CN220438719U - Laminated glass and laminated glass control system - Google Patents
Laminated glass and laminated glass control system Download PDFInfo
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- CN220438719U CN220438719U CN202320695952.4U CN202320695952U CN220438719U CN 220438719 U CN220438719 U CN 220438719U CN 202320695952 U CN202320695952 U CN 202320695952U CN 220438719 U CN220438719 U CN 220438719U
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- 239000005340 laminated glass Substances 0.000 title claims abstract description 60
- 239000000758 substrate Substances 0.000 claims abstract description 175
- 239000011521 glass Substances 0.000 claims abstract description 116
- 239000003792 electrolyte Substances 0.000 claims abstract description 64
- 230000007704 transition Effects 0.000 claims abstract description 22
- 230000008859 change Effects 0.000 claims abstract description 9
- 230000005693 optoelectronics Effects 0.000 claims description 10
- 239000011324 bead Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000011244 liquid electrolyte Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000007784 solid electrolyte Substances 0.000 claims description 4
- 125000006850 spacer group Chemical group 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 153
- 239000000463 material Substances 0.000 description 22
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- -1 polypropylene carbonate Polymers 0.000 description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000005357 flat glass Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229920000767 polyaniline Polymers 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 3
- 229910013684 LiClO 4 Inorganic materials 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 3
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 238000001755 magnetron sputter deposition Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 229920005569 poly(vinylidene fluoride-co-hexafluoropropylene) Polymers 0.000 description 3
- 229920002239 polyacrylonitrile Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 229920000379 polypropylene carbonate Polymers 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 229910001558 CF3SO3Li Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- ZBTDXCKMNFFZGJ-UHFFFAOYSA-N fluoro(oxo)silicon Chemical compound F[Si]=O ZBTDXCKMNFFZGJ-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000013077 target material Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013292 LiNiO Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 238000010329 laser etching Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000005344 low-emissivity glass Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The embodiment of the utility model discloses laminated glass, which comprises the following components: a color changing assembly and a photoelectric display assembly; the color-changing component comprises: a first target substrate, a second target substrate, and an electrolyte layer interposed between the first target substrate and the second target substrate; the color-changing component is attached to the photoelectric display component through the second target substrate; the first target substrate includes: a first glass substrate; a first conductive layer on the first glass substrate; the main color-changing layer is positioned on the first conductive layer; a first transition layer between the primary color-changing layer and the electrolyte layer; the second target substrate includes: a second glass substrate; the second conductive layer is positioned on the second glass substrate; the auxiliary color-changing layer is positioned on the second conductive layer; and the second transition layer is positioned between the auxiliary color-changing layer and the electrolyte layer. The laminated glass disclosed by the embodiment of the utility model can realize the compatible functions of color change and information display of the laminated glass through a specific film layer structure, and improve the use experience of a user. The application also provides a laminated glass control system.
Description
Technical Field
The utility model relates to the technical field of display glass, in particular to laminated glass.
Background
Building energy-saving glass plays an increasingly important role in the way of low-carbon and energy-saving industry development. At present, the energy-saving glass for buildings in China is mainly low-emissivity glass, so that sunlight passing through the window glass is greatly reduced, and the heat insulation performance of the window glass is improved, but when the energy-saving glass is used, only a single function of improving the heat insulation performance of the window glass can be realized, and more display information cannot be obtained from a body.
Based on this, it is an urgent need to provide a glass that can improve the insulating properties of the window glass and also can provide more display information.
Disclosure of Invention
The utility model provides laminated glass, which can realize the function of compatibility of the heat insulation performance and the photoelectric display performance of the window glass through the specific structural design of the film layer so as to increase the experience of a user.
Specifically, an embodiment of the present utility model provides a laminated glass, including: a color changing assembly and a photoelectric display assembly; the color-changing assembly includes: a first target substrate, a second target substrate, and an electrolyte layer interposed between the first target substrate and the second target substrate; the first target substrate includes: a first glass substrate; a first conductive layer on the first glass substrate; the main color-changing layer is positioned on one side of the first conductive layer away from the first glass substrate; the second target substrate includes: a second glass substrate; a second conductive layer on the second glass substrate; an auxiliary color-changing layer located at a side of the second conductive layer away from the second glass substrate, wherein the electrolyte layer is located between the main color-changing layer and the auxiliary color-changing layer; the first target substrate further includes: a first transition layer located between the primary color-changing layer and the electrolyte layer; the second target substrate further includes: a second transition layer located between the auxiliary color-changing layer and the electrolyte layer; the electrolyte layer includes: a lithium-containing compound, a high molecular polymer and an organic solvent; the lithium-containing compound is specifically: one or a combination of at least two of LiAsF6, liPF6, liBF4, CF3SO3Li, and LiClO 4; the high molecular polymer specifically comprises: one or a combination of several of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate and polyvinyl chloride; the organic solvent is used for dissolving the organic polymer of the high molecular polymer, and specifically comprises the following components: propylene carbonate, ethylene carbonate, diethyl carbonate, methyl ethyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, ethyl acetate, or a combination of at least two solvents; the electro-optical display assembly includes: a third glass substrate, a fourth glass substrate, and a display lamp interposed between the third glass substrate and the fourth glass substrate; wherein, the display lamp includes: red, green and blue LED beads; the third glass substrate of the optoelectronic display assembly is attached to the second glass substrate of the second target substrate.
In addition, the embodiment of the utility model discloses a laminated glass, which comprises: a color changing assembly and a photoelectric display assembly; the color-changing assembly includes: a first target substrate, a second target substrate, and an electrolyte layer interposed between the first target substrate and the second target substrate; the electrolyte layer includes: an organic solvent, a lithium-containing compound, and a high molecular polymer; the electro-optical display assembly includes: a third glass substrate, a fourth glass substrate, and a display lamp interposed between the third glass substrate and the fourth glass substrate; wherein, the display lamp includes: red, green and blue LED beads; the third glass substrate and the second target substrate of the photoelectric display assembly are attached to each other.
In one embodiment of the present utility model, the lithium-containing compound is specifically: one or a combination of at least two of LiAsF6, liPF6, liBF4, CF3SO3Li, and LiClO 4; the high molecular polymer specifically comprises: one or a combination of several of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate and polyvinyl chloride; the organic solvent includes: propylene carbonate, ethylene carbonate, diethyl carbonate, methyl ethyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, ethyl acetate, or a combination of at least two solvents.
In one embodiment of the utility model, the electrolyte layer is a liquid electrolyte layer; the color-changing assembly further includes: and a frame forming a receiving cavity with the first target substrate and the second target substrate to receive the liquid electrolyte layer.
In one embodiment of the present utility model, the electrolyte layer further includes: a curing agent; the electrolyte layer is a colloidal electrolyte layer or a solid electrolyte layer.
In one embodiment of the present utility model, the first target substrate includes: a first glass substrate; a first conductive layer on the first glass substrate; a main color-changing layer located on the first conductive layer; the second target substrate includes: a second glass substrate; a second conductive layer on the second glass substrate; an auxiliary color-changing layer positioned on the second conductive layer; the electrolyte layer is located between the main color-changing layer and the auxiliary color-changing layer, and the third glass substrate of the photoelectric display assembly is attached to the second glass substrate of the second target substrate.
In one embodiment of the utility model, the thicknesses of the first glass substrate, the first conductive layer, the primary color-changing layer, the second glass substrate, the second conductive layer, and the secondary color-changing layer are at least partially the same.
In one embodiment of the present utility model, the first target substrate further includes: a first transition layer located between the primary color-changing layer and the electrolyte layer; the second target substrate further includes: a second transition layer located between the auxiliary color-changing layer and the electrolyte layer; the first transition layer is a film layer formed by bonding the electrolyte layer and the main color-changing layer and then performing chemical reaction through heating treatment; the second transition layer is a film layer formed by the chemical reaction of the electrolyte layer and the auxiliary color-changing layer after being attached and subjected to heating treatment.
In one embodiment of the present utility model, the electrolyte layer further includes: and insulating the spacers to ensure that the first target substrate and the second target substrate are uniformly spaced.
In addition, in an embodiment of the present utility model, there is provided a laminated glass control system including: a laminated glass as claimed in any one of the preceding claims; and the control device is connected with the color-changing component and the photoelectric display component of the laminated glass so as to control the color change of the color-changing component and the information display of the photoelectric display component.
The technical scheme has the following advantages or beneficial effects: through a specific film layer structure, one side of the laminated glass can be subjected to stable and high-efficiency color change, so that the heat insulation performance of the glass is improved, the information display function of the other side of the laminated glass is improved, and the applicability of the laminated glass is improved; through setting up control system, the user can nimble control laminated glass in order to realize the display function, can increase user's use experience sense.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present utility model, the drawings required for the description of the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present utility model, and other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
Fig. 1 is a schematic view of a laminated glass according to an embodiment of the present utility model.
Fig. 2 is a schematic view showing an exploded structure of an electro-optical display assembly in the laminated glass of fig. 1.
Fig. 3 is a schematic structural view of a laminated glass control system according to another embodiment of the utility model.
Detailed Description
The following description of the embodiments of the present utility model will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are only some, but not all embodiments of the utility model. All other embodiments, which can be made by those skilled in the art based on the embodiments of the utility model without making any inventive effort, are intended to be within the scope of the utility model.
It should be noted that the terms "first," "second," "one side," "external," "internal," and the like in the description and in the claims of the present utility model are used for distinguishing between similar objects and not necessarily for describing a particular sequential or chronological order. It is to be understood that the terms so used are interchangeable under appropriate circumstances such that the embodiments of the utility model described herein are capable of operation in sequences other than those illustrated or otherwise described herein. Furthermore, the terms "comprises," "comprising," and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, system, article, or apparatus that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed but may include other steps or elements not expressly listed or inherent to such process, article, or apparatus.
According to the laminated glass provided by the embodiment of the utility model, the plurality of first display lamps and the plurality of second display lamps with the same light emitting direction are respectively arranged on the two adjacent side surfaces of the two glass, and the projections of the plurality of first display lamps and the plurality of second display lamps on the second side surfaces are mutually staggered, so that high-definition display with high lattice density is difficult to realize under the condition that the width of the conducting wire is not reduced in the prior art, the density of the display lamps on the glass is improved, the display pixels of the display glass are improved, and the high-lattice density display of the display lamps is realized.
Referring to fig. 1, which shows a laminated glass 10 disclosed in an embodiment of the present utility model, the laminated glass 10 includes, for example: a color shifting assembly 100 and an optoelectronic display assembly 200.
Wherein the color shifting assembly 100 is used to effect a color shift to improve the insulating properties of the glazing. The electro-optical display assembly 200 is used to enable display of information. Wherein the combination of the color-changing assembly 100 and the electro-optical display assembly 200 constitutes both sides of the laminated glass 10 with respect to the external environment, for example, the laminated glass 10 is installed on the side of a roof or a wall, and one side of the color-changing assembly 100 of the laminated glass 10 is used toward the external space, i.e., outdoors. The side of the electro-optical display assembly 200 of the laminated glass 10 faces the interior space, i.e., the room for use. However, in the present embodiment, the present utility model is not limited thereto, and the present utility model can be set and used according to actual situations.
Further, the color-changing assembly 100 includes, for example: the first target substrate 110, the second target substrate 130, and the electrolyte layer 120, the electrolyte layer 120 being interposed between the first target substrate 110 and the second target substrate 130. The electrolyte layer 120 includes, for example: organic solvents, lithium-containing compounds, and high molecular weight polymers. The electro-optical display assembly 200 includes, for example: a third glass substrate 201, a fourth glass substrate 203, and a display lamp 202 interposed between the third glass substrate 201 and the fourth glass substrate 203. The third glass substrate 201 of the electro-optical display assembly 200 is attached to the second target substrate 130.
Wherein the first target substrate 110, the second target substrate 130, and the electrolyte layer 120 combine to form a "sandwich" structure. The organic solvent is used for dissolving an organic polymer of the high molecular polymer, and specifically includes, for example: propylene carbonate, ethylene carbonate, diethyl carbonate, methyl ethyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, ethyl acetate, or a combination of at least two solvents. The lithium-containing compound is specifically, for example: liAsF 6 、LiPF 6 、LiBF 4 、CF 3 SO 3 Li and LiClO 4 Or a combination of at least two thereof. The high molecular polymer is specifically exemplified by: polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate, and polyvinyl chlorideOne or a combination of several kinds. The third glass substrate 201 and the fourth glass substrate 203 are, for example, float glass, ultra-white glass, high-alumina glass, medium-alumina glass, various-color glass (such as gray glass, green glass, lake blue glass, etc.), PET (Polyethylene terephthalate ) film materials, etc. Referring to fig. 2, the display lamps 202 are, for example, a plurality of LED lamps or the like, including, for example, red LED beads, green LED beads, and blue LED beads, and are embedded between the third glass substrate 201 and the fourth glass substrate 203. Each display lamp 202 also includes electrode pins. The plurality of LED lamps are connected to the conductive circuit 204 via the electrode pins, and are controlled by one end of the conductive circuit 204 and connected to the controller 205, wherein the controller 205 is, for example, an LED display driving chip, etc., it should be noted that the relative positions of the controller 205 and other structures shown in fig. 2 are only for better understanding of the present embodiment, and the specific position of the controller 205 is not limited in this embodiment. In this embodiment, the optoelectronic display assembly 200 is a conventional structure, and detailed arrangement of the display lamp and the glass substrate is omitted herein. The bonding manner of the third glass substrate 201 and the second target substrate 130 is, for example, bonding by glue bonding, high-temperature bonding, etc. in the prior art, and is not described in detail herein, so long as the two glass substrates are combined into one and are not easy to separate.
It should be noted that, the specific film structure of the present utility model is understood to be formed by combining the color-changing component 100 and the electro-optical display component 200, and in consideration of the operation of performing the wire arrangement by performing the laser etching on the glass substrate, in order to avoid the damage caused by performing the etching operation on both sides of the glass substrate, one of the glass substrates (one of the second glass substrate 134 and the third glass substrate 201 in the embodiment is not reduced when the two components (the color-changing component 100 and the electro-optical display component 200 in the embodiment) are combined. In the present embodiment, the thickness of one glass substrate at the bonding layer can be increased, for example, to reduce the use of one glass substrate.
Further, the electrolyte layer 120 is a liquid electrolyte layer. The color-changing assembly 100 also includes, for example: the frame forms a receiving chamber with the first target substrate 110 and the second target substrate 130 to receive the liquid electrolyte layer.
The frame is, for example, a rectangular frame, so as to be conveniently sleeved on the first target substrate 110 and the second target substrate 130, and the size and shape of the frame are set according to the first target substrate 110 and the second target substrate 130, which is not limited herein. The liquid electrolyte layer is accommodated in the accommodating cavity, and is injected between the first target substrate 110 and the second target substrate 130 for accommodating, for example, by means of pouring.
Further, the electrolyte layer 120 further includes, for example: the curing agent, electrolyte layer 120 is a colloidal electrolyte layer or a solid electrolyte layer.
Wherein the curing agent is used for curing the electrolyte, and comprises, for example: and an ultraviolet curing agent. When the electrolyte layer 120 is a colloidal electrolyte layer, for example, the electrolyte layer is injected between the first target substrate 110 and the second target substrate 130 by way of pouring, and then the colloidal electrolyte layer is irradiated with ultraviolet light so as to be cured and attached between the first target substrate 110 and the second target substrate 130. When the electrolyte layer 120 is a solid electrolyte layer, it is subjected to a heat treatment so as to be bonded between the first target substrate 110 and the second target substrate 130.
Specifically, the electrolyte layer 120 is an ion conductor electrolyte layer, and the materials thereof are mixed and selected to achieve the beneficial effect of ensuring the stability of the color change of the laminated glass 10. In addition, the states of the electrolyte layer 120 include, for example: liquid, colloidal and solid are understood herein to be the differences in the viscosity of the electrolyte. In the embodiment, the state of the electrolyte layer 120 and the material are selected and mixed, but not limited to this, and the state thereof can be designed according to practical requirements.
Further, the first target substrate 110 includes, for example: a first glass substrate 111, a first conductive layer 112, and a main color change layer 113. The first conductive layer 112 is located on the first glass substrate 111. The main color-changing layer 113 is located at a side of the first conductive layer 112 away from the first glass substrate 111. The second target substrate 130 includes, for example: a second glass substrate 134, a second conductive layer 133, and an auxiliary color-changing layer 132. The second conductive layer 133 is located on the second glass substrate 134. The auxiliary color-changing layer 132 is located at one side of the second conductive layer 133 away from the second glass substrate 134, the electrolyte layer 120 is located between the main color-changing layer 113 and the auxiliary color-changing layer 132, and the third glass substrate 201 of the optoelectronic display assembly 200 is attached to the second glass substrate 134 of the second target substrate 130.
The first glass substrate 111 and the second glass substrate 134 are, for example, float glass, ultra-white glass, high-alumina glass, medium-alumina glass, various-color glass (such as gray glass, green glass, lake blue glass, etc.), PET (Polyethylene terephthalate ) film materials, etc. In addition, one side of the first glass substrate 111 faces the outside, and the whole of the color changing assembly (100) faces the outside space, for example, the outside, and reduces light radiation by changing color to improve the heat insulation performance of the glass.
The materials of the first conductive layer 112 and the second conductive layer 133 are selected from, for example, a semiconductor oxide material, a metal material, or an organic conductive material. The semiconductor oxide material is, for example, one or a combination of at least two of FTO (fluorosilicon oxide), ITO (indium tin oxide), IGZO (indium gallium zinc oxide), AZO (aluminum zinc oxide), GZO (gallium zinc oxide), a combination thereof such as AZO and GZO, or a combination of three thereof such as FTO (fluorosilicon oxide), ITO (indium tin oxide) and GZO (gallium zinc oxide), a combination of even more, or the like. The metal material is, for example, at least one of silver (Ag), gold (Au), copper (Cu), and aluminum (Al). The organic conductive material is, for example: at least one of polyacetylene, polypyrrole, polyaniline and polythiophene. Of course, the first conductive layer 112 and the second conductive layer 133 may be any combination of the foregoing three types of materials, and the materials selected for the first conductive layer 112 and the second conductive layer 133 may be the same or different. The first conductive layer 112 and the second conductive layer 133 are coated on the first glass substrate 111 and the second glass substrate 134 with a semiconductor oxide material, a metal material, or an organic conductive material as a coating material, for example, under the condition of magnetron sputtering.
The main color-changing layer 113 is a solar spectrum adjusting functional layer, and the material of the main color-changing layer 113 is selected from one or more oxides in W, mo, no, ti, ta. Specifically, the primary color-changing layerFor example, the materials of (a) are: WO (WO) 3 、WMoO x 、WNoO x ，WMoTiO x 、WNbTaO x Etc., wherein x represents the oxygen element's stoichiometric value. The stoichiometric ratio of the oxide may be either oxygen sufficient or oxygen insufficient. The main color-changing layer 113 is formed by using one or a combination of at least two of W, mo, nb, ti, ta oxide as a target material under the condition of magnetron sputtering, and the main color-changing layer 113 is deposited on the first conductive layer 112 under the condition of magnetron sputtering.
The material of the auxiliary color-changing layer 132 is selected from at least two oxides in Ni, V, co, ir, fe, mn. Specifically, the material of the auxiliary color-changing layer 132 may be NiVOx, niCoO x 、NiIrO x 、NiFeO x Or a combination of three or even more. Wherein x represents the oxygen element metering value. The stoichiometric ratio of the oxide may be either oxygen sufficient or oxygen insufficient. The auxiliary color-changing layer 132 is formed by using one or a combination of at least two of Ni, V, co, ir, fe, mn oxide as a target material, and depositing the auxiliary color-changing layer 132 onto the second conductive layer 133.
Further, the thicknesses of the first glass substrate 111, the first conductive layer 112, the main color-changing layer 113, the second glass substrate 134, the second conductive layer 133, and the auxiliary color-changing layer 132 are at least partially the same.
The thicknesses of the first glass substrate 111 and the second glass substrate 134 are, for example, 0.02mm to less than 2mm. The thicknesses of the first conductive layer 112 and the second conductive layer 133 are, for example, each greater than 10nm and 300nm or less. The thickness of the main color-changing layer 113 is, for example, greater than 30nm and equal to or less than 500nm. The thickness of the auxiliary color-changing layer 132 is, for example, greater than 10nm and 300nm or less. In this embodiment, it is not limited to at least partially the same, but may also be different, and specifically may be set according to practical situations.
Further, the first target substrate 110 further includes, for example: the first transition layer 114 is located between the main color-changing layer 113 and the electrolyte layer 120. The second target substrate 130 further includes, for example: a second transition layer 131 between the auxiliary color-changing layer 132 and the electrolyte layer 120.
The first transition layer 114 is a film layer formed by bonding the electrolyte layer 120 and the main color-changing layer 113 and then performing a chemical reaction by a heat treatment. The second transition layer 131 is a film layer formed by bonding the electrolyte layer 120 and the auxiliary color-changing layer 132 and then performing a chemical reaction by a heat treatment.
Specifically, the material of the first transition layer 114 depends on the materials of the main color-changing layer 113 and the electrolyte layer 120. The material of the second transition layer 131 depends on the materials of the auxiliary color-changing layer 132 and the electrolyte layer 120. For example, when the material of the main color-changing layer 113 is W oxide and the material of the auxiliary color-changing layer 132 is Ni oxide, the first transition layer 114 is a LiWO salt and the second transition layer 131 is a LiNiO salt after the Li compound in the electrolyte layer 120 reacts with the oxides in the main color-changing layer 113 and the auxiliary color-changing layer 132. The beneficial effects of setting the film layer generation in the embodiment are as follows: under the condition of electrification, the movement of Li+ can be promoted, free extraction and insertion of Li+ are realized, namely the color-changing efficiency is improved, and in addition, the method can be understood that under the condition of electrification, the generation amount of Li+ can be improved, and the higher color-changing efficiency can be obtained only by a small amount of charges.
Further, in the electrolyte layer 120, for example, there are included: the spacers are insulated so that the first and second target substrates 110 and 130 are spaced apart at a uniform distance.
The insulating spacer is made of insulating materials in the prior art, such as porcelain, insulating piezoelectric material, and the like, and can play roles in supporting and spacing between the first target substrate layer 110 and the second target substrate layer 130, so that the thickness of the electrolyte layer 120 between the first target substrate layer 110 and the second target substrate layer 130 is uniform, and further the color of the glass is uniform.
In summary, according to the laminated glass provided by the embodiment of the utility model, through the specific film layer structure, one side of the laminated glass can be subjected to stable and high-efficiency color change, so that the heat insulation performance of the glass and the information display function of the other side are improved, and in the overall function realization, the use experience of a user can be increased.
Referring to fig. 3, another embodiment of the present utility model proposes a laminated glass control system 20, for example, including: a control device 21 and a laminated glass 10. The structure and function of the laminated glass 10 disclosed in this embodiment are as described in the previous embodiment, and will not be described here again. The control device 21 is for example a remote control for use by a user. The control device 21 is provided with function selection buttons for selecting the states presented on both sides of the laminated glass 10, and the laminated glass 10 receives corresponding control signals transmitted by the control device 21 to display the states.
For example, the laminated glass 10 is installed on a roof, one side of the color-changing assembly 100 in the laminated glass 10 faces outdoors, and the electro-optical display assembly 200 in the laminated glass 10 faces indoors. To adjust the transmittance of the color changing assembly 100 to sunlight, the remote control is operated to select a transmittance parameter, the control device 21 transmits a signal of the responsive transmittance parameter to the controller of the color changing assembly 100 of the laminated glass 10, and the controller of the color changing assembly 100 of the laminated glass 10 receives the signal to control li+ movement in the laminated glass 10 to promote free extraction or insertion of li+ to change the color of the laminated glass 10 on the outdoor side. Meanwhile, the controller 21 transmits the display content signal to the controller of the optoelectronic display assembly 200 of the laminated glass 10, and the controller of the optoelectronic display assembly 200 receives the display content signal to display the corresponding content on the indoor side of the laminated glass 10, wherein the controller of the color-changing assembly 100 is, for example, a singlechip, and the controller of the optoelectronic display assembly 200 is, for example, a display driving chip.
In summary, in the laminated glass system provided by the other embodiment of the present utility model, the control device connected to the laminated glass is provided, so that the user can select the color-changing parameters and the display content of the laminated glass independently, and the system is flexible to operate, and can further increase the user experience.
In addition, it should be understood that the foregoing embodiments are merely exemplary illustrations of the present utility model, and the technical solutions of the embodiments may be arbitrarily combined and matched without conflict in technical features, contradiction in structure, and departure from the purpose of the present utility model.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solution of the present utility model, and are not limiting; although the utility model has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit and scope of the technical solutions of the embodiments of the present utility model.
Claims (9)
1. A laminated glass (10), characterized by comprising:
a color changing assembly (100) and an optoelectronic display assembly (200);
the color-changing assembly (100) includes: a first target substrate (110), a second target substrate (130), and an electrolyte layer (120) interposed between the first target substrate (110) and the second target substrate (130);
the first target substrate (110) includes:
a first glass substrate (111);
a first conductive layer (112) on the first glass substrate (111);
a main color-changing layer (113) located on a side of the first conductive layer (112) away from the first glass substrate (111);
the second target substrate (130) includes:
a second glass substrate (134);
a second conductive layer (133) on the second glass substrate (134);
an auxiliary color-changing layer (132) located on a side of the second conductive layer (133) away from the second glass substrate (134), wherein the electrolyte layer (120) is located between the main color-changing layer (113) and the auxiliary color-changing layer (132);
the first target substrate (110) further includes: a first transition layer (114) located between the primary color-changing layer (113) and the electrolyte layer (120);
the second target substrate (130) further includes: a second transition layer (131) located between the auxiliary color-changing layer (132) and the electrolyte layer (120);
the electro-optical display assembly (200) includes: a third glass substrate (201), a fourth glass substrate (203), and a display lamp (202) interposed between the third glass substrate (201) and the fourth glass substrate (203); wherein the display lamp (202) comprises: red, green and blue LED beads;
wherein the third glass substrate (201) of the electro-optical display module (200) is bonded to the second glass substrate (134) of the second target substrate (130).
2. A laminated glass (10), characterized by comprising: a color changing assembly (100) and an optoelectronic display assembly (200);
the color-changing assembly (100) includes: a first target substrate (110), a second target substrate (130), and an electrolyte layer (120) interposed between the first target substrate (110) and the second target substrate (130);
the electro-optical display assembly (200) includes: a third glass substrate (201), a fourth glass substrate (203), and a display lamp (202) interposed between the third glass substrate (201) and the fourth glass substrate (203); wherein the display lamp (202) comprises: red, green and blue LED beads;
wherein the third glass substrate (201) of the electro-optical display assembly (200) is attached to the second target substrate (130).
3. A laminated glass according to claim 2, wherein the electrolyte layer (120) is a liquid electrolyte layer; the color-changing assembly (100) further comprises: and a frame forming a receiving chamber with the first target substrate (110) and the second target substrate (130) to receive the liquid electrolyte layer.
4. A laminated glass according to claim 2, wherein the electrolyte layer (120) further comprises: a curing agent; the electrolyte layer (120) is a colloidal electrolyte layer or a solid electrolyte layer.
5. A laminated glass according to claim 2, wherein the first target substrate (110) comprises:
a first glass substrate (111);
a first conductive layer (112) on the first glass substrate (111);
-a main colour-changing layer (113) located on said first electrically conductive layer (112);
the second target substrate (130) includes:
a second glass substrate (134);
a second conductive layer (133) on the second glass substrate (134);
an auxiliary color-changing layer (132) on the second conductive layer (133);
the electrolyte layer (120) is located between the main color-changing layer (113) and the auxiliary color-changing layer (132), and the third glass substrate (201) of the optoelectronic display assembly (200) is attached to the second glass substrate (134) of the second target substrate (130).
6. The laminated glass according to claim 5, wherein the thicknesses of the first glass substrate (111), the first conductive layer (112), the main color change layer (113), the second glass substrate (134), the second conductive layer (133), and the auxiliary color change layer (132) are at least partially the same.
7. The laminated glass according to claim 5, wherein the first target substrate (110) further comprises: a first transition layer (114) located between the primary color-changing layer (113) and the electrolyte layer (120);
the second target substrate (130) further includes: a second transition layer (131) located between the auxiliary color-changing layer (132) and the electrolyte layer (120);
wherein the first transition layer (114) is a film layer formed by bonding the electrolyte layer (120) and the main color-changing layer (113) and then performing a chemical reaction through heating treatment; the second transition layer (131) is a film layer formed by bonding the electrolyte layer (120) and the auxiliary color-changing layer (132) and then performing a chemical reaction through a heating treatment.
8. A laminated glass according to claim 2, wherein the electrolyte layer (120) further comprises: and insulating spacers so that the first target substrate (110) and the second target substrate (130) are spaced apart by a uniform distance.
9. A laminated glass control system (20), comprising:
the laminated glass (10) of any of claims 1 to 8;
and a control device (21) which is connected with the color changing component (100) and the photoelectric display component (200) of the laminated glass (10) and used for controlling the color changing of the color changing component (100) and the information display of the photoelectric display component (200).
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| Application Number | Priority Date | Filing Date | Title |
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| CN202320695952.4U CN220438719U (en) | 2023-03-27 | 2023-03-27 | Laminated glass and laminated glass control system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202320695952.4U CN220438719U (en) | 2023-03-27 | 2023-03-27 | Laminated glass and laminated glass control system |
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| CN220438719U true CN220438719U (en) | 2024-02-02 |
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| CN (1) | CN220438719U (en) |
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