CO5210976A1 - METHOD FOR REDUCING THE VISCOCITY OF HEAVY CRUDE OILS - Google Patents
METHOD FOR REDUCING THE VISCOCITY OF HEAVY CRUDE OILSInfo
- Publication number
- CO5210976A1 CO5210976A1 CO00012704A CO00012704A CO5210976A1 CO 5210976 A1 CO5210976 A1 CO 5210976A1 CO 00012704 A CO00012704 A CO 00012704A CO 00012704 A CO00012704 A CO 00012704A CO 5210976 A1 CO5210976 A1 CO 5210976A1
- Authority
- CO
- Colombia
- Prior art keywords
- formation
- amine
- acids
- group
- chelating agent
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000010779 crude oil Substances 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 2
- 239000002738 chelating agent Substances 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 abstract 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000005594 diketone group Chemical group 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 150000002678 macrocyclic compounds Chemical class 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 150000003009 phosphonic acids Chemical class 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- -1 saturated aliphatic secondary amines Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
- C10L1/2493—Organic compounds containing sulfur, selenium and/or tellurium compounds of uncertain formula; reactions of organic compounds (hydrocarbons, acids, esters) with sulfur or sulfur containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2691—Compounds of uncertain formula; reaction of organic compounds (hydrocarbons acids, esters) with Px Sy, Px Sy Halz or sulfur and phosphorus containing compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17D—PIPE-LINE SYSTEMS; PIPE-LINES
- F17D1/00—Pipe-line systems
- F17D1/08—Pipe-line systems for liquids or viscous products
- F17D1/16—Facilitating the conveyance of liquids or effecting the conveyance of viscous products by modification of their viscosity
- F17D1/17—Facilitating the conveyance of liquids or effecting the conveyance of viscous products by modification of their viscosity by mixing with another liquid, i.e. diluting
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fats And Perfumes (AREA)
Abstract
Nuevos complejos amina-quelato caracterizados porque se forman por calentamiento conjunto de por lo menos una amina orgánica con por lo menos un agente quelante, en donde la amina orgánica se selecciona del grupo conformado por: monoaminas primarias alifáticas (C1-C40); polialquilaminas; monoaminas terciarias, aminas secundarias alifáticas saturadas ó sustancialmente saturadas (C1-C40); y poliaminas seleccionadas entre alcanos de cadena recta ó ramificada que contienen dos o más grupos amino, por lo menos uno de los cuales es un grupo amino primario, y en donde el agente quelante se selecciona del grupo conformado por: ácidos carboxílicos, ácidos aminocarboxílicos; ácidos fosfónicos; polifosfatos; 1,3 dicetonas; fenoles; aminofenoles; oximas; compuestos que contienen azufre; compuestos macrocíclicos; ácidos policarboxílicos; oligómeros del ácido acrílico con terminales insaturadas; otros compuestos poliméricos; y las sales de los anteriores, según sea apropiado. Un método para la extracción de petróleo crudo pesado de una formación petrolífera que tiene por lo menos un orificio de pozo que penetra dicha formación y en comunicación fluida con ésta, método que comprende los pasos de:(a) inyección dentro del pozo y formación de una cantidad de un complejo amina-quelato reductor de la viscosidad acorde con la Reivindicación 1;(b) permitir que el complejo amina-quelato se disperse dentro de la formación; y(c) extracción del petróleo con viscosidad reducida.New amine-chelate complexes characterized in that they are formed by joint heating of at least one organic amine with at least one chelating agent, wherein the organic amine is selected from the group consisting of: aliphatic primary monoamines (C1-C40); polyalkylamines; tertiary monoamines, saturated or substantially saturated aliphatic secondary amines (C1-C40); and polyamines selected from straight or branched chain alkanes containing two or more amino groups, at least one of which is a primary amino group, and wherein the chelating agent is selected from the group consisting of: carboxylic acids, aminocarboxylic acids; phosphonic acids; polyphosphates; 1.3 diketones; phenols; aminophenols; oximes; sulfur-containing compounds; macrocyclic compounds; polycarboxylic acids; acrylic acid oligomers with unsaturated terminals; other polymeric compounds; and the salts of the foregoing, as appropriate. A method for extracting heavy crude oil from an oil formation that has at least one well hole that penetrates said formation and in fluid communication with it, a method comprising the steps of: (a) injection into the well and formation of an amount of a viscosity reducing amine-chelate complex according to claim 1; (b) allowing the amine-chelate complex to be dispersed within the formation; and (c) oil extraction with reduced viscosity.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12249699P | 1999-03-02 | 1999-03-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
CO5210976A1 true CO5210976A1 (en) | 2002-10-30 |
Family
ID=22403038
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CO00012704A CO5210976A1 (en) | 1999-03-02 | 2000-02-23 | METHOD FOR REDUCING THE VISCOCITY OF HEAVY CRUDE OILS |
Country Status (7)
Country | Link |
---|---|
US (1) | US6402934B1 (en) |
EP (1) | EP1033471B1 (en) |
CN (1) | CN1205404C (en) |
CA (1) | CA2299104C (en) |
CO (1) | CO5210976A1 (en) |
MX (1) | MXPA00001955A (en) |
NO (1) | NO326829B1 (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040232044A1 (en) * | 2003-05-23 | 2004-11-25 | Ravindranath Mukkamala | Oil-soluble imine-acid reaction products as asphaltene dispersants in crude oil |
US20040232042A1 (en) * | 2003-05-23 | 2004-11-25 | Ravindranath Mukkamala | Amine-acid reaction products as asphaltene dispersants in crude oil |
US7097759B2 (en) * | 2003-05-23 | 2006-08-29 | Rohm And Haas Company | Carbonyl, thiocarbonyl or imine containing compounds as asphaltene dispersants in crude oil |
US7122112B2 (en) * | 2003-05-29 | 2006-10-17 | Rohm And Haas Company | Compounds containing amide and carboxyl groups as asphaltene dispersants in crude oil |
US7435333B2 (en) * | 2004-07-02 | 2008-10-14 | Exxonmobil Research And Engineering Company | Upgrading asphaltene containing oils |
US7674365B2 (en) | 2004-10-07 | 2010-03-09 | Rohm And Haas Company | Formulations useful as asphaltene dispersants in petroleum products |
CA2568764A1 (en) * | 2005-12-07 | 2007-06-07 | Rohm And Haas Company | Asphaltene dispersants for petroleum products |
PL2069467T3 (en) | 2006-10-06 | 2015-02-27 | Vary Petrochem Llc | Separating compositions and methods of use |
US8062512B2 (en) * | 2006-10-06 | 2011-11-22 | Vary Petrochem, Llc | Processes for bitumen separation |
US7758746B2 (en) | 2006-10-06 | 2010-07-20 | Vary Petrochem, Llc | Separating compositions and methods of use |
US8394872B2 (en) | 2009-07-10 | 2013-03-12 | Nalco Company | Method of reducing the viscosity of hydrocarbon fluids |
WO2011031920A2 (en) | 2009-09-10 | 2011-03-17 | Board Of Regents, The University Of Texas System | Process of using hard brine at high alkalinity for enhanced oil recovery (eor) applications |
US9315715B2 (en) | 2009-10-20 | 2016-04-19 | Nalco Company | Method of reducing the viscosity of hydrocarbons |
AR081549A1 (en) * | 2010-05-25 | 2012-10-03 | Univ Texas | FORMULATIONS OF ALKALINE POLYMERS WITHOUT SURFACTANT TO RECOVER REACTIVE CRUDE OIL |
CN103422841B (en) * | 2012-05-17 | 2017-04-26 | 中国石油化工股份有限公司 | Viscosity reduction method and viscosity reducer for viscous oil |
US20140323369A1 (en) * | 2013-04-24 | 2014-10-30 | Upali P. Weerasooriya | Use of amines in heavy oil transport |
GB2542080B (en) * | 2014-09-30 | 2021-08-04 | Halliburton Energy Services Inc | Non-reducing stabilization complexant for acidizing compositions and associated methods |
US10125306B2 (en) | 2014-10-02 | 2018-11-13 | Croda, Inc. | Asphaltene inhibition |
CN105214557A (en) * | 2015-10-28 | 2016-01-06 | 北京工商大学 | A kind of N-alkyl aminopropionic acid type Gemini surface active agent and method for making |
US10407611B2 (en) | 2016-01-08 | 2019-09-10 | Ecolab Usa Inc. | Heavy oil rheology modifiers for flow improvement during production and transportation operations |
EP3475384A1 (en) | 2016-06-24 | 2019-05-01 | Croda, Inc. | Method and compositon for asphaltene dispersion |
MX2020000139A (en) | 2017-07-06 | 2020-07-22 | Innospec Oil Field Chemicals Llc | Compositions and methods and uses relating thereto. |
CN113509960B (en) * | 2021-03-29 | 2023-10-31 | 中国石油天然气股份有限公司 | Application of crown ether transition metal complex in underground in-situ modification of thickened oil and underground in-situ modification method of thickened oil |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3964548A (en) | 1975-03-27 | 1976-06-22 | Marathon Oil Company | Method for oil recovery by flooding with micellar dispersions containing crude oil sulfonates |
US4026870A (en) * | 1976-01-21 | 1977-05-31 | General Electric Company | Extraction of copper catalyst from polyphenylene oxide solutions |
US4192755A (en) | 1976-03-08 | 1980-03-11 | Texaco Inc. | Process for recovering hydrocarbons from a hydrocarbon-bearing formation |
US4407367A (en) | 1978-12-28 | 1983-10-04 | Hri, Inc. | Method for in situ recovery of heavy crude oils and tars by hydrocarbon vapor injection |
US4687586A (en) | 1981-06-19 | 1987-08-18 | Marathon Oil Company | Oil recovery process and system |
US4425246A (en) | 1981-09-18 | 1984-01-10 | Exxon Research & Engineering Co. | Oil recovery using stabilized saline heat-treated heteropolysaccharide solutions |
US4769160A (en) | 1986-07-31 | 1988-09-06 | Ciba-Geigy Corporation | Use of organic fluorochemical compounds with oleophobic and hydrophobic groups in asphaltenic crude oils as viscosity reducing agents |
US4938876A (en) * | 1989-03-02 | 1990-07-03 | Ohsol Ernest O | Method for separating oil and water emulsions |
US5190656A (en) * | 1989-04-03 | 1993-03-02 | Mobil Oil Corporation | Method for removing scale via a liquid membrane in combination with an amino carboxylic acid and a catalyst |
JP2776953B2 (en) * | 1990-04-10 | 1998-07-16 | 日本メジフィジックス株式会社 | Multifunctional metal chelate compounds and their uses |
US5143156A (en) | 1990-09-27 | 1992-09-01 | Union Oil Company Of California | Enhanced oil recovery using organic vapors |
US5271863A (en) * | 1992-02-26 | 1993-12-21 | Betz Laboratories, Inc. | Compositions for extracting iron species from liquid hydrocarbon systems |
DE19709797A1 (en) * | 1997-03-10 | 1998-09-17 | Clariant Gmbh | Synergistic mixtures of alkylphenol formaldehyde resins with oxalkylated amines as asphaltene dispersants |
US6239183B1 (en) * | 1997-12-19 | 2001-05-29 | Akzo Nobel Nv | Method for controlling the rheology of an aqueous fluid and gelling agent therefor |
-
2000
- 2000-02-21 EP EP00301332A patent/EP1033471B1/en not_active Expired - Lifetime
- 2000-02-22 CA CA002299104A patent/CA2299104C/en not_active Expired - Lifetime
- 2000-02-23 CO CO00012704A patent/CO5210976A1/en active IP Right Grant
- 2000-02-24 NO NO20000903A patent/NO326829B1/en not_active IP Right Cessation
- 2000-02-24 MX MXPA00001955A patent/MXPA00001955A/en active IP Right Grant
- 2000-02-28 US US09/514,462 patent/US6402934B1/en not_active Expired - Lifetime
- 2000-03-02 CN CN00103678.5A patent/CN1205404C/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CN1265446A (en) | 2000-09-06 |
NO20000903D0 (en) | 2000-02-24 |
US6402934B1 (en) | 2002-06-11 |
CA2299104A1 (en) | 2000-09-02 |
NO326829B1 (en) | 2009-02-23 |
NO20000903L (en) | 2000-09-04 |
EP1033471A1 (en) | 2000-09-06 |
CN1205404C (en) | 2005-06-08 |
CA2299104C (en) | 2004-05-04 |
MXPA00001955A (en) | 2002-03-08 |
EP1033471B1 (en) | 2003-09-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Application granted |