CO5160333A1 - TETRAZINE DERIVATIVES PESTICIDLY ACTIVE AND COMPOSITION THAT CONTAINS THEM - Google Patents

TETRAZINE DERIVATIVES PESTICIDLY ACTIVE AND COMPOSITION THAT CONTAINS THEM

Info

Publication number
CO5160333A1
CO5160333A1 CO00044621A CO00044621A CO5160333A1 CO 5160333 A1 CO5160333 A1 CO 5160333A1 CO 00044621 A CO00044621 A CO 00044621A CO 00044621 A CO00044621 A CO 00044621A CO 5160333 A1 CO5160333 A1 CO 5160333A1
Authority
CO
Colombia
Prior art keywords
carbon atoms
alkyl
haloalkyl
cycloalkyl
alkylene
Prior art date
Application number
CO00044621A
Other languages
Spanish (es)
Inventor
Werner Zambach
Rudolf Naef
Trah Sthepan
Andre Jeanguenat
Martin Erbele
Arthur Steiger
Original Assignee
Novartis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novartis Ag filed Critical Novartis Ag
Publication of CO5160333A1 publication Critical patent/CO5160333A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D257/00Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
    • C07D257/02Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D257/08Six-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

La presente invención se refiere a compuestos de la fórmula general:<EMI FILE="00044621_1" ID="1" IMF=JPEG >en donde:T-V es -N=N- ó -NH-NH-; X1 es R1;X2 y X3 son cada uno independientemente del otro, H ó R1;R1 es, por ejemplo, halógeno, CN, NO2, alquilo de 1 a 6 átomos de carbono, cicloalquilo de 3 a 8 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, halocicloalquilo de 3 a 8 átomos de carbono, alcoxilo de 1 a 6 átomos de carbono, cicloalcoxilo de 3 a 8 átomos de carbono, o haloalcoxilo de 1 a 6 átomos de carbono;Ar1 es arilo o heteroarilo insustituido o mono- a tetra-sustituido;Ar2 es arilo o heteroarilo insustituido o mono- a penta-sustituido;A es un solo enlace, alquileno de 1 a 12 átomos de carbono, O, O(alquileno de 1 a 12 átomos de carbono), S(O)n, S(O)n(alquileno de 1 a 12 átomos de carbono), alquenileno de 2 a 8 átomos de carbono,alquinileno de 2 a 8 átomos de carbono; NR6, NR6(alquileno de 1 a 12 átomos de carbono), ó C(=Z); Z es O, NR4, NNR4R5 ó NOR4;R2 es H, alquilo de 1 a 6 átomos de carbono, o cicloalquilo de 3 a 8 átomos de carbono; R4 y R5 son cada uno independientemente del otro, H, alquilo de 1 a 6 átomos de carbono, o haloalquilo de 1 a 6 átomos de carbono;R6 es H, alquilo de 1 a 6 átomos de carbono, cicloalquilo de 3 a 8 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, alquenilo de 2 a 8 átomos de carbono, alquinilo de 2 a 8 átomos de carbono, arilalquilo de 1 a 6 átomos de carbono, (CH2)pC(0)R7 ó alcoxilo de 1 a 6 átomos de carbono-alquilo de 2 a 6 .átomos de carbono;R7 es H, alquilo de 1 a 6 átomos de carbono, cicloalquilo de 3 a 8 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, alcoxilo de 1 a 6 átomos de carbono, N(R8)2, ó alcoxilo de 1 a 6 átomos de carbono-alquilo de 2 a 6 átomos de carbono;R8 es H, alquilo de 1 a 6 átomos de carbono, cicloalquilo de 3 a 8 átomos de carbono, haloalquilo de 1 a 6 átomos de carbono, o arilalquilo de 1 a 6 átomos de carbono;n es 0, 1, ó 2;The present invention relates to compounds of the general formula: <EMI FILE = "00044621_1" ID = "1" MFI = JPEG> wherein: T-V is -N = N- or -NH-NH-; X1 is R1; X2 and X3 are each independently of each other, H or R1; R1 is, for example, halogen, CN, NO2, alkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, haloalkyl of 1 to 6 carbon atoms, halocycloalkyl of 3 to 8 carbon atoms, alkoxy of 1 to 6 carbon atoms, cycloalkoxy of 3 to 8 carbon atoms, or haloalkoxy of 1 to 6 carbon atoms; Ar1 is unsubstituted aryl or heteroaryl or mono- to tetra-substituted; Ar2 is unsubstituted aryl or heteroaryl or mono- to penta-substituted; A is a single bond, alkylene of 1 to 12 carbon atoms, O, O (alkylene of 1 to 12 carbon atoms) , S (O) n, S (O) n (alkylene of 1 to 12 carbon atoms), alkenylene of 2 to 8 carbon atoms, alkynylene of 2 to 8 carbon atoms; NR6, NR6 (alkylene of 1 to 12 carbon atoms), or C (= Z); Z is O, NR4, NNR4R5 or NOR4; R2 is H, alkyl of 1 to 6 carbon atoms, or cycloalkyl of 3 to 8 carbon atoms; R4 and R5 are each independently of each other, H, alkyl of 1 to 6 carbon atoms, or haloalkyl of 1 to 6 carbon atoms; R6 is H, alkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 8 atoms carbon, haloalkyl of 1 to 6 carbon atoms, alkenyl of 2 to 8 carbon atoms, alkynyl of 2 to 8 carbon atoms, arylalkyl of 1 to 6 carbon atoms, (CH2) pC (0) R7 or alkoxy of 1 to 6 carbon atoms-alkyl of 2 to 6 carbon atoms; R7 is H, alkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, haloalkyl of 1 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms, N (R8) 2, or alkoxy of 1 to 6 carbon atoms-alkyl of 2 to 6 carbon atoms; R8 is H, alkyl of 1 to 6 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, haloalkyl of 1 to 6 carbon atoms, or arylalkyl of 1 to 6 carbon atoms, n is 0, 1, or 2;

CO00044621A 1999-06-21 2000-06-15 TETRAZINE DERIVATIVES PESTICIDLY ACTIVE AND COMPOSITION THAT CONTAINS THEM CO5160333A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH114899 1999-06-21

Publications (1)

Publication Number Publication Date
CO5160333A1 true CO5160333A1 (en) 2002-05-30

Family

ID=4203614

Family Applications (1)

Application Number Title Priority Date Filing Date
CO00044621A CO5160333A1 (en) 1999-06-21 2000-06-15 TETRAZINE DERIVATIVES PESTICIDLY ACTIVE AND COMPOSITION THAT CONTAINS THEM

Country Status (6)

Country Link
EP (1) EP1187818A1 (en)
JP (1) JP2003502413A (en)
AU (1) AU5405600A (en)
CO (1) CO5160333A1 (en)
EG (1) EG22089A (en)
WO (1) WO2000078739A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103300040B (en) * 2012-03-10 2015-11-25 陕西韦尔奇作物保护有限公司 A kind of Efficient insecticidal composition
CN102702122B (en) * 2012-05-16 2014-05-14 南通大学 Method for preparing tetrazine by oxidizing dihydro tetrazine
CN105037329B (en) * 2015-09-06 2017-03-22 青岛科技大学 Fluorine-containing tetrazine pyrazol acaricide
CN105061399B (en) * 2015-09-06 2017-03-22 青岛科技大学 Fluorine-containing tetrazine pyridine compounds and application thereof
CN105130962B (en) * 2015-09-06 2017-09-26 浙江博仕达作物科技有限公司 A kind of tetrazine pyrazoles acaricide
EP3483142A1 (en) 2016-07-05 2019-05-15 Guangzhou Maxinovel Pharmaceuticals Co., Ltd. Aromatic acetylene or aromatic ethylene compound, intermediate, preparation method, pharmaceutical composition and use thereof
EP3733659B1 (en) 2017-12-29 2023-12-20 Guangzhou Maxinovel Pharmaceuticals Co., Ltd. Aromatic vinyl or aromatic ethyl derivative, preparation method therefor, intermediate, pharmaceutical composition, and application

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0005912B1 (en) * 1978-05-25 1982-07-14 Fbc Limited Acaricidal, larvicidal and ovicidal tetrazine derivatives and compositions, processes for their preparation and methods of using them
EP0029657A3 (en) * 1979-11-16 1981-08-26 Fbc Limited Pesticidal tetrazines, their use and compositions, processes for their preparation and preparation intermediates
DE3173083D1 (en) * 1980-03-22 1986-01-16 Fbc Ltd Pesticidal heterocyclic compounds, processes for preparing them, compositions containing them, and their use
HU212613B (en) * 1993-07-21 1996-09-30 Chinoin Gyogyszer Es Vegyeszet Tetrazine-derivatives, process for production of the compounds, acaricidal,larvicidal and ovicidal compositions containing the compounds as active ingredient and process for their production and their use

Also Published As

Publication number Publication date
EG22089A (en) 2002-07-31
AU5405600A (en) 2001-01-09
JP2003502413A (en) 2003-01-21
EP1187818A1 (en) 2002-03-20
WO2000078739A1 (en) 2000-12-28

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