CS263481B1 - Copy paper coating - Google Patents

Abstract

The product used as the non-precipitating brown coal wax is the crystallization product of crude wax from gasoline with a Ubelohde drop point of 85 to 86 °C, a saponification number of 87 to 90, an acid number of 26 to 29 and a resin content of 1.86 to 2.0 at a weight composition of the coating t

Description

1 ΟΠΗΟΑΗΗΕ H3OBPETEHHB TO ABTOPCKOMY ΟΒΚΠΕΤΕΠΒΟΤΒΥ 3aHBJieHo: 28.04.84 3a «BKa« · 3734100728-12 MKH4 B 41 M 5/00

Abtopu: M.C.XaňKHH, JI.A.Kosjiob, Γ.Β.ΠΙτpetic, K) .U.

Ha3BaHne H3o6peTeHna: Coctsb ποκρμτηη KonnpoBa / n> Hoň 6yMarh

Hao6peTeHne othochtch k nponaBoflCTBy KonHpoBanbHoň OyMarn η Μοχετ 6brrbHcnojib3oBaHo b nenntoJio3Ho-6yMaxHoň npoMbmneHHocTH npH HsroTOBjíeHHH κοπκρο-BanbHoň 6yMaru MHoropásoBoro HCnojn> 3OBaHHH flJiH MamHHonHCH.

Uenbto Η3ο6ρετβΗΗΗ HBJíaeTCH noBnnnne rjuiHua h cmraceHne οτμθρμβηηηη. B KanecTBe πΗΓΜθΗτβ Ha ocHoBe caxH stotcocthb cortepjKHT caxy raaoByio κβ-HanbHyio wih ee cMecb c μοηογηαρητομ okhch xejies (xeJitMM xeneaooKHCHbM rinr-ΜβΗΤΟΜ). B KanecTBe Maca npHMeHHeTCH MHHepanbHoe Macao, HanpHMep, HHnycTpHanbHoewih CMecb MHHepaabHoro h pacTHTenbHóro (KacTopoBoro) Macea. B KaaecTBe noHoreHHoro nonHMepHoro ffucnepraTopa cocTae ποκρμτηη κοπκρο-BaabHoň 6yMarw coaepxHT HaTpHňCyTaAHeHoBbift Kayayx c nnůCTHHHocTbtQ HNU conoaHMep OyTaflHeHa 0.62 to 0.66 · H 2 MeTnn-5-c BHHnjinnpnAHHa MoaeKynapHoft MAC-CON 3000-30000.

BbnneyKa3aHHbie κοΜποΗβΗΤΜ μοχηο ββοαητβ b cocTaB ποκρητηβ KonupoBaabHoon6yMarn HHAHBHjayajibHo wih b BHAe cneuHaJibHbK caxeBbix nacT.

Bypass CypoyroabHoro Bocxa, 6CoMoMoNoNoCoMeNoMeH3HHa, b cocTaBeRoMeCoMeNoMyoMyH, noBbunaeT nOKasaTenb raHHija h chh-xaeT ero oTMapwBaHHe. Τ τ φ n n n n n n n n n n n n H H H H ep ep ep ep ep ep ep ep ep ep ep ep M M M M M M M M 263,481 -2- 06eccMOJieHHbiň SypoyroJibHbiň bock c coflepacaHHeM cmoji Bbnue 2.0% h-TeMnepa Typoň Mrač 85C ΗΜβετ 6oJiee hh3kog hhcjio ομμπθηηη (ηημ 87) Πρκ BBeflGHHH TaKOTO Bock B COCTaB κοπηροβηπβηογο ποκρμτηη Osecna HG-HBA-gtcb cymecTBeHHoe cHHaceHHe οτμηρμβηηηη h noBbroieHne rJiHHiia.

Bock c coflepacaHHeM cmoji HME 1.86% yflaeTCH nojiyflHTb jiranb πρκ ΜΗοτοκρβτ-hon KpncTajuiH3au HH H3 6eH3HHa what CHHaceHHeM Bbixofla nponyKTa, one hundred meters πρκ ΤβΜ-nepaTypa KanJienafleHHH o6eccMOJieHHoro BocX yBejiHHHBaeTCH He3HamrrejibHo c OFL-HOBpeMGHHblM BO3PaCTaHHeM HHCJia OMMJieHHH. ΠΟΒΜΠΙβΗΗβ TBepflOCTH BOCK 06yCJIOB ~ jiHBaeT oflHoBpeMeHHoe noBbnneHHe TBepflocTH KonHpoBaJibHoro ποκρμτηη, mh chh-aeT aflre3Hio ποκρμτηη to 6yMare-ocHOBe.

HeČoJibraoe H3MeH6HHe khcjiothoto nncjia y óypoyroJibHoro Bock oSeccMOJieHHo-ro KpHCTaJiJiH3au (Heiii H3 6eH3HHa, 3aMeTHoro bjihhhhh Ha noKa3aTejiH KonHpoBaJib-hon SyMarn Ile oKa3bmaeT, Πρκ ηρΗΜβΗβΗΗΗ CMeCH Bock ~ MOHTaHa Cbiporo H o6eCCMOJieHHoro 6ypoyroJibHoroBOCKa, noJiyneHHoro KpHCTajniH3aflHeň H3 6eH3HHa, cooTHomeHHe bockob eocTaBJín-βΤ OT 2.5: 1 flo 1: 2 ,. πρκ yBeJIHHeHHH COflepKaHHH BOCK3 "MOHTaHa Cbiporo b 3TOňCM6CH CHHStaeTCH TJlHHeu KOnHPOBaJIbHOro ΠΟΚΡΜΤΗΗ H yBCJIHHHBaeTCH OTMapbIBaHHe, πρκ BBefleHHH 3anpeflejibHoro KOJiHHecTBa o6eccMoJieHHoro 6ypoyroJibHoro Bock 3A1-TpyflHHeTCH flHcneprnpoBaHHe cocTaBa h HapymaeTCH paBHoMepHocTb HaneceHHH πο-κρμτηη, HTO b cbok) onepeflb TaKwe CHHacaeT BejmhHHy rjiHHiia ποκρμτηη. H3o6peTeHHe muiiocTpHpyeTCH cjieflyioniHMH npHMepaMH. IIpHMep 1 (πό ο3ο6ρβτβΗΗΚ>). B peaKTop py6aniKoň η c -MeniajiKoň 3arpyacaioTnapa <J) HH Bock-MOHTaH cbipoň.H oSeccMOJieHHbiň SypoyroJibHbiň Bock oSeccMOJieHHbiňKpHCTaJiJiH3ai | H3 HEN 6eH3HHa c TeMnepaTypoň KanJienafleHHH (no Y66ejiofle) 85 ° C HHCJIOM OMbUieHHH 87 KHCJIOTHblM HHCJIOM 29 coflepjicaHHeM CMOJI 1.86%. (BocKOByw CMecb pacnJiaBJíHioT πρκ nepeMemHBaHHH. The nojiyneHHoMy pacnJiaBy no-CTeneHHo flo6aBJiHioT caweByio loads coflepacamyro nenHyio cawy ^ HHflycTpHanbHoeMacJio h conoJiHMep SyTaflHeHa H 2-methyl-5-BHHHJuiHpflHHHa, pacTBop oJieaToB HH-flyjlHHa H MGTHJI ^ lHOJieTOBorO KpaCHTeJIH B OJieHHOBOň KHCJIOTe, KOTOPblň ΓΟΤΟΒΗΤ H3HHflHBHflyaJIbHbIX KpaCHTejieň H3BeCTHblM CnOCOÓOM, MOHĎTHflpaT OKHCH 3KeJie3a Η Flo ~ noJiHHTejibHoe KOJiHnecTBo HHflycTpnaJibHoro MacJia. CMecb nepeMeniHBaioT NPN TeMnepaType 100-110 ° C flo noJiyneHHH oflHopoflHoňMaccbi, KOTopyio 3βτβΜ neperapaioT oflHH PAA KpacKoTepKe Ha.

HoJiynaioT KonHpoBaJibHoe ποκρΗΤΗβ, coflepncamee (b Mac.%): Eaacy J7,8, moho-rnflpaT okhch Hcene3a 5.0, HHflyjiHH 0.7, ΗβτΗΠφκοιιττΒΜΗΒΜΗ KpacHTeJib. 0, conoIHMep SyTaflHeHaH 2, 2-Me-THI-5-BHHHiHHHHlHHa 1.2, napa}} HH 4.0, βοοκ-μοητθη cbipoon 12.0, bock 6ypo-yroHibiOn, cSecMMiHiHHiH KPHCTαJuH3aflHene H3 6eH3HHa, 24.0.

HaHocHT Ha 6yMary-ocHoBy Maccoň 1 m2 - 16 r πρκTeMnepaType 90 ° C Ha KpacKOHocnnieň MamHHe 10 t / m2. IIoJiyHaioT o6pa3flbi nepHoň KonHpoBaJibHoň SyMarn, κοτορμθ HcnbiTbiBaioT. Onpefle-JIHKJT KOJIHHeCTBO OflHOBpeMeHHbK H nOCJIeflOBaTeJIbHbK ΚΟΠΗΗ, OTMapbIBaHHe ΠΟΚΡΜ-ΤΗΗ KonHpoBajibHoon SyMarn h CMa3bfflaHHe οτπεπβτκοΒ Ha κοπηηχ.

KpoMe toto, c npHMeHeHHeM rjiHHflMeTpa onpefleJinioT nowaTenb rnHHfla κοπη-poBaJibHoro ποκρμτηη ÓyMarH.

PeayJibTaTbi ηοπμτηηηη npuBefleHbi b Ta6jiHfle. IIpHMep 2 (no H3o6peTeHHio). CocTaB ο ar π ρ y y y y y, y y y y h a y y 4,0 H y y y y y y y y ,1 ,1 ,1 ,1 ,1 H,,,,,,,,, -Toposoe Macjio 6.0 HaTpHň6yTaflHeHoBbiň KaynyK 0.4, 8.0 πβρβφΗΗ Bock-mohthhcbipoň 28.5 Bock 6ypoyroJibHbiň, o6eccMOJieHHbiň KpHCTajiJiH3anHeň H3 6eH3HHa, cTeMnepaTypoň KanJienafleHHH 86 DEG hhcjiom ομμπθηηη 90 khcjiothmm hhcjiom 29 h 263481-3 -. cowepxaHHeM cmoji 2.0% - 11.4, KonHpoBanbHyro 6yMary c sthm ποκρωτκβΜ nonyna- »τ h HcnbiTbroaioT and Hanorwmo npHMepy 1.

PesynbTaTbi ncnwTaHnn πρΗΒβΑθΗΗ b Ta6nHne. ΠρΗΜβρ 3 (no Η3θ6ρβτβΗ ο). CocTaB ποκρωτΗΗ KonHpoeanbHoň 6yMarH, what «ep-» amnft (b Mac -,%): caxy rasoByio KaHanbHyto 18.5, ΡΑΑΡβτ okhch xeneaa 5.2, HHnyJIHH 1.0, ΜβΤΗΠφΗΟΠβΤΟΒΜ &amp; KpaCHTejIb One., OneHHOByiO KMCJlOTy 4,3, HHfly-CTpHanbHoe Macno 26,1, HaTpnnCyTaRneHoBbiň KaynyK 1,6, napačbuH 8,0, bočk-MoHTaH cbipoň 15,5, bock CypoyronbHM, M M á ň ň ann H H H ° ° ° ° ° ° ,0 ,0 ° ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 ,0 c c c c c c c -roKpáTHoro nepeTHpa Ha κρβοκοτβρκβ.

KonHpoeaJibHyio ÓyMary nonynioT h HcnuTusaioT ananorHMHo npHMepy 1.

Pe3ynbTaTbi HcnbrraHHn πρκββββΗΜ B TaSnHiie. ΠρΗΜβρ 4 (no Η3θ0ΡβΤβΗΗΚ>), CoCTaB ΠΟΚΡΜΤΗΗ KOnHpoBaJlb ň CyMarH, COflGp-xame (b Mac,%): caxy 22,3, HHfliyJHM 1,0, ΗέτΗπφΗοπβτσΒωή KpacHTenb 2,5, oneHHoByio KHcnoTy '3,5, HHAycTpHanbHoe Macno 19 3, 'KacTopoBoe Macno 6,0, co-ποπΗΜβρ ByTaflHena h 2-MeTnn ~ 5-BHHHnnHpHRHHa 0,4, πβρβφΗΗ 5,0, bock-μοητβηcbipon 28,0, bock 6ypoyroJibHbift, o6eccMoneHHouse KpHCTaJiJiHaanHeift hs 6eH3HHa, cTeMnepaTyp KannenaneHHH 86 ° C , mhcjiom oMuneHHe 89, khcjiothmm hhcjiom 29 'hcoflep »hHeM cmoji 1,92% - 12,0, γοτοβητ aHanoriwHo npHMepy 1 c τβΜ οτπΗΗΗβΜ, hto caxy, HHnycTpHajibHoe Macno H conoJiHMep SyTaAHeHa η 2-ΜβτΗΠ-5-ΒΗΗΗΠπΗρΗ-flHHa bboaht b cocTaB nyTeM AoOaBneHHH κ ocTaJibHWM κομπο ηθητβμ caxesoň nacTbi,

KonHpoBanbHyio CyMary noJiynamT h HcnuTMBaioT aHanorHMHO npHMepy 1 ..

PeayjibTaTM HcnwTaHirii npHBefleHM b TaOJiHne. ΠρΗΜβρ 5 (no npoTOTHny). CocTaB ποκρητηη KonHpoaanbHoň OyMarH coflepxHT (b Mac.%): Caxy 17.8, μοηογηαρβτ okhch xenesa 5.4; ηηαϋηηη 1,0, τβτηηφΗοηβ — TOBbion xpacHTenb 2,5, oJieHKOB> io. KHCJioTy 3,5 ,. HHflycTpHaJibHoe Macno 26.0, Kac-TopoBoe Macno 5.0, * HaTpHA6yTaAHeHOBbift.KayHyK 0.8, πβρβφΗΗ3.0, bock — mohtBhcbipoft 18.5, BocK-HToHTaH oTCeneHHun 16.5. KonupoBanbHyioCyMary c βτημ ποκρώ-τηθμ nonynawT η ηοπμτηβΒμτ ηηηπογηηηο npHMepy 1.

PeaynbTaTH HcnbrraHMň npHBeneHbí b TáOJiHne. ΠρΗΜβρ 6 (KOHTpoJIbHMň), CocTaB ΠΟΚΡΜΤΗΗ KOnHpoBaJlbHOň CyMarH COAepHHT (b Mac.%): Caxy 18.0, μοηογηαρβτ okhch xeneaa 5.0, HHnynHH 1.0, τβτκπφΗοηβ-ToBbi KpacHTejib 2.5, oneHHoeyio KHcnoTy 4.0, HHAycTpnanbHoe Macno 26,0, HaT — pHnayTaaHeHOBhtn Kayqyx0,5, ηβρβφΗΗ 9,0, bock — at least 8.0, bock 6ypo-yrojibHbi, OJ c M p p p ° ° ° ° ° ° ° ° ° ° ° ° with 29 H coAepxaRHeM CMon '2.0% - 26.0. ApMý »bbbb »Oy Oy Oy Oy Oyýýýýýýýýonyonyonyonyonyonynnnnnnnnnnnnnnnnnnnnnnnnn '' '' '' '' '' '' '' '' '' ΠρΗΜβρ 7 (KOHTpoJIbHhl). CocTaB ΟΚΡΜΤΗΗΟΚΡΜΤΗΗnnnnBBllbbňňňňarfffffffffffffff b b b b b b b b b b b b b b caxaxaxaxaxaxaxaxaxaxaxaxaxaxaxaxax,0,0,0enenenen enenenenenenenenenenenenenenenenenenenenenenpppppppppppppppppppppppppppppppppppppppppppppp Kayuyx 0,5; πβρβφΗΗ 9.0; bock6ypoyronbHbn, oCeccMojiHHBb KpHCTaJinHsatiHen to SeHsHHa c TeMnepaTypo xnnHHB 86h, CoAepxaHHeM CMon2% - 26.0. KonHpoBanbHy »CyMary nonynawT h HCnMTbieaioT aHanorHHHO npHMepy 1.Prg 3tom cocTaB ποκρωτΗΗ TpyqHO AHcneprHpoBancH h HepaBHoMepHo HaHocHncH HaCyMary-ocHoBy.

Ha KonnpoBanbHOM ποκρωτΗΗ HaCJÍioAaioTCH nonocbi, KanecTBo οτπβηβτκοΒ Ha κο- πηηχ HepaBHOMepHoe.

Pe3yJibTaTbi HcnbrraHHn πρΗΒβΑβΗΜ b TaCnnne. 263481 -4-

Tafínuna noKaaaTeJiH Πο Η3θ6ρβΤβΗΗΚ) Πο NPO-Tóthné KoHTpOJlbHbie ΠρΗΜβρ 1 ΠρΗΜβρ 2 ΠρΗΜβρ 3 ΠρΗΜβρ 4 ΠρΗΜβρ 5 ΠρΗΜβρ 6 ΠρΗΜβρ 7 HhCJTO OflHOBpeMeH-HbtX OTTHCKOB 8 8 8 8 8 8 8 Hhcjio nocnefloBa-TeJlbHblX OTTHCKOB 18 18 18 18 18 18 18 PaBHowepHocTb HHT6HCHBHOCTH OTTHCKOB e b BO BO BO BO HT BO BO BO BO BO BO BO BO BO J J 6 6 6 6 6 6 6 6 6 6 0.16 0.17 0.16 0.16 0; 20 0.20 u noKa3aTenb rnaHua 20 22 24 24 10 12 14 ΦΟΡΜΥΠΑ H30BPETEHH8 I. CocTaB noKpbiTHH -KonHpoBaJibHoft 6yMarn, coftepacamHň ΠΗΓΜβΗΤ Ha ochos Ca- «Η, HHflyJIHH, KpaCHTeJTb ΜβΤΗΠφΗΟΠβΤΟΒΗή, OneHHOBym KHCJIOTy, MaCJlO, ΜΟΗΟΓβΗ-Hbtň noJiHMepHbiň gncnepraTop, napa $ HH Bock-MoHTaH cwpoň h o6eccMoneHHbiň 6Y-poyronbHbtň Bock T ΟΤΒ m T T T T T T T T T T T OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC OC 3auHH cbiporo bockb H3 6eH3HHa c TeMnepaTypoň KanJienafle-hhb no Y66ejiofle 85-86 ° C, hhcjiom OMbUieHHH 87-90; 1-23.7 HHflyJIHH 0.7-1.3 MeTHjieJoJoToBB KpacHTejib 1.0-2.5 OJieHHOBan KHCJioTa 2.8-4.3 MacJio 23.0-29.0 MoHoreHHbn nonHMepHibble flnc- nepraTop 0.4-1, 6 ΠβρβφΗΗ 4.0-8.0 'BoCK-MOHTaH cbipoň 1.2.0-28.5 Bock Sypoyronbibin, oOcCMoJHHbn KpHCTaJuiH3anHen H3 6eH3HHa 11.4-24.0 263481 2, CocTaB noKpbiTHH KdnHpoBaJibHoň ĎyMarn no nl; ητο b KanecTBe πογμθητη oh coflepacHT caxy hjih CMech cam c μοηογκηρβτομ okhch acejie3a. -5- 3. Coctsb ποκρΜΤΗΛ KonupoBanhHoň OyMarH no n.l, oTJiřwafomHftcH τβΜ, ητοb KanecTBe noHoreHHo nonwMepHoro «HcnepraTopa oh copiepjKHT HaTpHn-SyTaňHe-HoBbbi Kay ^ iyK híih cononuMep CyTaflHeHa h 2-MeTHn-5-BHHnnnnpnnnH &amp; c MoneKynap-Hoft Maccoft 3000-30000.

Hctobhhkh ΗΗφορΜβμΗΗ, npHHHTbie bo BHHMaHne npn 3KcnepTH3e: SU, A, 867686 SU, A, 1076317 SU, A, 1038358

P E Φ E P A T COCTAB ΠΟΚΡΗΤΗΗ ΚΟΠΗΡΟΒΑΠΒΗΟΠ ΒΥΜΑΓΉ

HacToamee Μ3θ6ρβτβΗΗβ othochtch to npoH3BoncTBy KonHpoBanhHoň SyMarH, baacTHoCTH κ cocTaeaM ποκρμτηλ KonnpoBanbHoft CyMarH.

CocTas noKpbiTHa KonHpoBaJibHoň.CyMarH conepsKHT πηγμθητ ocHoBe ca Ha »H hhflyjiHH, KpacHTenh ΜβτκπφΗοηβτοΒΜή, oneMHosyio KHcnoTy, mation, HOHoreHHMft no-nuMepHbiň flHcnepraTop, napa $ nH Bock-mohthh cbipoň h oCeccMoneHmifi 6ypoyrne-'poflHwň Bock CornacHo H3o6peTeHHJo b Ka CT T oro oro oro oro oro oro p p p p p p p p p p p p p p------------ cnenyrameM cooTKomeHtm com-ποηθητοβ cocTasa: ΠΗΓΜβΗΤ 22,1-23,7 HHflyiHH 0,7-1,3 MeTHiNiOnOn xpacHTenb 1,0-2,5 oHHoBan KHcnoTa 2,8-4,3 Macno. 23,0-29,0 HOHOreHHbl ΠΟΠΜΜβρΗΗή flHC- nepraTop 0,4-1,6 ΠβρβφΗΗ 4,0-8,0. BOCK- MOHT3H Cbipoft 12.0 to 28.5 eypoyrojibHbiň Bock, oOeccMo- neHHbift KpncTaJiJiH3anHeň H3 6eH3HHa 11.4 to 24.0 IIpH3HaHo Η3ο6ρετεΗΗβΜ well peaynbTaTaM 3KcnepTH3M, ocymecTBneHHOň FocynapcT-B6HHMM ΚοΜΗΤβΤΟΜ CCCP ΠΟ fleJlaM Η3θ6ρβΤβΗΗβ H OTKPMTHft. 263481

Claims (3)

SUBJECT OF THE INVENTION What is claimed is: 1. A copying paper coating comprising a base pigment, indulin, carbon black, methylvioleic dye, oleic acid, an oil, an ionic polymeric dispersant, paraffin, a crude monohydrate wax, and a resinsless lignite wax, wherein: abrasion contains, as the resin-free brown wax, a crystalline process wax product from gasoline with a Ubelohde dropping point of 85 to 86 ° C, a saponification number of 87 to 90, an acid number of 26 to 29 and a pitch of 1.86 to 2.00 at a pigment content of 22.1 up to 23.7 indulin 0.7 to 1.3 methylviolium dye 1.0 to 2.5%, oleic acid 2.8 to 4.3 23.0 to 29.0% oil, ionogenic polymer dispersant 0.4 to 1 , 6%, paraffin 4.0 to 8.0%, crude montan wax 12.0 to 28.5% and lignite wax, stripped of resin by crystallization from petrol 11.4 to 24.0% · 2. Coating according to claim 1, characterized in that the pigment comprises carbon black or a mixture of carbon blacks with iron oxide polyhydrate · 263481-7- 3. Coating according to claim 1, characterized in that a sodium butadiene rubber or a copolymer of butadiene and 2-methyl-5-vinil-pyridine having a molecular weight of 3000 to 30,000 is used as the polyologenic polymeric disperser. "Patent", Gagarina 101, UZgorodIP 6908, Price 2,40 Kčs