CS201239B3 - Method of flameproof finish of polyester fibres or webs - Google Patents
Method of flameproof finish of polyester fibres or webs Download PDFInfo
- Publication number
- CS201239B3 CS201239B3 CS329978A CS329978A CS201239B3 CS 201239 B3 CS201239 B3 CS 201239B3 CS 329978 A CS329978 A CS 329978A CS 329978 A CS329978 A CS 329978A CS 201239 B3 CS201239 B3 CS 201239B3
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- treated
- compounds
- phosphonium
- webs
- quaternary
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 8
- 229920000728 polyester Polymers 0.000 title claims description 6
- 239000000463 material Substances 0.000 claims description 13
- 238000011282 treatment Methods 0.000 claims description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 4
- PMOIAJVKYNVHQE-UHFFFAOYSA-N phosphanium;bromide Chemical compound [PH4+].[Br-] PMOIAJVKYNVHQE-UHFFFAOYSA-N 0.000 claims description 4
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 3
- 229920001634 Copolyester Polymers 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 claims description 3
- CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- USJRLGNYCQWLPF-UHFFFAOYSA-N chlorophosphane Chemical compound ClP USJRLGNYCQWLPF-UHFFFAOYSA-N 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000004254 Ammonium phosphate Substances 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 2
- 235000019289 ammonium phosphates Nutrition 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- -1 bis (hydroxyethyl) -5-sulfoisophthalic acid sodium salt Chemical compound 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 206010051602 Laziness Diseases 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- JKRKEUQXIACMDT-UHFFFAOYSA-K [Na+].OCCC1=C(C(=O)[O-])C=C(C=C1C(=O)[O-])S(=O)(=O)[O-].[Na+].[Na+] Chemical compound [Na+].OCCC1=C(C(=O)[O-])C=C(C=C1C(=O)[O-])S(=O)(=O)[O-].[Na+].[Na+] JKRKEUQXIACMDT-UHFFFAOYSA-K 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Vynález ee týká apoeobu nehorlavej úpravy polyesterových vlákien a plošných materiálov, založený na tom, že ea na materiál povrchové upravený pleionomérnymi kopolyestermi kyseliny tereftálovej a 5-sulfoizoftálovej poaobí kvartérnymi nehořlavými přípravkami.The invention relates to an apoeobic flame retardant treatment of polyester fibers and sheet materials, based on the fact that the surface treated with pleionomeric copolyesters of terephthalic acid and 5-sulfoisophthalic is treated with quaternary flame retardants.
Doteraz používané impregnačně proatriedky pre nehořlavá úpravu textilných materiálov eú predovšetkým vhodné roztoky anorganických soli samotných, alebo vo vzájomných zmesiach. Významné aú najma amonné soli, kyselina boritá a niektoré jej zlúčeniny. Z amonných solí sa používajú amidoaulfonan amonný a stredný fosforečnan amonný, najčastejšie v kombinácii 8 močovinou, alebo so síranom amonným. Sálej je známa zmee kyseliny boritej a boraxu samotná, alebo a přísadou stredného fosforečnanu amonného.The impregnating agents hitherto used for the flame-retardant treatment of textile materials are in particular suitable solutions of inorganic salts alone or in mixtures with one another. Significant are especially ammonium salts, boric acid and some of its compounds. The ammonium salts used are ammonium amido sulfonate and ammonium phosphate, most often in combination with urea or ammonium sulfate. It is known to mix boric acid and borax alone, or with the addition of middle ammonium phosphate.
Zo skupiny organických zlúčenin sa používajú halogénové deriváty - bróm, chlór -, organofosforečné zlúčeniny, dusíkaté zlúčeniny, a to bu3 samotné alebo v synergických zmesiach.From the group of organic compounds, halogen derivatives - bromine, chlorine -, organophosphorus compounds, nitrogen compounds, are used alone or in synergistic mixtures.
V doterajšej praxi používané spósoby nehorlavej úpravy založené na prípravkoch, ktoré sa přidávájú do hmoty vlákna, negativna ovplyvňujú niektoré vlastnosti textilných materiálov: ťaánosí, belosť, špinivosť a eú ekonomicky neatraktivně. Najčastejšie používaný spósob nehorlavej úpravy založený na použití nehořlavých apretúr zhoršuje ohmat a úprava má poměrně malú stálosť pri praní.In practice, flame retardant treatments based on preparations that are added to the fiber mass negatively affect some properties of textile materials: dullness, whiteness, dirtiness and eu economically unattractive. The most commonly used non-flammable treatment method based on the use of non-flammable finishes worsens the feel and the treatment has a relatively low wash stability.
Uvedené nedostatky odstraňuje spósob podlá vynálezu, ktorého podstata je v tom, že saThe above-mentioned drawbacks are overcome by the method according to the invention, which is based on the fact that it
201 239201 239
Z01 239 na materiál upravený pleionomérnymi kopolyestermi kyseliny tereftálovej a 5-aulfoizoftáloveJ pósobí 4 % roztokom kvartérnych fosfóniovýeh zlúčenin, výhodná tetrakia/kyancentyl/foafónium bromidom, alebo tetrakia/hydroxymetyl/foafónium chloridom alebo etylén bia /tria/2-kyanoetyl/ foafónium bromidom, čím nastáva viazanie kvartérpeho katiónu na anión sulfoekupiny pleionoméru.Z01 239 to a material treated with pleionomeric copolyesters of terephthalic acid and 5-sulfoisophthalic acid is treated with a 4% solution of quaternary phosphonium compounds, preferably tetrakia / cyancentyl / phaphonium bromide, or tetrakia / hydroxymethyl / phaphonium bromide / triethylenium / triethylenebium / triethylenebia binding of the quaternary cation to the anion of the sulfo group of the pleionomer occurs.
Výhody navrhovaného sposobu nehoříavej úpravy polyesterových materiélov apočívajú v tom, že pri úpravě dochádza k chemickému viazaniu kattónového nehořlavého přípravku na aniónove upravený povrch polyesterového materiálu, čím aa dosiahne permanentnost úpravy bez zhoréenia lažnosti a bělosti, pri zachovaní dobrého ohmatu. Takto upravený materiál aa vyzná čuja i nižšou tvorbou statického náboje a Íaháím vypráním ňpiny pri pracom procese.The advantages of the proposed method of non-flammable treatment of polyester materials are that the treatment involves chemical bonding of the kattone non-combustible composition to the anionically treated surface of the polyester material, thereby achieving durability of treatment without compromising laziness and whiteness while maintaining good feel. The treated material aa is characterized by a lower static charge and by washing the dirt in the washing process.
V óaláom je tento spoaob úpravy doložený príkladmi prevedenia bas toho, že by aa lan na tieto typy výlučné vztahoval.In óaáa, this type of adjustment is exemplified by examples of bass making that aa lan solely apply to these types.
Příklad 1Example 1
Dimetylteraftalát a 5 mól. % aodnej soli bis/hydroxyetyl/-5-aulfoizoftálovej kyseliny a etylénglykol aa kondenzujú pri teplote 204 °C 135 min v přítomnosti octanu zinočnatého ako katalyzátore. Získaný produkt mal teplotu topenia 67,8 °C a limitné viskozitné číslo 5,72 ml/g. Produkt ea dispergoval vo voda a z disperzie sa naniesol na fularda na polyesterová tkaninu v množstva 4 % hmotnosti materiálu. Tkanina aa vyauSila pri teplota 90 °C počas 30 minút a potom aa ustálila pri teplote 150 °C 3 minúty. fialej aa tkanina impregnovala 4 % roztokom tetrakia/kyanoatyl/fosfónium bromidu počaa 10 min pri teplote miestnosti. Potom sa tkanina vyprala.Dimethyl terephthalate and 5 mol. % of the bis (hydroxyethyl) -5-sulfoisophthalic acid sodium salt and ethylene glycol a and condensed at 204 ° C for 135 min in the presence of zinc acetate catalyst. The product obtained had a melting point of 67.8 ° C and a viscosity limit of 5.72 ml / g. The product ea was dispersed in water and from the dispersion was applied to the fulards on a polyester fabric in an amount of 4% by weight of the material. Fabric aa burst at 90 ° C for 30 minutes and then aa settled at 150 ° C for 3 minutes. purple and the fabric was impregnated with 4% tetrakia / cyanoatyl / phosphonium bromide solution for 10 min at room temperature. The fabric was then washed.
Nehořlavost materiálu sa hodnotila na základe etanovenia limitných kyslíkových čísial. Limitné kyslíkové číslo upraveného materiálu bolo 27,8 v porovnaní a hodnotou 20,6 pra ne* upravený materiál. Súčasne aa znížila hodnota povrchového potenciálu z 2,6 kV na 0,3 kV. Hodnota L01 po 30 pracích cykloch bola 25,2 a po piatych cykloch chemického čistenia 26,8.The non-flammability of the material was evaluated by determining the limit oxygen numbers. The cut-off oxygen number of the treated material was 27.8 compared to 20.6 for the treated material. At the same time, aa decreased the surface potential from 2.6 kV to 0.3 kV. The L01 value after 30 wash cycles was 25.2 and after the fifth dry cleaning cycles was 26.8.
Příklad 2Example 2
Postup ako v příklade 1, ale s tým, že ne aniónovú úpravu povrchu aa použije přípravek s obsahom 20 mól % aodnej soli hydroxyetyl-5-sulfoizoftálovej kyseliny. Teplota várky produktu je 213 °C. Získaný produkt má teplotu topenia 102,9 °C a limitné viskozitné číslo 7,07 ml/g. Tkanina sa impregnovala 4 iá-ným roztokom tetrakiahydroxymetyl foafónium chloridom.Procedure as in Example 1, but with the nonionic treatment of the surface aa using a preparation containing 20 mol% of hydroxyethyl 5-sulfoisophthalic acid sodium salt. The batch temperature of the product is 213 ° C. The product obtained has a melting point of 102.9 ° C and a viscosity limit of 7.07 ml / g. The fabric was impregnated with a 4% solution of tetrakiahydroxymethyl foaphonium chloride.
Týmto postupom upravená tkanina mala limitné kyslíkové číslo 29,2 v porovnaní a hodnotou 20,6 pre neupravená tkaninu. Elektrický povrchový potenciál aa znížil z hodnoty .2,6 kV na hodnotu 0,8 kV.This fabric treated fabric had an oxygen limit of 29.2 compared to 20.6 for the untreated fabric. The electric surface potential aa decreased from .2 kV to 0.8 kV.
Příklad 3Example 3
Postup ako v příklade 1 β tým, že sa na aniónovú úpravu povrchu použije prípravok β obsahom 15 mól % sodnéJ soli hydroxyetyl-5-aulfoizoftálovej kyseliny. Tkanina aa impregnuje 4 % roztokom etylén bia /tria/2-kyanoetyl//foafónium bromidu.Procedure as in Example 1 β by using β preparation of 15 mole% sodium hydroxyethyl-5-sulfoisophthalic acid for anionic surface treatment. Fabric aa was impregnated with a 4% ethylene-bia / tria / 2-cyanoethyl / phosphonium bromide solution.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS329978A CS201239B3 (en) | 1978-05-22 | 1978-05-22 | Method of flameproof finish of polyester fibres or webs |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS329978A CS201239B3 (en) | 1978-05-22 | 1978-05-22 | Method of flameproof finish of polyester fibres or webs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS201239B3 true CS201239B3 (en) | 1980-10-31 |
Family
ID=5372623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS329978A CS201239B3 (en) | 1978-05-22 | 1978-05-22 | Method of flameproof finish of polyester fibres or webs |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS201239B3 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4702857A (en) * | 1984-12-21 | 1987-10-27 | The Procter & Gamble Company | Block polyesters and like compounds useful as soil release agents in detergent compositions |
-
1978
- 1978-05-22 CS CS329978A patent/CS201239B3/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4702857A (en) * | 1984-12-21 | 1987-10-27 | The Procter & Gamble Company | Block polyesters and like compounds useful as soil release agents in detergent compositions |
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