CN2592632Y - Instant film-forming photocatalysis-oxidation water treating apparatus - Google Patents

Instant film-forming photocatalysis-oxidation water treating apparatus Download PDF

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Publication number
CN2592632Y
CN2592632Y CN 02283501 CN02283501U CN2592632Y CN 2592632 Y CN2592632 Y CN 2592632Y CN 02283501 CN02283501 CN 02283501 CN 02283501 U CN02283501 U CN 02283501U CN 2592632 Y CN2592632 Y CN 2592632Y
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China
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filter element
water
utility
model
treatment
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Expired - Fee Related
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CN 02283501
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Chinese (zh)
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魏宏斌
彭海清
邹平
徐迪民
梁存楷
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Tongji University
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Tongji University
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  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The utility model relates to an instant film-forming photocatalysis-oxidation water treating device, which relates to a water treatment device. The utility model comprises a ball-shaped upper seal head with a flange, a porous baffle (2), a column-shaped casing body (5), a filtering element (8), and a cone-shaped lower seal head (9), wherein, the filtering element (8) is formed by the fixed connection of the top (15), a top plate (16), a stainless steel screen (17), a post (18), and a base plate (19). The fixed connection of the top (15) is fixedly connected with the porous baffle (2). The upper seal head (1), the porous baffle (2), and the casing body (5) are fixed to form a body via a screw bolt (3) and a screw nut (4). The utility model is characterized in that the filtering element (8) is arranged in an ultraviolet germicidal lamp (6) with a quartz socket tube (7). The stainless steel screen (17) can be coated or removed with a photocatalyst film as required, and the film thickness, etc., can be adjusted at any time. The photocatalyst film removed can be reused. The utility model has the advantages of reasonable structure, low operation cost, and good treatment effect and can be individually used as the treatment of various organic waste water, the advanced treatment of drinking water, and the terminal and pre-treatment of high purity water.

Description

Instant film-forming type photochemical catalytic oxidation water treatment device
Technical field
The utility model relates to a kind of water treatment device, refers to especially organic wastewater with difficult degradation thereby, high density, device that high chroma organic waste water is handled and the advanced treatment of tap water, the terminal and the pretreatment unit of high purity water.
Background technology
In recent decades, because developing rapidly of organic chemical industry, petrochemical complex, medicine, agrochemical industry, the kind and the output of organic compound grow with each passing day, and having entered particularly water surrounding of human environment by various approach, the organism in the water surrounding has 96000 kinds more than approximately according to estimates.They are very big to the harm of environment.No matter be river, river, lake water, waste water or tap water, organic pollutant has wherein become the principal contradiction that water pollutes, and the organic pollutant of removing in the water has become one of top priority of water treatment.
But traditional biochemical treatment often is difficult to reach treatment effect preferably.And start under the rayed excite transitions of electronics in the semi-conductor, with UV/TiO 2If the most common photochemical catalytic oxidation has been proved to be the enough reaction times, just can be CO with the organism permineralization 2And H 2Simple inorganics such as O.But based on following two reasons, photocatalysis oxidation technique is not applied to actual engineering of water treatment so far.One, traditional suspending phase photochemical catalytic oxidation is directly with TiO 2Powder places waste water by UV-irradiation, TiO after reaction is finished 2Powder is not only time-consuming but also require great effort with separating of water; Its two, traditional stationary phase photochemical catalytic oxidation adopts methods such as colloidal sol-gel or vapor deposition to make TiO in advance on carriers such as glass fibre (cloth), glass sphere 2Film, film complexity, cost height, and film forming thickness is very limited, and the efficient of photocatalysis oxidation reaction is low, is difficult to adapt to the requirement of actual engineering.Simultaneously, cleaning behind the photocatalyst film " poisoning " or replacing are all undesirable or complicated, thereby have also limited the process that photocatalysis oxidation technique transformed to the practical stage.
China utility model patent ZL96229378.4 discloses a kind of filtering apparatus for drinking water, adopts diatomite as flocculating aids, can instant film forming, instant recoil wash off on the filter element that stainless (steel) wire is made.But this device only limits to filteration, only can remove suspended substance and colloid in the water, to almost not removal effect of deliquescent organism in the water.
Summary of the invention
The purpose of this utility model is at the problems referred to above, design a kind of efficient, cheap, cleaned and changed photocatalyst film of coating and can remove organic novel photocatalysis oxidized water treatment equipment in the water easily, satisfy dirt, the wastewater discharge standard requirement of increasingly stringent, and solve the difficulty of shortage of water resources.
In order to achieve the above object, the utility model is performed such: comprise flanged (FLGD) spherical upper cover, taper lower cover, cylindrical housings, filter element, foraminous dividing plate.The foraminous dividing plate is divided into upper and lower two portions with the utility model, and top is clean water chamber, and the bottom is the photocatalysis oxidation reaction chamber.Filter element is is firmly connected and composed by top retaining plate, top board, base plate, post, Stainless Steel Cloth, and places in the housing.Be connected with filter element nut, filter element bolting with the foraminous dividing plate with the top retaining plate that filter element is solidified as a whole.By screw bolt and nut flanged (FLGD) spherical upper cover, the foraminous dividing plate of intrinsic filter element, cylindrical housings are solidified as a whole.Its structural feature is: the inside of filter element is provided with the ultraviolet germicidal lamp that has quartz socket tube.Ultraviolet germicidal lamp passes upper cover and is connected with power supply.Stainless Steel Wire can apply or remove photocatalyst film on the net as required immediately, removes organic processing requirement in the water to satisfy.
Characteristics of the present utility model and advantage comprise:
1. because the utility model need not film forming in advance, be that the scene forms photocatalyst film immediately on filter element, and under the ultraviolet germicidal lamp effect, carry out photochemical catalytic oxidation and smart filter and disinfection, so can also remove turbidity, SS, colloid, suspended substance and the floating matter of water in the various organic whiles of thorough removal, the turbidity of filter back water can reach zero Ntu, and water quality is limpid bright, and the utility model treatment effect is good.
2. photocatalyst film thickness of the present utility model, aperture and ultraviolet light intensity can be adjusted at any time, and not only photochemical catalytic oxidation ability is 3-5 times of traditional photocatalytic oxidation device, and has the essence filter effect that traditional photocatalytic oxidation device does not have.
Since the utility model through after the reaction of certain hour and filtering, stifled and cause aquifer yield to descend as photocatalyst film, or remove the effect of pollutent when undesirable by dirt, then can utilize intake pump easily the photocatalyst film recoil to be washed off.Photocatalyst under the back flushing can also utilize once more.So the utility model has not only solved the separation problem of reaction back photocatalyst and water, but also can reclaim photocatalyst, working cost is low.
4, because filter element can be set up in advance, and the ultraviolet germicidal lamp of setting can take out from upper cover and change, so the utility model is rational in infrastructure, it is easy to maintenance to make.
5. the utility model is of many uses, both can be used as the processing of various organic waste waters separately, can be used as the pre-treatment or the terminal process of conventional water treatment process again, water outlet can directly be discharged or reuse, saves precipitation, air supporting or other filtration means and terminal sterilisation measure.
Description of drawings
Fig. 1 is a structural representation of the present utility model.
Fig. 2 is an A-A synoptic diagram of the present utility model.
Fig. 3 establishes the structural representation of the filter element of ultraviolet germicidal lamp in being
Fig. 4 is the B-B synoptic diagram of filter element of the present utility model.
Fig. 5 is a workflow diagram of the present utility model.
Embodiment
See also Fig. 1, Fig. 2, the utility model is made up of flanged (FLGD) spherical upper cover 1, foraminous dividing plate 2, bolt 3, nut 4, cylindrical housings 5, ultraviolet germicidal lamp 6, quartz socket tube 7, filter element 8, taper lower cover 9, water distribution board 10, viewing window 11, filter element nut 12, filter element bolt 13, a silk mouthful screen cap 14.Place 4 filter elements 8 in the housing 5 all to be solidified as a whole by filter element nut 12, filter element bolt 13, be solidified as a whole with bolt 3 and nut 4 foraminous dividing plate 2, housing 5 again upper cover 1, intrinsic filter element 8 with foraminous dividing plate 2.Dividing plate 2 is divided into two portions with the utility model, and top is clean water chamber, and the bottom is the photocatalysis oxidation reaction chamber.The ultraviolet germicidal lamp 6 that has quartz socket tube 7 passes upper cover 1 and inserts in the filter element 8.Quartz socket tube 7 is sealed into one with upper cover 1 by silk mouth screen cap 14.The intrinsic water distribution board 10 in the lower end of taper lower cover 9.There is viewing window 11 in housing 5 fronts.
See also Fig. 3 and Fig. 4.Each filter element 8 firmly connects and composes by top retaining plate 15, top board 16, Stainless Steel Cloth 17, post 18 and base plate 19.Top board 16 is an annular, its external profile diameter and circular base plate 19 equal diameters.Earlier 12 posts 18 firmly are welded on the outer rim of top board 16 and base plate 19, form skeleton, and then tightly wrap up stainless (steel) wire 17, make filter element 8 be rendered as cylindrical shape in the skeleton outside.The top board 16 and the top retaining plate 15 of filter element 8 are welded as a whole, and by filter element nut 12, filter element bolt 13 top retaining plate on the filter element 8 15 and porous plate 2 are solidified as a whole again.The inside of filter element 8 is provided with the ultraviolet germicidal lamp 6 of band stone sleeve pipe 7.Can apply or remove the photocatalyst filtrate as required immediately on the Stainless Steel Cloth 17, with the processing requirement of organism and turbidity, SS, colloid, suspended substance, floating matter and bacterium, virus in the satisfied removal water.
See also Fig. 5.During work, instant film-forming type photochemical catalytic oxidation water treatment device of the present utility model and the water tank 20, intake pump 22 that have stirring arm and speed governing stirrer 21 are formed by pipe connection.
At first in the water tank 20 that is added with water in advance, add commercially available TiO 2Powder starts speed governing stirrer 21, makes the photocatalyst slurries.Open valve 23 then, start intake pump 22, open valve 24, valve 25, valve 26 again, the photocatalyst slurries enter the utility model by the bottom, slit by filter element outside stainless (steel) wire 17 enters the filter element 8 inner clean water chambers that flow into, flow out by the utility model top again, and beginning circulates between water tank 20 and the utility model.Through 20 minutes circulation, it is clear that the photocatalyst slurries become, and this moment, filter element 8 surfaces formed the photocatalyst filter membrane.In water tank 20, inject waste water then, light ultraviolet germicidal lamp 6 again, open and adjust water valve 27 again, control water flow meter 28 is at suitable water flow, determine the residence time of waste water in the utility model according to waste water quality, unnecessary waste water then is back to water tank 20.When waste water was flowed through the photocatalyst filter membrane, under ultraviolet irradiation, photocatalyst was excited and produces the hydroxyl radical free radical (OH) with extremely strong oxidation capacity, can directly the organic pollutant in the water be degraded to CO 2, H 2Simple inorganics such as O.When photocatalysis oxidation reaction carried out, photocatalyst film was also at the performance filteration.Along with the carrying out of reaction, the filter cake layer on photocatalyst film surface is thickening slowly, and the head loss between the utility model reaction chamber and the clean water chamber will constantly increase.When head loss reaches 0.1Mpa or during the water flow that can not obtain to need by regulated valve 27, valve 25, gets final product stopped reaction, wash.Elder generation's valve-off 26, valve 27, valve-off 24 again, close intake pump 22.Open then that the photocatalyst filter membrane of the utility model blow-off valve more than 29,90% will come off and flow out, reclaim with water.Open valve 25, valve 30 again, open intake pump 22, the photochemical catalytic oxidation agent filter membrane on the counterflush filter element from top to bottom 8, the photocatalyst that washes can reclaim again and use.After filter element 8 is rinsed totally, can begin new film forming and reaction process.

Claims (2)

1. instant film-forming type photochemical catalytic oxidation water treatment device comprises flanged (FLGD) spherical upper cover (1), foraminous dividing plate (2), cylindrical housings (5), filter element (8), taper lower cover (9); Filter element (8) is is firmly connected and composed by top retaining plate (15), top board (16), Stainless Steel Cloth (17), post (18) and base plate (19); Fixedly connected with filter element nut (12), filter element bolt (13) with foraminous dividing plate (2) with the top retaining plate (15) that filter element (8) is solidified as a whole; Be solidified as a whole by bolt (3) and nut (4) foraminous dividing plate (2), housing (5) flanged (FLGD) spherical upper cover (1), intrinsic filter element (8); It is characterized in that: be provided with the ultraviolet germicidal lamp (6) that has quartz socket tube (7) in the filter element (8), ultraviolet germicidal lamp (6) passes spherical upper cover (1) and is connected with power supply; Can apply or remove photocatalyst film as required immediately on the Stainless Steel Cloth (17).
2. instant film-forming type photochemical catalytic oxidation water treatment device according to claim 1 is characterized in that: the also intrinsic water distribution board in lower end (10) in the described taper lower cover (9).
CN 02283501 2002-12-24 2002-12-24 Instant film-forming photocatalysis-oxidation water treating apparatus Expired - Fee Related CN2592632Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 02283501 CN2592632Y (en) 2002-12-24 2002-12-24 Instant film-forming photocatalysis-oxidation water treating apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 02283501 CN2592632Y (en) 2002-12-24 2002-12-24 Instant film-forming photocatalysis-oxidation water treating apparatus

Publications (1)

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CN2592632Y true CN2592632Y (en) 2003-12-17

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CN 02283501 Expired - Fee Related CN2592632Y (en) 2002-12-24 2002-12-24 Instant film-forming photocatalysis-oxidation water treating apparatus

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102897959A (en) * 2012-11-07 2013-01-30 河海大学 Integrated water treatment equipment and method
CN110294559A (en) * 2019-08-12 2019-10-01 佛山科学技术学院 A kind of photocatalytic water treatment device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102897959A (en) * 2012-11-07 2013-01-30 河海大学 Integrated water treatment equipment and method
CN110294559A (en) * 2019-08-12 2019-10-01 佛山科学技术学院 A kind of photocatalytic water treatment device

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