DE10163765A1 - Device for producing hydrogen-containing gas mixture made from water or aqueous solution comprises reaction vessel, permanent magnets arranged in base of vessel - Google Patents

Device for producing hydrogen-containing gas mixture made from water or aqueous solution comprises reaction vessel, permanent magnets arranged in base of vessel

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Publication number
DE10163765A1
DE10163765A1 DE10163765A DE10163765A DE10163765A1 DE 10163765 A1 DE10163765 A1 DE 10163765A1 DE 10163765 A DE10163765 A DE 10163765A DE 10163765 A DE10163765 A DE 10163765A DE 10163765 A1 DE10163765 A1 DE 10163765A1
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reaction vessel
water
vessel
aqueous solution
permanent magnets
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DE10163765A
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KESER OSMAN
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KESER OSMAN
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/10—Mixing gases with gases
    • B01F23/14—Mixing gases with gases with moving mixing elements, e.g. with liquid seal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
    • B01F23/2336—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer
    • B01F23/23362—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements characterised by the location of the place of introduction of the gas relative to the stirrer the gas being introduced under the stirrer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/55—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers driven by the moving material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • B01F27/90—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms 
    • B01F27/906—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with paddles or arms  with fixed axis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/05—Mixers using radiation, e.g. magnetic fields or microwaves to mix the material
    • B01F33/053—Mixers using radiation, e.g. magnetic fields or microwaves to mix the material the energy being magnetic or electromagnetic energy, radiation working on the ingredients or compositions for or during mixing them
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/45—Magnetic mixers; Mixers with magnetically driven stirrers
    • B01F33/453—Magnetic mixers; Mixers with magnetically driven stirrers using supported or suspended stirring elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/45—Magnetic mixers; Mixers with magnetically driven stirrers
    • B01F33/453—Magnetic mixers; Mixers with magnetically driven stirrers using supported or suspended stirring elements
    • B01F33/4531—Magnetic mixers; Mixers with magnetically driven stirrers using supported or suspended stirring elements using an axis supported in several points for mounting the stirring element
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80—Mixing plants; Combinations of mixers
    • B01F33/836—Mixing plants; Combinations of mixers combining mixing with other treatments
    • B01F33/8362—Mixing plants; Combinations of mixers combining mixing with other treatments with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/05—Stirrers
    • B01F27/11—Stirrers characterised by the configuration of the stirrers
    • B01F27/19—Stirrers with two or more mixing elements mounted in sequence on the same axis
    • B01F27/192—Stirrers with two or more mixing elements mounted in sequence on the same axis with dissimilar elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/30—Driving arrangements; Transmissions; Couplings; Brakes
    • B01F35/32—Driving arrangements
    • B01F35/32005—Type of drive
    • B01F35/32015—Flow driven
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/085—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy creating magnetic fields
    • B01J2219/0852—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy creating magnetic fields employing permanent magnets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/085—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy creating magnetic fields
    • B01J2219/0862—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy creating magnetic fields employing multiple (electro)magnets
    • B01J2219/0866—Four (electro)magnets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0884—Gas-liquid

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Mixers With Rotating Receptacles And Mixers With Vibration Mechanisms (AREA)

Abstract

Device for producing a hydrogen-containing gas mixture comprises a reaction vessel partially filled with water or an aqueous solution, several permanent magnets arranged in the base of the vessel to pass a magnetic field through the solution, and a stirring arrangement for rapidly moving liquid in the vessel and having a product outlet arranged at the top of the vessel. Device for producing a hydrogen-containing gas mixture made from water or an aqueous solution comprises a reaction vessel (1) partially filled with water or an aqueous solution, several permanent magnets (6) arranged in the base of the vessel to pass a magnetic field through the solution, and a stirring arrangement (7-10) for rapidly moving liquid in the vessel and having a product outlet (11) arranged at the top of the vessel.

Description

Die Erfindung betrifft eine Vorrichtung zur Erzeugung eines wasserstoffhaltigen Gasgemisches aus Wasser oder einer wässsrigen Lösung. The invention relates to a device for producing a hydrogen-containing Gas mixture from water or an aqueous solution.

Nach dem Stand der Technik ist es üblich, im Wege der Elektrolyse Wasserstoff oder wasserstoffhaltige Gasgemische herzustellen. Dabei befindet sich das Wasser oder die wässsrige Lösung in einem Elektrolysegefäß mit zwei in die Flüssigkeit eintauchenden Elektroden, an denen eine Gleichspannung angelegt wird. Unter dem Einfluß des dann fließenden elektrischen Stroms findet eine Dissoziation in Wasserstoff und Sauerstoff statt, so daß aus dem Gefäß ein wasserstoffhaltiges Gasgemisch, z. B. Knallgas abgezogen werden kann. According to the prior art, it is common to use hydrogen to electrolysis or to produce hydrogen-containing gas mixtures. This is where Water or the aqueous solution in an electrolysis vessel with two in the Liquid immersed electrodes to which a DC voltage is applied becomes. Under the influence of the electrical current then flowing, one finds Dissociation in hydrogen and oxygen takes place, leaving one in the vessel hydrogen-containing gas mixture, e.g. B. detonating gas can be withdrawn.

Es ist Aufgabe der Erfindung, einen völlig neuen und effektiveren Weg zur Erzeugung von Wasserstoff aus Wasser oder einer wässsrigen Lösung aufzuzeigen. It is an object of the invention to develop a completely new and more effective way Generation of hydrogen from water or an aqueous solution show.

Gegenstand der Erfindung ist eine Vorrichtung zur Erzeugung eines wasserstoffhaltigen Gasgemisches aus Wasser oder einer wässsrigen Lösung, welche gekennzeichnet ist durch

  • - ein teilweise mit Wasser oder einer wässsrigen Lösung gefülltes Reaktionsgefäß,
  • - mehrere im Boden des Reaktionsgefäßes angeordnete Permanentmagnete, deren Magnetfelder die wässsrige Lösung durchsetzen,
  • - eine Rührvorrichtung für die Erzeugung einer schnellen Flüssigkeitsbewegung in dem Reaktionsgefäß,
  • - und einen oben am Reaktionsgefäß befindlichen Produktgasauslaß.
The invention relates to a device for producing a hydrogen-containing gas mixture from water or an aqueous solution, which is characterized by
  • a reaction vessel partially filled with water or an aqueous solution,
  • several permanent magnets arranged in the bottom of the reaction vessel, the magnetic fields of which penetrate the aqueous solution,
  • a stirring device for generating a rapid liquid movement in the reaction vessel,
  • - And a product gas outlet located at the top of the reaction vessel.

Die Erfinder haben überraschenderweise herausgefunden, daß die Dissoziation von Wasser in Wasserstoff und Sauerstoff auch gelingt, wenn man Wasser oder eine wässsrige Lösung schnell durch das stehende Magnetfeld von Permanentmagneten bewegt. Der physikalisch-chemische Vorgang als solcher ist noch nicht geklärt. Dennoch haben die Erfinder festgestellt, daß verhältnismäßig große Mengen eines wasserstoffhaltigen Gases entstehen, wenn man entsprechend der Erfindung verfährt. The inventors surprisingly found that the dissociation of water in hydrogen and oxygen also succeeds if you use water or an aqueous solution quickly through the standing magnetic field of Permanent magnet moves. The physico-chemical process as such has not yet been resolved. Nevertheless, the inventors have found that relatively large amounts of a hydrogen-containing gas are produced, if one proceeds according to the invention.

Zweckmäßig ist das Reaktionsgefäß zylindrisch ausgebildet, wobei die Permanentmagnete im Boden des Reaktionsgefäßes kreisringförmig um die Zylinderachse des Reaktionsgefäßes angeordnet sind und das Rührwerkzeug eine schnelle Drehbewegung um die Zylinderachse des Reaktionsgefäßes erzeugt. Bei dieser geometrischen Konfiguration ist es möglich, eine schnelle Relativbewegung zwischen der Flüssigkeit und dem Magnetfeld der Permanentmagneten herzustellen. The reaction vessel is expediently cylindrical, the Permanent magnets in the bottom of the reaction vessel in a ring around the Cylinder axis of the reaction vessel are arranged and the stirring tool a rapid rotary movement around the cylinder axis of the reaction vessel generated. With this geometric configuration it is possible to have a quick one Relative movement between the liquid and the magnetic field of the Manufacture permanent magnets.

Die Erzeugung des wasserstoffhaltigen Gasgemisches wird noch erheblich intensiviert, wenn das Reaktionsgefäß unten mit einem Gaszuführungsanschluß versehen ist, über welchen dem Reaktionsgefäß das Abgas eines Verbrennungsmotors zugeführt wird, welches in fein verteilter Form in die im Reaktionsgefäß befindliche Flüssigkeit eingeperlt wird. Die Erfinder haben beobachtet, daß man die Leistung eines Verbrennungsmotors, beispielsweise in einem Kraftfahrzeug, erheblich dadurch steigern kann, daß man ein derartiges Reaktionsgefäß in einen Teilabgasstrom des Motors legt und das entstehende Gasgemisch in den Ansaugstrom des Motors zurückführt. The generation of the hydrogen-containing gas mixture is still considerable intensified when the reaction vessel bottom with a gas supply connection is provided, via which the exhaust gas of a Combustion engine is supplied, which in a finely divided form in the Liquid in the reaction vessel is bubbled in. The inventors have observed that the performance of an internal combustion engine, for example in a motor vehicle, can significantly increase in that one Place the reaction vessel in a partial exhaust gas stream of the engine and the resulting Leads the gas mixture back into the intake flow of the engine.

Um das bei der Gaserzeugung verbrauchte Wasser zu ersetzen, ist vorgesehen, daß das Reaktionsgefäß mit einem Wasserzuführungsanschluß versehen ist, über welchen dem Reaktionsgefäß Wasser oder eine wässsrige Lösung zugeführt wird. In order to replace the water used in gas generation, that the reaction vessel is provided with a water supply connection, over which the reaction vessel is water or an aqueous solution is fed.

Um die Wassermenge in dem Reaktionsgefäß konstant zu halten, ist weiterhin vorgesehen, daß der Wasserzuführungsanschluß mit einem Mengenregler versehen ist. In order to keep the amount of water in the reaction vessel constant, is still provided that the water supply connection with a flow regulator is provided.

Der erforderliche Rührvorgang in dem Reaktionsgefäß wird auf einfache Weise dadurch bewerkstelligen, daß das Rührwerkzeug der Rührvorrichtung von einem Flügelrad angetrieben ist, welches von dem durchtretenden Abgas in Drehung versetzt wird. The required stirring process in the reaction vessel is simple in that the stirring tool of the stirring device of an impeller which is driven by the exhaust gas passing through Rotation is offset.

Ein Ausführungsbeispiel der Erfindung wird im folgenden anhand der Zeichnung näher erläutert, die eine Vorrichtung gemäß der Erfindung schematisch darstellt. An embodiment of the invention is described below with reference to the drawing explained in more detail, which schematically represents a device according to the invention.

In der Zeichnung ist ein zylindrisches Reaktionsgefäß mit dem Bezugszeichen 1 bezeichnet. Das Reaktionsgefäß 1 ist unten zum Teil mit einer Flüssigkeit 2 gefüllt, die aus Wasser oder einer wässsrigen Lösung besteht. In the drawing, a cylindrical reaction vessel is designated by the reference number 1 . The reaction vessel 1 is partially filled at the bottom with a liquid 2 consisting of water or an aqueous solution.

In einer Seitenwand des Reaktionsgefäßes 1 befindet sich ein Wasserzuführungsanschluß 3, über den das Reaktionsgefäß 1 geregelt mit Wasser oder einer wässsrigen Lösung versorgt wird, und zwar derart, daß der Flüssigkeitsspiegel ständig etwa gleich hoch bleibt. In a side wall of the reaction vessel 1 there is a water supply port 3 is regulated is supplied with water or a solution wässsrigen through which the reaction vessel 1, in such a manner that the liquid level constantly remains about the same.

Unten im Boden des Reaktionsgefäßes 1 befindet sich ein Gaszuführungsanschluß 4, über den beispielsweise ein Teil-Abgasstrom eines Otto-Motors zugeführt wird. Dieses Abgas gelangt über eine Lochplatte 5 in fein verteilter Form in die Flüssigkeit 2 und steigt durch diese hindurch nach oben. At the bottom in the bottom of the reaction vessel 1 there is a gas supply connection 4 , via which, for example, a partial exhaust gas stream of an Otto engine is supplied. This exhaust gas enters the liquid 2 via a perforated plate 5 in finely divided form and rises through it.

Im Boden des Reaktionsgefäßes 1 unterhalb der Lochplatte 5 befinden sich mehrere Permanentmagnete 6, die ringförmig mit gleichem Abstand zur Zylinderwand des Reaktionsgefäßes 1 angeordnet sind und deren Magnetfelder die Flüssigkeit 2 durchsetzen. In the bottom of the reaction vessel 1 below the perforated plate 5 there are a plurality of permanent magnets 6 which are arranged in a ring at the same distance from the cylinder wall of the reaction vessel 1 and whose magnetic fields penetrate the liquid 2 .

Unterhalb der Oberfläche der Flüssigkeit 2 befindet sich ein drehend angetriebenes Rührwerkzeug 7, welches auf einer Rührwelle 8 sitzt, welche oben und unten in Lagern 9a und 9b gelagert ist. Auf der Rührwelle 8 sitzt weiter oben ein Flügelrad 10, welches von dem aufsteigenden Gas in Drehbewegung versetzt wird und damit das Rührwerkzeug 7 antreibt. Mittels des Rührwerkzeuges 7 wird die Flüssigkeit 2 in eine schnelle Drehbewegung versetzt. Below the surface of the liquid 2 there is a rotating driven stirring tool 7 , which is seated on a stirring shaft 8 , which is mounted above and below in bearings 9 a and 9 b. On the agitator shaft 8 sits an impeller 10 , which is set in rotation by the rising gas and thus drives the agitator 7 . The liquid 2 is set into a rapid rotary movement by means of the stirring tool 7 .

Im Deckel des Reaktionsgefäßes 1 befindet sich ein Produktgasauslaß 11, über den das erzeugte Gasgemisch das Reaktionsgefäß 1 verläßt. In the lid of the reaction vessel 1 there is a product gas outlet 11 , via which the gas mixture generated leaves the reaction vessel 1 .

Beim Betrieb der Vorrichtung treibt das durchtretende Abgas, welches mit dem durch Dissoziation von Wasser erzeugten Wasserstoff angereichert ist, über das Flügelrad 10 das Rührwerkzeug 7 und damit die Flüssigkeit 2 zu einer schnellen Drehbewegung um die Zylinderachse des Reaktionsgefäßes 1 an. Durch die Relativbewegung zwischen dem schnell wirbelnden Wasser-Gas-Gemisch und den Magnetfeldern der Permanentmagnete 6 wird in erheblichem Umfang Wasserstoff erzeugt, welcher das durchtretende Abgas anreichert. When the device is in operation, the exhaust gas passing through, which is enriched with the hydrogen generated by dissociation of water, drives the stirring tool 7 and thus the liquid 2 via the impeller 10 to make a rapid rotary movement about the cylinder axis of the reaction vessel 1 . The relative movement between the rapidly swirling water-gas mixture and the magnetic fields of the permanent magnets 6 generates a considerable amount of hydrogen, which enriches the exhaust gas that passes through.

Claims (6)

1. Vorrichtung zur Erzeugung eines wasserstoffhaltigen Gasgemisches aus Wasser oder einer wässsrigen Lösung, gekennzeichnet durch
ein teilweise mit Wasser oder einer wässsrigen Lösung gefülltes Reaktionsgefäß (1),
mehrere im Boden des Reaktionsgefäßes (1) angeordnete Permanentmagnete (6), deren Magnetfelder die wässsrige Lösung durchsetzen,
eine Rührvorrichtung (7-10) für die Erzeugung einer schnellen Flüssigkeitsbewegung im Reaktionsgefäß (1)
und einen oben am Reaktionsgefäß (1) befindlichen Produktgasauslaß (11). 1. Device for generating a hydrogen-containing gas mixture from water or an aqueous solution, characterized by
a reaction vessel ( 1 ) partially filled with water or an aqueous solution,
a plurality of permanent magnets ( 6 ) arranged in the bottom of the reaction vessel ( 1 ), the magnetic fields of which penetrate the aqueous solution,
a stirring device ( 7-10 ) for generating a rapid liquid movement in the reaction vessel ( 1 )
and a product gas outlet ( 11 ) located at the top of the reaction vessel ( 1 ). 2. Vorrichtung nach Anspruch 1, dadurch gekennzeichnet, daß das Reaktionsgefäß (1) zylindrisch ausgebildet ist, daß die Permanentmagnete (6) im Boden des Reaktionsgefäßes (1) kreisringförmig um die Zylinderachse des Reaktionsgefäßes (1) angeordnete sind und daß die Rührvorrichtung (7-10) eine schnelle Drehbewegung um die Zylinderachse des Reaktionsgefäßes (1) erzeugt. 2. Device according to claim 1, characterized in that the reaction vessel (1) is cylindrical, that the permanent magnets (6) are annularly arranged around the cylinder axis of the reaction vessel (1) in the bottom of the reaction vessel (1) and that the stirring device (7 -10 ) generates a rapid rotary movement around the cylinder axis of the reaction vessel ( 1 ). 3. Vorrichtung nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, daß das Reaktionsgefäß (1) und den mit einem Gaszuführungsanschluß (4) versehen ist, über welchen dem Reaktionsgefäß (1) das Abgas eines Verbrennungsmotors zugeführt wird, welches in fein verteilter Form in die im Reaktionsgefäß (1) befindliche Flüssigkeit (2) eingeperlt wird. 3. Device according to claims 1 and 2, characterized in that the reaction vessel ( 1 ) and which is provided with a gas supply connection ( 4 ) via which the reaction vessel ( 1 ) is supplied with the exhaust gas of an internal combustion engine, which in finely divided form in the liquid ( 2 ) in the reaction vessel ( 1 ) is bubbled in. 4. Vorrichtung nach den Ansprüchen 1 bis 3, dadurch gekennzeichnet, daß das Reaktionsgefäß (1) mit einem Wasserzuführungsanschluß (3) versehen ist, über welchen dem Reaktionsgefäß (1) Wasser oder eine wässsrige Lösung zugeführt wird. 4. Device according to claims 1 to 3, characterized in that the reaction vessel ( 1 ) is provided with a water supply connection ( 3 ) through which the reaction vessel ( 1 ) is supplied with water or an aqueous solution. 5. Vorrichtung nach den Ansprüchen 1 bis 4, dadurch gekennzeichnet, daß der Wasserzuführungsanschluß (3) mit einem Mengenregler versehen ist. 5. Device according to claims 1 to 4, characterized in that the water supply connection ( 3 ) is provided with a flow regulator. 6. Vorrichtung nach den Ansprüchen 1 bis 5, dadurch gekennzeichnet, daß das Rührwerkzeug (7) der Rührvorrichtung (7-10) von einem Flügelrad (10) angetrieben ist, welches von dem durchtretenden Abgas in Drehung versetzt wird. 6. Device according to claims 1 to 5, characterized in that the stirring tool ( 7 ) of the stirring device ( 7-10 ) is driven by an impeller ( 10 ) which is caused to rotate by the exhaust gas passing through.
DE10163765A 2001-12-27 2001-12-27 Device for producing hydrogen-containing gas mixture made from water or aqueous solution comprises reaction vessel, permanent magnets arranged in base of vessel Withdrawn DE10163765A1 (en)

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CN116712956B (en) * 2023-06-08 2023-11-17 唐山明州科技有限公司 Energy-saving sulfonation reaction kettle for reactive dye production

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