CS245256B1 - Mixture for wood modification - Google Patents
Mixture for wood modification Download PDFInfo
- Publication number
- CS245256B1 CS245256B1 CS812663A CS266381A CS245256B1 CS 245256 B1 CS245256 B1 CS 245256B1 CS 812663 A CS812663 A CS 812663A CS 266381 A CS266381 A CS 266381A CS 245256 B1 CS245256 B1 CS 245256B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- wood
- mixture
- modified
- ferrocene
- phenolfurfuralformaldehyde
- Prior art date
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- 239000002023 wood Substances 0.000 title claims abstract 7
- 239000000203 mixture Substances 0.000 title claims abstract 6
- 230000004048 modification Effects 0.000 title claims abstract 4
- 238000012986 modification Methods 0.000 title claims abstract 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920005989 resin Polymers 0.000 claims abstract 4
- 239000011347 resin Substances 0.000 claims abstract 4
- SPKJCVZOZISLEI-UHFFFAOYSA-N cyclopenta-1,3-diene;1-cyclopenta-1,3-dien-1-ylethanone;iron(2+) Chemical compound [Fe+2].C=1C=C[CH-]C=1.CC(=O)C1=CC=C[CH-]1 SPKJCVZOZISLEI-UHFFFAOYSA-N 0.000 claims 2
- 230000032683 aging Effects 0.000 claims 1
- 239000010875 treated wood Substances 0.000 claims 1
- 230000006378 damage Effects 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- 235000009421 Myristica fragrans Nutrition 0.000 description 4
- 239000001115 mace Substances 0.000 description 4
- QXOQNNAWFUXKMH-UHFFFAOYSA-N 1-(Malonylamino)cyclopropanecarboxylic acid Chemical compound OC(=O)CC(=O)NC1(C(O)=O)CC1 QXOQNNAWFUXKMH-UHFFFAOYSA-N 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
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- Management, Administration, Business Operations System, And Electronic Commerce (AREA)
Abstract
Řešení se týká směsi pro získání dřevní hmoty modifikované syntetickou pryskyřicí a je určeno k využití ve dřevozpracujícím průmyslu. Cílem je vyvingut směs pro modifikaci dřevní hmoty umožňující zachování fyzikálně mechanických vlastností modifikované dřevní hmoty v průběhu dlouhodobého používání v teplotně a vlhkostně kolísajícím prostředí vlivem sníženi destrukce modifikovaného polymeru v dřevní hmotě. Směs pro modifikaci dřevní hmoty se připravuje na bázi fenolfurfuralformaldehydové pryskyřice. Novým podle řešeni je to, že se do známé směsi jako stabilizátor procesu destrukce modifikovaného polymeru přidává ferocén nebo monoacetylferooén. Přitom se výchozí ingredienty berou v tomto poměru /hmot. %/: fenolfurfuralformaldehydová pryskyřice 98,5 až 99,5 a ferocén nebo monoacetylferocén 0,5 až 1,5.The solution relates to a mixture for obtaining wood masses modified with synthetic resin and is intended for use in woodworking industry. The aim is to develop a mixture for modification wood masses allowing physical preservation mechanical properties modified wood mass during the long term use in temperature and humidity fluctuations environment due to reduced destruction modified polymer in wood. Mixture for wood material modification it is based on phenolfurfuralformaldehyde resin. The new one is that it is known blends as a stabilizer of the destruction process of the modified polymer adds ferrocene or monoacetylferooene. Doing so is the default the ingredients take this ratio / weight. % /: phenolfurfuralformaldehyde resins 98.5 to 99.5 a ferrocene or monoacetylferocene 0.5 to 1.5.
Description
-2- Η30όρβτβΗΗβ othochtch κ aepeBOodpadaTNBaiomefi npoMum-JteHHOCTH, B HHCTHOCTH K MOJ[H$HKaHHH ΛρθΒβΟΗΗΗ. H3BeCTeH COCTaB JUIH MOflH$HKaXXEH ΛρβΒβΟΗΗΗ, BKJnonaK)-mnít nojiEKOHBeHcaííHOHHyro cMOJiy [i].-2- Η30όρβτβΗΗβ othochtch κ aepeBOodpadaTNBaiomefi npoMum-JteHHOCTH, B HHCTHOCTH K MOJ [H $ HKaHHH ΛρθΒβΟΗΗΗ. H3BeCTeH COCTaB JUIH MOflH $ HKaXXEH ΛρβΒβΟΗΗΗ, BKJnonaK) -continued.
Handojiee 0ΛΗ3ΚΒΜ k npejyioKeHHOMjr ηβληθτοη cocTaB juhMOjmÍHKamm ^peBecHHH, coBepaaiflHH φβΗΟΗφγρφγροΗφορΜευϋΛθ-rnnHjno CMOJiy [2],Handojiee 0ΛΗ3ΚΒΜ k npejyioKeHHOMjr ηβληθτοη cocTaB juhMOjmHHammam ^ peBecHHH, coBepaaiflHH φβΗΟΗφγρφγροΗφορΜευϋΛθ-rnnHjno CMOJiy [2],
HeflOCTaTKOM Ε3ΒβΟΤΗΗΧ COCTaBOB HBJIHeTCH ÓHCTpoe CTa-perae MO®i$EmHpoBaHfíoiÍ λρθβθοηηη, ycKopnenoe βο3λθηοτβη-eM M3MefíeHHfi TeMnepaTypu e βλβχηοοτη cpejiu. líejit Η3θόρβτβΗΗΗ - savemieHEe cTapeHHfl MonH$imnpo-BaHHOfi ΛρβΒβΟΗΗΗ. 3TO SOCTHraeTCH ΤβΜ, HTO COCTaB .HOnOJIHETeJIBHO COflep-ket áepponeH eeh MOHoaueTHjiiheppoiíeH npa cjienyromeM cootho-mefíHH κομποηθητοβ, Macc.%: $eHOJi^yp$ypoji$op^ajii>BerHjiHaH cwojia 98,5-99,5φβρρουεΗ mm MOHoaueTaraJeppoqeH 0,5-1,5.ΦβρροπβΗ mm MOHoaaeTiM$eppoiieH npejicTaBJíínoT co doň noponiKoodpasHHe co6RHH6HHH, pacTBopHMHe b opraHB^jecKEXpacTBopHTejiHx. CocTaB γοτοβητ cjiejiyBmHM otípaeoM. ΠρΗΜθρ I. B $eHO^^yp$ypojr$opzajEbflerEflHyK) cwojiy /99,5 Macc.%/,pacTBopeHHyK) b aueTOHe /20% ot waccn cmojih/, bbojiht KaTa- 245256 -3-HeflOCTaTKOM Ε3ΒβΟΤΗΗΧ COCTaBOB HBJIHeTCH HHCTpoe CTa-perae MO®i $ EmHpoBaHfiOi λρθβθοηηη, ycKopnenoe βο3λθηοτβη-eM M3MefiHHfi TeMnepaTypu e βλβχηοοτη cpejiu. ej3θόρβτβΗΗΗ - savemieHEe cTapeHHfl HρβΒβΟΗΗΗ. 3TO SOCTHraeTCH fβΜ, HTO COCTaB .HOnOJIHETeJIBHO COflep-ket áepponeH eeh MOHoaueTHjiiheppoiíeH npa cjienyromeM cootho-mefíHH κομποηθητοβ, Macc.%: $ EHOJi ^ yp $ ypoji $ op ^ ajii> -1,5.ΦβρροπβΗ mm MOHoaaeTiM $ eppoItToToToToToTo DoNoponiKoodpasHHe co6RHH6HHH, pacTBopHMHe b opraHB ^ jecKEXpacTBopHTejiHx. CocTaB γοτοβητ cjiejiyBmHM otípaeoM. ΠρΗΜθρ I. B $ eHO ^^ yp $ ypojr $ opzajEbflerEflHyK) cwojiy / 99,5 Macc.% /, PacTBopeHHyK) b aueTOHe / 20% ot waccn cmojih /, bbojiht KaTa- 245256 -3-
Jffl3aT0p-óeH30JICy£h(^KECJI0Ty B ΚΟΛΕΗβΟΤΒβ 0,8# OT MaCCHcmojiu. KaTajm3aTop npesBapuTejiLHO pacTBopmoT b HeóojiBinoMKOJDinecTBe aueTOHa. IIojiyHeHHHfi pacTBop TmaTejiiHo nepeMe-mHBaroT, 3aTew npa KOMHaTHoS TewnepaType npa nepeMenniBa-HHH ΒΒΟΛΗΤ 0,5 MaCC.# φθρρΟΙΙθΗβ. ΠρΒΜβρ 2. OTJnraaeTCH οτ npnMepa I τθμ, ητο ncxonmie HHrpefln-θητη ÓepyT β cjtejyiomeM cooTHonieuHB, Mace.#: $eHOJi$yp$ypoji$op4ajiBsenWHaH cwojia 99,0 φβρροηβΗ 1,00. ΠρΒΜβρ 3. OTJiEraaeTCH οτ npnMepa 2 τθμ, ητο βμθοτο $eppoueHaHcnoJiB3ywT MOHoapeTiui^eppoiíeH β CJieAyioqeM οοοτηοεθηβη,Mace.#: $eHOJi$yp$ypoji^pj!ajiijíernnHan cwiojia 99,0 MOHoaiieTEJi$epponeH 1,00. ΠρκΜβρ 4.Jffl3aT0p-óeH30JICy £ h (B ^ KECJI0Ty ΚΟΛΕΗβΟΤΒβ 0.8 # OT MaCCHcmojiu. KaTajm3aTop npesBapuTejiLHO pacTBopmoT b HeóojiBinoMKOJDinecTBe aueTOHa. IIojiyHeHHHfi pacTBop TmaTejiiHo NEP-mHBaroT, 3aTew NPA KOMHaTHoS TewnepaType nepeMenniBa NPA-HHH ΒΒΟΛΗΤ 0.5 MACC. # ΦθρρΟΙΙθΗβ. ΠρΒΜβρ 2 . OTJnraaeTCH οτ npnMepa I τθμ, ητο ncxonmie HHrpefln β-θητη ÓepyT cjtejyiomeM cooTHonieuHB Mace. #: eHOJi $ $ $ yp ypoji $ op4ajiBsenWHaH cwojia 99.0 φβρροηβΗ 1.00. ΠρΒΜβρ third OTJiEraaeTCH οτ npnMepa τθμ 2, $ ητο βμθοτο eppoueHaHcnoJiB3ywT MOHoapeTiui ^ eppoiíeH β CJieAyioqeM οοοτηοεθηβη, Mace. #: $ eHOJi $ yp $ ypoji ^ pj!
HcxoflHue EHrpefluenTH ÓepyT b cjiejiyromeM cooTHomeHO,HcxoflHue EHrpefluenTH ÓepyT b cjiejiyromeM cooTHomeHO
Mace.#: $efíoji^yp$ypoji$op.,aji£jierimHaa CMOJiaφβρροπ,βΗ 98,5 1,5. B Taójume npencTaBJíeHU pe3yjitTaTU ncnuTaKnn .upeBecn·HH, MOflH^mmpOBaHHOfi Πρβί,ΛΟΚβΗΗΗΜ COCTaBOM.Mace. #: $ Efioji ^ yp $ ypoji $ op., Aji £ jierimHaa CMOJiaφβρροπ, βΗ 98,5 1,5. B T A T A T E R T E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R E R C H E R C H E R COCTaBOM.
MccjrenoBaHiie npopecca CTapema npoBojpuiocB no Μβτο-ΛΗΚβ ycKopenHoro cTapeHEH. Uekji cTapemra: βημηηηββηηθ mo-An$miHpoBaHHoa jipeBecHHu b TeneHne 3 cyTOK β βολθ npnI8-23°C; BHcyraHBaHHe npn I05°C - 8 ή; Bunepsuca npnI5-23°C - 16 h.MccjrenoBaHiie npopecca CTapema npoBojpuiocB no Μβτο-ΛΗΚβ ycKopenHoro cTapeHEH. Uekji cTapemra: mi mi β mi mi mi mi mi mi mi mi mi mi mi mi mi mi mi mi mi mi T T T T T T T T -23 -23 -23 -23 BHcyraHBaHHe npn I05 ° C - 8; Bunepsuca npnI5-23 ° C - 16 h.
KaK BH£HO H3 TaÓJTEHU, COCTaB UJIH ΜΟΛΗφΗΚΘΙίΗΗ ΛρβΒβ-chhu π03Β0ΛΗβτ 3awe,iyniTi> CTapeHiie λρθβθοηηη, oóecneuHBa-βτ coxpaHeHHe bucokoě npo^mocTU. 245256 -4-KaK BH HO HO H3 TaÓJTEHU, COCTaB UJIH ΗΚΘΙφΗΚΘΙίΗΗ ΛρβΒβ-chhu π03Β0ΛΗβτ 3awe, iyniTi> CTapeHiie λρθβθοηηη, oóecneuHBa-βτ coxpaHeHHe bucokoe npo ^ mocTU. 245256 -4-
TaójnmaTaójnma
HsMeHeHiae npe^ejia iipohhocth npn ckstiih bhojibbojiokoh H noTepa Niaccu ΛρεΒβοΗΗΟϋ b npopecce cTapema ‘ OÓLeKT JéJí' ECCJieflOBaHHfl ripeaea npouHocTE πρκ οε&τκη bbojibBO.TOKOH, kTc/cM^ Uhkjih cTapeHEH 3 : 6 : 9 : 12 : 19 I : 2 3 : 4 : 5 : 6 : 7 I. HaTypajitnas ΛρβΒβ-CKiia* 980 942 932 925 889 2. ínsBecHHa.Mojni^Emi-DonaKHan (peHOJwyp-?y no jrcpopr.aji£Ae rm-Η0Γ1 Cí/.OJiOĚ 1440 1321 1298 1272 1193 3.£pc-E5ci:na, vojinínmn-posanHaa $eHOJ»ryp-ciy pojiíJo p.iajiijie γελ-HOU CMOJIOii c í%<peppopeHa 1441 1349 1333 1309 1302 4. UpeBecHHa.woflKŽEUH-poBaHHafl φβΐίΟΛφγρσγ-ροχφο majiBge γκβηοηcizojiok c 1% MOHoaue-TiDipeppoixeHa "l366 1350 1328 1309 1303S Β e Β Β ^ ej i Β Β Β Β Β Β Β Β Β no no no no no no no no no no no no no no no no no 4: 5: 6: 7 I. HaTypajitnas ΛρβΒβ-CKiia * 980 942 932 925 889 2nd ecsBecHHa.Mojni ^ Emi-DonaKHan (peHOJwyp-? Y no jrcpopr.aji £ Ae rm-Η0Γ1 Ci / .OJiOE 1440 1321 1298 1272 1193 3.--5 ci,,, na 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 1441 1349 1333 1309 1302 4. UpeBecHHa.woflKŽEUH-poBaHHafl φβΐίΟΛφγρσγ-ροχφο majiBge 1% MOHoaue-TiDipeppoixeHa "366 1350 1328 1309 1303
IIpoflOJEteiíiie TaÓJUHH ‘Ίη • Ποτερπ KaccH, % miKjni CTapeHEH * 24 : 3 : 6 : 9 : 12 : 19 : 24 I : 8 : 9 : 10 : II : 12 : 13 : 14 I 837 0,00 1,12 2,00 2,18 3,96 4,00 2 1074 8,11 8,68 - 8,78 9,50 13,18 3 1300 9,32 9,63 9,70 9,88 - 9,85 4 1236 9,59 10,07 10,13 10,40 10,13 10,62 245256 -5- ΦΟΪΜΑ Η30ΕΡΕΤΕΗΗΗIIpoflOJEteiíiie TaÓJUHH '•η • Ποτερπ KaccH,% miKjni CTapeHEH * 24: 3: 6: 9: 12: 19: 24 I: 8: 9: 10: II: 12: 13: 14 I 837 0.00 1.12 2, 00 2,18 3,96 4,00 2 1074 8,11 8,68 - 8,78 9,50 13,18 3 1300 9,32 9,63 9,70 9,88 - 9,85 4 1236 9, 59 10.07 10.13 10.40 10.13 10.62 245256 -5- ΦΟΪΜΑ Η30ΕΡΕΤΕΗΗΗ
Coctsb λζιη Mojpa$HKaií0H λρθβθοζηη, coflepsamirii čpeHOJi-$yp$ypoji$opviajii.1nerHaHyio cMÓJiy, oTjiHHaBmocflΤβΜ, HTO, C peJILIO 3ΗΜ6ΛΛ6ΗΕΗ CTapeHHH MOflH$HIXHpOBaHHOĚΛρβΒβΟΖΗΗ, OH ΒΟΠΟΛΗΗΤβΛΒΗΟ CO^epfflJT φβρρΟΙΙβΗ ΖΛΗ MOHO-θρβΤΗΛφβρροΐίβΗ npz cjieflyromeM coothoeshhh κομποηθητοβ,Mace. %·. 0eHOJt$yp$ypoji$op4ajiE,fl;e γκλημ CMOJia 98,5-99,5 φβρροπβΗ hjxh MOHoaneTO$eppoueH 0,5- 1,5. 245256 -6- AHHOTAUMíi Η300ρθΤβΗΜΘ OTHOCHTCH K COCTSBaM flJM ΠΟΛγπβΗΗΗ Λρβ-ΒβΟΗΗΗ, ΜΟβΗφΗφίρΟΒΑΗΗΟβ ΟΜΗΤΘΤΗΧΙΘΟΚΟβΟΜΟΛΟΑ, Η Πρβ£Η£13-HaueHO ftJifl ncnojib3OBaHHH β AepeBooópatiaTHBanoieft προΜΜπ-JieHHOCTH. Iíejibra Μ3θδρβτβΗΜΗ ηβτιηθτοη pa3padoTxa cocTasa ,π,ππΗρθΒβΟΗΗΗ, Π03ΒΟΛΗΚ)ΠξθΓΟ COXpaHHTb $H3HK0- ΜβΧΘΗΗΗβΟΚΗβ CBOÍiCTBa MOflH$HIJHpOBaHHOfl ApeBeCHHH B npo-qecce fljiWTeJibHott SKCiuiyaTaijHH ee npw HajiHWMH TeMnepaTyp-HO-BJíaXHOCTHOrO ΚΟΛβόβΗΗΚ CpeflM 3a CTOT ΟΗΗΜΘΗΗΗ flBCTpyK-uhh MOflH$HqHpyioinero nojiHMepa b flpeBecHHe.Coctsb λζιη Mojpa $ HKaií0H λρθβθοζηη, yp coflepsamirii čpeHOJi- $ $ $ ypoji opviajii.1nerHaHyio cMÓJiy, oTjiHHaBmocflΤβΜ, HTO, C peJILIO 3ΗΜ6ΛΛ6ΗΕΗ CTapeHHH MOflH $ HIXHpOBaHHOĚΛρβΒβΟΖΗΗ OH ΒΟΠΟΛΗΗΤβΛΒΗΟ CO ^ epfflJT φβρρΟΙΙβΗ ΖΛΗ may θρβΤΗΛφβρροΐίβΗ NPZ-cjieflyromeM coothoeshhh κομποηθητοβ Mace. % ·. 0eHOJt $ yp $ ypoji $ op4ajiE, fl; e γκλημ CMOJia 98,5-99,5 φβρροπβΗ hjxh MOHoaneTO $ eppoueH 0,5- 1,5. 245256 -6- AHHOTAUMíi TH300ρθΤβΗΜΘ OTHOCHTCH TO COCTSBaM flJM ΟΛ β β Λ β 13 13 13 13 £ 13-HaueHO ftJifl ncnojib3OBaHHH β AepeBooópatiaTHBanoieft προΜΜπ-JieHHOCTH. Iíejibra Μ3θδρβτβΗΜΗ ηβτιηθτοη pa3padoTxa cocTasa, π, ππΗρθΒβΟΗΗΗ, Π03ΒΟΛΗΚ) ΠξθΓΟ COXpaHHTb $ H3HK0- ΜβΧΘΗΗΗβΟΚΗβ CBOÍiCTBa MOflH $ HIJHpOBaHHOfl ApeBeCHHH B-NPO qecce fljiWTeJibHott SKCiuiyaTaijHH ee NPW HajiHWMH TeMnepaTyp-HO-BJíaXHOCTHOrO ΚΟΛβόβΗΗΚ CpeflM 3a CTOT ΟΗΗΜΘΗΗΗ flBCTpyK-uhh MOflH $ HqHpyioinero nojiHMepa b flpeBecHHe.
CocTae rmi ΜΟΑκφκκΒμκιι flpeBecHHU npnroTaBjinBaeTCfl Haochob6 $eHOJi$yp$ypoJi$opMajibfterii£HOtt cmojih. Ηοβη3ηβ saflBjíneMoro cocTaBa eaioiiOHaeTCH b tom, hto bH3BecTHHft cocTaB β κβηθοτβθ CTaÍHJiHeaTopa npoqecca flect-ργκφΐΗ MOflH$HHHpyiomero nojiHMepa ββοαητ φβρροηβΗ hjih mo-HoaqeTH4$eppoqeH. lípu θτομ ηοχοληηθ ΗΗΓρββΗβΗΤΗ ÓepyT bcjieAyioqeM οοοτηοπθηηη (Macc.%): φβΗΟΛφτρφ^ροΑφορΜβΛΒΛβΓΗΑΗβΗ CMOJia 98,5-99,5φβρρομβΗ hjih MOHoaqeTHJi$eppoueH 0,5-1,5. 245256CocTae rmi peΑκφκκΒμκιι flpeBecHHU npnroTaBjinBaeTCfl Haochob4 $ eHOJi $ yp $ ypoJi $ opMajibfterii £ HOtt cmojih. Oroοβη3ηβ saflBoMo cocTaBa eaioiiOHaeTCH b tom, hto bH3BecTHHft cocTaB β κβηθοτβθ CTaÍHJiHeaTopa npoqecca flect-ργκφΐΗ MOflH $ HHHpyiomero nojiHMepa ββοαητ φβρροηβΗ hjih mo-HoaqeTH4 $ eppoqeH. lime tree c β β β β β β β y T c c c c c c OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ OJ -1 -1 245256
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS812663A CS245256B1 (en) | 1981-04-07 | 1981-04-07 | Mixture for wood modification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS812663A CS245256B1 (en) | 1981-04-07 | 1981-04-07 | Mixture for wood modification |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS266381A1 CS266381A1 (en) | 1985-12-16 |
| CS245256B1 true CS245256B1 (en) | 1986-09-18 |
Family
ID=5364391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS812663A CS245256B1 (en) | 1981-04-07 | 1981-04-07 | Mixture for wood modification |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS245256B1 (en) |
-
1981
- 1981-04-07 CS CS812663A patent/CS245256B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS266381A1 (en) | 1985-12-16 |
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