CO6400134A2 - Proceso de amoximación - Google Patents

Proceso de amoximación

Info

Publication number
CO6400134A2
CO6400134A2 CO11083876A CO11083876A CO6400134A2 CO 6400134 A2 CO6400134 A2 CO 6400134A2 CO 11083876 A CO11083876 A CO 11083876A CO 11083876 A CO11083876 A CO 11083876A CO 6400134 A2 CO6400134 A2 CO 6400134A2
Authority
CO
Colombia
Prior art keywords
redox
catalyst
amoximation
metal atom
atoms
Prior art date
Application number
CO11083876A
Other languages
English (en)
Inventor
Robert Raja
Alexander James Paterson
Original Assignee
Univ Southampton
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Southampton filed Critical Univ Southampton
Publication of CO6400134A2 publication Critical patent/CO6400134A2/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/065—Aluminophosphates containing other elements, e.g. metals, boron the other elements being metals only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
    • C07C249/08—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes by reaction of hydroxylamines with carbonyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Se describe un proceso de amoximación redox en el cual una cetona o aldehído reacciona con amoniaco yoxígeno en presencia de un catalizador, en donde: el catalizador es un catalizador redox a base de aluminofosfato que tiene la fórmula general cualitativa (I) M1M2AlPO-5 (I) en la cual M1 es al menos un átomo de metal de transición que tiene la capacidad catalítica redox; M2 es al menos un átomo de metal en el estado de oxidación (IV) ; M1 y M2 son diferentes entre sí; y una proporción de los átomos de fósforo de la estructura tipo M1M2AIPO-5 es sustituida por átomos de M2.
CO11083876A 2009-01-07 2011-07-06 Proceso de amoximación CO6400134A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0900198.3A GB0900198D0 (en) 2009-01-07 2009-01-07 Ammoximation process

Publications (1)

Publication Number Publication Date
CO6400134A2 true CO6400134A2 (es) 2012-03-15

Family

ID=40379264

Family Applications (1)

Application Number Title Priority Date Filing Date
CO11083876A CO6400134A2 (es) 2009-01-07 2011-07-06 Proceso de amoximación

Country Status (12)

Country Link
US (2) US8444917B2 (es)
EP (1) EP2373614A1 (es)
JP (1) JP2012514628A (es)
KR (1) KR20110134874A (es)
CN (1) CN102227404B (es)
BR (1) BRPI1005523A2 (es)
CO (1) CO6400134A2 (es)
GB (1) GB0900198D0 (es)
MX (1) MX2011004942A (es)
RU (1) RU2532163C2 (es)
SA (1) SA110310039B1 (es)
WO (1) WO2010079324A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8772476B2 (en) 2011-10-28 2014-07-08 Honeywell International Inc. Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams
US20220040666A1 (en) * 2020-08-10 2022-02-10 Arizona Board Of Regents On Behalf Of Arizona State University Material to separate and pump oxygen
CN116393163B (zh) * 2023-03-27 2024-05-24 湖北兴发化工集团股份有限公司 用于环己酮肟一步法合成6-氨基己腈的组合型催化剂及其制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4801364A (en) 1983-07-15 1989-01-31 Uop Separation and conversion processes using metal aluminophosphates
US4567029A (en) 1983-07-15 1986-01-28 Union Carbide Corporation Crystalline metal aluminophosphates
US4793984A (en) * 1984-04-13 1988-12-27 Union Carbide Corporation Molecular sieve compositions
US4917876A (en) 1984-04-13 1990-04-17 Uop Iron-titanium-aluminum-phosphorus-oxide molecular sieve compositions
US4956165A (en) 1984-04-13 1990-09-11 Uop Molecular sieve compositions
IT1222171B (it) 1987-07-29 1990-09-05 Montedipe Spa Processo per la produzione di chetossime
NO318680B1 (no) * 2001-11-07 2005-04-25 Polymers Holding As Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav
AU2003297832A1 (en) 2002-12-09 2004-06-30 Medtronic Vascular Modular stent having polymer bridges at modular unit contact sites
SG123723A1 (en) 2004-12-22 2006-07-26 Sumitomo Chemical Co Process for producing cyclohexanone oxime
GB2450711A (en) 2007-07-03 2009-01-07 Univ Southampton An aluminophosphate based redox catalyst

Also Published As

Publication number Publication date
RU2532163C2 (ru) 2014-10-27
MX2011004942A (es) 2011-06-16
US20110257390A1 (en) 2011-10-20
KR20110134874A (ko) 2011-12-15
EP2373614A1 (en) 2011-10-12
US20130245322A1 (en) 2013-09-19
CN102227404B (zh) 2014-03-26
GB0900198D0 (en) 2009-02-11
CN102227404A (zh) 2011-10-26
JP2012514628A (ja) 2012-06-28
RU2011133043A (ru) 2013-02-20
WO2010079324A1 (en) 2010-07-15
BRPI1005523A2 (pt) 2019-09-24
US8444917B2 (en) 2013-05-21
US8779124B2 (en) 2014-07-15
SA110310039B1 (ar) 2013-11-04

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