DE100236C - - Google Patents
Info
- Publication number
- DE100236C DE100236C DENDAT100236D DE100236DA DE100236C DE 100236 C DE100236 C DE 100236C DE NDAT100236 D DENDAT100236 D DE NDAT100236D DE 100236D A DE100236D A DE 100236DA DE 100236 C DE100236 C DE 100236C
- Authority
- DE
- Germany
- Prior art keywords
- metals
- phosphorus
- iron
- dephosphorization
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 150000002739 metals Chemical class 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 7
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 240000002989 Euphorbia neriifolia Species 0.000 claims description 2
- 229910052771 Terbium Inorganic materials 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- -1 didym Chemical compound 0.000 claims description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 10
- 239000011574 phosphorus Substances 0.000 description 9
- 229910052698 phosphorus Inorganic materials 0.000 description 9
- OFJATJUUUCAKMK-UHFFFAOYSA-N Cerium(IV) oxide Chemical compound [O-2]=[Ce+4]=[O-2] OFJATJUUUCAKMK-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 229910000420 cerium oxide Inorganic materials 0.000 description 2
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052590 monazite Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UXBZSSBXGPYSIL-UHFFFAOYSA-N phosphoric acid;yttrium(3+) Chemical compound [Y+3].OP(O)(O)=O UXBZSSBXGPYSIL-UHFFFAOYSA-N 0.000 description 2
- 229910000164 yttrium(III) phosphate Inorganic materials 0.000 description 2
- 229910000722 Didymium Inorganic materials 0.000 description 1
- 241000224487 Didymium Species 0.000 description 1
- 230000036826 Excretion Effects 0.000 description 1
- 241000530268 Lycaena heteronea Species 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 240000001987 Pyrus communis Species 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- FZTWZIMSKAGPSB-UHFFFAOYSA-N phosphide(3-) Chemical compound [P-3] FZTWZIMSKAGPSB-UHFFFAOYSA-N 0.000 description 1
- 229910000499 pig iron Inorganic materials 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/064—Dephosphorising; Desulfurising
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
KLASSE 18: Eisenerzeugung.CLASS 18: Ironmaking.
JOHN GORDON in RIO DE JANEIRO. Verfahren zur Entphosphorung von Eisen und anderen Metallen. JOHN GORDON in RIO DE JANEIRO. Process for dephosphorization of iron and other metals.
Patentirt im Deutschen Reiche vom 17. Mai 1898 ab.Patented in the German Empire on May 17, 1898.
Vorliegende Erfindung bezweckt in erster Linie die Entfernung des Phosphors aus Eisen, kann jedoch auch zur Entphosphorung anderer Metalle, z. B. Kupfer, in Anwendung gebracht werden.The present invention is primarily intended to remove phosphorus from iron, however, it can also be used for dephosphorization of other metals, e.g. B. copper, brought into use will.
Der Erfinder hat beobachtet, dafs der Phosphor in Gesteinen, Schlacken u. s. w. vorzugsweise in Verbindung mit den seltenen Erden und deren Metallen vorkommt, indem er Monazit, Xenotim und andere ähnliche Phosphate bildet.The inventor has observed that phosphorus is preferred in rocks, slag, and so on occurs in connection with the rare earths and their metals by monazite, Forms xenotime and other similar phosphates.
Er hat ferner gefunden, dafs es möglich ist, bei der Stahlerzeugung nach dem basischen Verfahren diejenigen Phosphorreste, welche sich nicht mit dem Kalk verbinden, sondern in dem geschmolzenen Metall zurückbleiben, ganz oder theilweise mit Hülfe der seltenen Erden bezw. ihrer Metalle oder deren Carbide, Fluoride, Cyanide, Silicate oder anderer solcher Metallsalze oder mit Mischungen dieser Körper zu entfernen. Diese Wirkung beruht darauf, dafs die Oxyde der seltenen Erden, insbesondere Ceroxyd, stärker basisch sind bezw. eine gröfsere Affinität zum Phosphor bezw. der Phosphorsäure haben, als Kalk.He has also found that it is possible to use basic steel in steel-making Process those phosphorus residues that do not combine with the lime, but remain in the molten metal, wholly or partly with the aid of the rare ones Earth resp. their metals or their carbides, fluorides, cyanides, silicates or other such To remove metal salts or mixtures of these bodies. This effect is based on that the oxides of the rare earths, in particular cerium oxide, are more basic or. one greater affinity for phosphorus respectively. of phosphoric acid than lime.
Die vorliegende Erfindung besteht demnach darin, das geschmolzene phosphorhaltige Metall mit seltenen Erden, deren Metallen oder den oben erwähnten Verbindungen zwecks Entphosphorung in Berührung zu bringen.The present invention thus consists in the molten phosphorus-containing metal with rare earths, their metals or the compounds mentioned above for the purpose of dephosphorization to bring in touch.
Bekanntlich werden unter der Bezeichnung »seltene Erden« die Oxyde des Cer, Thor, Lanthan, Didym, Erbium, Terbium, Yttrium u. s. w. zusammengefafst, welche hauptsächlich in den Mineralen Monazit, Xenotim und anderen Phosphaten vorkommen. Die erwähnten Metalle werden auch als die Metalle der Cergruppe bezeichnet.It is well known that the oxides of cerium, thor, Lanthanum, didymium, erbium, terbium, yttrium, etc., summarized, which mainly occur in the minerals monazite, xenotime and other phosphates. The mentioned Metals are also referred to as the metals of the cerium group.
Bei der Entphosphorung von Stahl oder Eisen wird das geschmolzene Metall mit den Oxyden der vorbenannten seltenen Erden oder diesen Elementen selbst oder mit den Carbiden in Berührung gebracht. Eine solche Behandlung des Eisens oder Stahls ist sowohl beim basischen He,rdprocefs als auch beim basischen Bessemerprocefs anwendbar. Zu dem genannten Zwecke können als entphosphorende Agenden auch Legirungen oder Verbindungen der genannten Metalle der Cergruppe bezw. deren Carbide mit Eisen oder mit Eisen und Magnesium (Ferromagnesium) in Anwendung gebracht werden, und es hat sich gezeigt, dafs gerade bei Verwendung solcher Verbindungen die vollständige Ausscheidung des Phosphors bezw. die Verschlackung der Phosphate und Phosphide vor sich geht.When steel or iron is dephosphorized, the molten metal is mixed with the Oxides of the aforementioned rare earths or these elements themselves or with the carbides brought into contact. Such treatment of iron or steel is both at basic He, rdprocefs as well as the basic Bessemerprocefs applicable. To the above Purposes can bezw as dephosphoric agendas also alloys or compounds of the mentioned metals of the cerium group. their carbides with iron or with iron and magnesium (ferromagnesium) in use and it has been shown that it is precisely when such compounds are used the complete excretion of phosphorus bezw. the slagging of phosphates and Phosphide is going on.
Natürlich hängt die Menge des zur Entphosphorung dienenden Mittels von dem Phosphorgehalte des zu reinigenden Metalles und von der chemischen Zusammensetzung des Mittels selbst ab. Wenn z. B. beim Roheisen der Procentsatz an Phosphor durch die Analyse bestimmt ist, kann die erforderliche Menge des Zuschlagmittels vom Hüitenchemiker leicht bestimmt werden. So stellt sich beispielsweise nach den chemischen Aequivalenten für Ceroxyd das Verhältnifs folgendermafsen:Of course, the amount of dephosphorus used depends on the phosphorus content the metal to be cleaned and the chemical composition of the agent itself. If z. B. the pig iron Percentage of phosphorus determined by the analysis can be the required amount of the The aggregate can easily be determined by the Hüitenchemiker. So arises, for example according to the chemical equivalents for cerium oxide, the ratio is as follows:
Phosphor °>54; Phosphorus °> 54 ;
Ceroxyd 2,83,Ceria 2.83,
d. h. die Menge des Ceroxyds würde procentualiter etwa fünf- bis sechsmal so grofs seind. H. the amount of ceria would be about five to six times as great in percentage terms
müssen als der durch die Analyse festgestellte Phosphorgehalt der Charge.must than the phosphorus content of the batch determined by the analysis.
Wie bereits erwähnt, kann der beschriebene Entphosphorungsprocefs auch für andere Metalle angewendet werden.As already mentioned, the dephosphorization process described can also be used for other metals be applied.
Die zur Entphosphorung dienenden Agentien werden entweder mit dem Metall gemischt, oder der Ofen bezw. die Birne wird damit ausgekleidet.The agents used for dephosphorization are either mixed with the metal, or the furnace respectively. the pear is lined with it.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE100236C true DE100236C (en) |
Family
ID=371074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT100236D Active DE100236C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE100236C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3211549A (en) * | 1960-12-26 | 1965-10-12 | Yawata Iron & Steel Co | Additional alloys for welding and steel making |
-
0
- DE DENDAT100236D patent/DE100236C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3211549A (en) * | 1960-12-26 | 1965-10-12 | Yawata Iron & Steel Co | Additional alloys for welding and steel making |
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