CS272037B1 - Lubrication for glass fibres treatment - Google Patents
Lubrication for glass fibres treatment Download PDFInfo
- Publication number
- CS272037B1 CS272037B1 CS891241A CS124189A CS272037B1 CS 272037 B1 CS272037 B1 CS 272037B1 CS 891241 A CS891241 A CS 891241A CS 124189 A CS124189 A CS 124189A CS 272037 B1 CS272037 B1 CS 272037B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- weight
- glass fibers
- lubrication
- treatment
- lubricant
- Prior art date
Links
- 239000003365 glass fiber Substances 0.000 title claims description 20
- 238000005461 lubrication Methods 0.000 title description 17
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 230000002787 reinforcement Effects 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- HSSTXIXETHIWKY-UHFFFAOYSA-N cyclohexen-1-ylsilane Chemical class [SiH3]C1=CCCCC1 HSSTXIXETHIWKY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920001519 homopolymer Polymers 0.000 claims abstract description 3
- 239000000314 lubricant Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 6
- -1 cationic nitrogen derivatives Chemical class 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- HOZMLTCHTRHKRK-UHFFFAOYSA-N 2-methyl-1-silylprop-2-en-1-one Chemical class CC(=C)C([SiH3])=O HOZMLTCHTRHKRK-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- 239000012716 precipitator Substances 0.000 claims 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims 1
- 239000000080 wetting agent Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 7
- MLXMQBGBMIFRSY-UHFFFAOYSA-N 2-(cyclohexen-1-yl)ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CCCCC1 MLXMQBGBMIFRSY-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- 239000011118 polyvinyl acetate Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Vodná kompozícia obsahuje l až 10 % haotnosti suSiny disperzie homopolymérov a/alebo kopolymérov vinylacetátu, 0,05 až 1 % hmotnosti cyklohexenylsilanov ako cyklohexenyletyltrietoxysilan a 0,01 až 1,5 % hmotnosti antistatických Sinidiel. Upravené vlákna sú vhodné ako výstuž plástev.The aqueous composition contains 1 to 10% the dispersion of homopolymer dispersions and / or vinyl acetate copolymers, 0.05 to 1% by weight of cyclohexenylsilanes as cyclohexenylethyltriethoxysilane and 0.01 to 1.5% by weight of antistatic sinters. The treated fibers are suitable as a honeycomb reinforcement.
Description
Vynález ea týká lubrikácie na úpravu skleněných vlákien, vhodných ako výstuž plastov.The invention relates to a lubricant for the treatment of glass fibers suitable as a reinforcement for plastics.
Skleněná vlákna ako výstuž plastov sa používajú najčastejšie vo forme rohoží, tkanin, rovingov a sekaného vlákna. Změna povrchových vlastností skleněných vlákien a výrobkov na ich báze aa dosahuje použitím priamych lubrikácií. Každý druh lubrikácie ovplyvňuje v róznej miere mechanické a chemické vlastnosti skleněných vlákien ako pevnost, odolnost voči abrázii, tuhost, dielektrické vlastnosti, zmáčavosl a pod. Je známe, že so stúpajúcou vlhkostou klesá pevnost skleněných vlákien a zároveň aj pevnost sklovláknitých kompozicií. Priemyselne je najpoužívanejší sposob aplikovat lubrikácie k povrchovej úpravě skleněných vlákien z vodných systémov, hlavně z ddvodu, že použitie organických rozpúšladiel je obmedzené, či už pre ich toxicitu, hořlavost a v neposlednom řade aj z ekonomických příčin. Riešenie tohto problému použitím róznych hydrofobizačných přísad, napr. minerálnych či silikonových olejov, je sice čiastočne účinné, no uvedené látky zároveň pósobia ako silné separétory, v důsledku čoho sa výrazné zhoršuje adhézia na fézovom rozhraní skleněné vlákno, matrica.Glass fibers as a reinforcement for plastics are most often used in the form of mats, fabrics, rovings and chopped fibers. The change of the surface properties of glass fibers and products based on them is achieved by the use of direct lubrications. Each type of lubrication affects to a different extent the mechanical and chemical properties of glass fibers such as strength, abrasion resistance, stiffness, dielectric properties, wettability and the like. It is known that with increasing humidity, the strength of glass fibers decreases and at the same time the strength of glass fiber compositions. Industrially, the most widely used method is to apply lubricants to the surface treatment of glass fibers from aqueous systems, mainly due to the fact that the use of organic solvents is limited, either due to their toxicity, flammability and, last but not least, for economic reasons. The solution to this problem by using various hydrophobicizing additives, e.g. mineral or silicone oils, is partially effective, but these substances also act as strong separators, as a result of which the adhesion at the filament interface of the glass fiber, matrix is significantly impaired.
Uvedené nedostatky v podstatné} miere odstraňuje lubrikécia podlá vynálezu, ktorá je vhodná na úpravu skleněných vlákien, vhodných ako výstuž plastov. podstata vynálezu spočívá v tom, že sa skládá z 1 až 10 % hmotnosti sušiny disperzie na báze homopolymérov a/alebo kopolysérov vinylacetátu, 0,05 až 1 % hmotnosti cyklohexenylsilanov obecného vzorca (CHgJgSÍÍORJxCOGgH^NMzJy kde R je alkyl s 1 alebo 2 atómami uhlíka, x a y je celé číslo 0, 1, 2 alebo 3 a platí, že x + y · 3, 0,01 až 1,5 % hmotnosti antistatických činidiel ako chlorid lítny, chlorid amonný alebo katíontícké dusíkaté deriváty a zbytok do 100 % hmotnosti tvoří voda. Textilné vlastnosti vlákien a stabilitu kompozície je možné v případe potřeby, hlavně podlá použitého technologického zariadenia, reguloval pridavkom stopy až 3,5 % hmotnosti aspoň jednej přísady zo skupiny vazbových prostriedkov, regulétorov pH, emulgátorov, platifikétorov, mazadle1, znáčadiel a odpeňovačov ako vinylsilany, metakrylsilany,, dichlórdichrómmetakryláty, organické kyseliny, zásady, estery, polyetylénglykoly a tenzidy, případné 0,5 až 4 % hmotnosti sušiny polyesterovéj emulzie.These shortcomings are substantially eliminated by the lubrication according to the invention, which is suitable for the treatment of glass fibers suitable as plastic reinforcement. The invention consists in that it consists of 1 to 10% by weight of dry matter of a dispersion based on homopolymers and / or copolysers of vinyl acetate, 0.05 to 1% by weight of cyclohexenylsilanes of the general formula (CH 2) , x and y is an integer of 0, 1, 2 or 3 and x + y · 3, 0.01 to 1.5% by weight of antistatic agents such as lithium chloride, ammonium chloride or cationic nitrogen derivatives and the remainder up to 100% by weight The textile properties of the fibers and the stability of the composition can be controlled, if necessary, mainly according to the technological equipment used, by adding traces of up to 3.5% by weight of at least one additive from the group of binders vinylsilanes, methacrylsilanes, dichlorodichrome methacrylates, organic acids, bases, esters, polyethylene glycols and surfactants, optionally 0.5 to 4% by weight of the dry weight of the polyester emulsion.
Lubrikácie podlá vynálezu je vhodná k úpravě skleněných vlákien, používaných ako výstuž plastov, predovšetkým nenasýtených polyesterových živíc, vyznačuje sa dobrou skladovou stabilitou, čo umožňuje připravoval vačšie množetvá lubrikácie bez vplyvu na jej kvalitu. Při jej používaní sa prakticky neprejavujú problémy s vznikom konstantých dermatóz, či už pri manipulácii s lubrikáciami alebo za jej použitie upravených skleněných vlákien. Oproti známým lubrikáclaa sa podstatné zlepšuje hydrolytická stabilita či už samotných upevněných skleněných vlákien, no predovšetkým kompozicií na ich báze.The lubricant according to the invention is suitable for the treatment of glass fibers used as a reinforcement for plastics, in particular unsaturated polyester resins, and is characterized by good storage stability, which makes it possible to prepare larger quantities of lubricants without affecting its quality. When using it, there are practically no problems with the occurrence of constant dermatoses, either when handling lubricants or using modified glass fibers. Compared to known lubricants, the hydrolytic stability of the fixed glass fibers themselves, but especially of the compositions based on them, is substantially improved.
Suroviny použité k výrobě lubrikácie podlá vynálezu sú známe a celý rad je ich aj bežne komerčně dostupných. Z polymernych disperzi! má najvačší význam samotný polyvinylacetát a kopolyméry vinylacetátu s butylakrylátom, 2-etylhexylakrylátom a dibutylmaleinátom. V případe aplikécie skleněných vlákien k výrofbe vysokptran^parentných sklolaminátov je potřebné disperzie polymérov vyrábal tak, aby pri ich výrobě nebol použitý ako ochranný koloid polyvinylalkohol, ktorý ako Je známe je separator plyesterových živíc.The raw materials used to make the lubrication according to the invention are known and a number of them are also commercially available. From polymer dispersions! polyvinyl acetate alone and copolymers of vinyl acetate with butyl acrylate, 2-ethylhexyl acrylate and dibutyl maleate are of the greatest importance. In the case of glass fibers to aplikécie productions f ^ BE vysokptran parentných FRP is required dispersion of polymer was produced so that in their manufacture has not been used as protective colloid polyvinyl alcohol which, as is known separator plyesterových resins.
Vynález je 3alej objasněný formou príkladov, v ktorých zloženie Je uvádzané v hmotnostněj koncentrácii.The invention is further illustrated by the following examples, in which the composition is given in a concentration by weight.
CS 272037 Bl příklad 1CS 272037 B1 Example 1
Oo nádoby opatrenej miešadlom aa přidalo 2 1 vody, 10 g acylpolyglykoléteru na báze mastných kyselin kokosového oleja s 10 mólmi etylénoxidu a 10 g cyklohexenyletyItrietoxiailanu. Po homogenizácii ea k vzniknutej emulzii přidalo 5 g kyseliny octo vej a 10 g 3-metakryloxypropyltrÍmetoxyeilanu. V teplej vodě sa rozpustilo 5 g lauryl amidoetyIpyridínlumchloridu a 20 g chloridu lítneho a přidalo za mieSania ku kompozici!. Po přidaní 300 g polyvinylacetátovej diaperzie (sušina 5,5 %) ea lubrikácia doplnila vodou na objem 10 1. Připravená lubrikácia má ph · 4,2 a povrchové napátie 30,5 mN.m-1 pri 20 °C. Rozdelovanie ani sedimentácia lubrikácie nebole pozorovaná ani po 2 dnoch stánia. skleněné vlákna upravené touto lubrikáciou sú vhodné k výrobě pramencových rohoží vhodných ako výstuž nenaeýtených polyesterových živíc.2 l of water, 10 g of acyl polyglycol ether based on coconut oil fatty acids with 10 mol of ethylene oxide and 10 g of cyclohexenylethyltriethoxiailane were added to a vessel equipped with a stirrer. After homogenization and 5 g of acetic acid and 10 g of 3-methacryloxypropyltrimethoxyilane were added to the resulting emulsion. 5 g of lauryl amidoethylpyridine chloride and 20 g of lithium chloride were dissolved in warm water and added to the composition with stirring. After adding 300 g of polyvinyl acetate dispersion (dry matter 5.5%), the lubrication was made up to 10 l with water. The prepared lubrication has a pH of 4.2 and a surface tension of 30.5 mN.m -1 at 20 ° C. No lubrication distribution or sedimentation was observed even after 2 days of standing. glass fibers treated with this lubrication are suitable for the production of strand mats suitable as reinforcement for unsaturated polyester resins.
Příklad 2Example 2
Lubrikácia ea připraví postupem ako v přiklade 1, s tým rozdielom, že namiesto polyvinylacetátovej disperzie sa použije ekvivalentně množstvo kopolymernej diaperzie na báze 93 % vinylacetátu a 7 % dibutylmaleinátu (sušina 52 %). Připravená lubrikácia má pH 4,4 a povrchové napátie pri 20 °C 30,3 mN.m1. skleněné vlákna upravené touto lubrikáciou sú zvláěť vhodné k výrobě transparentných laminátev so zvýšenou odolnosťou voči vodě.Lubrication ea was prepared according to the procedure of Example 1, except that instead of the polyvinyl acetate dispersion, an equivalent amount of a copolymer dispersion based on 93% vinyl acetate and 7% dibutyl maleate (dry matter 52%) was used. The prepared lubrication has a pH of 4.4 and a surface tension at 20 ° C of 30.3 mN.m 1 . glass fibers treated with this lubrication are particularly suitable for the production of transparent laminates with increased water resistance.
příklad 3Example 3
Lubrikácia sa připraví postupom ako v příklade 1, e tým rozdielom, že namiesto cyklohexenyletyItrietoxysilanu a 3-metakryloxypropyltrimetoxysilanu sa použije 30 g 3-cyklohexenyletyl/2-amlnoetoxy/dietoxisilanu a z receptúry sa vypustí uvedený acylpolyglykoléter. připravená lubrikácia má pH > 5,7 a povrchové napátie 37,2 mN.*1 pri teplote 20 °C.Lubrication was prepared as in Example 1, except that 30 g of 3-cyclohexenylethyl [2-aminoethoxy] diethoxisilane was used instead of cyclohexenylethyltriethoxysilane and 3-methacryloxypropyltrimethoxysilane and the acylpolyglycol ether was discarded from the formulation. the prepared lubrication has a pH> 5.7 and a surface tension of 37.2 mN. * 1 at a temperature of 20 ° C.
Příklad 4Example 4
Do nádoby opatrenej mieěadlom sa přidalo 2 1 vody, 4 g acylpolyglykoléteru ako v příklade 1 a 20 g cyklohexenyletyltrietoxysilanu. Po homogenizácii sa k vzniknutej emulzi! přidalo 5 g kyseliny octovej a 10 g vazbového prostriedku na báze aduktu epoxidovej živice na báze dianu o priemernej nolekulovej hmotnosti 380 a 3-/2~aminoetyl/ami~ nopropyItrimetoxysilanu v molárnom pomere 1 ; 3,7. Po 0,5 h miešania sa přidalo 20 g dimetylsulfátom kvartenizovaného oktadecylamínu oxyetylovaného 20 mólmi etylénoxidu, 500 g kopolyméru-dibutylmalelnát, 300 g polyesterovej etnulzie (sušina 40 %) a doplnilo vodou na objem 10 1. Připravená lubrikácia má pH 5,3 a povrchové napátie 38,7 mN.o“1 pri 20 °C. Skleněné vlákna upravené touto lubrikáciou sú vhodné k výrobě sklolaminátov technológiou striekania.2 l of water, 4 g of acyl polyglycol ether as in Example 1 and 20 g of cyclohexenylethyltriethoxysilane were added to a flask equipped with a stirrer. After homogenization, the resulting emulsion is added! added 5 g of acetic acid and 10 g of a dian-based epoxy resin adduct binder with an average molecular weight of 380 and 3- (2-aminoethyl) aminopropyltrimethoxysilane in a molar ratio of 1; 3.7. After stirring for 0.5 h, 20 g of dimethyl sulfate quaternized octadecylamine oxyethylated with 20 moles of ethylene oxide, 500 g of dibutyl maleate copolymer, 300 g of polyester ethanol (40% dry matter) were added and made up to 10 L with water. The prepared lubrication has a pH of 5.3 and a surface lubrication. voltage 38.7 mN.o “ 1 at 20 ° C. Glass fibers treated with this lubrication are suitable for the production of fiberglass by spraying technology.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS891241A CS272037B1 (en) | 1989-02-27 | 1989-02-27 | Lubrication for glass fibres treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS891241A CS272037B1 (en) | 1989-02-27 | 1989-02-27 | Lubrication for glass fibres treatment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS124189A1 CS124189A1 (en) | 1990-03-14 |
| CS272037B1 true CS272037B1 (en) | 1990-12-13 |
Family
ID=5346298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS891241A CS272037B1 (en) | 1989-02-27 | 1989-02-27 | Lubrication for glass fibres treatment |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS272037B1 (en) |
-
1989
- 1989-02-27 CS CS891241A patent/CS272037B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS124189A1 (en) | 1990-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69300806T2 (en) | Paint auxiliaries and water-dilutable paint composition. | |
| DE3686135T2 (en) | POLYMERS MODIFIED BY SILANE. | |
| DE2659370A1 (en) | COATED FIBERGLASS | |
| DE69032063T2 (en) | Sizing for glass fibers | |
| DE3782897T2 (en) | COATING COMPOSITION. | |
| US6521683B1 (en) | Antistatic agents and resin compositions incorporated therein | |
| EP0469240A2 (en) | Silanised glass fibre reinforced polyamide, silanised glass fibres and process for their preparation | |
| CS272037B1 (en) | Lubrication for glass fibres treatment | |
| DE3685570T2 (en) | CURTAINABLE ORGANOSILICON COMPOSITION AT AMBIENT TEMPERATURE. | |
| US3316232A (en) | Polypropylene compositions and a method for their preparation | |
| EP0073911A1 (en) | Aqueous coating compositions based on silicon resin | |
| US2710268A (en) | Process of bonding asbestos fibers with a titanium polymer and article produced thereby | |
| DE3614412C2 (en) | ||
| WO2007003277A1 (en) | Silicone resins having a defined reactivity | |
| US5120780A (en) | Glass fiber size composition and synthetic organosilane lubricants used therein | |
| DE69114996T2 (en) | THERMOPLASTIC ELASTOMERS AND METHOD FOR THEIR PRODUCTION. | |
| DE4243550C1 (en) | Fiber auxiliaries and their use | |
| DE1570357A1 (en) | Process for the production of polyamides reinforced with inorganic fibers | |
| AU596233B2 (en) | Size composition | |
| WO2014060350A1 (en) | Aqueous silicone resin emulsion and its application | |
| CS271996B1 (en) | Lubrication for glass fibres treatment | |
| EP0553493B1 (en) | Coated bobbins, process for their fabrication and their use in the processing of glass fibers | |
| EP0663424A2 (en) | Use of a resin composition from a linear high-molecular polyester and an olefincopolymer | |
| DE1247009B (en) | Thermoplastic masses for the production of anti-static moldings made of highly crystalline polyethylene | |
| CS267790B1 (en) | Lubrication for glass fibres treatment |