CS237444B1 - Method of esther preparation - Google Patents
Method of esther preparation Download PDFInfo
- Publication number
- CS237444B1 CS237444B1 CS816343A CS634381A CS237444B1 CS 237444 B1 CS237444 B1 CS 237444B1 CS 816343 A CS816343 A CS 816343A CS 634381 A CS634381 A CS 634381A CS 237444 B1 CS237444 B1 CS 237444B1
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- CS
- Czechoslovakia
- Prior art keywords
- pressure
- kpa
- atmospheric
- residual pressure
- acid
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract 3
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 239000003377 acid catalyst Substances 0.000 claims abstract 4
- 239000002253 acid Substances 0.000 claims abstract 3
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 3
- 150000002148 esters Chemical class 0.000 claims abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000001298 alcohols Chemical class 0.000 claims abstract 2
- 150000008064 anhydrides Chemical class 0.000 claims abstract 2
- 230000003993 interaction Effects 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims abstract 2
- 238000000926 separation method Methods 0.000 claims abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000012467 final product Substances 0.000 claims 1
- 230000032050 esterification Effects 0.000 abstract 2
- 238000005886 esterification reaction Methods 0.000 abstract 2
- -1 aromatic dicarboxylic acids Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 101150115538 nero gene Proteins 0.000 description 4
- 239000002699 waste material Substances 0.000 description 2
- 101100366940 Mus musculus Stom gene Proteins 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- HCZHHEIFKROPDY-UHFFFAOYSA-N kynurenic acid Chemical compound C1=CC=C2NC(C(=O)O)=CC(=O)C2=C1 HCZHHEIFKROPDY-UHFFFAOYSA-N 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Unknown Constitution (AREA)
Abstract
Způsob přípravy esterů esterifikací alifatické nebo aromatické dikarboxylové kyseliny nebo jejího anhydridu s počtem uhlíkových atomů 6 až ,8 alifatickým C^ až C,2 -alkoholem s přímým nebo rozvětveným řetězcem nebo směsí uvedených alkoholů s přídavkem kyselého katalyzátoru při 90 až 180 °C a tlaku od atmosférického do zbytkového tlaku 2,666 kPa a odděleňím konečného produktu, při němž se esterifikace provádí nejprve vzájemným působením odpovídající kyseliny a alkoholu při 90 až ,40 °C a při tlaku od atmosférického do zbytkového tlaku 13,332 kPa během 0,1 až 0,2 h, potom se k získané reakční hmotě přidává kyselý katalyzátor a proces se provádí při ,00 až 180 °C a tlaku od . atmosférického do zbytkového tlaku 2,666 kPa. Uvedené estery jsou použitelné hlavně jako změkčovadla pro různé polymery.Process for preparing esters by esterification aliphatic or aromatic dicarboxylic acids acid or anhydride thereof with a number of carbon atoms of 6 to 8 aliphatic C 1-4 straight-chain or branched C12 -alcohol chain or mixture of said alcohols with addition of acid catalyst at 90 ° C up to 180 ° C and pressure from atmospheric to a residual pressure of 2,666 kPa and separation the final esterification product performed first by interaction the corresponding acid and alcohol at 90 to 40 ° C and at atmospheric pressure to a residual pressure of 13,332 kPa during 0.1 to 0.2 h, then to the obtained reaction adds an acid catalyst and process is carried out at 00 to 180 ° C and pressure from. atmospheric to residual pressure 2,666 kPa. These esters are mainly useful as plasticizers for various polymers.
Description
1 H30ÓpeTeHHe othochtch k opraHHHecKOMy CHHTe3y, bHacTHocTH, κ cnocoóy nojiyneHHH cjiojkhhx θφκροΒ θτθρπφΗ-KaniieS ajiH$aTínecKiíx km apoMaTHnecKHx oKapÓOHOBHxKHCJIOT HJIH HX aHTBflpiWOB aJIH$aTHHeCKHMH CnapTaMH HOp-MajILHOrO H H30CTp06HHH HJIH ΟΜΘΟΒ» yKa3áHHHX GHHpTOB BnpHcyTCTBHH khcjioio KaTanH3aTopa 3TepH$HKan;HH. nojiynae-MH6 npOAyKTU HaXOAHT ΠρΗΜβΗΘΗΗΘ B OĎHÓBHOM B ΚΗΗβΟΤΒΘΙΗΗΟΤΗφΗΚΒΤΟρΟΒ pa3JIHHHHX ΠΟΗΗΜβρΟΒ. Κ3ΒθοτβΗ cnocoó noJiyneHHH cjiojkhhx θφπροΒ nyTeMB3aHMC®6HCTBHH KHCJIOTH CO ΟΠΗρΤΟΜ B npHCyTCTBHH THKHXKaTajiH3aTopoB, ksk cepHaa KHCJioTa, óeH3OJicyjn>&OKHCJiOTa,napaTojiyojicyjih$OKHcj[OTa, . πρκ 80-I80°C, oÓhhho I25-I50°C(I).1 H30ÓpeTeHHe othochtch to opraHHHecKOMy CHHTe3y, bHacTHocTH, κ cnocoóy nojiyneHHH cjiojkhhx θφκροΒ θτθρπφΗ-KaniieS ajiH $ aTínecKiíx km apoMaTHnecKHx oKapÓOHOBHxKHCJIOT HJIH HX aHTBflpiWOB aJIH $ aTHHeCKHMH CnapTaMH Hop-H MajILHOrO H30CTp06HHH HJIH ΟΜΘΟΒ »yKa3áHHHX GHHpTOB BnpHcyTCTBHH khcjioio KaTanH3aTopa 3TepH $ HKan; HH. nojiynae-MH6 npOAyKTU HaXOAHT ΠΗΜΗΜ OΗΘΗΗΘ O OĎΚΗΗĎĎĎĎĎĎĎ B B B B B B B B B B333333333333333333333333333333. Κ3ΒθοτβΗ cnocoó noJiyneHHH cjiojkhhx θφπροΒ nyTeMB3aHMC®6HCTBHH KHCJIOTH CO ΟΠΗρΤΟΜ B npHCyTCTBHH THKHXKaTajiH3aTopoB, ksk cepHaa KHCJioTa, óeH3OJicyjn> πρκ 80-80 ° C, α 25 -50 ° C (I).
Oahhko KHCjme κητ&ηη3ητορη cnocoÓCTByBT Aeriwpa-TaiíHH CHHpTOB C OÓpa3OBaHH6M HpOCTHX 3$HpOB Z ΗΘΠρθ-ΛΘΟΗΗΧ ΟΟθΑΗΗβΗΗϋ, KOTOpUe 3aTeM KOímeHCHpyiOTCa Hokhcjihbtch , oÓpa3ya OKpameHHue πρΗΜβοκ. 9το πρηβολητ kyxyíjueHHio npeTa nejieBoro nponyKTa h yMeiiLincHHio Buxojxano cnnpTy. íbia npeaoTBpameHHH okecjiohhh 0Ópa3yKMíHxcHb nponecce θτβρΗφΗΚΒίίΗΗ npHMecež npejyiaraaíT í,oóaBJiHTBb peaKiíHOHHyio cmgcb pa3JnwHHe noÓaBKH, HanpHMep πκρο-φορΗΗΗ BHCMyT, COJIH ΜθΑΗ, 3Kejie3a, OJIOBa, XpOMa. OSHaKOπρΗΜθΗθΗΗθ AoóaBOK ynopoaaeT h ycjiosHHeT nponecc. 237444 -2-Oahhko KHCjme κητ & ηη3ητορη cnocoÓCTByBT Aeriwpa-TaiíHH CHHpTOB C OÓpa3OBaHH6M HpOCTHX 3 $ HpOB Z ΗΘΠρθ-ΛΘΟΗΗΧ ΗΗθΑΗΗβΗΗϋ, KOTOpUe 3aTeM KOemeHCHpyiOTCa Hokhcjihbtch, oÓpa3ya OKpameHHue πρΗΜβοκ. 9το πρηβολητ kyxyíjueHHio npeTa nejieBoro nponyKTa h yMeiiLincHHio Buxojxano cnnpTy. Ibia npeaoTBpameHHH okecjiohhh 0Ópa3yKMíHxcHb nponecce θτβρΗφΗΚΒίίΗΗ npHMecež npejyiaraaíT s, oóaBJiHTBb peaKiíHOHHyio cmgcb pa3JnwHHe noÓaBKH, HanpHMep πκρο-φορΗΗΗ BHCMyT, COJIH ΜθΑΗ, 3Kejie3a, OJIOBa, XpOMa. OSHaKOπρΗΜθΗθΗΗθ AoóaBOK ynopoaaeT h ycjiosHHeT nponecc. 237444 -2-
Haadojiee ójih3kkm no TexiunecKOž cyinHOCTH n aoctb-raeMOMy pe3yjiBTaTy κ npeppiaraeMOMy ηβληθτοη cnocoónojiyneHHH cjioxhhx 9φηροΒ, Hanpnwiep AH(2-9TmireKC]aji)$Ta-jiaTa, 3aKJnonaKníOCfl bo B3anwi,eiíCTBo $Tajiesoro βηγεα-PW c 2-3THJireKcaHOJiOM b npncyTCTBo kucjiopo KaTajinsa-Topa nyTeM nx BBOňa b nepBUH annapaT KacKa#a poaKTopoBujih b nepBya ceKmno ceKpHOHHpoBaHHoro peaKTopa, rflenojmepMBaiOT 90-18Q°C n AaazieHHe ot aTMoeýepHoro roοοτβτοηηογο 2,666 κπα. HojiyneHHufi cupep c 3ap,aHHHMkhcjiothhm nncjioM HenpepuBHo otboaht ks nocjieAHero an-napaTa Kacnajia hjik ποοχθαηθη οθκρηκ οθκιιηοηηροβηηηογοpeaKTopa. IIojiyneiiHaiá 3$np-cnpen noABepraioT HeSTpajinsa-Bjzlk, nocjie nero προβοαητ OTPOHKy h3Óhtohhopo cnzpra κnojiyneHHHfi npojiyKT oópaóaTHBaioT copóeHTOM. IIojiynaioT9$np c bhxoaom 94,6 Bec.$ (no cnnpTy) κ hbctom nomiaTííHO-KOÓajiLTOBoií nncajie 200 eju Xa3ena (2).Haadojiee ójih3kkm no TexiunecKOž cyinHOCTH n-aoctb raeMOMy pe3yjiBTaTy κ npeppiaraeMOMy ηβληθτοη cnocoónojiyneHHH cjioxhhx 9φηροΒ, Hanpnwiep (AH 2-9TmireKC] aji) $ Ta-Fusing, 3aKJnonaKníOCfl bo B3anwi, eiíCTBo $ Tajiesoro βηγεα PW-c 2-3THJireKcaHOJiOM b npncyTCTBo kucjiopo KaTajinsa- Topa nyTeM nx BBOňa b nepBUH annapaT KacKa # a poaKTopoBujih b nepBya ceKmno ceKpHOHHpoBaHHoro peaKTopa, rflenojmepMBaiOT 90-18Q ° C AaazieHHe ot aTMoeýepHoro roοοτβτοηηογο 2,666 κπα. HojiyneHHufi cupep c 3ap, aHHHMkhcjiothhm nncjioM henpepuBHo otboaht ks nocjieAHero an-napaTa Kacnajia hjik ποοχθαηθη οθκρηκ οθκιιηοηηροβηηηογοpeaKTopa. IIojiyneiiHaiá 3 $ np-cnpen noABepraioT HeSTpajinsa-Bjzlk, nocjie nero προβοαητ OTPOHKy h3Óhtohhopo cnzpra κnojiyneHHHfi npojiyKT oópaóaTHBaioT copóeHTOM. IIojiynaioT9 $ np c bhxoaom 94,6 Bec. $ (No cnnpTy) κ hbctom nomiaTííHO-KOÓajiLTOBoií nncajie 200 eju Xa3ena (2).
He^ocTaTKOM η3βθοτηογο cnocoóa ηβ&ηθτοη to, ήτο bnponecce 9Tepn$KKaiw oópa3yK)TCfí OKpaineHHue πρκΜθοκ,KOTopne ne y^aziaiOTCH πρκ oópaóOTKe 3$Kpa-cnppa copÓeH-thmh. IIoxyneHHHE nponyKT κμθθτ HeyAOBJíeTBopHTejiBHHSΐίΒθτ, hto 3ηηηητθ;ιβηο orpaHHHHBaeT oÓJiacTB ero npKMeHe-ηβη. Πρκ 9tom nacTL cnnpTa, sarpyscaeMoro Ha 9Tepaí)KKa-HHK), AerimpaTHpyeTCH c 0Ópa30BaHHeM Henpe£ejiBHHX coepfí-ΗβΗΗΗ n npocTHx θφκροΒ. 3το πρΗΒΟΑΗτ κ norepaM cnnpTaΚ, ΟΟΟΤΒΘΤΟΤΒΘΗΗΟ, ΟΗΗΚΘΗΚΚ) ΒΗΧΟ,Ε,Η ΓξθΛΘΒΟΓΟ npOflyKTa ΠΟcnnpTy.He ^ ocTaTKOM η3βθοτηογο cnocoóa ηβ & ηθτοη to, bnponecce 9Tepn $ KKaiw oópa3yK) TCfí OKpaineHHue πρκΜθοκ, KOTopne ne y ^ aziaiOTCH πρκ oópaóOTKe 3 $ Kpa-cnppa copÓeH-thmh. IIoxyneHHHE nponyKT κμθθτ HeyAOBJiTBopHTejiBHHSΐίΒθτ, hto 3ηηηητθ; ιβηο orpaHHHHBaeT oÓJiacTB ero npKMeHe-ηβη. Πρκ 9tom nacTL cnnpTa, sarpyscaeMoro Ha 9Tepaí) KKa-HHK), AerimpaTHpyeTCH c 0Ópa30BaHHeM Henpe £ ejiBHHX coepfi-ΗβΗΗΗ n npocTHx θφκροΒ. 3το πρΗΒΟΑΗτ κ norepaM cnnpTaΚ, ΟΟΟΤΒΘΤΟΤΒΘΗΗΟ, ΟΗΗΚΘΗΚΚ, Ε, Η ΓξθΛΘΒΟΓΟ npOflyKTa ΠΟcnnpTy.
UejiL Η3θόρβτθΗΗΉ - noBHnieHHe KanecTBa pejieBoronpopyKTa. ÍIocTaBjíeHHan pejiB αοοτκγηθτοη τβΜ, ητο corjiacnocnocoóy nojiyneHKH cjiojkhhx θφκροΒ, 3aKJnonaiomeMycH boB3anM0p,eficTB2H ajiJ0$aTHnecKOH kjih apoMaTKnecKOH AHKapóo-HOBOÍí KHCJIOTH HJIK θβ aHPHApKUa C HKCJIOM yrjiepoAHHXaTOMOB 6-18 c aji0$aTjaHecK0M οπκρτοΜ HopMaiiBHoro mnaHsocTpoeHHfl c khcjiom ypjiepoAHax aTOMOB 4-12, min cmocbkjyica3aHHHx οππρτοΒ b npjaoyTCTBHH κηολογο KaTajnasaTopa 237444 ' “3" πρϋ 90-I80°C h AaBHeHHH ot aTMOc$epHoro ao οοτβτοηηογο2,666 Kiia c nocjieAyioiWi BUAejieHHeM neneBoro npoAyK-Ta, STepajiiiKamno προΒΟΑΗΤ nepBOHanajiLHO nyTeM B3anMO-AeĚCTBHH cooTBeTCTByromiix khcjioth h cnnpTa npH 90-I40°Ch AaBjíeHHH ot aTMOG0epHoro ao ocTaTOHHoro 100 mm ρτ.οτ.b τβπβΗΗβ 0,1-2,0 η, nocjie nero κ nojiygeHHoS peaiojHOH-Hoft Macce AoóaBAHKzr kucahíí KaTann3aTop z nponecc npoBO-AHT npn I00-I80°0 h AaBAeHjau ot aTMoccpepHoro ao ocTa-ΤΟΉΗΟΓΟ 2,666 Kila. 3ΤΟ Π03Β0ΑΗβΤ ΠΟΒΗΟΗΤΒ ΒΗΧΟΑ Η ΚΒΗθΟΤΒΟ ΠβΑθΒΟΓΟnpOAyKTa. ΠρΗ προΒβΑβΗΗΗ nponecca 3TepB$HKannH nonpejyiaraeMOMy cnocody cnnpTH b μθηβπιθκ CTeneHH noABep-raDT AerMApaTano, n b 1,5-3,5 paea coKpamaeTca kojih-necTBO otípasylOAHXCfl npmaeceft. Πρκ ηοπολς>3οββηζε ηε3κο-ΚΗΠΗπμιχ οπκρτοΒ c hhcaom yrjiepoAHHx ητομοβ 4-8 HarpeBH BHAepKKy MO2CHO npOBOAHTL ΠρΕ ΒΤΜΟΟφθρΗΟΜ AaBJíeHEK.UejiL Η3θόρβτθΗΗΉ - noBHnieHHe KanecTBa pejieBoronpopyKTa. ÍIocTaBjíeHHan pejiB αοοτκγηθτοη τβΜ, ητο corjiacnocnocoóy nojiyneHKH cjiojkhhx θφκροΒ, 3aKJnonaiomeMycH boB3anM0p, eficTB2H ajiJ0 $ aTHnecKOH southward apoMaTKnecKOH AHKapóo-HOBOÍí KHCJIOTH HJIK θβ aHPHApKUa HKCJIOM yrjiepoAHHXaTOMOB C 6-18 c aji0 $ aTjaHecK0M οπκρτοΜ HopMaiiBHoro mnaHsocTpoeHHfl c khcjiom ypjiepoAHax aTOMOB 4-12 min cmocbkjyica3aHHHx οππρτοΒ b npjaoyTCTBHH κηολογο KaTajnasaTopa 237,444 ' "3" πρϋ 90-I80 ° C h AaBHeHHH rt aTMOc $ epHoro and οοτβτοηηογο2,666 Kiia c nocjieAyioiWi BUAejieHHeM neneBoro npoAyK-Ta, STepajiiiKamno προΒΟΑΗΤ nepBOHanajiLHO rivet B3anMO-AeĚCTBHH cooTBeTCTByromiix khcjioth h cnnpTa NPH 90-I40 ° Ch AaBjíeHHH ot aTMOG0epHoro ao ocTaTOHHoro 100 mm ρτ.οτ.b τβπβΗΗβ 0,1-2,0 η, nocjie nero κ nojiygeHHoS peaiojHOH-Hoft Macce AoóaBAHKzr kucahíí ao ocTa-ΤΟΉΗΟΓΟ 2,666 Kilo 3ΤΟ Π03Β0ΑΗβΤ Π Π ΒΗΧΟΑ Η ΟΤΒΟθΟΤΒΟ ΠβΑθΒΟΓΟnpOAyKTa. ΠρΗ προΒβΑβΗΗΗ nponecca 3TepB $ HKannH nonpejyiaraeMOMy cnocody cnnpTH b μθηβπιθκ CTeneHH noABep-raDT AerMApaTano, n b 1,5-3,5 paea coKpamaeTca Πρκ ηοπολς> 3οβηζε ηε3κο-ΚΗΠΗπμιχ οπκρτοΒ c hhcaom yrjiepoAHHx ητομοβ 4-8 HarpeBH BHAepKKy MO2CHO npOBOAHTL ΠρΕ ΒΤΜΟΟφθρΗΟΜ AaBJieHEK.
HpZ HCnOJH>3OBaHHH ΒΗΟΟΚΟΚΗΠΗΗΙΕΧ ΟΠΕρΤΟΒ C HHCJIOM yme-POAhux htomób 8-12 αλη tíojiee ποαηογο yAaneHEH peaKnnoH-Hoá boah a3eoTponHofi οτγοηκοΜ co οπηρτομ nponecc aarpe-Ba nejiecooópa3HO προβοαητβ npa oct&tohhom AaBjíeHZH ao13,332 Kila. ΤβΧΗΟΑΟΓΕΗβΟΚΗ neJieCOOdpa3HO HarpeBaTBCMGCB KECJIOTH EJIE ββ aHTBApW B CHHpTa ΠρΕ ΒΤΜΟΟφβρΗΟΜΑΗΒΛΘΗΕΗ AO 90-I40°C H 3aT6M BO ΒρβΜΗ ΒΗΑθΡΧΚΗ ΠΟΟΤβ-πθηηο πρπ ποοτοΗΗΗοδ TeMiiepaType yrjiydjiaTL BaicyyM aoOCTaTOHHOrO AaBJíeHIW ΗΘ ΗΗΗβ 13,332 κΠδ.HPZ HCnOJH> 3OBaHHH ΒΗΟΟΚΟΚΗΠΗΗΙΕΧ ΟΠΕρΤΟΒ C HHCJIOM YME-POAhux htomób 8-12 αλη tíojiee ποαηογο yAaneHEH peaKnnoH-ho boah a3eoTponHofi οτγοηκοΜ what οπηρτομ nponecc AARP-Ba nejiecooópa3HO προβοαητβ Oct NPA & tohhom AaBjíeHZH ao13,332 pounds. ΤβΧΗΟΑΟΓΕΗβΟΚΗ neJieCOOdpa3HO HarpeBaTBCMGCB KECJIOTH EJIE ββ aHTBApW B CHHpTa ΠρΕ ΒΤΜΟΟφβρΗΟΜΑΗΒΛΘΗΕΗ AO 90-I40 ° C H 3aT6M BO ΒρβΜΗ ΒΗΑθΡΧΚΗ ΠΟΟΤβ-πθηηο πρπ ποοτοΗΗΗοδ TeMiiepaType yrjiydjiaTL BaicyyM aoOCTaTOHHOrO AaBJíeHIW ΗΘ ΗΗΗβ 13332 κΠδ.
Ilocjie BBOAa khcjiopo KaTajiH3aTopa αλη 3aBepmeHHHnponecca TeMnepaTypy noBumaiOT ao I00-I80°C, a aTMoc$ep-Hoe AaBjíeHHe cHEscaDT ao οοτβτοήηογο ηθ ηεεθ 20 mm ρτ.οτ.Ilocjie BBOAa khcjiopo KaTajiH3aTopa αλη 3aBepmeHHHnponecca TeMnepaNoBumaiOT Types and I00-I80 ° C, and aTMoc $ ep-Hoe AaBjíeHHe cHEscaDT and about 20mm ρτ.οτ.
Cnocod peajiH3yKT Ha ycTaHOBKax kbk nepiio,n,mecKoro,Tas e HenpepNBHoro aoSctbeh. lípu nepnoAiraecKOM npon3-BOACTBe b peaKTop 3arpysaiOT KapdoHOByro KECJioTy ejie eeaHTEApnA h cnHpT, peaKnnoHHyio cMecB HarpeBaioT npn AaB-ΑβΗΗΗ OT aTMOC$epHOrO AO OCTaTOnHOPO 13,332 Kila. AO90-I40°C b b Teneime 0,1-2,0 ή βηαορηηβηκζγ npH yica3aH- 237444 -4- hok TeMnepaType. 3aTeM b peaKnaoHHyio CMect bboaht khc-jinfi KaTajiH3aTop a nponecc 3aBepinaioT npa I00-I80°C aAaBjíeHKa οτ aTMoc$epHoro no οοτβτοηηογο 20 mm ρτ.οτ.Cnocod peajiH3yKT Ha ycTaHOBKax kbk nepiio, n, mecKoro, Tas e HenpepNBHoro aoSctbeh. lipu nepnoAiraecKOM npon3-BOACTBe b peaKTop 3arpysaiOT CapoHOByro KECJioTy ejie eeaHTEApnA h cnHpT, peaKnnoHHyio cMecB HarpeBaioT npn AaB-ΑβΗΗΗ OT aTMOC $ epHOrO AO OCTaTOnHOPO 13,332 Kilo. AO90-I40 ° C b b Teneime 0,1-2,0 or βηαορηηβηκζγ npH yica3aH- 237444 -4- hok TeMnepaType. 3aTeM b peaKnaoHHyio CMect bboaht khc-jinfi KaTajiH3aTop and nponecc 3aBepinaioT npa I00-I80 ° C aAaBjeeHKa οτ aTMoc $ epHoro no οοτβτοηηογο 20 mm ρτ.οτ.
Hpa HenpepuBHOM npoa3BoncTBe KapóoHOByio KacnoTyana ee aHPanpan a οππρτ HenpepHBHo b sanaHHOM cootho-meHO BBOAHT Β φθρθφΗρΒ3ΗΤΌρ, KOTOpUM CJiyMT ΠβρΒΗΗannapaT Kacnana peaKTopos ra nepsán ceKnaa οθκηηοηη-poBaHHoro peararopa. Β φορ3φηρη3ητορβ no/wepMBaioTTeMnepaTypy 90-I40°C a nanceHae οτ ητΜοοφβρΗΟΡο noOCTaTOHHOrO· 13,332 κΠα. PeaiOíaOHHyK) CMeCL C nOCTOHH-ηογο ypoBHH φορ3φΒρη3Βτορη HenpepHBHo otboaht bo BTopofiannapaT Kacnana ana bo BTopyio ceKiíino ceKnaoHapoBaHHOPOpeaKTopa, Kyna bboaht kbcjihh KaiajiasaTop a rne ποηηθρ-OBaiOT TeMnepaTypy I00-I80°C a naBjreHae οτ ητΜοοφβρκοροno ocTaTonnoro 2,666 κπη. B KanecTBe KaTajiK3aTopamosího πρκΜθΗΒΤΒ pa3jiaHHHe kbcjioth, Tanae, Kaa cepnaaKKCjiOTa, óeH30Jicyjn^0KKCji0Ta, napaTojiyojicyjn4>OKHCJioTa.Hpa HenpepuBHOM npoa3BoncTBe KapoHOByio KacnoTyana ee aHPanpan and HenpepHBHo b sanaHHOM cootho-me BBOAHT φ φθρθφΗρΒ3ΗΤΌρ, KOTOpUM CJiyMT ΠβρΒΗΗannapaT Kacnana peaKTopos not written ceKnaa οθκηηοηη-poBaHHoro peararopa. 90 φορ3φηρη3ητορβ no / wepMBaioTTeMnepaTypes 90-I40 ° C and nanceHae οτ ητΜοοφβρΗΟΡο noOCTaTOHHOrO · 13,332 κΠα. PeaiOíaOHHyK) CMeCL nOCTOHH C-ηογο ypoBHH φορ3φΒρη3Βτορη HenpepHBHo otboaht bo bo BTopofiannapaT Kacnana ana BTopyio ceKiíino ceKnaoHapoBaHHOPOpeaKTopa, KYNA bboaht kbcjihh KaiajiasaTop and RNE-ποηηθρ OBaiOT TeMnepaTypy I00-I80 ° C naBjreHae οτ ητΜοοφβρκοροno ocTaTonnoro 2666 κπη. B KanecTBe KaTajiK3aTopamosí πρκΜθΗΒΤΒ pa3jiaHHHe kbcjioth, Tanae, Kaa cepnaaKKCjiOTa, óeH30Jicyjn ^ 0KKCji0Ta, napaTojiyojicyjn4> OKHCJioTa.
HpaMep I.HpaMep I.
Ha ycTaHOBKe HenpepuBHoro ηθκοτΒΗΗ, BKjnonaoueSKacKan as. 4-KyóoBHx annapaTOB c MemajiKoS eMKOcTLX) no2 n Kasnníí, nonynaioT na(2-3TanreKCBJi^ajiaT B3aaMoneS-CTBaeM φτβΛβΒΟΡΟ aHranppna c 2-3TBjireKcaH0Ji0M β npa-cyTCTBKB cepHoa khcjioth b KanecTBe KaTajiasaTopa b cpeneB3ÓHTonHoro 2-3TajireKcaHOjia» B nepBna annapaT Kacaana HenpepHBHo nonaioT pacnnasφΤΗΐιβΒΟΓο aHPanpana a 2-3THjipeKcaH0Jia co CKopocTLio380 a 800 p/n οοοτβθτοτβθηηο. B yKasaHHOM annapaTenonnep&HBaioT TeMnepaTypy I2Q-I25°C, BpeMH npedusanaapeaKnaoHHoa CMeca 1,2 h. PÍ3 nepBOPO aimapaTa peaKnaoH-Hyio GMecL HenpepHBHo c ποοτοηηηογο ypoBHH nonaior bo bto-poa peaKTop nacnana, β κοτορπη Tarase ΒΒοηπτ cepnyroaacnoTy co CKopocTLio 4 p/n. TeMnepaTypy bo btopom pean-τορβ nonnepsasaioT I30°C, a b ocTajnsmix I30-I35°C, oc-TaTOHHoe nasjíenae bo scex annapaTax KacKana cocTaBJweT13,332-16 Kila. 237444 -5-Ha ycTaHOBKe HenpepuBHoro ηθκοτΒΗΗ, BKjnonaoueSKacKan as. 4-KyóoBHx annapaTOB MemajiKoS eMKOcTLX c) NO2 n Kasnníí, nonynaioT to (2-3TanreKCBJi ^ ajiaT B3aaMoneS-CTAB φτβΛβΒΟΡΟ aHranppna c 2-3TBjireKcaH0Ji0M β-NPA cyTCTBKB cepHoa khcjioth b KanecTBe KaTajiasaTopa b cpeneB3ÓHTonHoro 2-3TajireKcaHOjia »B nepBna annapaT Kacaana HenpepHBHo nonaioT pacnnasφΤΗΐιβΒΟΓο aHPanpana and 2-3THjipeKcaH0Jia what CKopocTLio380 and 800 p / n οοοτβθτοτβθηηο. yKasaHHOM annapaTenonnep B & HBaioT TeMnepaTypy I2Q-I25 ° C BpeMH npedusanaapeaKnaoHHoa CMEC 1.2 h. PI3-nepBOPO aimapaTa peaKnaoH Hyio GMecL HenpepHBHo c ποοτοηηηογο ypoBHH nonaior bo bto- poa peaKTop nacnana, β κοτορπη Tarase ΒΒοηπτ cepnyroaacnoTy what CKopocTLio 4 p / n. 237444 -5-
Hapn peaicmioHHOň βολή η 2-9ToreKcaHo.ua, βηκηπβιο-qne b nponecce peaxmm, HanpaBjíHioí B χολοαοβηηκ,ότκυ-fla oxjias&eHHHH κοηλθηοητ HanpaBjíHioT bo φπορβΗΤΗΗοκίώcocyA. W3 φηορβΗτηδοκοΓο cocyaa BOAy nepe3 hhhhhS cjikbHenpepHBHO ΟΤΒΟΑΗΤ B ΠρΗθΜΗΗΚ BOAH, a CHHpT C ΒβρΧΗβΓΟypoBHH HenpepHBHO nepe3 ropo3aTBop B03BpamaioT b nepBHfiannapaT KacKa^a. M3 nocjieAHero peaKTopa Kacnajia HenpepHBHO bhboahtpacTBop iíejieBOíO npoAyKTa b h3Óhtohhom 2-9ToreKcaH0Aeo KHCJIOTHHM hhcjiom 2-3,5 ΜΓ KOH/r, κοτορκδ HanpaBJwroTHa HeHTpajioamoo b KyóoBHíi annapaT c MemajiKOÉ oóteMOM2 λ, ny^a TaKxe HenpepHBHO co cKopocTLip 320 r/n bboaht2$-hh2 boahhh pacTBop mejionn. TeMnepaTypa b HeÉTpajua-3aTope 70°C, A^BJíeHne aTMoc$epHoe. Ή3 HefiTpajiH3aTopa 9$Hp-CHpen c khcjiothhm hhcaom0,07 mt KOH/r οημοτθκομ c ποοτοηηηογο ypOBHH nocTynaeTB OTCTOHHHK Ο0Ϊ.ΘΜΟΜ 3 JI, ΓΑθ OCBOÓOHÍAaeTCH OT ΒΟΑΗΟΓΟpacTBopa qejioHH h cojiefi. M3 οτοτοηηηκη ηηχηηη boahhhcjioh nepHOAireecKH cjiHBaioT, a 9$Hp-CHpen; c ποοτοηηηογοypoBHH HanpaBjíHioT b annapaT jvlh προμηβκη οόι,βΜΟΜ 3 ji,Kyna HenpepHBHO bboaht npoMHBHyio BOAy co ckopoctbk1000 r/n. npoMHBKy προβοαητ npn 70°C h aTMoc$epnoMAaBAeHO. Jlajiee b οτοτοηΗΗκε ο0έθμομ 3 η θφπρ-ΟΗρβη οτ-AeJIHIOT OT npOMHBHOS boah, ΠΟΟΗΘ ΉθΓΟ HanpaBjíHioT B Ky-ÓOBufi οτΓΟΗΗΗδ annapaT c MemajiKofi, β ηηχηθΙ nacTia koto-poro pacnoAoaeH πθρφορΗροΒΗΗΗΗΗ βμθθβηκ. Hepe3 3MeeBHKβ annapaT noAaiOT οοτρκη neperpeTHfi boahhoh nap c TeMne-paTypoĚ I60-I70°C b KOjioecTBe 400 r/n. TeMnepaTypa bοτγοηηομ annapaTe I60°C, ocTaTOHHoe AaBjíeHne 17,332 κπηΟΦητ- Β 9THX yCAOBHHX OT 9$Hpa-CHpna ΟΤΓΟΗΗΙΟΤ H3ÓHTOHHHHοπηρτ h jieTynne κομποηθητη, nocjie nero 3$np-CHpen oó-paóaTHBaKT copÓeHTHMH - βκτηβηροββηηημ yrjieM h rjumofinpn 80°C (pacxoA copóeHTOB no 0,5$ ot Beca iwacTH$HKa-TOpa) Η ΟΤφΟΒΤρΟΒΗΒεϋΟΤ ·Hapn peaicmioHHOň η 2-9ToreKcaHo.ua, βηκηπβιο-qne b nponecce peaxmm, HanpaBjíHioí B χολοαοβηηκ, oxτκυ-fla oxjias & eHHHH κοηλθηοητ HanpaBjíHioT bo φπορβΗΤΗΗοκίώcocyA. W3 φηορβΗτηδοκοΓο cocyaa BOAy nepe3 hhhhhS cjikbHenpepHBHO ΟΤΒΟΑΗΤ B ΠρΗθΜΗΗΚ BOAH, and CHHpT C ΒβρΧΗβΓΟypoBHH HenpepHBHO nepe3 ropo3aTBop B03BpamaioT b nepBHfiannapaT M3 nocjieAHero peaKTopa Kacnajia HenpepHBHO bhboahtpacTBop iíejieBOíO npoAyKTa b h3Óhtohhom 2-9ToreKcaH0Aeo KHCJIOTHHM hhcjiom 2-3.5 ΜΓ KOH / r κοτορκδ HanpaBJwroTHa HeHTpajioamoo b KyóoBHíi annapaT MemajiKOÉ oóteMOM2 λ c, ny ^ and TaKxe HenpepHBHO what cKopocTLip 320 r / n bboaht2 $ - hh2 boahhh pacTBop mejionn. TeMnepaTypes b HeÉTpajua-3aTope 70 ° C, A ^ BJíeHne aTMoc $ epHoe. H3 HefiTpajiH3aTopa 9 $ Hp-CHpen c khcjiothhm hhcaom0,07 mt KOH / r οημοτθκομ c ποοτοηηηογο ypOBHH nocTynaeTB OTCTOHHHK Ο0Ϊ.ΘΜΟΜ 3 JI, θΑθ OCBOÓOHÍAaeTCH OT ΗΟΓΟΑΗΟΓΟpacTBopa qejioHH h cojiefi. M3 οτοτοηηηκη ηηχηηη boahhhcjioh nepHOAireecKH cjiHBaioT, and 9 $ Hp-CHpen; c ποοτοηηηογοypoBHH HanpaBjíHioT b annapaT jvlh προμηβκη οόι, βΜΟΜ 3 her, Kyna HenpepHBHO bboaht npoMHBHyio BOAy what ckopoctbk1000 r / n. npoMHBKy προβοαητ npn 70 ° C h aTMoc $ epnoMAaBAeHO. Laj θ Ή-pa-pa pa ann ann ann ann ann ann ann ann apa apa apa apa apa apa apa apa apa apa apa apa apa oto oto oto oto oto oto oto Hepe3 3MeeBHKβ annapaT noAaiOT οοτρκη neperpeTHfi boahhoh nap c TeMne-paTypoĚ I60-I70 ° C b KOjioecTBe 400 r / n. TeMnepaTypa bοτγοηηομ annapaTe I60 ° C ocTaTOHHoe AaBjíeHne 17332 κπηΟΦητ- Β 9THX yCAOBHHX OT 9 $ Hpa-CHpna ΟΤΓΟΗΗΙΟΤ H3ÓHTOHHHHοπηρτ h jieTynne κομποηθητη, nocjie nero 3 $ CHpen NP-Oo-paóaTHBaKT copÓeHTHMH - βκτηβηροββηηημ yrjieM rjumofinpn h 80 ° C (no pacxoA copóeHTOB 0.5 $ ot Beca iwacTH $ HKa-TOpa) Η ΟΤφΟΒΤρΟΒΗΒεϋΟΤ ·
Bhxoa ho cnnpTy η πβθτ nojiyneHHoro αη(2-9τογθκ- 237444 -6~ ciu)$TajiaTa πρΗΒθββΗΗ b Taójiw» IIpHMep 2.Bhxoa ho cnnpTy η πβθτ nojiyneHHoro αη (2-9τογθκ- 237444 -6 ~ ciu) $ TajiaTa πρΗΒθββΗΗ b Taójiw »IIpHMep 2.
Ha ycTaHOBKe HenpepNBHoro AeĚCTBUH, onucaHHOH bupaMepe I, nojiynaiOT £0Κ3θΛθΑθιι;ιυιφτ&7ΐΒΤ nyTeM B3anMo~AeHCTBHH $TaJieBOPO aHTJampUfta θ ΗΒΟΛΟ^ΘΙζΚΠΟΒΗΜ οπκρτοΜ bnpHcyTCTBJKH napaTOJiyojicyjiL$OKHCjiOTH b KanecTBe KaTajua-saTopa, B nepBHíi pearcrop Kacna^a HenpepuBHO no^aioTpacmiaB $TajieBoro aHrnnpnna η η30λοαθπ;οοβηη οππρτ cockopoctlx) 370 sl 940 r/n οοοτβθτοτβθηηο , r#e nojmepo-saioT TewmepaTypy I40°C, a BpeMH npeduBaHHH b yKasaHHOMannapaTe 0,9 a. KaTajinsaTop-pacTBop napaTOJtyojicyjiL$o-khcjiotu b Η30Λ0Λθη;ο0Β0Μ οπΗρτθ, bboaht BO BTopoS annapaTKacKa^a co οκοροοτΒ® 80 γ/ή, rn,e noanep^nBaiOT I65°C,b ocTajiLHHX peaKTopax KacKa^a 2,666 Kila. KncjioTHoe ήηοjío 3$0pa-cKpn;a 3,8 μγ ΚΟΗ/γ. IIojiyaeHHHS: 3φηρ odpadaTH-BajOT Η3ΒΘΟΤΗΗΜ CIIOCOÓOM. Βηχοβ no cruapTy η ββθτ nojiyneHHoro 3$npa npuBeAeHHb TaÓJiflue.Ha ycTaHOBKe HenpepNBHoro AeĚCTBUH, onucaHHOH bupaMepe I nojiynaiOT £ 0Κ3θΛθΑθιι; ιυιφτ & 7ΐΒΤ rivet B3anMo ~ AeHCTBHH $ TaJieBOPO aHTJampUfta θ ΗΒΟΛΟ ^ ΘΙζΚΠΟΒΗΜ οπκρτοΜ bnpHcyTCTBJKH napaTOJiyojicyjiL $ OKHCjiOTH b KanecTBe KaTajua-saTopa B nepBHíi pearcrop cation ^ and HenpepuBHO NOx aioTpacmiaB $ TajieBoro aHrnnpnna η η30λοαθπ; οοβηη οππρτ cockopoctlx) 370 sl 940 r / n οοοτβθτοτβθηηο r # e nojmepo saioT TewmepaTypy-I40 ° C, and b BpeMH npeduBaHHH yKasaHHOMannapaTe and 0.9. KaTajinsaTop-pacTBop napaTOJtyojicyjiL $ o khcjiotu b Η30Λ0Λθη; ο0Β0Μ οπΗρτθ , bboaht BO BTopoS annapaTKacKa ^ a 80 ° C, or, rn, e n a p e n a p e r i rt 65 ° C, b ocTiLHHX peaKTopax KacKa ^ and 2,666 Kila. KncjioTHoe is 3 $ 0pa-cKpn and 3.8 µg ΚΟΗ / γ. IIojiyaeHHHS: 3φηρ waste TH TH-BajOT Η3ΒΘΟΤΗΗΜ CIIOCOÓOM. Cruηχοβ no cruapTy η ββθτ nojiyneHHoro 3 $ npa npuBeAeHHb TaÓJiflue.
Hpmep 3.Hpmep 3.
Ha ycTaHOBKe πθρκοΛΧΉθοκοΓΟ αθηοτβηη , BKJtmaioineĚKOJióy cmkoctbio I jí c MemajiKož h pydanncoÉ juih noABOjxaoÓorpeBannero areHTa, βοαηηοη xojioaejibhhk , $JiopeHT0HCK0Kcocyn a npn6MHHK βολή, nojiynaioT AHtíyT0Jia£HnHHaT b npn-cyTCTBO deH3OjrcyjrB$OKiícJiOTi2 b nanecTBe naTajinsaTopa.Ha ycTaHOBKe πθρκοΛΧΉθοκοΓΟ αθηοτβηη, BKJtmaioineĚKOJióy cmkoctbio She, c h MemajiKož pydanncoÉ juih noABOjxaoÓorpeBannero areHTa, βοαηηοη xojioaejibhhk, and $ JiopeHT0HCK0Kcocyn npn6MHHK βολή, nojiynaioT AHtíyT0Jia £ HnHHaT b npn cyTCTBO deH3OjrcyjrB $ OKiícJiOTi2 b nanecTBe naTajinsaTopa.
B Kojidy sarpysaBT 146 r ajuanuHOBOH khcjioth h158 r dyTaHOJia, HarpeBaioT peaKuxoHHyío CMecB #o 90°Cnpn aTMoc$epHOM jQ,aBjicH0H 0 BH£epx0BaK>T ee πρ0 btoh τθμ~nepaType b TeneHne 0,5 a. Jlajiee b peaKUHOHHyio CMecBbboaht 1,5 r deH3OjicyjiB$OK0CJioTH, pacTBopeHHoS b 20 rdyTaHOJia, 0 np0 I30°C 0 aTMOc$epHOM saBjíeHHH λοβοαητpeaKiyuo η,ο κηο;ιοτηογο nncjia 3,5 mt KOH/γ. IIojiyneHHHH9$0p odpadaTHBaroT 03βθοτηημ cnocodoM, a εμθηηο, sarpy-saioT θφηρ-ΟΗρεί]; b Kojidy c MemajiKOÉ, Týna se aodaBjmiOT120 r 2%-ηογο BOAHoro pacTBopa mejionn 0 nepeMeniHBaioTcoflepxBMoe KOJidH b Teneme 0,5 ή npx 70°C 0 aTiwoc$epHOM 237444 -Ί- nasjíeHEH. 3aTeM nocjie paccjiaHBaHKH CMecn hejkhee boaho-COJieBOfí CJIOii CJIEBaKT, a 3φΕρ C KECJIOTHUM HECJIOM0,03 mt KOH/r flBasWH npoMUBaioT 200 r βολή b TeneHEe0,5 í lípu 60°C. Jlajiee npE I40°C η οοτητοηηομ naBJíeHHE60 MM PT.CT. ΟΤΓΟΗΗΒΤ E3dUT0nHHÉ ΟΠΕρΤ. 3aTeM OCTaTKEJieTyHEX ΚΟΜΠΟΗΘΗΤΟΒ ΟΤΓΟΗΗΙΟΤ OCTpUM ΠθρβΓρβΤΗΜ IiapOMnpH I40°C E OCTaTOHHOM AaBJíeHEE’ 13,332 Kila. HOCJienero oópatíaTKBaiOT ηκτεβηροβηηηημ yrjieM e tjiehoíí npn90°C E OCTaTOHHOM ^aBJíeHEE 5,333 Kila. B ΤΘΗθΗΕθ 0,5 Ή.3aTeM COUepOMOe KOJldU ΟΤφΕΛΒΤρΟΒΗΒΗΚΤ. ΙίΒΘΤ 3$Epa E ΒΗΧΟΛ HO CEEpTy ΠρΗΒΘΑθΗΕ B TaÓJIEEe. ΠρΕΜθρ 4.B Cojidy sarpysaBT 146 r ajuanuHOBOH khcjioth h158 r dyTaHOJia, HarpeBaioT peaKuxoHHyío CMecB #o 90 ° Cnpn aTMoc jp0 btoh τθμ ~ nepaType b TeneHne 0,5 a. 5 r deH3OjicyjiB $ OK0CJioTH, pacTBopeHHoS b 20 rdyTaHOJia, 0 np0 I30 ° C 0 aTMOc $ epHOM saBjieHHH λοβοαητpeaKiyuo η, ο ηοτηογο nncjia 3,5 mt KOH / γ. IIojiyneHHHH9 $ 0p waste, THBaroT 03βθοτηημ cnocodoM, and εμθηηο, sarpy-saioT θφηρ-ΟΗρεί]; b Cojidy c MemajiKOÉ, Týna se aodaBjmiOT120 r 2% -ηογο BOAHoro pacTBopa mejionn 0 nepeMeniHBaioTcoflepxBMoe KOJidH b Teme 0.5 or npx 70 ° C 0 aTiwoc $ epHOM 237444 -Ί- feedHEH. 3CMChChChChChChChChhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhh ... Jlajiee npE I40 ° C η οοτητοηηομ naBJíeHHE60 MM PT.CT. 3 E3dUT0nHHÉ ΟΠΕρΤ. 3aTeM OCTaTKEJieTyHEX ΚΟΜΠΟΗΘΗΤΟΒ ΟΤΓΟΗΗΙΟΤ OCTpUM IiapOMnpH I40 ° C E OCTaTOHHOM AaBJíeHEE ’13,332 Kilo. HOCJienero pat KB KB KB KB KB ai ai ai ai ai ai ° ° ° ° ° ° ° ° ° ° CT CT ,3 ,3 ,3 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 B 0.5 ΤΘΗ.3aTeM COUepOMOe KOJldU ΟΤφΕΛΒΤρΟΒΗΒΗΚΤ. $ίpa 3 $ EpaΒΗΧΟΛe CEEpTy ΠρΗΒΘΑθΗΕ B TaÓJIEEe. ΠρΕΜθρ 4.
Ha onEcaHHOĚ b npEMepe 3 ycTaHOBKe nojiynaioT θφκρI,I6-reKcafleKaHftHKapóoHOBo& kechoth e CMecn HopMajihHuxCEEpTOB Cy-Cg. B kojióv 3arpysaiOT 135 r οπερτοβ C?-Cg e 157 rΙ,Ι6“Γθκο8βθκβΗβκκΕρ0θΗθΒοίί kecjiotu, HarpeBajOT peaK-IíEOHHyK) CMeCB £O I40°C npE OCTHTOHHOM HaBJíeHHH 26,664 Kila e BimepSHBaDT ee npn stoh TeMnepaType β TeneHHe2 h. Jajiee b peaKnzoHHy» ομθοβ bboaht 2 r napaTOJiyojicyjit-Φοκεολοτη, pacTBOpeHHOH b 30 r οππρτοΒ, e 3aBepnia»Tnponeco npn I50°C e οοτητοηηομ AaBJíeHHE 13,332 Kna.KECJIOTHOe HECJIO θφΕρΒ-ΟΗρί^ 3,7 ΜΓ KOH/r. HOJiyHeHHHŽθφΕρ oÓpaóaTHBaioT cnocodoM, kbk onzcaHo b npEMepe 3.Ha onEcaHHO b npEMepe 3 ycTaHOBKe nojiynaioT θφκρI, I6-reKcafleKaHftHKapoHOBo & kechoth e CMecn HopMajihHuxCEEpTOB Cy-Cg. B kojióv 3arpysaiOT 135 οπερτοβ C r? E -Cg 157 rΙ, Ι6 "Γθκο8βθκβΗβκκΕρ0θΗθΒοίί kecjiotu, HarpeBajOT peak-IíEOHHyK) CMeCB £ O I40 ° C NPE OCTHTOHHOM HaBJíeHHH 26664 Kilo e BimepSHBaDT ee npn stack TeMnepaType β TeneHHe2 h. Jajiee b peaKnzoHHy» ομθοβ bboaht 2 r napaTOJiyojicyjit-Φοκεολοτη, pacTBOpeHHOH b 30 r οππρτοΒ, e 3aBepnia »Tnponeco npn I50 ° C aο τοοητοηηομ AaBJíeHHE 13,332 Kna.KECJIOTHOe HECJIO θφΕρΒ-ΟΗρί ^ 3,7 ΜΓ KOH / r. HOJiyHeHHHŽθφΕρ oÓpaóaTHBaioT cnocodoM, kbk onzcaHo b npEMepe 3.
UseT ^φHpa e βηχολ no cnnpTy πρεβθλθηη b Tadjinne.ΠρΗΜβρ 5«,UseT ^ φHpa e βηχολ no cnnpTy πρεβθλθηη b Tadjinne.ΠρΗΜβρ 5 «,
Ha onncaiiHOH b npEMepe 3 ycTaHOBKe nojiynanr λε-reKCHJicedaiíHHaT b npEcyTCTBHE cepHož kecjiotu b KanecTBeKaTajiE3aTopa. B Kondy 3arpyjKaiOT 202 r cedanzoHOBOM kecjiotu e245 r reKCHJioBoro cnEpTa, HarpeBaíOT peaKiíHOHHyro CMecBΛΟ 90°C npE ocTaTOHHOM nasjíeHEH 13,332 Kna. e bu-Η,βρκΗΒΒΒτ ee npn stoS TeMnepaType 0,1 k. Jlajiee bpeaKEEOHHyro ομθοβ bboaht 2 r cepHofi kecjiotu e aoboahtpeaioíEB npn I00°C η οοτβτοηηομ jjaBJíeHEE· 5,333 Kna. 237444 -8- £0 KHCJIOTHO.rO HHCJia 3,8 ΜΓ KOH/r. nOJiyHeHHHH 3φκρ οό— patíaTHBaioT cnocoóoM, KaK onncaHo b npHMepe 3.Ha onncaiiHOH b npEMepe 3 ycTaHOBKe nojiynanr λε-reKCHJicedaiíHHaT b npEcyTCTBHE cepHož kecjiotu b KanecTBeKaTajiE3aTopa. B Horses 3arpyjKaiOT 202 r cedanzoHOBOM kecjiota e245 r reKCHJioBoro cnEpTa, HarpeBaíOT peaKiHOHHyro CMecBΛΟ 90 ° C npE ocTaTOHHOM nasříeHEH 13,332 Kna. e bu-Η, βρκΗΒΒΒτ ee npn stoS M M M M M M M M M M M M M M M M 00 00 00 00 00 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 · 5,333 Kna. 237444 -8- £ 0 KHCJIOTHO.rO HHCJia 3.8 ΜΓ KOH / y. nOJiyHeHHHH 3φκρ οό— patíaTHBaioT cnocoóoM, KaK onncaHo b npHMepe 3.
Bhxoa no cnupTy h η;βθτ 3$npa πρηβθλθηη b Taójnme* IIpeAziaraeMHfí cnocoó no3BojmeT yjiynuiHTL ηβθτ nojiy- naeMHx 3φηροΒ Ha 50-100 eji. Xa3eHa, npn stom npoHcxo^HTyBCJiHHCHjae βηχολβ nejieBoro npoAyKTa no cnnpTy Ha 2-I0$oBhxoa no cnupTy h η; βθτ 3 $ npa πρηβθλθηη b Taójnme * IIpeAziaraeMHfí cnocoó no3BojmeT yjiynuiHTL ηβθτ nojiy- naeMHx 3φηροΒ Ha 50-100 eji. Xa3eHa, npn stom npoHcxo ^ HTyBCJiHHCHjae β η oro oro 2 2 2 2 2 2 2 2
--T--T
Cnocoó np™ep_ AH(2-3THJI- Γθκοηιι)φτΒCnocoó np ™ ep_ AH (2-3THJI- Γθκοηιι) φτΒ
jiaT AHH3O- none- HHJI-jiaT AHH3O- none- HHJI-
ipTajiaT £HÓy~ THJI-ipTajiaT £ HÓy ~ THJI-
I j 3φ2PjI,I6-reKca- ajmnn- i neKaJtUHKap-HaT i ÓOHOBOS KHC-jJIOTH H CMe-jCH HOpMaJIL-íhhx οππρτοΒ{Ογ-Οθ ΛΗΓβκοιω-I j 3φ2PjI, I6-reKca- ajmnn- i neKaJtUHKap-HaT i ÓOHOBOS KHC-jJIOTH H CMe-jCH HOpMaJIL-ihhx οππρτοΒ {Ογ-Οθ ΛΗΓβκοιω-
ceóannHaTceóannHaT
Bhxoa nocnnpTy,% 1Í3B6CTHNH 94,6 90,5- 84,0 Ilpejyiarae-MHH 97,0 95,2 Ββθτ no íuia-THHOKOÓajEb-toboh niKane,eA.Xa3eHa Κ3ΒθΟΤΗΗΗ 200 100-125 Upejuarae-MHH 100 80 94,9- 94,4 95,0 92,5 96,1 96,8 97,2 125-150 200 150 100 125 90 237444 -9- ΦΟΡΜΖΚΑ Η30ΕΡΕΤΕΗΜΗBhxoa nocnnpTy,% 1Í3B6CTHNH 94.6 90.5-84.0 Ilpejyiarae-MHH 97.0 95.2 Ββθτ no íuia-THHOKOÓajEb-toboh niKane, eA.Xa3eHa Κ3ΒθΟΤΗΗΗ 200 100-125 Upejuarae-MHH 100 80 94.9- 94.4 95.0 92.5 96.1 96.8 97.2 125-150 200 150 100 125 90 237444 -9- ΦΟΡΜΖΚΑ Η30ΕΡΕΤΕΗΜΗ
Cnocoó nOJiyHeHHH CJIOKHHX 3φΗρθΒ IiyTeM 9TepH$HKa-iíhh ajiH$aTjnecKofí hjih apoMaTinecKOfí «HHKaptíoHOBOfi khcjio-tu, ran ee aHTBSPUHa c hhcjiom yrjiepojwx btomob 6-18C aHH$aTi!raeCKITM ΟΠΚρΤΟΜ HOpMaJILHOro 0JM Η300Τρ0θΗΒΗ C -hbcjiom yrjiepoAHUx aTOMOB 4-12, mu ομθοβκ) yKa3aHHUxciuapTOB b npHcyTCTBHH KHCjioro KaTajiH3aTopa npn 90-I80°Ch saBjíeHHH ot aTMoc$epHoro jj,o ocTaTOHHoro 20 mm ρτ.οτ.c nocjieAyianyíM βηλθλθηηθμ uejieBoro npoflyKTa, OTJunaramtíi-Cfl ΤΘΜ, HTO, C BejILIO HOBHineHHH KanecTBa ijejieBoro npo-AyKTa, 9Tepn$HKamno προβολητ nepBOHaHain>HO nyTeM B3aHMo-aeĚCTBHfl cooTBeTCTBywtx khcjioth m cnnpTa npn 90-I40°Ch flaBjíeHHB ot aTMoc$epHoro ro οοτβτοήηογο 100 mm ρτ.οτ.b τθΗθΗΒθ 0,1-2,0 ή, nocjie nero κ nojiyneHHofí peaKijHOH-hoh Macce AoóaBjíHioT khcjihh KaTajiH3aTop h nponecc προβολητnpn I00-I80°C h .naBJíeHiffl ot aTMoc$epHoro ro οοτβτοηηογο20 mm ρτ.οτ. 237444Cnocoó nOJiyHeHHH CJIOKHHX 3φΗρθΒ IiyTeM 9TepH $ HKA-iíhh ajiH $ aTjnecKofí hjih apoMaTinecKOfí «HHKaptíoHOBOfi khcjio-tu, wounds ee aHTBSPUHa c hhcjiom yrjiepojwx btomob 6-18C $ Ti ahh! RaeCKITM ΟΠΚρΤΟΜ HOpMaJILHOro 0JM Η300Τρ0θΗΒΗ C -hbcjiom yrjiepoAHUx aTOMOB 4-12, he ομθοβκ) yKa3aHHUxciuapTOB b npHcyTCTBHH KHCjioro KaTajiH3aTopa NPN 90-I80 ° Ch rt saBjíeHHH aTMoc $ epHoro mu ocTaTOHHoro about 20 mm ρτ.οτ.c nocjieAyianyíM βηλθλθηηθμ uejieBoro npoflyKTa, OTJunaramtíi CFL ΤΘΜ, HTO, C BejILIO HOBHineHHH KanecTBa ijejieBoro NPO-AyKTa, 9Tepn $ HKamno προβολητ nepBOHaHain> HO nyTeM B3aHMo-aeĚCTBHfl cooTBeTCTBywtx khcjioth m cnnpTa npn 90-I40 ° Ch flaBjeeHHB ot aTMoc $ epHoro ro οοτβτοήηογηο 100 mm ρτ.οτ.b 0,1-2,0 or nocjie nero κ nojiyneHHof -hoh Macce AoóaBjíHioT khcjihh KaTajiH3aTop h nponecc προβολητnpn I00-I80 ° C h.naBJíeHiffl ot aTMoc $ epHoro ro οοτβτοηηογο20 mm ρτ.οτ. 237444
Severografia, n. p., MOSTSeverografia, n. P., MOST
Cena 2,40 Kčs wPrice 2.40 Kčs w
AHHOTAIW Π3θόρθτθΗΒθ othccbtca k opraHinecKOMy CBHTG3y«AHHOTAIW Π3θόρθτθΗΒθ othccbtca k opraHinecKOMy CBHTG3y «
UejIB Β300ρθΤθΗΒΗ - ΠΟΒΗΙΙΙΘΗΒΘ KHBOCTBa ΒΘΑΘΒΟΡΟnpojtyKTa. IIocTaBJíeHHaa ijejih AOCTBraeTCH τθμ» hto 9TepB$BKa-IífDO ΠΡΟΒΟΛΗΤ nepBOHaHajILHO HyTBM B3ajaMO#e2OTBílH COOT-BeTCTByroiumc khcjioth h cnHpTa npn 90-I40°C ά a&bjiohhh otaTMoc$epHoro ao οοτβτοβηογο 100 mm ρτ.οτ. b τθήθηβθ0»1-2,0 π, nocjie βθγο k nojtyqeHHOž ρθβκπ,ηοηηοη MacceAOÓaBJDWT KHCAHB KaTaAH3aT0p B nponecc npOBOAST npBI00-I80°C b AaBJíeHBB ot aTMoc$epHoro ao ocTaTOHHoro20 Mty pT.CT. 237444UejIB Β300ρθΤθΗΒΗ - ΠΟΒΗΙΙΙΘΗΒΘ KHBOCTBa ΒΘΑΘΒΟΡΟnpojtyKTa. AOCTBraeTCH θ 9 9epTTTTTííTTTTTTTTTTOCOCOCOCOCOCOCOCTTTTTTTT Hy Hy Hyiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumiumium b τθήθηβθ0 »1-2,0 π, nocjie βθγο k nojtyqeHHOž ρθβκπ, ηοηηοη MacceAOÓaBJDWT KHCAHB KaTaAH3aT0p B npOBOAST npBI00-I80 ° C b AaBJíeHBB ot aTMoc $ epHoro ao ocTaTOHHoro20 Mty pT.CT. 237444
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU792845752A SU1038335A1 (en) | 1979-11-28 | 1979-11-28 | Process for preparing esters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS634381A1 CS634381A1 (en) | 1984-11-19 |
| CS237444B1 true CS237444B1 (en) | 1985-08-15 |
Family
ID=20861875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS816343A CS237444B1 (en) | 1979-11-28 | 1981-08-25 | Method of esther preparation |
Country Status (2)
| Country | Link |
|---|---|
| CS (1) | CS237444B1 (en) |
| SU (1) | SU1038335A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10043545A1 (en) * | 2000-09-05 | 2002-03-14 | Oxeno Olefinchemie Gmbh | Process for the preparation of carboxylic acid esters |
-
1979
- 1979-11-28 SU SU792845752A patent/SU1038335A1/en active
-
1981
- 1981-08-25 CS CS816343A patent/CS237444B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS634381A1 (en) | 1984-11-19 |
| SU1038335A1 (en) | 1983-08-30 |
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