CS267790B1 - Lubrication for glass fibres treatment - Google Patents
Lubrication for glass fibres treatment Download PDFInfo
- Publication number
- CS267790B1 CS267790B1 CS886394A CS639488A CS267790B1 CS 267790 B1 CS267790 B1 CS 267790B1 CS 886394 A CS886394 A CS 886394A CS 639488 A CS639488 A CS 639488A CS 267790 B1 CS267790 B1 CS 267790B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- weight
- lubricant
- treatment
- vinyl acetate
- fibers
- Prior art date
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- 239000003365 glass fiber Substances 0.000 title claims description 18
- 238000005461 lubrication Methods 0.000 title description 11
- 239000000835 fiber Substances 0.000 claims abstract description 23
- 229920001577 copolymer Polymers 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920003023 plastic Polymers 0.000 claims abstract description 6
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 239000011230 binding agent Substances 0.000 claims abstract description 4
- 230000003014 reinforcing effect Effects 0.000 claims abstract 2
- 239000000314 lubricant Substances 0.000 claims description 25
- 239000000839 emulsion Substances 0.000 claims description 13
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 6
- -1 cationic nitrogen derivatives Chemical class 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229920001225 polyester resin Polymers 0.000 claims description 5
- 239000004645 polyester resin Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract description 5
- 229920000728 polyester Polymers 0.000 abstract description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920002689 polyvinyl acetate Polymers 0.000 description 6
- 239000011118 polyvinyl acetate Substances 0.000 description 6
- 230000002787 reinforcement Effects 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- VPSZKCCWOGZNLS-CFYXSCKTSA-N dibutyl (z)-but-2-enedioate;ethenyl acetate Chemical compound CC(=O)OC=C.CCCCOC(=O)\C=C/C(=O)OCCCC VPSZKCCWOGZNLS-CFYXSCKTSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical class NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 235000021168 barbecue Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- RWYFURDDADFSHT-RBBHPAOJSA-N diane Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.C1=C(Cl)C2=CC(=O)[C@@H]3CC3[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(C)=O)(OC(=O)C)[C@@]1(C)CC2 RWYFURDDADFSHT-RBBHPAOJSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- XPXMKIXDFWLRAA-UHFFFAOYSA-N hydrazinide Chemical compound [NH-]N XPXMKIXDFWLRAA-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- FJWSMXKFXFFEPV-UHFFFAOYSA-N prop-2-enamide;hydrochloride Chemical compound Cl.NC(=O)C=C FJWSMXKFXFFEPV-UHFFFAOYSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Lubrikáoia aa akladá z 0,5 až 8 hmotnoati aúžiny kopolymárov na báze vinylaoetátu a dialkylmaleinátov alebo fumarátov, 0,05 až 3,5 % hmotnosti vazbovýoh proatriedkóv, 0,02 až 1,3 hmotnoati antiatatiokýoh žinldiel a zbytku do 100 % hmotnoati vody. Upravená vlákna sú vhodná pre výstuž plast>v, hlavně polyesterových živio.Lubrikáoia aa ranges from 0.5 to 8 the masses of the base copolymers vinyl acetate and dialkyl maleate; \ tor. \ t fumarates, 0.05 to 3.5% by weight binding agent, 0.02 to 1.3 hmotnoati antiatatiokýoh žinldiel a 100% by weight of water. adjusted the fibers are suitable for reinforcing plastic> v, mainly polyester life.
Description
Vynález sa týká lubrikáoie na úpravu skleněných vlákien, vhodných ako výstuž plastov.The invention relates to a lubricant for the treatment of glass fibers suitable as a reinforcement for plastics.
Transparentní lamináty na báze skloněných vlákien a nenasýtených polyesterových živio sú neustále v pozornosti výskumu, hlavně z doVodu, že na ioh kvalitu, tj. zvýšený přestup světla, vplýva oelý rad faktorov. Bolo zistená, že i pri zhodnosti indexu lomu živice a skloněných vlákien je prakticky nemožná připravil· transpanentný laminát. Z týchto dovodov Je s vývojem tronsparentnýoh laminátov úzko spatý aj vývoj povrchovýďi úprav skleněných vlákien. Na druhéj strano povrchová úprava skloněných vlákien niolen nemá negativno vyplýval· na transparonoiu, ale im musí zároveň uděloval· vlastnosti, ktorá umožnujú ich textilní a teohnologiokí spraoovanie.Transparent laminates based on inclined fibers and unsaturated polyester animals are constantly in the spotlight of research, mainly from the reason that the ioh quality, ie. increased light transmission is influenced by a number of factors. It was found that even with the same refractive index of resin and inclined fibers, it is practically impossible to prepare a transparent laminate. For these reasons, the development of surface treatment of glass fibers is closely connected with the development of transparent transparent laminates. On the other hand, the surface treatment of the inclined niolene fibers does not have a negative effect on the transparency, but at the same time it must give them properties which allow them to be processed textile and theoretically.
Skloněná vlákna oko výstuž plastov sa použivajú najčastejšie vo forme rohoží, tkanin, rovingov a sekaního vlákna. Prioraysolne jo najpoužívanéjší sposob aplikoval· kompozíoie k povrchovej úpravě skleněných vlákien z vodných systímov, hlavně z dóVodu, že použitie organických Γozpú3l·adel jo obmedzoní, či už pro ich toxicitu, horlavosl· a v noposlednom rado aj z ekonomických příčin.Inclined fibers of eye reinforcement plastics are most commonly used in the form of mats, fabrics, rovings and chopped fibers. Prioraysolne was the most widely used method of applying compositions for the surface treatment of glass fibers from aqueous systems, mainly due to the fact that the use of organic solvents will limit them, whether for their toxicity, flammability and, last but not least, for economic reasons.
Vodná lubrikační kompozíoie používaní pre tento účel sa epravidla skladajú z filmotvorných látok, vazbových prostriedkov a antistatik. Z týohto dovodov nažil žirokí úplatnenie polymírae disperzie na báze vinylacetátu, pričom emulzná polymerizáoia sa uskutečňuje v přítomnosti Specifických emulgátorov či ochranných koloidov /čs.aut.osv.č. 162 472, 189 240, 197 045 a 218 085/, aby sklenění vlákna mohli byl· použitá k výrobě transpajrentnýoh laminátov /čs.aut.osv.č. 160 59θ a 173 131/. V tomto případe jo potřební, aby povrchový film vytvořený na skloněných vláknaoh sa dobré zmáčal a rozpú3l·al v laminačnoj živici, presnojšie v jej monomírnom rozpú3l·adle, kteří je najčastejžie tvoření styrínom či jeho zmesou s akrylátmi a metakrylátmi. Zlepšenie voči použitiu lubrikáoií na báze polyvinylaoetátovýoh disperzi! je možní dooielil· za použitia emulzi! polyesterových živíc /čs.aut.osv.č. 176 378, 220 282, 222 882 a 242 337/, no ioh použitie stálo naráža na oolý rad problímov, či už z dovodov ekonomických, ekologických a zdravotnýoh,Aqueous lubricating compositions used for this purpose generally consist of film-forming agents, binders and antistatics. For these reasons, the vinyl acetate-based polymer dispersion has been widely used, the emulsion polymerization being carried out in the presence of specific emulsifiers or protective colloids. 162,472, 189,240, 197,045 and 218,085 / so that the glass fibers can be used for the production of transparent laminates (e.g. 160 59θ and 173 131 /. In this case, it is necessary for the surface film formed on the inclined fibers to be well wetted and dissolved in the laminating resin, more particularly in its monomeric solvent, which is most often formed by styrine or a mixture thereof with acrylates and methacrylates. Improvement over the use of lubricants based on polyvinyl acetate dispersions! it is possible to doolil · using an emulsion! of polyester resins /čs.aut.osv.č. 176 378, 220 282, 222 882 and 242 337 /, but its use constantly encounters a number of problems, whether due to economic, ecological and health reasons,
Pri aplikačnom výskume sme zlatili, že tieto problínty sa v podstatnej micro odstránia při použití lubrikáoie podlá vynálezu na úpravu skloněných vlákien.In the application research, we found that these problems are substantially removed by using the lubricant according to the invention for the treatment of inclined fibers.
Vynález popisuje lubrikáoiu na úpravu sklenenýoh vlákien, vhodných ako výstuž plastov. Podstata vynálezu spočívá v tom, že lubrikáoia sa skládá z 0,5 až 8 £ hmotnosti sušiny kopolymírnej dieperzie zloženoj z 65 až 98 % hmotnosti vinylaoetátu a 2 až 35 % hmotnosti dialkylmaleinátu a/alebo dialkylfumarátu s 4 až 8 atámami uhlíka v alkylovýoh skupinách, 0,05 až 3,5 % hmotnosti vKzbovýoh prostriedkov zo skupiny zlúčenín kremíka, ohržmu, titanu, 0,02 až 1,3 % hmotnosti antistatických činidlel ako chlorid lít rty, chlorid aoSmy a/alebo kati orlická dusíkatí deriváty a zbytku do 100 % hmotnosti vody. V případe potřeby, hlavně od technologie výroby a spracovania sklenenýoh vlákien može lubrikáoia obsahoval· stopy až 3,5 % hmotnosti aspoň jednej přísady zo skupiny regulátorov pH, plastifikátorov, mazadiel, zmáčadiel ako organická kyseliny, zásady, estery, polyetylénglykoly a tenzidy. Reguláoiu textilnýoh vlastností vlákien je možná uskutečňovat prídavkom 0,2 až 5 % hmotnosti emulzie sušiny polymárov na báze vinylickýoh a/alebo elefiniokýoh monomírov ako vinylaoetát, styrín, kyselina akrylová či metakrylová a ioh estery, připadne tiež prídavkom 0,1 až 5 hmotnosti cpoxidovej a/alebo polyesterovéj živice,The invention describes a lubricant for the treatment of glass fibers suitable as a reinforcement for plastics. The invention is based on the fact that the lubricant consists of 0.5 to 8% by weight of dry matter of a copolymer diestere composed of 65 to 98% by weight of vinyl acetate and 2 to 35% by weight of dialkyl maleate and / or dialkyl fumarate having 4 to 8 carbon atoms in the alkyl groups. 0.05 to 3.5% by weight of crosslinking agents from the group of silicon compounds, titanium compounds, titanium, 0.02 to 1.3% by weight of antistatic agents such as lithium chloride, chloride and / or catalytic nitrogen derivatives and the remainder up to 100% weight of water. If necessary, mainly from the technology for the production and processing of glass fibers, the lubricant may contain traces of up to 3.5% by weight of at least one additive from the group of pH regulators, plasticizers, lubricants, wetting agents such as organic acids, bases, esters, polyethylene glycols and surfactants. The control of the textile properties of the fibers can be effected by adding 0.2 to 5% by weight of dry matter emulsion of polymers based on vinyl and / or elefinic monomers such as vinyl acetate, styrine, acrylic or methacrylic acid and ioh esters, or by adding 0.1 to 5% by weight of cpoxide and / or polyester resin,
Lubrikáoia podlá vynálezu Je vhodná k úpravo sklenenýoh vlákien, používaných ako výstuž plastov, hlavně nenasýtenýoh polyesterových živíc. Vyznačuje sa vysokou skladovaoou stabilitóu, čo umožňuje připravoval· vačšio množstvá lubrikáoie bez negativného vplyvu na jej kvalitu, Pri joj používaní sa prakticky noprejavujú problámy s vznikem kontaktnýoh dermatíz, či už pri manipuláoii s lubrikáoiou alebo za jej použitia upravených sklenenýoh vlákien. Oproti známým upraveným vláknam, hlavně za použitia lubrikáoií na báze polyvinylacetátu, sa vlákna podlá vynálezu vyznačujú zlepšenou textilnou spracovatednos-tou a zmáčavosíou v laminačnýoh živioiaoh pri výrobě sklolaminátov, čo máThe lubricant according to the invention is suitable for the treatment of glass fibers used as reinforcement for plastics, in particular unsaturated polyester resins. It is characterized by high storage stability, which allows the preparation of larger quantities of lubricants without adversely affecting its quality. Compared to known treated fibers, mainly using polyvinyl acetate-based lubricants, the fibers according to the invention are characterized by improved textile processability and wettability in laminating animals in the production of fiberglass, which has
II
CS 267 79Ο Bl kladný dopad na colý rad aplikaSnýoh uplatnění.EN 267 79Ο Positive impact on the whole range of applications.
Kopolyméry vinylacetátu s dialkylmaleinátmi a/alebo dialkylfumarátmi sú znáno. Pripravujú sa emulznou polymerizáoiou vlnylaoetátu a dibutylmaleinátom, dioktylmalelnátom, dlizobutylmalolnáiom, bis (2—etylhexyl)malelnátom, 81 obdobnými diestermi kyseliny fumá— rovej,Copolymers of vinyl acetate with dialkyl maleates and / or dialkyl fumarates are known. They are prepared by emulsion polymerization of wool oleate and dibutyl maleate, dioctyl maleate, dlisobutyl malonate, bis (2-ethylhexyl) maleate, 81 similar diesters of fumaric acid,
Ako vazbových prostriedkov je možná použil oelý rad známých silanov, ako nenasýtené trialkoxysilony, zvlášl 3-metakryloxypropyltrimetoxyailan, 81 už vo formě hydrolyzátov, alebo emulzi!, adukty aminoaialnov s epoxidovými živioami, metakrylchrómohlorid, titanáty ako izopropyldimetakryltitanát apod.A number of known silanes can be used as coupling agents, such as unsaturated trialkoxysilones, in particular 3-methacryloxypropyltrimethoxyilane, 81 already in the form of hydrolysates or emulsions, adducts of aminoaials with epoxy resins, methacrylchlorochloride, titanates and acrylates such as isopropyl.
Zlepšenio antistatických vlastností sa dosahuje přídavkem hydroskopickýoh látok, hlavně anorganických solí, a/alebo kationickými dusíkatými derivátmi ako laurylamidoetylpyridinium chlorid, sulfáty oxyetýlovaných alkylamínov, mastných kyselin apod., ktorá spravidla plnia aj úlohu zmáSadla 81 mazadla nakolko znižujú povrchové napatie lubrikaSnej kompozíoie.The improvement of antistatic properties is achieved by the addition of hygroscopic substances, mainly inorganic salts, and / or cationic nitrogen derivatives such as laurylamidoethylpyridinium chloride, sulphates of oxyethylated alkylamines, fatty acids and the like, which generally also act as a lubricant 81
V případe potřeby može lubrikácia obsahoval regulátor pH ako kyselina octová, mrav8ia, chlorovodíková, ktoré sa najSastejžie používajú pri přípravě hydrolyzátov silanov, 81 zásady, hlavně 8pavok, ktorý sa používá k hydrolýze metakrylchr&aohloridu. Pri použití vazbových prostriedkov vo forme emulzií je ich možné stabilizoval známými postupmi za použitia tenzidev, ochranných koloidov a stabilizátorov. Ako plastiflkátor kopolymérov je možné použil oelý rad známých zlúéenín. Sú to hlavně monomérne estery kyseliny ftalo' vej, adipovej, polyestery, polyesterpolyoly, polyéterpolyoly 81 leh kombináoie. Funkoiu mazadiel skloněných vlákien majú látky schopné znlžoval napatie pri textilnom a teohnologickom spracovaní vlákien 81 výrobkov na ich báze. Medzi najoblúbenejšie patrla rožne aminoamidy a imidazolíny na báze mastných kyselin a alifatických polyamínov. ZmáSadlá, tj. látky amfipatickóho charakteru znižujú povrchové napatie lubrikáoie, 8ím sa zlepšuje prooes povliekania skleněných vlákien. NajSastejšie sa používajú rožne deriváty etylénoxidu a/alebo propyldnoxldu. Textlíná vlastnosti, predovšetkým tuhoal pramoňov a pramenoov vlákien, je možné spolu a povrchovými vlaatnoalami vlákien reguloval kombináoiou a polymárnymi disperziami, hlavně polyvinylaoetátom, kopolymérom vinylaoetát-akrylát a styrén-akrylát. Přídavky epoxidovanýoh a polyesterových živíc sú predovšetkým vhodné pri formulácii lubrikáolí teohnológiou strlekania. Vyšší obsah epoxidovanýoh živio je potřebný v případe lubrikáolí určených k výrobě skleněných vlákien používaných hlavně pre textilné spraoovánie na tkaniny.If necessary, the lubrication may contain a pH adjuster such as acetic acid, formic acid, hydrochloric acid, which are most commonly used in the preparation of silane hydrolysates, 81 bases, mainly ammonium, which is used to hydrolyze methacrylic chloride. By using emulsion binders, they can be stabilized by known methods using surfactants, protective colloids and stabilizers. A variety of known compounds can be used as plasticizers for copolymers. These are mainly monomeric esters of phthalic acid, adipic acid, polyesters, polyester polyols, polyether polyols and other combinations. The function of the fibers of the inclined fibers has substances capable of reducing the tension in the textile and theological processing of the fibers of 81 products based on them. Among the most popular were barbecue aminoamides and imidazolines based on fatty acids and aliphatic polyamines. Lubricants, ie. amphipathic substances reduce the surface tension of the lubricant, thereby improving the coating process of the glass fibers. Most commonly, various derivatives of ethylene oxide and / or propylene oxide are used. The textile properties, in particular the stiffness of the strands and the strands of the fibers, can be controlled together and with the surface fibers of the fibers by combination and polymer dispersions, mainly polyvinyl acetate, vinyl acetate-acrylate copolymer and styrene-acrylate. The additions of epoxidized and polyester resins are particularly suitable for the formulation of lubricants by spray theory. A higher content of epoxidized nutrients is needed in the case of lubricants intended for the production of glass fibers used mainly for textile processing into fabrics.
Všetky uvedená možnosti regulácie vlastností lubrikáoie sú odborníkem známo a hlavně závisle od podmienok technologie výroby a spraoovania skloněných vlákien.All the mentioned possibilities of regulating the properties of the lubricant are known to the person skilled in the art and mainly depend on the conditions of the technology of production and processing of inclined fibers.
Pri aplikaSnýoh skúškach roznyoh kopolymérov vinylacetát-maleinát sme zlatili, že a množatvom obsahu maleinátu významné atúpa, zvyšuje sa zmášavosl a rozpustnost kopolymámou lubrikáoiou upravených skleněných vlákien v laminaSnýoh živioiach, a to aj v případe, kež pri emulznej kopolymorizáoii bol použitý ako ochranný koloid polyvinylalkohol. V tabulko 1 sú uvedené vlastnosti kopolymérnyoh disperzi! vinylaoetát-dibutylmaloinát a režným obsahom komonoméru. Tvrdost filmov bola hodnotená pódia metódy ČSN 67 3075 a rozpustnost vážkovou metodou na základe rýohlosti rozpúšlania filmu kopolyméru v styréne, který je najéastejšie používaný ako monomérne reaktivně riedidlo nenasýtenýoh polyesterových živio.In tests of various vinyl acetate-maleate copolymers, we found that the amount of maleate content significantly increased the wettability and solubility of copolymer lubricated glass fibers in laminated resins, even when the emulsion copolymer was used as an emulsion colloid alcohol. Table 1 shows the properties of the copolymer dispersion! vinyl acetate dibutyl malonate and the comonomer gray content. The hardness of the films was evaluated according to the ČSN 67 3075 method and the solubility by the gravimetric method based on the rate of dissolution of the copolymer film in styrene, which is most often used as a monomer reactive diluent of unsaturated polyester resins.
Tabulka 1 dibutylmaleinát vinylaoetát tvrdost rozpustnost v styréne (% hmot.) hmot.) (8. tužky) (mg.om-2.h-1)Table 1 dibutyl maleate vinyl acetate hardness solubility in styrene (% by weight) by weight) (8th pencil) (mg.om - 2.h -1 )
8,6 10,5 ’δ,'* 19,18.6 10.5 ’δ,’ * 19.1
CS 267 790 B1CS 267 790 B1
KeDžo jo známe, že polyvinylalkohol je separátor polyesterových živíc, je výhodné pri syntézo kopolymórov podlá vynálezu používal bu3 tonzidy, s výhodou neiónové, napr. deriváty celulózy, hlavně hydroxyetylcelulózu. Týmto sposobom sa rozj>ustnosl kopolymórov v styréne zvyšuje na hodnotu 20 až 35 mg.cm ,h v závislosti od obsahu dialkylmaleinátu.Since polyvinyl alcohol is known to be a separator of polyester resins, it is preferred in the synthesis of the copolymers according to the invention to use buz tonsides, preferably non-ionic, e.g. cellulose derivatives, mainly hydroxyethylcellulose. In this way, the solubility of the copolymers in styrene increases to 20 to 35 mg.cm, depending on the dialkyl maleate content.
Skloněná vlákna upravené lubrikáoiami podlá vynálezu sú zvlášl vhodné ako výstuž nonasýtených polyesterových živio, či už vo formě rohoží, sekaných a nekonečných prameňov a pramencov. Možu nájsl aj uplatnenie ako výstuž termoplastov, ktoré sa čoraz viac používajú ako konštrukčný materiál.The lubricated fibrous fibers of the present invention are particularly useful as a reinforcement for unsaturated polyester resins, whether in the form of mats, chopped and endless strands and strands. They can also be used as a reinforcement for thermoplastics, which are increasingly used as a construction material.
Vynález jo Sálej objasněný formou príkladov.The invention is illustrated by way of example.
Příklad 1 .Example 1.
Do nádoby opatrenej miešadlom sa přidalo 2 1 vody a 10 g kationického silanu (sušina 50 Jí hmotnosti) vzorca CII3 + CH =CCOO(CH )„(CH )„N(CH ) Si(OCH ) 0C(CH ) OHCCOCH .ClTo a stirred vessel were added 2 L of water and 10 g of cationic silane (dry weight 50 L by weight) of formula CII 3 + CH = CCOO (CH) n (CH) n N (CH) Si (OCH) OC (CH) OHCCOCH. Cl
V osobitnej nádobě sa zmiešalo 5 β dibutylftalátu, 10 g 3-n>etakryloxypropylmotoxysilanu, 3,5 g blokového etylénoxid-propylénoxidového kopolyméru o priemernej molekulovej hmotnosti 3 000 s obsahom vlaženého etylénoxidu kO $ hmotnosti, 1,5 g nonylfenolu oxyetylovaného 9 mólmi etylénoxidu, po homogenizáoii sa kompozíoia emulgovala vodou za použitia mixóra a vzniknutá emulzia sa přidala k roztoku kationiokého silanu. V teplej vodě sa rozpustilo 5 g laurylamidoetylpyridínium chloridu, 20 g chloridu lítneho a přidalo sa za miešania ku kompozici!, Po přidaní 300 g kopolymérnej disperzie (sušina 52 % hmotnosti) zloženej z 93 í hmotnosti vinylaoetátu a 7 £ hmotnosti dibutylmaleinátu, stabilizovanéj tenzidmi, sa lubrikácia doplnila vodou na objem 10 1. Připravená lubrikáoia má pH=6,9 a povrchové napatie 32 mN.m“ pri 20 °C. Rozdelovanie ani sedimentáoia lubrikácie nebola pozorovaná ani po 2 dňooh stánia. Rovnakým sposobom bola připravená lubrikácia, ktoré namiesto kopolyméru vinylaoetát—dibutylmaleinát obsahovala rovnaké množstvo homopolymóru polyvinylaoetátu. Lubrikáoiou upravené skloněné vlákna sa vysušili pri 120 °C po dobu 6 h. Meranie zmáčavosti takto upravených vlákien bolo uskutečňované v nenasýtenej polyesterovéj živioi podía DIN 53 396 a dosiahnutó výsledky sú uvedené v tabulko 2,In a separate vessel, 5 β of dibutyl phthalate, 10 g of 3- n- ethacryloxypropylmotoxysilane, 3.5 g of a block molecular weight of ethylene oxide-propylene oxide copolymer with an average molecular weight of 3,000 containing lukewarm ethylene oxide of 0% by weight, 1.5 g of nonylphenol oxyethylated with 9 moles of ethylene oxide were mixed. after homogenization, the composition was emulsified with water using a mixer, and the resulting emulsion was added to a cationic silane solution. 5 g of laurylamidoethylpyridinium chloride, 20 g of lithium chloride were dissolved in warm water and added with stirring to the composition. the lubrication was made up to 10 l with water. The prepared lubricant has a pH = 6.9 and a surface tension of 32 mN.m “at 20 ° C. No distribution or sedimentation of lubrication was observed even after 2 days of standing. In the same manner, a lubricant was prepared which contained the same amount of polyvinyl acetate homopolymer instead of the vinyl acetate-dibutyl maleate copolymer. The lubricated fibrous fibers were dried at 120 ° C for 6 hours. The measurement of the wettability of the fibers thus treated was carried out in an unsaturated polyester resin according to DIN 53 396 and the results obtained are shown in Table 2.
Tabulka 2 .Table 2.
Transparenci» (% T/s) podía vynálezu 60/15 70/30 7k/6O 78/120 polyvinylacetát 55/15 65/30 ?0/60 76/120Transparency »(% T / s) according to the invention 60/15 70/30 7k / 6O 78/120 polyvinyl acetate 55/15 65/30? 0/60 76/120
Příklad 2Example 2
K 2 1 vody sa za miešania přidalo 20 g 3-(2-amlnoetyl)aminopropyltrlmetoxysilanu, 1 kg kopolymémej disperzie vlnylaoetát-dlbutylmaleinát (sušina 59 % hmotnosti) s róznym obsahom komonoméru, kO g dimetylsulfátom kvartenlzovanóho oktadocylamínu oxyetylovaného 20 mólmi etylénoxidu a kompozíoia sa doplnila vodou na objem 10 1. Skleněné vlákna o priemernej hrúbke 15 /um s 200 vláknami v prameni sa po upravení příslušnou lubrikáoiou vysušili pri 120 °C po dobu 6 h. Vlastnosti upravených skleněných vlákien sú uvedené v tabulko 3.To 2 l of water was added with stirring 20 g of 3- (2-aminoethyl) aminopropyltrimethoxysilane, 1 kg of a copolymer dispersion of fluoroacetate-dlbutyl maleate (dry weight 59% by weight) with different comonomer content, 10 g of dimethyl sulphate of quaternized octadocylaminoethylammonium oxyethylamine water to a volume of 10 1. Glass fibers with an average thickness of 15 .mu.m with 200 fibers in the strand were dried at 120 DEG C. for 6 hours after treatment with an appropriate lubricant. The properties of the treated glass fibers are given in Table 3.
CS 267 790 BlCS 267 790 Bl
Tabulka 3 dibutylmaleinát vinylacetát lubrikačný nános tuhost hmot.) (% hmo t,) (% hmot.) (cm)Table 3 dibutyl maleate vinyl acetate lubricating coating stiffness by weight (% by weight) (% by weight) (cm)
Příklad 3Example 3
K 2 1 vody sa za miešania přidalo 20 β kyseliny ootovej, 5 g aduktu epoxidováj živice na váze dianu o priomernej molekulovej hmotnosti 380 g s 3-(2-aminoetyl)aminopropyltrimetoxysilanom v molárnom pomere 1 : 3,7 a 15 β 3~lnetakryloxypropyltrimetoxysilanu. Po 0,5 h miešania sa přidalo 30 g dimetylsulfátom kvartenizovaného oktadeoylaminu oxyetylovaného 20 mólmi etylénoxidu, 500 g kopolyméru (sušina 52 % hmotnosti) na báze 93 £ hmotnosti vinylaoetátu, 7 % dibutylmaleinátu a lubrikácia sa doplnila na objem 10 1.To 2 1 of water while stirring was added 20 β of acetic acid, 5 g of resin adduct epoxidováj weight Diana priomernej a molecular weight of 380 g with 3- (2-aminoethyl) aminopropyltrimethoxysilane in a 1: 3.7 and 15 3-β Inc. takryloxypropyltrimetoxysilanu . After stirring for 0.5 h, 30 g of dimethyl sulfate quaternized octadeoylamine oxyethylated with 20 moles of ethylene oxide, 500 g of copolymer (dry matter 52% by weight) based on 93% by weight of vinyl acetate, 7% of dibutyl maleate were added and the lubrication was made up to 10 l.
Rozdělovánie ani sedimentáoia lubrikácia nebolo pozorované ani po 2 dňooh 3tánia, penivost lubrikáoie metódou Ross-Mitlesa v Sase 0 Je 30 mm, povrchové napatie 41 mN.m-1 pri 20 °C a pH Je 3,5, V případe potřeby Je možné penivosí eliminoval prídavkom odpeňovaSov, zvlášt na báze silikonových Si olejových roztokov a emulzi! v množstve 0,001 až 0,5 jó hmotnosti. Lubrikáoiou upravené skleněné vlákna o priemernej hrúbke 11 obsahujú 0,50 jí hmotnosti povlaku, majú tuhost po opracovaní do rofingových o i cvek 10,0 cm a povrchový potenciál podlá Ss.aut.osv.S. 215 536 350 V.Distribution or sedimentary lubrication was not observed even after 2 days of melting, foaming of lubrication by Ross-Mitles method in Sase 0 is 30 mm, surface tension 41 mN.m -1 at 20 ° C and pH is 3.5. eliminated by the addition of defoamers, especially on the basis of silicone oil solutions and emulsions! in an amount of 0.001 to 0.5 .mu.g by weight. Lubricated glass fibers with an average thickness of 11 contain 0.50 .mu.m by weight of the coating, have a stiffness after processing into rofing lines of 10.0 cm and a surface potential according to Ss.aut.osv.S. 215 536 350 V.
Příklad 4Example 4
Lubrikácia sa připraví postupem ako v příklade 3, s tým rozdielom, že sa použije kopolymér na báze 84 % hmotnosti vinylaoetátu, 16 hmotnosti bis(2-etylhexyl)maleinátu modifikovaný 10 hmotnosti dibutylftalátu v množstve 800 g. Připravená lubrikácia má pH 4,2 a povrchová napatie pri 20 °C 39 mN.m”1. Lubrikáoiou upravené skleněné vT/tma o priemernej hrúbke 15 ^um obsahujú 0,88 hmotnosti povlaku, majú tuhost 13,5 cm a povrchový potenciál 410 V. V případe potřeby Je možné znlžil povrchový potenciál prídavkom 0,3 hmotnosti chloridu lítneho na 40 V.Lubrication was prepared according to the procedure of Example 3, except that a copolymer based on 84% by weight of vinyl acetate, 16% by weight of bis (2-ethylhexyl) maleate modified with 10 parts by weight of dibutyl phthalate in an amount of 800 g was used. The prepared lubrication has a pH of 4.2 and a surface tension at 20 ° C of 39 mN.m ” 1 . Lubricated glass vT / dark with an average thickness of 15 .mu.m contain 0.88 parts by weight of coating, have a stiffness of 13.5 cm and a surface potential of 410 V. If necessary, it is possible to reduce the surface potential by adding 0.3 weight of lithium chloride to 40 volts.
Příklad 5Example 5
K 2 1 vody s obsahom 5 β kyseliny ootovej sa za miešania přidá 30 8 3-(2-aminoetyl)ominopropyltrimetoxysilenu, 20 g emulzie epoxidovéj živioe na báze dianu o priemernej molekulovej hmotnosti 380, 50 g emulzie (sušina 12,5 % hmotnosti) amínoamidu kyseliny olejovej s dietyléntriamínom solubilizovaný kyselinou ootovou, 20 g chloridu lítneho, 600 g kopolyméru na báze 90 % hmotnosti vinylaoetátu, 10 % hmotnosti dibutylmaleinátu (sušina 52 jí hmotnosti) a doplní sa vodou na objem 10 1. Připravená lubrikácia má pH 5,1 a povrchové napatie 40 mN.m”1 pri 20 °C. Upravené skleněné vlákna o priemernej hrúbke 13 zum obsahujú 0,71 % hmotnosti povlaku, majú tuhost 11,5 cm a povrchový potenciál 60 V,30 g of 3- (2-aminoethyl) ominopropyltrimethoxysilene, 20 g of a diane-based epoxy resin emulsion with an average molecular weight of 380.50 g of emulsion (dry matter 12.5% by weight) are added to 2 l of water containing 5 β of ootic acid with stirring. oleic acid amine amide with diethylenetriamine solubilized with ootic acid, 20 g of lithium chloride, 600 g of copolymer based on 90% by weight of vinyl acetate, 10% by weight of dibutyl maleate (dry matter 52 by weight) and made up to 10 l with water. The prepared lubrication has a pH of 5.1 and a surface tension of 40 mN.m -1 at 20 ° C. The modified glass fibers having an average thickness of 13 microns containing 0.71% by weight of the coating, the stiffness of 11.5 cm have a surface potential of 60 V,
Příklad 6Example 6
Lubrikácia sa připraví postupem ako v příklade 5, a tým rozdielom, že sa použije 300 g uvedeného kopolyméru a 300 g polyvinylácetátovéj disperzie (sušina 52 Jí hmotnosti), Týmto sposobom je možné připravit upravené skloněné vlákna so zvýšenou tuhostou o hodnotěLubrication was prepared according to the procedure of Example 5, except that 300 g of said copolymer and 300 g of polyvinyl acetate dispersion (dry weight 52% by weight) were used.
CS 26? 790 BlCS 26? 790 Bl
13,5 cmPříklad 713.5 cmExample 7
K 2 1 vody sa za miešania přidá 100 g komplexu metakrylohróm chloridu a 20 g 1 roztoku Čpavku. K hydrolyzátu sa přidá 10 g emulzie aminoamidu a roztok připravený hydrolýzou 30 g 3-™etakryloxypropyltrimetoxysilanu v přítomnosti 5 g kyseliny ootovej a 2 g oxyetylovaného nonylfenolu 9 mólmi etylénoxidu. Nakonieo sa přidá 700 g polyesterová j emulzie (sušina 40 $ hmotnosti) a 500 g kopolyméru vinylaoetát-dibutylmaleinát ako v příklade 1. Upravené skloněné vlákna s 1,1 % hmotnosti povlaku sú vhodné k výrobě sklolaminátov teohnológiou etriekania.100 g of methacrylochlor chloride complex and 20 g of 1 ammonia solution are added to 2 l of water with stirring. To the hydrolyzate are added 10 g of an aminoamide emulsion and a solution prepared by hydrolysis of 30 g of 3-ethacryloxypropyltrimethoxysilane in the presence of 5 g of ootic acid and 2 g of oxyethylated nonylphenol with 9 moles of ethylene oxide. Finally, 700 g of polyester emulsion (dry weight 40% by weight) and 500 g of vinyl acetate-dibutyl maleate copolymer as in Example 1 are added.
Příklad 8Example 8
Lubrikáoia sa připraví postupom ako v příklade 7, * tým rozdielom, že namiesto komplexu tne t akry lahróm chloridu sa použije ekvivalentně množstvo titanacetanylaoetonátu.The lubricant was prepared according to the procedure of Example 7, except that an equivalent amount of titanium acetanyl oleateate was used instead of the acrylamide chloride complex.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS886394A CS267790B1 (en) | 1988-09-28 | 1988-09-28 | Lubrication for glass fibres treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS886394A CS267790B1 (en) | 1988-09-28 | 1988-09-28 | Lubrication for glass fibres treatment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS639488A1 CS639488A1 (en) | 1989-07-12 |
| CS267790B1 true CS267790B1 (en) | 1990-02-12 |
Family
ID=5410881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS886394A CS267790B1 (en) | 1988-09-28 | 1988-09-28 | Lubrication for glass fibres treatment |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS267790B1 (en) |
-
1988
- 1988-09-28 CS CS886394A patent/CS267790B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS639488A1 (en) | 1989-07-12 |
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