CN220429544U - Transparent encapsulation front bezel and photovoltaic module that shocks resistance - Google Patents

Transparent encapsulation front bezel and photovoltaic module that shocks resistance Download PDF

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CN220429544U
CN220429544U CN202320792251.2U CN202320792251U CN220429544U CN 220429544 U CN220429544 U CN 220429544U CN 202320792251 U CN202320792251 U CN 202320792251U CN 220429544 U CN220429544 U CN 220429544U
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layer
transparent
thickness
front plate
impact
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孙楠楠
许先华
朱建飞
薛群山
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Zhongtian Photovoltaic Materials Co ltd
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Zhongtian Photovoltaic Materials Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

The utility model provides an impact-resistant transparent packaging front plate and a photovoltaic module. The anti-impact transparent packaging front plate comprises an anti-reflection layer (1), a weather-proof layer (2), a first bonding layer (31), a reinforcing layer (4), a second bonding layer (32) and a supporting layer (5); wherein: the anti-reflection layer (1) is a layer made of organic-inorganic hybrid nano materials; the support layer (5) comprises a transparent coating, a transparent PET layer and a transparent coating. The anti-impact transparent packaging front plate can ensure that the light transmittance reaches 80 percent, the ultraviolet blocking rate reaches 99.99 percent, and the testing requirement of 25mm hail impact in the IEC61215 testing standard is met; delamination risk does not occur between layers; under the performance requirement of ensuring the self light transmittance, the problems that the prior front plate is not impact-resistant, the material is not weather-resistant and is easy to turn yellow can be overcome.

Description

Transparent encapsulation front bezel and photovoltaic module that shocks resistance
Technical Field
The utility model relates to an impact-resistant transparent packaging front plate and a photovoltaic module, and belongs to the technical field of photovoltaics.
Background
In the photovoltaic field, the transparent packaging material used by the prior double-sided component or single-sided component mainly comprises glass, but the glass is heavy and thick and has no bending effect, so that the development requirement of the future photovoltaic component cannot be met; the conventional high polymer material front plate at present is difficult to meet the corresponding test standard requirements in terms of impact resistance.
In order to meet the use requirements of distributed photovoltaics, light flexible components have increasingly stringent requirements for packaging materials.
In the research of light flexible component packaging materials, light transmittance is a basic requirement for ensuring power output, and the use environment of the front plate is required to have good impact resistance, and the impact resistance of some current transparent polymer front plates has a great hidden trouble.
At present, the common polymer packaging material cannot meet the hail resistance experiment related to the impact resistance capability in the latest IEC standard due to the characteristics of the structure of the common polymer packaging material. For example: CN 215184007U proposes a transparent front plate, which mainly solves the problems of heavy weight and brittleness of the existing photovoltaic cell assembly using glass as the front plate, and proposes to use a 550 μm polyester film as an impact resistant layer. However, the polyester film with larger thickness is difficult to obtain in the current production process, and the production cost of the polyester film with the thickness of 550 μm is difficult to be produced in batches in the market at present. And the product bonded by the multilayer polyester film has the risk of delamination caused by smaller interlayer peeling force, for example, CN 215184007U is bonded with double-sided PET by adopting glue, and the risk of delamination exists in the using process, so that the photovoltaic module can not be ensured to meet the requirement of 15 years of outdoor service.
In addition, when a single-layer fluororesin material is used for protecting the resin glass fiber layer, the layer is easy to cause yellowing and ageing problems under the ultraviolet ageing condition, and the power generation efficiency of subsequent components is affected. For example: CN 208835079U proposes a lightweight impact-resistant photovoltaic module, which is a lightweight impact-resistant photovoltaic module meeting high light transmittance, and the module mainly uses a resin glass fiber layer to improve the impact resistance of a front plate, but only uses a single-layer fluororesin material to protect the resin glass fiber layer, so that the resin glass fiber layer is easy to be subjected to ultraviolet irradiation to generate obvious yellowing, and the power generation efficiency of the subsequent module is affected.
Disclosure of Invention
In order to solve the technical problem that a high polymer material front plate is not impact-resistant, the utility model aims to provide the transparent packaging front plate which has the advantages of light weight, strong impact resistance, difficult delamination and failure, no yellowing, higher power generation efficiency and the like.
In order to achieve the above purpose, the utility model provides an impact-resistant transparent packaging front plate, wherein the impact-resistant transparent packaging front plate comprises an anti-reflection layer, a weather-resistant layer, a first bonding layer, a reinforcing layer, a second bonding layer and a supporting layer;
wherein:
the anti-reflection layer is a layer made of organic-inorganic hybrid nano materials;
the support layer includes a transparent coating, a transparent PET layer, and a transparent coating.
According to a specific embodiment of the utility model, the anti-reflection layer, the weather-resistant layer, the first bonding layer, the reinforcing layer, the second bonding layer and the supporting layer are sequentially arranged.
According to a specific embodiment of the present utility model, preferably, the refractive index of the anti-reflection layer is 1.2 to 1.5.
According to a specific embodiment of the present utility model, preferably, the thickness of the anti-reflection layer is 3-5 μm.
According to a specific embodiment of the present utility model, preferably, the organic-inorganic hybrid nanomaterial serving as a material of the anti-reflection layer is a nano silica-polysiloxane hybrid material or a nano titania-polysiloxane hybrid material.
According to the specific embodiment of the utility model, the anti-reflection layer can play a good role in anti-reflection, and can also play roles in resisting abrasion and increasing the surface hardness of the material. The anti-reflection layer can be compounded on the surface of the weather-resistant layer by adopting a brushing method or a physical vapor deposition method such as vacuum evaporation, ion plating and the like.
According to the specific embodiment of the utility model, the weather-resistant layer can provide good ultraviolet blocking capability and weather resistance for the impact-resistant transparent packaging front plate.
According to a specific embodiment of the present utility model, the thickness of the weathering layer is preferably 280-320 μm, more preferably 300-320 μm.
According to a specific embodiment of the present utility model, preferably, the weather resistant layer is a single-sided coated photovoltaic front panel.
According to a specific embodiment of the present utility model, preferably, the single-sided coated photovoltaic front sheet is a polyvinylidene fluoride single-sided coated front sheet (KPX, KPC) or a polyvinyl fluoride single-sided coated front sheet (TPX).
According to a specific embodiment of the present utility model, preferably, the polyvinylidene fluoride-based single-sided coated front plate or the polyvinyl fluoride-based single-sided coated front plate includes a transparent film layer, a glue layer, a PET (polyethylene terephthalate) layer, and a transparent coating layer.
According to a specific embodiment of the present utility model, preferably, in the polyvinylidene fluoride-based single-sided coated front plate or the polyvinyl fluoride-based single-sided coated front plate, the transparent film layer is a PVDF (polyvinylidene fluoride) layer, an ECTFE (alternating copolymer of ethylene and chlorotrifluoroethylene 1:1) layer, a PVF (polyvinyl fluoride) layer, or an ETFE (ethylene-tetrafluoroethylene copolymer) layer, and has a thickness of 15 to 30 μm.
According to a specific embodiment of the present utility model, preferably, in the polyvinylidene fluoride single-sided coated front plate or the polyvinyl fluoride single-sided coated front plate, the glue layer is a polyurethane glue layer, and the thickness is 5 to 50 μm, more preferably 5 to 10 μm.
According to a specific embodiment of the present utility model, preferably, in the polyvinylidene fluoride-based single-sided coated front plate or the polyvinyl fluoride-based single-sided coated front plate, the thickness of the PET layer is 250 to 280 μm.
According to a specific embodiment of the present utility model, preferably, in the polyvinylidene fluoride-based single-sided coated front plate or the polyvinyl fluoride-based single-sided coated front plate, the transparent coating layer is a FEVE (fluorocarbon resin) layer, a PVDF layer, a PVF layer, or an ETFE layer, and has a thickness of 5 to 15 μm. Preferably, the main component of the transparent coating is fluorine-containing paint doped with metal oxide nano particles, for example, FEVE, PVDF, PVF, ETFE and other fluorine-containing paint with main components and metal oxide nano materials such as nanometer yttrium oxide, nanometer cerium oxide, nanometer lanthanum oxide and the like.
According to a specific embodiment of the present utility model, preferably, the polyvinylidene fluoride single-sided coated front plate includes a transparent film layer, a glue layer, a PET layer, and a transparent coating layer;
wherein the transparent film layer is a PVDF layer with the thickness of 15-30 μm;
the glue layer is a polyurethane glue layer with the thickness of 5-50 mu m;
the thickness of the PET layer is 250-280 mu m;
the transparent coating is a FEVE layer, a PVDF layer, a PVF layer or an ETFE layer, and the thickness is 5-15 mu m.
According to a specific embodiment of the present utility model, preferably, the polyvinyl fluoride type single-sided coated front plate includes a transparent film layer, a glue layer, a PET layer, and a transparent coating layer;
wherein the transparent film layer is a PVF layer with the thickness of 15-30 mu m;
the glue layer is a polyurethane glue layer with the thickness of 5-50 mu m;
the thickness of the PET layer is 250-280 mu m;
the transparent coating is a FEVE layer, a PVDF layer, a PVF layer or an ETFE layer, and the thickness is 5-15 mu m.
According to a specific embodiment of the present utility model, preferably, the first adhesive layer is a thermoplastic adhesive film or a thermosetting adhesive film, more preferably an EVA adhesive film, a POE adhesive film, an EPE adhesive film, or the like, and has a thickness of 100 to 200 μm, more preferably 120 to 200 μm; the second adhesive layer is a thermoplastic adhesive film or a thermosetting adhesive film, more preferably an EVA adhesive film, a POE adhesive film or an EPE adhesive film, and the like, and has a thickness of 100-200 μm, more preferably 120-200 μm. The adhesive layer can bond two adjacent layers together well.
According to a specific embodiment of the present utility model, preferably, the reinforcing layer is a glass fiber layer.
According to a specific embodiment of the present utility model, the thickness of the reinforcing layer is preferably 10 to 100 μm, more preferably 50 to 100 μm.
According to a specific embodiment of the present utility model, the thickness of the support layer is preferably 200 to 300 μm, more preferably 260 to 300 μm.
According to a specific embodiment of the utility model, the main material of the supporting layer is a double-sided coated photovoltaic front panel material (CPC), which mainly plays a role in supporting the materials of each layer.
According to a specific embodiment of the present utility model, preferably, in the support layer, the transparent coating layer is a FEVE layer, a PVDF layer, a PVF layer, or an ETFE layer, and has a thickness of 5 to 15 μm.
According to a specific embodiment of the present utility model, preferably, in the support layer, the transparent PET layer has a thickness of 250 to 280 μm.
According to the specific embodiment of the utility model, the transparent film and the glue layer in the weather-resistant layer have good ultraviolet blocking capability, and can play a role in protecting the inner layer material. Moreover, the PET layer used for the weather-resistant layer and the supporting layer can play a role in supporting each layer and blocking certain ultraviolet. The transparent coating used for the weather-proof layer and the supporting layer can play roles of assisting in enhancing the bonding capability between layers and increasing the light transmittance.
The utility model also provides a photovoltaic module, wherein the photovoltaic module is provided with the impact-resistant transparent packaging front plate.
According to the utility model, the glass fiber layer is arranged, so that the problem that an independent high polymer material is not impact-resistant can be solved, the light weight is realized, and the high impact resistance is provided; the transparent coating and the bonding layer are arranged, so that the delamination failure problem of each layer in the use process can be effectively avoided; the weather-resistant layer can still have ultraviolet blocking capability of more than 95% after ultraviolet irradiation of 500kwh, so that the inner layer is effectively ensured not to yellow after ultraviolet aging, and the power generation of the component is not influenced; the anti-reflection functional layers are arranged between the layers, so that the solar energy can be effectively utilized to increase the power generation efficiency when the anti-reflection functional layers are used as front plate packaging materials.
According to the anti-impact transparent packaging front plate, through adding anti-reflection components in the joint of each layer and the outermost layer structure, the initial light transmittance can be guaranteed to reach 80%, the ultraviolet blocking rate can reach 99.99%, and the testing requirement of 25mm hail impact in the IEC61215 testing standard can be met; delamination risk does not occur between layers; under the performance requirement of ensuring the self light transmittance, the problems that the prior front plate is not impact-resistant, the material is not weather-resistant and is easy to turn yellow can be overcome.
The impact-resistant transparent packaging front plate is mainly applied to the photovoltaic field, can be used as a light flexible component at a roof curtain wall and the like with weaker bearing capacity, and can be used as a photovoltaic component front plate after being laminated with an adhesive film.
Drawings
Fig. 1 is a schematic structural view of an impact-resistant transparent packaging front plate provided in embodiment 1.
The main reference numerals illustrate:
an anti-reflection layer 1, a weather-proof layer 2, a first bonding layer 31, a reinforcing layer 4, a second bonding layer 32 and a supporting layer 5.
Detailed Description
The technical solution of the present utility model will be described in detail below for a clearer understanding of technical features, objects and advantageous effects of the present utility model, but should not be construed as limiting the scope of the present utility model.
Example 1
Embodiment 1 provides an impact-resistant transparent packaging front plate, and the structure of the impact-resistant transparent packaging front plate is shown in fig. 1.
The anti-impact transparent packaging front plate comprises an anti-reflection layer 1, a weather-proof layer 2, a first bonding layer 31, a reinforcing layer 4, a second bonding layer 32 and a supporting layer 5 which are sequentially arranged;
wherein:
the anti-reflection layer 1 is a layer made of organic-inorganic hybrid nano materials, in particular to a nano silicon dioxide-polysiloxane hybrid material or a nano titanium dioxide-polysiloxane hybrid material; the refractive index of the anti-reflection layer 1 is 1.42, and the thickness is 5 mu m;
the weather-resistant layer 2 is a polyvinylidene fluoride single-sided coating front plate and comprises a transparent film layer, a glue layer, a PET layer and a transparent coating, wherein: the transparent film layer is a PVDF layer with the thickness of 30 mu m; the glue layer is a polyurethane glue layer with the thickness of 10 mu m; the thickness of the PET layer is 280 μm; the transparent coating is a FEVE layer with the thickness of 15 μm;
the first adhesive layer 31 is an EVA adhesive film with the thickness of 200 mu m;
the reinforcing layer 4 is a glass fiber layer with the thickness of 100 mu m;
the second adhesive layer 32 is an EVA adhesive film with the thickness of 200 mu m;
the support layer 5 comprises a transparent coating, a transparent PET layer and a transparent coating, wherein the two transparent coatings are FEVE layers respectively, and the thickness of the two transparent coatings is 15 mu m respectively; the thickness of the transparent PET layer was 280. Mu.m.
The performance of the impact resistant transparent packaging front plate of example 1 with other structured products was tested, wherein:
the light transmittance is detected as follows: GB/T2680-2021 building glass visible light transmittance, sunlight direct transmittance, solar total transmittance, ultraviolet transmittance and related window glass parameters are measured;
impact resistance is carried out according to IEC61215 related regulations;
the detection of delamination was performed as follows: GB/T2790-1995 180 adhesive 180 degree peel strength test method flexible material versus rigid material;
the detection of yellowing is performed in the following manner: GB/T7921-2008 uniform color space and color difference formula.
In the above test, light transmittance, interlayer peeling, ultraviolet aging yellowing are the results of evaluation of individual material tests, and impact resistance is the result of evaluation of performance of the test after the assembly is made.
Specific test results are shown in Table 1.
TABLE 1
Wherein:
fluororesin+glass fiber means: adopting a structure consisting of 50 mu m PVDF film, 200 mu m EVA and 400 mu m glass fiber;
uncoated refers to: the structure of weather-resistant layer, adhesive layer 1, reinforcing layer and adhesive layer 2+ support is directly adopted without adding the uppermost anti-reflection layer in the embodiment 1, and the specific materials and thickness are consistent with those in the embodiment 1;
the weather-proof layer is not used for: the other structures were the same as in example 1 without adding the weathering layer in example 1;
the thinning of the weathering layer to 200 μm (PVDF film 15 μm, PET 175 μm, subbing layer 5 μm, coating 5 μm) means: the weather-resistant layer was subjected to thinning treatment on the basis of example 1;
the weather-resistant layer structure is formed by coating photovoltaic front panel materials (CPCs) with the same thickness on two sides, and the method comprises the following steps: the weather-resistant layer of example 1 was modified to have the same structure as the support layer, and the other was the same as example 1;
the unsupported layer refers to: the support layer was omitted on the basis of example 1, the others being identical to example 1;
the glass fiber-free layer refers to: the reinforcing layer (glass fiber layer) was omitted from example 1, and the other was the same as in example 1.
"pass" in the column of impact resistance refers to the corresponding sample being able to pass a 25mm size hail experiment at an impact velocity of 23m/s in a 25mm hail experiment.
"undetectable" in each interlayer peeling means: the peel force between the layers was very small and could not be measured.
From the data in table 1, it can be seen that: compared with products with other structures, the impact-resistant transparent packaging front plate can effectively solve the problem that a high polymer material is not impact-resistant, and meets the requirements of IEC61215 on hail resistance experiments; the light transmittance of the impact-resistant transparent packaging front plate can be kept above 80%; after ultraviolet aging is carried out for 300kwh, the yellowing value of the front plate packaging material is less than 0.5, so that the subsequent power generation of the assembly can be effectively ensured.

Claims (13)

1. The anti-impact transparent packaging front plate is characterized by comprising an anti-reflection layer (1), a weather-proof layer (2), a first bonding layer (31), a reinforcing layer (4), a second bonding layer (32) and a supporting layer (5);
wherein:
the anti-reflection layer (1) is a layer made of organic-inorganic hybrid nano materials;
the support layer (5) comprises a transparent coating, a transparent PET layer and a transparent coating.
2. The impact resistant transparent encapsulation front plate according to claim 1, characterized in that the refractive index of the anti-reflection layer (1) is 1.2-1.5.
3. The impact resistant transparent packaging front plate according to claim 1 or 2, characterized in that the thickness of the anti-reflection layer (1) is 3-5 μm.
4. The impact resistant transparent encapsulation front panel according to claim 1, characterized in that the weatherable layer (2) is a single-sided coated photovoltaic front panel.
5. The impact resistant transparent encapsulation front sheet of claim 4, wherein the single-sided coated photovoltaic front sheet is a polyvinylidene fluoride-based single-sided coated front sheet or a polyvinyl fluoride-based single-sided coated front sheet.
6. The impact resistant transparent packaging front plate according to claim 4, characterized in that the thickness of the weathering layer (2) is 280-320 μm.
7. The impact resistant transparent encapsulation front panel of claim 5, wherein the polyvinylidene fluoride-based single-sided coated front panel or the polyvinyl fluoride-based single-sided coated front panel comprises a transparent film layer, a glue layer, a PET layer, and a transparent coating layer;
wherein the transparent film layer is a PVDF layer, an ECTFE layer, a PVF layer or an ETFE layer, and the thickness is 15-30 mu m;
the glue layer is a polyurethane glue layer with the thickness of 5-50 mu m;
the thickness of the PET layer is 250-280 mu m;
the transparent coating is a FEVE layer, a PVDF layer, a PVF layer or an ETFE layer, and the thickness is 5-15 mu m.
8. The impact resistant transparent packaging front plate according to claim 1, characterized in that the first adhesive layer (31) is a thermoplastic adhesive film or a thermosetting adhesive film, with a thickness of 100-200 μm;
the second adhesive layer (32) is a thermoplastic adhesive film or a thermosetting adhesive film, and the thickness is 100-200 mu m.
9. The impact resistant transparent encapsulation front panel according to claim 1, characterized in that the reinforcement layer (4) is a glass fiber layer.
10. The impact resistant transparent packaging front plate according to claim 9, characterized in that the thickness of the stiffening layer (4) is 10-100 μm.
11. The impact resistant transparent packaging front plate according to claim 1, characterized in that the thickness of the support layer (5) is 200-300 μm.
12. The impact resistant transparent packaging front plate according to claim 1 or 11, characterized in that in the supporting layer (5), the transparent coating is a FEVE layer, a PVDF layer, a PVF layer or an ETFE layer, with a thickness of 5-15 μm;
the thickness of the transparent PET layer is 250-280 mu m.
13. A photovoltaic module characterized in that it has an impact-resistant transparent encapsulation front sheet according to any one of claims 1 to 12.
CN202320792251.2U 2023-04-11 2023-04-11 Transparent encapsulation front bezel and photovoltaic module that shocks resistance Active CN220429544U (en)

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CN202320792251.2U CN220429544U (en) 2023-04-11 2023-04-11 Transparent encapsulation front bezel and photovoltaic module that shocks resistance

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CN202320792251.2U CN220429544U (en) 2023-04-11 2023-04-11 Transparent encapsulation front bezel and photovoltaic module that shocks resistance

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