CN2889669Y - Device for eliminating free formaldehyde in artificial plate - Google Patents
Device for eliminating free formaldehyde in artificial plate Download PDFInfo
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- CN2889669Y CN2889669Y CN 200520133434 CN200520133434U CN2889669Y CN 2889669 Y CN2889669 Y CN 2889669Y CN 200520133434 CN200520133434 CN 200520133434 CN 200520133434 U CN200520133434 U CN 200520133434U CN 2889669 Y CN2889669 Y CN 2889669Y
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- treatment box
- formaldehyde
- free formaldehyde
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- artificial board
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Abstract
The utility model relates to a device for eliminating free formaldehyde in man-made board. The device comprises a sealed processing box, an ozone generator, a humidifier, and a plurality of UV lamps. The ozone generator is connected with the air inlet and outlet of the processing box through pipes, the humidifier is connected with the humidifying hole of the processing box, and the UV lamps are mounted in the box. Ozone generated by the device is dissolved by contacting the wet surface of man-made board, and can produce free oxyradical (.O) under radiation of UV ray, which reacts with H2O to produce hydroxyl radical (.OH). At the same time, H2O2 produced on the wet surface is decomposed to .OH under radiation of UV ray, and .OH permeates into the man-made board to eliminate free formaldehyde by reacting with it to produce CO2 and H2O. The utility model has simple structure and convenient manufacture.
Description
Technical field
The utility model relates to a kind of device of eliminating formaldehyde, particularly about a kind of device of eliminating free formaldehyde in artificial board.
Background technology
In the interior decoration process, can produce multiple pollutant inevitably, what wherein pollution was the most serious is exactly formaldehyde.Formaldehyde is irritative gas colourless, that have overpowering odor, and proportion is slightly larger than air, and is soluble in water, is a kind of VOC.Formaldehyde is the magma poisonous substance, can and combined with protein, suck high-concentration formaldehyde and can cause symptoms such as the serious stimulation of respiratory tract and oedema, eye shouting pain, headache, bronchial astehma.Skin directly contacts formaldehyde, can cause dermatitis, color spot, necrosis.Long-term contact formaldehyde mucous hyperemia, headache can occur, feels sick, a series of symptom such as insomnia, vegetative nervous disorder even cause rhinocarcinoma.If air formaldehyde concentration reaches 30mg/m
3The time in addition the people is caused death.
The origin cause of formation and rule that artificial board formaldehyde pollutes are as follows: 1, the material about 90% of wood-based plate is a timber, and itself distributes formaldehyde timber.Make glued board with veneer, make particieboard and medium density fibre board (MDF) with wood shavings and fiber, all need timber analysed and and separate and experience dryly, this just makes formaldehyde of timber itself generation overflow to the external world.Under identical working condition, the burst size of methanal of Oak Tree particieboard is starkly lower than the pine particieboard.The birch particieboard is higher by 20% than the burst size of methanal of dragon spruce particieboard, and the dragon spruce plate is higher by 10% than the burst size of methanal of oak plate.The particieboard that contains a large amount of barks, its burst size of methanal is lower.The particieboard of spruce bark and pine bark, burst size of methanal are lower than beech bark particieboard.The ratio that big and flat wood shavings account in the particieboard is big more, and the burst size of methanal of particieboard is just low more.Under the same conditions, the formaldehyde amount of sawdust plate release exceeds 10 times than the planing particieboard.In addition, the wooden moisture content of sheet material is high more, and the sheet material burst size of methanal is big more.2, wood-based plate is wanted applying glue in manufacture process, and the free shape formaldehyde of the reaction of having neither part nor lot in is arranged in the adhesive.Glue commonly used at present is Lauxite and melamine resin adehsive, and these glue owing to the prescription difference or the adhesive-preparing technology difference that are adopted, contain a certain amount of free formaldehyde (being controlled at about 1.5% usually) in the resin glue that causes making when producing.The mol ratio of formaldehyde and urea (F/U) is big more in the resin, and free formaldehyde content is high more.Wood-based plate resin added in manufacture process is big more, and formaldehyde discharges many more.Under the identical situation of other condition, when resin added raising 5%, the burst size of methanal of sheet material will increase by 20%.3, to pass through hot pressing in the sheet material manufacture process, solidify generation formaldehyde during hot pressing fully.Make the resin glue of linear structure become network structure, i.e. curing reaction.But because in the process of slab pressurization, usually exist the thermograde that from the surface to the sandwich layer, progressively reduces in the slab thickness direction, make this process be difficult to usually carry out fully, cause slab inside, especially sandwich layer, the linear structure resin that exists some that curing reaction does not take place is easy to decomposite formaldehyde and distributes to the external world.The burst size of methanal of wood-based plate reduces with the consumption increase of curing agent (ammonium chloride), does not use the plank of curing agent compacting, its burst size of methanal maximum.But because the restriction of curing rate, the addition of ammonium chloride can not be too much in the production.Add ammoniacal liquor and urea in the curing component, also can reduce burst size of methanal, can slow down curing rate but too much add ammoniacal liquor.As for urea, only can be used for free formaldehyde and surpass 0.4% resin, be lower than 0.4% resin for free formaldehyde, use urea can increase the expansion rate of particieboard.Hot pressing temperature is high more in the sheet material manufacture process, and hot pressing time is long more, and the formaldehyde that sheet material discharges when hot pressing is many more, and finished product sheet material burst size of methanal is low more.4, the wood-based plate finished product is stacked generally stacking immediately after hot press comes out, the cooling back is stacked and forced to cool off the back and stack three kinds of stacking methods naturally.Evidence, the sheet material that stack the cooling back is compared with the sheet material of directly stacking without cooling, and burst size of methanal reduces by 44%, and stack than the sheet material of forcing the cooling back to be stacked the cooling back naturally, burst size of methanal reduces 5%.When being cooled to 60～70 ℃, stacks again particieboard, and better to content of formaldehyde effect in the reduction plate.5, artificial board formaldehyde distributes and has chronicity and intractable, wood-based plate is under the various service conditions that are not quite similar, tend to be subjected to the influence of environmental conditions such as temperature, humidity, soda acid, weathering, illumination, make that original resin that does not absolutely solidify degraded takes place and discharges formaldehyde in the plate, cause formaldehyde emission even completely crued resin also can disintegrate because of the tribulation of with the passage of time mal-condition.These reasons cause the wood-based plate that used after the long duration, and the formaldehyde emission amount of the similar plank after its formaldehyde emission amount and the hot pressing just is very nearly the same, increases sometimes even to some extent.The temperature of environment for use and relative humidity are big more, and the burst size of methanal of sheet material is big more.
In process, reduce the art methods of artificial board formaldehyde burst size, comprise the wood shavings content that reduces in the timber, naturally cooling after the hot pressing, increase hot pressing temperature, prolong hot pressing time, add formaldehyde catching agent or formaldehyde inhibitor, reduce resin added or turn down the content etc. of formaldehyde in the urea-formaldehyde resin adhesive.But these methods or increased the production cost and the production cycle of wood-based plate, or in process, increased new pollutant, or reduced the bonding quality of wood-based plate, its result is unsatisfactory, has certain limitation.And as the consumer, people have to take to add forced ventilation, postpone new house and move in the time, spray formaldehyde eliminating agent on finished product furniture, replace indoor use air purifier or plantation flowers and plants or with solid wood furniture passive method such as artificial board furniture to avoid artificial board formaldehyde to discharge the harm that brings when using wood-based plate.But adopt the method for strengthening room ventilation that practical difficulty is arranged in cold season, the sheet material exposed surface is present in inside of furniture more, and general method of ventilation does not have very good effect yet.Investigation shows, fits up and move into furniture, places after 6 months, and indoor formaldehyde concentration is significantly reduced, and personnel reentered and can significantly reduce the harm that the formaldehyde pollution brings this moment.Though this method is effective, the cycle is oversize, does not generally have practical significance.A large amount of methods of using solid wood furniture to replace artificial board furniture, in short supply limited from timber resources with consuming capacity, do not have the meaning of popularization in China.
The composition of formaldehyde eliminating agent mainly divides three classes: a class is medicaments such as sulphite, ammonia, organic amine.After being sprayed on the wood-based plate surface, can play polymerisation with the formaldehyde that wood-based plate discharges.Shortcoming is that quantity for spray is limited, and after medicament ran out of very soon, the elimination effect was promptly lost efficacy.Second class is a sealer.This class material can not be eliminated formaldehyde, and its principle is to form the fine and close diaphragm of one deck on the wood-based plate surface.Shortcoming is poor for rough surperficial result of use, for there being combination with decorative surfaces to use.The 3rd class is the bioactive enzyme of energy decomposing formaldehyde.Shortcoming is to cost an arm and a leg, and should not promote.Because it is a very long process that artificial board formaldehyde distributes, therefore use traditional air purification method, waste time and energy and effect limited.
Summary of the invention
At the problems referred to above, the purpose of this utility model provides that a kind of reaction efficiency height, good stability, cheap, no new nuisance generate and based on the device of the elimination free formaldehyde in artificial board of advanced oxidation processes principle.
For achieving the above object, the utility model is taked following technical scheme: a kind of device of eliminating free formaldehyde in artificial board is characterized in that: it comprises a closed processes case, an ozone generator, a humidifier and several uviol lamps; Described treatment box has an openable chamber door, described ozone generator by pipeline connect respectively described treatment box into and out of pore, described humidifier connects the wet hole that adds of described treatment box by pipeline, described uviol lamp is installed in the described treatment box.
Be provided with fan in the described treatment box.
Described treatment box is provided with humidifier.
Be provided with heater in the described treatment box.
Described heater is an electric heater.
Described heater is the water-gas type heat exchanger that is arranged in the described treatment box, described heat exchanger by entery and delivery port be positioned at described treatment box external heated pipeline and link to each other.
Described heater is for being arranged on intercalated water sleeve on the described treatment box wall, the water in the described water jacket by entery and delivery port be positioned at described treatment box external heated pipeline and link to each other.
Described ozone generator and humidifier are arranged in the described treatment box.
When the utility model uses, wood-based plate is placed in the continuous ozoniferous closed processes case, ozone hour generating capacity on average is not less than 1g/hm to the inner headroom volume of treatment box
3(4) use the surface of UV-irradiation wood-based plate simultaneously with step (3), the general power of uviol lamp on average is not less than 1W/m to the area of processing wood-based plate
2Ozone and moist wood-based plate surface contacts and dissolve by above-mentioned steps,, produce free oxygen free radical (O), free oxygen free radical (O) and water molecule reaction generation hydroxyl radical free radical (OH) when ozone during by UV-irradiation; Meanwhile produce hydrogen peroxide (H at the high humidity material surface
2O
2), hydrogen peroxide (H
2O
2) decomposition generation OH (hydroxyl radical free radical) under the irradiation of ultraviolet light; Along with hydroxyl radical free radical (OH) to the sheet material internal penetration, the free formaldehyde in institute's permeable areas is oxidized to carbon dioxide and water, thereby eliminates the free formaldehyde in the wood-based plate.
The utility model method compared with prior art, have the following advantages and the high-lighting effect: 1, the utility model employing ozone generation hydroxyl radical free radical (OH) is eliminated the free formaldehyde in the artificial board, hydroxyl radical free radical (OH) standard electrode EMF is 2.8V, oxidability is very strong, so the purification efficiency height.2, the utility model finally is oxidized to carbon dioxide and water with harmful substance, so non-secondary pollution.3, the utility model is compared with the method that formaldehyde eliminating agents such as use sulphite, ammonia, urea are handled free formaldehyde in the wood-based plate, and is with low cost, do not have and decomposes the danger that may or produce new nuisance that produces formaldehyde again.4, the employed ozone generation technology of the utility model, uviol lamp manufacturing technology are comparatively ripe prior aries, therefore generate the process stabilization of hydroxyl radical free radical (OH), and the wood-based plate purification efficiency is stable.5, the utility model flow process is simple, and used assembly can directly buy on market, is easy to realize.6, the utility model can be realized control to hydroxyl radical free radical (OH) growing amount, the detergent power of adjusting device easily by regulating ozone output or ultra violet lamp number.
Description of drawings
Fig. 1 is the utility model apparatus structure schematic diagram
Fig. 2～Fig. 7 is that the utility model is 3g at the ozone generating capacity, when treatment temperature is respectively 45 ℃, 60 ℃, deal with core-board separately 2h, 4h, 6h after, the concentration of formaldehyde change curve of core-board
The specific embodiment
The utility model is described in further detail below in conjunction with accompanying drawing and preferred embodiment.
As shown in Figure 1, the utility model device comprises a closed processes case 1, and several uviol lamps 3, an ozone generator 5, one humidifiers 6 are installed on treatment box 1 surface.Ozone generator 5 links to each other with air admission hole 10, venthole 11 on the treatment box respectively by pipeline.Humidifier 6 links to each other with the wet hole 12 that adds on the treatment box 1 by pipeline.
In the said apparatus, the size of treatment box 1 can if treatment box 1 space allows, can be arranged on treatment box 1 inside with ozone generator 5 and humidifier 6 according to the quantity and the size design of the wood-based plate of planning single treatment.Can be in the treatment box 1 in the bottom or both sides wood-based plate fixed support 7 is set, wood-based plate can the compartment of terrain vertical or horizontal direction be folded between the fixed support 7, the number of fixed support 7 is determined by the quantity of processing wood-based plate.The import and export of treatment box 1 can be top cover, certain sidewall whole or local of treatment box 1, preferably make the chamber door 2 of an activity, to make things convenient for wood-based plate from the chamber door of opening 2 treatment boxes 1 of coming in and going out.One thieff hatch 8 also is set, to carry out the concentration of formaldehyde test on treatment box 1.
The humidification amount of the generating capacity of ozone generator 5, humidifier 6 is according to the concrete size decision of treatment box 1, and the ozone hour generating capacity of general ozone generator 5 on average is not less than 1g/hm to treatment box 1 inner headroom volume
3, the humidification amount of humidifier 6 wants generally to guarantee that with the air in the treatment box 1 humidification reaches 80% relative humidity at least when treatment temperature is 30～60 ℃ usually, purpose is the excessive vaporization that prevents the wood-based plate surface moisture.
The ultraviolet wavelength of uviol lamp can be positioned at arbitrary scope of A, B, C triband, and wherein A band is 320～400nm; The B wave band is 275～320nm; C-band is 200～275nm.The general power of uviol lamp is according to the treating capacity decision of wood-based plate, and the general power of uviol lamp on average should be not less than 1W/m to the gross area of processing wood-based plate
2
One one or two ones or more windy fan 4 can be housed in treatment box 1, and the position of fan 4 can be selected, and hour air quantity of fan 4 should promote the equally distributed effect of ozone in the case to reach more than or equal to treatment box inside headroom volume.
Treatment box 1 can be provided with a heater 13, and this heater can be taked various mode, such as: first kind is that electric heater is placed directly in the treatment box 1; Second kind is that water-gas type heat exchanger is placed in the treatment box 1, is heat transferring medium with water in the heat exchanger, heat exchanger by entery and delivery port 14,15 be positioned at treatment box 1 external heated pipeline and link to each other; The third is the water jacket that each wall of treatment box 1 or part wall is designed to have interlayer, the water in the water jacket by entery and delivery port be positioned at treatment box 1 external heated pipeline and link to each other.
Embodiment 1:
Buy three wood-based plates of same batch of same producer, be sawn into two halves respectively, test the formaldehyde emission amount of these six wood-based plate samples then.Test result shows that the formaldehyde emission amount of two half block plates of same wood-based plate is equal substantially.Optional one is placed on the ventilation from two samples that derive from same wood-based plate, allows it distribute naturally, and adopts the utility model method to handle on another sample.Processing procedure is as follows:
(1) feed ozone in the aqueous solution that contains 5% hydrogen peroxide, the ozone generating capacity of the ozone generator that per kilogram solution is mated is 1200mg/h, 10 minutes feeding time.
(2) with this solution with 10g/m
2Density be sprayed on the wood-based plate specimen surface of three half blocks.
(3) in advance the temperature in the treatment box 1 is heated to 45 ℃, opens the chamber door 2 of treatment box 1, wood-based plate is put into treatment box 1, be fixed on two fixed supports 7, an electric-heating steam humidifier 6 is increased to 80% by adding wet hole with relative humidity in the treatment box 1.Open fan 4, open uviol lamp 3, ultraviolet light is directly or by reflected illumination each surface at wood-based plate.Start ozone generator 5 simultaneously and feed ozone in treatment box 1, the ozone generating capacity is 3g/h, and the processing time is set at 2h, 4h and 6h respectively.
(4) behind setting-up time, close ozone generator 5, uviol lamp 3, fan 4, take out processed wood-based plate sample, be placed in the ventilated environment identical dry with other three wood-based plate samples that distribute naturally.
After (5) 72 hours, three wood-based plate samples that adopt the utility model method to handle are distributed three wood-based plate samples in addition of handling with the employing nature carry out the formaldehyde emission amount according to test.Test is carried out in treatment box 1.It is airtight respectively institute's test specimens to be put into treatment box 1, and the fan 4 that blows in measures concentration of formaldehyde in the treatment box 1 by thieff hatch 8.The concentration of formaldehyde of each sample in treatment box 1 changes as Fig. 2, Fig. 3, shown in Figure 4, " A " curve among the figure is the concentration of formaldehyde change curve of treated core-board, and " B " curve is the concentration of formaldehyde change curve of the not treated core-board that is used for contrasting.
As shown in Figure 2, be 3g/h at the ozone generating capacity, 45 ℃ of treatment temperatures, under the condition of processing time 2h, the formaldehyde emission amount of handling the back test specimen is compared with the test specimen that adopts nature to distribute processing and has approximately been reduced 64%.
As shown in Figure 3, be 3g/h at the ozone generating capacity, 45 ℃ of treatment temperatures, under the condition of processing time 4h, the formaldehyde emission amount of handling the back test specimen is compared with the test specimen that adopts nature to distribute processing and has approximately been reduced 73%.
As shown in Figure 4, be 3g/h at the ozone generating capacity, 45 ℃ of treatment temperatures, under the condition of processing time 6h, the formaldehyde emission amount of handling the back test specimen is compared with the test specimen that adopts nature to distribute processing and has approximately been reduced 76%.
Embodiment 2:
The step of present embodiment is identical with embodiment 1.Except treatment temperature being changed into 60 ℃, all the other processing parameters are identical, and the concentration of formaldehyde of each sample in treatment box 1 changes as Fig. 5, Fig. 6, shown in Figure 7." A " curve among the figure is the concentration of formaldehyde change curve of treated core-board, and " B " curve is the concentration of formaldehyde change curve of the not treated core-board that is used for contrasting.
As shown in Figure 5, be 3g/h at the ozone generating capacity, 60 ℃ of treatment temperatures, under the condition of processing time 2h, the formaldehyde emission amount of handling the back test specimen is compared with the test specimen that adopts nature to distribute processing and has approximately been reduced 74%.
As shown in Figure 6, be 3g/h at the ozone generating capacity, 60 ℃ of treatment temperatures, under the condition of processing time 4h, the formaldehyde emission amount of handling the back test specimen is compared with the test specimen that adopts nature to distribute processing and has approximately been reduced 74%.
As shown in Figure 7, be 3g/h at the ozone generating capacity, 60 ℃ of treatment temperatures, under the condition of processing time 6h, the formaldehyde emission amount of handling the back test specimen is compared with the test specimen that adopts nature to distribute processing and has approximately been reduced 72%.
The comparative result of present embodiment shows: adopt the utility model device to eliminate the interior free formaldehyde of wood-based plate, its treatment effect was determined jointly by advanced oxidation efficient, treatment temperature, processing time.When treatment temperature was 60 ℃, because the reduction rate of ozone and free hydroxyl is accelerated, the depth of interaction that permeates to wood-based plate inside reduced.So along with the prolongation in processing time, treatment effect moves closer to and the treatment effect when being lower than 45 ℃.
Claims (10)
1, a kind of device of eliminating free formaldehyde in artificial board is characterized in that: it comprises a closed processes case, an ozone generator, a humidifier and several uviol lamps; Described treatment box has an openable chamber door, described ozone generator by pipeline connect respectively described treatment box into and out of pore, described humidifier connects the wet hole that adds of described treatment box by pipeline, described uviol lamp is installed in the described treatment box.
2, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 1 is characterized in that: be provided with fan in the described treatment box.
3, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 1, it is characterized in that: described treatment box is provided with humidifier.
4, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 2, it is characterized in that: described treatment box is provided with humidifier.
5, as claim 1 or 2 or 3 or 4 described a kind of devices of eliminating free formaldehyde in artificial board, it is characterized in that: be provided with heater in the described treatment box.
6, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 5, it is characterized in that: described heater is an electric heater.
7, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 5, it is characterized in that: described heater is the water-gas type heat exchanger that is arranged in the described treatment box, described heat exchanger by entery and delivery port be positioned at described treatment box external heated pipeline and link to each other.
8, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 5, it is characterized in that: described heater is for being arranged on intercalated water sleeve on the described treatment box wall, the water in the described water jacket by entery and delivery port be positioned at described treatment box external heated pipeline and link to each other.
9, as claim 1 or 2 or 3 or 4 or 6 or 7 or 8 described a kind of devices of eliminating free formaldehyde in artificial board, it is characterized in that: described ozone generator and humidifier are arranged in the described treatment box.
10, a kind of device of eliminating free formaldehyde in artificial board as claimed in claim 5, it is characterized in that: described ozone generator and humidifier are arranged in the described treatment box.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200520133434 CN2889669Y (en) | 2005-11-22 | 2005-11-22 | Device for eliminating free formaldehyde in artificial plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200520133434 CN2889669Y (en) | 2005-11-22 | 2005-11-22 | Device for eliminating free formaldehyde in artificial plate |
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| Publication Number | Publication Date |
|---|---|
| CN2889669Y true CN2889669Y (en) | 2007-04-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200520133434 Expired - Fee Related CN2889669Y (en) | 2005-11-22 | 2005-11-22 | Device for eliminating free formaldehyde in artificial plate |
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| Country | Link |
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| CN (1) | CN2889669Y (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101940905A (en) * | 2010-08-13 | 2011-01-12 | 上海交通大学 | Visible light-based hydroxyl radical generator and trapping method |
| CN101988265A (en) * | 2009-07-31 | 2011-03-23 | 李增发 | Method and device for removing or effectively reducing harmful constituents of clothing |
| CN110142829A (en) * | 2019-06-03 | 2019-08-20 | 三门县晶昌机械科技有限公司 | A kind of board making equipment with formaldehyde absorbing function |
-
2005
- 2005-11-22 CN CN 200520133434 patent/CN2889669Y/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101988265A (en) * | 2009-07-31 | 2011-03-23 | 李增发 | Method and device for removing or effectively reducing harmful constituents of clothing |
| CN101940905A (en) * | 2010-08-13 | 2011-01-12 | 上海交通大学 | Visible light-based hydroxyl radical generator and trapping method |
| CN101940905B (en) * | 2010-08-13 | 2012-08-22 | 上海交通大学 | Visible light-based hydroxyl radical generator and trapping method |
| CN110142829A (en) * | 2019-06-03 | 2019-08-20 | 三门县晶昌机械科技有限公司 | A kind of board making equipment with formaldehyde absorbing function |
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