CN2245056Y - Device for preparation of ozone water and treatment - Google Patents

Device for preparation of ozone water and treatment Download PDF

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Publication number
CN2245056Y
CN2245056Y CN 95221691 CN95221691U CN2245056Y CN 2245056 Y CN2245056 Y CN 2245056Y CN 95221691 CN95221691 CN 95221691 CN 95221691 U CN95221691 U CN 95221691U CN 2245056 Y CN2245056 Y CN 2245056Y
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water
gas
ozone
ozone water
ozonizer
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CN 95221691
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刘力群
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Tsinghua University
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Tsinghua University
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  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

The utility model relates to a device for preparation and treatment of ozone water. An ozone generator can convey prepared ozone to a gas-water mixing chamber composed of N (N = 1, 2, 3...) stages of Venturi tubes through an ozone conveying pipeline. The prepared ozone then can enter a swirl electric field treatment chamber through the contact reaction of a fixing screw flow mixing pipe and / or a multi-node orifice-plate flow mixing pipe to cause gas-water mixed solution to cool the ozone generator. The treatment efficiency can be increased in the electric field treatment of the gas-water mixed solution. The utility model has the advantages of good disinfecting effect, dozen of times extended service life, no pollution and no residual toxicity, and is used for disinfection and water treatment of travel industries, catering industries, service industries, hospitals, families and public places.

Description

Contain ozone water and carry out the device that ozone water is handled a kind of the preparation
The utility model relates to a kind of water treatment device, and particularly a kind of promptly can providing contains ozone water to be used for its place, can finish processing, purification, disinfectant devices such as ozone oxidation to water, electric field again in this device.
Usually the method that water is sterilized, disinfected has: chemical classes: chlorine method, iodine method etc., physics class: uviolizing, activated carbon, adsorption filtration, high-temperature sterilization, embrane method etc.Because contaminated being on the rise of nature water body, tradition has exposed some drawbacks to sterilization, the sterilization method of water.As: use the chlorine disinfectant processing can cause generating in the water THM (halohydrocarbon, carcinogens); Uviolizing also owing to the penetrativity limited (only tens mms) of ultraviolet ray in water body make disinfect very not thorough.In disinfection treatment method before or owing to the cost height, or owing to complicated operation, use inconvenience, or because treatment effect is bad, and use is restricted.
Ozone is a kind of extremely strong oxygenant, and its standard oxidation potential is-2.07Ve to be only second to fluorine and atomic oxygen; Ozone still is a kind of broad-spectrum biocide, at normal temperatures, prokaryotic organism, straight nuclear biology, protozoon, metazoan is all had extremely strong kill activity, thus, can finish for bacterium mould, algae, virus, moment and to kill disinfection; And the ozone final product is an oxygen, and therefore, ozone is a kind of wide spectrum, powerful disinfectant that does not have residual hazard.
Ozone at sterilization, disinfectant simultaneously, the all right effectively degraded poison that meets, nuisance, plant matter, sulfide, kelene agrochemical as alkane, benzene, phenol, the bitter edible plant, anthracene, alkylbenzene, chlorobenzene, oil of mirbane, organic amine, xylogen, corruption, also can destroy the prussiate and the strong carcinogens such as benzo (a) pyrene, benzanthrene of severe toxicity.Ozone can also be removed metal ions such as iron in the water, manganese, and is to colourity, the turbidity of water body, also very effective to the removal of special odor mouthfeel.
At present the domestic type water purification, disinfect device, adopt activated carbon adsorption mostly, or use the micro-filtration or the ultrafiltration of fiber or film, sterilization ultraviolet ray, triiodide resin or the silver ionss of using more.These the device all exist disinfect effect and work-ing life limited problem.And the ozone equipment of the water treatment that is useful in the past all is the very numerous and jumbled technical scale main equipment of equipment, only limits to disinfecting of central water supply.
Water typeization a kind of novelty, little that the purpose of this utility model provides, long-life, with the air be raw material only the preparation of consumed power contain ozone water or directly carry out the innoxious device of ozonize.
The purpose of this utility model provides a kind of hypomegetic ozonizer of producing ozone with corona discharge method.
The purpose of this utility model provides a kind of n (n=1,2,3 ...) level Venturi meter gas, the water dissolving device formed; Behind its final stage expansion section, adopt fixing spiral multinode orifice plate mixed flow also can change the current vector direction structure the miscible device of gas, water, be used for containing transfer and the diffusion of ozone in water body of ozone gas.
The purpose of this utility model provides a kind of new structure formation: the shell of ozonizer is as the part of gas, the miscible device of water, make the water of handling through this device, when carrying out ozonize, also can carry out electric field treatment, can improve processing efficiency and can cool off ozonizer again.
The utility model is realized by following proposal: contain ozone water and carry out the device that ozone water is handled a kind of the preparation, comprise ozonizer, air pretreater 17 power supply circuit boards 2 and contain ozone gas and the miscible reaction unit of water, it is characterized in that: the upper chamber that is communicated with high voltage electrode 5 25 of ozonizer passes through vent line 18 connection air pretreaters 17; Forming lower chamber 26, the logical ozone pipeline 14 that gas corona discharge chamber 6 is communicated with between the insulating medium layer 7 by isolated high-voltage electrode 5 and ground connection low-field electrode 9 and high voltage electrode is communicated with by n level n=1,2,3 ... the miscible chamber 12 of gas, water that Venturi meter is formed; The final stage of described gas, the miscible chamber of water expands the affixed inwall of section section the mixed flow tube 131 of spiral and/or the mixed flow tube 132 that inwall is provided with the multinode orifice plate is set fixedly; Water-in 10 is communicated with the ozone water water outlet 16 that is fixed in shell 8 one ends by gas, the miscible chamber 12 of water, mixed flow tube 131,132.Power supply 1 connects the power supply circuit board 2 of adjustable voltage, telecommunications, frequency, pulsewidth, through the high voltage electrode 5 of step-up transformer 3, output lead 4 feed-in ozonizers.The high-voltage electrode 5 that ozonizer is made of conductive metal pipe, be arranged at the insulated dielectric tube 7 in the outside, be arranged at and leave the formed gas corona discharge chamber 6 in gap between insulated dielectric tube 7 and the interior high-voltage electrode 5, and, form by water, shell 8, the ground connection low voltage electrode 9 that is dipped in the water in the insulated dielectric tube outer rim.Air pretreater 17 is dry air treater or oxygen-rich treated device.Upper chamber 25 1 ends of ozonizer are provided with the interface 181 that is communicated with vent line 18, following tracheae 26 1 ends of ozonizer are provided with the interface 141 of output ozone, described interface 141 is communicated with logical ozone pipeline 14, and the end interface in addition 142 of this pipeline 14 inserts gas, the miscible chamber 12 of water.Gas, the water mixed pipe line be made up of mixed flow tube 131 and/or 132 insert ozonizer at ozonizer bottom interface 133 places.Be connected in series a magnetic valve 11 with gas, water between the miscible chamber 12 at water-in 10.Ozonizer lower case 8 is whirlwind-type gas, water reaction and electric field processing chamber 15 with the gap of insulated dielectric tube 7.Gas passage is made up of high-voltage electrode pipe 5 inwalls and gas corona discharge chamber 6 in the ozonizer, exports 141 places at gas feed 181, ozone and is connected with upper and lower air chamber 25,26 respectively.By the high voltage power supply circuit that electronic component is formed, high-voltage output connects high-voltage electrode 5, and high voltage field is crossed over gas discharge chamber 6 and insulating medium layer 7, forms the loop at ground connection low electrode 9, and the energy of its conveying forms corona discharge in gas discharge chamber 6.The insulating medium layer 7 of ozonizer is simple glass, high boron hard glass, 95 material glass, silica glass, enamel or stupalith.
This preparation contains ozone water or ozone equipment for treating water is made up of high voltage circuit, ozonizer, air pretreatment unit, gas, the miscible reaction unit of water, and be contained within the same apparatus housing, form integral structure, have compact construction, volume little, in light weight, characteristics simple and direct, easy to use are installed.
This device also can be eliminated reduction treatment apparatus and some other attached parts of joining by in addition attached ozone tail gas.
The utility model can be widely used in the disinfecting and the water treatment sterilization of tourism, catering trade, service sector, hospital, family, car and boat and public health infrastructure, also can be used for mineral water disinfects, disease control and Preservation Treatment in aquaculture, the plant husbandry, and the assorted population center of loosing, provide disinfecting of water source from the beginning for oneself, that relieves the people in stricken areas and supply water temporarily disinfects, semi-conductor stamen sheet cleans, disinfecting of warehousing water, Highrise buildings water tank, water tower, some treatment of diseases, the sterilization of medicine equipment etc.
In structure design of the present utility model, gas, the miscible reaction unit of water are adopted n (n=1,2,3 ...) dissolving device formed of level Venturi meter, and adopting fixedly at its final stage expansion section, spiral links to each other with multinode orifice plate mixed flow tube and with ozonizer, set up the processing capacity of electric field to water, prolonged gas, the miscible flow process of water, gas, the miscible solution of water have cooled off ozonizer simultaneously.Above-mentioned measure impels processing efficiency height of the present utility model, and power consumption is about 40 watts.From work-ing life, the utility model working hour is tens thousand of hours, and conventional ultraviolet disinfector was only worked 2000-5000 hour.
In gas of the present utility model, the miscible contact reacts device of water, effectively utilized the ozonizer shell, gas, the miscible solution of water form eddy flow and have improved reaction effect like this, and are subjected to the processing of electric field, have cooled off ozonizer simultaneously.Air admission ozonizer after handling in addition is after the high-voltage electrode inside pipe wall enters the gas corona discharge chamber, also can cool off ozonizer, ozonizer is under gas, liquid dual cooling effect, heat dissipation problem has obtained fabulous solution, can improve the performance and the ozone output of ozonizer greatly.
The utility model is different from existing domestic type water treating device, utilize the ozone preparation to contain ozone water and carry out water treatment, ozone is a kind of strong oxidizer, and is again a kind of broad-spectrum sterilization and multiple hazardous and noxious substances had degraded, elimination effect, and itself does not stay residual hazard.
The utility model adopts the electronics high-tension circuit to drive, and its frequency, pulsewidth, voltage, electric current are all adjustable, thereby can regulate according to different targets, satisfies different requirements.
Fig. 1 the utility model structural representation
Fig. 2 ozonizer and high-voltage electric field diagrammatic cross-section
Fig. 3 gas, the miscible reaction unit diagrammatic cross-section of water
Now further narrate structure of the present utility model in conjunction with the accompanying drawings:
Referring to Fig. 1-3: the utility model is with ozone generating-device, and gas, the miscible contact reacts device of water are positioned in the same container casing, forms integrated apparatus.And ozonizer is communicated with gas, the miscible contact reacts device of water, make and contain ozone gas, the miscible contact reacts device connection of water, make to contain ozone gas, the miscible solution stream of water when ozonizer, further obtain the processing of electric field, simultaneously this gas, the miscible solution cooling of water ozonizer.
In ozone generating-device, comprise ozonizer, constitute the high voltage power supply circuit that is different from power frequency by electronic component; Dry air or oxygen-rich treated device 17.
High voltage power supply circuit plate 2 is made up of electronic devices and components, and signal source is provided by 3524 or 494 switch power special integrated manipulators, and high power transistor is used in inverter power output, or metal-oxide-semiconductor etc.Behind transformer 3 boosted voltages, be fed to ozonizer high-voltage electrode 5, the frequency of circuit, parameters such as pulsewidth are adjustable, to adapt to the different requirements of ozonizer.Attaching plug 1 meets civil power 220V, high pressure output lead 4, and connection terminal 24 inserts high voltage electrode 5.
Ozonizer adopts corona discharge method to produce ozone.Producer constitutes high-voltage electrode 5 by conductive metal pipe; The high-voltage electrode outside is an insulated dielectric tube 7, leave the gap between itself and high-voltage electrode, form gas corona discharge chamber 6, insulated dielectric tube external ground, water and ozonizer shell constitute, the low voltage utmost point 9, or establish a ground connection low voltage electrode in addition and place insulated dielectric tube to be dipped in water outward.The metal tube that constitutes high-voltage electrode is first-selected with the stainless steel, or uses aluminum pipe.Ground connection low voltage electrode 9 adopts plated film, the conductive layer of filming, conductive mesh, liquid or solid.
The insulating medium layer 7 of ozonizer adopts inorganic materials to make, as adopting simple glass, high boron hard glass, 95 material glass, silica glass or enamel, ceramic material.
Gas passage in the ozonizer is made up of high-voltage electrode pipe 5 inwalls and gas corona discharge chamber 6, at the import and export 181,141 of gas upper and lower air chamber 25,26 is set.End at upper chamber 25 is provided with interface 181, is communicated with air pretreater 17 by vent line 18.
Air pretreater 17 is handled for dry air or oxygen enriching is handled or both combinations.Dry air is handled and is adopted freezing, siccative absorption, or the chemical method drying.In adsorption desiccant, adopt silica gel, aluminium glue, molecular sieve.In oxygen enriching is handled, adopt membrane sepn oxygen enrichment or fractionation by adsorption oxygen enrichment.
End at lower chamber 26 is provided with ozone gas output interface 141.Be communicated with the interface 142 of gas, the miscible chamber of water and the ozone of ozonizer output is imported water, the miscible chamber 12 of water by logical ozone pipeline 14.
Oxygen molecule in the gas further synthesizes the formation ozone molecule, its reaction formula with oxygen molecule after being ionized and being decomposed into Sauerstoffatom:
Ionization
Figure Y9522169100111
Gas, the miscible contact reacts device of water comprise: by the water-in 10 of magnetic valve 11 control flooding velocity and speed; Be communicated with water-in 10 by n (n=1,2,3 ...) the miscible chamber 12 of gas, water formed of level Venturi meter; Behind gas, the miscible chamber of water final stage expansion section, adopt inwall with the fixedly mixed flow tube 131 of spiral or the mixed flow tube 132 that inwall has the multinode orifice plate, or both use simultaneously, constantly change the current vector direction; Mixed flow tube with at ozonizer, the interface 133 that is provided with in the lower case 8 is communicated with.Making and entering the gap of being made up of high voltage power supply circuit, ground connection low voltage electrode 9, shell 8 and insulating medium layer 7 through gas, the miscible solution of water is in whirlwind-type gas, water reaction and the electric field processing chamber 15, at this moment further obtain electric field treatment by gas, the miscible solution of water, improve processing efficiency.Finish in preparation ozone, constantly finish ozone and in water, shift and the process that spreads.
As required, the utility model also be provided with ozone tail gas eliminate reducing apparatus 19, referring to Fig. 1: the tail gas that enters from tail gas inlet mouth 20, by motor and fan 21, by sorbent material, the catalyzer 22 of electrical heating element or elimination ozone tail gas, ozone is converted into oxygen 23 discharges from the air outlet through handling.
Foul smell generation of the present utility model, diffusion transfer and gas, water reaction process are performed such:
Preparation ozone required air is after air pretreater 17 is handled, by vent line 18, enter upper chamber 25 from interface 181, flow through in the high-voltage electrode pipe by the top of high-voltage electrode pipe 5, enter gas corona discharge chamber 6 from the bottom outflow, the upper end that the gas behind the formation ozone rises to corona discharge chamber 6 enters lower chamber 26, after compiling, through the interface 141 logical ozone pipeline 14 of flowing through, enter gas, the miscible chamber 12 of water from interface 142; By magnetic valve 11 control with from the water of water-in 10 at n (n=1,2,3 ...) 12 li of dissolving devices forming of Venturi meter are miscible, after fixing spiral mixed flow tube 131 or miscible pipe 132 of multinode orifice plate or the further contact reacts of its both combination, enter the ozonizer shell from interface 133 and be reaction of whirlwind-type air water and electric field processing chamber 15, further flow out by water outlet 16 after the reaction treatment.This installs required electric energy and is obtained from utility grid by attaching plug 1, be modulated to required voltage, electric current, frequency, pulsewidth by power supply circuit board 2 after, by high voltage and current output lead 4 feed-in ozonizers.
Embodiment:
N (n=1,2,3 in gas, the miscible contact reacts device of water ...) Venturi meter adopts fixing spiral mixed flow tube 131 or multinode orifice plate mixed flow tube 132 or both to use simultaneously at the final stage expansion section, with perpendicular to ozonizer shell vertical axis, and rotate direction and ozonizer less than ± 45 at this vertical plane, gas, the miscible solution reaction of water, and be connected with electric field processing chamber 15, make the miscible solution of the gas, the water that enter this reaction chamber form eddy flow.
The frequency 10 of the high voltage power supply circuit that constitutes by electronic component 3-10 4HZ, voltage 10 3-10 4V.

Claims (11)

1, contains ozone water and carry out the device that ozone water is handled a kind of the preparation, comprise ozonizer, air pretreater (17) power supply circuit board (2) and contain ozone gas and the miscible reaction unit of water is characterized in that: the upper chamber (25) that is communicated with high voltage electrode (5) of ozonizer is communicated with air pretreater (17) by vent line (18); Forming lower chamber (26), the logical ozone pipeline (14) that gas corona discharge chamber (6) is communicated with between the insulating medium layer (7) by isolated high-voltage electrode (5) and ground connection low-field electrode (9) and high voltage electrode is communicated with by n level (n=1,2,3 ...) the miscible chamber of gas, water (12) formed of Venturi meter; The affixed inwall of final stage expansion section of described gas, the miscible chamber of water is provided with the mixed flow tube (132) that the fixing mixed flow tube of spiral (131) and/or inwall are provided with the multinode orifice plate; Water-in (10) is communicated with the ozone water water outlet (16) that is fixed in shell (8) one ends by gas, the miscible chamber of water (12), mixed flow tube (131), (132).
2, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: power supply (1) connects the power supply circuit board (2) of adjustable voltage, telecommunications, frequency, pulsewidth, through the high voltage electrode (5) of step-up transformer (3), output lead (4) feed-in ozonizer.
3, prepare ozone water and carry out the device that ozone water is handled by claim 1 is described, it is characterized in that: the high-voltage electrode that ozonizer is made of conductive metal pipe (5), be arranged at the insulated dielectric tube (7) in the outside, be arranged between insulated dielectric tube (7) and the interior high-voltage electrode (5) and leave the formed gas corona discharge chamber in gap (6), and, form by water, shell (8), the ground connection low voltage electrode (9) that is dipped in the water in the insulated dielectric tube outer rim.
4, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: air pretreater (17) is dry air treater or oxygen-rich treated device.
5, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: upper chamber (25) one ends of ozonizer are provided with the interface (181) that is communicated with vent line (18), following tracheae (26) one ends of ozonizer are provided with the interface (141) of output ozone, described interface (141) is communicated with logical ozone pipeline (14), and the end interface (142) in addition of this pipeline (14) inserts gas, the miscible chamber of water (12).
6, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: locate to insert ozonizer at ozonizer bottom interface (133) by gas, water mixed pipe line that mixed flow tube (131) and/or (132) are formed.
7, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: between water-in (10) and gas, the miscible chamber of water (12), be connected in series a magnetic valve (11).
8, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: ozonizer lower case (8) is whirlwind-type gas, water reaction and electric field processing chamber (15) with the gap of insulated dielectric tube (7).
9, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: gas passage is made up of high-voltage electrode pipe (5) inwall and gas corona discharge chamber (6) in the ozonizer, locates to be connected with upper and lower air chamber (25), (26) respectively in gas feed (181), ozone outlet (141).
10, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: the high voltage power supply circuit of forming by electronic component, high-voltage output connects high-voltage electrode (5), high voltage field is crossed over gas discharge chamber (6) and insulating medium layer (7), form the loop at ground connection low electrode (9), the energy of its conveying forms corona discharge in gas discharge chamber (6).
11, contain ozone water and carry out the device that ozone water is handled described the preparation by claim 1, it is characterized in that: the insulating medium layer of ozonizer (7) is simple glass, high boron hard glass, 95 material glass, silica glass, enamel or stupalith.
CN 95221691 1995-09-22 1995-09-22 Device for preparation of ozone water and treatment Expired - Lifetime CN2245056Y (en)

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Application Number Priority Date Filing Date Title
CN 95221691 CN2245056Y (en) 1995-09-22 1995-09-22 Device for preparation of ozone water and treatment

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Application Number Priority Date Filing Date Title
CN 95221691 CN2245056Y (en) 1995-09-22 1995-09-22 Device for preparation of ozone water and treatment

Publications (1)

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CN2245056Y true CN2245056Y (en) 1997-01-15

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CN 95221691 Expired - Lifetime CN2245056Y (en) 1995-09-22 1995-09-22 Device for preparation of ozone water and treatment

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Country Link
CN (1) CN2245056Y (en)

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