CN2293761Y - Cooling & cool-storing apparatus for air conditioner - Google Patents
Cooling & cool-storing apparatus for air conditioner Download PDFInfo
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- CN2293761Y CN2293761Y CN 96245837 CN96245837U CN2293761Y CN 2293761 Y CN2293761 Y CN 2293761Y CN 96245837 CN96245837 CN 96245837 CN 96245837 U CN96245837 U CN 96245837U CN 2293761 Y CN2293761 Y CN 2293761Y
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Abstract
The utility model relates to a cold and heat production and cold and heat storage device for air conditioners. The utility model is characterized in that a cold production loop is additionally provided with a counter flow type subcooler which is communicated with a cold storage groove; the cold is stored to cause the cool medium to be subcooled, the cold storage quantity which higher than the return water temperature of the air conditioner is utilized, and then the limited temperature range of the cold storage for air conditioners is widened. The subcooler absorbs the residual heat which is lower than the return water temperature of a warm air blower in a heat production loop, and storages heat. The subcooler can be reformed into an evaporator to store heat in low-temperature for supplying heat. The lower limitation of the temperature of heat storage for supplying heat is widened. The cold and the heat storage in unit capacity are improved. The utility model can singly use water as the cold and the heat storage material. The utility model has the advantages that the operation is stable; the manufacture cost is low; the utilization rate is high; the utility model opens up a new path for cold storage air conditioners.
Description
The utility model relates to a kind of idle call refrigeration and cold accumulation or heats regenerative apparatus.
The cold accumulation air-conditioner device can be when electric power be abundant refrigeration and cold accumulation, and when power supply shortage, the cold of savings is replenished to use in refrigeration system, thereby can play regulate supply and demand, the effect of balance electrical network peak load difference, and can reduce operating cost, become various countries' technology of research promotion energetically.
Roll up (the special collection of cold-storage) according to Japanese " economizing energy " magazine (special collection) " utilization ice heat storage air conditioner makes the electric power utilization ratioization " and " freezing " magazine the 63rd, existing cold accumulation air-conditioner device is divided into two classes basically: a class is a cold accumulating device by ice, another kind of is to adopt fusing point to be higher than the cold-storage device of the phase transformation material (being called for short the PCM material) of zero degree (generally 4-8 ℃ of scope), this two classes device all is to utilize the air conditioner backwater to make to have held in the cold-storage groove cold and the mode agent for storage of coldness fusing of solidifying is utilized cold storage capacity, therefore its available cold storage capacity all must be the cold that the temperature of agent for storage of coldness is lower than the air conditioner return water temperature, and the cold storage capacity that is higher than the air conditioner return water temperature can not be utilized.The return water temperature that general Air-conditioner design adopts is 12 ℃, consider the heat transfer temperature difference factor again, then can only be below 10 ℃, if by cold-storage directly separately to the air conditioner cooling, then agent for storage of coldness only its temperature be lower than air conditioner below feed temperature 5-7 ℃ the time cold storage capacity just can be used effectively, limited by some air conditioner refrigerating unit compressor capacity, the evaporating temperature of its evaporimeter inner refrigerant is generally more than 4 ℃.Retrieval is so far China's patent documentation from 1985, for example application number is 9219770.9 and is called that the application number of " cold-storing peak-averting refrigeration air conditioner " and Japanese mitsubishi electric Co., Ltd. is 93102863.9, name is called " heat stored air conditioner " etc., all is subjected to the restriction of this cold-storage temperature.If consider the cold-storage heat transfer temperature difference, then the best of agent for storage of coldness melting point scope of solidifying should be at 6 ℃-8 ℃.In order to reduce the cost of cold-storage device, require the cold storage capacity of unit volume big as far as possible, therefore must select the big agent for storage of coldness of the suitable latent heat of phase change of melting point for use.The melting point of agent for storage of coldness reduces will cause device efficient reduction when cold-storage, and unit efficiency will be than the device that uses 8 ℃ of phase-change materials low about 30% when using the ice cold-storage.Yet be lower than in the so narrow temperature range of air conditioner return water temperature being higher than zero degree, select to store up that cold is big, stable performance, cheap agent for storage of coldness are suitable difficulty.According to phase change cold-storage device Japan sole agent Morley (MoLi) the latent heat of phase change cold-storage device design brief data introduction that Co., Ltd. provided of the U.S. in Japan, and Jiangsu HVAC refrigeration " ice cold-storage special edition " 95 year the 2nd phase introduction, 8.3 ℃ of PCM materials (a kind of band crystallization water complex salt) of Harvard University's exploitation and 5 ℃ PCM material, latent heat of phase change only is about 22.8 kilocalories/kilogram and 30 kilocalories/kilogram respectively, and price is expensive.Complex salt has ageing of performance and unstable defect.Though it is cheap that ice is made agent for storage of coldness, in order to allow water freezing, must arrange the very big heat transfer pipe network of density in the ice groove, cause the cost of ice groove also very high and efficient is low.In view of above reason, your cold storage capacity cost of the unit kilojoule of employed these two kinds of cold accumulation air-conditioner devices is all more expensive on market at present, becomes the main cause that is difficult to promote.
Japan's " freezing " magazine the 63rd volume has been introduced for No. 734 a kind of by the employing cold-producing medium excessively cold ice-storage air-conditioning device of NKK Corp in exploitation in 1988.This device is the evaporimeter of refrigerating circuit during both as cold-storage the coil pipe in the cold-storage ice groove, again as the subcooler of putting refrigerating circuit when cold.Do the evaporimeter time spent, the evaporation of coil pipe inner refrigerant is build-up ice the water in the cold-storage groove; Do the subcooler time spent, high temperature refrigerant makes the ice fusing also by cold excessively in the coil pipe.Utilized the raising degree of supercooling of all mentioning in refrigeration textbook or the Refrigeration Technique handbook in kind of refrigeration cycle can improve the principle of refrigerating capacity, the cold of the melting heat of ice is passed to the air conditioner backwater indirectly by making the cold excessively mode of cold-producing medium, manage the difficulty of outer molten ice and the ice storage rate of raising ice groove when solving fine and close freezing with this.This device adopts coiled cold-storage ice groove to make subcooler, the subcooler that formula is soaked in this pond carried out heat exchange by 0 ℃ of ice temperature when entering subcooler at the cold-producing medium more than 40 ℃ before this, about 25 ℃ of mean temperature difference, then cold-producing medium evaporates in evaporimeter, carry out heat exchange with about 7 ℃ mean temperature difference and air conditioner backwater again, this with the air conditioner backwater is directly compared with the mode of ice heat exchange of ice groove, heat transfer temperature difference has approximately increased degree more than 20, thereby the heat transfer irreversible loss of device is increased, efficient reduces.In addition, after the ice fusing finishes, water in the cold-storage groove is to rise with mean temperature, the temperature that causes cold-producing medium to be crossed after cold is also constantly gone up, cold-producing medium is crossed the cold cold that increases and is constantly reduced, device cooling unstable properties causes the above cold storage capacity of the inherent air conditioner return water temperature of cold-storage groove also to fail to be fully utilized.For large-scale cold-storage device, this has also increased the filling weight of the refrigeration working medium in the refrigerating circuit (refrigerant) and has increased flow resistance greatly, and is therefore also inadvisable.
The purpose of this utility model is to overcome the deficiency of above-mentioned existing cold accumulation air-conditioner device, a kind of temperature range that idle call cold-storage/heat accumulation limits of having widened is provided, the cold of the agent for storage of coldness that the air conditioner return water temperature that can utilize existing cold accumulation air-conditioner device to be difficult to make full use of is above comes cooling, can improve the unit volume cold storage capacity of existing agent for storage of coldness, and can make water have enough big sensible heat to come cold-storage as the agent for storage of coldness of idle call separately, the refrigeration and cold accumulation device that the low running cost of unit kJ (kilojoule) cold storage capacity initial cost is economized for idle call; In needs heat supply area, can also use double-purpose device instead, and can utilize the low-temperature heat accumulating amount that is higher than environment temperature and is lower than the water of warm-air drier return water temperature to come heat supply into water refrigeration/thermal storage heat/heat.
Accompanying drawing 1 is the flow process principle schematic of the utility model idle call refrigeration and cold accumulation device.
This idle call refrigeration and cold accumulation device, comprise the refrigeration and cold accumulation two large divisions, its refrigerating part contains the backwater of refrigerating circuit (GL) and cooling and feed water interface (10), (11), cold-storage partly contains cold-storage loop (SL), cold-storage is put cold loop and directly the air conditioner backwater put cold backwater and feed water interface (10), (11), described refrigerating circuit (GL) comprises compressor (1), condenser (2), high-pressure gas-liquid separator (14), subcooler (3), flow controller (4), evaporimeter (5) and cold-producing medium wherein, is connected and composed by connecting line; The water side of evaporimeter (5) both constituted cold-storage loop (SL) with the cold-storage groove that agent for storage of coldness is housed (6), mistake cold circulating pump (7), connecting pipe and refrigerating medium wherein, leave interface (10), (11) that can constitute evaporimeter cooling loop (VA) again with the coil pipe blower fan (9) of air conditioner, cooling circulating pump (8) and refrigerating medium, it is characterized in that in the described refrigerating circuit (GL) high-pressure gas-liquid separator (14) afterwards, the subcooler (3) adorned before of flow controller (4) is reverse-flow subcooler; By comprising subcooler (3) (water side), cold-storage groove (6) and at subcooler cold junction water inlet (S
1) to cold-storage groove cold junction delivery port (S
4) between and subcooler hot junction delivery port (S
2) to cold-storage groove hot junction water inlet (S
3) between connecting pipeline, be contained in the cold circulating pump of mistake (7) in the pipeline and the refrigerating medium (water) in the pipeline and constitute and be circulated throughout the cold cold loop of putting.
Described to be circulated throughout the cold cold loop of putting can be by cold-storage groove (6), at its cold junction delivery port (S
4) with the cold junction water inlet (S of subcooler (3)
1) between direct connecting line (S
4-S
1), the hot junction delivery port (S of subcooler (3)
2) with the hot junction water inlet (S of cold-storage groove (6)
3) between direct connecting line (S
2-S
3), the cold circulating pump of mistake (7) in the pipeline, subcooler (3) water side, and be contained in the cold excessively cold loop (GS) of putting of the direct circulation that the refrigerating medium (water) in the loop constitutes; Also can be by cold-storage groove (6), from cold-storage groove (6) cold side outlet (S
4) to mistake cold circulating pump (7), through pipe prong (S
5), to valve (V
3), to one-way valve (D
4), to the delivery port (E of evaporimeter (5)
2), to cooling circulating pump (8), to the connecting line (S of the feedwater interface (11) of air conditioner (9)
4-S
5-11) with from the backwater interface (10) of air conditioner (9), through valve (V
6), to the water inlet (E of evaporimeter (5)
1) after, change through pressure-reducing valve (JV
1), to valve (V
4), to pipeline prong (S
6), to valve (V
14), again to the cold junction water inlet (S of subcooler (3)
1) connecting line (10-E
1-S
6-S
1) and hot junction delivery port (S
2), to the hot junction water inlet (S of heat storage tank (6)
3) connecting line, subcooler (3) water side, the cold circulating pump of mistake (7) in the pipeline is put cold circulating pump (8), valve is contained in and cuts cryogen (water), the cold excessively cold loop (GSA) of putting of the indirect cyclic process that external air conditioner (9) constitutes in the loop.
The utility model idle call refrigeration and cold accumulation device is provided with promising minimizing or avoids hot backwater and the water conservancy diversion or the split-flow baffles of the mutual blending of groove inner cold water in the described cold-storage groove (6).The dividing plate of this anti-blending, can be to change flow direction but the diaphragm (12) of maintenance cold-storage groove fluid connection, it also can be the stationary barrier (13) that cold-storage groove is separated into two or more at least isometric(al) sections, or make a plurality of isometric(al) cold-storage grooves, wherein leaving a dead band or dead slot begins to put at cold-storage groove and is not filled with water in order to accept the hot backwater from subcooler when cold, all the other sections or groove are equipped with cold water, accept hot backwater by having used up new section (groove) being available behind the cold-storage water successively later on; By multistage cold-storage groove or a plurality of cold-storage groove that stationary barrier is separated, autocontrol valve is equipped with in the import and export of each groove of each section.
The utility model idle call refrigeration and cold accumulation device, described agent for storage of coldness can be separately a water, and it directly is contained in the cold-storage groove, and this moment, it also was a refrigerating medium; Or not only utilized the ice latent heat of fusion, but also utilized the frozen water of the sensible heat of water to use thing with; Or not only utilized PCM latent heat of phase change, but also utilize the thing of using with of the PCM material of sensible heat of PCM and refrigerating medium (water) and water; The fusing of described phase change cold accumulating agent-freezing point scope can expand to more than 10 ℃, below 27 ℃; For example, can select Na for use
2SO
410H
2O/NaCl/NH
4The complex salt of Cl (13 ℃ of fusing points), or C
16Paraffin (fusing point 14-18 ℃), or Na
2SO
410H
2O/0.45CaCl
2Complex salt (16 ℃ of fusing points).Described ice or PCM material are to be contained in respectively in the ball-type or flat container of sealing, then are deposited in the cold-storage groove again, are full of refrigerating medium around it.When ice was agent for storage of coldness, refrigerating medium was the anti-icing fluid that water and ethylene glycol are made into.
The utility model idle call refrigeration and cold accumulation device also can be used instead to refrigeration and cold accumulation and heats the accumulation of heat dual-purpose apparatus.
Accompanying drawing 2 is a kind of refrigeration and cold accumulation of the present utility model and the flow process principle schematic that heats the accumulation of heat dual-purpose apparatus.
This dual-purpose apparatus is characterised in that control valve (V is equipped with at the import and export two ends of subcooler (3)
9) and (V
10), and increase subcooler the is arranged bypass line (L of (3)
13-L
4) and bypath valve (V
11); From subcooler (3) outlet and subcooler discharge control valve (V
10) between increase cold-producing medium low-pressure steam pipeline (L between compressor (1) inlet
11-L
12) and control valve (V
8); From flow controller (4) outlet (L
5) respectively to subcooler (3) inlet (L
10) between increase cold-producing medium low pressure liquid pipeline (L
5-L
9-L
10) and check valve (D
3) and to condenser (2) outlet (L
2) between increase pipeline (L
9-L
2) and control valve (V
7), and to evaporimeter (5) inlet (L
6) between increase control valve (V
12); At control valve (V
12) outlet (L
6) with the inlet (L of high-pressure gas-liquid separator (14)
3) between increase high pressure refrigerant liquid mozzle (L
6-L
3) and check valve (D
2); At condenser (2) outlet (L
2) with the inlet (L of high-pressure gas-liquid separator (14)
3) between increase check valve (D
1), and in compressor turnover pipeline, the cross valve (T that changes refrigerant flow direction is housed
1, T
2, T
3, T
4).
Because the utility model adopts reverse-flow subcooler in refrigerating circuit, soaking the formula subcooler with the pond that prior art adopts compares, have following advantage: 1. cold-storage water and the cold-producing medium heat exchange temperature difference in subcooler reduces, and the heat transfer irreversible loss reduces, and unit efficiency improves; 2. the cold water inlet temperature of the temperature of subcooler cold junction refrigerant outlet and subcooler cold junction is approaching, and is promptly synchronous with cold-storage groove cold junction leaving water temperature, thereby can keep stable degree of supercooling, makes system also stable because of the refrigeration work consumption of crossing cold increase; 3. by regulating the flow of water side in the reverse-flow subcooler, the refrigeration work consumption that adjusting device increased easily; 4. can make cold-storage water go back up to higher temperature, for example reach 30 ℃ of environment temperatures, thereby can utilize the sensible heat of more agent for storage of coldness to come cold-storage.Improved the cold storage capacity of agent for storage of coldness unit volume; 5. reverse-flow subcooler heat exchange property is good, and is stable, so heat exchange area can reduce, the subcooler volume reduced, thereby can make close-coupled, saves equipment and materials; 6. the subcooler volume is little, and the refrigerant charging loading amount is reduced, and not only saves cost, but and the stabilising arrangement runnability; 7. the cold-producing medium minimizing reduces the refrigeration system flow resistance, thereby saves power.In a word, reduce from installation cost, running cost is saved, and all many-sides such as unit efficiency raising, stable performance all are beneficial to.
The utility model is by subcooler (3) (water side), cold-storage groove (6), at subcooler cold junction water inlet (S
1) to cold-storage groove cold junction delivery port (S
4) between and subcooler hot junction delivery port (S
2) to cold-storage groove hot junction water inlet (S
3) between connecting pipeline, be contained in the cold cold loop of putting that is circulated throughout that the cold circulating pump of mistake (7) in the pipeline and the refrigerating medium (water) in the pipeline constitute, the cold that can utilize the agent for storage of coldness of cold-storage groove to be higher than the air-conditioning return water temperature makes the liquid of the high pressure, high temperature refrigerant that flows through subcooler cold excessively, the cold-producing medium of crossing after cold has absorbed cold storage capacity, after flow controller (4) step-down, in evaporimeter, evaporate, and the cold storage capacity that absorbs is passed to the air conditioner backwater to increase unit circularly cooling amount mode to be lower than the air conditioner return water temperature.Directly be circulated throughout cold putting in the cold loop (GS) by what cold-storage groove (6), subcooler (3), circulating pump (7) constituted, refrigerating medium (water) is from the cold side outlet (S of cold-storage groove (6)
4), through cold circulating pump (7), flow through valve (V
2), valve (V
14), to subcooler cold junction water inlet (S
1) advance subcooler (3) water side, again from subcooler hot junction water side outlet (S
2), through regulating flow valve (V
1), to cold-storage groove (6) hot junction inlet (S
3), flow back to cold-storage groove (6).Thisly directly be circulated throughout the cold cold loop (GS) of putting, can be transferred to the air conditioner backwater to the agent for storage of coldness cold above and below the air conditioner return water temperature by the cold excessively mode of cold-producing medium, device is simple, convenient operation and control.In addition, at cold-storage groove (6) cold junction delivery port (S
4) and subcooler (3) cold junction water inlet (S
1) connecting line between series connection cold excessively the putting in the cold loop (GSA) of indirect cyclic process of advancing air conditioner (fan coil) (9) again, refrigerating medium (water) is from the cold side outlet (S of cold-storage groove (6)
4), through cold circulating pump (7), flow through flow control valve (V
3), check valve (D
4), at evaporator water side outlet (E
2), converge with air conditioner feedwater through evaporimeter cooling, through putting cold circulating pump (8), deliver to air conditioner (9), emit behind the cold in company with the air conditioner backwater, through valve (V
6), at evaporator inlet (E
1) shunting, through pressure-reducing valve (JV
1) and control valve (V
4), to S
6, through valve (V
14), to the cold junction water inlet (S of subcooler (3)
1), again through subcooler (3), the cold that is higher than the above backwater of air conditioner return water temperature is exchanged to after the high pressure, high temperature refrigerant, from the hot junction water side outlet (S of subcooler (3)
2), through flow control valve V
1, to cold-storage groove hot junction inlet (S
3), flow back to cold-storage groove (6).This indirect cyclic process is cold excessively puts cold circulation (GSA), format surface is to utilize the backwater of air conditioner to make refrigerant cold excessively, but because the recirculated water that the air conditioner cooling is used must replenish with cold-storage water, and can not replenish with other water that is higher than the air conditioner return water temperature, therefore remain in fact and shift cold storage capacity by making the cold excessively method of refrigerant with cold storage capacity.The cold storage capacity of the unit kilogram subcooler discharge that this method can shift equals the enthalpy difference of unit kg of water of the temperature difference of subcooler hot water outlet temperature and cold-storage groove cold water outlet temperature.When its advantage is to shift the cold storage capacity that is lower than the air conditioner return water temperature, its required subcooler heat exchange area is little than the former, but the Inlet and outlet water flow equilibrium that must keep cold-storage groove promptly must keep the air conditioner backwater to equate for the shunt volume of subcooler with the flow that cold-storage groove is given the air conditioner feedwater.Though control is complicated, can realize.
The utility model idle call refrigeration and cold accumulation device, owing in cold-storage groove, be provided with water conservancy diversion or split-flow baffles (12), thereby can reduce or avoid blending from low-temperature cold water in the high-temperature tempering of subcooler and the cold-storage groove, thereby avoid occurring the shortcoming reproduction that formula (ice groove) subcooler is soaked in the pond, cooperate reverse-flow subcooler, the advantage of reverse-flow subcooler can be given full play to.
Adopt the utility model idle call refrigeration and cold accumulation device, agent for storage of coldness can be separately a water.Because it is not difficult that general air conditioner is reduced to 4 ℃ to cold-storage water, when cold-storage water backheat to 30 ℃ in subcooler, then the available sensible heat cold storage capacity of unit kg of water be 108 kilojoules you (about 26 kilocalories), the latent heat of phase change of it and PCM agent for storage of coldness is more or less the same, but water is dirt cheap, stable performance, not aging, good heat-transfer, refrigerating efficiency height during cold-storage, technology is simple, has very big advantage.In addition, selecting water for use is independent agent for storage of coldness, heat the accumulation of heat time spent when changing in the winter time, establishing environment temperature is 5 ℃, the calculating from 10 ℃ to 50 ℃ of the available amount of stored heat of water, can reach 168 Jiao Er (about 40 kilocalories), also approaching with the latent heat of phase change of other phase change heat storage materials, the water of using as agent for storage of coldness like this, but the double as heat-storage agent is used again, thereby saved an other cover heat storage tank, the cost of dual-purpose apparatus is reduced greatly.
When the utility model idle call refrigeration and cold accumulation device changes refrigeration and cold accumulation into and heats the accumulation of heat dual-purpose apparatus, control valve (V is housed because of importing and exporting two ends at subcooler (3)
9) and (V
10), and increase the bypass line of subcooler (L is arranged
13-L
4) and by-passing valve (V
11); From subcooler (3) outlet and subcooler discharge control valve (V
10) between increase cold-producing medium low-pressure steam pipeline (L between compressor (1) inlet
11-L
12) and control valve (V
8); From flow controller (4) outlet (L
5) respectively to subcooler (3) inlet (L
10) between increase cold-producing medium low pressure liquid pipeline (L
5-L
9-L
10) and check valve (D
3), to condenser (2) outlet (L
2) between increase pipeline (L
9-L
2) and control valve (V
7), to evaporimeter (5) inlet (L
6) between increase control valve (V
12); At control valve (V
12) outlet (L
6) and high-pressure gas-liquid separator (14) inlet (L
3) between increase high pressure refrigerant liquid mozzle (L
6-L
3) and check valve (D
2), the outlet (L of condenser (2)
2) with the inlet (L of high-pressure gas-liquid separator (14)
3) between increase check valve (D
1); And in compressor turnover pipeline, the cross valve (T that changes refrigerant flow direction is housed
1, T
2, T
3, T
4).Above-mentioned design can make subcooler (3) make evaporimeter respectively, and subcooler and condenser are used.In the process of cool of doing the refrigeration and cold accumulation time spent, subcooler (3) transforms evaporimeter usefulness into, and at this moment, kind of refrigeration cycle (GSL) is: cold-producing medium from compressor (1) through cross valve (T
1), to condenser (2), give air exchange heat, again through check valve (D
1), high-pressure gas-liquid protractor (14), subcooler bypass pipe (L
13-L
4) and by-passing valve (V
11), to flow controller (4), again through check valve (D
3), advance the subcooler of using as evaporimeter (3), evaporation exchanges cold to being circulated in the cold refrigerating medium (water) of putting cold loop (GS) therein, and water is turned cold, and the cold-producing medium after the evaporation is through subcooler outlet (L
11) to compressor (1), the refrigerating medium that is cooled in subcooler is under the work that directly is circulated throughout the cold cold circulating pump of mistake (7) of putting cold loop (GS), be back to cold-storage groove (6), carry out heat exchange with the agent for storage of coldness of heat, agent for storage of coldness is lowered the temperature gradually, till the suitable low temperature of setting; Heating the accumulation of heat time spent, when the heat that is used for utilizing the heat storage tank that is lower than the warm-air drier feed temperature heats to warm-air drier (9) (former title air conditioner) heat supplying process, subcooler (3) transforms evaporimeter into to be used, the accumulation of heat of this moment heats heat supply circulation (GSAR): refrigerant vapour is discharged from compressor (1), through cross valve T
3Path advances by former evaporimeter (5) condenser in generation, through heat exchange heat is passed to the backwater of warm-air drier (9) in this condenser, then through check valve (D
2), high-pressure gas-liquid separator (14), subcooler by-passing valve (V
11), flow controller (4), check valve (D
3) laggard by former subcooler (3) evaporimeter in generation, after having absorbed heat from the hot water of heat accumulation groove, heat exchange evaporates therein, and vaporized refrigerant vapour is through subcooler outlet (L
11), control valve (V
8), to suction port of compressor (L
12), get back to compressor (1); Heat the accumulation of heat time spent heat heat supply and being lower than the low warm in the heat accumulation process of warm-air drier return water temperature, subcooler (3) is still as subcooler usefulness, this moment is cold excessively to heat circulation (GSR) and be: refrigerant vapour is from compressor (1) discharge, through cross valve T
3Path advances by former evaporimeter (5) condenser in generation, therein exchange heat is given the backwater of warm-air drier (9), then through check valve (D
2), high-pressure gas-liquid separator (14), subcooler (3), flow controller (4), control valve (V
7) after, advance the evaporimeter that substitutes by former condenser (2), after heat exchange has absorbed the heat of environment, cross cross valve (T therein
2) path is to suction port of compressor (L
12) get back to compressor (1).Because of carrying out (GSAR) circulation time, the hot water temperature of heat storage tank is than environment temperature height, thus heat circulation will provide than from the circulation of surrounding air heat absorption bigger heat power, heating fan is used.When carrying out (GSR) circulation time, the condenser of former refrigerating circuit (2) is made evaporimeter usefulness, and subcooler (3) will provide the waste heat amount that is lower than the warm-air drier feed temperature to be used for heat accumulation to heat accumulation groove (6).In heating the full heat-accumulating process of accumulation of heat, former subcooler (3) transforms condenser usefulness again into, and the water side path water of evaporimeter (5) stops circulation, heats accumulation of heat circulation (ASR) this moment to be: after the compressed machine of cold-producing medium (1) compression is boosted, through cross valve (T
3) path and the check valve (D of path, pervaporation device (5)
2), the path of high-pressure gas-liquid separator (14), the preceding control valve (V of subcooler (3)
9), advance former subcooler (3) condenser in generation, through heat exchange heat is passed to recirculated water from heat accumulation groove (6) therein, be condensed into liquid, through flow controller (4), control valve (V
7) to the evaporimeter in former condenser (2) generation, absorbed the heat of environment betwixt after, through cross valve (T
2) path flows back to compressor (1).Carrying out the GSL circulation time, cold-storage groove (6) can obtain cold from subcooler (3) evaporimeter in generation, so the evaporimeter cold-storage loop (SL) in the alternative former refrigeration and cold accumulation device, (SL) loop connecting leg (S
5-E
2) and (S
6-E
1) can cast out as Fig. 2.
Owing to adopted above-mentioned a series of technical measures, the utility model refrigeration and cold accumulation and heat heat-storing device when being used for air-conditioning cooling/hot, compared with prior art, widened the temperature range of the available cold-storage/heat defined in the air-conditioning cooling (heat supply), existing refrigeration and cold accumulation unavailable cold storage capacity that is higher than the air-conditioning return water temperature also can be used for the air-conditioning cooling, also can be used for the warm-air drier heating to the quantity of heat storage that is lower than the warm-air drier return water temperature, thereby make the unit volume cold-storage/heat of the cold-storage/thermic devices that adopts ice or PCM phase change cold-storage material obtain to improve.Also can select for use, stable performance big at 10 ℃ to 27 ℃, latent heat of phase change in molten o'clock, cheap material to make cold-storage/heat accumulation material, cold-storage/thermic devices volume is reduced, investment of equipment reduces; What is more important, the utility model therefore make existing refrigeration and cold accumulation device the sensible heat of the water that can not utilize the separately scheme that is used for cold accumulation air-conditioner become feasible, a difficult problem of utilizing water to make agent for storage of coldness is separately solved, when adopting refrigeration and cold accumulation cooling of the present utility model and heating heat accumulation heat supply dual-purpose apparatus, optional water is made cold-storage (heat accumulation) material water cheapness separately, stable performance, good thermal conduction, transport easily, this will make the cost of cold-storage device and coolness storing material greatly reduce, cold accumulation air-conditioner device runnability is stable, reliability improves, the summer cold-storage, store away in winter heat, utilization ratio of device improves, operating cost is saved greatly, and you reduce the unit kilojoule by the cold-storage cost greatly.Thereby adopt the cold-storage heat-storage technology to open up new approach for promoting at central air conditioning plant.
Further specify embodiment of the present utility model below in conjunction with accompanying drawing.
Embodiment 1: accompanying drawing 3 is a kind of single refrigeration cold-storage device implementing procedure principle schematic that supplies the air-conditioning cold-room to use of the present utility model.Fluid flow distributor, visor, low-pressure gas-liquid separator and electric control system have been omitted among the figure.Refrigerating circuit in the present embodiment comprises: compressor 1, aerial condenser 2, high-pressure gas-liquid separator (liquid reservoir) 14, board-like reverse-flow subcooler 3, flow controller 4, evaporimeter 5, fill fluorine Lyons R in the loop
22Cold-producing medium; Cold-storage groove 6 is for dividing grooved, and being provided with code name is 6
1, 6
2, 6
3, 6
4Four branch grooves, control valve V is equipped with at every groove top respectively
31, V
32, V
33, V
33, V
34, with the cold-storage groove S of always intaking
3Be connected in parallel; Every groove bottom is equipped with control valve V respectively
41, V
42,, V
43, V
44, with total delivery port S of cold-storage groove
4Be connected in parallel.Wherein groove at first leaves a dead slot, and for example groove 6
1, the tabular PCM of volume 1/4th is housed in all the other grooves, this PCM material be contained in the rectangular plastic magazine, can to select for use by prescription be Na
2SO
410H
2O/NaCl/NH
4The complex salt hydrate that Cl constitutes, about 11 ℃-13 ℃ of its fusing point, latent heat of phase change is 180 kJ (kilojoule)/kilograms, adds full water then in groove; Directly being circulated throughout the cold cold loop of putting comprises: cold-storage groove 6, subcooler 3 (water side), connecting line S therebetween
1-S
4And S
2-S
3, the water adorned in the cold circulating pump 7 of mistake in the pipeline and the pipeline, constitute closed circuit GS, flow control valve V is housed in the loop
1In addition, the control valve V in the loop
2, be switching control valve used when need adopting that indirect cyclic process is cold excessively puts cold loop; Control valve V
13And V
14Set for switching to cold-storage loop SL; Cold-storage loop SL comprises: evaporimeter 5 (water side), cold-storage groove 6, connecting line E therebetween
1-S
6-S
7-S
3And E
2-S
5-S
4, at pipeline S
4-S
5In cold circulating pump 7, pipeline (S were housed
5-E
2) in flow-control transfer valve V is housed
3With check valve D
4, at pipeline S
6-E
1In control valve V is housed
4With pressure-reducing valve JV
1, at pipeline S
6-S
7Between and S
7-S
3Between V is housed respectively
13And valve V
1When carrying out cold-storage circulation time, valve V
5, valve V
6With valve V
14And valve V
2Close the branch valve that the cold-storage groove two ends divide valve to remove dead slot, for example V
31, V
41Outside closing, all the other are all open-minded.The cold excessively cold loop GSA of putting of indirect cyclic process is by the pressure-reducing valve JV that increases in the cold-storage loop
1, check valve D
4, transfer valve V
13, and at the valve V that directly is circulated throughout in the cold loop
2With valve V
14Make into afterwards.When carrying out this circulation time, valve V
2And V
13Close; Evaporimeter cooling loop comprises: evaporimeter 5, cooling circulating pump 8, interface 10 and 11, external air conditioner 9 is equipped with control valve V before the interface 11,10 of pipeline
5And V
6
When the circulation of carrying out refrigerating circuit GL and the circulation time of cold-storage loop SL, cold-producing medium goes out compressor 1, emits heat through condenser 2, through high-pressure gas-liquid separator 14, again through subcooler 3; Because of valve V
2, V
14Close, cold-producing medium does not carry out heat exchange in subcooler, and then cold-producing medium is through 5 evaporations of the laggard evaporimeter of flow controller 4 step-downs, through heat exchange cold is passed to the recirculated water of cold-storage loop SL betwixt, gets back to compressor 1.Among the SL of cold-storage loop, the water of circulation takes the cold that is absorbed from evaporimeter 5 to cold-storage groove 6, after heat exchange, makes the agent for storage of coldness cold accumulation cooling-down, then recirculated water is delivered to evaporimeter 5 exchanges to the heat that is absorbed again, and the temperature of agent for storage of coldness drops to till the suitable temperature that sets in cold-storage groove 6.
When carrying out refrigerating circuit GL and directly being circulated throughout cold cold loop GS and evaporimeter cooling loop VA circulation time, the valve V put
3, V
4, V
13Close, the cold water of cold-storage groove 6 is through cold circulating pump 7, valve V
2, valve V
14, to subcooler 3 water side entrance S
1, advance the water side of subcooler 3, through heat exchange the cold of agent for storage of coldness is exchanged to the high high pressure liquid refrigerant of temperature betwixt.Because the liquid refrigerant temperature of leaving condenser is generally up to more than 40 ℃, therefore the cold water through reverse-flow subcooler 3 water sides can backheat arrive quite high temperature, heat exchange area as subcooler 3 is provided with rationally, it is suitable to cross colod-application quantity of circulating water adjustment, cold water temperature can go back up to 25-30 ℃ or higher, and cold-producing medium then can cool to the inflow temperature near subcooler cold junction water inlet.Cross colod-application recirculated water again through valve V
1, to cold-storage groove hot water inlet S
3, flow back to the top of the hot water end of cold-storage groove 6, because cold-storage groove 6 when beginning to utilize the sensible heat cold storage capacity of cold-storage groove, after promptly cold-storage groove bottom coolant-temperature gage is higher than the agent for storage of coldness fusing point, must begin to carry out branch groove cooling for dividing a grooved.At first, divide valve V
31, V
42Open, all the other each minute valve close, so hot water is at first got back to dead slot 6
1, cold water is earlier with groove 6
2, when groove 6
2Cold water when using up, divide valve V
32, V
43Open and divide valve V
31, V
42Close, go successively later on, avoided the hot water and the cold water blending of returning, thereby can guarantee that the cold water that is sent to subcooler 3 from the regenerator bottom can both carry out work with the temperature of initial cold-storage in the long duration from subcooler 3.When the phase transformation material heat exchange in hot water and the cold-storage groove 6, because the hot water temperature is far above the fusing point of phase transformation material, institute is so that putting of phase change cold-storage material coldly also becomes easy, and it is more thorough to put cold energy, and PCM is hidden in the hiding at latent heat more than 12 ℃ and sensible heat can be made full use of.And the cold excessively cold-producing medium that has absorbed cold storage capacity is when evaporimeter 5 evaporations, in the unit interval, can provide than cold circulation more refrigeration capacity only to the backwater of air conditioner 9, increase share and equal the cold that cold-producing medium was drawn from the circulating water of subcooler 3 in the unit interval; Degree of supercooling is big more, and it is many more to increase refrigerating capacity.With R
22Cold-producing medium is an example, and when being chilled to 12 ℃ and evaporating temperature from 48 ℃ of mistakes and being 0 ℃, comparable only cold circulation increases by about 30% refrigerating capacity.
When carrying out refrigerating circuit GL, taking over cold cold loop GSA, evaporimeter cooling loop VA circulation time, the V put
2, V
13Close, the cold water of cold-storage groove 6 is delivered to the delivery port E of evaporimeter 5 through pump 7
2, with air conditioner 9 recirculated water blending after evaporimeter 5 cooling after cooling circulating pump 8 is sent to air conditioner 9, and the air conditioner backwater is advancing evaporimeter 5 water side entrance E
1Splitter section is through valve JV before
1, valve V
4, valve V
14To subcooler 3 water inlet S
1, backheat is delivered to cold-storage groove 6 again to high temperature after subcooler 3 and cold-producing medium heat exchange.The hot water flow that the cold water flow that the working method requirement in this loop is sent from cold-storage groove 6 must equal to flow into.This circulation is to utilize the air conditioner backwater to make the cold excessively circulation of cold-producing medium, takes over the cold cold circulation of putting between also claiming.The cold that this circulation increases to air conditioner equals this to be taken over and coldly puts recirculated water among the cold loop GSA and reduce to the cold that temperature that cold-storage groove 6 cold water bring out mouthful is emitted from the temperature of subcooler 3 delivery port S2, is that this recirculated water is from subcooler 3 delivery port S by crossing the cold that cold form shifts wherein
2Temperature reduce to the air conditioner backwater at subcooler 3 water inlet S
1The temperature cold of emitting.When valve V
13Open, valve V
14When closing, take over and coldly to put cold circulation GSA and become and utilize the air conditioner backwater directly to make agent for storage of coldness put the cold cold circulation of directly putting, this circulation only is suitable for the situation that the agent for storage of coldness temperature is lower than the air conditioner return water temperature.At this moment, if valve V
13With valve V
14Open, take over the cold cold-peace of putting between can carrying out and directly put cold combined cycle, this circulation is more suitable for the enclosed cold-storage groove; For the open type cold-storage groove, then Flow-rate adjustment bothers.
The reverse-flow subcooler that present embodiment is used can be reverse-flow plate type heat exchanger or reverse-flow shell and tube exchanger, and also the counter current exchanger of available other patterns substitutes.The heat exchange amount of subcooler is about the 30-40% of former refrigerating capacity.
Embodiment 2.But present embodiment is a kind of not only refrigeration and cold accumulation cooling of the present utility model but also the dual-purpose apparatus that can heat storage heating.
Fig. 2 is for changing the refrigeration and cold accumulation cooling apparatus of the utility model idle call in the embodiment schematic diagram of the cold, hot two-purpose device that also can be used for heating the heat accumulation heat supply.Some accessories among Fig. 2 as high and low pressure gas-liquid separator, drier etc., omit and do not draw.This cold, hot two-purpose device comprises refrigeration and cold accumulation and heats the heat accumulation two large divisions, and leaves and the feed pipe of air conditioner/warm-air drier and the interface 11 and 10 that return pipe joins.Its refrigerating/heating partly is to have increased the cross valve (T that changes the airflow direction of compression in former single refrigeration cold-storage device
1～T
4) and keep the check valve D that joint device 4 flows to
1, D
2, control valve V
7And V
12, inducer and the outlet section at subcooler 3 increased control valve V in addition
9And V
10, increased the bypass pipe L of subcooler 3
13-L
4With by-passing valve V
11, increased from subcooler outlet L
11To suction port of compressor L
12Low pressure steam line L
11-L
12With control valve V
8Cold-storage/heat accumulation agent water, cold-storage/heat accumulation groove adopts vertical split-flow baffles type.
This cold, hot two-purpose device is in the process of cool that refrigeration and cold accumulation is used, former subcooler 3 is made evaporimeter usefulness, and the refrigerating circuit circulation route of this process is: cold-producing medium is discharged from compressor 1, through cross valve T1 path, to condenser 2, give surrounding air exchange heat through heat exchange therein; The cold-producing medium that becomes highly pressurised liquid is through check valve D
1, high-pressure gas-liquid separator 14, subcooler bypass pipe L
13-L
4With by-passing valve V
11, to flow controller 4, step-down is after check valve D
3Flow to by the former subcooler evaporimeter in 3 generations, therein through heat exchange, cold-producing medium exchanges cold to the recirculated water from cold-storage groove 6, and the cold-producing medium that flashes to steam is through low pressure steam line L
11-L
12With control valve V
8Flow back to compressor 1.Water in cold-storage groove 6 and subcooler 3 water sides and the loop thereof is under the driving of crossing cold circulating pump 7, and circulation is endlessly passed to agent for storage of coldness to the cold of refrigerating circuit, makes agent for storage of coldness cooling cold-storage.
When carrying out refrigeration and cold-storage associating cooling, refrigerating circuit recovers the running status of the cold kind of refrigeration cycle GL of mistake as shown in Figure 1, and subcooler 3 is still made subcooler usefulness, the by-passing valve V of subcooler 3
11Close control valve V
8Close valve V
7Close valve V
9, V
10And V
12Open direct cold excessively cold loop GS work, the valve V of evaporimeter cooling loop VA put
5, V
6Open, 8 work of cooling circulating pump at this moment, were passed through cold circulation, and the cold that is higher than the air conditioner return water temperature also can append to use in refrigeration system.
When this cold, hot two-purpose device is heating the state that heat accumulation is used, former cold-storage groove 6 existing becoming are the heat accumulation groove, and former cooling circulating pump 8 now is the heat supply circulating pump, can carry out following 3 kinds of circulations.
(1). the cold excessively heat supply circulation GSR that heats:
Valve T in the device
1, T
4, V
8, V
11, V
12Close all the other control valve T
2, T
3, V
9, V
10, V
1, V
5, V
6, V
7Open, cold-producing medium is discharged from compressor 1, through cross valve T3, advances the condenser that is substituted by former evaporimeter 5, gives the recirculated water of evaporimeter heat supplying loop exchange heat through heat exchange therein, i.e. the backwater of warm-air drier 9, and condensation of refrigerant becomes highly pressurised liquid, through check valve D
2, high-pressure gas-liquid separator 14, control valve V
9To subcooler 3, through heat exchange the waste heat that is lower than warm-air drier 9 feed temperatures is exchanged the recirculated water of putting cold loop GS to cold excessively therein; Cold-producing medium crosses cold after control valve V
10, advancing flow controller 4 step-downs, low pressure refrigerant is through control valve V
7,,, absorb heat after cross valve T therein with the outside air heat exchange to the evaporimeter that substitutes by former condenser 2
2Path returns compressor.The direct cold excessively cold loop GS of putting is under the driving of crossing cold circulating pump 7, and its recirculated water constantly is transferred to heat the heat accumulation agent (water) of heat accumulation poor 6 from subcooler 3.The circulation of the heat supplying loop that condenser, cooling circulating pump 8 and the warm-air driers 9 that substituted by former evaporimeter 5 are formed has been given warm-air drier heating the heat that circulation is higher than the warm-air drier feedwater, and room usefulness heats.
(2). accumulation of heat heats heat supply circulation GSAR:
Valve V in the device
7, V
9, V
10, V
12, T
1, T
4Close, all the other control valves are opened, and cold-producing medium is discharged from compressor 1, through cross valve T
3, advance by the former evaporimeter condenser in 5 generations, therein exchange heat is given the backwater of warm-air drier 9, condensation of refrigerant becomes high-pressure fluid, through check valve D
2, high-pressure gas-liquid separator 14, change its course through by-passing valve V
11 Advance flow controller 4, after the throttling step-down, through check valve D
3Advance by the former subcooler evaporimeter in 3 generations, absorb from the heat of the recirculated water of heat storage tank 6 through heat exchange therein and evaporate, again through control valve V
8Flow back to compressor.Because the hot water temperature that heat storage tank provides is higher than environment temperature, so kind of refrigeration cycle can be supplied with more heat to warm-air drier 9.When water temperature approaches environment temperature in the heat accumulation groove 6, can switch to the cold heat supply circulation that heats.
(3). heat accumulation of heat circulation A SR:
This circulation only is that with the cold excessively difference that heats the heat supply circulation heat supplying loop is out of service when heating accumulation of heat, and promptly heat supply circulating pump 8 stops, control valve V
5, V
6Close.Carrying out this circulation time can make heat accumulation groove 6 interior heat-storage agents obtain to be higher than the temperature of warm-air drier backwater.For example 50 ℃.
Embodiment 3:
But Fig. 4 changes the another embodiment schematic diagram that double as heats the cold, hot two-purpose device that the heat accumulation heating plant uses into for the refrigeration and cold accumulation cooling apparatus of the utility model idle call.The difference of this device and embodiment 2 only is from crossing cold circulating pump 7 outlet S
5Water side outlet E to evaporimeter 5
2, flash-pot 5 water side entrance E
1To subcooler 3 water side entrance S
2Between increased pipeline S as shown in Figure 3
5-E
2And S
6-E
1And pipeline S
6-S
7, increased valve V
2, V
3, V
4, V
13, V
14And check valve D
4, pressure-reducing valve JV
1, also can carry out 1 described of embodiment thus and take over and coldly put cold circulation and directly put cold/heat release circulation.
Claims (5)
1. idle call refrigeration and cold accumulation device, comprise the refrigeration and cold accumulation two large divisions, its refrigerating part contains the backwater of refrigerating circuit (GL) and cooling and feed water interface (10), (11), cold-storage partly contains cold-storage loop (SL), cold-storage is put cold loop and directly the air conditioner backwater put cold backwater and feed water interface (10), (11), described refrigerating circuit (GL) comprises compressor (1), condenser (2), high-pressure gas-liquid separator (14), subcooler (3), flow controller (4), evaporimeter (5) and cold-producing medium wherein, is connected and composed by connecting line; The water side of evaporimeter (5) both constituted cold-storage loop (SL) with the cold-storage groove that agent for storage of coldness is housed (6), cooling circulating pump (8), connecting pipe and refrigerating medium wherein, left interface (10), (11) that can constitute evaporimeter cooling loop (VA) with coil pipe blower fan (9), cooling circulating pump (8) and the refrigerating medium of air conditioner again; It is characterized in that in the described refrigerating circuit (GL) high-pressure gas-liquid separator (14) afterwards, the subcooler (3) adorned before of flow controller (4) is reverse-flow subcooler; By comprising subcooler (3) (water side), cold-storage groove (6) and at subcooler cold junction water inlet (S
1) to cold-storage groove cold junction delivery port (S
4) between and subcooler hot junction delivery port (S
2) to cold-storage groove hot junction water inlet (S
3) between connecting pipeline, be contained in the cold circulating pump of mistake (7) in the pipeline and the refrigerating medium (water) in the pipeline and constitute and be circulated throughout the cold cold loop of putting.
2. idle call refrigeration and cold accumulation device as claimed in claim 1 is characterised in that to be provided with the dividing plate that reduces or avoid hot backwater and the mutual blending of groove inner cold water in the described cold-storage groove (6).
3. idle call refrigeration and cold accumulation device as claimed in claim 1 is characterised in that described agent for storage of coldness is separately a water.
4. idle call refrigeration and cold accumulation device as claimed in claim 1 is characterised in that described agent for storage of coldness adopts fusing point at 10-27 ℃ phase-change material.
5. idle call refrigeration and cold accumulation device as claimed in claim 1 is characterized in that control valve (V is equipped with at the import and export two ends of described subcooler (3) when it being used instead for refrigeration and cold accumulation and heating the accumulation of heat dual-purpose apparatus
9) and (V
10), and increase subcooler the is arranged bypass line (L of (3)
13-L
4) and bypath valve (V
11); From subcooler (3) outlet and subcooler discharge control valve (V
10) between increase cold-producing medium low-pressure steam pipeline (L between compressor (1) inlet
11-L
12) and control valve (V
8); From flow controller (4) outlet (L
5) respectively to subcooler (3) inlet (L
10) between increase cold-producing medium low pressure liquid pipeline (L
5-L
9-L
10) and check valve (D
3), to condenser (2) outlet (L
2) between increase pipeline (L
9-L
2) and control valve (V
7), to evaporimeter (5) inlet (L
6) between increase control valve (V
12); At control valve (V
12) outlet (L
6) with high-pressure gas-liquid separator (14), inlet (L
3) between increase high pressure refrigerant liquid mozzle (L
6-L
3) and check valve (D
2); At condenser (2) outlet (L
2) with the inlet (L of high-pressure gas-liquid separator (14)
3) between increase check valve (D
1), and in compressor turnover pipeline, the cross valve (T that changes refrigerant flow direction is housed
1, T
2, T
3, T
4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96245837 CN2293761Y (en) | 1996-11-10 | 1996-11-10 | Cooling & cool-storing apparatus for air conditioner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96245837 CN2293761Y (en) | 1996-11-10 | 1996-11-10 | Cooling & cool-storing apparatus for air conditioner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN2293761Y true CN2293761Y (en) | 1998-10-07 |
Family
ID=33918743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96245837 Expired - Fee Related CN2293761Y (en) | 1996-11-10 | 1996-11-10 | Cooling & cool-storing apparatus for air conditioner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN2293761Y (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306223C (en) * | 2002-07-12 | 2007-03-21 | 松下电器产业株式会社 | Air-conditioner |
| CN100458293C (en) * | 2007-07-05 | 2009-02-04 | 南京大学 | Self circulation type cold storage air conditioner system |
| CN105823152A (en) * | 2016-04-06 | 2016-08-03 | 广东美的制冷设备有限公司 | Air conditioner system and control method thereof |
| CN109294523A (en) * | 2018-10-18 | 2019-02-01 | 浙江大学山东工业技术研究院 | A kind of cold accumulation air-conditioner |
| CN110173779A (en) * | 2019-05-29 | 2019-08-27 | 中国科学院广州能源研究所 | A kind of big temperature difference cold supply system of combined type and its control method |
| CN110226068A (en) * | 2017-01-17 | 2019-09-10 | 株式会社Ed7 | Waste Heat Recovery type mixing heat pump system |
| CN113310339A (en) * | 2021-06-16 | 2021-08-27 | 北京建筑大学 | Electric energy storage utilization method utilizing peak-valley load difference of power grid |
-
1996
- 1996-11-10 CN CN 96245837 patent/CN2293761Y/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306223C (en) * | 2002-07-12 | 2007-03-21 | 松下电器产业株式会社 | Air-conditioner |
| CN100458293C (en) * | 2007-07-05 | 2009-02-04 | 南京大学 | Self circulation type cold storage air conditioner system |
| CN105823152A (en) * | 2016-04-06 | 2016-08-03 | 广东美的制冷设备有限公司 | Air conditioner system and control method thereof |
| CN105823152B (en) * | 2016-04-06 | 2018-09-04 | 广东美的制冷设备有限公司 | Air-conditioning system and its control method |
| CN110226068A (en) * | 2017-01-17 | 2019-09-10 | 株式会社Ed7 | Waste Heat Recovery type mixing heat pump system |
| CN110226068B (en) * | 2017-01-17 | 2022-05-31 | 株式会社Ed7 | Waste heat recovery type hybrid heat pump system |
| CN109294523A (en) * | 2018-10-18 | 2019-02-01 | 浙江大学山东工业技术研究院 | A kind of cold accumulation air-conditioner |
| CN110173779A (en) * | 2019-05-29 | 2019-08-27 | 中国科学院广州能源研究所 | A kind of big temperature difference cold supply system of combined type and its control method |
| CN110173779B (en) * | 2019-05-29 | 2024-05-17 | 中国科学院广州能源研究所 | Combined type large-temperature-difference cooling system and control method thereof |
| CN113310339A (en) * | 2021-06-16 | 2021-08-27 | 北京建筑大学 | Electric energy storage utilization method utilizing peak-valley load difference of power grid |
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| CF01 | Termination of patent right due to non-payment of annual fee |