CS260329B1 - Method of milk products production by means of fortificated fibrous material - Google Patents
Method of milk products production by means of fortificated fibrous material Download PDFInfo
- Publication number
- CS260329B1 CS260329B1 CS8610224A CS1022486A CS260329B1 CS 260329 B1 CS260329 B1 CS 260329B1 CS 8610224 A CS8610224 A CS 8610224A CS 1022486 A CS1022486 A CS 1022486A CS 260329 B1 CS260329 B1 CS 260329B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- weight
- lubricating oil
- oil according
- oils
- ethylene oxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 3
- 239000002657 fibrous material Substances 0.000 title 1
- 239000008267 milk Substances 0.000 title 1
- 210000004080 milk Anatomy 0.000 title 1
- 235000013336 milk Nutrition 0.000 title 1
- 239000003921 oil Substances 0.000 claims description 13
- 239000010687 lubricating oil Substances 0.000 claims description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 6
- -1 alkyl carbon Chemical compound 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 229920001400 block copolymer Polymers 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004166 Lanolin Substances 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 229940039717 lanolin Drugs 0.000 claims description 3
- 235000019388 lanolin Nutrition 0.000 claims description 3
- 238000005461 lubrication Methods 0.000 claims description 3
- 239000003209 petroleum derivative Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 241000251468 Actinopterygii Species 0.000 claims description 2
- 240000002791 Brassica napus Species 0.000 claims description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 244000020551 Helianthus annuus Species 0.000 claims description 2
- 235000003222 Helianthus annuus Nutrition 0.000 claims description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 2
- 235000011613 Pinus brutia Nutrition 0.000 claims description 2
- 241000018646 Pinus brutia Species 0.000 claims description 2
- 235000004443 Ricinus communis Nutrition 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 235000019688 fish Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims 2
- 240000006240 Linum usitatissimum Species 0.000 claims 1
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 1
- 150000001656 butanoic acid esters Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GUSGFQYXYUAQAQ-UHFFFAOYSA-N C(C(C)C)C(CCCCCCCCCCC)SP(O)(O)=S.[Zn] Chemical compound C(C(C)C)C(CCCCCCCCCCC)SP(O)(O)=S.[Zn] GUSGFQYXYUAQAQ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
Description
Vynález sn lýka niazaciplw olejů pre tvórnenic kovov za studená, zvlášf pre rozvalcovanio ložiskových krúžkov. a lisovanie krúžkov ililovýeh ložísk. Oleje podía tohoto vynálezu zabezpečuji! účinné chladcnie a niazanie při (várnení, dostateční! protikeróznu odolnosl’ no opracováni. Oleje sá z povrchu súčiastok lehko oplachuji! už technologickou vodou bez použitia obrovu. Povrch po opláchnutí je vhodný pre ďalšie mechanické alebo tepelné opracovanie. .The invention relates to cold-forming oils for metal blocks, in particular for the rolling of bearing rings. and pressing the rings of the ilil bearings. The oils of the present invention provide! Effective cooling and welding during (welding, sufficient! anti-anticorrosive resistance) no oil rinses from the surface of components easily with technological water without the use of a giant. The surface after rinsing is suitable for further mechanical or thermal treatment.
Pri tváření dochádza k uvolňovaniu tepla a k rožne těsným kontaktem nástroja a pretvárííovanélio kovu. Je preto potřebné účinné ehladenie a mazanic různej účinnosti a mechanizmu. Prostredie, v ktorom tvárniaci proces prebieha, musí preto obsahovat rožne aktivně přísady zabezpečujúce ehladenie a mazanie pri elastohydrodynamickom i medznom, připadne zmiešanom tření. Nevyhnutou vlastnosťou mazacieho oleja musí byť dostatočná protikorozně účinnost a oxidačná stabilita.During molding, heat is released and the spit is tightly contacted by the tool and the metal is deformed. Effective smoothing and lubrication of different efficiencies and mechanisms are therefore needed. The environment in which the molding process takes place must therefore contain active ingredients which ensure smoothing and lubrication at both elastohydrodynamic and ultimate, or mixed, friction. The essential property of the lubricating oil must be sufficient corrosion resistance and oxidation stability.
Obzvlášť výhodné sú také mazacie oleje, které nevytvárajú na súčiastkách hrubé vrstvy a sú z povrehov 1'ahko opratelné, najlepšie technologickou vodou bez ohřevu. Bežne dostupné mazacie prostriedky do určitej miery plnia vešobecné nároky na funkčnost, avšak nezaručujú celý požadovaný súbor ná2 rokov —- bud majú špécifické použitie, vyšsin agresivitu, malú protikoróznu schopnost, připadne rieplnia požiadavky 1'ahkej opřatelnosti.Particularly preferred are those lubricating oils which do not form thick layers on the components and are easy to clean from the surfaces, preferably with process water without heating. The commercially available lubricants meet to some extent the general demands for functionality, but do not guarantee the entire set required for two years - whether they have a specific use, high aggressiveness, low corrosion resistance or meet the requirements of easy wear.
Mazacie oleje podía vynálezu v značnej miere vyhovujú stanoveným poziadavkám.The lubricating oils according to the invention largely meet the stated requirements.
Mazací olej pre studené tvárnenie kovov, zvlášť pré rozvalcovanie ložiskových krúžkov a lisovanie krúžkov ihlových ložísk podlá vynálezu pozostáva z 0,01 až 2,5 % hmotnostných neionového tenzidu, s výhodou blokového kopolymerů etylénoxidu a proipylénoxidu, z 0,1 až 5 % hmotnostných zinočnatej alebo amónnej soli dialkylditiofosforečnej kyseliny, s počtem alkylových uhlíkov 3 až 12, z 0,1 až 2,5 % hmotnostných antioxidantu, s výhodou alkylfenolového typu, z 0,005 až 2 % hmotnostných aminu alifatického, alicyklického alebo alkanolamínu o počte uhlíkov v molekule 2 až 18, z 0,01 až 10 % hmotnostných olejov živočišného alebo rastlinného původu a to aj oxidovaných alebo kondenzovaných s etylénoxidom ako· je .naprkíklad olej 1’anový, řepkový, slnečnicový, ricínový, borovicový, tálový, rybí, spermový, lanolín. Ďalej zmes obsahuje 0,01 až 25 % hmotnostných chlórovanej přísady s obsahom chlóru 25 až 45 % hmotnostných a/alebo 0,01 až 25 % hmotnostných přísady obsahujúcej síru, s výho26 0 3 30The lubricating oil for the cold forming of metals, in particular for the rolling of the bearing rings and the pressing of the needle bearing rings according to the invention consists of 0.01 to 2.5% by weight of a nonionic surfactant, preferably block copolymers of ethylene oxide and proipylene oxide, 0.1 to 5% by weight of zinc or an ammonium salt of dialkyldithiophosphoric acid having an alkyl carbon number of 3 to 12, from 0.1 to 2.5% by weight of an antioxidant, preferably of the alkylphenol type, from 0.005 to 2% by weight of an amine of an aliphatic, alicyclic or alkanolamine having a carbon number of 2 to 18, from 0.01 to 10% by weight of oils of animal or vegetable origin, whether oxidized or condensed with ethylene oxide such as oil, rapeseed, sunflower, castor, pine, talc, fish, semen, lanolin. Further, the composition comprises 0.01 to 25% by weight of a chlorinated additive with a chlorine content of 25 to 45% by weight and / or 0.01 to 25% by weight of a sulfur-containing additive, preferably 26 0 3 30
260330 dou sířeného oleja, sulfurovaného butylesteru kyseliny olejovej alebo sulfurovaného ricínového oleja a zvyšok do 100 % hmotnostných tvorý ropný destilát o viskozitě 1 až 50 pri 50 °C, s výhodu 12 až 25 mm2. s_1 pri 50 °C. Mazací olej pre tvárnenie kovov za studená je bližšie uvedený nasledujúcimi príkladmi. ktoré rozsah vynálezu neobmedzujú.260330 of a sulphurized oil, a sulphurated butyl oleic acid ester or a sulphurized castor oil and the remainder to 100% by weight is a petroleum distillate having a viscosity of 1 to 50 at 50 ° C, preferably 12 to 25 mm 2 . with _1 at 50 ° C. The cold forming lubricating oil is illustrated by the following examples. which do not limit the scope of the invention.
Přiklad 1Example 1
Mazací olej pozostáva z 0,5 % hmotnostných blokového kopolyméru etylénoxidu a propylénoxidu, z 2,2 % hmotnostných zinočnatej soli izobutyl-dodecylditiofosforečnej kyseliny, z 1 % hmotnostného 2,6-di-terc.butylmetylfenolu, z 0,2 % hmotnostných monoetanolamínu, z 0,5 % lanolínu a 95,6 % hmotnostných ropného oleja o viskozitě 21 mm2. s1 pri 50 °C.The lubricating oil consists of 0.5% by weight of a block copolymer of ethylene oxide and propylene oxide, 2.2% by weight of zinc isobutyl-dodecyldithiophosphoric acid, 1% by weight of 2,6-di-tert-butylmethylphenol, 0.2% by weight of monoethanolamine, of 0,5% lanolin and 95,6% of petroleum oil of 21 mm 2 viscosity. with 1 at 50 ° C.
Takto připravený olej bol použitý na mazanie pri studenom rozvalcovaní ložiskových krúžkov o 0 120 mm z ocele triedy 14 109 a ocele BPS na zariadení typu UPW 63. Rozměrové parametre vyrobených krúžkov (priemer otvoru, oběžněj dráhy, šířka a ovalita obeznej dráhy] plné vyhovovali pre ďalšie opracovanie. Povrch rozvalcovaných krúžkov bol lesklý, bez trhlin. Olej počas operácie rozvalcovania nedymil. Po opratí vyrobených krúžkov studenou vodou boli tieto dostatočne odmaštěné pre tepelné spracovanie a chráněné před koróziou po dobu medzioperačného skladovania (min. 14 dní).The oil prepared in this way was used for cold rolling of bearing rings of 0 120 mm of 14 109 grade steel and BPS steel on UPW 63 equipment. The dimensional parameters of the produced rings (bore diameter, raceway width, raceway width) were fully suitable for The surface of the rolled rings was shiny, without cracks The oil did not smoke during the rolling operation, after the rings were cooled with cold water, they were sufficiently degreased for heat treatment and protected against corrosion for a period of intermediate storage (min. 14 days).
Příklad 2Example 2
Mazací olej pozostáva z 0,28 % hmotnostných blokového kopolyméru etylénoxidu a propylénoxidu, z 3,7 % hmotnostných amónnej soli izobutyl-(2-etyl)hexylditiofosforečnej kyseliny, z 1,8 % hmotnostných 2,6-di-terc.butylmetylfenolu, z 0,2 % hmotnostných řepkového oleja, z 1,4 % hmotnostných oktadecylamínu, z 5 % hmotnostných chlórovaného parafinu o obsahu 44 % hmotnostných chlóru, z 0,8 % hmotnostných sulfurovaného butylesteru kyseliny olejovej a z 86,82 % hmotnostných ropného destilátu o viskozitě 32 mm2. s1 pri 50 °C.The lubricating oil consists of 0.28% by weight of a block copolymer of ethylene oxide and propylene oxide, 3.7% by weight of ammonium isobutyl- (2-ethyl) hexyldithiophosphoric acid, 1.8% by weight of 2,6-di-tert-butylmethylphenol, 0.2% by weight of rapeseed oil, 1.4% by weight of octadecylamine, 5% by weight of chlorinated paraffin with a content of 44% by weight of chlorine, 0.8% by weight of sulfurized butyric oleic acid ester and 86.82% by weight of petroleum distillate of viscosity 32 mm 2 . with 1 at 50 ° C.
Takto připravený mazací olej bol použitý pri fahaní lisovaných krúžkov ihlových ložísk s redukciou hrůbky steny 15 až 20 °/o, kde sa požaduje vysoká rozherová přesnost. Olej zabezpečil parametre (geometria, drsnost, homogenita hrůbky steny a homogenita vzhfadu) na úrovni špičkových výrobcov, avšak bol lepšie a 1'ahšie z povrchu lisovaných súčiastok odstranitelný praním neohrievanou vodou.The lubricating oil prepared in this way was used in punching of pressed needle bearing rings with a wall thickness reduction of 15-20% where high spreading accuracy is required. The oil provided the parameters (geometry, roughness, homogeneity of the wall depth and homogeneity of appearance) at the level of the top manufacturers, but it was better and easier to remove from the surface of the molded parts by washing with non-heated water.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS8610224A CS260329B1 (en) | 1986-12-30 | 1986-12-30 | Method of milk products production by means of fortificated fibrous material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS8610224A CS260329B1 (en) | 1986-12-30 | 1986-12-30 | Method of milk products production by means of fortificated fibrous material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS1022486A1 CS1022486A1 (en) | 1988-05-16 |
| CS260329B1 true CS260329B1 (en) | 1988-12-15 |
Family
ID=5448374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS8610224A CS260329B1 (en) | 1986-12-30 | 1986-12-30 | Method of milk products production by means of fortificated fibrous material |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS260329B1 (en) |
-
1986
- 1986-12-30 CS CS8610224A patent/CS260329B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS1022486A1 (en) | 1988-05-16 |
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