CN86102420A - The method of carboxylic acid alcohols production by hydrogenation - Google Patents
The method of carboxylic acid alcohols production by hydrogenation Download PDFInfo
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- CN86102420A CN86102420A CN86102420.6A CN86102420A CN86102420A CN 86102420 A CN86102420 A CN 86102420A CN 86102420 A CN86102420 A CN 86102420A CN 86102420 A CN86102420 A CN 86102420A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
Preparing ethanol or prepare the method for propyl alcohol from propionic acid from acetic acid, is under catalyzer exists and heats up, and makes acetic acid or propionic acid and hydrogen carry out gas phase under the 1-150 bar pressure and contacts.This catalyzer comprises precious metal and (II) rhenium of VIII family in its basal component (I) periodic table of elements.These basal components are loaded on a kind of carrier, as are loaded on the graphitized charcoal on high surface.
Description
The present invention relates to the hydrogenation of carboxylic acid.More particularly, the present invention relates in the presence of the catalyzer of containing element periodictable VIII family's precious metal and rhenium, with acetic acid and propionic acid respectively hydrogenation be the method for ethanol and propyl alcohol.
Using by the VIII family noble metal catalyst that carries, is that corresponding alcohol is from for example USP-A-4524225 with carboxylic acid hydrogenation; USP-A-4104478; GB-A-1534232; GB-A-155174 and EP-A-147219 and know.Above-mentioned patent all relates to C except that GB-A-1534232
4The hydrogenation , And of higher carboxylic acid and the same with GB-A-1534232 all be in liquid phase, to react.In addition, be disclosed after the priority date that the application requires owing to the EP-A-147219 of more Zao priority date is arranged than the application, therefore, EP-A-147219 is a publication in the middle of.
GP-A-1534232 relates to heating up and add and depressing, and in the presence of water and/or other solvent, the palladium rhenium catalyst catalyzed oxidation carboxylic acid (comprising acetate and propionic acid) that is used on the carrier is produced pure.The weight ratio of palladium and rhenium is 0.01-5 in the catalyzer: 1.The reaction pressure scope is a 50-1000 normal atmosphere.Its unique method that exemplifies is C under very high pressure
4The hydrogenation of higher diprotic acid.
We have found that in liquid phase and to use VIII family noble metal catalyst that such shortcoming is arranged, that is, rhenium and VIII family precious metal from catalyzer by lixiviate.Not only undesirable oxidiferous carrier also can be taken place by lixiviate by lixiviate in catalytic metal.We are surprised to find that, use above-mentioned catalyzer to compare with previously used method in gas phase, catalytic activity height under low pressure, and the good life-span of selectivity is also long.And reaction has overcome the lixiviate problem relevant with liquid phase reaction basically in gas phase.
Therefore, the invention provides a kind of from the acetic acid production ethanol or the method for producing propyl alcohol from propionic acid, this method comprises, under intensification and 1-150 bar pressure, in main component is in the presence of the catalyzer of the precious metal of (1) a kind of periodic table of elements VIII family and (II) rhenium, and steaming gasiform acetic acid or propionic acid contact with hydrogen.
Except alcohol, method of the present invention produces by product one corresponding ester usually, and for example, acetic acid hydrogenation generally also produces vinyl acetic monomer, and propionic acid hydrogenation generally also produces propyl propionate.If desired, the ratio of ester can increase in the product, by the operation of for example low-conversion, as the transformation efficiency of per pass less than 50%, perhaps by introduce acid in the catalyzer to promote " on the spot " esterification.On the other hand, the ratio of alcohol can increase, for example by supplying water altogether or operating under the high conversion of per pass.
Acetic acid and propionic acid all can have been bought form that , And obtains on can its market in large quantities from the market and not add and be not used for method of the present invention with purifying.If necessary, can further purify.
Hydrogen more can have been bought on a large scale from the market, can purify or use without purification.
Catalyzer comprises the precious metal and the second composition-rhenium of first composition-a kind of VIII family.For fear of suspection, can point out that VIII family precious metal is osmium, palladium, platinum, rhodium, ruthenium and iridium.As mentioned above, group VIII metal, palladium and ruthenium are best.
This catalyzer preferably also comprises a kind of carrier.Suitable carrier comprises the graphitized charcoal of high surface area, graphite, and silica gel, alumina and silica gel/alumina, wherein the graphitized carbon of high surface area and silica gel are best.Best silica-gel carrier is the high silica gel of surface-area, and typical silica gel specific surface is greater than 50m
2/ g.
Good especially carrier is at GB-A-2136704(BP Case NO.5536) described in the graphitized carbon of high surface area.Best charcoal is the particulate state charcoal, for example the grain charcoal.The size of carbon granule depends on the allowable pressure drop (providing the smallest particles size) of any given reactor and the diffusion constant (providing maximum carbon granule size) of reagent in carbon granule.Minimum carbon granule size is preferably 0.5mm and maximum carbon granule size is preferably 10mm, for example not quite greater than 5mm.
This charcoal is porous charcoal preferably.Requiring this carbon granule when requiring best carbon granule size is porous, can satisfy best surface-area characteristic like this.
This charcoal can be by their BET, and bottom surface is long-pending and edge surface is long-pending characterizes.The BET surface-area is to use Brunauer Emmett and Teller at J.Am.Chem.Soc.60, and 309(1938) method in is by the surface-area of nitrogen absorption measurement.Bottom surface is long-pending to be to see P489 for details with Proc.Poy.Soc A314 P473-498() described method, by the surface-area of the heat of adsorption mensuration of laccerane from normal heptane on charcoal.Edge surface is long-pending to be to be used in Proc.Roy.Soc(to see P495 for details) described method, by the surface-area of the heat of adsorption mensuration of normal butane from normal heptane on charcoal.
The BET surface-area of used charcoal is at least 100m among the present invention
2/ g is preferably 200m at least
2/ g, best is 300m at least
2/ g.The BET surface-area is not more than 1000m
2/ g is not more than 750m for well
2/ g is better.
BET surface-area and floorage than being not more than 4: 1 for good, be not more than 2.5: 1 better, this ratio preferably is not more than 1.5: 1.
The bottom surface of used carbon granule long-pending with edge surface long-pending than be at least 10: 1 for good, preferably at least 100: 1.Although this ratio does not have the upper limit, but, be no more than 200: 1 in fact usually.
Best charcoal carrier can contain the charcoal starting material by thermal treatment and prepare.Said starting material can be a kind of oleophylic graphites, and the preparation method described in GB1168785 perhaps can be a carbon ink.
Yet oleophylic graphite contains flaky very thin grain charcoal, is unsuitable for doing support of the catalyst.We preferably avoid using this charcoal.Similarly consider to be equally applicable to the carbon black of fine particle.
Best starting material are the gacs from vegetable material, as the cocoanut charcoal or the peat composed of rotten mosses, but perhaps by the charcoal of the polymkeric substance gained of coal or carbonization.These materials are specified granular size through thermal treatment , And and above being not less than, and is best charcoal carrier.
Best raw material has following characteristic: the BET surface-area is at least 100m
2/ g preferably is at least 500m
2/ g.
In order to prepare the charcoal of specified characteristic carrier is arranged; best heat treatment process comprise continuously (1) under protection of inert gas in 900-3300 ℃ of heating raw material of wood-charcoal material; (2) at this raw material of wood-charcoal material of 300-1200 ℃ of oxidation, (3) under protection of inert gas in 900-3000 ℃ of heating.
At oxidation stage, when when making oxygenant, being preferably under 300-600 ℃ and carrying out with oxygen (as air).
The time length of heating in rare gas element is not strict.But the heating charcoal should be enough in the raw material of wood-charcoal material to produce required variation to the required time of required top temperature.
Oxidation stage obviously needn't carry out under the condition of charcoal complete oxidation.For fear of peroxidation, preferably use gaseous oxidizer under the speed of control, to carry out oxidation.The example of gaseous oxidizer has: water vapour, the gas of carbonic acid gas and molecule-containing keto such as air.Oxygenizement proceeds to and calculates carbon weight loss by the weight of oxidized carbon is 10% for well at least, preferably 15%(weight at least) carbon loss.Carbon weight loss is not more than 40% for well, preferably is not more than 25%(weight) carbon loss.
The input speed of oxygenant is preferably such, and the carbon weight loss of requirement was finished in 2 hours at least, preferably finished at least 4 hours.
When needing protection of inert gas, can supply with nitrogen or a kind of other rare gas element.
It is 0.1-10%(weight that the catalyzer that is fit to is formed) VIII family precious metal, preferably 0.5-5%(weight) VIII family precious metal; 0.1-20%(weight) rhenium, preferably 1-10%(weight) rhenium; Rest part is a carrier.
This catalyzer can be by adding the I A family of one or more periodic table of elements, and II A family or IV A family metal improve, and preferably adds a kind of I A family metal.A kind of suitable metal is a potassium.Playing the add-on of one or more metals of improved action, can be 0.1-20%(weight based on the catalyzer total amount).The metal that has added improved action in this catalyzer has useful effect, and the hydrogenolysis of C-C can be suppressed either large or smallly during hydrogenation, therefore, has improved this method to requiring product selectivity.
This catalyzer can prepare with various methods.One of method for preparing this catalyzer is, with the solution impregnating carrier of the soluble compound of rhenium and VIII family precious metal, but these compound thermolysiss/be reduced to metal and/or metal oxide.
Dipping method can be common dipping or flood in succession, preferably adopt pickling process in succession.Pickling process is preferably used VIII family metal impregnation earlier in succession, and then floods with rhenium.
For a kind of best method of producing the catalyzer that is used for the inventive method was made up of following two steps:
(A) with the solution impregnating carrier of solubility VIII family precious metal chemical complex (but this compound thermolysis/be reduced into VIII family precious metal), remove then desolvate and
(B) the impregnated carrier of VIII family precious metal with the VIII family metal rhenium compound solution impregnation that is made into of the solvent of insoluble and solvable rhenium compound (but this rhenium compound thermolysis/be reduced into rhenium metal and/or oxide compound) basically, removes then and desolvates again.
Water is suitable for doing (A) solvent in step, and lower alcohol such as ethanol can be used as (B) solvent in step.Can avoid the lixiviate of the palladium any discernable degree in (B) step on the carrier that is immersed in (A) step with the catalyzer of aforesaid method production.
Production is used for the another kind of best method of the catalyzer of the inventive method and is made up of following steps:
(A ') removes then and desolvates with the solution impregnating carrier of solubility VIII family precious metal chemical complex (but this compound thermolysis/be reduced into VIII family precious metal).
VIII precious metal on (B ') heating carrier and
The impregnated carrier of (C ') VIII family's precious metal is used the solution impregnation (but this rhenium compound thermolysis/be reduced into rhenium metal and/or oxide compound) of solubility rhenium compound again, removes then and desolvates.
VIII family precious metal on carrier can or a kind of rare gas element such as nitrogen, reducing gas such as hydrogen, perhaps there are down suitably heating in oxygen-containing gas such as air.Can in 150-350 ℃ of scope, finish in the heating in the presence of the rare gas element.Can in 100-350 ℃ scope, finish in the heating in the presence of the reducing gas.Can in 100-300 ℃ scope, finish in the heating in the presence of the oxygen-containing gas.When making carrier with the high surface area graphitized carbon, upper temperature limit is 200 ℃.
Under particular case of the present invention, in step (C '), not necessarily require to use VIII family precious metal to go up insoluble solvent substantially.Therefore, any appropriate solvent all can be used in the step (A ') and (C ') of present method.The suitable solvent comprises independent water and alcohols.
Be preferably in step (A) and (B) between or increase the step that a VIII family impregnated carrier of precious metal is dried between step (A ') and (B ') again.Drying is to finish at 50-150 ℃ of scope internal heating.If desired, this step can inserting step (B ') in, this is fine understanding for the personnel that are familiar with this technical field.
The VIII family precious metal chemical complex that is fit to that decomposes/be reduced into metal comprises the salt of these metals, carboxylate salt for example, and nitrate and VIII family precious metal are present in some compounds of anionicsite, for example tetrachloro-palladium acid ammonium and tetranitro palladium acid ammonium.The rhenium compound that is fit to that decomposes/be reduced into rhenium metal and/or oxide compound comprises capric acid two rheniums, ammonium perrhenate and seven rhenium oxides.
Periodic table of elements I A family, whenever the metal of II A family or IV A family can being added in this catalyst composition in preparation process.This year, palladium/rhenium catalyst can be with the solution impregnation of the soluble compound of this metal.On the other hand, the soluble compound of this metal can be added in the common dipping solution or in succession the dipping solution in.
A kind of catalyzer preferably contains palladium and the rhenium that is stated from the high surface area graphitized charcoal, and this has been described among the above-mentioned GB-A-2136704.In contrast, use above-mentioned EP-A-0147219(referring to reference C) technology, when the equal size of palladium Jinping is 100
Or more hour, the selectivity loss is defective and the throughput loss is nonconforming during hydrogenation of maleic acid.We have found that, in acetic acid or propionic acid hydrogenation, catalyst selectivity and throughput basically with 30-150
Palladium Jinping in the scope all size is irrelevant.Therefore, we can be 30-99.9 with the brilliant size of palladium
Catalyzer.
In the method for the invention, before catalyzer uses preferably in heat up down with or hydrogen or hydrogen/rare gas element (as nitrogen) mixing contact 1-20 hour and activate.Intensification can be 200-350 ℃ of scope.On the other hand, can in the presence of reagent, be heated to temperature of reaction and come deactivated catalyst.
Can not provide extremely reliably for the accurate characteristic of catalyzer on the carrier and to measure, but be sure of that VIII family precious metal composition is the form of metal element and the rhenium composition is the form that is in metal element and/or its oxide compound.
Method of the present invention is suitable for carrying out under 100-350 ℃, preferably 150-300 ℃.Suitable pressure is less than 50 crust.
Method of the present invention can batch or continuous production, preferably continuous production.Catalyzer can fixed bed, moving-bed or fluidized-bed form are used.Quantity-produced gas hourly space velocity is with 50-50,000h
-Be advisable 2000-30 preferably, 000h
-
Method of the present invention can be illustrated further by following examples.
Preparation of Catalyst
Catalyzer is according to the method preparation of summarizing below.In these methods, the HSAG charcoal is represented the high surface area graphitized carbon, and its preparation and characteristic are as follows:
The charcoal that is used as carrier is by commercial commercially available Preparation of Activated Carbon, and buying the trade mark from Degussa is the gac of BKIV.Gac is in order to method processing down.This gac was heated to 1700 ℃ from room temperature in about 1 hour under argon atmospher; Be heated to after 1700 ℃, under argon atmospher, be cooled to 25 ℃; Then, be heated to about 520 ℃ in a blind roaster under air, exceeded by experience judgement weight loss to 20% heat-up time; Then, under argon atmospher, be heated between 1800-1850 ℃.At last, under argon atmospher, be cooled to room temperature.Gained graphitiferous charcoal is worn into 16-30 order BSS.
The gained charcoal has following character:
BET surface-area 710m
2/ g
Bottom surface amasss 389m
2/ g
Edge surface amasss 2.3m
2/ g
BET/ bottom surface long-pending 1.83
Bottom surface amasss/edge surface long-pending 169
Embodiment 1
In following each method, the nominal bearing capacity is meant the weight (not being salt) that is added in the metal on the carrier, and represents with the percentage ratio that accounts for vehicle weight.
The aqueous solution that A. will be dissolved with Palladous nitrate and rhenium heptoxide is added in the HSAG charcoal, with rotatory evaporator water is removed then.The impregnated charcoal of gained under 100 ℃ in vacuum oven overnight with its oven dry.The quantity (representing with the nominal bearing capacity) of the various components that four kinds of catalyzer are selected for use is as follows: Al-Pd2.5%, Re5%; A2-Pd2.5%, Re2%; A3-Pd2.5%, Re10%; A4-Pd5%, Re is removed.
B. adopt the method for preparing catalyst A, but wherein replace Re with an amount of ammonium perrhenate
2O
7, and the quantity (representing with the nominal bearing capacity) of the various components that four kinds of catalyzer are selected is as follows: B1-Re5%, Pd2.5%; B2-Re5%, Pd10%; B3-Re5%, Pd0.5%; B4-Re5%, Pd removes.
The aqueous solution that C. will be dissolved with Palladous nitrate is added among the HSAG, removes with rotatory evaporator and anhydrates, and the impregnated charcoal of gained is placed on dried overnight in 100 ℃ the vacuum drying oven.Then this catalyzer is cooled off, and insert in the Glass tubing, in the inherent hydrogen stream it was heated to 280 ℃ from about 30 ℃ in 6 hours.Keep 280 ℃ it to be cooled off in hydrogen after 10 hours, and with nitrogen purge for several times.
With Re
2O
7Palladium on the aqueous solution and the charcoal mixes, with rotatory drier solvent removed again, and with catalyzer dried overnight in 100 ℃ vacuum drying oven.Palladous nitrate and Re in the final catalyzer
2O
7Quantity (nominal bearing capacity) be Pd2.5%, Re5%.
D. repeat to prepare the method for catalyzer C, but difference is before the dipping of rhenium, the Pd/carbon catalyst that flooded palladium is to handle down in 300 ℃ in nitrogen environment, rather than 280 ℃ of processing down in hydrogen.
E. repeat to prepare the method for catalyzer C, difference is that the hydrogen treat step before the rhenium dipping is replaced with air handling, the charcoal that promptly will flood palladium in 6 hours in fluidizing air is heated to 180 ℃ from 20 ℃, keep 180 ℃ 4 hours, in air, be cooled to 30 ℃ then.
F. this catalyzer is by method C preparation, and difference is after drying, and the palladium on the Pd/carbon catalyst not be used in the hydrogen and heats, and the used solvent of dipping rhenium is not a water, but ethanol.
G. using method C, difference is before the dipping of rhenium promptly carries out, and in flowing nitrogen the ortho states palladium of going back on the Pd/carbon catalyst is heated to about 650-700 ℃ from 30 ℃ in three hours, And continues down to keep 6 hours at 650 ℃-700 ℃, is cooled to 30 ℃ then.The effect of this additional step be for the grain size that increases palladium (measuring) with XRD from 30A ° (catalyzer for preparing the method C) to 150A ° (present method preparation catalyzer).
H. contain, the catalyzer of palladium, potassium prepares as follows: the HSAG charcoal is mixed mutually with the solution that contains ruthenium trichloride and ammonium perrhenate, and removes with rotatory evaporator and to desolvate, with gained catalyzer dried overnight in about 100 ℃ vacuum drying oven.Then catalyzer was heated to 300 ℃ , And from about 30 ℃ in 2 hours in mobile hydrogen and continues down to keep 1 hour, cooling and use nitrogen purge in hydrogen then at 300 ℃.After this, will go back potassium on the ortho states catalyst soakage with the Potassium ethanoate aqueous solution.The quantity (representing with the nominal bearing capacity) of various components is as follows in four kinds of catalyzer:
H1-Re5%, Ru5%, (K removes); H2-Re5%, Ru5%, K10%; H3-Ru5%, K5%, (Re removes); H4-Ru5%(Re and K are removed).
I. the catalyzer that contains ruthenium and rhenium prepares by method C, but difference is to replace Palladous nitrate with nitrosonitric acid calcium, ruthenium on the Pd/carbon catalyst is 120 ℃ of dryings down, rather than it is dry down at 100 ℃, heat-up rate with 4 ℃/minute is heated to 300 ℃ in hydrogen then, and continues down to keep 1 hour at 300 ℃.The quantity of each component (nominal bearing capacity) is ruthenium 1%, rhenium 10%.
J. a ruthenium/rhenium catalyst is that different is at first to flood rhenium by method I preparation.
K. adopt method A, different is to replace the HSAG charcoal with Dai Weixun 57 silica gel (Davison), replaces Palladous nitrate with the tetrachloro-palladium acid ammonium, and having prepared a kind of nominal bearing capacity with present method is Pd2.5%, the catalyzer of Re5%.
L. the catalyzer of platiniferous and rhenium is usefulness method C preparation, but hydroxide four ammonia platinum have replaced Palladous nitrate, and the nominal bearing capacity is Pt1%, Re5%.
The test of catalyzer
Experiment is carried out under the pressure of 1-11 crust (gauge pressure), and warp is the catalyzer of the 2.5mls that packs in the anticorrosion stainless steel tube of 6-7mm in one, and reaction tubes is contained in the tubulose process furnace.Then, in two hours, under normal pressure, in the hydrogen stream catalyzer is heated to 280 ℃ or 300 ℃, and under final temperature, continues to keep 1 hour, after the activation, catalyzer is cooled to needed temperature of reaction in hydrogen catalyst activation.The mixed gas that makes carboxylic acid steam and hydrogen is by catalyzer, and reaction pressure transfers to needed numerical value with back pressure regulator.Steam/hydrogen mixture forms in evaporating area, in this district's liquid acetic acid and hydrogen charging respectively.Sampled to the product steam that leaves reactor and other gases, and analyze with gas one liquid chromatography instrument (glc).
Similar method and apparatus is used in the experiment of carrying out under 11-50 crust (gauge pressure), and the internal diameter of different is reaction tubes is 10mm, has used the catalyzer up to 10mls, and product is by condenser, and gaseous state and liquid product are measured respectively with glc.
In above-mentioned two kinds of methods, temperature all is by inserting the thermocouple measurement of catalyst bed.
Product mixture generally contains corresponding nitre and ester (ester generates owing to esterification reaction takes place in pure and mild unreacted acid), and contains the corresponding alkyl oxide of trace, aldehyde, by product methane, ethane and propane (only under the situation of propionic acid).Usually, under the situation of using charcoal and silica gel, primary product is alcohol, and is particularly all the more so under the situation of high conversion.
To each embodiment, all calculated transformation efficiency and selectivity respectively, promptly the ratio of hydrogenation of carboxylic acid and unconverted be the ratio of the hydrogenation of carboxylic acid of alkane by product.Thereby the selective meter is shown in the ability of catalyzer hydrogenization under the situation that does not have alkanisation.In all examples (except as otherwise noted), only there are the alkyl oxide of trace (≤2%) and aldehyde to generate.
Definition
The hourly space velocity that WHSV=calculates by weight=kilogram liquid feeding/kg catalyst hour.
The hourly space velocity that LHSV=by volume calculates=rise liquid feeding/rise catalyzer hour.
Throughput=kilogram acid conversion/kg catalyst hour.
Embodiment 2-7
With the catalyzer for preparing among the method A of example 1 and the method C acetate is carried out hydrogenation.WHSV is about 1.1(LHSV=0.35), the feed ratio of hydrogen and acetic acid is about 11: the 1(mole), pressure is 10.3 crust (gauge pressure).Except that example 7(c) catalyzer at 280 ℃ down the activation, other catalyzer all are 300 ℃ of activation down.The results are shown in table 1.Can see that in all cases catalytic activity is stable, in reaching 24 hours operating process, not find the deactivation phenomenon.
Table 1
The result shows that it is very favorable (embodiment 7) that pd and Re flood in succession, the poor performance of catalyst A 4 (embodiment 6), and this catalyzer is not a product of the present invention, it only contains palladium.
Embodiment 8-13
Adopt and the same method of embodiment 2-7, but the catalyzer of the method B preparation of use embodiment 1.All catalyzer are all 300 ℃ of activation down.The results are shown in table 2.
Table 2
The catalyzer of embodiment 13 is not a product of the present invention, and it is measured is in order to compare.
Embodiment 14-17
In acetic acid hydrogenation, compare with method C, the D of embodiment 1, the catalyzer of E, F preparation.Adopt the method identical with embodiment 2-7, different is that WHSV is about 4(LHSV=1.34), the feed ratio of hydrogen Dichlorodiphenyl Acetate is 9: the 1(mole).In 280 ℃ of activation down, temperature of reaction is 228-230 ℃ to catalyzer before use.The results are shown in table 3.
Table 3
The result shows: in experimental error, utilize the different technology of stain in succession to produce and have similar highly active catalyzer.
Embodiment 18
Catalyzer that use embodiment 1 method G prepares and the method that repeats embodiment 14-17.Find throughput be 1.0 kg/kg catalyzer/hour, selectivity is 92.7%.In experimental error, these results and in embodiment 14 resulting result similar, although the Pd crystal of present embodiment catalyzer on average is 150A ° greater than (measuring with XRD), and the Pd crystal mean size of the catalyzer of embodiment 14 is 30A °.The result shows: when use contains the catalyzer of less pt crystal (<100A °), can't cause active and optionally significantly descend this and EP-A-147219(comparative example C) viewpoint be opposite.
Embodiment 19
With the catalyzer of method C preparation, under 50 crust (gauge pressure) and 227 ℃, carry out acetic acid hydrogenation.WHSV is 15, and the feed ratio of hydrogen Dichlorodiphenyl Acetate is 9: the 1(mole).Catalyzer is 280 ℃ of activation down.
The acetic acid transformation efficiency is 40%, and selectivity is 96%, corresponding throughput be 6 kg/kg catalyzer/hour.Similar as other conditions, but during WHSV=3.6, then transformation efficiency is 74%, and selectivity is 96%.
Embodiment 20-24
The catalyzer of employing method H preparation in acetic acid hydrogenation.Catalyzer is 300 ℃ of activation down.WHSV is about 1.1) (LHSV=0.35), the feed ratio of hydrogen Dichlorodiphenyl Acetate is 11: the 1(mole), the results are shown in table 4.
Table 4
The result shows: potassium is having good effect aspect the improvement selectivity, and the non-constant of the performance of catalyzer H3, H4.These several catalyzer are not products of the present invention.
Implement 25-28
In the hydrogenation of propionic acid, adopt the catalyzer of embodiment 1 method I, J preparation to carry out.Repeat the method for embodiment 2-7, the different catalytic amounts that is to use is 2mls, LHSV=1, propionic acid is 1 10(mole to the feed ratio of hydrogen), pressure is 9 crust (gauge pressure).Catalyzer is 280 ℃ of activation down.The results are shown in table 5.In each case, other embodiment of the concentration ratio of aldehyde want high in the product, thereby we have listed the independent selective data to aldehyde.
Table 5
The result shows: carry out Ru dipping earlier and then carry out the prepared catalyzer of the Re dipping situation that capable Re dipping carries out the Ru dipping again of emulating the advanced and will get well.
Embodiment 29 and 30
Adopt the catalyzer of embodiment 1 method K preparation in the hydrogenation of acetic acid, and with the method for embodiment 2-7, the catalyzer of different is embodiment 30 is 450 ℃ of activation down, and the catalyzer of embodiment 29 activates down at 300 ℃.The results are shown in Table 6.
Table 6
Embodiment 31
Be used for the hydrogenation of acetic acid by the catalyzer of method L preparation, and adopt the method for embodiment 14-17.Transformation efficiency for 11.0%(throughput be 0.5 kg/kg catalyzer/hour), selectivity is 93.8%.
Embodiment 32
Be used for the liquid phase hydrogenation of acetic acid by the catalyzer of method B1 preparation.1.01 gram powder catalysts are packed in the stainless steel autoclave of 100ml with 50.2 gram acetic acid.Autoclave is cleaned the back be pressurized to 100 crust (gauge pressure), be heated to 200 ℃ under stirring, and under this temperature, continue to keep 6 hours with hydrogen.After the cooling, liquid product is shifted out and filters, organic products and rhenium metal and palladium are analyzed.Cooled resulting pressure is 50 crust (gauge pressure).
We find to contain in the product ethanol (corresponding hydrogenation throughput be 1.5 kg/kg catalyzer/hour) of 27.9% vinyl acetic monomer and 2%.In addition, find that original rhenium and palladium on catalyzer has 16% and 0.06% to be leached in the solution respectively.
Present embodiment shows: a large amount of rheniums takes place by the lixiviate phenomenon in the liquid phase hydrogenation of acetic acid.To be reflected at the situation of carrying out in the gas phase opposite with this for this.Under the situation of gas-phase reaction, perceptible rhenium loss can not take place.
This example is not embodiments of the invention, because it carries out in liquid phase, only is to do for sake of comparison.
Claims (18)
1, a kind ofly prepares ethanol or prepare the method for propyl alcohol by propionic acid by acetic acid, this method comprises that acetic acid or propionic acid contact with hydrogen in gas phase and in the presence of catalyzer, contact is to be to carry out under the 1-150 crust at temperature rise and pressure, the basal component of this catalyzer includes precious metal and (II) rhenium of VIII family in (I) periodic table of elements.
2, the described method of claim 1, VIII family precious metal wherein is a palladium.
3, the described method of claim 1, VIII family precious metal wherein is a ruthenium.
4, any one the described method during aforesaid right requires, wherein catalyzer suppressed by vector carrying.
5, the described method of claim 4, wherein carrier is the graphitized carbon of high-ratio surface.
6, the described method of claim 4, wherein carrier is a silica gel.
7, any one described method during aforesaid right requires, wherein catalyzer improves with the method for I A family metal in the addition element periodictable.
8, the described method of claim 7, the metal that wherein improves usefulness is a potassium.
9, a kind of method for preparing catalyst system therefor in the described method of claim 1-8, this method may further comprise the steps:
(A) with a kind of carrier of solution impregnation (this metallic compound is heated and can decomposes/be reduced to VIII family precious metal) of solubility VIII family precious metal chemical complex, then solvent is removed,
(B) carrier of having been crossed by VIII family metal impregnation with the solution impregnation of solubility rhenium compound is removed solvent then, and the solvent of this solution should not dissolve VIII family metal basically, but this solubility rhenium compound thermolysis/be reduced to rhenium metal and/or oxide compound.
10, the described method of claim 9, the solvent that wherein is used for step (A) is a water, the solvent that is used for step (B) is an ethanol.
11, a kind of method for preparing catalyst system therefor in the described method of claim 1-8, this method may further comprise the steps:
(A ') then, removes and desolvates with a kind of carrier of solution impregnation of solubility VIII family precious metal chemical complex (but this compound thermolysis/be reduced to VIII family precious metal),
VIII family precious metal on (B ') heating carrier,
(C '), removes solvent by the impregnated carrier of VIII family precious metal (but this rhenium compound thermolysis/be reduced to rhenium metal) then with solubility rhenium compound dipping.
12, the described method of claim 11, wherein the VIII family precious metal on the carrier will and be warming up to 150-350 ℃ of heating in the presence of rare gas element.
13, the described method of claim 11, wherein the VIII family precious metal on the carrier will and be warming up to 100-350 ℃ of heating in the presence of reducing gas.
14, the described method of claim 11, wherein the VIII family precious metal on the carrier will be in the presence of oxygen-containing gas and 100-300 ℃ temperature range heating, if used carrier is the graphitized charcoal of high surface area, upper temperature limit is 200 ℃.
15, any one the described method during aforesaid right requires, wherein catalyzer will be used in the method activation that contacts with hydrogen or hydrogen/noble gas mixtures under the intensification before using, and activation temperature is 200-350 ℃, and the cycle is 1-20 hour.
16, any one described method among the claim 1-14, wherein catalyzer will be used in the method activation that the reactant existence is heated to temperature of reaction down.
18, improving one's methods of the described method of a kind of claim 1-10 has corresponding ester together to generate during this is improved one's methods, and the way of the low-conversion of available per pass or introducing acid constituents in catalyzer improves the ratio of ester.
Applications Claiming Priority (2)
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GB858509530A GB8509530D0 (en) | 1985-04-13 | 1985-04-13 | Hydrogenation of carboxylic acids |
GB8509530 | 1985-04-13 |
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CN86102420A true CN86102420A (en) | 1986-10-08 |
CN1006788B CN1006788B (en) | 1990-02-14 |
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CN86102420A Expired CN1006788B (en) | 1985-04-13 | 1986-04-12 | The method of carboxylic acid alcohols production by hydrogenation |
CN86102452A Expired CN1008088B (en) | 1985-04-13 | 1986-04-12 | Alcohols production by hydrogenation of carboxylic acids |
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CN86102452A Expired CN1008088B (en) | 1985-04-13 | 1986-04-12 | Alcohols production by hydrogenation of carboxylic acids |
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US (5) | US4777303A (en) |
EP (2) | EP0198682B1 (en) |
JP (2) | JPS61275234A (en) |
CN (2) | CN1006788B (en) |
AT (2) | ATE94861T1 (en) |
AU (2) | AU592981B2 (en) |
CA (2) | CA1264727A (en) |
DE (2) | DE3677809D1 (en) |
GB (1) | GB8509530D0 (en) |
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Also Published As
Publication number | Publication date |
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US5061671A (en) | 1991-10-29 |
DE3689050T2 (en) | 1994-01-13 |
DE3689050D1 (en) | 1993-10-28 |
US4990655A (en) | 1991-02-05 |
AU592980B2 (en) | 1990-02-01 |
CN86102452A (en) | 1986-12-03 |
EP0198681A3 (en) | 1988-05-04 |
EP0198682A2 (en) | 1986-10-22 |
US4804791A (en) | 1989-02-14 |
JPS61275234A (en) | 1986-12-05 |
JPS61275237A (en) | 1986-12-05 |
JPH0825931B2 (en) | 1996-03-13 |
EP0198682A3 (en) | 1988-06-08 |
GB8509530D0 (en) | 1985-05-15 |
CN1008088B (en) | 1990-05-23 |
NZ215765A (en) | 1988-11-29 |
CN1006788B (en) | 1990-02-14 |
US4777303A (en) | 1988-10-11 |
ATE94861T1 (en) | 1993-10-15 |
CA1262719A (en) | 1989-11-07 |
NZ215766A (en) | 1988-11-29 |
ATE61327T1 (en) | 1991-03-15 |
CA1264727A (en) | 1990-01-23 |
AU592981B2 (en) | 1990-02-01 |
DE3677809D1 (en) | 1991-04-11 |
AU5601386A (en) | 1986-10-16 |
EP0198681B1 (en) | 1993-09-22 |
AU5601286A (en) | 1986-10-16 |
US4826795A (en) | 1989-05-02 |
EP0198682B1 (en) | 1991-03-06 |
EP0198681A2 (en) | 1986-10-22 |
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