CS248252B1 - Method of azo-dye stuffs production - Google Patents
Method of azo-dye stuffs production Download PDFInfo
- Publication number
- CS248252B1 CS248252B1 CS791666A CS166679A CS248252B1 CS 248252 B1 CS248252 B1 CS 248252B1 CS 791666 A CS791666 A CS 791666A CS 166679 A CS166679 A CS 166679A CS 248252 B1 CS248252 B1 CS 248252B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- hjih
- polyorganosiloxanes
- hydrolysis
- process according
- azo
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 4
- 239000000987 azo dye Substances 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 150000004982 aromatic amines Chemical class 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 230000007062 hydrolysis Effects 0.000 claims 3
- 238000006460 hydrolysis reaction Methods 0.000 claims 3
- 150000001367 organochlorosilanes Chemical class 0.000 claims 3
- 230000002378 acidificating effect Effects 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 125000005375 organosiloxane group Chemical group 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 150000001282 organosilanes Chemical class 0.000 claims 1
- 235000017399 Caesalpinia tinctoria Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 101000980827 Homo sapiens T-cell surface glycoprotein CD1a Proteins 0.000 description 1
- 101150096418 Mepe gene Proteins 0.000 description 1
- 101100066898 Mus musculus Flna gene Proteins 0.000 description 1
- 241001553014 Myrsine salicina Species 0.000 description 1
- 229910003849 O-Si Inorganic materials 0.000 description 1
- 229910003872 O—Si Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 102100024219 T-cell surface glycoprotein CD1a Human genes 0.000 description 1
- 241000388430 Tara Species 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/008—Dyes containing a substituent, which contains a silicium atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
11
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Tax fíbuio npefljioaceHO πρημθηητβ flJia OKpanwBaHHH ÓTBepxflaeMbix nojmopraHOCHJioK-CHHOB KpacHTejm, KOTOpwe COgepXaT TpHC-(TpHMeTHJIČHJIOKCH-)CHJIHJiajIKHJiaMHHOByiOrpynny. B onHcaHHSX Η3θ6ρβτβΗΗή κ naŤeHTaM CD1A 3 888 891, 3 963 744 h3 981 859 penb HfleT b ochobhom o xhhohobmx, ηηαηγοβμχ, τηοηη^ηγοββιχ, ifcTajio-Hhhhhhobmx η aaoKpacHTejiHX. y«e πρκ nojryqeHHH tphc-(TpHMeTHJiCHJioKCH“)cHJiHjiajiKHJiaMHHa TpeCyeTCH cjioxHaa,flopórajt TexHojiorHH, πρκΗβΜ aMHH ofípaayeTCH jmmb b HeaHaHHTejibHbix KOjranecT-Bax. KpoMe Toro, KpacHTejm Ha 3τοή ocHOBe πρΗΜβΗΗΜΜ jmmb b orpaHHueHHOM .OČbeMe H3-3a ΗββΚΤΗΒΗΜΧ flJIJI nOJIHMepH3aHHH TpHC-(TpHMeTHJICHJIOKCH-)cHJlHJIbHb!XpaflHKajioB. B onHcaHHHX H3o6peTeHHň κ naTeHTaM C1IIA 2 925 3Í3, 2 927 839, 2 931 693 h2 957 744 onncbroaioTCJi xpacHTejiH Ha ocHOBe apHJiaMHHoajiKHjicHJiaHOB, Ohh τοματ-CH flJIH OKpaiUHBaHHH CTeKJIOBOJIOKOH, HaTypajIbHblX BOJIOKOH TaKHX, T3K mepCTb,xjionqaTOňyMajKHoe bojiokho, mejíK, a τβκκβ opraHHHecKHX CHHTeTHnecKHX bojiokoh; 248252 2 tskhx, K3K nojmaMHflHoe, nojmaqeTaTHoe, nojiH34>HpHoe bojiokho η t.a. ΠρΗΜβΗε-ηηθ τβΚΗΧ KpacHTejieň ftjifl nojiHopraHOCHJiOKcaHOB hejihctch o/jHaico aaTpynHeHHbíMH3-3a ckjiohhocth srn KpacHTejieft κ cHHepesHca (onHcaHHe Η3ο6ρετε- hhh k naTeHTy CU1A 3 888 891).Tax fíbuio npefljioaceHO πρημθηητβ flJia OKpanwBaHHH ÓTBepxflaeMbix nojmopraHOCHJioK-CHHOB KpacHTejm, KOTOpwe COgepXaT TpHC- (TpHMeTHJIČHJIOKCH-) CHJIHJiajIKHJiaMHHOByiOrpynny. B onHcaHHSX Η3θ6ρβτβΗΗή κ naŤeHTaM CD1A 3,888,891, 3,963,744 h3,981,859 penb HfleT b ochobhom o xhhohobmx, ηηαηγοβμχ, τηοηη ^ ηγοββιχ, ifcTajio-Hhhhhhobmx η aaoKpacHTejiHX. y «e πρκ nojryqeHHH tphc- (TpHMeTHJiCHJioKCH)) cHJiHjiajiKHJiaMHHa TpeCyeTCH cjioxHaa, floporage TexHojiorHH, πρκΗβΜ and MHH ofipaayeTCH jmmb b HeaHaHHTejibHbix KOjranecT-Bax. KpoMe Toro, KpacHTejm Ha 3 ο oc H e ΗΜ ΗΜ m m m m m m m m 3 3 3 M M M M ΚΤΗΒΗΜΧ ΚΤΗΒΗΜΧ ΚΤΗΒΗΜΧ ΚΤΗΒΗΜΧ ΚΤΗΒΗΜΧ p p. B onHcaHHHX H3o6peTeHHň κ naTeHTaM C1IIA 2925 3i3, 2,927,839, 2,931,693 h2 957,744 onncbroaioTCJi xpacHTejiH Ha ocHOBe apHJiaMHHoajiKHjicHJiaHOB, oh τοματ CH flJIH OKpaiUHBaHHH CTeKJIOBOJIOKOH, HaTypajIbHblX BOJIOKOH TaKHX, T3K mepCTb, xjionqaTOňyMajKHoe bojiokho, mejíK and τβκκβ opraHHHecKHX CHHTeTHnecKHX bojokoh; 248252 2 tskhx, K3K nojmaMHflHoe, nojmaqeTaTHoe, nojiH34> HpHoe Boot η t.a. Π ΗΜ p p p p ň HT p ej p p p p p p p p H H H H H H H H H H H
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HeopraHHyecKue ΠΗΓΜεΗτω hbjihwtch τεκχε no πρηηΗΗε bmcokhx TpeSoBaHHň κ τερ-MoycToňnnBOCTH jihpjb orpaHHneHHonpHMeHHMMMH. Tax, HanpHMep, caxca πρπ B03-fleňCTBHH Bbl(?OKHX TeMnapaTyp MOW8T OKHCJIHTbCH flO flByOKHCH yrjiepOfla H CJiyJKHTΠΟ3ΤΟΜΥ B fiojIblDHHCTBe CJiynaeB TOjibKO fljlH flOCTHXeHHH npOBOflHMOCTH' CHJIHKOHO-Bbix ποπΗΜεροΒ (onHcaHHe Η3ο6ρετεΗΗΗ κ naTeHTy BejiHKo6pHTaHHH 884 208). Πρ«-MeneHne HeopraHnnecKHX ΠΗΓΜεΗτΟΒ HBjíneTCH, κροΜε τογο, TexHOjiornnecKHoneHb floporo η ΗΜεετ τοτ κεβοοτετοκ, ητο H3-3a BBefleHHH sthx nyxcepoflHbix noOTHomeHHio κ cujiHKOHy ΠΗΓΜβΗΤΟΒ yxyffraawTCH onpefleneHHbie cBoňcTBa nanojmen-Hbix nojiHopranocHJioKcaHOB.HeopraHHyecKue ΠΗΓΜεΗτω hbjihwtch τεκχε no bgcokhx TpeSoBaHHn κ τερ-MoycToňnnBOCTH jihpjb orpaHHneHHonpHMeHHMMMH. Tax, HanpHMep, caxca πρπ B03-fleňCTBHH Bbl (? OKHX TeMnapaTyp MOW8T OKHCJIHTbCH FLO flByOKHCH yrjiepOfla H CJiyJKHTΠΟ3ΤΟΜΥ B fiojIblDHHCTBe CJiynaeB TOjibKO fljlH flOCTHXeHHH npOBOflHMOCTH 'CHJIHKOHO-Bbix ποπΗΜεροΒ (onHcaHHe Η3ο6ρετεΗΗΗ κ naTeHTy BejiHKo6pHTaHHH 884,208). Πρ «-MeneHne HeopraHnnecKHX ΠΗΓΜεΗτΟΒ HBjíneTCH H3-3a BBefleHHH sthx nyxcepoflHbix noOTHomeHHio κ cujiHKOHy ΠΗΓΜβΗΤΟΒ yxyffraawTCH onpefleneHHbie cBoňcTBa nanojmen-Hbix nojiHopranocHJioKcaHOB.
Bo bcrx cjiynaax πρκ H3BecTHbix Meroflax OKpanwBaHHH pěni HfleT o φΗ3ΗΗεεκοΜ33ΜεΠΙΗΒΗΗΗΗ KpaCHTejIH. BcjieflCTBHe 3ΤΟΓΟ OflHOpOfliHOCTb OKpaCKH nOCTOHHHOnofleepraeTCH onacHOCTH h menna cnHepe3nca n MHrpaimn MoryT bo μηογηχcjiynaax οτρκηετειίΒΗΟ ποβληβτβ Ha csoňcTBa chjjhkohobwx npoflyxTOB.Bo bcrx cjiynaax πρκ H3BecTHbix Meroflax OKpanwBaHHH foam HfleT o φΗ3ΗΗεεκοΜ33ΜεΠΙΗΒΗΗΗΗ KpaCHTejIH. BcjieflCTBHe 3ΤΟΓΟ OflHOpOfliHOCTb OKpaCKH nOCTOHHHOnofleepraeTCH onacHOCTH h menna cnHepe3nca n MHrpaimn MoryT Bo μηογηχcjiynaax οτρκηετειίΒΗΟ ποβληβτβ Ha csoňcTBa chjjhkohobwx npoflyxTOB.
Uejib Η3θ6ρετεΗΗΗUejib Η3θ6ρετεΗΗΗ
Uejib Η3θ6ρετεΗΗΗ 3aKjuonaeTCH b tom, hto6m, hcxo/jh H3 jierKOflocTynHbix hcxo/i,-Hbix BemecTB, ΗβΗΤΗ TexHojiorHHHbiň η προετοή cnoco6 nojiyneHHH KpacHTejieň, cnOMOmbK) KOTOpbIX BO3MOWHO ĎblJIO 6bl KpacOHHO OÓjOpMJIHTb OCOĎOHHO CHJIHKOHbl HJIHMaccbi Ha 6a3e chjihkohob η κοτορΜε no MeHbnieň Mepe oTBenaioT bmcokhm tcxho-JlOrHHeCKHM ,ΤρεβθΒ3ΗΗΗΜ K CHJIHKOHaM. flÓJBKHa ΠΟ BO3MOJKHOCTH COXpafíHTbCH H3“BecTHaa τθχηο,πογηλ nojiyqeHHJí H περερβόοτκη chjihkohob xak, HanpHMep, ot-BepwfleHHe, cniHBKa, b flaHHOM cjiynae c ΠρΗΜεΗεΗκεΜ oĎmhho Hcnojib3yeMbix fločarrbok . ΠρΗ 3 tom KpacamHň κομποηβητ flojixeH 6biTb BCTpoeH b nojiHMepHyK) MOjiexyjiyc noMombio roMeonojiapHoň cb«3h h xpacHTajm He flojcKHbí noKa3HBaTb pa3pbiBOBCMeiDHBaeMOCTH C CHJTHKOHaMH H CJiyXHTb npHHHHOft HBJíeHHH CHHepe3HCa HJIH MHrpa-Uhh πρκ flajibHeňmeft nepepaÓOTKe. H3jioaceHHe cymHocTH Η3θ6ρετεΗΗΗ B cooTBeTCTBHH c Η3θ6ρετεΗΗβΜ u,ejib Η3Ό6ρετεΗΗΗ fločTHraeTCH tcm, hto a3OKpa-cHTejiH nojiynawT Ha ochobo opraHocHJioKcaHOB hjih nojmopraHocHjioKcaHOB, koto-pbie nocTpoaHbí H3 MOHOMepHbtx eflHHHH o6meií φopMyJΠ>ϊ R3S^°1/2, R2S*-0 h/hjih RSiOg^ rp,e R o3HaqaoT oflHHaKOBbie hjih pasjíHHHMe opraHHnecKHe paflHKajibi, 3tom BOflopo-pia hjih coflepxanmií a3orpynny opraHHnecKHň pa^HKaji.Uejib Η3θ6ρετεΗΗΗ 3aKjuonaeTCH b that hto6m, hcxo / JH H3 jierKOflocTynHbix hcxo / i -Hbix BemecTB, ΗβΗΤΗ TexHojiorHHHbiň η προετοή cnoco6 nojiyneHHH KpacHTejieň, cnOMOmbK) KOTOpbIX BO3MOWHO ĎblJIO 6BL KpacOHHO OÓjOpMJIHTb OCOĎOHHO CHJIHKOHbl HJIHMaccbi Ha 6a3e chjihkohob η κοτορΜε well MeHbnieň Mepe oTBenaioT bmcokhm tcxho-JlOrHHeCKHM, ΤρεβθΒ3ΗΗΗΜ K CHJIHKOHaM. flóJBKHa ΠΟ BO3MOJKHOCTH COXpafíHTbCH H3 “BecTHaa τθχηο, πογηλ nojiyqeHHJí H περερβόοτκη chjihkohob xak, HanpHMep, ot-BepwfleHHe, cniHBKa, b flaHHOM cjiynae c ΠρΗΜεΗεΗκεΜ oĎmhho Hcnojib3yeMbix fločarrbok. 3 ΠρΗ that KpacamHň κομποηβητ flojixeH 6biTb BCTpoeH nojiHMepHyK b) MOjiexyjiyc noMombio roMeonojiapHoň CB «h 3h xpacHTajm He flojcKHbí noKa3HBaTb pa3pbiBOBCMeiDHBaeMOCTH CHJTHKOHaMH C H CJiyXHTb npHHHHOft HBJíeHHH CHHepe3HCa HJIH MHrpa-uhh πρκ flajibHeňmeft nepepaÓOTKe. H3jioaceHHe cymHocTH Η3θ6ρετεΗΗΗ B cooTBeTCTBHH Η3θ6ρετεΗΗβΜ c u ejib Η3Ό6ρετεΗΗΗ fločTHraeTCH TCM, HTO-a3OKpa cHTejiH nojiynawT Ha ochobo opraHocHJioKcaHOB hjih nojmopraHocHjioKcaHOB, Koto-pbie nocTpoaHbí H3 MOHOMepHbtx eflHHHH o6meií φopMyJΠ> ϊ ^ R3S ° 1/2, R2S -0 * h / hjih RH 3 O 2 RH 3 O 2 H 2 O 2 CO 2 O 2 H 2 O 2 H 2 O 2 H 2 H 2 O 2 H 2 O 2 H 2 O 2 O 2 H 2 O 2 CO 2 2 2 2 1 2 3 1 2 1 2 1 2 1 2 1 2 1 2 1 2 3 3 4 5 5 5 5 5 5 5 5 5.
HooJKHflaHHbíM oSpaaoM ĎbUio oĎHapyxeHO, hto b KanécTBe HBeTOOĎpaayiomero κομπο-ΗβΗΤβ flJIH flHa3OTHpOBaHHbfX apOMaTHHeCKHX aMHHOB MOryT HCnojIb3OBaTbCH CHJ1OKCH“saMemeHHbie apoMaTHnecKHe coeflHHeHHH noflOĎHbie apoMaTHnecKHM φεκοπΒΜ, εκο.πΗ3Η-pyeMblM COeflHHCHHHM HJIH apOMaTHHeCKHM aMHHaM, CHJIOKCH3aMemaHHbIB apOMaTHHeC-κηθ coeflHHBHHH He Hy«flaioTCH hh b khkhx flpyrnx 3aMecTHTenax KpOMe CHjioKcano-HooJKHflaHHbíM oSpaaoM ĎbUio oĎHapyxeHO, HTO b KanécTBe HBeTOOĎpaayiomero κομπο-ΗβΗΤβ flJIH flHa3OTHpOBaHHbfX apOMaTHHeCKHX aMHHOB Ballad HCnojIb3OBaTbCH CHJ1OKCH "saMemeHHbie apoMaTHnecKHe coeflHHeHHH noflOĎHbie apoMaTHnecKHM φεκοπΒΜ, εκο.πΗ3Η-pyeMblM COeflHHCHHHM HJIH apOMaTHHeCKHM aMHHaM, CHJIOKCH3aMemaHHbIB apOMaTHHeC κηθ coeflHHBHHH Ile-Hy« flaioTCH hh b khkhx flpyrnx 3aMecTHTenax KpOMe CHjioKcano-
BblX, HTOĎbl ĎbITb cnOCOSHblMH CJiyWHTb B KaneCTBe HBeTOO6pa3y»MerO ΚΟΜΠΟΗβΗΤβ 248252 3 fljiH cojieň flHaaoHHH. TaK κεκ cHJioKCH3aMemeHHbie apoMaTHnecKHe coeflHHeHHH mo-ryT 6biTb HcnoabaoBaHM b KanecTBe HBeTOo6pa3yiomero κομποηθητη npaKTHHecKHflJifl scex flna3orapoBaHHbix apoMaTHnecKHX 3μηηοβ, oKa3biBaeŤcn bo3mojkhmm c no-Mombio peaxnHH, corjiacHO Η3θ6ρβτβΗΗΐο, nonyueHHe pa3jiHHHbix a3OKpacHTejieH, ko-Topue no3BojiHT nonyqaTb oKpaiueHHbie opranocHJioKcaHbí hjih nojiHOpraHocHJioKcaHbi. CHaoKCH3aMemeHHbie apoMaTnaecKue coeflHHeHHH MoryT 6biTb Hcnojit30BaHH b KaaecT-Be UBeTOo6pa3yioDíero KOMnoHeHTa fljiH, HanpHMep, cjieflyroiUHX apoMaTHnecKHX 3mh—BOB B flHa3OTHpOBaHHOň φΟρΜβ! 3HHJIHH, 1-3MHHO-2,4“flHHHTpo6eH3OJI, l-aMHHO-2“-xjiop-6en3oji, l-aMHHo-4-xjiop6eH3Oji, l-aMHHo-2,5-flHXjiop6eH3oji, n-aMHHo-aneT-aHHJiHfl, MeTaHHJiOBan KHCJiOTa, cyjib<i>aHHJiOBaH KHCJlOTa, o-TOjiyHflHH, M-TojiynflHH,Π—TOJiyHflHH, 3HH3HflHH, φβΗΘΤΗΑΗΗ, KCHJIHflHH, n-aMHHOa306eH30Jl, 3ΜΗΗΟΗ3φτθΤΙ,ΗΜΜΗΟΙίΒφτΟΟνΠΒφΟΗΟΒΒΗ KHCJlOTa, 1-aMHHO-2-rHflpOKCH-4-HHTpo6eH3OJl H T.fl.BblX, HTOÏbl ĎbITb cnOCOSHblMH CJiyWHTb B KaneCTBe HBeTOO6pa3y »MerO ΟΗΠΟΗβΗΤβ 248252 3 fljiH cojieň flHaaoHHH. TaK κεκ cHJioKCH3aMemeHHbie apoMaTHnecKHe coeflHHeHHH MO-engravable 6biTb HcnoabaoBaHM b KanecTBe HBeTOo6pa3yiomero κομποηθητη npaKTHHecKHflJifl Scex flna3orapoBaHHbix apoMaTHnecKHX 3μηηοβ, oKa3biBaeŤcn bo3mojkhmm C NO-Mombio peaxnHH, corjiacHO Η3θ6ρβτβΗΗΐο, nonyueHHe pa3jiHHHbix a3OKpacHTejieH co-tops no3BojiHT nonyqaTb oKpaiueHHbie opranocHJioKcaHbí hjih nojiHOpraHocHJioKcaHbi. CHaoKCH3aMemeHHbie apoMaTnaecKue coeflHHeHHH MoryT 6biTb Thickness 30BaHH b KaaecT-Be UBeTOo6pa3yioDoomHjHoH, HanpHMep, cjieflyroiUHX apoMaTHnecKHX 3mh — BOB B flHa3OTHPOBaHHO φΟρΜβ! 3HHJIHH, 1-3MHHO-2,4 "flHHHTpo6eH3OJI, 1-aMHHO-2" -xjiop-6en3oji, 1-aHHo-4-xjiop6eH3Oi1, 1-aHHo-2,5-flHXjiop6eH3oji, n-aHHo-aneT-aHHJiHfl, MeTaHHJiOBan KHCJiOTa, cyjib <i> aHHJiOBaH KHCJlOTa, o-TOjiyHflHH M-TojiynflHH, Π-TOJiyHflHH, 3HH3HflHH, φβΗΘΤΗΑΗΗ, KCHJIHflHH, n aMHHOa306eH30Jl, 3ΜΗΗΟΗ3φτθΤΙ, ΗΜΜΗΟΙίΒφτΟΟνΠΒφΟΗΟΒΒΗ KHCJlOTa 1 aMHHO-2-4-rHflpOKCH HHTpo6eH3OJl H T. fl.
Cnoco6, corjiacHO Η3θ6ρβτβΗΗΚ>, OTjiHnaeTCH HeoxHaaHHO npocToň βηποπηημοοτβιο.'TexHOjiornnecKan óaaa, coflepacaman peaKUHio οοηθτ3ηηη, ΜΟίκετ 6biTb oSbeflHHeHaC flpyrHMH OfíbWHblMH flJIH nepepa6OTKH KpeMHHHOpraHHHeCKHX COeflHHeHHň TeXHOJlO-ΓΗΗΘΟΚΗΜΗ $a3aMH. CoqgTaHHe C flna3OTHpOBaHHblMH apOMaTHMeCKHMH aMHHaMH npo-BOflHTCH B KHCJIOM paCTBOpe, flJIH ΗΘΓΟ MOXteT 6bITb npHMO HCnOJlb3OBaH KHCJIblíípacTBop rHflpojiH3a opraHOxjiopcHJiaHOB. B cjiynae Hcnojib3OBaHHH ajih rHflpojiH3ab KauecTBe pacTBopHTejia apoMaTHnecKHX coeflHHeHHň, ocymecTBjíHeTCH nocjieflyio-utaH aa coaeTaHHeM aacTKa KpacHTejiH, corjiacHO H3o6peTeHHio, npocTbiM OTflejie-ΗΗβΜ BOflHOÍÍ φβ3Η.Cnoco6, corjiacHO Η3θ6ρβτβΗΗΚ> OTjiHnaeTCH HeoxHaaHHO npocToň βηποπηημοοτβιο.'TexHOjiornnecKan óaaa, coflepacaman peaKUHio οοηθτ3ηηη, ΜΟίκετ 6biTb oSbeflHHeHaC flpyrHMH OfíbWHblMH flJIH nepepa6OTKH KpeMHHHOpraHHHeCKHX COeflHHeHHň TeXHOJlO-ΓΗΗΘΟΚΗΜΗ $ a3aMH. CoqgTaHHe C flna3OTHpOBaHHblMH apOMaTHMeCKHMH andMHHaMH npo-BOflHTCH B KHCJIOM paCTBOpe, flJIH X MOXteT 6bITb npHMO HCnOJlb3OBaH KHCJIbpacTBop rHflpojH3a opraHOxjiopcHJiaHOB. B cjiynae Hcnojib3OBaHHH ajih rHflpojiH3ab KauecTBe pacTBopHTejia apoMaTHnecKHX coeflHHeHHn, ocMecTBiHeTCH nocjieflyio-utaH aa coaTHHeM aacTKa KpacHTejiH, corjiacHO H3o6peTeHHio, npocTbiM OTflejie-ΗΗΗΗ
Tax, HanpHMep, MoryT 6ητβ rHflpojiH3OBaHbi ο6μηηβιμ cnocoBoM xjiopcHJiaHbí, coflep-xcaniHe φeHHJIbHy^o rpynny, b tbkom apoMaTHflecKOM coeflHHeHHH, xax TOJiyoji. Bkhcjimh oxjiaxaeHHbiň rHflpojiH3Hbiň pacTBop npHKanbroáwT πρκ nepeMeniHBaHHH npefl-BapHTejibHO αη33οτηροβ3ηηβιη pacTBop apoMaranecKOFO aMHHa, Moxho Tarae flo-SapnHTb KHCJlblH rHflpOJIH3HblH paCTBOp ΚρβΜΗΗΗΟρΓΒΗΗΗβΟΚΟΓΟ CoeflHHeHHH K pacT~BOpy cojih flHa30HHH. 3aTeM fljia aaBepmeHHfl coaeTaHHH flonojiHHTejibHO nepeMenm-eaioT h no οκοηη3ηηη OTflejiHWT BopHyio φa3y. OpraHHnecKyio nacTB HarpeBaioT flonpH6jiH3HTe,nbHO 160°G npH nerKOM BaxyyMe (10-200 τορρ) πρκ 9tom οτγοηηιοτοηocTaTonHaa a3eoTponHaH CMecb BOfla - xjiopHCTbiň BOflopofl - pacTBopHTejib h jie-Tynne κομποηθητη, TaKHM cnocoGoM nojiynaiOT b cootbgtctbhh c Hcnojib3OBaHHbiMflH33OTHpOB3HHbIM ΚΟΜΠΟΗβΗΤΟΜ COOTBeTCTBylOmHe KpaCHTejIH Ha OCHOBe OpraHOCHJI“oKcaHos hjih nojmopraHCHnoKcaHOB, npeRHa3HaneHHbie oco6eHHo ajih chjihkohobHJIH M3CC Ha OCHOBe CHJIHKOHOB. OcoSblM npeHMymeCTBOM penieHHH, corjiacHO H3O6-ρβτβΗΗΐο, HBjíHeTCH το, Ητο flocTaTOHHO ywe óflHoro CHJiOKcaHOBoro aaMecTHTejiab apoMaranecKOM coeflHHeHHH, hto6m cflejiaTb sto coeflHHeHHe npHroflHbíM b xa-necTBe flBeTOoČpaayiomero KOMnoHeHTa ajih αη33οτηροβ3ηηογο apoMaraHecKoro 3mh—Ha h tíTOÓM nojiyxiHTb aaoKpacHTejih. 3to 03HanaeT, hto npaKTHnecKH Bce opraHo-CHfloKcaHbí, nojmopraHocHJioKcaHbí hjih opraHocHJioKcaHOBbie coeflHHeHHH MoryT 6μτβHCnOJlb3OBaHbl Β Κ3ΗβΟΤΒβ flBeTOO6pa3ywmerO KQMnOHBHTa fljiH flHa3OTHpOB3HHbIX __apoMaTHaecKHx βμηηοβ,nocKOJibKyohh ημθιοτοαηη eflHHCTBeHHbiňHe3aMemeHHbiii apoMa-THnecKHň paflHKaji y aTOMa κρθμηηη, b npocTeňmeM cjiyaae φβΗΗΐη,Ηωύ paflHKaji.Tax, HanpHMep, MoryT 6ητβ rHflpojiH3OBaHbi ο6μηηβιμ cnocoBoM xjiopcHJiaHbí, coflep-xcaniHe φeHHJIbHy ^ o rpynny, b tbkom apoMaTHflecKOM coeflHHeHHH, xax TOJiyoji. Bkhcjimh oxjiaxaeHHbiň rHflpojiH3Hbiň pacTBop npHKanbroáwT πρκ nepeMeniHBaHHH npefl-BapHTejibHO αη33οτηροβ3ηηβιη pacTBop apoMaranecKOFO aMHHa, tara Moxhe Flo-SapnHTb KHCJlblH rHflpOJIH3HblH paCTBOp ΚρβΜΗΗΗΟρΓΒΗΗΗβΟΚΟΓΟ CoeflHHeHHH The pACT-BOpy cojih flHa30HHH. 3aTeM fljia aaBepmeHHfl coaeTaHHH flonojiHHTejibHO nepeMenm-eaioT h no οκοηη3ηηη OTflejiHWT BopHyio φa3y. OpraHHnecKyio nacTB HarpeBaioT flonpH6jiH3HTe, nbHO 160 ° C NPH nerKOM BaxyyMe (10-200 τορρ) πρκ 9tom οτγοηηιοτοηocTaTonHaa a3eoTponHaH CMecb BOfla - xjiopHCTbiň BOflopofl - pacTBopHTejib H-jie Týnn κομποηθητη, Takhte cnocoGoM nojiynaiOT cootbgtctbhh b c Hcnojib3OBaHHbiMflH33OTHpOB3HHbIM ΚΟΜΠΟΗβΗΤΟΜ COOTBeTCTBylOmHe KpaCHTejIH Ha OCHOBe OpraHOCHJI "oKcaHos hjih nojmopraHCHnoKcaHOB, npeRHa3HaneHHbie oco6eHHo ajih chjihkohobHJIH M3CC Ha OCHOB CHJIHKOHOB. OcoSblM npeHMymeCTBOM penieHHH, corjiacHO H3O6-ρβτβΗΗΐο, HBjíHeTCH το, Ητο flocTaTOHHO YWE óflHoro CHJiOKcaHOBoro aaMecTHTejiab apoMaranecKOM coeflHHeHHH, hto6m cflejiaTb hundred coeflHHeHHe npHroflHbíM b XA necTBe flBeTOoČpaayiomero KOMnoHeHTa ajih αη33οτηροβ3ηηογο apoMaraHecKoro 3MH-Ha H tíTOÓM nojiyxiHTb aaoKpacHTejih. 3to 03HanaeT, HTO npaKTHnecKH BCE Oprah-CHfloKcaHbí, nojmopraHocHJioKcaHbí hjih opraHocHJioKcaHOBbie coeflHHeHHH Ballad 6μτβHCnOJlb3OBaHbl Β Κ3ΗβΟΤΒβ flBeTOO6pa3ywmerO KQMnOHBHTa fljiH flHa3OTHpOB3HHbIX __apoMaTHaecKHx βμηηοβ, nocKOJibKyohh ημθιοτοαηη eflHHCTBeHHbiňHe3aMemeHHbiii Apa-THnecKHň paflHKaji Y is κρθμηηη b npocTeňmeM cjiyaae φβΗΗΐη, Ηωύ paflHKaji.
Tax KaK b npoflecce peaxflHH coHeTaHHH coxpaHHioTCH Bce ΦνΗΚΑΗΟΗΗτίΒΗΗβ rpyn-nbi, HMeiomHecH β αΑηηομ cjiynae y aTOMa κρβΜΗΗΗ hjih b opraHOCHjioKcaHOBoň mo-Jiexyjie, το hhhto He MemaeT flajihHeňraeň nepepa6oTKe sthx KpacHTejieň, OhhMOryT 6bITb HCnOJlb3OBaHbI B ΤΗΠΗΗΗΜΧ φΟρΜβΧ ΠρΗΜΘΗΘΗΗΗ CHJIHKOHOB, HanpHMep,Tax KaK b npoflecce peaxflHH coHeTaHHH coxpaHHioTCH BCE ΦνΗΚΑΗΟΗΗτίΒΗΗβ rpyn-NBI HMeiomHecH β αΑηηομ cjiynae y carbon κρβΜΗΗΗ hjih b opraHOCHjioKcaHOBoň Mo-Jiexyjie, το hhhto He MemaeT flajihHeňraeň nepepa6oTKe sthx KpacHTejieň, OhhMOryT 6bITb HCnOJlb3OBaHbI B ΤΗΠΗΗΗΜΧ φΟρΜβΧ ΠρΗΜΘΗΘΗΗΗ CHJIHKOHOB, HanpHMep,
B BHfle oKpameHHoro MeTHJ^eHHJi- hjih Φθηηιιοηιιηκοηοβογο Mácjia, Kax oKpameH-1 Hblň CHJIHKOHOBblň KayHVK HJIH KaK ΟΚρ3ΠΙβΗΗ3Η CHJIHKOHOB 33 CMOJia. OHH MOryT 6biTb nojiyueHbí KaK b HeHanojiHeHHOM ‘coctohhhh b BHfle OKpaineHHbrx np03panHbixnpoflyKTOB hjih B BHfle, HanpHMep, HanójiHeHfibix OKpameHHbix cnjiHKOHOBbix Kayay- 248252 4 ΚΟΒ, Tax Η ΠρΗΜβΗΘΗΜ Β BHfle ΟΤΤβΗΟΜΗΗΧ naCT flna flpyrHX nOjiHMepOB, ecjmOHH C ΗΗΜΗ ΒΜβΟΤβ CfflHBaiOTCH HJTH COnOJIHMepHByiOTCH. 06pa6OTKH HJ1H ΠΟΚρΗΤΗΗnoBepXHOCTeň c uejibio, HanpHMep προτΗΒΟχορροΒΗΟΗΗοϋ samu to MoryT c hx no-Μοπρ,ιο Taxxe npoBOflHTbcH, xax h c flpyrHMH cHJWKOHaMH, rax xax sth npopyxTH,COrnaCHO Η3θ6ρβΤβΗΗΚ>, HBJIHIOTCH X3X XpaCHTejIHMH, ΤβΚ H CHJIHXOHaMH,B BHfle oKpameHHoro MeTHJ ^ eHHJi- hjih Φθηηιιοηιιηκοηοβογο Mácjia, Kax oKpameH-1 Hblň CHJIHKOHOBblň KayHVK HJIH KaK ΟΚρ3ΠΙβΗΗ3Η CHJIHKOHOB 33 CMOJia. OHH Ballad 6biTb nojiyueHbí KaK HeHanojiHeHHOM b 'b coctohhhh BHfle OKpaineHHbrx np03panHbixnpoflyKTOB hjih B BHfle, HanpHMep, HanójiHeHfibix OKpameHHbix cnjiHKOHOBbix Kayay- ΚΟΒ 4 248 252, Tax Η ΠρΗΜβΗΘΗΜ Β BHfle ΟΤΤβΗΟΜΗΗΧ retrieves flna flpyrHX nOjiHMepOB, ecjmOHH C ΗΗΜΗ ΒΜβΟΤβ CfflHBaiOTCH HJTH COnOJIHMepHByiOTCH. 06pa6OTKH HJ1H ΠΟΚρΗΤΗΗnoBepXHOCTeň c uejibio, HanpHMep προτΗΒΟχορροΒΗΟΗΗοϋ itself that no Ballad c HX-Μοπρ, ιο taxxi npoBOflHTbcH, c h XAX flpyrHMH cHJWKOHaMH Rax XAX STH npopyxTH, COrnaCHO Η3θ6ρβΤβΗΗΚ> HBJIHIOTCH X3X XpaCHTejIHMH, ΤβΚ CHJIHXOHaMH H,
ΠρΗΜβρΜ OCymeCTBJieHHH H3O6peTeHHH ΠρΗΜβρ 1ΠρΗΜβρΜ OCymeCTBJieHHH H3O6peTeHHH ΠρΗΜβρ 1
PacTBOp 21,2 BecoBOfl nacTH 4>eHHJrrpHXjiopcHJiaHa b 10 BecoBbix aacTHx TOjiyojianpHKanbiBaiOTonpH nepeMemnBaHHH b τβηβΗΗβ 10 mhh. b Tpexropjiyw xoji6y c 06-paTHblM XOJIO^HJIbHHKOM, B KOTOpOH HaXOflHJlHCb 54~BeCOBbie M3CTH flHCTHrtJIHpOBaH ·Hoň BOflbí h 32 BecoBwe mbcth MeTaHojia. Ho οκοημηηηη npHKanuBaHHH pacTBOpa(fceHHJiTpHXjiopcHJiaHa peaxnHOHHyio CMecb oxjiawflaioT flo 5°C h ΜβρυιβΗΗΟ npHxanbi-BaiOT paeTBOp COJIH ffiHa3OHHH, nOJTiyHeHHOfi 06blHHblM cnocoeoM H3 9,3 Becosoftmbcth aHHJiHHa, c Taxoň cKopocTBio, hto6m TeMnepaTypa ne npeBbímajia 10°0,Ilocae 3τογο coflepatHMoe nepeMenmBajOT etne τρκ qáca npa noHHxeHHoň TeMnepaTy-pe, mto6h nojiHOCTbw 3aBepmHTb peaKymo ccnieTaHna. Πο OKomamm οτρ,εηπητBOflHyro 4>a3y h «HcTRnnanHeň ynajjflioT opraromecKuň pacTBopHTejib. OcTaBnraňcHnpoflyKT npeflCTaBJíaeT co6oň npO3paMHy» xejiTO-xopHHHeByio CMOjiy, KpacanjHňκομποηθητ β κοτοροή xapaxTepHayeTCH MOHOMepHbíMH eflHHHpaMH cnepyromeň o6qeft4>opMy.ní>i: (CéH5-N=N-CéH4SÍO3/2 )x ngHMeg_2PacTBOp 21.2 BecoBOfl nacTH 4> eHHJrrpHXjiopcHJiaHa b 10 BecoBbix aacTHx TOjiyojianpHKanbiBaiOTonpH nepeMemnBaHHH b τβηβΗΗβ 10 mhh. b Tpexropjiyw xoji6y c 06-paTHblM XOJIO ^ HJIbHHKOM, B KOTOpOH HaXOflHJlHCb 54 ~ BeCOBbie M3CTH flHCTHrtJIHpOBaH · Fight BOflb h 32 BecoBwe mbcth MeTaHojia. Ho οκοημηηηη npHKanuBaHHH pacTBOpa (fceHHJiTpHXjiopcHJiaHa peaxnHOHHyio CMecb oxjiawflaioT flo 5 ° C h-ΜβρυιβΗΗΟ npHxanbi BaiOT paeTBOp COJIH ffiHa3OHHH, nOJTiyHeHHOfi 06blHHblM cnocoeoM H3 9.3 Becosoftmbcth aHHJiHHa c cKopocTBio taxa, hto6m TeMnepaTypa not npeBbímajia 10 ° 0 Ilocae 3τογο coflepatHMoe nepeMenmBajOT Etne τρκ qáca noHHxeHHoň TeMnepaTy NPA-PE mto6h nojiHOCTbw 3aBepmHTb peaKymo ccnieTaHna. Πο OKomamm οτρ, εηπητBOflHyro 4> a3y h «HcTRnnanHeň ynajjflioT opraromecKuň pacTBopHTejib. OcTaBnraňcHnpoflyKT npeflCTaBJíaeT co6oň npO3paMHy» xejiTO-xopHHHeByio CMOjiy, KpacanjHňκομποηθητ β κοτοροή xapaxTepHayeTCH MOHOMepHbíMH eflHHHpaMH cnepyromeň o6qeft4> opMy.ní > i: (C 6 H 5 -N = N-C 6 H 4 SiO 3/2) x ngHMeg_2
CoOTBGTCTBeHHO npHMepy 1 ΓΟΤΟΒΗΤ FHflpOJIH3HbIH paCTBOp 4>eHHnTpHXJIOpCHJiaHa.06bWHbiM cnocofíoM AHaaorapyioT 18,3 BecoBoň tiaCTH 2,4-flHHHTpoaHHjiHHa, Tuňpo-jni3Hbiň paeTBOp npHxanbiBaioT npH nepeMeuiHBaraiH B oxjia«peHHbiň flo 0°C pacTBopcojth flna3OHna c Taxoň cxopocTbto, mto6h TeMnepaTypa He npeBbirnajia 5°C. ΠοoxoHwaHHH npHxanbroaHHH flanbHeňmyio o6pa6oTxy ηροΒΟ^ΗΤ Tax xe, xax onucanob npHMepe 1. ΤβΜΗΟ-κορΗΜΗβΒΗή npoflyxT coflepxHT b xanecTBe xpacantero χομπο-HeHTa MOHOMepHbie 3BeHbH, onHCbmaeMbie cjienyioineft oómseň 4>opMyjioň: I . C(O2N\ CsH3-N=N-CeH4SiO3/2Jx 10 BecoBbix aacTeťí cmojim pacTBoparoT B 90 BecoBbtx nacTflx Tonyojia h hshochttohxhm cjioeM Ha ajuoMHHHeBbie, CTajibHbie h MeflHbie nojiocKH. Taxxe nocTynajiH cocMonoťi, flaHHoň b npHMepe 1, nojiyneHHOň, o#Haxo, 6es floĎaBKH cojih flHa3OHHH.Ó6pa6oTaHHbie MeTajuiHMecxne hojiockh noMemajin b sxcHxaTOp c cojiHHoxHcjioft cpe-floň. Ilocjie 20 flHeň BbwepxKH hojiockh, xoTOpwé 6mjih ποχρωτω HeoxpameHHoft cmo-noň, noxa3broajiH yxenpH3HaxH xoppO3HH, TOrfla xax apyrne 6mjih eme 6β3 sthxnpH3HaxOB. ΠρΗΜβρ 3 CMecb h3 50 BecoBbix nácTeň φβΗΗήτρΗΧΠοροΗΠβΗΗ, 25 BecoBbix nacTeň ,π,ΗφβΗΗπ-flHXJiopcHJiaHa h 100 BecoBbix nacTeň Tojiyojia CMeioHBaioT nocTeneHHO npn nepeMe-ΠΜΒβΗΗΗ B XpyrJlOflOHHoft XOJl6e C OÓpaTHMM XOJIOffHJIbHHKOM C 200 BeCŮBblMH MaCTH“mh flHCTHJuiHpoBaHHoň BOflbi. Ποτομ nepeMeniHBaioT eme 30 mhh, η 3βτβΜ npHxanhiBa-KJT ΠΡΗ 0°C paCTBOp COJIH £H33OHHH, nojiyMeHHOň H3 56 BecóBbix Hacreň Π-ΗΗΤρθ-aHHJiHHa, c τβκοή cxopocTbio, mto6w TeMnepaTypa He npeBbímajia 5 C, fljia aaBep-meHHH peaxHHH coMeTariHH nepeMemHBajiH eme 30 mhh, Hocjie οτρεηβΗΗΗ HeopraHH- 248252 5 qecKoro pacTBopa οτγοηηιιη c πομοπιβιο BaKyyMHoň ahctujuihuhh oprammecKuňpacTBOpHTenb. lIojiyqajicH KpacHO-κορΗΗΗβΒωή pacnjiae, Π£ΗΜ£2_4 B KpyrnoflOHHoň Koji6e CMemHBaiOT npH nepeMeniHBaHHH 58,6 BecoBoň qacTH ΜετΗΠ-TpHaneTOKCHCHJiaHa c 29 BecoBbíMH qacTHMH fln<beHnjicmiaH#HOjia, Πο oJcjiajK#eHHHflo 0°C npoflyKT Hcnojib3ywT b KaqecTBe UBeT0o6pa3yromero κομποηθητβ ^jih pacT-Bopa cojih flHa30HHH, nojiyqeHHoro H3 27,6 BecoBoň qacTH n—HHTpoaHHJiHHa, noč-ně saBepme.Wia πρκ okojio 5 C peaKimu coqeTaHHH h OTflejieHHH o6pa3OBaBnierocHnojiHopraHocHJiOKcaHa nojiyqaioT 3ejieHo—KopHqHeBbiň pacnjiaB, κοτορωή xapaKTepn-3yeTca cjienymmeň o6meň <l>opMy.noň: (CH3COO)2 (CH3)Si-O-Si(RťR2) -O-Si(CH3)(CHjCOO^ R’ = -C6H5-N=N-C6H4-NO2 R< Π£ΗΜβ£_5 nonyqaiomywcH no npnMepy 1 CMecb no OTgejieHHH BOflHOň φβ3Μ oxjiaacflaiOT eme pa3flO npH6jlH3HTeJlbHO 0-5°C H CMeiDHBaiOT C paCTBOpOM COJIH ΉΗ33ΟΗΗΗ, nOJiyqeHHOňH3 28,7 BecoBoň qacTH 1 —ημηηοη3Φτηιι3μηη3 . CMecb nepeMeniHeaiOT eme 3 qac. npHnoHHHceHHoň TeMnepaType, 3βτβΜ b nejiHTejibHÓň BopoHKe OTflejiaioT BOflHyio φa3y hocTaTOK flHCTHJumpyioT b BaxyyMe tijih yflajieHHH pacTBopHTejiH, nojiyqaeTCH xpac-Hbiň pacnnaB, κοτοριπή πθγκο pacTBopneTCH b 6eH3ojie, Tojiyojie, KCHJione, rh-ΜβτηηφορΜβΜΗΑβ, 3THJiaťieTaTe, aqeTOHe h T.fl, ΠρΗΜβρ 6 B KpyrnoflOHHoň Koji6e pacTBopawT 13 BecoBbix qacTeň n-xnopaHHJiHHa, 50 BecoBbixqacTeň BOflbí h 30 BecoBbix qacTeň KOHueHTpHpOBaHHoň cojiHHQň khcjiótij h no ox-jiajKfleHHH flo 0°C flHa3OTHpy»T. B stot pacTBOp cojih αη33οηηη npHKanbiBawT πρκ0°C CMecb H3 22 BecoBbix qacTeň AeHHJiTpHXJiopcHJiaHa h 20 eecoBbix qacTeň to-jiyojia c τβκοή cKopocTbio, ητοβω TeMnepaTypa peaKiiHOHHoň cMecn He npeBbímajia+5 C. Πο OKOHqaHHH npHKanbroaHHH nepeMemHBaioT πρκ ποηη^κθηηοη TeMnepaTypeeme 3 qac. ajih 3aBepmeHHH peaKiiHH coqeTaHHH h 3aTeM nocTynaioT Tax we, khkonncaHO b npHMepe 1. nojryqaeTCH CMOjiHCTbiň npOflyKT necoqHoro flBeTa.CoOTBGTCTBeHHO npHMepy 1 ΓΟΤΟΒΗΤ FHflpOJIH3HbIH paCTBOp 4> eHHnTpHXJIOpCHJiaHa.06bWHbiM cnocofíoM AHaaorapyioT 18.3 BecoBoň tiaCTH 2,4-flHHHTpoaHHjiHHa, Tuňpo-jni3Hbiň paeTBOp npHxanbiBaioT NPH nepeMeuiHBaraiH B oxjia «peHHbiň flo 0 pacTBopcojth flna3OHna C taxon cxopocTbto, mto6h TeMnepaTypa He npeBbirnajia 5 ° C. ΠοoxoHwaHHH npHxanbroaHHH flanbHenmyio o6pa6oTxy ηροΒΟ ^ ΗΤ Tax xe, xax onucanob npHMepe 1. npoflyxT coflepxHT b xanecTBe xpacantero-HeHTa MOHOMepHbie 3BeHbH, onHCbmaeMbie cjienyioineft oómseň 4> opMyjioň: I. C (O 2 N \ SCH3-N = N-CeH4SiO3 / 2JX 10 BecoBbix AACt cmojim pacTBoparoT B 90 BecoBbtx nacTflx Tonyojia h hshochttohxhm cjioeM Ha ajuoMHHHeBbie, CTajibHbie h MeflHbie nojiocKH. Taxxi nocTynajiH cocMonoťi, flaHHoň b npHMepe 1 nojiyneHHOň about # Haxo, 6es floĎaBKH cojih flHa3OHHH.Ó6pa6oTaHHbie MeTajuiHMecxne hojiockh noMemajin b sxcHxaTOp c-CPE cojiHHoxHcjioft Flon. Ilocjie 20 flHeň BbwepxKH hojiockh, xoTOpwé 6mjih ποχρωτω HeoxpameHHoft CMO-non noxa3broajiH yxenpH3HaxH xoppO3HH, TOrfla XAX apyrne 6mjih EME 6β3 sthxnpH3HaxOB. ΠρΗΜβρ CMecb 3 H3 50 BecoBbix loaded φβΗΗήτρΗΧΠοροΗΠβΗΗ 25 BecoBbix loaded, π, ΗφβΗΗπ-flHXJiopcHJiaHa h 100 BecoBbix loaded Tojiyojia CMeioHBaioT nocTeneHHO npn NEP-ΠΜΒβΗΗΗ B XpyrJlOflOHHoft XOJl6e C OÓpaTHMM XOJIOffHJIbHHKOM C 200 BeCŮBblMH MaCTH "mh flHCTHJuiHpoBaHHoň BOflbi. Ποτομ nepeMeniHBaioT EME 30 MHH, η 3βτβΜ npHxanhiBa-KJT ΠΡΗ 0 C paCTBOp COJIH £ H33OHHH, nojiyMeHHOH H3 56 BecóBbix Hacreň-Π-ΗΗΤρθ aHHJiHHa c τβκοή cxopocTbio, mto6w TeMnepaTypa He npeBbímajia 5C fljia aaBep-meHHH peaxHHH coMeTariHH nepeMemHBajiH 30 eme MHH, Hocjie οτρεηβΗΗΗ HeopraHH- 248252 5 qecKoro pacTBopa οτγοηηιιη c πομοπιβιο BaKyyMHoň ahctujuihuhh oprammecKuňpacTBOpHTenb. lIojiyqajicH KpacHO-κορΗΗΗβΒωή pacnjiae, Π £ 24 £ ΗΜ B KpyrnoflOHHoň Koji6e CMemHBaiOT NPH nepeMeniHBaHHH 58.6 BecoBoň qacTH ΜετΗΠ TpHaneTOKCHCHJiaHa C-29 BecoBbíMH qacTHMH FLN <beHnjicmiaH # heals Πο oJcjiajK eHHHflo # 0 npoflyKT Hcnojib3ywT b KaqecTBe UBeT0o6pa3yromero κομποηθητβ-south pACT-Bopa cojih flHa30HHH, nojiyqeHHoro H3 27.6 BecoBoň qacTH n HHTpoaHHJiHHa NOC-saBepme.Wia them πρκ okojio C 5 H peaKimu coqeTaHHH OTflejieHHH o6pa3OBaBnierocHnojiHopraHocHJiOKcaHa nojiyqaioT 3ejieHo-KopHqHeBbiň pacnjiaB, κοτορωή xapaKTepn-3yeTca cjienymmeň o6meň <l> opMy.noň : (CH 3 COO) 2 (CH 3) Si-O-Si (R 1 R 2) -O-Si (CH 3) (CH 3 COO 2 R '= -C 6 H 5 -N = N-C 6 H 4 -NO 2 R Π £ ΗΜβ £ _5 nonyqaiomywcH no npnMepy 1 CMecb no OTgejieHHH BOflHOň φβ3Μ oxjiaacflaiOT EME pa3flO npH6jlH3HTeJlbHO 0-5 ° C CH CMeiDHBaiOT paCTBOpOM COJIH ΉΗ33ΟΗΗΗ, nOJiyqeHHOňH3 28.7 BecoBoň qacTH 1 -ημηηοη3Φτηιι3μηη3. CMecb nepeMeniHeaiOT EME 3 QAC. npHnoHHHceHHoň dark paType, 3βτβΜ b nejiHTejibHÓň BopoHKe OTflejiaioT BOflHyio φa3y hocTaTOK flHCTHJumpyioT b BaxyyMe tijih yflajieHHH pacTBopHTejiH, nojiyqaeTCH xpac-Hbiň pacnnaB, κοτοριπή πθγκο pacTBopneTCH b 6eH3ojie, Tojiyojie, KCHJione, rh-ΜβτηηφορΜβΜΗΑβ, 3THJiaťieTaTe, aqeTOHe h T.fl, ΠρΗΜβρ 6 B KpyrnoflOHHoň Koji6e pacTBopawT 13 BecoBbix qacTen n-xnopaHHJiHHa, 50 BecoBbixqacTen BOflb h 30 BecoBbix qacTen KOHueHTpHHErHErHhQHhhhhhhhhhhhhhhhhhhhhhHhH flo 0 ° C flHa3OTHpy »T. B one hundred tons pacTBOp cojih αη33οηηη npHKanbiBawT πρκ0 C H3 CMecb BecoBbix qacTeň AeHHJiTpHXJiopcHJiaHa 22 h 20 eecoBbix qacTeň to-jiyojia c τβκοή cKopocTbio, ητοβω TeMnepaTypa peaKiiHOHHoň cMecn He npeBbímajia +5 C. Πο OKOHqaHHH npHKanbroaHHH nepeMemHBaioT πρκ ποηη ^ κθηηοη TeMnepaTypeeme 3 QAC. ajih 3aBepmeHHH peaKiiHH coqeTaHHH h 3aTeM nocTynaioT Tax we, khkonncaHO b npHMepe 1. nojryqaeTCH CMOjiHCTbine npOflyKT necoqHoro flBeTa.
OopMyjia H3o6peTeHHH 1. Cnocoó nojiyqeHHH aáOKpacHTejieň Ha. ocHOBe opraHOCHJioKcaHOB h nojmopraHO-CHJIOKCaHOB, CHHTeSHpOBaHHbIX H3 MOHOMepHbIX eflHHHfl R3SiO^2 , RjSiO h/hjih RSiO3/2 rfle R o3HaqaeT oflHHaKOBbie hjih pa3jiHqHbie opraHHqecKHe paflHKajibi, 3tom BOflůpo-fla hjih κοΜποΗεκτ, coflepxaniHH a3orpynny, c πομοπιβιο rHflpojiH3a h KOHfleHcaiiHHopraHoxjiopcHjiaHOB hjih qepe3 peaKUHio opraHocHJiaHOB hjih OpraHOCHJioKcaHOB, hjihnojiHopraHocHjiOKcaHOB,OTjiHqajotnHňcH τβΜ, hto CHJioKCH3aMemeHHbie apoMaTHqecKHeCOeflHHeHHH ČoqeTaiOT c AH33OTHpOBaHHbIMH apOM3THqeCKHMH aMHHHMH· 2. Cnocofí no nyHKTy 1, OTJinqaiomHňcH τθμ, hto coqeTaHHe c flHa3OTHpoBaHHbiMHapOMHTHqeCKHMH aMHHaMH npOHCXOflHT B KHCJIOM BOflHOM paeTBOpe BO BpeMH rHfl-pojiHaa opranoxjiopcHjiaHOB. 248252 6 3. Cnocofí no nynKTy 1, OTJiHHawinHHCH τβΜ, mto coneTaHHe c αηη3οτηροβ3ηημμηapoMaTunecKHMH aMHHaMH προτβκθβτ b khcjiom bo#hom pacTBope nocjie rHflpojiH·3a opraHOxnopcnJiaHOB. 4. Cnoco6 no nyHKTy 1, OTjnrqáioDutňcH τβΜ, ητο coneTaHHe c αη33Οτηροβ3ηημμηapoMaTHMecKHMH aMHHaMH προτεκββτ nocne hjih bo BpeMa npeBpameHHH b nojiH-OpraHOCHJlOKČaHM. AHHOTAUHfl_OopMyjia H3o6peTeHHH 1. Cnocoó nojiyqeHHH aáOKpacHTejieň Ha. ocHOBe opraHOCHJioKcaHOB h nojmopraHO-CHJIOKCaHOB, CHHTeSHpOBaHHbIX H3 MOHOMepHbIX eflHHHfl R3 SiO ^ 2 RJSI h / hjih RSiO3 / 2 rfle R o3HaqaeT oflHHaKOBbie hjih pa3jiHqHbie opraHHqecKHe paflHKajibi, 3tom BOflůpo-Fla hjih κοΜποΗεκτ, coflepxaniHH a3orpynny c πομοπιβιο rHflpojiH3a h KOHfleHcaiiHHopraHoxjiopcHjiaHOB hjih qepe3 peaKUHio opraHocHJiaHOB hjih OpraHOCHJioKcaHOB, hjihnojiHopraHocHjiOKcaHOB, OTjiHqajotnHňcH τβΜ, HTO CHJioKCH3aMemeHHbie apoMaTHqecKHeCOeflHHeHHH ČoqeTaiOT c AH33OTHpOBaHHbIMH apOM3THqeCKHMH aMHHHMH · second Cnocofí well nyHKTy 1 OTJinqaiomHňcH τθμ, HTO coqeTaHHe c flHa3OTHpoBaHHbiMHapOMHTHqeCKHMH aMHHaMH npOHCXOflHT B KHCJIOM BOflHOM paeTBOpe BO BpeMH rHfl-pojiHaa opranoxjiopcHjiaHOB. 248252 6 3. Cnocofí no nynKTy 1, OTJiHHawinHHCH τβΜ, mto coneTaHHe c αηη3οτηροβ3ηημμηapoMaTunecKHMH aMHHaMH προτβκθβτ b khcjiom bo # hom pacTBope nocjie rHflpojiH · 3a opraHOxnopcnJiaHOB. 4. Cnoco6 no nyHCTy 1, OTjnrqáioDutňcH τβΜ, ητο coneTaHHe c αη33Οτηροβ3ηημμηapoMaTHMecKHMH andMHHaMH προτεκββτ nocne hjih bo BpeMa npeBpameHHH b nojiH-OpraHOCHJlOKČaHM. AHHOTAUHfl_
Η3θ6ρβτβΗΗβ KacaeTCH a3OKpacHTejieň Ha οοηοβθ OpraHOCHJioKcaHOB hjih nojinop-raHOCHJIOKCaHOB. OhH CHHTe3HpOBaHbI H3 MOHOMepHbIX eflHHHIU R5SÍOf^2 , RzŠíO m/hjih RSiO3/2 ryje R osHanaeT oflHHaKOBwe hjih pa3jiHHHbie opr&HHHecKHe pa^HKanbi, btom BOflopo-fla hjih κομποηθητ, conepJKamHň a3orpynny. KpacHmHň κοΜΠΟΗβΗΤ CB«3aH c chjihko-HOBoň MojieKynoň roMeonojiupHoň cbh3I>jo h BCTpanBaeTCB b nojiHMepHyro MOjieKyjiyconeTaHHeM c αηββοτηροββηηημη apoMHTHUecKHMH aMHHaMH. Πο 3 το My npocroMy cnoco6y mojkho nojiyuaTb OKpameHHbie b mHpoKHň οπβκτρ chjihkoho-Bbie npoayKTbi Bcex bh«ob . 3thKpacHTeJiH npHMeHHMbi ksk cMonbi,MacJia hjih KayqyK,cMe~raaHHbiň b naHHOM cnynae c ο6ηηημμη flo6aBKaMH,TaK h b xanecTBe οττβΗΟΗΗωχ nacr ^jihOKpameHHbix chjihkohob.Ohh npHroflHhi TaiCKe ftJiíi Bcex flpyrnx H3BecTHbix nejieBbixΠρΗΜβΗβΗΗΗ pHJIHKOHOB ΤΗΚΗΧ, KBK cononHMepH3an;HH C ftpyFHMH nojiHMepaMH, o6-paÓoTKa hjih ποκρΜΤΗβ nosepxHOCTeň, ttanpHMep, KepaMHnecKofi, cHJiHKaTHoň hjihMeTanJiHneeKOH npHpoflbí, a τβκχβ hjih o6pa6oTKH τθκοτηπη. ΠρΗ3Η3ΗΟ Η3θ6ρβΤβΗΗβΜ ΠΟ pe3yjIhTaTaM 3KCnepTH3bI, OCyiHeCTBJíeHHOfl BeflOMCTBOMΠΟ fleJiaM Η3θ6ρεΤβΗΗ/ί Η ΠβΤβΗΤΟΒ FflP. 248252Θ3θ6ρβτβΗΗβ KacaeTCH and 3OKpacHTejie Ha οοηοβθ OpraHOCHJioKcaHOB hjih nojinop-raHOCHJIOKCaHOB. Ohh CHHTe3HpOBaHbI H3 MOHOMepHbIX eflHHHIU R5SiOf ^ 2, RsO m / hjih rsi3 / 2 ryje R osHanaeT oflHHaKOBwe hjih pa3jiHHHbie opr & HHHecKHe pa ^ HKanbi, btom BOflopo-fla hjih κομποηθητ, conepJKamHn a3orpynny. KpacHmHň κοΜΠΟΗβΗΤ CB «3aH c chjihko-HOBoň MojieKyno roMeonojiupHoň cbh3I> jo h BCTpanBaeTCB b nojiHMepHyro MOjieKyjiyconeTaHHeM c αηββοτηροββηηημη apoMHTHUecKHMH andMHHaMH. Πο 3 το My npocroMy cnoco6y mykho nojiyuaTb OKpameHHbie b mHpoKHn οπβκτρ chjihkoho-Bbie npoayKTbi Bcex bh «ob. 3thKpacHTeJiH npHMeHHMbi KSK cMonbi, MacJia hjih KayqyK CME raaHHbiň b ~ c naHHOM cnynae ο6ηηημμη flo6aBKaMH and HB xanecTBe οττβΗΟΗΗωχ NaCrO ^ jihOKpameHHbix chjihkohob.Ohh npHroflHhi TaiCKe ftJiíi Bcex flpyrnx H3BecTHbix nejieBbixΠρΗΜβΗβΗΗΗ pHJIHKOHOB ΤΗΚΗΧ, CSC cononHMepH3an; HH C ftpyFHMH nojiHMepaMH, O6-paÓoTKa hjih ποκρΜΤΗβ nosepxHOCTen, ttanpHMep, KepaMHnecKofi, cHJiHKaTHoň hjihMeTanJiHneeKOH npHpoflbí, and τβκχβ hjih o6pa6oTKH τθκοτηπη. Πρθ3Η3ΗΟ θ3θ6ρβΤβΗΗβΜ ΠΟ pe3yjIhTaTaM 3KCnepTH3bI, OCyiHeCTBJeHHOfl BeflOMCTBOMPΟ fleJiaM Η3θ6ρεΤβΗΗ / ί Η ββΤβΗΤΟΒ FflP. 248252
Claims (3)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD20458978A DD140469B1 (en) | 1978-04-05 | 1978-04-05 | PROCESS FOR THE PREPARATION OF AZOFINES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS248252B1 true CS248252B1 (en) | 1987-02-12 |
Family
ID=5512076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS791666A CS248252B1 (en) | 1978-04-05 | 1979-03-12 | Method of azo-dye stuffs production |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS54148819A (en) |
| CS (1) | CS248252B1 (en) |
| DD (1) | DD140469B1 (en) |
| DE (1) | DE2908206A1 (en) |
| FR (1) | FR2421931A1 (en) |
| GB (1) | GB2018804B (en) |
| SU (1) | SU973579A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0283206A3 (en) * | 1987-03-12 | 1990-08-22 | Hewlett-Packard Company | Covalently labeled siloxane polymers |
| US5070158A (en) * | 1987-03-12 | 1991-12-03 | Hewlett-Packard Company | Covalently labeled siloxane polymers |
| DE19710461A1 (en) * | 1997-03-13 | 1998-09-17 | Wacker Chemie Gmbh | Organopolysiloxanes containing dye residues |
| JP5518697B2 (en) * | 2007-05-11 | 2014-06-11 | ビーエーエスエフ ソシエタス・ヨーロピア | Polymer dye |
-
1978
- 1978-04-05 DD DD20458978A patent/DD140469B1/en not_active IP Right Cessation
-
1979
- 1979-03-02 DE DE19792908206 patent/DE2908206A1/en not_active Withdrawn
- 1979-03-07 SU SU797770489A patent/SU973579A1/en active
- 1979-03-12 CS CS791666A patent/CS248252B1/en unknown
- 1979-03-23 GB GB7910305A patent/GB2018804B/en not_active Expired
- 1979-04-04 FR FR7908522A patent/FR2421931A1/en not_active Withdrawn
- 1979-04-05 JP JP4152779A patent/JPS54148819A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE2908206A1 (en) | 1979-10-11 |
| DD140469B1 (en) | 1980-12-24 |
| SU973579A1 (en) | 1982-11-15 |
| FR2421931A1 (en) | 1979-11-02 |
| GB2018804B (en) | 1982-12-08 |
| DD140469A1 (en) | 1980-03-05 |
| GB2018804A (en) | 1979-10-24 |
| JPS54148819A (en) | 1979-11-21 |
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