CS245741B1 - Solution containing quinone namely photographic bleach liquid - Google Patents

Solution containing quinone namely photographic bleach liquid Download PDF

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Publication number
CS245741B1
CS245741B1 CS632082A CS632082A CS245741B1 CS 245741 B1 CS245741 B1 CS 245741B1 CS 632082 A CS632082 A CS 632082A CS 632082 A CS632082 A CS 632082A CS 245741 B1 CS245741 B1 CS 245741B1
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Czechoslovakia
Prior art keywords
solution containing
photographic bleach
containing quinone
bleach liquid
xhhoh
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CS632082A
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Czech (cs)
Inventor
Goetz Pollakowski
Johann-Albrecht Keiler
Original Assignee
Goetz Pollakowski
Keiler Johann Albrecht
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Application filed by Goetz Pollakowski, Keiler Johann Albrecht filed Critical Goetz Pollakowski
Publication of CS245741B1 publication Critical patent/CS245741B1/en

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/40Chemically transforming developed images
    • G03C5/44Bleaching; Bleach-fixing

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Detergent Compositions (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Description

-2- OÓJiaCTL· ΠΡΜΜ6Η6ΗΗΗ Η30ΰρβΤθΗΗΗ H30ópei6HMe othochtch k pacTBopy, co^epacameMy xhhoh h b qacT-hocth κ (JoTorpattumecKOMy OTóeoBaiomeMy pacTBopy, κοτορΗίί npe-ΛΟΧρΑΗΛβΤΟΗ OT ΠρθΧΑθΒρθΜβΗΗΟΜ ΗΘΠρΗΓΟΑΗΟΟΤΗ, ΠρΗΗΗΗΗβΜΟίί^ΒθτοΒΗΜ η3μθηθημ6μ η pa3JioxeHneM. Μ3θόρθτβΗΗθ laxie ynoTpeó-ΛΛβΜΟ ΛΛΗ CTaOHJIH3aiJHH paGTBOpOB, COAepxaiKHX XHHOH Η B APyTHXOÓAaCTflX ΠρΗΜβΗβΗΗΗ.-2- OÓJiaCTL · ΠΡΜΜ6Η6ΗΗΗ Η30ΰρβΤθΗΗΗ H30ópei6HMe othochtch pacTBopy to what epacameMy xhhoh ^ HB-Qact hocth κ (JoTorpattumecKOMy OTóeoBaiomeMy pacTBopy, κοτορΗίί NPE-ΛΟΧρΑΗΛβΤΟΗ OT ΠρθΧΑθΒρθΜβΗΗΟΜ ΗΘΠρΗΓΟΑΗΟΟΤΗ, ΠρΗΗΗΗΗβΜΟίί ΒθτοΒΗΜ η3μθηθημ6μ η ^ pa3JioxeHneM. Μ3θόρθτβΗΗθ Laxia ynoTpeó-ΛΛβΜΟ ΛΛΗ CTaOHJIH3aiJHH paGTBOpOB, COAepxaiKHX XHHOH Η B APyTHXOÓAaCTflX ΠρΗΜβΗβΗΗΗ.

XapaKTepHCTHKa h3B6Cthux τθχηηηοοκηχ peineHHflXapaKTepHCTHKa h3B6Cthux τθχηηηοοκηχ peineHHfl

PacTBopti, coíepxaiHHe xhhoh ynoTpeóAJWT npeHMymecTBeHHO b Ka-UeCTBe OTÓeJIHBaBUlHX paCTBOpOB B φΟΤΟΓρβφΗΗ. Μ3ΒΘ0ΤΗ0, hto co-Aepxamne xhhoh pacTBopu πρΗΜβΗΛΚτ b chjii>ho khcaoK cpe^e b Ka-qecTBe οκηοαητθλη αλλ cepeópa b $OTorpa$HnecKHx aMyjiBCHOHHbixcjiohx / US 2 259 981 /. Taxse η3βθοτηο πρΗΜβΗβΗΗβ XHHOHa b Ka-qecTBe KaiaosaTopa b nepcyAB$aTHHX OTóejiHBaioiuHX paciBopax/OD WP 141 727 /. B ocíohx c^yqaflx, npoAOAXHTeABHOCTB npaiCTH-HeCKO0 ΓΟΑΗΟΟΤΗ paCTBOpOB OrpaHHHHBaeTCH ΗΒθΤΟΒΗΜ Η3ΜβΗ6ΗΗ6ΜH pa3JI0X6HH6U XHHOHa. 3ΤΟ Η3Μ6Η6ΗΗβ HBeTa BapBHpyOT OT CaMHXΟΒθΤΛΗΧ K CaMHM T6MHH1Í ΚΟρΗΗΗθΒΗΜ OTTeHKaM. Β,ΒβΤΟΒΟΘ Η3ΜΘΗβΗΗβHactynaeT paHBine ηλη no3xe κ πρηηηηλθτ HOAonycTHMoe h npoHHoeOKpaniHBaHHe otípaóoiaeMoro Φηλβμογο MaTepnajia. Πρκ ΑβΛΒΗβΗΐιιβωpa3JI0JC6HHH CHHSaGTCH aKTHBHOCTB paCTBOpOB, TaK KaK paCTBOp Τβ-ρ«βτ cooTBeTCTBycmee κοΛΗΗβοτΒΟ XHHOHa. y,najienue npoAyKTOBpa3JI0X6HHfl H3 paCTBOpOB B ΠρΟΜΗΙΙΙΛβΗΗΗΧ yCJIOBHHX CBH3aH0 C 3aT-paiaMH. 245741 -3-PacTBopti, coíepxaiHHe xhhoh ynoTpeóAJWT npeHMymecTBeHHO b Ka-UeCTBe OTÓeJIHBaBUlHX paCTBOpOB B φΟΤΟΓρβφΗΗ. Μ3ΒΘ0ΤΗ0, hto co-Aepxamne xhhoh pacTBopu ΗΜ b> ho-------------------------------nec nec. Taxa η3βθοτηο πρΗΜβΗβΗΗβ XHHOHa b Ka-qecTBe KaiaosaTopa b nepcyAB $ aTHHX OTóejiHBaioiuHX paciBopax / OD WP 141 727 /. B ociohx c ^ yqaflx, npoAOAXHTeABHOCTB npaiCTH-HeCKO0 ΓΟΑΗΟΟΤΗ paCTBOpOB OrpaHHHHBaeTCH ΗΒθΤΟΒΗΜ Η3ΜβΗ6ΗΗ6ΜH pa3J10X6HH6U XHHOHa. 3ΤΟ Μ3Μ6Η6ΗΗβ HBeTa BapBHpyOT OT CaMHXΟΒθΤΛΗΧ K CaMHM T6MHH1I ΚΟρΗΗΗθΒΗΜ OTTeHKaM. Β, ΒβΤΟΒΟΘ Η3ΜΘΗβΗΗβHactynaeT paHBine ηλη no3xe κ πρηηηηλθτ HOAonycTHMoe h npoHHoeOKpaniHBaHHe otípaóoiaeMoro Φηλβμογο MaTepnajia. Πρκ ΑβΛΒΗβΗΐιιβωpa3JI0JC6HHH CHHSaGTCH aKTHBHOCTB paCTBOpOB, TaK KaK paCTBOp Τβ-ρ «βτ cooTBeTCTBycmee κοΛΗΗβοτΒΟ XHHOHa. y, najienue npoAyKTOBpa3JI0X6HHfl H3 paCTBOpOB B ΠρΟΜΗΙΙΙΛβΗΗΗΧ yCJIOBHHX CBH 3 α H 2 O 3aT-paiaMH. 245741 -3-

UeJIb Μ30ΰρβΤΘΗΗΑUeJIb Μ30ΰρβΤΘΗΗΑ

UeJIhB H3O0peTeHHH HBJIfleTCfl npeAOXpaHflTL ΟΤ ΠρβΧΛθΒρβΜβΗΗΟβΗΘΠρΗΓΟΛΗΟΟΤΗ, ΠρΗΊΗΗΗβΜΟβ ΡΒβΤΟΒΗΜ Η3Μ6Η6ΗΜ6Μ Μ ρβ3Λ0ΧθΗΗΘΜ,co^epxamne xmhoh pacTBopu η β qaciHOCTit <ž>OTorpa<J)HqecKHe οτΰβ-jiMBaKnnwe pacTBopu.UeJIhB H3O0peTeHHH HBJIfleTCfl npeAOXpaHflTL ΟΤ ΠρβΧΛθΒρβΜβΗΗΟβΗΘΠρΗΓΟΛΗΟΟΤΗ, ΠρΗΊΗΗΗβΜΟβ ΡΒβΤΟΒΗΜ Η3Μ6Η6ΗΜ6Μ Μ ρβ3Λ0ΧθΗΗΘΜ what ^ epxamne xmhoh pacTBopu η β qaciHOCTit <z> OTorpa <J) HqecKHe οτΰβ-jiMBaKnnwe pacTBopu.

CyiiiHOCTb M3O0peTeHna ΠρΜΗΗΗΟίί ΗΒβΤΟΒΟΓΟ H3M6H6HMH X pa3JI0XeHHfl ΗΒΛΗβΤΟΗ uyBCTBH-TfiJIBHOCTh XHHOH&amp; ΠΟ ΟΤΗΟΒβΗΜΙ) K ΟΚΗΟΛΜΤβΛΗΜ Η βΓΟ COOHHOCTbK aBTOOKKCJIHTejIBHHM npOyeCCaM. Hpx 3T0M B03HHKai)T pa3H00típa3-Hue nocjieAynmxe προ,πγκτΗ βπλοτβ λο ryuxHOBiix kmcjíot. 3emaxaH30ópeTeHHX - npenxTCTBOBaTb $opMHpoBaHHi> sthx προ^γκτοΒ pa3-λοχθηηη nocpexciBOM λοΟββλθηηη noAxoAxmero XHrxóxTopa. B co-οτΒβτοτΒΜΗ c »3θ0ρβτβΗχθΜ 3axaqa peueHa Taxuii otípasou, ητο κTaxoMy co,gepxwMy xmhoh paciBopy ^oóaBXXDT MeAHue mohu bHH3KMX KOHneHTpanMHX, a ΗΜβΗΗΟ Β ΚΟΗΗβΗΤρβίρΐΜ ΜΗΗΜΜβΛΒΗΟ Iμμολβ, npexuymecTBeHHo 4 mmojib. ΠρΜΜβΡΜ ΠΡΜΜβΗβΗΗΗ ΠρχΜβρ I: ΟτόβΛΗΒβηιιιχβ pacTBop λλη oópatíOTKH πΒβτοφοτοΓρβφχηβοκχχ Maie-pxajiOB cocTaBHeH npx c^e^yiomeM οοοτηοπιθημμ κομποηθητοβ / koh-neHTpauxH β γ/λ /: nepoKcojíMcyHb$aT khjihhCyiiiHOCTb M3O0peTeHna ΠρΜΗΗΗΟίί ΗΒβΤΟΒΟΓΟ H3M6H6HMH X pa3JI0XeHHfl ΗΒΛΗβΤΟΗ uyBCTBH-TfiJIBHOCTh XHHOH &amp; ΠΟ ΟΤΗΟΒβΗΜΙ) K ΟΚΗΟΛΜΤβΛΗΜ Η βΓΟ COOHHOCTbK aBTOOKKCJIHTejIBHHM npOyeCCaM. Hpx 3T0M B03HHKai) T pa3H00tpa3-Hue nocjieAynmxe προ, πγκτΗ βπλοτβ λο ryuxHOBiix kmcjíot. 3emaxaH30ópeTeHHX - npenxTCTBOBaTb $ opMHpoBaHHi> sthx προ ^ γκτοΒ pa3-λοχθηηη nocpexciBOM λοΟββλθηηη noAxoAxmero XHrxóxTopa. B co-οτΒβτοτΒΜΗ c »3θ0ρβτβΗχθΜ 3axaqa peueHa Taxuii otípasou, ητο κTaxoMy what, gepxwMy xmhoh paciBopy ^ oóaBXXDT MeAHue I can bHH3KMX KOHneHTpanMHX, and ΗΜβΗΗΟ Β ΚΟΗΗβΗΤρβίρΐΜ ΜΗΗΜΜβΛΒΗΟ Iμμολβ, npexuymecTBeHHo 4 mmojib. ΠρΜΜβΡΜ ΠΡΜΜβΗβΗΗΗ ΠρχΜβρ I: ΟτόβΛΗΒβηιιιχβ pacTBop λλη oópatíOTKH πΒβτοφοτοΓρβφχηβοκχχ Maia-pxajiOB cocTaBHeH npx c ^ e ^ yiomeM οοοτηοπιθημμ κομποηθητοβ / KOH neHTpauxH β γ / λ /: nepoKcojíMcyHb $ aT khjihh

όρΟΜΜΑ KHJIHHόρΟΜΜΑ KHJIHH

XMHOH μθληηΚ cyjib$aT κρκοτ.aueiax hhtphh chkk.ycxycHaH kmcjioth κοηη. / mji / 5 10 2XMHOH μθληηΚ cyjib $ aT κρκοτ.aueiax hhtphh chkk.ycxycHaH kmcjioth κοηη. / mji / 5 10 2

I 5 20I 5 20

TaKOM pacTBop yCTOBHHBUK όβ3 ΗΒβΤΟΒΟΓΟ Η3ΜβΗβΗΜΗ ΠΟ ΜβΗΒΒββMepe b xeqeHMe rpex μθοηιχθβ; ero ιχΒβτ cBexji03exeH0BaT0xejiTuA. 245741 4' ΠρΗΜθρ 2: ΟτΰβΛΗΒΗΒΙΙξΗΜ paCTBOp flJIfl OÓpaĎOTXH ΙίΒβΤΟφΟΤΟΓρΒφΜΗβΟΧΗΧ Mate-pwaJioB cocTaBJíeH c^ejiyiomitu oópaeoM / KOHuenipamífl b γ/λ /: nepoKCOíHcyjib$ai κωπ 10ΟρΟΜΗΛ KaJIHH 10ΓΜΛρΟΧΜΗΟΗ 2MejiHuK cy4b$aT χρκοτ. Iaiieiai Haipiia cmxx. 5ycKycaaa XMcaoia xohu. / ují / 15pH = 3,4 B MCxoflHOM paciBope γηλροχηηοη, πρκ πομοπιη nepoKcoAHcyab$aTaκθλμη npeBpamaeTca cpa3y b xhhoh. Taxo» pacTBop ycioawHBHfi0β3 ΙίΒβΤΟΒΟΓΟ H3M6H6HHH ΠΟ ΜθΗΒΠΙβΚ Μβρβ Β ΤβΗβΗΗβ ΤρβΧ ΜβΟΛ-ΙίβΒ; βΓθ ΙίΒβΤ CB6TJIO36JI6HOBaTOX6JITH0. B03M0XH0CTB ΙίΒβΤΟΒΟΓΟΗ3ΜβΗβΗΗΉ ΤβΧΟΓΟ pOfla paCTBOpOB Π0ΛΗ00ΤΒΒ HCXXBHaeTCfl. TaKUMoópa3OM M3óexaBT Taxxe h oxpauiHBaHHe oópaóOTaeuoro ΦηλβμογοMaTepnaaa. ΠροΛΟΛχκτβΛί,ΗΟΟτΒ excmiyaTaiiHH paciBopoB yBeaHHH-BaeTca b peay/ibTaTe HHrHOHpoBaHHH paspymeHna XHHOHa. Οληο-ΒρβΜΘΗΗΟ B03M0XH0 yUBHBUIHTL· XOHIieHTpaiíHB XHHOHa Β ΟΤΰβΛΗΒβ-βληχ pacTBopax, Tax xax ero nojiHaa axTHBHOcTb He cHHxaeTCHBCJieACTBue pa3pyuieHHH. Sto CBH3aH0 Taxxe c sxoHOMHuecxHUHnpeuMymecTBaMH. Πρκ peunpxyjifliio pacTBopoB b ycaoBHax npoMbim-Λ6ΗΗ0Γ0 ΠρΗΜβΗβΗΗΗ Β ΧΗΗΟφΜΛΒΜΧΟΠΗρΟΒβΛ BHhlX 3aB0^aX, ρβΓβΗβ-pauMH ynpomaeTCfl nocpe^ciBOM Hcnoflb30BaHHa HHmĎMpoBaHHWXpacTBopoB. lípu 3T0M οτπβΛββτ yjiajieHHe npoAyxtoB pa3JioxeHHH bΜΟΗΟΟΰΜδΗΗΗΧ XOJIOHXaX, HTO CBH3aH0 C annapaTypHHMH Η φΗΗβΗΟΟ-BHMH 3aTpaTaMH. ΚρΟΜβ TOTO, BO ΒΗΗΜβΗΗβ npHHHTH H HHTepeCHoxpaHeHMH oxpyxaBmea cpe^u, Tax xax óxaro,napfl οηηχθηηοΑ xoh-ueHTpaiíHK XHHOHa, b OTpaóOTaHHtie βολή nona^aei MeHbme ΒρβΛ-HHX BemeCTB. 245741 -5- $opMyjia M30ĎpeTeHMfl 1. PacTBop, co^epsamita xmhoh, b u&amp;cthoctm φοτοΓρβφΜΜβοκΗίί οτóejiHBawa pacxBop, oTJijmawifícfl τθμ, hto oh coíepsni bKaqeCTBe ΜΗΓΜΰΗΤΟρΒ ΜβΛΗΗβ MOHU B HM3KO0 KOHIíeHTpaiíHM. 2. PacTBop, coAepxaimia xmhoh no nyHKTy I, OTJiimaiouiHKcH τβω,MTO MeAHbie MOHbi CO^epacaTCH ΜΜΗΜΜβΛΒΗΟ B KOHIíeHTpaiíHM IiňíOJIB, npeHMymeCTBeHHO 4 ΜΜΟΛΒ. 245741 -6-TaKOM pacTBop yCTOBHHBUK όβ3 ΗΒβΤΟΒΟΓΟ Η3ΜβΗβΗΜΗ ΠΟ ΜβΗΒΒββMepe b xeqeHMe rpex μθοηιχθβ; ero ιχΒβτ cBexji03exeH0BaT0xejiTuA. 245741 4 'ΠρΗΜθρ 2: CTτΰβΛΗΒΗΒΙΙξΗΜ paCTBOp flJIfl OOpaĎOTXH ΙίΒβΤΟφΟΤΟΓρΒφΜΗβΟΧΗΧ Mate-pwaJioB cocTaBJíeH c ^ ejiyiomitu oópaeoM / KOHuenipamf b γ / λ /: neoKCHHyjib $ ai κωπ 10ΟρΟΜΗΛ KaJIHH 10ΓΜΛρΟΧΜΗΟΗ 2MejiHuK cy4b $ aT χρκοτ. Iaiieiai Haipiia cmxx. 5ycKycaaa XMcaoia xohu. / uji / 15pH = 3,4 B MCxoflHOM paciBope γηλροχηηοη, πρκ πομοπιη nepoKcoAHcyab $ aTaκθλμη npeBpamaeTca cpa3y b xhhoh. Taxo »pacTBop ycioawHBHfi0β3 ΙίΒβΤΟΒΟΓΟ H3M6H6HHH ΠΟ ΜθΗΒΠΙβΚ Μβρβ ΒβΗβΗΗβ ΤρβΧ ΜβΟΛ-ΙίβΒ; βΓθ ΙίΒβΤ CB6TJIO36JI6HOBaTOX6JITH0. B03M0XH0CTB ΙίΒβΤΟΒΟΓΟΗ3ΜβΗβΗΗΉ ΤβΧΟΓΟ pOfla paCTBOpOB Π0ΛΗ00ΤΒΒ HCXXBHaeTCfl. TaKUMoPa3OM M3óexaBT Taxxe h oxpauiHBaHHe oópaóOTaeuoro ΦηλβμογοMaTepnaaa. ΠροχκτβΛί, ΗΟΟτΒ excmiyaTaiiHH paciBopoB yBeaHHH-BaeTca b peay / ibTaTe HHrHOHpoBaHHH paspymeHn XHHOHa. 03ληο-ΒρβΜΘΗΗΟ B03M0XH0 yUBHBUIHTL · XOHIieHTpaiíHB XHHOHa Β ΛΗΒβΛΗΒβ-βληχ pacTBopax, Tax xax ero nojiHaa axTHBHOcTb He cHHxaeTCHBCJieACTBue pa3pyuieHHH. Hundred CBH3aH0 Taxxe c sxoHOMHuecxHUHnpeuMymecTBaMH. Πρκ peunpxyjifliio pacTBopoB b ycaoBHax npoMbim-Λ6ΗΗ0Γ0 ΠρΗΜβΗβΗΗΗ Β ΧΗΗΟφΜΛΒΜΧΟΠΗρΟΒβΛ BHhlX 3aB0 ^ aX, ρβΓβΗβ-pauMH ynpomaeTCfl nocpe ^ cpoBaHHWXpacTBopoB. lime 3T0M οτπβΛββτ yjiajieHHe npoAyxtoB pa3JioxeHHH bΜΟΗΟΟΰΜδΗΗΗΧ XOJIOHXaX, HTO CBH3aH0 C annapaTypHHMH Η φΗΗβΗΟΟ-BHMH 3aTpaTaMH. HTρΟΜβ TOTO, BO ΒΗΗΜβΗΗβ npHHHTH H HepepeCHoxpaHeHMH oxpyxaBmea cpe ^ u, Tax xax aroxaro, nap l χ oh oh oh e e ie ie ie ie H H H H H H eme eme eme eme eme eme eme. 245741 -5- $ opMyjia M30ĎpeTeHMfl 1. PacTBop, what ^ epsamita xmhoh, b u &amp; ctmctm φοτοΓρβφΜΜβοκΗίί οτóejiHBawa pacxBop, oTJijmawifícfl τθμ, hto oh coíepsni bKaqeCTBe ΜΗΓΜΰΗΤΟρΒ ΜβΛΗΗβ MOHU B HM3KO0 KOHIíeHTpaiíHM. 2. PacTBop, coAepxaimia xmhoh no nyHKTy I, OTJiimaiouiHKcH τβω, MTO MeAHbie MOHbi CO ^ epacaTCH ΜΜΗΜΜβΛΒΗΟB KOHIíeHTpaiiHM IiñiOJIB, npeHMymeCTBeHHO 4 ΜΜΟΛΒ. 245741 -6-

Pe3cuePe3cue

PacTBQP, coflepianmfl xhhoh, b qacTHOCTH ΦοίΌΓΡΜφΗ'^βοκΗΒ-οϊ4&amp;» jMBaciitMa pacTBÓp Μ30(5ρβτβΗΗβ othochtch κ pacTBopy, co,nepxameMy xhhoh h b nacT-hocth κ (frOTorpatítHwecKOMy OTóeoBaDmeMy paciBopy, ho He orpa-HHHHBaeTCH τολβκο pauKaMH $OTorpa$HqecKOfl χημηη. ΙίβΛίύο H30ó-ρβΤβΗΗΗ ΛΒΛΗβΤΟΗ ΠρθΛΟΧρβΗβΗΗθ ΟΟΛθρΧβΙΙΙΗΧ XHHOH paCTBOpOB OTnpexAeBpeueHHoa ηθπρηγοληοοτη, πρκΊΗΗΗβΜΟΚ ηβθτοβημ H3ideHeHn-eu h pa3JioxeHMeM. 3ajawa Κ30όρβτβΗΜΗ - npenaTCTBOBaib φορκΗ-pOBaHHB npO^yKTOB pa3JI0X6HHfl ΠΟΟρβΛΟΤΒΟΜ flOtíaBKH ΠΟΛΧΟΛΗΙΗβΓΟHHrHdHTopa. B cooTBeiCTBHH c Μ3θόρβτβΗΗβΜ, 3a^aqa perneHa τβκ,hto κ coAepxameMy xhhoh pacTBopy AOtíaBJíacT we^Htie mohu. 245741PacTBQP, coflepianmfl xhhoh b qacTHOCTH ΦοίΌΓΡΜφΗ '^ βοκΗΒ-οϊ4 &amp; »jMBaciitMa pacTBÓp Μ30 (5ρβτβΗΗβ othochtch κ pacTBopy what, nepxameMy xhhoh hb retrieves-hocth κ (frOTorpatítHwecKOMy OTóeoBaDmeMy paciBopy him He Orpa-HHHHBaeTCH τολβκο pauKaMH $ OTorpa $ HqecKOfl χημηη . ΙίβΛίύο H30ó-ρβΤβΗΗΗ ΛΒΛΗβΤΟΗ ΠρθΛΟΧρβΗβΗΗθ ΟΟΛθρΧβΙΙΙΗΧ XHHOH paCTBOpOB OTnpexAeBpeueHHoa ηθπρηγοληοοτη, πρκΊΗΗΗβΜΟΚ ηβθτοβημ H3ideHeHn-eu h pa3JioxeHMeM. 3ajawa Κ30όρβτβΗΜΗ - npenaTCTBOBaib φορκΗ-pOBaHHB NPO-yKTOB pa3JI0X6HHfl ΠΟΟρβΛΟΤΒΟΜ flOtíaBKH ΠΟΛΧΟΛΗΙΗβΓΟHHrHdHTopa. B cooTBeiCTBHH C Μ3θόρβτβΗΗβΜ, 3aR AQA perneHa τβκ, HTO κ coAepxameMy xhhoh pacTBopy iTiTiTiTiNT iT iTiTiTiNt iTiTiNt 245741

Claims (2)

7 246741 PŘEDMĚT VYNÁLEZU7 246741 OBJECT OF THE INVENTION 1. Roztok s obsahem chinonu, zejména fotografický bělici roztok, vyznačující se tím,že obsahuje jako inhibitor mědnaté ionty v nízké koncentraci.A quinone-containing solution, in particular a photographic bleach solution, characterized in that it contains copper ion ions in low concentration as an inhibitor. 2. Roztok podle bodu 1, vyznačující se tím, že mědnaté ionty jsou obsaženy v kon-centraci nejméně 1 milimol, výhodně 4 milimoly. Uznáno vynálezem na základě výsledků expertizy, provedené Úřadem pro vynálezectvía patentnictví, Berlin, LD. '92. A solution according to claim 1, wherein the copper ions are contained in a concentration of at least 1 millimole, preferably 4 millimoles. Recognized by the invention on the basis of the results of an expert review by the Patent Inventory Office, Berlin, LD. '9
CS632082A 1981-10-29 1982-08-31 Solution containing quinone namely photographic bleach liquid CS245741B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD23443281A DD222758A3 (en) 1981-10-29 1981-10-29 CHINO-CONTAINING SOLUTION, ESPECIALLY PHOTOGRAPHIC BIB

Publications (1)

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CS245741B1 true CS245741B1 (en) 1986-10-16

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BG (1) BG42973A1 (en)
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DD (1) DD222758A3 (en)
DE (1) DE3234467A1 (en)
SU (1) SU1357905A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH657710A5 (en) * 1983-07-20 1986-09-15 Ciba Geigy Ag METHOD FOR PROCESSING PHOTOGRAPHIC SILVER COLOR MATERIALS.
US5510232A (en) * 1994-12-22 1996-04-23 Eastman Kodak Company Photographic processing composition and method using cationic hydroquinone as organic catalyst for persulfate bleaching agent
US5656416A (en) * 1994-12-22 1997-08-12 Eastman Kodak Company Photographic processing composition and method using organic catalyst for peroxide bleaching agent

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE426661C (en) * 1924-12-01 1926-03-13 Emil Mayer Dr Bleacher for the photographic bromine printing process
GB1330729A (en) * 1970-06-01 1973-09-19 Ibm Method for recording in hardened gelatin
JPS5255531A (en) * 1975-10-31 1977-05-07 Fuji Photo Film Co Ltd Acceleration of silver bleaching
US4029509A (en) * 1975-11-17 1977-06-14 E. I. Du Pont De Nemours And Company Positive process using a low coating weight silver halide
US4047956A (en) * 1975-11-17 1977-09-13 E. I. Du Pont De Nemours And Company Low coating weight silver halide element and process
JPS5598750A (en) * 1979-01-23 1980-07-28 Fuji Photo Film Co Ltd Photographic bleaching composition

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BG42973A1 (en) 1988-03-15
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SU1357905A1 (en) 1987-12-07

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