification and removed with the raw gas. To remove both the fine dust <20 µm and the salt spray washed raw gas is fed to a condensation stage in which the raw gas is indirectly cooled by 5 to 10 ° C. Water is condensed from the water vapor-saturated raw gas and absorbs the fine dust and salt particles described. In a subsequent separator, the condensed water containing the dust and salt particles is removed from the raw gas. The raw gas purified in this way can then be fed directly, for example, to a desulfurization plant.
Im Folgenden wird die Erfindung an 5 Figuren und zwei Ausführungsbeispielen näher erläutert. Die Figuren zeigen:
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1 : Blockschema der Technologie -
2 : Dosiersystem für Brennstaub -
3 : Vorrichtung der Brennstaubzuführung für Hochleistungsgeneratoren -
4 : Vergasungsreaktor mit Vollquenchung -
5 : Vergasungsreaktor mit Teilquenchung
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1 : Block diagram of the technology -
2nd : Dosing system for fuel dust -
3rd : Device for supplying fuel dust for high-performance generators -
4th : Gasification reactor with full quenching -
5 : Gasification reactor with partial quenching
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Die
Die
An einem ersten Beispiel soll die Funktion anhand von Stoffströmen und verfahrenstechnischen Vorgängen erläutert werden:
- Einem Vergasungsreaktor mit einer Bruttoleistung von 1500 MW wird eine Kohlenstaubmenge von 240 Mg/h zugeführt. Dieser durch Trocknung und Mahlung aus Rohsteinkohle hergestellte Brennstaub besitzt einen
Feuchtigkeitsgehalt von 5,8%, einen Aschegehalt von 13 Ma% und einen Heizwert von 24.700 kJ/kg. Die Vergasung findet bei 1.550°C statt, die benötigte Sauerstoffmenge beträgt 208.000 m3 i. N./h. Die Rohkohle wird zunächst einer dem Stand der Technik entsprechende Trocknungs- und Mahlanlage zugeführt, in derder Wassergehalt auf 1,8 Ma% reduziert wird. Das nach der Mahlung vorhandene Körnungsband des aus der Rohkohle hergestellten Brennstaubes liegt zwischen 0 und 200 µm. Danach wird der gemahlene Brennstaub (1 ) dem Dosiersystem zugeführt, dessen Funktionsprinzip in2 gezeigt ist. Das Dosiersystem besteht aus drei gleichenEinheiten wie das 3 zeigt, wobei jede Einheit1 /3 der Gesamtstaubmenge, also 80 Mg/h, je einem Staubbrenner zuführt. Die drei dazugehörigen Staubbrenner befinden sich am Kopf des Vergasungsreaktors,dessen Prinzip 4 zeigt. Der einsatzfähige Brennstaub gelangt nach2 . die eine Einheit des Staubdosiersystems zeigt, aus dem Betriebsbunker1.1 in wechselseitig betriebene Druckschleusen1.2 . Injeder Einheit sind 3 Druckschleusen angeordnet. Die Aufpufferung auf den Vergasungsdruck geschieht mit einem inerten Gas wie beispielsweise Stickstoff, der über die Leitung1.6 zugeführt wird. Nach der Aufpufferung wird der unter Druck stehende Brennstaub dem Dosiergefäß1.3 zugeführt. Die Druckschleusen1.2 werden über die Leitung1.7 entspannt und können erneut mit Brennstaub befüllt werden.Die 3 genannten Druckschleusen in jeder Einheit werden wechselseitig befüllt, bespannt, in das Dosiergefäß entleert und entspannt. Danach beginnt dieser Vorgang erneut. Durch Zuführung eines als Fördergas dienenden trockenen Inertgases, beispielsweise gleichfalls Stickstoff über die Leitung1.5 wird im Unterteil des Dosiergefäßes1.3 eine dichte Wirbelschicht erzeugt, indie 3 Staubförderleitungen1.4 hineinragen. Die in den Förderleitungen1.4 fließende Brennstaubmenge wird überwacht, gemessen und in Relation zum Vergasungssauerstoff geregelt.Der Vergasungsreaktor 2 ist in3 gezeigt und näher erläutert. Die Förderdichte beträgt 250-420 kg/m3.Der Vergasungsreaktor 2 ist in3 gezeigt und näher erläutert. Der über die Förderleitungen1.4 dem Vergasungsreaktor 2 zufließende Brennstaub wird (3 ) in 3 Dosiersysteme mit einer Kapazität von je 80 Mg/h geschleust. Die insgesamt 9 Förderleitungen1.4 führen jeweils in Dreiergruppen zu 3 am Kopf desReaktors 2 angeordneten Vergasungsbrennern4.1 . Gleichzeitig werden jedem Vergasungsbrenner1 /3 der Gesamtsauerstoffmenge von 208.000 Nm3/h zugeführt. Die Staubbrenner sind symmetrisch im Winkel von 120° angeordnet, im Zentrum befindet sich ein Zünd- und Pilotbrenner, der dem Aufheizen desVergasungsreaktors 2 und der Zündung des Staubbrenners4.1 dient. Im Vergasungsraum2.3 , der sich durch eine gekühlte Reaktionsraumkontur2.4 auszeichnet, findet die Vergasungsreaktion, also die partielle Oxidation bei Temperaturen von 1.550°C statt. Die überwachten und gemessenen Brennstaubmengen werden einer Verhältnisregelung mit dem zugeführten Sauerstoffe unterzogen, die dafür sorgt, dass das Verhältnis von Sauerstoff zu Brennstoff einen Bereich von λ = 0,35 bis 0,65 nicht unter- oder überschreitet. Der λ-Wert stellt dabei das Verhältnis der benötigten Sauerstoffmenge bei der gewünschten Partialoxidation zu der Sauerstoffmenge dar, die bei vollständiger Verbrennung des eingesetzten Brennstoffes erforderlich wäre. Die entstandene Rohgasmenge beträgt 463 000 Nm3/h und zeichnet sich durch folgende Analyse aus:
- A coal dust quantity of 240 mg / h is fed to a gasification reactor with a gross output of 1500 MW. This fuel is made from raw coal by drying and grinding and has a moisture content of 5.8%, an ash content of 13% and a calorific value of 24,700 kJ / kg. The gasification takes place at 1,550 ° C, the amount of oxygen required is 208,000 m 3 i. N./h. The raw coal is first fed to a drying and grinding plant corresponding to the state of the art, in which the water content is reduced to 1.8% by mass. The grain size range of the fuel dust produced from the raw coal after grinding is between 0 and 200 µm. Then the ground fuel dust (
1 ) fed to the dosing system, the principle of which is described in2nd is shown. The dosing system consists of three identical units as that3rd shows, eachunit 1 /3rd the total amount of dust, i.e. 80 mg / h, is fed to a dust burner. The three associated dust burners are located on the head of the gasification reactor, its principle4th shows. The usable fuel dust arrives2nd . which shows a unit of the dust dosing system, from the operating bunker1.1 in mutually operated pressure locks1.2 . 3 pressure locks are arranged in each unit. Buffering to the gasification pressure takes place with an inert gas such as nitrogen, which is supplied via the line1.6 is fed. After the buffering, the fuel dust under pressure is transferred to the dosing vessel1.3 fed. The pressure locks1.2 be over the line1.7 relaxed and can be refilled with fuel dust. The3rd Pressure locks in each unit are alternately filled, covered, emptied into the metering vessel and relaxed. Then this process starts again. By supplying a dry inert gas which serves as the conveying gas, for example likewise nitrogen, via the line1.5 is in the lower part of the dosing vessel1.3 creates a dense fluidized bed in the 3 dust conveyor lines1.4 protrude. The in the delivery lines1.4 Flowing amount of fuel dust is monitored, measured and regulated in relation to the gasification oxygen. The gasification reactor2nd is in3rd shown and explained in more detail. The delivery density is 250-420 kg / m 3 . The gasification reactor2nd is in3rd shown and explained in more detail. The over the delivery lines1.4 the gasification reactor2nd incoming fuel dust is (3rd ) in 3 dosing systems with a capacity of 80 mg / h each. The total of 9 delivery lines1.4 lead in groups of three to 3 at the top of the reactor2nd arranged gasification burners4.1 . At the same time, everygasification burner 1 /3rd the total amount of oxygen of 208,000 Nm 3 / h supplied. The dust burners are arranged symmetrically at an angle of 120 °, in the center there is an ignition and pilot burner, which is used to heat the gasification reactor2nd and the ignition of the dust burner4.1 serves. In the gasification room2.3 , which is characterized by a cooled reaction chamber contour2.4 distinguished, the gasification reaction, i.e. the partial oxidation takes place at temperatures of 1,550 ° C. The monitored and measured amounts of fuel dust are subjected to a ratio control with the supplied oxygen, which ensures that the ratio of oxygen to fuel does not fall below or exceed a range of λ = 0.35 to 0.65. The λ value represents the ratio of the amount of oxygen required for the desired partial oxidation to the amount of oxygen that would be required if the fuel used were completely combusted. The resulting raw gas volume is 463,000 Nm 3 / h and is characterized by the following analysis:
Das
Nach einem Beispiel 2 soll der Vorgang der Brennstaubzuführung nach
BezugszeichenlisteReference list
- 11
- Pneumatische Dosiersysteme für BrennstaubPneumatic dosing systems for fuel dust
- 1.11.1
- Bunkerbunker
- 1.21.2
- DruckschleusePressure lock
- 1.31.3
- DosiergefäßDosing vessel
- 1.41.4
- FörderleitungConveyor line
- 1.51.5
- Leitung für WirbelgasLine for fluidizing gas
- 1.61.6
-
Leitung für Inertgas in
1.2 Line for inert gas in1.2 - 1.71.7
-
Entspannungsleitung aus
1.2 Relaxation line1.2 - 22nd
- Vergasungsreaktor mit gekühlter ReaktionsraumstrukturGasification reactor with a cooled reaction chamber structure
- 2.12.1
- Staubbrenner mit SauerstoffzuführungDust burner with oxygen supply
- 2.22.2
- Zünd- und PilotbrennerPilot and pilot burner
- 2.32.3
- VergasungsraumGasification room
- 2.42.4
- KühlschirmCooling screen
- 2.52.5
- AustrittsöffnungOutlet opening
- 33rd
- QuenchkühlerQuench cooler
- 3.13.1
- QuenchraumQuench room
- 3.23.2
- QuenchdüsenQuench nozzles
- 3.33.3
- QuenchdüsenQuench nozzles
- 3.43.4
- RohgasabgangRaw gas outlet
- 3.53.5
- Wasserbad mit SchlackeWater bath with slag
- 3.63.6
-
Unterer Abgang von
3 Lower exit from3rd - 3.73.7
- Auskleidunglining
- 44th
- RohgaswäscheRaw gas scrubbing
- 4.14.1
- AbhitzekesselWaste heat boiler
- 55
- Kondensation, TeilkondensationCondensation, partial condensation
Claims (21)
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DE102005048488.3A DE102005048488C5 (en) | 2005-10-07 | 2005-10-07 | Method and device for high power entrained flow gasifiers |
CN2005101272860A CN1944593B (en) | 2005-10-07 | 2005-12-05 | Method and device for high-capacity entrained flow gasifier |
CA002534407A CA2534407A1 (en) | 2005-10-07 | 2006-01-26 | Method and device for high-capacity entrained flow gasifier |
US11/359,608 US20070079554A1 (en) | 2005-10-07 | 2006-02-22 | Method and device for high-capacity entrained flow gasifier |
AU2006201142A AU2006201142B2 (en) | 2005-10-07 | 2006-03-20 | Method and device for high-capacity entrained flow gasifier |
DE102006029595.1A DE102006029595B4 (en) | 2005-10-07 | 2006-06-26 | Method for high current jet carburettor |
ZA2006/07404A ZA200607404B (en) | 2005-10-07 | 2006-09-05 | Method and device for high-capacity entrained flow gasifier |
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DE102005048488.3A Expired - Fee Related DE102005048488C5 (en) | 2005-10-07 | 2005-10-07 | Method and device for high power entrained flow gasifiers |
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- 2005-10-07 DE DE202005021659U patent/DE202005021659U1/en not_active Expired - Lifetime
- 2005-10-07 DE DE102005048488.3A patent/DE102005048488C5/en not_active Expired - Fee Related
- 2005-12-05 CN CN2005101272860A patent/CN1944593B/en not_active Expired - Fee Related
-
2006
- 2006-01-26 CA CA002534407A patent/CA2534407A1/en not_active Abandoned
- 2006-02-22 US US11/359,608 patent/US20070079554A1/en not_active Abandoned
- 2006-03-20 AU AU2006201142A patent/AU2006201142B2/en not_active Ceased
- 2006-06-26 DE DE102006029595.1A patent/DE102006029595B4/en not_active Expired - Fee Related
- 2006-09-05 ZA ZA2006/07404A patent/ZA200607404B/en unknown
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Also Published As
Publication number | Publication date |
---|---|
DE202005021659U1 (en) | 2010-01-14 |
DE102005048488B4 (en) | 2009-07-23 |
CA2534407A1 (en) | 2007-04-07 |
ZA200607404B (en) | 2008-01-08 |
DE102006029595A1 (en) | 2007-12-27 |
CN1944593B (en) | 2011-11-23 |
US20070079554A1 (en) | 2007-04-12 |
CN1944593A (en) | 2007-04-11 |
DE102005048488A1 (en) | 2007-05-03 |
DE102006029595B4 (en) | 2018-04-19 |
AU2006201142B2 (en) | 2011-07-21 |
AU2006201142A1 (en) | 2007-04-26 |
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