CN86101532A - Make the method for glass Mosaic with cullet - Google Patents
Make the method for glass Mosaic with cullet Download PDFInfo
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- CN86101532A CN86101532A CN 86101532 CN86101532A CN86101532A CN 86101532 A CN86101532 A CN 86101532A CN 86101532 CN86101532 CN 86101532 CN 86101532 A CN86101532 A CN 86101532A CN 86101532 A CN86101532 A CN 86101532A
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- glass
- minute
- mosaic
- aqueous solution
- cullet
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Abstract
The method of manufacturing glass Mosaic of the present invention is characterized in making main raw material with cullet, uses new molding adhesive (glue solution), inorganic colourant and a whole set of corresponding sintering instead.Forming pressure 150-450 kilograms per centimeter
2, 650～800 ℃ of minimum sintering temperatures burn till in continous way tunnel electrical kiln.Need not suds suppressor; Because the binding agent excellent property, consumption is few, can burn till fast.Cause product color various, no bubble, visual sense is strong, and is fine quality.
Description
Involved in the present invention is a kind of manufacture method of building material made.
Glass Ma Saike is mainly used in the decorating inner and external walls of buildings, and it has good use properties and mechanics index of physics, has wide practical use.The interior exterior wall of buildings with glass Ma Saike facing after, long service life does not need overcoating or overhauls, thereby has significantly reduced maintenance cost.
The powder sintering method of known production glass Ma Saike all adopts glass powder compacting and forms through sintering, and different is, and Japan's (clear 55-11620 is opened in special permission) adopts in the frit glass that the admixture alkali metal silicate aqueous solution is made the powder molding adhesive and needed to add the 3%(weight percentage) zinc oxide and 1.5%(weight percentage) condensed phosphate makes suds suppressor and foams when the sintering to prevent binding agent.Glass powder is then introduced by France (patent Fr220789), and to need water and organic binder bond to mix mixed, and its weight percent is respectively glass powder and accounts for 67%, and water accounts for 30%, and binding agent accounts for 3%.In the Soviet Union, make glass Ma Saike and adopt admixture 5%(weight percentage in glass powder) paraffin wax as molding adhesive.Adopt above-mentioned several binding agents to cause product cost to increase, influence quality product and contaminate environment.
The object of the present invention is to provide a kind of novel method of making glass Ma Saike.Adopt cullet to make main raw material, use new molding adhesive instead, inorganic colourant and a whole set of corresponding preparation flow reach and reduce cost, and improve the quality non-environmental-pollution, the simple purpose of technology.
The method of manufacturing glass Mosaic of the present invention mainly comprises following content:
(1) adopt cullet (glass waste products such as flat board, Bottle ﹠ Can, rod, pipe) to cross 40-100 order/inch through pulverizing the back for main raw material
2Sieve.Pulverize glass and can amass ball mill with wheel roller, powder glass sieves with vibratory screening apparatus.
() (2) add a certain amount of inorganic pigment coloring agent on demand, and mix, and colour mixture can be carried out in spice machine or ball mill.
(3) make binding agent with the printing and dyeing dehydrating solution, concentration is the 1-5%(weight percentage), the binding agent consumption is about 0.1～0.3% of glass powder weight, look goods sizes binding agent consumption and can regulate, available spice machine with binding agent and glass powder mix be mixed even.
(4) extrusion forming is with 25 * 25 millimeters of compactings
2Or 45 * 45 millimeters
2The mould of blank is in the 150-450 kilograms per centimeter
2Extrusion forming under the pressure.Can adopt the molding device such as the 50-60 ton friction press of general manufacturing ceramic mosaic, suppress plastic 25 * 25 millimeters at every turn
2Base substrate 20-40 piece.
(5) sintering.Be warming up to 650～800 ℃ of insulations of sintering temperature by 5-30 ℃/minute speed lowered the temperature with 5-30 ℃ of/minute clock rate in 2-20 minute again.
The present invention adopts rapid sintering technique, and firing time was generally 1～2 hour.Calcination equipment is a continous way tunnel electrically heated kiln.Kiln is wide to be 40-100 centimetre, and kiln is about 16-25 rice, and the flat-temperature zone temperature control precision is ± 5 ℃ in the kiln, and the goods walking speed is the 20-40 cm per minute, can produce ten thousand square metres of goods of 3-8 per year.
The method of the invention and goods thereof have following advantage:
The used binding agent of the present invention decomposes when sintering fully, and volatilization is applicable to fast burns till, and the adhesive property of binding agent is good, and consumption is few, low price, and goods can not foam in sintering process, do not need with suds suppressor.The used tinting material of the present invention is multiple mineral dye, can select and control tinting material kind and concentration thereof, makes product color various, and in bright gay color, visual sense is strong.
The characteristic of glass Mosaic that following table is classified as.
Measure the project characteristic remarks
Hardness (Vickers kg/mm
2) 590
The thermal expansion remainder (℃
-1) 105 ± 10 * 10
-7
Bending strength (kg/cm
2) 690
Ultimate compression strength (kg/cm
2) 3200
0.19 100 ℃ of water-resistant stability (mg/g) 7 hours
Proportion (g/cm
3) 2.4-2.5
When not splitting-15 ℃ for 10 times, freezing and thawing test do not drop into
Circulate in 80 ℃ of water.
The test sample size
It is 25 * 25 millimeters
The preparation flow of embodiment 1. glass Mosaic.
Cullet material pulverizing-mix-add binding agent (mixing)-extrusion forming to make base substrate-high temperature sintering-subsides base stock, drying with mineral dye.
By above-mentioned schema glass waste through pulverizing 40-100 order/inch
2After sieve back is added a certain amount of tinting material (consumption is about the 0.05-2% of glass powder weight) and mixed, add the aqueous solution mixing of binding agent, on press with the 150-450 kilograms per centimeter
2Pressure forming.Be of a size of 25 * 25(or 45 * 45) millimeter
2Blank press 5-30 ℃/minute temperature rise rate at tunnel electric furnace internal heating to 650-800 ℃ of insulation 2-25 minute and then by given pace (as 5-30 ℃/minute) cooling, after the paster drying, the cutting burr.
Embodiment 2. fires green glass mosaic (using above-mentioned flow process)
Raw material granularity tinting material binding agent
(kilogram) (order) (kilogram) (kilogram)
Sheet glass chrome green printing and dyeing dehydrating solution concentration is the 1-4%(weight percentage)
100 100 0.2-1 4-10
Blank forming pressure temperature rise rate sintering temperature soaking time rate of cooling effect
Kilograms per centimeter
2℃/minute (℃) (branch) (℃/minute)
150-450 50-30 680-780 2-20 10-30 surfacing,
No bubble, have
Gloss, green
Color distinct, do not have
Tone is disorderly
Embodiment 3. fires the white glass mosaic
Raw material granularity tinting material binding agent
Useless container glass titanium dioxide concentration is the 1.5-5% print thickener aqueous solution
(kilogram) (order) (kilogram) (kilogram)
100 80-100 1-4 4-10
Blank forming pressure temperature rise rate sintering temperature soaking time rate of cooling effect
(kilograms per centimeter
2) (℃/minute) (℃) (branch) (℃/minute) product is smooth,
150-450 5-30 700-750 5-18 5-25 do not have bubble,
White is distinct
Claims (3)
1, a kind of method of producing glass Mosaic with cullet powder compression moulding and agglomerating is characterized in that:
A. adopt the inorganic pigment coloring agent that mosaic is painted, used tinting material is: titanium dioxide, chrome green iron oxide black, iron oxide red, yellow pigment, pigment, melanochrome; Concentration range is 0.05-2% (weight percentage);
B. adopt the print thickener aqueous solution to make the glass powder molding adhesive;
C. powder needs in the 150-450 kilograms per centimeter
2Pressure under extrusion forming;
D. the blank of moulding needs to carry out high temperature sintering under 650-800 ℃;
E. need control heating-cooling speed;
2, according to the method for the described manufacturing glass Mosaic of claim 1, it is characterized in that it is the 0.1-0.3% of glass powder weight that the print thickener aqueous solution is made the consumption of binding agent, the concentration range of the print thickener aqueous solution is 1-5%.
3, method according to claim 1 is characterized in that: temperature rise rate is that 5-30 ℃ of/minute soaking time is 2-20 minute; Rate of cooling is 5-30 ℃/minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86101532 CN86101532A (en) | 1986-07-26 | 1986-07-26 | Make the method for glass Mosaic with cullet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86101532 CN86101532A (en) | 1986-07-26 | 1986-07-26 | Make the method for glass Mosaic with cullet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN86101532A true CN86101532A (en) | 1988-02-10 |
Family
ID=4801432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86101532 Pending CN86101532A (en) | 1986-07-26 | 1986-07-26 | Make the method for glass Mosaic with cullet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN86101532A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100469729C (en) * | 2001-11-08 | 2009-03-18 | 迈克尔·J·豪恩 | Method for making product from waste glass |
| CN102381129A (en) * | 2011-08-05 | 2012-03-21 | 郭朝军 | Manufacturing technology of imitation jade bonsai shallow pot |
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
| CN103951169A (en) * | 2014-05-05 | 2014-07-30 | 柳铁刚 | Method for manufacturing glass accessories and abnormal glass mosaic by waste glass |
| CN105271645A (en) * | 2014-06-04 | 2016-01-27 | 刘从荡 | Glass mosaic production process |
| CN105347678A (en) * | 2015-10-27 | 2016-02-24 | 武汉理工大学 | Method for preparing decorative material by using waste toughened glass |
| CN108558205A (en) * | 2018-05-14 | 2018-09-21 | 洪德强 | The production method and agate glass product of agate glass are made of waste material |
| CN113461330A (en) * | 2021-07-20 | 2021-10-01 | 广东伟祺艺术玻璃有限公司 | Impact-resistant glass mosaic and preparation method thereof |
-
1986
- 1986-07-26 CN CN 86101532 patent/CN86101532A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100469729C (en) * | 2001-11-08 | 2009-03-18 | 迈克尔·J·豪恩 | Method for making product from waste glass |
| CN102381129A (en) * | 2011-08-05 | 2012-03-21 | 郭朝军 | Manufacturing technology of imitation jade bonsai shallow pot |
| CN102515853A (en) * | 2011-12-30 | 2012-06-27 | 江苏拜富科技有限公司 | Preparation method of zirconium silicate wrapped high-temperature sulfur cadmium selenide bright red pigment |
| CN103951169A (en) * | 2014-05-05 | 2014-07-30 | 柳铁刚 | Method for manufacturing glass accessories and abnormal glass mosaic by waste glass |
| CN105271645A (en) * | 2014-06-04 | 2016-01-27 | 刘从荡 | Glass mosaic production process |
| CN105347678A (en) * | 2015-10-27 | 2016-02-24 | 武汉理工大学 | Method for preparing decorative material by using waste toughened glass |
| CN108558205A (en) * | 2018-05-14 | 2018-09-21 | 洪德强 | The production method and agate glass product of agate glass are made of waste material |
| CN113461330A (en) * | 2021-07-20 | 2021-10-01 | 广东伟祺艺术玻璃有限公司 | Impact-resistant glass mosaic and preparation method thereof |
| CN113461330B (en) * | 2021-07-20 | 2023-09-05 | 广东伟祺艺术玻璃有限公司 | Impact-resistant glass mosaic and preparation method thereof |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |