CS267771B1 - A method of purifying waste water from asbestoseactive production - Google Patents

A method of purifying waste water from asbestoseactive production Download PDF

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CS267771B1
CS267771B1 CS881644A CS164488A CS267771B1 CS 267771 B1 CS267771 B1 CS 267771B1 CS 881644 A CS881644 A CS 881644A CS 164488 A CS164488 A CS 164488A CS 267771 B1 CS267771 B1 CS 267771B1
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sludge
water
tank
production
sludge water
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CS881644A
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Czech (cs)
Slovak (sk)
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CS164488A1 (en
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Frantisek Bisaha
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Frantisek Bisaha
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Abstract

Riešenie sa týká tpotobu Ustenia odpadové} kalovej vody z azbestoeementového priemyslu a rieši neutralizéciu kalovej vody ÍJ pH na.gH 6 až 8 a redukciu chrómu Cr° na Cr , Podstata spočívá v tom, že redukda chrómu a neutrelizácia pH sa prevádza naraz v čelom objeme vypuatenej odpadové} kalovej vody posobenlra skalice zelenej a oxidu uhličitého v rozvirenej kalovej vodě prlano v nédržl kalovej vody bez dávkovania do zariadenia čistiacej stanice odpadovej vody.The solution concerns the process of wastewater sludge water discharge from the asbestos cement industry and solves the neutralization of sludge water pH to pH 6 to 8 and the reduction of chromium Cr° to Cr. The essence is that the reduction of chromium and pH neutralization are performed simultaneously in the main volume of discharged wastewater sludge water, with the addition of green slag and carbon dioxide in the stirred sludge water, washed in a sludge water tank without dosing into the wastewater treatment plant equipment.

Description

CS 267 771 Θ1 1EN 267 771 Θ1 1

Vynález s* týk» sposobu člstenla odpadovej kalovej vody z a zbestocenentoveJ vý-roby obsahujůccj zlúčenlny chrómu Cr a alkalitou 12 pH.The present invention relates to a method for sludge drainage from and to the production of a product comprising Cr Cr compounds and 12 pH alkalinity.

Prl výroba azbestocementových výrobkov dochádza v prlebehu výroby a hlavně po Jejpreruienl k vypustenlu odpadovej kalovej vody, ktori obsahuje ceaent, azbeat a partit.Uvedeni pevni zloiky vytvirajú odpadovi kaly.The production of asbestos-cement products occurs in the course of production and, in particular, the release of waste sewage containing ceaent, azbeat and partite.

Kalová voda aa sústreóuje v nádrži kde aa mlela kalovými čerpadlami, aby tazabránilo sedimentácll kalov a zároveň aa přečerpává do čiatiecej atanlce odpadovýchvffd. Dávkováním akallce zelenej v množatve 2,8 - 3 kg/·3 prebieha redukcla chrómuna Cr3 + a posobenlm oxidu uhHČItiho v reaktore v množatve 7,5 - 8 kg/»3 ta dotlahlaten při nlzkej koncentricH kalu neutrallzácia vody z 12 pH na 8 pH, a následnýmpřečerpáváním do gravltačniho zásobnlka, kde prebieha aeparácla kalu, ktorý aa lisujena páaovom I1ae a oddělaná voda sa využívá na technologická účely, alebo odchádzaako voda odpadová. Nízký ilstlacl efekt, vysoká alkallta vyčlstenej odpadovej vody nevyhovuje dnei-nýa požladavkaa na čistotu vypůltanej vody a ochranu žlvotniho prostredla.Sludge water and and concentrates in the tank where aa mills the sludge pumps to prevent sludge sedimentation and, at the same time, pumped into the wastewater treatment facility. By dosing akallka green in the amount of 2.8 - 3 kg / · 3, the reduction of Cr3 + chromium and the post-carbonation of the carbon monoxide in the reactor in the amount of 7.5 - 8 kg / 3 and 3 liters at a low concentration of sludge water neutralization from 12 pH to 8 pH , followed by pumping to the gravel container, where the sludge takes place and which is compressed by the steam and the separated water is used for technological purposes or waste water leaves. The low ilelation effect, the high alkali leached wastewater does not meet today's demand for cleanliness of the drained water and protection of the glandular environment.

Uvedený spoaob člstenla azbestoceaentovej odpadovej vody je nevýhodný aj v tom.The aforementioned asbestoseacent wastewater is also disadvantageous.

Ze výkon člstlacej stanice je limitovaný objemom člstiaclch zarladenl, ktori sa zaná-lajú kalou a aú náročná na čistěním, údržbu a obsluhu. Přídavná voda používaná na čis-tenle zarladenl spósobuje prebytok vody a dochádza k rledenlu kalovej vody v nádržia tým k zaene jej chemlckiho zloženla a k predlženlu doby člstenla.The power of the booster station is limited by the volume of the screed traps that are clogged with the sludge and difficult to clean, maintain and service. The additional water used in the clarifier causes excess water, and the sludge water in the reservoir is precipitated, thereby causing its chemical composition to deteriorate.

Vyllle uvedeni nevýhody odstraňuje navrhnutý spoaob člstenla odpadovej vody z az-beatocenentovej výroby podta vynálezu, vyznačujúceho aa tým, že do celáho množstva ka-lovej vody vypuatenej z ezbestocementovej výroby, sústredenej v kalovej nádrži, »1«la-nej kalovými čerpadlami dávkujeme 2,8-3 kg/m3 skalice zelenej a na výtlačnú stranu ka-lových čerpadlel prlvádzame oxid uhličitý v množatve 7,5-8 kg/»3. M1elan1e kalovej vodyv nádrži možeme prevleat tiež známými rotačnýml »1elača1 pr1 aúčasnom přívode oxiduuhHČItiho do spodnej časti nádrže. Vířením kalovej vody v nádrži doslahneme preale-lanle a vaielanle oxidu uhličltáho a akallce zelenej s následnou neutral1záclouna pH 6 až 8 a redukclu Cr6+ na Cr3+ bez poatupniho spracovanla na zarladenl člstlacejstanice odpadovej vody.Accordingly, the disadvantage of this invention is eliminated by the proposed waste water drainage system of the invention, characterized by the fact that 2 liters are dispensed into the entire amount of hot water discharged from the non-cement production, concentrated in the sludge tank. 8-3 kg / m3 of vitrified green, and carbon dioxide of 7.5-8 kg / 3 is fed to the discharge side of the boiler pumps. Also, the sludge water in the reservoir can also be known by the known rotary pressurizer and the current feed of carbon monoxide to the bottom of the tank. By swirling the sludge water in the reservoir, we achieve a preale-lance and a carbon dioxide and a cola of green carbon with a subsequent neutralization of pH 6 to 8 and a Cr6 + reduction to Cr3 + without treatment to form a waste water stopper.

Vyčlatenle odpadovej kalovej vody s vylúčenlm použltla zarladenl člstlacej sta-nice ako neutra11 začniho reaktora a óalHch přídavných zarladenl by sa dosiahlo zvýle-nie produktivity práce, zniženle nákladov na údržbu, znlženie spotřeby elektrickejenergie a investlčných nákladov na výstavbu člstlacej stanice odpadovej vody. Přiklad 1The effluent sludge with the excrement used used to set up the feed station as a neutral reactor, and additional auxiliaries would increase labor productivity, reduce maintenance costs, reduce electricity consumption, and reduce the cost of building a sewage waste station. Example 1

Redukala zlúčenln chrómu c/* na Cr3+ a neutrallzácia pH 12 na pH 8 sa prevádzav nádrži kalovej vody o obsahu 250 »3, kde sa kalová voda z azbestocementověj výrobysústreóuje a mlela kalovými čerpadlami.It reduced the c? + Compound to Cr3 + and neutralized pH 12 to pH 8 with a slurry water tank of 250? Where the asbestos-cement sludge water was sprayed and milled with sludge pumps.

Redukcla zlúčenln chrómu Cr^ + na Cr3+ aa prevádza prlamo v nádrži kalovej vody,kde aa na 1 m3 dávkuje 2,8 - 3 kg skalice zelenej, ktorá sa a kalovou vodou zaleiaa redukuje na Cr^+ na Cr3+. Takto upravená voda obsahuje 0,1 mg/l chrómu Cr^+ maximál-ně 2 ng/l chrómu Cr3+. Súčasne s redukclou chrómu prebieha neutrallzácia 12 pH na 8 pH přidávaní» plyn-niho oxidu uhličltáho v množatve 7,5-8 kg/»3 na výtlačnú stranu kalových čerpadlel.The reduction of the Cr 3 + a chromium compound to Cr 3+ aa converts in the sludge water tank, where aa per 1 m 3 dosed 2.8 - 3 kg of green vitriol, which is reduced to Cr 3+ and Cr 3+ by sludge water. The water thus treated contains 0.1 mg / l of Cr3 + chromium + 2 ng / l of Cr3 + chromium. Simultaneously with the reduction of chromium, neutralization of 12 pH takes place at 8 pH of the addition of gaseous carbon dioxide at a rate of 7.5-8 kg / 3 to the discharge side of the sludge pumps.

Claims (1)

2 CS 267 771 B1 Přiklad 2 Odpadová kalová voda sa kontinuálně dopravuje do nádrže, kde sa i»1eia mechanic-kým rotaínýn mleSaiom prlíom sa do nádrže dávkuje roztok skalice zelenej v množstve2,8 - 3 kg /a3 a na dno nádrže sa dávkuje oxid uhličitý 7,5 - 8 kg/m^ člstenej kato-vej vody, ktorý sa s kalovou vodou premleía a tým znlžl jej alkalltu na 8 pH, Redu-kovaná a neutralizovaná kalová voda sa dopravuje do 5trb1novej sed1 ment ač nej nádržekde dochádza k sedimentácil katu. Oddělená voda sa prlvádza do Saliej sed1 ment ačnejnádrže, kde ledlaentujů nerozpustná tátky. Takto vyčištěná voda sa vypúita do kana-llzácle, alebo sa spotřebuje vo výrobě. A zbestoceraentový sediment zo itrblnovej od-vodnovacej nádrže sa vyváža mechanlzmarni na určenu skládku ako odpad s maxlmálnymobsahom 2 mg/l Cr3+ a 0,1 rag/l Cr^+. Uvedený sposob čistenla odpadovej kalovej vody z azbestocementovej výroby je možné využit vo vietkých podnlkoeh azbestocementováho prlemystu, lebo navrhnutý sposobčistenla odpadovej kalovej vody využívá sůčasné technologická zarladenla, hlavně vy-budovaná nádrže kalovej vody, v ktorých sa prevedle llkvldácia odpadu z a zbestocemen-tovej výroby, bez potřeby 1nvest1čnej výstavby člstiacej stanice odpadovej kalovejvody. PREDMET VTnXlEZU Sposob Čistenla odpadovej kalovej vody z azbestocementovej výroby obsahujůcejzlúčenlny chrómu Cr*+ s alkatltou 12 pH sůstredenej v kalovej nádrži a mlelanej kalo-vými čerpadlaml, alebo mechanickými v1r1čmi pósobenlm skalice zelenej a oxidu uhliči-tého, vyznačujúcl sa tým, ie do cetáho množstva člstenej kalovej vody sa dávkuje2,8 až 3,5 kg/m^ skalice zelenej a do rozvirenej kalovej vody sa prlvádza oxid uhli-čitý v množstve 7,5 až 9,5 kg/m·5.2 CS 267 771 B1 Example 2 Sewage sludge water is continuously conveyed to the tank, where a green rock solution is dosed into the tank by a mechanical rotain with a quantity of 2.8 - 3 kg / a3 and an oxide is dispensed to the bottom of the tank. carbon dioxide of 7.5 - 8 kg / m 2 of treated water, which is slurried with sludge water and thereby reduced its alkali to 8 pH, the reduced and neutralized sludge water being conveyed to the 5-bed sedimentation tank where sedimentation occurs katu. The separated water is fed to Salia's sedimentation tank, where the insoluble melts are ice-cooled. The purified water is discharged into the canister or consumed in production. And the sedimentation sediment from the itrbline drainage tank is exported mechanically to the designated landfill as waste with a maximum content of 2 mg / l Cr3 + and 0.1 rag / l Cr ^ +. This method of sewage sludge purification from asbestos-cement production can be used in larger asbestos-cement bedding because the designed sewage sludge treatment utilizes the current technological equipment, mainly the built-up sludge tanks, where the waste disposal is carried out with a cement-based production, without the need for a 1-year construction of a sewage drainage station. SUBJECT MATERIAL Waste water treatment from asbestos cement production contains Cr * + chromium compounds with alcatlt 12 pH in the sludge tank and milled with sludge pumps, or by mechanical agitation of green and carbon dioxide. 2.8 to 3.5 kg / m 2 of green rock is metered into the spent sludge water and carbon dioxide is introduced into the shredded sludge water in an amount of 7.5 to 9.5 kg / m · 5.
CS881644A 1988-03-14 1988-03-14 A method of purifying waste water from asbestoseactive production CS267771B1 (en)

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