CS274117B1 - Glass with high manganese content suitable especially for recalibration standards production - Google Patents
Glass with high manganese content suitable especially for recalibration standards production Download PDFInfo
- Publication number
- CS274117B1 CS274117B1 CS415089A CS415089A CS274117B1 CS 274117 B1 CS274117 B1 CS 274117B1 CS 415089 A CS415089 A CS 415089A CS 415089 A CS415089 A CS 415089A CS 274117 B1 CS274117 B1 CS 274117B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- oxide
- glass
- weight
- recalibration
- iron
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 42
- 239000011572 manganese Substances 0.000 title claims abstract description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011575 calcium Substances 0.000 claims abstract description 5
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims abstract description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 3
- 229910052776 Thorium Inorganic materials 0.000 claims abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 3
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract 3
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052681 coesite Inorganic materials 0.000 claims abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract 2
- 239000011574 phosphorus Substances 0.000 claims abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract 2
- 229910052682 stishovite Inorganic materials 0.000 claims abstract 2
- 229910052905 tridymite Inorganic materials 0.000 claims abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000004458 analytical method Methods 0.000 claims description 7
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 6
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 4
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 3
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 3
- 229940112669 cuprous oxide Drugs 0.000 claims description 3
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 3
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 3
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 2
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052810 boron oxide Inorganic materials 0.000 claims description 2
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 229910000311 lanthanide oxide Inorganic materials 0.000 claims description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 2
- 229910001887 tin oxide Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 2
- 229910000439 uranium oxide Inorganic materials 0.000 claims description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 2
- 238000004846 x-ray emission Methods 0.000 claims description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims 2
- 229910000423 chromium oxide Inorganic materials 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims 2
- 239000005751 Copper oxide Substances 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 229910017976 MgO 4 Inorganic materials 0.000 claims 1
- 229910000413 arsenic oxide Inorganic materials 0.000 claims 1
- 229960002594 arsenic trioxide Drugs 0.000 claims 1
- 239000012237 artificial material Substances 0.000 claims 1
- 229910000416 bismuth oxide Inorganic materials 0.000 claims 1
- 238000009614 chemical analysis method Methods 0.000 claims 1
- 229910000431 copper oxide Inorganic materials 0.000 claims 1
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 238000004940 physical analysis method Methods 0.000 claims 1
- 229910001923 silver oxide Inorganic materials 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011651 chromium Substances 0.000 abstract description 5
- 239000011698 potassium fluoride Substances 0.000 abstract description 5
- 239000010949 copper Substances 0.000 abstract description 4
- 229910052747 lanthanoid Inorganic materials 0.000 abstract description 4
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 239000010936 titanium Substances 0.000 abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- 229910052684 Cerium Inorganic materials 0.000 abstract description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052770 Uranium Inorganic materials 0.000 abstract description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052785 arsenic Inorganic materials 0.000 abstract description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052788 barium Inorganic materials 0.000 abstract description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052797 bismuth Inorganic materials 0.000 abstract description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 2
- 229910017052 cobalt Inorganic materials 0.000 abstract description 2
- 239000010941 cobalt Substances 0.000 abstract description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002602 lanthanoids Chemical class 0.000 abstract description 2
- 229910052746 lanthanum Inorganic materials 0.000 abstract description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052744 lithium Inorganic materials 0.000 abstract description 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 2
- 239000011733 molybdenum Substances 0.000 abstract description 2
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 235000003270 potassium fluoride Nutrition 0.000 abstract description 2
- 229910052712 strontium Inorganic materials 0.000 abstract description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052720 vanadium Inorganic materials 0.000 abstract description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052727 yttrium Inorganic materials 0.000 abstract description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052726 zirconium Inorganic materials 0.000 abstract description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- 239000011787 zinc oxide Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 5
- 239000000956 alloy Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 229940117975 chromium trioxide Drugs 0.000 description 2
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 1
- 239000006121 base glass Substances 0.000 description 1
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Description
zejména k výrobě rekalibračnich standardů (57) sklo vykazuje dostatečnou chemickou stálost a homogenitu, výrazně vyšěi výtěžnost než jiná skla s vysokým obsahem manganu, dobrou tavitelnost. Obsahuje v procentech hmotnosti 30 až 40 oxidu manganatého MnO, 1 až 8 oxidu draselného KgO, 1 až 8 oxidu hořečnatého MgO, 1 až 10 oxidu zinečnatého ZnO/ 1 až 8 oxidu boritého, B20g, až 16 oxidu hlinitého Al203 a 30 až 40 oxidu křemičitého Si02« Dále může sklo β výhodou obsahovat v procentech hmotnosti nejméně jeden oxid prvku ze skupiny zahrnující lithium Li 0,1 až 5/ sodík Na 0,1 až 10, vápnik Ca 0,1 až 10/ stroncium Sr 0,1 až 10, baryum Ba 0,1 až 10, yttrium Y 0,1 až 10, lanthan La a lanthanoidy 0,1 až 10/ cér Ce 0/1 až 5/ cín Sn 0/1 až 5, olovo Pb 0,1 až 10/ foafor P 0,1 až 10, arsen As 0,1 až 5/ antimon Sb 0/1 až 5, bizmut Bi 0/1 až 5, chrom Cr 0/1 až 3, molybden Mo 0,1 až 5, wolfram W 0/1 až 5, železo Fe 0,1 až 10, kobalt Co 0/1 až 10/ nikl Ni Oyl až 10, thorium Th 0,1 až 5/ uran U 0,1 až 5, měí Cu 0,1 až 5/ stříbro Ag 0/1 až 3, kadmium Cd 0,1 až 5, titan Ti 0,1 až 10, zirkonium Zr 0,1 až 5,' vanad V 0,1 až 5, přičemž celkový obsah uvedených oxidů čini 0,1 až 15* Dále může sklo β výhodou obsahovat v procentech hmotnoeti 0,1 až 4 fluoridu draselného KF,in particular for the production of recalibration standards (57), the glass exhibits sufficient chemical stability and homogeneity, a significantly higher yield than other glasses with a high manganese content, good fusibility. Contains by weight 30 to 40 MnO, 1 to 8 KgO, 1 to 8 MgO, 1 to 10 ZnO / 1 to 8 boron oxide, B 20 g, up to 16 alumina Al 2 0 3 and 30 to 40 silica SiO 2. Further, the glass β may advantageously contain at least one oxide of an element of the group comprising lithium Li 0.1 to 5 / sodium Na 0.1 to 10, calcium Ca 0.1 to 10 / strontium Sr 0.1 to 10, barium Ba 0.1 to 10, yttrium Y 0.1 to 10, lanthanum La and lanthanides 0.1 to 10 / cerium Ce 0/1 to 5 / tin Sn 0/1 to 5, lead Pb 0.1 to 10 / phaphor P 0.1 to 10, arsenic As 0.1 to 5 / antimony Sb 0/1 to 5, bismuth Bi 0/1 to 5, chromium Cr 0/1 to 3, molybdenum Mo 0 , 1 to 5, tungsten W 0/1 to 5, iron Fe 0.1 to 10, cobalt Co 0/1 to 10 / nickel Ni Oyl to 10, thorium Th 0.1 to 5 / uranium U 0.1 to 5 It contains Cu 0.1 to 5 / silver Ag 0/1 to 3, cadmium Cd 0.1 to 5, titanium Ti 0.1 to 10, zirconium Zr 0.1 to 5, vanadium V 0.1 to 5 5, wherein the total content of said oxides is 0.1 to 15. Further, the glass β may advantageously contain 0.1 to 4% by weight of potassium fluoride KF,
CS 274117 BlCS 274117 Bl
Vynólez se týká složeni skla š vyáókým obsahem manganu, které Je vhodné zejména k výrobě rekalibráěnich standardů používaných k rekalibraci a seřizováni rentgenových emlsnich a fluorescenčních spektrometrů.The present invention relates to a composition of high manganese glass which is particularly suitable for the production of recalibrated standards used for recalibration and adjustment of X-ray emission and fluorescence spectrometers.
Použiti skleněných standardů k rekalibraci rentgenových spektrometrů Je známo z čsl· autorského osvědčeni č* 231 390, které rovněž uvádí příkladná složeni skel vhodných pro použiti jako rekalibračni standardy. Mezi příkladnými skly ss uvádí i sklo s vysokým obsahem manganu, a to 45 % hmot·, které se používá jako rekalibračni standard při analýze s vysokým obsahem manganu, např. rud a slitin· 3ak věak bylo zjištěno, výroba uvedeného skla a vysokým obsahem manganu činí značné technologické obtíže, neboť během taviciho procesu dochází k silnému pěněni, obtížnému čeření a značné korozi žórovzdorných materiálů v tavícím agregátu. Důsledkem těchto jevů je velmi nízká výtěžnost, asi %, při výrobě kvalitních destiček z tohoto skla pro daný účel.The use of glass standards for recalibration of X-ray spectrometers It is known from the author's certificate No. 231,390 which also provides exemplary compositions of glasses suitable for use as recalibration standards. Among the exemplary DC glasses, there is also a high manganese glass of 45% by weight, which is used as a recalibration standard in high manganese analysis such as ores and alloys. it causes considerable technological difficulties, since during the melting process there is a strong foaming, difficult refining and considerable corrosion of the refractory materials in the melting aggregate. The consequence of these phenomena is a very low yield, about%, in the production of quality plates of this glass for the purpose.
Z uvedeného důvodu došlo k Četným pokusům modifikovat známé složení skla s vysokým obsahem manganu, za účelem odstraněni nežádoucích jevů při současném zachováni potřebných vlastností skla, mezi něž patři obsah manganu nejméně 30 % hmot., dostatečná chemická stálost a homogenita.For this reason, numerous attempts have been made to modify the known composition of glass with a high manganese content in order to eliminate undesirable phenomena while maintaining the necessary properties of the glass, including a manganese content of at least 30% by weight, sufficient chemical stability and homogeneity.
Uvedeným účelům vyhovuje sklo s vysokým obsahem manganu Mn, vhodné zejména k výrobě rekalibračních standardů, podle vynálezu, jehož podstata spočivá v tom, že sklo obsahuje v procentech hmotnosti 30 až 40 oxidu manganatého MnO, 1 až 8 oxidu draselného K^O, 1 až 8 oxidů hořečnatého MgO, 1 až 10 oxidu zinečnatého ZnO, 1 až 8 oxidu boritého BgOg, 6 až oxidu hlinitého Al203 a 30 až 40 oxidu křemičitého SiOg,Mn glass suitable for the production of recalibration standards according to the invention is suitable according to the invention, characterized in that the glass contains, in percent by weight, 30 to 40 MnO, 1 to 8 K 2 O, 1 to 8 8 MgO, 1 to 10 ZnO, 1 to 8 BgOg, 6 to Al 2 O 3 and 30 to 40 SiOg,
Za účelem použiti skla jako rakalibračniho standardu pro další analytické rozbory, např. ostatních složek ve slitinách, může sklo dále s výhodou obsahovat v procentech hmotnosti nejméně jeden oxid ze skupiny zahrnující oxid lithný LigO 0,1 až 5, oxid sodný Na£0 0,1 až 10, oxid vápenatý CaO 0,1 až 10, oxid strontnatý SrO 0,1 až 10, oxid barnatý BaOFor the purpose of using glass as standard rakalibračniho for further analytical analysis, e.g. other components of the alloys, the glass may further preferably comprise in percentages by weight of at least one oxide from the group comprising lithium oxide LigO 0.1 to 5, sodium oxide Na £ 0 0 1 to 10, calcium oxide CaO 0.1 to 10, strontium oxide SrO 0.1 to 10, barium oxide BaO
0,1 až 10, oxid yttritý Y2°3 ^·0· oxid lanthanitý La203 a/nebo oxidy lanthanoidů0.1 to 10, yttrium oxide Y 2 ° 3 ^ · 0 · lanthanum oxide La 2 0 3 and / or lanthanide oxides
0,1 až 10, oxid ceričitý Ca02 0,1 až 5, oxid cinatý SnO 0,1 až 5, oxid olovnatý PbO 0,1 až 10, oxid fosforečný P20g 0,1 až 10, oxid arsenitý As203 0,1 až 5, oxid antimonitý Sb203 0,1 až 5, oxid bismutitý BlgOg °»1 5» oxid chromitý Cr2O3 a/nebo oxid chromový0.1 to 10, cerium oxide CaO 2 0.1 to 5, tin oxide SnO 0.1 to 5, lead oxide PbO 0.1 to 10, phosphorus pentoxide P 2 0g 0.1 to 10, arsenic trioxide As 2 0 3 0.1 to 5, antimony trioxide Sb 2 0 3 0.1 to 5, bismuth trioxide BlgOg ° »1 5 » chromium trioxide Cr 2 O 3 and / or chromium trioxide
CrO3 0,1 až 3, oxid molybdenový Mo03 0,1 až 5, oxid wolframový W03 0,1 až 5, oxid železnatý FeO a/nebo oxid železitý Fe203 °,1 ež 10, oxid kobalnatý CoO 0,1 až 10, oxid nikelnatý NiO 0,1,až 10, oxid thoričitý Th02 0,1 až 5, oxid uranový U03 0,1 až 5, oxid měčfný Cu20 a/nebo oxid měčfnatý CuO 0,1 až 5, oxid stříbrný Ag20 0,1 až 3, oxid kademnatý CdO 0,1 až 5, oxid titaničitý Ti02 0,1 až 10, oxid zirkoničitý Zr02 0,1 až 5, oxid vanadičný V20g 0,1 až 5, přičemž celkový obsah uvedených oxidů čini 0,1 až 15 % hmotnosti skla.CrO 3 0.1 to 3, molybdenum oxide Mo0 3 0.1 to 5, tungsten oxide W0 3 0.1 to 5, iron oxide FeO and / or iron oxide Fe 2 0 3 °, 1 to 10, cobalt oxide CoO 0 , 1 to 10, nickel oxide NiO 0.1, to 10, thorium oxide ThO 2 0.1 to 5, uranium oxide UO 3 0.1 to 5, cuprous oxide Cu 2 0 and / or cuprous oxide CuO 0.1 to 5 5, silver Ag 2 0 0.1 to 3, cadmium oxide CdO 0.1 to 5, titanium dioxide TiO 2 0.1 to 10, zirconia ZrO 2 0.1 to 5, vanadium oxide V 2 0g 0.1 5 to 5, wherein the total content of said oxides is 0.1 to 15% by weight of glass.
Pro rozšířeni možnosti použiti skla ke stanoveni fluoru v analyzovaných surovinách může sklo g výhodou dále obsahovat v procentech hmotnosti 0,1 až 4 fluoridu draselného KF, který snižuje viskozitu, a tim přispívá k lepší tvarovatelnosti skla a současně slouži Jako čeřivo.To extend the possibility of using glass to determine fluorine in the raw materials analyzed, glass g may advantageously further contain 0.1 to 4 KF of fluoride, which reduces viscosity, thereby contributing to better formability of the glass while serving as a fining agent.
Sklo podle vynálezu vykazuje dostatečnou chemickou stálost a homogenitu, technologické výhody spočívající v lepší tavitelnosti a výrazně vyšší výtěžnosti vzhledem k velmi nízkému obsahu bublin. Rozšířením základního složeni ss zvětšuji možnosti uplatnění tohoto rekalibračniho standardu při rekalibraci přístroje pro řadu dalších analytických rozborů bez nutnosti použití samostatných standardů. Rekalibrace pro dalši analýzy, například ostatních složek ve slitinách, respektive jiné obecné analýzy, proběhne tak v jednom cyklu.The glass according to the invention exhibits sufficient chemical stability and homogeneity, technological advantages in terms of improved fusibility and significantly higher yields due to the very low bubble content. By extending the basic composition of the DC, I increase the possibility of applying this recalibration standard in the recalibration of the instrument for a number of other analytical analyzes without the need of using separate standards. The recalibration for further analysis, for example of other components in alloys or other general analysis, will be done in one cycle.
Příprava skel probíhá klasickými sklářskými postupy z kmene, do kterého jsou Jednotlivé požadované oxidy vnášeny jako takové nebo v podobě vhodných soli, uhličitanů, dusičnanů apod.The preparation of glasses is carried out by classical glass processes from a batch into which the individual desired oxides are introduced as such or in the form of suitable salts, carbonates, nitrates and the like.
Podstata vynálezu je bliže objasněna příklady složeni skel podle vynálezu, uvedenými v tabulce, kde:The principles of the invention are illustrated in greater detail by the examples of glass compositions according to the invention given in the table, where:
Sklo č. 1 je základním sklem bez dalších přídavků, vhodné k rekalibraci analytických postupů na stanoveni manganu Mn v jeho sloučeninách nebo jednodušších rudách a slitinách. Oeho výhodou je vysoká výtěžnost, až 90 %, daná příznivými technologickými vlastnostmi při tavení.Glass No. 1 is a base glass without further additions, suitable for recalibrating analytical procedures to determine manganese Mn in its compounds or simpler ores and alloys. Its advantage is the high yield, up to 90%, given by the favorable technological properties during melting.
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Claims (3)
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| Application Number | Priority Date | Filing Date | Title |
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| CS415089A CS274117B1 (en) | 1989-07-06 | 1989-07-06 | Glass with high manganese content suitable especially for recalibration standards production |
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| Application Number | Priority Date | Filing Date | Title |
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| CS415089A CS274117B1 (en) | 1989-07-06 | 1989-07-06 | Glass with high manganese content suitable especially for recalibration standards production |
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| CS415089A1 CS415089A1 (en) | 1990-08-14 |
| CS274117B1 true CS274117B1 (en) | 1991-04-11 |
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