CN2523767Y - Sodium hypochlorite generators - Google Patents

Sodium hypochlorite generators Download PDF

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Publication number
CN2523767Y
CN2523767Y CN 02212885 CN02212885U CN2523767Y CN 2523767 Y CN2523767 Y CN 2523767Y CN 02212885 CN02212885 CN 02212885 CN 02212885 U CN02212885 U CN 02212885U CN 2523767 Y CN2523767 Y CN 2523767Y
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CN
China
Prior art keywords
sodium hypochlorite
electrolysis tube
electrolysis
hydrochloric acid
tube
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Expired - Fee Related
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CN 02212885
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Chinese (zh)
Inventor
林绍金
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Individual
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Individual
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Priority to CN 02212885 priority Critical patent/CN2523767Y/en
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Publication of CN2523767Y publication Critical patent/CN2523767Y/en
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Expired - Fee Related legal-status Critical Current

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The utility model discloses a sodium hypochlorite generation device used for producing the sodium hypochlorite solution, which is composed of a salt dissolving device, a high position balancing tank, a water pump balancing tank, a tubular type electrobath and an automatic hydrochloric acid cleaning device. The high position balancing tank ensures the electrolyte flow entering the electrolysis tube to keep balance, the device is additionally provided with a clean water back flush conduit, so the electrolysis tube and the subsidiary conduit in the electrobath can be conveniently cleaned after the electrolytic process every day; after the sodium hypochlorite generation device works for 1-2 months, the automatic hydrochloric acid cleaning device can completely clean the dirt in the electrolysis tube without dismantling the equipment, which can prolong the service life of the electrobath. The sodium hypochlorite solution production process of the utility model is automatic and has the advantages of easy operation, high output of chlorine, low salt consumption, long service life of the electrolysis tube, good sealing property of the whole equipment and so on.

Description

A kind of clorox generating unit
Technical field
The utility model relates to a kind of clorox generating unit.
Background technology
The chlorine bleach liquor is a kind of safe, sterilizing agent and oxygenant efficiently, is widely used in the sterilization of hospital sewage, sanitary sewage, industrial circulating water, Drinking Water etc., also can be used for containing the processing of cyanogen trade effluent, has functions such as bleaching, decolouring, deodorizing.Existing clorox generating unit adopts water pump that salt solution directly is sent to electrolytic tank electrolysis more, and electrolytic solution is not just substituted by new salt solution when electrolytic process is also abundant, makes that the clorox concentration that produces is very low; Secondly, electrolysis tube in the existing clorox generating unit electrolyzer is generally the 8-10 root, because the electrolysis tube radical is many, the resistance that forms is big, electric current by the time heat that produces also big, to such an extent as to after the clorox generating unit used for some time, the anode surface coating of last two electrolysis tubes came off easily, cause that electrolytic efficiency is low, current consumption big, reduced the concentration of clorox.During the work of clorox generating unit, to produce the precipitation of hydroxide of metal ions such as calcium magnesium on the negative electrode of electrolyzer, these settlings are deposited on cathode surface, not only influence anodic electroconductibility, and can cause between the cathode and anode when serious and be short-circuited, consequently increased the power consumption of producing clorox, the productive rate that has reduced clorox.The method that solves cathode deposit has at present: (1) washes away cathode surface by swiftly flowing salt solution, prevents the negative electrode fouling, and this method scale removal is difficult for thoroughly; (2) electrode tube is taken apart, used the hydrochloric acid soaking and washing, dissolving has been deposited on settling on the negative electrode, and this method is very loaded down with trivial details, has not only increased workload, and clean, when installing accidentally, break the component of equipment easily; (3) adopt negative electrode commutation descaling method, promptly in electrolyzer, increase an auxiliary cathode, when needs are removed the main cathode surface deposits, the main cathode commutation is anode, auxiliary cathode is as negative electrode, and settling dissolving that just can it is surperficial when main cathode uses as anode is removed, though this method is easy to operate, but in the as easy as rolling off a log damage of practical middle-jiao yang, function of the spleen and stomach, scale removal also is difficult for thoroughly.And existing clorox generating unit electrolyzer is used the cathode material of stainless material as electrolysis tube more; corrosion can not take place in stainless material in the electrolytic process under the protection of cathode potential; but outage back stainless steel surface contacts with the chlorine bleach liquor corrosion can take place; have a strong impact on the work-ing life of stainless steel cathode; iron, the chromium plasma of the stripping of the process of corrosion simultaneously have contamination to electrolytic solution, have limited the range of application of clorox generating unit.
Summary of the invention
In order to overcome the deficiency of existing clorox generating unit, the utility model provide a kind of cleaning easily and thoroughly, the high clorox generating unit of clorox concentration produced.
Comprising of the utility model clorox generating unit salt device, high-order equilibrium box, water pump equilibrium box, tubular type electrolyzer and hydrochloric acid automatic flushing device, high-order equilibrium box is connected by water sprayer with the water pump equilibrium box, the tubular type electrolyzer is connected with high-order equilibrium box by advancing brine pipeline, the hydrochloric acid automatic flushing device by with advance the pipeline that brine pipeline communicates and be connected with electrolyzer, be provided with clear water back flushing pipeline in the device, this pipeline is connected with electrolyzer.Industrial Salt process in changing the salt device is dissolved, forms saturated saline solution and is removed the salt solution liquid-storing box in the inflowization salt device behind the suspended substance.The water pump equilibrium box is furnished with into water float(ing)valve, on the water pump output channel water sprayer is housed, in order to suction salt solution saturated solution.During starting mode of pump, water sprayer is under water-aspirator pressure, form vacuum, the salt solution saturated solution is picked up, a spinner-type flowmeter is installed on the suction tube of water sprayer, is controlled the lifting capacity of saturated saline solution, make it to mix the back proportioning and become required brine concentration with the water sprayer injection water, be sent to high-order equilibrium box, in the electrolysis tube of spinner-type flowmeter inflow tubular type electrolyzer, carry out electrolysis again.Owing to be equipped with the balance float(ing)valve in the high-order equilibrium box, it makes the flow of electrolyte that enters electrolysis tube keep balance, promptly when electrolytic process is insufficient in the electrolysis tube, salt solution in the high-order equilibrium box no longer flows in the electrolysis tube, when being discharged into liquid-storing box Deng the chlorine bleach liquor who produces after the electrolysis fully, the salt solution in the high-order equilibrium box just begins to flow in the electrolysis tube.This just makes salt solution fully electrolysis in electrolysis tube, and the clorox concentration of generation improves greatly.Electrolysis tube adds up to the 2-6 root in the electrolyzer, the resistance that produces is few, thereby current consumption is few, the top coat difficult drop-off of anode tube, guaranteed carrying out smoothly of electrolytic process, because the enlarged diameter of cathode and anode pipe, the tube spacing of cathode and anode pipe is from being 3mm, thereby the surface-area when having increased the electrolysis of solutions makes the chlorine bleach liquor that electrolytic solution still can the output higher concentration under the few situation of electrolysis tube radical.Be provided with clear water back flushing pipeline in the clorox generating unit; after every day, electrolytic process finished; open back flushing pipeline valve; the pvc pipe that washes electrolysis tube and be connected 10 minutes with electrolysis tube; can not only prevent that effectively dirt deposits in a large number in the electrolysis tube; and can protect the stainless steel cathode pipe, prolong the work-ing life of cathode tube.After clorox generating unit work 1-2 month, hydrochloric acid in the hydrochloric acid automatic flushing device is sent to by acid proof pump circulation and advances the pipeline that brine pipeline links to each other, clean electrolysis tube with hydrochloric acid and reach the pvc pipe that is connected with electrolysis tube, scavenging solution is got back to again in the hydrochloric acid automatic flushing device, and the time only needs 20 minutes.
Adopt the utility model to produce clorox, the production whole process can be carried out automatically, adopts high-order equilibrium box to control the balance electrolysis, makes electrolytic process abundant, the clorox concentration height of generation; The electrolysis tube radical mostly is 6 most in the electrolyzer, and current consumption is few; Be provided with clear water back flushing pipeline and hydrochloric acid automatic flushing device, it is convenient to clean, and has prolonged the work-ing life of electrolysis tube.With the clorox generating unit of chlorine yield 500g per hour is example, and through Fujian Province Central Inspect Station's check, index is as follows:
Interventions Requested National standard Assay
1. direct current consumption ≤7.0kWh/kg ?4.2kWh/kg
2. ac consumption ≤10kWh/kg ?6.3kWh/kg
3. salt consumes ≤6.0kg/kg ?4.2kg/kg
4. effective chlorine density ≥8.0g/L ?8.9g/L
5. strenuous test time anode life ≥10h ?>24h
6. chlorine gas concentration in the environment <3.0mg/m 3 ?0.05mg/m 3
Description of drawings
Below in conjunction with drawings and Examples the utility model is further specified.
Fig. 1 is the structural representation of clorox generating unit
Embodiment
As shown in Figure 1, Industrial Salt dissolves, forms saturated saline solution and removes the salt solution liquid-storing box in the entering salt device 1 behind the suspended substance through mechanical stirring in changing salt device 1.Regulate the spinner-type flowmeter 2 on water sprayer 3 suction tubes earlier, control the lifting capacity of saturated saline solution, open the water pump 4.1 of water pump equilibrium box 4, with jet extracting principle, by water sprayer 3 saturated saline solution is picked up from the salt solution liquid-storing box, make it to mix the back proportioning and become required brine concentration with water sprayer 3 injection waters, be sent to high-order equilibrium box 5, from high-order equilibrium box 5, flow in the electrolysis tube 7 of electrolyzer again through spinner-type flowmeter 6, open liquid level ball valve 14, see to have or not salt solution to flow out, flow out if any salt solution, illustrate that salt solution has been full of whole electrolysis tube, at this moment turn on the power switch and carry out electrolysis.Open valve 8 simultaneously and regulate cooling water flow, the electrolyte temperature of cyclic electrolysis pipe end pipe is controlled between 20-35 ℃.After electrolysis was finished, solution flowed into liquid-storing box 9.When equipment needs operation continuously, the balanced reservoir pump switch can be pushed the automatic control gear, water pump is subjected to the back and forth operation automatically of liquid level control of high-order equilibrium box 5, and spinner-type flowmeter 2,6 also only needs to regulate once.The hypochlorite generator is controlled by the liquid level of liquid-storing box 9 and high-order equilibrium box 5, moves electrolytic process automatically.After every day, electrolytic process finished, valve-off 8,10 was opened back flushing pipeline valve 11, and flushing electrolysis tube 7 reaches pvc pipe 3-5 minute that is connected with electrolysis tube, and sewage flows away from end-of-the-pipe.After clorox generating unit work 1-2 month, hydrochloric acid in the hydrochloric acid automatic flushing device 12 is sent to by acid proof pump circulation and advances the pipeline that brine pipeline 13 communicates, clean electrolysis tube 7 with hydrochloric acid and reach the pvc pipe that is connected with electrolysis tube, scavenging solution is got back to again in the hydrochloric acid automatic flushing device 12, and flush time is 20 minutes.

Claims (2)

1. clorox generating unit, comprising salt device, water pump equilibrium box, tubular type electrolyzer, it is characterized in that: also comprise high-order equilibrium box and hydrochloric acid automatic flushing device, high-order equilibrium box is connected by water sprayer with the water pump equilibrium box, the tubular type electrolyzer is connected with high-order equilibrium box by advancing brine pipeline, the hydrochloric acid automatic flushing device by with advance the pipeline that brine pipeline communicates and be connected with electrolyzer, be provided with clear water back flushing pipeline in the device, this pipeline is connected with electrolyzer.
2. clorox generating unit according to claim 1 is characterized in that: electrolysis tube is the 2-6 root in the described tubular type electrolyzer, and the spacing of the cathode and anode pipe of electrolysis tube is 3mm.
CN 02212885 2002-02-10 2002-02-10 Sodium hypochlorite generators Expired - Fee Related CN2523767Y (en)

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Application Number Priority Date Filing Date Title
CN 02212885 CN2523767Y (en) 2002-02-10 2002-02-10 Sodium hypochlorite generators

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Application Number Priority Date Filing Date Title
CN 02212885 CN2523767Y (en) 2002-02-10 2002-02-10 Sodium hypochlorite generators

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CN2523767Y true CN2523767Y (en) 2002-12-04

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104975305A (en) * 2014-04-03 2015-10-14 开物科技股份有限公司 Hypochlorous acid water production system
TWI582360B (en) * 2013-01-28 2017-05-11 石井義久 Deodorization and sterilization apparatus
CN109371417A (en) * 2018-12-24 2019-02-22 成都科佑达技术开发有限公司 A kind of sodium hypochlorite electrolytic preparation device
CN109536987A (en) * 2018-12-26 2019-03-29 九阳股份有限公司 A kind of new structural electrolysis unit

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI582360B (en) * 2013-01-28 2017-05-11 石井義久 Deodorization and sterilization apparatus
CN104975305A (en) * 2014-04-03 2015-10-14 开物科技股份有限公司 Hypochlorous acid water production system
CN109371417A (en) * 2018-12-24 2019-02-22 成都科佑达技术开发有限公司 A kind of sodium hypochlorite electrolytic preparation device
CN109371417B (en) * 2018-12-24 2023-10-27 成都科佑达技术开发有限公司 Sodium hypochlorite electrolytic preparation device
CN109536987A (en) * 2018-12-26 2019-03-29 九阳股份有限公司 A kind of new structural electrolysis unit

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